Seasonal variation of particulate polycyclic aromatic hydrocarbons associated with PM10 in Guangzhou, China

Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous pollutants in the urban atmosphere. An investigation on seasonal variation of PAHs in the urban atmosphere of Guangzhou, China was conducted in this study. 112 PM10 (particulate matter with aerodynamic diameter < 10 μm) samples were collected at two sites between June 2002 and June 2003. PAHs were analyzed with GC–MS (gas chromatography–mass spectrometry). The result showed that PAHs exhibit distinct seasonal variation. The seasonal concentration for the ∑PAHs ranged from 8.11 to 106.26 ng m^− 3. The average ∑PAHs measured were highest in winter and lowest in summer. The PAHs distribution patterns were similar within each season at two sites. 5–6 ring PAHs were the abundant compounds, which accounted for 65–90% of ∑PAHs and benzo [b + k] fluoranthene dominated in four seasons. The PAHs concentration and distribution pattern fluctuated greatly in winter for the cold air current. Based on the different temperature in winter, the samples were split into two groups. PM10 and the abundance of the PAHs in winter-1 (temperature, 12–22 °C) were much greater than in winter-2 (temperature, 8–12 °C). In winter-1 benzo [b + k] fluoranthene and Indeno [1, 2, 3] pyrene dominated while chrysene and benzo [b + k] fluoranthene dominated in winter-2. Meteorological conditions such as wind speed and temperature had a strong influence on the seasonal variation. Potential sources of PAHs were identified using the molecular diagnostic ratios between PAHs. Results showed fossil fuel combustion may be the major source of PAHs at the two sites.     

The differences of the size distribution of polycyclic aromatic hydrocarbons (PAHs) between urban and rural sites of Guangzhou, China

Size distribution aerosol samples collected at two urban locations (Liwan and Wushan) and a suburban location (Xinken) in Guangzhou (South China) in autumn using a MOUDI (Micro-orifice Uniform Deposit Impactor) have been analyzed for 13 polycyclic aromatic hydrocarbons (PAHs) by gas chromatography with mass selective detection (GC-MS). Different PAH size distribution models were found for urban locations and a suburban location. The particle size distributions of PAHs tend to shift toward a larger size in a suburban location than in an urban location caused by aerosol aging processes. The ratios of total-PAH/TSP changed greatly during different sampling periods, even though the samplings were conducted consecutively. This can be the result of reactions between PAHs and atmospheric photooxidants, and the formation of SOAs (secondary organic aerosols) during the aging process. Adsorption behavior on available aerosol surface area, absorption behavior in available aerosol organic mass and multilayer adsorptive accumulation in coarse mode aerosols were the three mechanisms which control the size distribution of PAHs.     

Determination of selected atmospheric aromatic hydrocarbons at remote continental and oceanic locations using photoionization/flame-ionization detection

A new gas chromatographic technique with a modified photoionization detector connected in series with a conventional flame ionization detector was used to determine low concentrations of atmospheric hydrocarbons in remote atmospheres. Average mixing ratios of five aromatic hydrocarbons measured between 42°N and 30°S latitude in the Pacific Ocean in October/November 1983 were highest in the Northern Hemisphere. The average mixing ratios in the northern and southern marine atmospheres were 49±25 ppt (n=35) and 10±2 ppt (n=21) for benzene, 20±12 ppt (n=32) and 5.6±1.6 ppt (n=12) for toluene, 7.6±3.7 ppt (n=35) and 3.7±1.6 ppt (n=21) for ethylbenzene, 25±12 ppt (n=35) and 13±5 ppt (n=20) for the sum of m- and p-xylenes, and 14±6 ppt (n=35) and 6.6±3.0 ppt (n=21) for o-xylene, respectively. The first latitudinal gradients for these five aromatic compounds are reported. Benzene and toluene mixing ratios measured between July 1982 and October 1983 at a rural, mid-latitude continental site in eastern Washington state gave average values of 226±108 ppt and 133±84 ppt, respectively, with higher wintertime than summertime benzene levels. These continental samples gave calculated air mass ages averaging six days based on benzene-to-toluene ratios.     

