Geochemistry and genesis on saturated hydrocarbon of crude oils in Gas Hure Oilfield in Qaidam Basin

Gas Hure Oilfield is the biggest one in the Qaidam Basin.Through intensive sampling and GC-MS analysis,the authors analyzed the geochemical characteristics of the crude oils in the Gas Hure Oilfield.The results show that the crude oils have even-odd carbon predominance for n-alkanes.In shallow reservoir,part of crude oils suffered biogenic degradation.As for normal oils,they have low Pr/Ph ratios with abundant gammacerane and C35 homohopane,which indicate that the crude oils are formed in strong reducing sa...     

鄂尔多斯盆地姬塬油田延长组原油性质与来源分析

通过原油与油田水物理性质、原油与烃源岩族组成、饱和烃气相色谱以及萜烷与甾烷等生物标志化合物特征的多项地球化学指标对比,表明鄂尔多斯盆地姬塬油田延长组长8、长6、长4+5等油层组原油性质较为复杂,其成熟度、母源氧化-还原环境及母质类型等方面存在显著差异。烃源岩评价也显示长9、长8、长7、长6、长4+5段的暗色泥岩有机质质量和类型有所差别,但均具备生排烃能力。油源对比结果进一步证明:成藏过程存在多套油源混源供油的成藏效应,其中长8油层组原油主要来源于长7—长8段烃源岩;长6油层组原油主要来源于长7—长6段烃源岩;长4+5油层组原油存在长7、长6及长4+5段多源烃源岩的贡献。     

Geochemistry and genesis of magmatic PGE-bearing Cu-Ni sulphide deposit in Wadi Bayhan，southeastern Yemen

The Wadi Bayhan mafic-ultramafic intrusions associated with magmatic PGE-bearing Cu-Ni sulphide deposit are located in the south margin of the Arabian-Nubian Shield,SW Yemen.The intrusions consist of dunite,olivine-pyroxenite,lherzolite,hornblendite,gabbro and gabbronorite.The dunite and lherzolite are the main host rock for the Cu-Ni ores.The new data of the chemical compositions of the rocks have SiO2(50%-53.6%),Al2O3(0-32%) and MgO(4%-28%),and relatively low TiO2(0-3.2%) and K2O+Na2O(0.04%-5.2%).The geochemical characteristics indicate that the parental magma is high-magnesium tholeiitic.Sulfur had reached saturation and immiscible sulfides droplets segregated from silicate magmas before their emplacement.     

Geochemistry and metallogenic age of Sishanlinchang gold-silver deposit in Jidong of Heilongjiang

the Sishanlinchang gold-silver deposit is mainly composed of gold-quartz vein type ores.It has many kinds of sulfides and gold in high grade.The Au has a close correlation with As,Pb,Ag and Cu.Geochemically,the deposit is characterized by relatively enrichment in LREE with moderate or lower Eu negative anomaly.Sulfur isotopes appear as single and deep source,and lead isotopes indicate the Pb is from the earth’s mantle and crust,which mainly are orogenic belt Pb,the ore-forming fluid has a temperature of 215℃-350℃ and a low salinity with a mixture of characteristics of magmaitc hydrothermal and meteoric water.The ore-forming age is 111.1-111.4 Ma.The deposit is formed in mineralization and precipitation of metallogenic materials caused by the mixture of the magmatic hydrothermal fluid and meteoric water.     

断层垂向封闭性定量分析及其在渤海湾盆地A油田中的应用

在油藏内部,断层垂向封闭程度对原油物性具有重要影响。根据断层封闭机理及其影响因素研究,通过垂直断面方向上的断面正压力（δ_F）及断裂带物质抗压强度（δ_C）对比,建立起利用断层紧闭指数（I_FT=δ_F/δ_C）表征断层垂向封闭性的方法,并将其应用于渤海湾盆地A油田原油物性平面差异的研究中。结果表明:①不同断层的I_FT不同,I_FT越大,垂向封闭性越好,A油田明化镇组下段断至潜山但不沟通海底的断层,I_FT最高,来自深层的热量向浅层运移,形成局部高温环境,生物降解弱,原油物性好;②同一断层不同断点的断面正压力和断层缝充填物质相对含量不同,沿断层走向,I_FT也不相同;③A油田断块区主控断层从西南往东北I_FT逐渐降低,形成差异生物降解,使地层原油黏度向东北逐渐增大。利用断层紧闭指数法判断油藏主控断层的垂向封闭性,并与原油物性分布的差异性进行对比,两者规律相吻合,表明利用断层垂向封闭性判断油藏原油物性是可行的。      

