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1.
Jade Star Lackey John W. Valley Hans J. Hinke 《Contributions to Mineralogy and Petrology》2006,151(1):20-44
Peraluminous granitoids provide critical insight as to the amount and kinds of supracrustal material recycled in the central
Sierra Nevada batholith, California. Major element concentrations indicate Sierran peraluminous granitoids are high-SiO2 (68.9–76.9) and slightly peraluminous (average molar Al2O3/(CaO + Na2O + K2O)=1.06). Both major and trace element trends mimic those of other high-silica Sierran plutons. Garnet (Grt) in the peraluminous
plutons is almandine–spessartine-rich and of magmatic origin. Low grossular contents are consistent with shallow (<4 kbar)
depths of garnet crystallization. Metasediments of the Kings Sequence commonly occur as wallrocks associated with the plutons,
including biotite schists that are highly peraluminous (A/CNK=2.25) and have high whole rock (WR) δ18O values (9.6–21.8‰, average=14.5±2.9‰, n=26). Ultramafic wallrocks of the Kings–Kaweah ophiolite have lower average δ18O (7.1±1.3‰, n=9). The δ18O(WR) of the Kings Sequence is variable from west to east. Higher δ18O values occur in the west, where quartz in schists is derived from marine chert; values decrease eastward as the proportion
of quartz from igneous and metamorphic sources increases. Peraluminous plutons have high δ18O(WR) values (9.5–13‰) consistent with supracrustal enrichment of their sources. However, relatively low initial 87Sr/86Sr values (0.705–0.708) indicate that the supracrustal component in the source of peraluminous magmas was dominantly altered
ocean crust and/or greywacke. Also, plutons lack or have very low abundances (<1% of grains) of inherited zircon (Zrc) cores.
Average δ18O(Zrc) is 7.9‰ in peraluminous plutons, a higher value than in coeval metaluminous plutons (6–7‰). Diorites associated with
peraluminous plutons also have high δ18O(Zrc), 7.4–8.3‰, which is consistent with the diorites being derived from a similar source. Magmatic garnet has variable
δ18O (6.6–10.5‰, avg.=7.9‰) due to complex contamination and crystallization histories, evidenced by multiple garnet populations
in some rocks. Comparison of δ18O(Zrc) and δ18O(Grt) commonly reveals disequilibrium, which documents evolving magma composition. Minor (5–7%) contamination by high δ18O wallrocks occurred in the middle and upper crust in some cases, although low δ18O wallrock may have been a contaminant in one case. Overall, oxygen isotope analysis of minerals having slow oxygen diffusion
and different times of crystallization (e.g., zircon and garnet), together with detailed textural analysis, can be used to
monitor assimilation in peraluminous magmas. Moreover, oxygen isotope studies are a valuable way to identify magmatic versus
xenocrystic minerals in igneous rocks.
Electronic Supplementary Material Supplementary material is available for this article at 相似文献
2.
I. J. Richards Theodore C. Labotka Robert T. Gregory 《Contributions to Mineralogy and Petrology》1996,123(2):202-221
Late Proterozoic to Cambrian carbonate rocks from Lone Mountain, west central Nevada, record multiple post-depositional events
including: (1) diagenesis, (2) Mesozoic regional metamorphism, (3) Late Cretaceous contact metamorphism, related to the emplacement
of the Lone Mountain granitic pluton and (4) Tertiary hydrothermal alteration associated with extension, uplift and intrusion
of silicic porphyry and lamprophyre dikes. Essentially pure calcite and dolomite marbles have stable isotopic compositions
that can be divided into two groups, one with positive δ13C values from+3.1 to +1.4 ‰ (PDB) and high δ18O values from +21.5 to +15.8 ‰ (SMOW), and the other with negative δ13C values from –3.3 to –3.6‰ and low δ18O values from +16.9 to +11.1‰. Marbles also contain minor amounts of quartz, muscovite and phlogopite. Brown and blue luminescent,
clear, smooth textured quartz grains from orange luminescent calcite marbles have high δ18O values from +23.9 to +18.1‰, while brown luminescent, opaque, rough textured quartz grains from red luminescent dolomite
marbles typically have low δ18O values from +2.0 to +9.3‰. The δ18O values of muscovite and phlogopite from marbles are typical of micas in metamorphic rocks, with values between +10.4 and
+14.4‰, whereas mica δD values are very depleted, varying from −102 to −156‰. No significant lowering of the δ18O values of Lone Mountain carbonates is inferred to have occurred during metamorphism as a result of devolatilization reactions
because of the essentially pure nature of the marbles. Bright luminescence along the edges of fractures, quartz cements and
quartz overgrowths in dolomite marbles, low δD values of micas, negative δ13C values and low δ18O values of calcite and dolomite, and depleted δ18O values of quartz from dolomite marbles all indicate that meteoric fluids interacted with Lone Mountain marbles during the
Tertiary. Partial oxygen isotopic exchange between calcite and low 18O meteoric fluids lowered the δ18O values of calcite, resulting in uniform quartz-calcite fractionations that define an apparent pseudoisotherm. These quartz-calcite
fractionations significantly underestimate both the temperature of metamorphism and the temperature of post-metamorphic alteration.
Partial oxygen isotopic exchange between quartz and meteoric fluids also resulted in 18O depletion of quartz from dolomite marbles. This partial exchange was facilitated by an increase in the surface area of the
quartz as a result of its dissolution by meteoric fluids. The negative δ13C values in carbonates result from the oxidation of organic material by meteoric fluids following metamorphism. Stable isotopic
data from Lone Mountain marbles are consistent with the extensive circulation of meteoric hydrothermal fluids throughout western
Nevada in Tertiary time.
Received: 1 February 1994/Accepted: 12 September 1995 相似文献
3.
Distinguishing magmatic from subsolidus epidote: laser probe oxygen isotope compositions 总被引:1,自引:0,他引:1
Epidote occurs in four textural varieties in the Mount Lowe intrusion of southern California: euhedra, anhedra, intergrowths
and cross-cutting veins. Of these, conspicuous elongate euhedra, which range up to 3 cm in length, meet most of the established
textural criteria for magmatic epidote. Equant anhedral grains, which are ˜5 mm in diameter, are texturally ambiguous although
rare allanite cores are suggestive of a magmatic origin. Epidote intergrowths with hornblende and biotite also meet certain
textural criteria for crystallization from a magma, notably, euhedral faces against biotite. Finally, late-stage veins of
epidote cross-cut all phases in the rock and are likely subsolidus. Oxygen isotopic compositions of these four textural varieties
of epidote determined using the laser probe indicate that the use of textural criteria alone in establishing epidote parageneses
can be misleading. Intracrystalline δ18O variations in the euhedra document both magmatic and subsolidus compositions. Oxygen isotope compositions are bimodal averaging
5.36 ± 0.13‰ (n = 11) and 4.66 ± 0.23‰ (n = 21). These data combined with plagioclase and zircon δ18O values are interpreted to indicate that magmatic oxygen isotopic compositions have been preserved where epidote δ18O is greater than 5‰. Significant portions of each euhedral crystal have been affected by subsolidus exchange and are characterized
by epidote δ18O values less than 5‰. Intracrystalline δ18O values of epidote anhedra range from 4.50 to 6.08‰ and thus also document both magmatic and subsolidus compositions. Subsolidus
exchange is volumetrically less significant in the anhedra than in the euhedra. Values of δ18O for intergrowths and late-stage cross-cutting veins of epidote average 3.81 ± 0.22‰ and document clearly subsolidus growth.