辽河水中PAHs的污染水平及源解析

在辽河的干支流选择12个例行监测断面,分别于2007年8月和11月采集水样,分析16种US EPA（美国环保署）优控多环芳烃（PAHs）的浓度变化。结果表明：辽河丰水期16种PAHs总量的浓度范围为216—848 ng/L,平均值为430 ng/L,枯水期16种PAHs总量的浓度范围为221—1360 ng/L,平均值为660 ng/L。特征指数表明,辽河水中PAHs主要来源于燃料的高温不完全燃烧,燃烧源为机动车、煤和生物质等。     

Monitoring of polycyclic aromatic hydrocarbons in the Lake Baikal basin in the areas of intensive anthropogenic impact

Presented are the results of studying the content of polycyclic aromatic hydrocarbons and benz(a)pyrene in the lake water, in sewage waters of the enterprise, and in the upper 2-cm layer of bottom sediments in the area of the sewage discharge of Baikal Pulp and Paper Mill (BPPM), in bottom sediments in the north of Lake Baikal in the area of the Baikal-Amur Railroad, and in the channel and delta front of the Selenga River. The results were obtained at Hydrochemical Institute in 1981?C1989. The different content of benz[a]pyrene was determined for the first time in bottom sediments (sands and silts) for the bottom area of polygons in the mentioned regions. An intensive pollution exceeding significantly the normalized parameters for the benz[a]pyrene in bottom sediments is registered in the BPPM area only and its content in other areas does not exceed the background values on the whole.     

基于卫星遥感的南海真光层底颗粒有机碳输出通量时空特征研究

在加强海洋强国建设、实现我国碳达峰和碳中和愿景目标背景下准确掌握南海碳通量时空变化格局具有重要的现实意义。根据2009—2018年10 a有机碳通量月度数据集,分析了南海真光层底颗粒有机碳通量变化特征。结果表明:(1)南海区域多年真光层底有机碳输出通量年平均值为55.40 mgC·m^-2·d^-1;其值大小在空间上的分布存在近岸＞陆架＞海盆的趋势。(2)从季节上看,南海真光层底颗粒有机碳输出通量冬季最高,春、秋季次之,夏季最小;真光层底颗粒有机碳输出通量1、4、7、10月平均值分别为82.43、47.37、46.34、54.75 mgC·m^-2·d^-1。研究结果可为全面掌握南海碳循环过程和机制提供技术支撑。     

Observational study of surface ozone at an urban site in East China

In this study, we present the observational data of near surface ozone and some meteorological parameters during 2004, at an urban site (36°42′ N, 117°08′ E, 34.5 m a.s.l.) of Jinan, China. Hourly ozone concentrations exceeding the standard value of China, 100 ppbv, were observed for 65 h (in 23 days) from April to October, and values exceeding US NAAQS (National Ambient Air Quality Standard) for 1 h ozone, 120 ppbv, were observed for 15 h (in 7 days) from late May to early July. Ozone formation presented the phenomenon of “weekend effect”, especially in summer. Monthly variation of ozone coincided with temperature except for July and August. The low ozone levels in July and August may be due to the short sunshine duration and much rainfall during this period. Among these meteorological parameters, daily averaged ozone shows a significant correlation with temperature (r = 0.66) in the year and with relative humidity (r = − 0.75) in summer. Throughout the year, high ozone concentrations were mainly associated with the wind from 180 to 247.5°, while high ozone concentration seemed to have no obvious correlation with a given wind direction in summer. An anomalous nocturnal high ozone episode during 23–25 May 2004 was investigated. Growth fractions of ozone during the nighttime episode were 62.2% and 71.1% for 23 and 24 May, respectively. Synoptic analysis shows that favorable synoptic condition had presumably elevated the background ozone level in this region. Backward trajectory analysis shows that the increase of ozone concentration and the relatively constant high ozone concentrations during the night of May 23 might originate from the transport of ozone rich air mass above boundary layer. Transport of ozone from Yangtze Delta and East Central China might be a significant process for the high ozone level during night May 24 at Jinan.     