泌阳凹陷下二门地区核桃园组油气成藏再认识

泌阳凹陷下二门地区位于泌阳凹陷东部,区内已发现下二门油田。该油田在核三上段至核二段下部为纯油藏,核二段上部为具气顶的油藏,核一段和廖庄组为纯气藏。经过40多年勘探开发,在下二门地区油气藏的发现难度越来越大,油气勘探陷入瓶颈期。为了进一步扩大该区勘探规模,取得新的油气发现,需要对该地区油气成藏机制再认识进而决定其下一步勘探方向。利用最新勘探和油藏资料,通过烃源条件分析、油源对比、天然气成分分析及油藏精细解剖,重新认识了该地区油气成藏机制。研究结果表明:泌阳凹陷深凹区的核二段泥页岩发育广,生烃指标较好,已进入低成熟阶段,具备较好的生油条件;下二门地区各层系油气与深凹区的源岩关系明确,表明油气以顺层运移为主,即核二段低熟油应该来自深凹区核二段低熟烃源岩,核三上段和核三下段原油分别来自深凹区核三上段和核三下段的成熟烃源岩;下二门地区核二段产出的天然气为低成熟伴生气,明显不同于深层凝析气,并非深层油气沿断层调整而来;下二门地区深层油气资源量大,但目前已发现储量规模有限,这预示着该区仍有较大的勘探潜力。因此,总结下二门地区的油气成藏特点及成藏模式,不仅可为该区油气勘探提供指导,而且可为我国东部类似断陷湖盆含油构造的进一步勘探提供借鉴。      

A study on accumulation and distribution of gas in southern Songliao Basin

A number of isolated fault sags in Late Jurassic--Early Cretaceous were developed in the early stage of southern Songliao Basin,and unified to a depression basin in the late stage.Therefore,multiple isolated lower petroliferous systems were formed with fault sags as source rocks.The source rocks of fault sags in Late Jurassic--Early Cretaceous were mainly described with gas generation as favorable source rocks,leading to the southern Songliao Basin rich in natural gas resources combined with organic gas resources in Nenjiang Formation.A number of tectonic movements in southern Songliao Basin led to the formation of abundant structural traps and complex fault systems,and controlled the distribution strata and positions of sources rocks in Late Jurassic--Early Cretaceous fault sags.The oil-gas reservoirs can be divided into two types,i.e.,primary and secondary ones.The primary oil-gas reservoirs were distributed in the fault sag strata and the bottom of overlying depression strata(lower Quan-1 Member).The oil-gas reservoir accumulation depended on the trap development situation and the distance from source rocks.The preservation conditions of oil-gas reservoirs depended on the degree of reconstruction in the late tectonism.The secondary oil-gas reservoirs were distribution in the Quantou Formation of depression strata,where oil and gas reservoir accumulation depended on three conditions,i.e.,trap development situation,deep gas sources and the fault to connect the shallow traps and deep gas sources.The southern Songliao Basin is rich in lower coal type gas,upper oil-gas and biogas resources,which are important resources in the future.     

Geology and fluid inclusion of Wadi Sharis Neoproterozoic orogenic gold deposits in northwestern Yemen

The Wadi Sharis orogenic gold deposit in northwestern Yemen is related to the fault and shear zones vein at medium depth in the crust in the Neoproterozoic meta-sedimentary and meta-volcanosedimentary succession of greenschist to amphibolite facies metamorphism.Three distinct fluid inclusion types have been identified in the gold-bearing quartz sulphide veins of the deposit:(1) type I:vapour-liquid two-phase(VH2O-LH2O),(2) type II:three-phase CO2(VCO2-LH2O-LCO2) and(3) type III:vapour-rich(LCO2-VCO2) inclusions.Six analysis of individual fluid inclusion indicate the fluid inclusions comprise mainly of H2O and CO2.Formation P-T conditions recorded by fluid inclusions in quartz crystals correspond to 180℃-380℃ and up to 130 MPa,as indicated by high-density CO2 bubbles(up to 0.98 g/cm3) observed in some inclusions.The estimated crystallization pressures correspond to approximately 4-10 km of overburden,assuming a lithostatic load.The salinity ranges from 0 to 22 wt%.The deposit holds at 0.2-5 g/t Au and contains low-moderate salinity.     