The data confirm that in the Mount Lowe intrusion, large euhedra of epidote are magmatic in origin, consistent with textural
evidence. The data also indicate that equant anhedra of epidote are also magmatic in origin and thus the absence of good crystal
faces does not necessarily indicate subsolidus growth. The subsolidus origin of intergrowths of epidote with euhedral faces
against biotite indicates that well developed crystal faces do not require growth from a magma. Finally, the subsolidus origin
of the vein epidote is consistent with textural evidence. The increased resolution available with laser-based oxygen isotope
measurements offers an important test for documenting whether epidote is of magmatic or subsolidus origin. Given the barometric
significance of magmatic epidote, oxygen isotope compositions can be used to aid in the interpretation of epidote-bearing
plutons.
Received: 9 April 1996 / Accepted: 3 August 1996 相似文献
4.
Ian Cartwright Ian S. Buick Roland Maas 《Contributions to Mineralogy and Petrology》1997,128(4):335-351
The Jervois region of the Arunta Inlier, central Australia, contains para- and orthogneisses that underwent low-pressure
amphibolite facies metamorphism (P = 200–300 MPa, T = 520–600 °C). Marble layers cut by metre-wide quartz + garnet ± epidote veins comprise calcite, quartz, epidote, clinopyroxene,
grandite garnet, and locally wollastonite. The marbles also contain locally discordant decimetre-thick garnet and epidote
skarn layers. The mineral assemblages imply that the rocks were infiltrated by water-rich fluids (XCO2 = 0.1–0.3) at ∼600 °C. The fluids were probably derived from the quartz-garnet vein systems that represent conduits for fluids
exsolved from crystallizing pegmatites emplaced close to the metamorphic peak. At one locality, the marble has calcite (Cc)
δ18O values of 9–18‰ and garnet (Gnt) δ18O values of 10–14‰. The δ18O(Gnt) values are only poorly correlated with δ18O(Cc), and the δ18O values of some garnet cores are higher than the rims. The isotopic disequilibrium indicates that garnet grew before the
δ18O values of the rock were reset. The marbles contain ≤15% garnet and, for water-rich fluids, garnet-forming reactions are
predicted to propagate faster than O-isotopes are reset. The Sm-Nd and Pb-Pb ages of garnets imply that fluid flow occurred
at 1750–1720 Ma. There are no significant age differences between garnet cores and rims, suggesting that fluid flow was relatively
rapid. Texturally late epidote has δ18O values of 1.5–6.2‰ implying δ18O(H2O) values of 2–7‰. Waters with such low-δ18O values are probably at least partly meteoric in origin, and the epidote may be recording the late influx of meteoric water
into a cooling hydrothermal system.
Received: 29 April 1996 / Accepted: 12 March 1997 相似文献
5.
Mark E. Brandriss Richard J. Nevle Dennis K. Bird James R. O’Neil 《Contributions to Mineralogy and Petrology》1995,121(1):74-86
Hydrogen and oxygen isotope analyses have been made of hydrous minerals in gabbros and basaltic xenoliths from the Eocene
Kap Edvard Holm intrusive complex of East Greenland. The analyzed samples are of three types: (1) primary igneous hornblendes
and phlogopites that crystallized from partial melts of hydrothermally altered basaltic xenoliths, (2) primary igneous hornblendes
that formed during late–magmatic recrystallization of layered gabbroic cumulates, and (3) secondary actinolite, epidote and
chlorite that formed during subsolidus alteration of both xenoliths and gabbros. Secondary actinolite has a δ18O value of −5.8‰ and a δD value of −158‰. These low values reflect subsolidus alteration by low–δ18O, low–δD hydrothermal fluids of meteoric origin. The δD value is lower than the −146 to −112‰ values previously reported
for amphiboles from other early Tertiary meteoric–hydrothermal systems in East Greenland and Scotland, indicating that the
meteoric waters at Kap Edvard Holm were isotopically lighter than typical early Tertiary meteoric waters in the North Atlantic
region. This probably reflects local climatic variations caused by formation of a major topographic dome at about the time
of plutonism and hydrothermal activity. The calculated isotopic composition of the meteoric water is δD=−110 ± 10‰, δ18O ≈−15‰. Igneous hornblendes and phlogopites from pegmatitic pods in hornfelsed basaltic xenoliths have δ18O values between −6.0 and −3.8‰ and δD values between −155 and −140‰. These are both much lower than typical values of fresh
basalts. The oxygen isotope fractionations between pegmatitic hornblendes and surrounding hornfelsic minerals are close to
equilibrium fractionations for magmatic temperatures, indicating that the pegmatites crystallized from low–δ18O partial melts of xenoliths that had been hydrothermally altered and depleted in 18O prior to stoping. The pegmatitic minerals may have crystallized with low primary δD values inherited from the altered country
rocks, but these values were probably overprinted extensively by subsolidus isotopic exchange with low–δD meteoric–hydrothermal
fluids. This exchange was facilitated by rapid self–diffusion of hydrogen through the crystal structures. Primary igneous
hornblendes from the plutonic rocks have δ18O values between +2.0 and +3.2‰ and δD values between −166 and −146‰. The 18O fractionations between hornblendes and coexisting augites are close to equilibrium fractionations for magmatic temperatures,
indicating that the hornblendes crystallized directly from the magma and subsequently underwent little or no oxygen exchange.
The hornblendes may have crystallized with low primary δD values, due to contamination of the magma with altered xenolithic
material, but the final δD values were probably controlled largely by subsolidus isotopic exchange. This inference is based
partly on the observation that coexisting plagioclase has been extensively depleted in 18O via a mineral–fluid exchange reaction that is much slower than the hydrogen exchange reaction in hornblende. It is concluded
that all hydrous minerals in the study area, whether igneous or secondary, have δD values that reflect extensive subsolidus
isotopic equilibration with meteoric–hydrothermal fluids.