Aliphatic alkanes and polycyclic aromatic hydrocarbons in atmospheric PM10 aerosols from Baoji, China: Implications for coal burning

Normal alkanes and PAHs in atmospheric PM₁₀ aerosols collected during 2008 winter and spring in Baoji, a mid-scale inland city of China, were determined on a molecular level. Concentrations of n-alkanes ranged from 232 to 3583 ng/m³ with an average of 1733 ng/m³ in winter and from 124 to 1160 ng/m³ with an average of 449 ng/m³ in spring, while PAHs in the PM₁₀ samples were 594 ± 405 and 128 ± 82 ng/m³ in the two seasons. Molecular compositions showed that CPI (odd/even) values of n-alkanes were close to unity for all the samples especially in winter, and diagnostic ratios of PAHs (e.g., Phe/(Phe + Ant), CPAH/ΣPAHs and IcdP/(IcdP + BghiP)) were found similar to those in coal burning smoke with a strong linear relationship (R² ≥ 0.85) between PAHs and fossil fuel derived n-alkanes, demonstrating that coal burning is the main source of n-alkanes and PAHs in the city, especially in winter due to house heating. Concentrations of the determined compounds in Baoji are much higher than those in Chinese mega-cities, suggesting that air pollution in small cities in the country is more serious and need more attention.     

Characterization of nutrients in the atmospheric wet and dry deposition observed at the two monitoring sites over Yellow Sea and East China Sea

To investigate the atmospheric deposition of nutrients into the coastal and shelf regions of the northwest Pacific Ocean, observation sites were established upon Qianliyan Island (within the Yellow Sea) and the Shengsi Archipelago (within the East China Sea), respectively. Nutrient concentrations, including , were determined in both aerosols and rainwater samples. The analytical results contain clear seasonal signatures, with high values during the dry season and low values during the rainy season. Similar trends are observed for deposition fluxes. The amount of wet deposition is greater than that of dry deposition for the studied nutrient species. The influence of meteorological factors such as rainfall means that samples from Qianliyan Island record higher nutrient values than those from Shengsi. Along with riverine inputs, atmospheric deposition plays an important role in determining the biogeochemistry of nutrient species in coastal and shelf oceans. An erratum to this article can be found at     

Precipitation chemistry and corresponding transport patterns of influencing air masses at Huangshan Mountain in East China

One hundred and ten samples of rainwater were collected for chemical analysis at the summit of Huangshan Mountain, a high-altitude site in East China, from July 2010 to June 2011. The volume-weighted-mean （VWM） pH for the whole sampling period was 5.03. SO2- and Ca2＋ were the most abundant anion and cation, respectively. The ionic concentrations varied monthly with the highest concentrations in winter/spring and the lowest in summer. Evident inter-correlations were found among most ions, indicating the common sources for some species and fully mixing characteristics of the alpine precipitation chemistry. The VWM ratio of [SO]-]/[NO3] was 2.54, suggesting the acidity of rainwater comes from both nitric and sulfuric acids. Compared with contemporary observations at other alpine continental sites in China, the precipitation at Huangshan Mountain was the least polluted, with the lowest ionic concentrations. Trajectories to Huangshan Mountain on rainy days could be classified into six groups. The rainwater with influencing air masses originating in Mongolia was the most polluted with limited effect. The emissions of Jiangxi, Anhui, Zhejiang and Jiangsu provinces had a strong influence on the overall rain chemistry at Huangshan Mountain. The rainwater with influencing air masses from Inner Mongolia was heavily polluted by anthropogenic pollutants.     

Regional Characteristics of Typhoon-Induced Ocean Eddies in the East China Sea

The asymmetrical structure of typhoon-induced ocean eddies(TIOEs) in the East China Sea(including the Yellow Sea)and the accompanying air–sea interaction are studied using reanalysis products. Thirteen TIOEs are analyzed and divided into three groups with the k-prototype method: Group A with typhoons passing through the central Yellow Sea; Group B with typhoons re-entering the sea from the western Yellow Sea after landing on continental China; and Group C with typhoons occurring across the eastern Yellow Sea near to the Korean Peninsula. The study region is divided into three zones(Zones Ⅰ, Ⅱ and Ⅲ) according to water depth and the Kuroshio position. The TIOEs in Group A are the strongest and could reverse part of the Kuroshio stream, while TIOEs in the other two groups are easily deformed by topography. The strong currents of the TIOEs impact on the latent heat flux distribution and upward transport, which facilitates the typhoon development. The strong divergence within the TIOEs favors an upwelling-induced cooling. A typical TIOE analysis shows that the intensity of the upwelling of TIOEs is proportional to the water depth, but its magnitude is weaker than the upwelling induced by the topography. In Zones Ⅰ and Ⅱ, the vertical dimensions of TIOEs and their strong currents are much less than the water depths.In shallow water Zone Ⅲ, a reversed circulation appears in the lower layer. The strong currents can lead to a greater, faster,and deeper energy transfer downwards than at the center of TIOEs.     