Sewage pollution in Negril, Jamaica: effects on nutrition and ecology of coral reef macroalgae

Coral reefs in the Negril Marine Park (NMP), Jamaica, have been increasingly impacted by nutrient pollution and macroalgal blooms following decades of intensive development as a major tourist destination. A baseline survey of DIN and SRP concentrations, C:N:P and stable nitrogen isotope ratios (δ15N) of abundant reef macroalgae on shallow and deep reefs of the NMP in 1998 showed strong P-limitation and evidence of increasing sewage pollution. In 1999, a sewage collection and treatment project began divertin...     

Zircon U-Pb age,geochemical and Nd isotopic data of Middle Jurassic high-Mg dioritic dike in Liaodong Peninsula,NE China

Zircon LA-ICP-MS U-Pb age, geochemical and Nd isotopic data are presented for a newly recognized high-Mg dioritic dike from Haicheng, Liaodong Peninsula, NE China, to constrain its petrogenesis. The zircons from the high-Mg diorite exhibit striped absorption and oscillatory growth zoning in the cathodoluminescence （CL） images, and have high Th/U ratios （0. 05-0.9）, indicating a magma origin. Zircon LA-ICP-MS U-Pb dating indicates that 206pb/238U ages of 12 spots of zircons are between 167 Ma and 178 Ma, yielding a weighted mean 206pb/238U age of 172 ＋ 2 Ma （MSWD =4. 1 ）, which represents the forming age of the high-Mg dioritic dike, i. e. Middle Jurassic. Geochemically, the samples have SiO2 =55.4-60. 6 wt. % , Na20 =2. 2-2.76 wt. % , K20 = 1.32-2. 02 wt. % and （Na2O ＋ K2O） =3.82--4. 47 wt. %, belonging to sub-alkaline series and displaying a calc-alkaline evolutionary trend. They are characterized by high MgO （4. 75-6.85 wt. % ）, Mg# （55-61）, Cr（130-262 ppm）, Ni（63-130 ppm）, Sr（568-857 ppm）, and Ba（484-1 130 ppm） contents, with geochemical features analogous to those of high-Mg adakites. They show variable end （t） values （ - 1.3 to - 3.9） , with a weighted value of - 2. 7, which plot intermediately between the field of the ancient continental crust and the depleted mantle source, indicating that both the lower crust and mantle source are necessary for the generation of the parent magma of the Haicheng high-Mg diorites. The Haicheng high-Mg dioritic dike in the Liaodong Peninsula and the Jurassic magmatism in the eastern North China Craton formed under a continental crustal thickening setting that may be related to subduction of the Paleo-Pacific oceanic plate.     

APPlication of sPectral decomPosition technology in shallow gas detection based on Wigner-Ville distribution

Shallow gas is comPosed of all kinds of shallow buried natural gas resources( <1500 m)with rela-tively small reserve for each gas resource. It has some advantages such as shallow burial dePth,good Phys...     

Application of constrained sparse spike inversion in reservoir predication: a case study of Oriente Basin in South America

In the conditions of low Signal-to-Noise Ratio(SNR) of seismic data and a small quality of log information,the consequences of seismic interpretation through the impedance inversion of seismic data could be more precise. Constrained sparse spike inversion(CSSI) has advantage in oil and gas reservoir predication because it does not rely on the original model. By analyzing the specific algorithm of CSSI,the accuracy of inversion is controlled. Oriente Basin in South America has the low amplitude in geological structure and complex lithologic trap. The well predication is obtained by the application of CSSI.     

UNUSUAL DISTRIBUTION OF TRITERPANE AND STERANE TERRESTRIAL BIOMARKERS IN YACHENG CONDENSATES FROM YING-QIONG BASINS, SOUTH CHINA SEA