Received: 22 March 1994 / Accepted: 26 January 1995 相似文献
6.
C. O'Reilly G. R. T. Jenkin M. Feely D. H. M. Alderton A. E. Fallick 《Contributions to Mineralogy and Petrology》1997,129(2-3):120-142
Fluid inclusions in granite quartz and three generations of veins indicate that three fluids have affected the Caledonian
Galway Granite. These fluids were examined by petrography, microthermometry, chlorite thermometry, fluid chemistry and stable
isotope studies. The earliest fluid was a H2O-CO2-NaCl fluid of moderate salinity (4–10 wt% NaCl eq.) that deposited late-magmatic molybdenite mineralised quartz veins (V1) and formed the earliest secondary inclusions in granite quartz. This fluid is more abundant in the west of the batholith,
corresponding to a decrease in emplacement depth. Within veins, and to the east, this fluid was trapped homogeneously, but
in granite quartz in the west it unmixed at 305–390 °C and 0.7–1.8 kbar. Homogeneous quartz δ18O across the batholith (9.5 ± 0.4‰n = 12) suggests V1 precipitation at high temperatures (perhaps 600 °C) and pressures (1–3 kbar) from magmatic fluids. Microthermometric data
for V1 indicate lower temperatures, suggesting inclusion volumes re-equilibrated during cooling. The second fluid was a H2O-NaCl-KCl, low-moderate salinity (0–10 wt% NaCl eq.), moderate temperature (270–340 °C), high δD (−18 ± 2‰), low δ18O (0.5–2.0‰) fluid of meteoric origin. This fluid penetrated the batholith via quartz veins (V2) which infill faults active during post-consolidation uplift of the batholith. It forms the most common inclusion type in
granite quartz throughout the batholith and is responsible for widespread retrograde alteration involving chloritization of
biotite and hornblende, sericitization and saussuritization of plagioclase, and reddening of K-feldspar. The salinity was
generated by fluid-rock interactions within the granite. Within granite quartz this fluid was trapped at 0.5–2.3 kbar, having
become overpressured. This fluid probably infiltrated the Granite in a meteoric-convection system during cooling after intrusion,
but a later age cannot be ruled out. The final fluid to enter the Granite and its host rocks was a H2O-NaCl-CaCl2-KCl fluid with variable salinity (8–28 wt% NaCl eq.), temperature (125–205 °C), δD (−17 to −45‰), δ18O (−3 to + 1.2‰), δ13CCO2 (−19 to 0‰) and δ34Ssulphate (13–23‰) that deposited veins containing quartz, fluorite, calcite, barite, galena, chalcopyrite sphalerite and pyrite (V3). Correlations of salinity, temperature, δD and δ18O are interpreted as the result of mixing of two fluid end-members, one a high-δD (−17 to −8‰), moderate-δ18O (1.2–2.5‰), high-δ13CCO2 (> −4‰), low-δ34Ssulphate (13‰), high-temperature (205–230 °C), moderate-salinity (8–12 wt% NaCl eq.) fluid, the other a low-δD (−61 to −45‰), low-δ18O (−5.4 to −3‰), low-δ13C (<−10‰), high-δ34Ssulphate (20–23‰) low-temperature (80–125 °C), high-salinity (21–28 wt% NaCl eq.) fluid. Geochronological evidence suggests V3 veins are late Triassic; the high-δD end-member is interpreted as a contemporaneous surface fluid, probably mixed meteoric
water and evaporated seawater and/or dissolved evaporites, whereas the low-δD end-member is interpreted as a basinal brine
derived from the adjacent Carboniferous sequence. This study demonstrates that the Galway Granite was a locus for repeated
fluid events for a variety of reasons; from expulsion of magmatic fluids during the final stages of crystallisation, through
a meteoric convection system, probably driven by waning magmatic heat, to much later mineralisation, concentrated in its vicinity
due to thermal, tectonic and compositional properties of granite batholiths which encourage mineralisation long after magmatic
heat has abated.
Received: 3 April 1996 / Accepted: 5 May 1997 相似文献
7.
Miriela María Ulloa Santana Márcia Abrahão Moura Gema R. Olivo Nilson Francisquini Botelho T. Kurtis Kyser Bernhard Bühn 《Mineralium Deposita》2011,46(1):91-104
The Camagüey district, Cuba, is known for its epithermal precious metal deposits in a Cretaceous volcanic arc setting. Recently,
the La Unión prospect was discovered in the southern part of the district, containing gold and minor copper mineralization
interpreted as porphyry type. Mineralization is hosted in a 73.0 ± 1.5 Ma calc–alkaline I-type oxidized porphyry quartz diorite
intrusive within volcanic and volcaniclastic rocks of the early Cretaceous Guáimaro Formation. The porphyry is affected by
propylitic alteration and crosscut by a network of quartz and carbonate veinlets and veins. Chlorite, epidote, sericite, quartz,
and pyrite are the main minerals in the early veins which are cut by late carbonate and zeolite veins. Late barite pseudomorphously
replaces pyrite. Gold is associated with pyrite as disseminations in the altered quartz diorite and in the veins, occurring
as inclusions or filling fractures in pyrite with 4 g/t Au in bulk samples, and up to 900 ppm Au in in pyrite. Fluid inclusion
and oxygen isotope data are consistent with a H2O–NaCl–(KCl) mineralizing fluid, derived from the quartz diorite magma, and trapped at least at 425°C and 1.2 kbar. This primary
fluid unmixed into two fluid phases, a hypersaline aqueous fluid and a low-salinity vapor-rich fluid. Boiling during cooling
may have played an important role in metal precipitation. Pyrite δ34S values for the La Unión prospect range between 0.71‰ and 1.31‰, consistent with a homogeneous magmatic sulfur source. The
fluids in equilibrium with the mineralized rocks have estimated δ18O values from 8‰ to 11.8‰, calculated for a temperature range of 480–505°C. The tectonic environment of the La Unión prospect,
its high gold and low copper contents, the physical–chemical characteristics of the mineralizing fluids and the isotopic signature
of the alteration minerals and fluids indicate that the La Unión gold mineralization is similar to the porphyry gold type,
even though the ore-related epidote–chlorite alteration can be classified as propylitic and not the classic potassic and/or
phyllic alteration. The low copper contents in the prospect could be due to a mineralizing fluid previously saturated in copper,
which is indicated by trapped chalcopyrite crystals in high-temperature fluid inclusions. The low-temperature paragenesis,
represented by carbonate, zeolite and barite, indicates epithermal overprint. The study shows the potential for other gold
porphyry-type deposits in the Cretaceous volcanoplutonic arc of Cuba. 相似文献
8.