Seasonal Variability of the Yellow Sea／East China Sea Surface Fluxes and Thermohaline Structure

We use the U.S. Navy‘s Master Oceanographic Observation Data Set (MOODS) for the Yellow Sea/East China Sea (YES) to investigate the climatological water mass features and the seasonal and non-seasonal variabilities of the thermohaline structure, and use the Comprehensive Ocean-Atmosphere Data Set (COADS) from 1945 to 1989 to investigate the linkage between the fluxes (momentum, heat, and moisture) across the air-ocean interface and the formation of the water mass features. After examining the major current systems and considering the local bathymetry and water mass properties, we divide YES into five regions: East China Sea (ECS) shelf, Yellow Sea (YS) Basin, Cheju bifurcation (CB) zone,Taiwan Warm Current (TWC) region, Kuroshio Current (KC) region. The long term mean surface heat balance corresponds to a heat loss of 30 W m^-2 in the ESC and CB regions, a heat loss of 65 W m^-2 in the KC and TWC regions, and a heat gain of 15 W m^-2 in the YS region. The surface freshwater balance is defined by precipitation minus evaporation. The annual water loss from the surface for the five subarea sranges from 1.8 to 4 cm month^-1. The fresh water loss from the surface should be compensated for from the river run-off. The entire water column of the shelf region (ECS, YS, and CB) undergoes an evident seasonal thermal cycle with maximum values of temperature during summer and maximum mixed layer depths during winter. However, only the surface waters of the TWC and KC regions exhibit a seasonal thermal cycle. We also found two different relations between surface salinity and the Yangtze River run-off,namely, out-of-phase in the East China Sea shelf and in-phase in the Yellow Sea. This may confirm an earlier study that the summer fresh water discharge from the Yangtze River forms a relatively shallow, low salinity plume-like structure extending offshore on average towards the northeast.     

中国东部夏季降水年际变化与东中国海及邻近海域海温异常的关系

本文首先利用1979～2008年中国756个站点和GPCP2.1的降水资料与Hadley中心的HadISST再分析海温资料以及应用合成和相关分析方法,分析了中国东部夏季降水年际变化及其与东中国海及邻近海域海温异常的关系.分析结果表明:当东中国海及邻近海域为暖(冷)异常时,长江中下游、江淮地区夏季降水减少(偏多),而东北南部的降水偏多(减少).并且,本文应用RegCM3区域气候模式对上述关系进行数值试验,结果表明了东中国海及邻近海域的暖(冷)异常,将使得我国长江、黄淮流域和华北大部分地区夏季降水的减少(增加),而华南地区、东北南部和朝鲜半岛等地夏季降水的增加(减少).此外,本文还利用NCEP/N     

Ship measurements of submicron aerosol size distributions over the Yellow Sea and the East China Sea

During the spring of 2005, the total particle concentrations and the submicron aerosol size distributions were measured on board the research vessel over the south sea of Korea and the Korean sector of the Yellow Sea. Similar measurements were made over the East China Sea in autumn 2005. The aerosol properties varied dynamically according to the meteorological conditions, the proximity to the land masses and the air mass back trajectories. The average total particle concentration was the lowest over the East China Sea, 4335 ± 2736 cm^− 3, but the instantaneous minimum, 837 cm^− 3, for the entire ship measurement was recorded during the Yellow Sea cruise. There was also a long (more than 6 h) stretch of low total particle concentrations that fell as low as 1025 cm^− 3 during the East China Sea cruise when the ship was the farthest from the shores and the air mass back trajectories resided long hours over the sea. These observations lead to the suggestion of ~ 1000 cm^− 3 as the background total particle concentration over the marine boundary layer in the studied region of the Yellow Sea and the East China Sea, implying significant anthropogenic influence even for the background value. In the mean time, average aerosol size distributions were unimodal and the mode diameter ranged between 52 and 86 nm, excluding the fog periods, which suggests that the aerosols measured in this study experienced relatively less aging processes within the marine boundary layer.     