The condensates from the Yacheng Gas Field, Ying-Qiong Basins, have unusual chemical characteristics, with distribution dominated by terpanes and steranes derived from higher-plants. Pr/Ph ratios (6- 11 ) are very high. Drimane, cadinanes and homocadinanes exist in high concentration. Anomalously abundant 18α(H)-oleanane and remarkably abundant bicadinanes are present in Yacheng condensates, while 17α( H)-hopanes are in extremely low concentration. Taraxastane and significantlyabundant 17α(H)-diabopanes occur in the condensates. In addition, a number of C29 and C30 unknown pentacyclic triterpanes were monitored in the condensates, some of which are abundant. The unknown compounds may be terrestrial biomarkers or their occurrence may suggest a sub-oxic (dyacrobic) clay-rich depositional environment. C29 homologues are relatively predominant in regular and rearranged steranes. The concentration of diasteranes is markedly higher than that of regular steranes. The characteristics of Yacheng condensates are indicative of terrestrial source input. Based on condensate-condensate and con-densate-rock correlations, combined with results of studies on sedimentary facies. Yacheng condensates may be sourced from Yacheng and Lingshui Formations in the Qiongdongnan Basin. The maturity of Yacheng condensate is relatively high, at late oil window stage ( corresponding to 0.9 % - 1.3 % R0 ),based on sterane and terpane maturity parameters.     

隔档式构造区岩溶地下水流系统多级次嵌套结构的水化学识别

川东隔档式构造区岩溶地下水流系统表现出多级次嵌套结构的特征,之前主要是定性的水文地质条件分析,缺乏来自水化学方面的量化依据。利用41个浅层和19个深层岩溶水样的水化学资料开展分析,发现浅层岩溶水为HCO₃-Ca·Mg型,ρ(Mg²⁺)较低,深层岩溶水为SO₄-Ca·Mg型且ρ(Mg²⁺)明显偏高,说明地下水在岩溶含水层中的滞留时间与ρ(Mg²⁺)具有正变关系。对典型剖面地下水流系统的分析表明,优先采用ρ(Mg²⁺)来评价地下水滞留时间,将地下水排泄点ρ(Mg²⁺)小于20,50 mg/L分别作为划分局部-中间、中间-区域水流系统的依据。浅层岩溶水受地貌作用控制明显,其中浅切沟谷泉点为局部地下水流系统的排泄点,深切沟谷泉点一般属于中间或区域流动系统的排泄点。ρ(Mg²⁺)反映了泉水循环的滞留时间,也能够反映钻孔所揭露的深循环特征。这种水化学识别方法可为相似岩溶区识别地下水流系统的多级次嵌套结构提供参考。     

地质模式约束的SVR属性融合在浅水三角洲储层描述中的应用: 以西湖凹陷X气田为例

X气田位于东海盆地西湖凹陷中央反转构造带,主要目的层H4层为浅水三角洲沉积环境,气田地震资料主频较低（25 Hz）,而H4层埋深较大（3 300~3 400 m）,储层低孔低渗,常规地震反演预测砂体厚度吻合度较低。针对X气田三维地震资料全覆盖及钻井较少的特点,通过地质模式指导下的正反演结合设置虚拟井来弥补SVR（Support Vector Regression）算法中样本点的不足,通过提取地震属性并优选表征砂体厚度的敏感属性,利用SVR算法进行多属性融合,完成了H4层砂体的定量预测。基于储层预测成果,提出H4层为浅水三角洲曲流型分流河道沉积,并进一步完成了砂体沉积模式解剖,成功指导了开发调整井部署,实钻砂体厚度与预测砂体厚度吻合度高达84%以上。探索得到了海上少井条件下地质模式约束的SVR算法储层定量预测方案,对X气田中深层分流河道储层完成了精准预测,亦对同类型油气田的储层描述具有一定指导意义。      

雅布赖盆地小湖次凹新河组下段层序及沉积相特征

目前雅布赖盆地小湖次凹中侏罗统新河组下段是玉门油田的主力勘探层位,其中YT6井已取得工业油流,显示出良好的勘探前景,而在层序格架下明确同期次砂体展布,将有利于油气的进一步勘探开发。基于岩心、测井、录井及地震资料的分析,依据经典层序地层学理论,对小湖次凹中侏罗统新河组下段的层序特征、沉积相类型、沉积演化规律及平面展布进行了系统研究,进而讨论了有利沉积相带的展布。研究表明,新河组下段具有完整的三级层序;主要发育扇三角洲相、辫状河三角洲相、湖泊相3种沉积相类型;次凹沉积相带发育具有南北分异、隆凹成带的特征,其中小湖次凹南部陡坡带发育扇三角洲前缘亚相,北部及西北部缓坡带发育辫状河三角洲前缘亚相,次凹中心则主要发育湖泊相;从低位期到高位期,不同时期的沉积相展布各异,总体表现出水体由浅变深,再变浅,沉积范围逐渐扩大,扇三角洲和辫状河三角洲先进积、后退积、再进积的特点;经分析认为分布于YT6井西北部新河组下段的高位域水下分流河道微相是最有利的储油相带。      