Jean Vallance Lluís Fontboté Massimo Chiaradia Agnès Markowski Susanne Schmidt Torsten Vennemann 《Mineralium Deposita》2009,44(4):389-413
The Jurassic (approximately 145 Ma) Nambija oxidized gold skarns are hosted by the Triassic volcanosedimentary Piuntza unit
in the sub-Andean zone of southeastern Ecuador. The skarns consist dominantly of granditic garnet (Ad20–98) with subordinate pyroxene (Di46–92Hd17–42Jo0–19) and epidote and are spatially associated with porphyritic quartz-diorite to granodiorite intrusions. Endoskarn is developed
at the intrusion margins and grades inwards into a potassic alteration zone. Exoskarn has an outer K- and Na-enriched zone
in the volcanosedimentary unit. Gold mineralization is associated with the weakly developed retrograde alteration of the exoskarn
and occurs mainly in sulfide-poor vugs and milky quartz veins and veinlets in association with hematite. Fluid inclusion data
for the main part of the prograde stage indicate the coexistence of high-temperature (500°C to >600°C), high-salinity (up
to 65 wt.% eq. NaCl), and moderate- to low-salinity aqueous-carbonic fluids interpreted to have been trapped at pressures
around 100–120 MPa, corresponding to about 4-km depth. Lower-temperature (510–300°C) and moderate- to low-salinity (23–2 wt.%
eq. NaCl) aqueous fluids are recorded in garnet and epidote of the end of the prograde stage. The microthermometric data (Th
from 513°C to 318°C and salinity from 1.0 to 23 wt.% eq. NaCl) and δ18O values between 6.2‰ and 11.5‰ for gold-bearing milky quartz from the retrograde stage suggest that the ore-forming fluid
was dominantly magmatic. Pressures during the early retrograde stage were in the range of 50–100 MPa, in line with the evidence
for CO2 effervescence and probable local boiling. The dominance of magmatic low-saline to moderately saline oxidizing fluids during
the retrograde stage is consistent with the depth of the skarn system, which could have delayed the ingression of external
fluids until relatively low temperatures were reached. The resulting low water-to-rock ratios explain the weak retrograde
alteration and the compositional variability of chlorite, essentially controlled by host rock compositions. Gold was precipitated
at this stage as a result of cooling and pH increase related to CO2 effervescence, which both result in destabilization of gold-bearing chloride complexes. Significant ingression of external
fluids took place after gold deposition only, as recorded by δ18O values of 0.4‰ to 6.2‰ for fluids depositing quartz (below 350°C) in sulfide-rich barren veins. Low-temperature (<300°C)
meteoric fluids (δ18Owater between −10.0‰ and −2.0‰) are responsible for the precipitation of late comb quartz and calcite in cavities and veins and
indicate mixing with cooler fluids of higher salinities (about 100°C and 25 wt.% eq. NaCl). The latter are similar to low-temperature
fluids (202–74.5°C) with δ18O values of −0.5‰ to 3.1‰ and salinities in the range of 21.1 to 17.3 wt.% eq. CaCl2, trapped in calcite of late veins and interpreted as basinal brines. Nambija represents a deep equivalent of the oxidized
gold skarn class, the presence of CO2 in the fluids being partly a consequence of the relatively deep setting at about 4-km depth. As in other Au-bearing skarn
deposits, not only the prograde stage but also the gold-precipitating retrograde stage is dominated by fluids of magmatic
origin. 相似文献
9.
At Sams Creek, a gold-bearing, peralkaline granite porphyry dyke, which has a 7 km strike length and is up to 60 m in thickness, intrudes camptonite lamprophyre dykes and lower greenschist facies metapelites and quartzites of the Late Ordovician Wangapeka formation. The lamprophyre dykes occur as thin (< 3 m) slivers along the contacts of the granite dyke. δ18Omagma values (+5 to +8‰, VSMOW) of the A-type granite suggest derivation from a primitive source, with an insignificant mature crustal contribution. Hydrothermal gold–sulphide mineralisation is confined to the granite and adjacent lamprophyre; metapelite country rocks have only weak hydrothermal alteration. Three stages of hydrothermal alteration have been identified in the granite: Stage I alteration (high fO2) consisting of magnetite–siderite±biotite; Stage II consisting of thin quartz–pyrite veinlets; and Stage III (low fO2) consisting of sulphides, quartz and siderite veins, and pervasive silicification. The lamprophyre is altered to an ankerite–chlorite–sericite assemblage. Stage III sulphide veins are composed of arsenopyrite + pyrite ± galena ± sphalerite ± gold ± chalcopyrite ± pyrrhotite ± rutile ± graphite. Three phases of deformation have affected the area, and the mineralised veins and the granite and lamprophyre dykes have been deformed by two phases of folding, the youngest of which is Early Cretaceous. Locally preserved early-formed fluid inclusions are either carbonic, showing two- or three-phases at room temperature (liquid CO2-CH4 + liquid H2O ± CO2 vapour) or two-phase liquid-rich aqueous inclusions, some of which contain clathrates. Salinities of the aqueous inclusions are in the range of 1.4 to 7.6 wt% NaCl equiv. Final homogenisation temperatures (Th) of the carbonic inclusions indicate minimum trapping temperatures of 320 to 355°C, which are not too different from vein formation temperatures of 340–380°C estimated from quartz–albite stable isotope thermometry. δ18O values of Stage II and III vein quartz range from +12 and +17‰ and have a bimodal distribution (+14.5 and +16‰) with Stage II vein quartz accounting for the lower values. Siderite in Stage III veins have δ18O (+12 to +16‰) and δ13C values (−5‰, relative to VPDB), unlike those from Wangapeka Formation metasediments (δ13Cbulk carbon values of −24 to −19‰) and underlying Arthur Marble marine carbonates (δ18O = +25‰ and δ13C = 0‰). Calculated δ18Owater (+8 to +11‰, at 340°C) and
(−5‰) values from vein quartz and siderite are consistent with a magmatic hydrothermal source, but a metamorphic hydrothermal origin cannot be excluded. δ34S values of sulphides range from +5 to +10‰ (relative to CDT) and also have a bimodal distribution (modes at +6 and +9‰, correlated with Stage II and Stage III mineralisation, respectively). The δ34S values of pyrite from the Arthur Marble marine carbonates (range from +3 to +13‰) and Wangapeka Formation (range from −4 to +9.5‰) indicate that they are potential sources of sulphur for sulphides in the Sams Creek veins. Another possible source of the sulphur is the lithospheric mantle which has positive values up to +14‰. Ages of the granite, lamprophyre, alteration/mineralisation, and deformation in the region are not well constrained, which makes it difficult to identify sources of mineralisation with respect to timing. Our mineralogical and stable isotope data does not exclude a metamorphic source, but we consider that the source of the mineralisation can best be explained by a magmatic hydrothermal source. Assuming that the hydrothermal fluids were sourced from crystallisation of the Sams Creek granite or an underlying magma chamber, then the Sams Creek gold deposit appears to be a hybrid between those described as reduced granite Au–Bi deposits and alkaline intrusive-hosted Au–Mo–Cu deposits. 相似文献
10.