东中国海夏季潜热通量的时空特征及其与中国东部降水的联系

利用1985—2006年OAflux、NCEP/NCAR再分析资料和中国大陆东部的120个测站降水资料,应用EOF分解和线性回归等方法分析了东中国海夏季海气热通量时空特征及其与中国东部夏季降水的关系。结果表明,东中国海夏季潜热通量EOF1模态空间场的强信号区为黄海、东海至台湾海峡和南海北部局部海域,时间系数(PC1)表现出显著的年际变化和1997年前后的突变。降水和经向环流的PC1回归分析还表明,夏季潜热通量的异常变化与中国东部降水和经向环流的变化密切相关,潜热通量正异常对应黄淮地区和华南地区的上升气流正异常,降水偏多,而东北与华北地区为下沉气流正异常,降水偏少。1997年前后东中国海潜热通量发生突变之后呈明显的上升增强趋势,使得上述现象更为显著,即:对应东中国海夏季潜热通量的正异常,黄淮地区和华南地区为上升气流正异常,降水偏多;东北地区和华北地区为下沉气流正异常,降水偏少。这表明夏季东中国海及邻近海域潜热通量的异常变化是导致中国东部汛期降水年际和年代际异常的重要原因之一。     

东中国海黑潮海洋锋的季节变化特征及其成因

利用高分辨率海洋和大气再分析资料研究了东中国海黑潮海洋锋的季节变化特征及其成因。研究表明,东海黑潮海洋锋存在明显的季节变化,从冬季到次年春季逐渐增强,并在春季达到最强,初夏以后强度逐渐减弱,9—10月达到全年最弱。通过诊断混合层热流量方程发现,东海黑潮区一年四季均表现为暖的温度平流,有利于海洋锋的形成和维持,该暖平流也存在季节变化并在春季达到最大,对海洋锋在春季达到最强起了重要作用。海气界面净热通量在秋冬季对海洋锋的形成有促进作用,有利于海洋锋增强,而在春夏季则起抑制作用,促进海洋锋消亡。温度垂直输送全年对海洋锋起一定程度的抑制作用。总之,在海温水平平流和海表净热通量的共同作用下导致海洋锋春季达到最强,而夏秋季海表净热通量和温度垂直输送作用的共同作用致使海洋锋减弱并最后消失。因此,海洋的动力和热力共同作用导致了东海黑潮海洋锋的季节变化,其中海温水平平流和海表净热通量对海洋锋的季节变化起主要作用,而温度垂直输送项对海洋锋的发展起抑制作用,但影响相对较小。     

东海黑潮暖舌的演变及其对我国气温的影响

利用高分辨率的海温分析资料模式资料,分析了黑潮暖舌与我国气温的关系,初步探讨了太平洋年代际振荡(PDO)等造成黑潮暖舌变化的可能原因。结果表明,冬季和春季东海黑潮暖舌存在明显的年际和年代际变化。暖舌在1996/1997年发生了一次突变,此前暖舌处在偏冷的状态,之后转为偏暖的状态。我国冬季和春季气温存在一定的年代际变化,1997年之后,冬季除东北和新疆外,气温有所偏高,而春季气温全国表现为一致的显著偏高。冬季和春季气温对黑潮暖舌存在邻(域)响应。冬季东海黑潮暖舌指数与冬季我国东部气温存在正相关,并且这一相关性能够延续到次年春季。冬季黑潮暖舌指数与我国4月海陆热力差异指数也存在显著的正相关。当冬季暖舌偏强(弱)时,4月海陆热力差异指数偏高(低),即东亚地区海陆热力差异偏大(小)。春季黑潮暖舌指数与春季我国中部及南方地区气温也存在正相关,当春季黑潮暖舌偏强(弱)时,上述地区气温将偏高(低)。PDO和黑潮暖舌之间的相互作用存在一个反馈机制。西风的增强,可通过使海洋向大气释放热量增加和向南的埃克曼(Ekman)输送,降低北太平洋中部的SST,而这一地区SST的降低对应着PDO的暖位相。增强的负风应力旋度在北太平洋副热带流涡中强迫出的向南斯维尔德鲁普(Sverdrup)流也偏强,而向北流动的东海黑潮的增强正是补偿了这一向南的海流。黑潮增强后经过两个月将大量热量输送至北太平洋中部,增强了这一地区的SST,而这对应着PDO的冷位相。     