山东省成武县土壤地球化学特征及土地质量现状

山东省成武县农业地质环境土壤地球化学调查是按浅层、深层土壤样品1点/4km2。测试N,P,K,Cu,Zn,B,Mo,Mn,F,As,Hg,Pb,Cr,Cd等14种指标。在统计这些指标的表层、深层土壤地球化学特征参数的基础上,对其与世界、全省同类参数的差异进行了分析,并分析了区内表层、深层土壤元素含量的相关性,认为该区表层土壤元素含量的显著特征是高F,Hg,Pb而低Mo;大部分元素在表层土壤中的含量继承了土壤母质的成分特征,但N,F,Hg,Pb等受人为活动和污染源的作用在表层土壤中明显富集。通过分析表层土壤营养元素有效量可知,P,K,Zn的有效量高;供肥能力强;而Mo,Cu,Mn明显偏低。利用易污染元素浅层土壤含量值,通过污染指数法,对全区土壤污染程度进行了评价;区内土壤无严重污染区存在,并且明显污染地段面积较小,呈零星分布,说明区内污染程度较轻。     

Optimization of ice cuttings transportation by cable-suspended core auger drills

Ice cores contain an abundance of information about the Earth''s climate in the past,and recovered from shallow drilling down to 300--350 m give sufficient information for reconstructing of the last climatic chan- ges and for monitoring of pollution from human being． Cable-suspended core auger drills use an armored cable with a winch to provide power to the down-hole motor system and to retrieve the down-hole unit． Because of their lightweight,convenient transportation and installation,high penetration rates and low power consumption, core auger drills are widely used for shallow drilling in ice． Nowadays at least 14 types of auger electromechani- cal drills were designed and tested in different foreign and national glaciological laboratories． However,auger options were usually determined by experience,and the main parameters (helix angle of the fights and rotational speed) are varied in a wide range from drill to drill． If parameters of auger are not chosen properly,poorly en- gineered drills had troubles with low efficiency of cuttings transportation,jam of ice cuttings,repeated fragmen- tation,cutters icing and stop penetration,abnormal power consumption,high rotation torques,and so on． Thus,this paper presents the method of optimization of ice cuttings transportation of cable-suspended core auger drill on the base of the theory of rotary auger． As the result,the optimal helix angle was determined correspond- ing to the rotational speed from the transportation efficiency point of view．     

常规测井气测资料在H油田K油藏碳酸盐岩储层流体识别中的应用

K油藏是中东伊拉克H油田重要的油气产层, 储层裂缝基本不发育, 储集空间主要为基质孔隙和溶孔, 渗透率极差范围大, 孔渗相关性较差。储层厚度大, 层间非均质性极强, 使得仅依靠常规测井资料和传统的测井评价方法来评价该区域碳酸盐岩储层流体性质识别效果差, 针对该问题, 进行H油田K油藏流体识别研究。通过分析常规测井资料发现, 深浅电阻率比值可以较好地划分水和烃类。在分析总结气测全烃曲线的形态特征及所对应的储层流体性质基础上, 发现气测曲线对于不同流体性质形态差异明显, 因此考虑利用气测曲线进行水和烃类进一步划分。统计发现重烃比值和烃气密度指数可以较好划分油水同层和水层, 为了定量表征识别过程建立水层-油水同层气测曲线识别法(ECR1), ECR1大于0为油水同层, 反之为水层。以烃气湿度指数、轻烃比值、挖掘效应可以较好划分气层和油层, 以此为基础建立气层-油层气测曲线识别法(ECR2), ECR2大于0为气层, 反之为油层。以该模型对H油田K油藏13口井38个小层的应用表明, 其识别符合率达到81.58%, 识别精确度高, 能满足研究区实际需要。通过建立的气测曲线识别法(ECR)模型, 在H油田K油藏取得较好应用效果, 可为本区块后续勘探开发具有一定借鉴意义, 同时也可以为国内外类似碳酸盐岩储层流体识别提供参考。      

东大别地区岩石圈磁场分布与构造关系分析

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