A. I. Grabezhev 《Geology of Ore Deposits》2010,52(2):138-153
The Early Devonian Gumeshevo deposit is one of the largest ore objects pertaining to the dioritic model of the porphyry copper
system paragenetically related to the low-K quartz diorite island-arc complex. The (87Sr/86Sr)t and (ɛNd)t of quartz diorite calculated for t = 390 Ma are 0.7038–0.7045 and 5.0–5.1, respectively, testifying to a large contribution of the mantle component to the composition
of this rock. The contents of typomorphic trace elements (ppm) are as follows: 30–48 REE sum, 5–10 Rb, 9–15 Y, and 1–2 Nb.
The REE pattern is devoid of Eu anomaly. Endoskarn of low-temperature and highly oxidized amphibole-epidote-garnet facies
is surrounded by the outer epidosite zone. Widespread retrograde metasomatism is expressed in replacement of exoskarn and
marble with silicate (chlorite, talc, tremolite)-magnetite-quartz-carbonate mineral assemblage. The 87Sr/86Sr ratios of epidote in endoskarn and carbonate in retrograde metasomatic rocks (0.7054–0.7058 and 0.7053–0.7065, respectively)
are intermediate between the Sr isotope ratios of quartz dioritic rocks and marble (87Sr/86Sr = 0.70784 ± 2). Isotopic parameters of the fluid equilibrated with silicates of skarn and retrograde metasomatic rocks
replacing exoskarn at 400°C are δ18O = +7.4 to +8.5‰ and δD = −49 to −61‰ (relative to SMOW). The δ13C and δ18O of carbonates in retrograde metasomatic rocks after marble are −5.3 to +0.6 (relative to PDB) and +13.0 to +20.2% (relative
to SMOW), respectively. Sulfidation completes metasomatism, nonuniformly superimposed on all metasomatic rocks and marbles
with formation of orebodies, including massive sulfide ore. The δ34S of sulfides is 0 to 2‰ (relative to CDT);87Sr/86Sr of calcite from the late calcite-pyrite assemblage replacing marble is 0.704134 ± 6. The δ13C and 87Sr/86Sr of postore veined carbonates correlate positively (r = 0.98; n = 6). The regression line extends to the marble field. Its opposite end corresponds to magmatic (in terms of Bowman, 1998b)
calcite with minimal δ13C, δ18O, and 87Sr/86Sr values (−6.9 ‰, +6.7‰, and 0.70378 ± 4, respectively). The aforementioned isotopic data show that magmatic fluid was supplied
during all stages of mineral formation and interacted with marble and other rocks, changing its Sr, C, and O isotopic compositions.
This confirms the earlier established redistribution of major elements and REE in the process of metasomatism. A contribution
of meteoric and metamorphic water is often established in quartz from postore veins. 相似文献
11.
The source of metasomatic fluids in iron-oxide–copper–gold districts is contentious with models for magmatic and other fluid sources having been proposed. For this study, δ
18O and δ
13C ratios were measured from carbonate mineral separates in the Proterozoic eastern Mt Isa Block of Northwest Queensland, Australia. Isotopic analyses are supported by petrography, mineral chemistry and cathodoluminescence imagery. Marine meta-carbonate rocks (ca. 20.5‰ δ
18O and 0.5‰ δ
13C calcite) and graphitic meta-sedimentary rocks (ca. 14‰ δ
18O and −18‰ δ
13C calcite) are the main supracrustal reservoirs of carbon and oxygen in the district. The isotopic ratios for calcite from the cores of Na–(Ca) alteration systems strongly cluster around 11‰ δ
18O and −7‰ δ
13C, with shifts towards higher δ
18O values and higher and lower δ
13C values, reflecting interaction with different hostrocks. Na–(Ca)-rich assemblages are out of isotopic equilibrium with their metamorphic hostrocks, and isotopic values are consistent with fluids derived from or equilibrated with igneous rocks. However, igneous rocks in the eastern Mt Isa Block contain negligible carbon and are incapable of buffering the δ
13C signatures of CO2-rich metasomatic fluids associated with Na–(Ca) alteration. In contrast, plutons in the eastern Mt Isa Block have been documented as having exsolved saline CO2-rich fluids and represent the most probable fluid source for Na–(Ca) alteration. Intrusion-proximal, skarn-like Cu–Au orebodies that lack significant K and Fe enrichment (e.g. Mt Elliott) display isotopic ratios that cluster around values of 11‰ δ
18O and −7‰ δ
13C (calcite), indicating an isotopically similar fluid source as for Na–(Ca) alteration and that significant fluid–wallrock interaction was not required in the genesis of these deposits. In contrast, K- and Fe-rich, intrusion-distal deposits (e.g. Ernest Henry) record significant shifts in δ
18O and δ
13C towards values characteristic of the broader hostrocks to the deposits, reflecting fluid–wallrock equilibration before mineralisation. Low temperature, low salinity, low δ
18O (<10‰ calcite) and CO2-poor fluids are documented in retrograde metasomatic assemblages, but these fluids are paragenetically late and have not contributed significantly to the mass budgets of Cu–Au mineralisation. 相似文献
12.
Fluid origin and structural enhancement during mineralization of the Jinshan orogenic gold deposit, South China 总被引:3,自引:0,他引:3
The Jinshan orogenic gold deposit is a world-class deposit hosted by a ductile shear zone caused by a transpressional terrane
collision during Neoproterozoic time. Ore bodies at the deposit include laminated quartz veins and disseminated pyrite-bearing
mylonite. Most quartz veins in the shear zone, with and without gold mineralization, were boudinaged during progressive shear
deformation with three generations of boudinage structures produced at different stages of progressive deformation. Observations
of ore-controlling structures at various scales indicate syn-deformational mineralization. Fluid inclusions from pyrite intergrown
with auriferous quartz have 3He/4He ratios of 0.15–0.24 Ra and 40Ar/36Ar ratios 575–3,060. δ18Ofluid values calculated from quartz are 5.5–8.4‰, and δD values of fluid inclusions contained in quartz range between −61‰ and
−75‰. The δ13C values of ankerite range from −5.0‰ to −4.2‰, and ankerite δ18O values from 4.4‰ to 8.0‰. The noble gas and stable isotope data suggest a predominant crustal source of ore fluids with
less than 5% mantle component. Data also show that in situ fluids were generated locally by pervasive pressure solution, and
that widespread dissolution seams acted as pathways of fluid flow, migration, and precipitation. The in situ fluids and fluids
derived from deeper levels of the crust were focused by deformation and deformation structures at various scales through solution-dissolution
creep, crack-seal slip, and cyclic fault-valve mechanisms during progressively localized deformation and gold mineralization. 相似文献
13.