Comparison of Characteristics Between the South China Sea Summer Monsoon Outbreaks in 2004 and 2008

The South China Sea summer monsoon is an important system affecting the weather and climate in China;its outbreak and evolution vary from year to year.Using the reanalysis data from the U.S.National Centers for Environmental Prediction (NCEP) and outgoing longwave radiation (OLR) data from the National Oceanic and Atmospheric Administration (NOAA),USA,we analyze the circulation pattern,precipitation distribution,convection,temperature,and humidity around the monsoon outbreaks in 2004 and 2008.Results show that the monsoon had a late onset in 2004 (May 19) but an early outbreak in 2008 (May 4).Prior to the monsoon outbreak in 2008,cross-equatorial flows in Somalia were weaker than in 2004,subtropical precipitation did not arrive in southern China as it did in 2004,and the strongest convection was located more southward than in 2004.The results also indicate that accumulated rainfall in the Indochina Peninsula was about 61% of that in 2004 during a period of 25 days leading up to the monsoon outbreak,causing differences in land surface processes and then different activity levels for the summer monsoon.Post-onset warm and humid conditions in 2008 (2004) maintained through the end of October (mid-September),while the summer monsoon lasted longer in 2008 than in 2004.     

近海面风场对黄东海域海平面特征影响的分析与模拟

基于1993—2012年TOPEX/Poseidon(T/P)卫星海平面异常SLA(Sea Level Anomaly)数据和FSCR(Climate Forecast System Reanalysis)再分析风场资料,分析黄东海域近20 a海平面的时空分布特征,尤其是不同时间尺度风场影响的变化特征,进而通过区域海洋模式对海面高度短期变化的可能机制进行探讨。结果表明:1)黄东海域海平面多年平均状态为南高北低,近海面季节性风场在岸线分布和海水热膨胀特征下,造成海面冬春季偏低,夏秋季偏高。近20 a黄东海域平均风速逐步减弱,平均海面上升速率为2.9 mm/a。2)风场的短期活动主要为灾害性大风,统计显示冬夏寒潮大风和台风大风均呈频数减少、强度增强的趋势。运用FVCOM(Finite Volume Community Ocean Model)模拟分析台风和寒潮作用下黄东海域海平面的变化,发现台风强风可形成辐散式海流气旋式涡旋,对应海面为下凹负值中心;北路寒潮大风可形成海流反气旋式涡旋,对应海面为上凸正值中心。两类涡旋的强海流部分增强了海面倾斜度。3)强海流部分动能和动量迅速向海水深部下传,无论在深度和强度上,寒潮造成的海流涡旋动能和动量下传比台风涡旋更迅速,更强。这与寒潮降温引起的海洋层结不稳定对流作用有关。     

东亚冬季环流季节内振荡与2008年初南方大雪关系

2008年1月10～16日、18～22日、24～29日和1月31日～2月2日,中国南方地区连续出现4次低温、雨雪、冰冻天气。根据NCEP/NCAR逐日再分析资料,利用LANCZOS滤波器以及小波分析等方法,探讨雨雪冰冻前期2007年12月2日～2008年1月1日、同期2008年1月2～21日及后期2008年1月22日～2月14日850 hPa风场季节内振荡特征及对低温、雨雪、冰冻天气的影响。2007年12月～2008年2月850 hPa风场低频振荡分析显示,中国南方地区风场表现显著的20~50 d低频振荡,季节内低频振荡的位相变化,较好地揭示了2008年1月10日～2月2日南方地区降雪过程的3种环流特征：1）沿高原东侧100°E附近南下的冷空气到达我国30~20°N地区,与东亚沿海低纬的偏南风距平气流在我国南方地区形成气旋性环流,南方降雪（水）过程中,偏南风距平气流比偏北风距平气流强;2）沿高原东侧100°E附近南下的强偏北风距平气流与东亚沿海低纬的偏南风距平气流在我国南方地区形成气旋性环流,南方降雪（水）过程中,偏北风距平气流比偏南风距平气流强,造成南方雨雪伴随低温冰冻天气;3）南方雨雪由偏北风距平气流与偏南风距平气流在东亚东部25°N形成的辐合带引起。