Whole rock and mineral stable isotope and microprobe analyses are presented from granitoids of the North Chilean Precordillera.
The Cretaceous to Tertiary plutonic rocks contain important ore deposits and frequently display compositional and textural
evidence of hydrothermal alteration even in barren rocks. Deuteric alteration includes replacement of biotite and amphibole
by chlorite and epidote, sericitization and saussuritization of feldspars, and uralitization of clinopyroxene and/or amphibole.
While whole rock compositions are not significantly affected, compositional variations in amphiboles suggest two types of
hydrothermal alteration. Hornblende with actinolitic patches and rims and tight compositional trends from hornblende to Mg-rich
actinolite indicate increasing oxygen fugacity from magmatic to hydrothermal conditions. Uralitic amphiboles exhibiting irregular
Mg-Fe distribution and variable Al content are interpreted as reflecting subsolidus hydration reactions at low temperatures.
The δD values of hydrous silicates vary from −63 to −105‰. Most δ18O values of whole rocks are in the range of 5.7 to 7.7‰ and are considered normal for igneous rocks in the Andes. These δ18O values also coincide well with the oxygen isotope composition of geochemically similar recent volcanics from the Central
Andean Volcanic Zone (δ18O = 7.0–7.4‰). Only one sample in this study (δ18O = 3.0‰) appears to be depleted by isotope exchange with light meteoric water at high temperatures. The formation of secondary
minerals in all other intrusions is mainly the product of deuteric alteration. This also holds true for the sample from El
Abra, the only pluton associated with mineralization. This indicates the dominant role of a magmatic rather than a meteoric
fluid in the alteration of the Cretaceous and Tertiary granitoids in northern Chile.
Received: 8 July 1998 / Accepted: 15 April 1999 相似文献
14.
Two kinds of mylonite series rocks, felsic and mafic, have been recognized in the NW-striking shear zone of the Jiapigou gold
belt. During ductile deformation, a large amount of fluid interacted intensively with the mylonite series rocks: plagioclases
were sericitized and theAn values declined rapidly, finally all of them were transformed to albites; dark minerals were gradually replaced by chlorites
(mostly ripidolite). Meanwhile, large-scale and extensive carbonation also took place, and the carbonatization minerals varied
from calcite to dolomite and ankerite with the development of deformation. The δ13C values of the carbonates are −3.0‰ – −5.6‰ suggesting a deep source of carbon. The ductile deformation is nearly an iso-volume
one (f
v≈1). With the enhancement of shear deformation, SiO2 in the two mylonite series rocks was depleted, while volatile components suchs as CO2 and H2O, and some ore-forming elements such as Au and S were obviously enriched. But it is noted that the enrichment of Au in both
the mylonite series rocks did not reach the paygrade of gold. The released SiO2 from water-rock interactions occurred in the form of colloids and absorbed gold in the fluid. When brittle structures were
formed locally in the ductile shear zone, the ore-forming fluids migrated to the structures along microfractures, and preciptated
auriferous quartz because of reduction of pressure and temperature. Fluid inclusion study shows that the temperature and pressure
of the ore-forming fluids are 245–292°C and 95.4–131.7 MPa respectively; the salinity is 12.88–16.33wt% NaCl; the fluid-phase
is rich in Ca2+, K+, Na+, Mg2+, F− and Cl−, while the gaseous phases are rich in CO2 and CH4. The δD and δ18O, values of the ore-forming fluid are −84.48‰ – −91.73‰ and −0.247‰ – +2.715‰ respectively, suggesting that the fluid is
composed predominantly of meteoric water.
This project is financially supported by the National Natural Science Foundation of China (No. 9488010). 相似文献
15.
Kerim Kocak 《International Journal of Earth Sciences》2006,95(4):587-607
On the Eastern Tauride Belt, the Cretaceous calc-alkaline Karamadazı Granitoid consists of quartz diorite containing mafic microgranular enclaves (MME) and leucocratic granite. The quartz diorite consists of plagioclase (An8-65), hornblende, biotite, K-feldspar, quartz, epidote and titanite. Subrounded MME in the quartz diorite are holocrystalline, fine-grained, quartz diorite to diorite in composition, and display a similar mineral assemblage to their host. Large crystals in MME and quartz diorite show various disequilibrium microstructures indicative of hybridization. Plagioclase crystals exhibit inverse, normal, and oscillatory zoning with maximum core-to-rim An content increase up to 38% in the enclave and 40% in the quartz diorite. Both hornblende and augite exhibit normal and reverse zoning even in the same sample. The new field, textural, mineral compositional, and geochemical evidence leads to the conclusion that MME could have formed through injection of successive pulses of basic magma into upward mobile magma chambers containing cooler, partially crystalline quartz diorite magma. The quartz diorites show similarity to high-Al TTG (tonalites–trondhjemites–granodiorites), with their high Na2O, Sr, LREE, and low Mg#, Cr, HREE contents, and are suggested to be produced by extensive interaction between the crustal and mantle-derived melts through mixing at depth. In contrast, leucogranites have geochemical characteristics distinct from the quartz diorites and MME, and are probably not involved in MME genesis. 相似文献
16.
Ozcan Yigit Albert H. Hofstra Murray W. Hitzman Eric P. Nelson 《Mineralium Deposita》2006,41(6):527-547
Gold Bar is one of several Carlin-type gold mining districts located in the Battle Mountain–Eureka trend, Nevada. It is composed of one main deposit, Gold Bar; five satellite deposits; and four resources that contain 1.6 Moz (50 t) of gold. All of the deposits and resources occur at the intersection of north-northwest- and northeast-trending high-angle faults in slope facies limestones of the Devonian Nevada Group exposed in windows through Ordovician basin facies siliciclastic rocks of the Roberts Mountains allochthon. Igneous intrusions and magnetic anomalies are notably absent. The Gold Bar district contains a variety of discordant and stratabound jasperoid bodies, especially along the Wall Fault zone, that were mapped and studied in some detail to identify the attributes of those most closely associated with gold ore and to constrain genetic models. Four types of jasperoids, J0, J1, J2, and J3, were distinguished on the basis of their geologic and structural settings and appearance. Field relations suggest that J0 formed during an early event. Petrographic observations, geochemistry, and δ18O values of quartz suggest it was overprinted by the hydrothermal event that produced ore-related J1, J2, and J3 jasperoids and associated gold deposits. The greater amount of siliciclastic detritus present in J0 jasperoids caused them to have higher δ18O values than J1,2,3 jasperoids hosted in underlying limestones. Ore-related jasperoids are composed of main-ore-stage replacements and late-ore-stage open-space filling quartz with variable geochemistry and an enormous range of δ18O values (24.5 and −3.7‰). Jasperoids hosted in limestones with the most anomalous Au, Ag, Hg, ±(As, Sb, Tl) concentrations and the highest δ18O values are associated with the largest deposits. The 28‰ range of jasperoid δ18O values is best explained by mixing between an 18O-enriched fluid and an 18O-depleted fluid. The positive correlation between the sizes of gold deposits and the δ18O composition of jasperoids indicates that gold was introduced by the 18O-enriched fluid. The lowest calculated δ18O value for water in equilibrium with late-ore-stage quartz at 200°C (−15‰) and the measured δD value of fluid inclusion water extracted from late-ore-stage orpiment and realgar (−116‰) indicate that the 18O-depleted fluid was composed of relatively unexchanged meteoric water. The source of the 18O-enriched ore fluid is not constrained. The δ34S values of late-ore-stage realgar, orpiment, and stibnite (5.7–15.5‰) and barite (31.5–40.9‰) suggest that H2S and sulfate were derived from sedimentary sources. Likewise, the δ13C and δ18O values of late-stage calcite (−4.8 to 1.5‰ and 11.5 to 17.4‰, respectively) suggest that CO2 was derived from marine limestones. Based on these data and the apparent absence of any Eocene intrusions in the district, Gold Bar may be the product of a nonmagmatic hydrothermal system. 相似文献
17.
Yilin Xiao Zeming Zhang Jochen Hoefs Alfons van den Kerkhof 《Contributions to Mineralogy and Petrology》2006,152(4):443-458
In order to reconstruct the formation and exhumation mechanisms of UHP metamorphic terrains, the Chinese Continental Scientific Drilling Program (CCSD) has been carried out in Donghai of the Dabie-Sulu ultrahigh-pressure (UHP) metamorphic belt, East China. Eclogite, gneiss, amphibolite (retrograded from eclogite), ultramafic rocks, and minor schist and quartzite have been drilled. Aiming to reveal the fluid behaviour in a vertical sequence of an UHP slab, we investigated fluid inclusion and oxygen isotope characteristics of selected drillcores from the main hole and the pilot-holes PP2 and ZK 703 of the CCSD. More than 540 laser-ablation oxygen isotope analyses on garnet, omphacite, quartz, kyanite, amphibole, phengite, rutile, epidote, amphibole, plagioclase, and biotite from various rocks in the depth range of 0–3,000 m (mainly eclogite and gneiss) show that the investigated rocks can be divided into two groups: 18O-depleted rocks (as low as δ18O = −7.4‰ for garnet) indicate interaction with cold climate meteoric waters, whereas 18O-normal rocks (with bulk δ18O > +5.6‰) have preserved the O-isotopic compositions of their protoliths. Meteoric water/rock interaction has reached depths of at least 2,700 m. Oxygen isotope equilibrium has generally been achieved. Isotopic compositions of mineral phases are homogeneous on a mm to cm scale regardless of lithology, but heterogeneous on the scale of a few metres. Oxygen isotope distributions in the vertical sections favour an “in situ” origin of the UHP metamorphic rocks. The very negative δ18O eclogites usually have higher hydroxyl-mineral contents than the normal δ18O rocks, indicating higher water content during UHP metamorphism. Fluid inclusion data suggest that rocks with depleted 18O compositions have had different fluid histories compared to those with normal δ18O values. Rocks with depleted 18O mainly have primary medium-to-high salinity inclusions in omphacite, kyanite and quartz, and abundant secondary low-salinity or pure water inclusions in quartz, indicating a high-salinity-brine-dominated fluid system during peak UHP metamorphism; no carbonic inclusions have been identified in these rocks. By contrast, primary very high-density CO2 inclusions are commonly found in the rocks with normal δ18O values. These observations suggest that fluid and oxygen isotope composition of minerals are related and reflect variable degrees of alterations of the Dabie-Sulu UHP metamorphic rocks. 相似文献
18.
Geology and geochemistry of telluride-bearing Au deposits in the Pingyi area, Western Shandong, China 总被引:2,自引:0,他引:2
Summary Telluride-bearing gold deposits of the Pingyi area, western Shandong, China, are located on the southeastern margin of the
North China Craton. There are two main types of deposits: (i) mineralized cryptoexplosive breccia, e.g., Guilaizhuang; and
(ii) stratified, finely-disseminated mineralization hosted in carbonate rocks, e.g., Lifanggou and Mofanggou deposits. In
Guilaizhuang, the cryptoexplosive breccia is formed within rocks of the Tongshi complex and Ordovician dolomite. The mineralization
is controlled by an E–W-trending listric fault. Stratified orebodies of the Lifanggou and Mofanggou deposits are placed along
a NE-trending, secondary detachment zone. They are hosted within dolomitic limestone, micrite and dolomite of the Early-Middle
Cambrian Changqing Group. The mineralization in the ore districts is considered to be related to the Early Jurassic Tongshi
magmatic complex that formed in a continental arc setting on the margin of the North China Craton. The host rocks are porphyritic
and consist predominantly of medium- to fine-grained diorite and pyroxene (hornblende)-bearing monzonite. SHRIMP U–Pb zircon
dating of diorites give a 206Pb/238U weighted mean age of 175.7 ± 3.8 Ma. This is interpreted as representing the crystallization age of the Tongshi magmatic
complex. Considering the contact relationships between the magmatic and host sedimentary rocks, as well as the genetic link
with the deposits, we conclude that this age is relevant also for the formation of mineralization in the Pingyi area. We hence
consider that the deposits formed in the Jurassic. The principal gold minerals are native gold, electrum and calaverite. Wall-rock
alteration comprises pyritization, fluoritization, silicification, carbonatization and chloritization. Fluid inclusion studies
indicate that all the analyzed inclusions are of two-phase vapor–liquid NaCl–H2O type. Homogenization temperatures of the fluid inclusions vary from 103 °C to 250 °C, and the ice melting temperatures range
from −2.5 °C to −13.5 °C, corresponding to a salinity range of 4.65 to 17.26 wt.% NaCl equiv. The δ34S values of pyrite associated with gold mineralization exhibit a narrow range of −0.71 to + 2.99‰, implying that the sulfur
was probably derived from the mantle and/or dioritic magma. The δ13CPDB values of the fluid inclusions in calcite range from −7.3 to 0.0‰. The δ18OSMOW values of vein quartz and calcite range from 11.5 to 21.5‰, corresponding to δ18Ofluid values of −1.1 to 10.9‰; δD values of the fluid inclusions vary between −70 and −48‰. The isotope data for all three deposits
suggest mixing of ore-forming fluids derived from the mantle and/or magma with different types of fluids at shallow levels.
Pressure release and boiling of the fluids, as well as fluid-rock interaction (Lifanggou and Mofanggou) and mixing of magmatically-derived
fluids with meteoritic waters (Guilaizhuang) played an important role in the ore-forming processes. 相似文献
19.
Oxygen isotope constraints on the petrogenesis of the Sybille intrusion of the Proterozoic Laramie Anorthosite Complex 总被引:2,自引:0,他引:2
The origin of monzonitic intrusions that are associated with Proterozoic massif-type anorthosite complexes is controversial.
A detailed oxygen isotope study of the Sybille intrusion, a monzonitic intrusion of the Laramie Anorthosite Complex (Wyoming),
indicates that either derivation from a basaltic magma of mantle origin with a metasedimentary component (∼20%) incorporated
early in its magmatic history, or a partial melt of lower crustal rocks is consistent with the data. The oxygen isotope compositions
of plagioclase, pyroxene and zircon from the Sybille monzosyenite, the dominant rock type in the Sybille intrusion, were analyzed
in order to establish the isotopic composition of the source of the magma. Plagioclase δ18O values range from 6.77 to 9.17‰. We interpret the higher plagioclase δ18O values (average 8.69 ± 0.30‰, n = 19) to be magmatic in origin, lower plagioclase δ18O values (average 7.51 ± 0.44‰, n = 22) to be the result of variable subsolidus alteration, and pyroxene δ18O values (average 6.34 ± 0.38‰, n = 19) to be the result of closed-system diffusional exchange during cooling. Low magnetic zircons, which have been shown
to retain magmatic oxygen isotope values despite high grade metamorphism and extensive subsolidus hydrothermal alteration,
have δ18O values (7.40 ± 0.24‰, n = 11) which are consistent with our interpretation of the plagioclase and pyroxene results. Oxygen isotope data from all
three minerals indicate that the magmatic oxygen isotope composition of the Sybille intrusion is enriched in 18O relative to the composition of average or “normal” mantle-derived magmas. This enrichment is approximately twice the oxygen
isotope enrichment that could result from closed-system fractionation, rendering a closed-system, comag- matic petrogenetic
model between the Sybille intrusion and the mantle-derived anorthositic lithologies of the Laramie Anorthosite Complex improbable.
Received: 7 April 1998 / Accepted: 19 January 1999 相似文献
20.
The Sarylakh and Sentachan gold-antimony deposits,Sakha-Yakutia: A case of combined mesothermal gold-quartz and epithermal stibnite ores 总被引:1,自引:0,他引:1
N. S. Bortnikov G. N. Gamynin O. V. Vikent’eva V. Yu. Prokof’ev A. V. Prokop’ev 《Geology of Ore Deposits》2010,52(5):339-372
New mineralogical, thermobarometric, isotopic, and geochemical data provide evidence for long and complex formation history
of the Sarylakh and Sentachan Au-Sb deposits conditioned by regional geodynamics and various types of ore mineralization,
differing in age and source of ore matter combined in the same ore-localizing structural units. The deposits are situated
in the Taryn metallogenic zone of the East Yakutian metallogenic belt in the central Verkhoyansk-Kolyma Fold Region. They
are controlled by the regional Adycha-Taryn Fault Zone that separates the Kular-Nera Terrane and the western part of the Verkhoyansk
Fold-Thrust Belt. The fault extends along the strike of the northwest-trending linear folds and is deep-rooted and repeatedly
reactivated. The orebodies are mineralized crush zones accompanied by sulfidated (up to 100 m wide) quartz-sericite metasomatic
rocks and replacing dickite-pyrophyllite alteration near stibnite veinlets. Two stages of low-sulfide gold-quartz and stibnite
mineralization are distinguished. The formation conditions of the early milk white quartz in orebodies with stibnite mineralization
at the Sarylakh and Sentachan deposits are similar: temperature interval 340–280°C, salt concentration in fluids 6.8–1.6 wt
% NaCl equiv, fluid pressure 3430–1050 bar, and sodic bicarbonate fluid composition. The ranges of fluid salinity overlapped
at both deposits. In the late regenerated quartz that attends stibnite mineralization, fluid inclusions contain an aqueous
solution with salinity of 3.2 wt % NaCl equiv and are homogenized into liquid at 304–189°C. Syngenetic gas inclusions contain
nitrogen 0.19 g/cm3 in density. The pressure of 300 bar is estimated at 189°C. The composition of the captured fluid is characterized as K-Ca
bicarbonatesulfate. The sulfur isotopic composition has been analyzed in pyrite and arsenopyrite from ore and metasomatic
zones, as well as in coarse-, medium-, and fine-grained stibnite varieties subjected to dynamometamorphism. The following
δ34S values, ‰ have been established at the Sarylakh deposit: −2.0 to −0.9 in arsenopyrite, −5.5 to −1.1 in pyrite, and −5.5
to −3.6 in stibnite. At the Sentachan deposit: −0.8 to +1.0 in arsenopyrite, +0.5 to +2.6 in pyrite, and −3.9 to +0.6 in stibnite.
Sulfides from the Sentachan deposit is somewhat enriched in 34S. The 18O of milk white quartz at the Sarylakh deposit varies from +14.8 to 17.0‰ and from +16.4 to + 19.3‰ at the Sentachan. The
δ18O of regenerated quartz is +16.5‰ at the Sarylakh and +17.6 to +19.8‰ at the Sentachan. The δ18O of carbonates varies from +15.0 to 16.3% at the Sarylakh and from +16.7 to +18.2‰ at the Sentachan. The δ13C of carbonates ranges from −9.5 to −12.1‰ and −7.8 to −8.5‰, respectively. The calculated $
\delta ^{18} O_{H_2 O}
$
\delta ^{18} O_{H_2 O}
of the early fluid in equilibrium with quartz and dolomite at 300δC are +7.9 to +10.1‰ for the Sarylakh deposit and +9.5
to +12.4‰ for the Sentachan deposit (+4.9 and 6.0‰ at 200°C for the late fluid, respectively). Most estimates fall into the
interval characteristic of magmatic water (°18O = +5.5 to +9.5‰). 相似文献