Temporal geochemical evolution in oceanic intra-plate volcanics: a case study from the Marquesas (French Polynesia) and comparison with other hotspots

Sr-, Nd-isotopic and trace element data are reported for a suite of Marquesan volcanic rocks. These data complement earlier work on the island of Ua Pou and reveal that the marked shifts in source composition between shield-building and post-shield eruptives noted there are common to most islands in the archipelago. In addition, there appears to be a relationship between the magnitude of these shifts and the repose period between shield-building and post-shield activity such that, the longer the period of volcanic inactivity, the larger the isotopic and trace element differences between the two phases of volcanism. This, coupled with the compositional uniformity of the shield-building phase, and its close geochemical similarity to depleted mantle reservoirs, implies a strong lithosperic control on magmatic evolution: models invoking entrainment of asthenospheric material during plume ascent are not readily compatible with the observed time-compositional paths. Comparisons with other oceanic islands reveal two end member styles of temporal evolution, herein termed Marquesan and Hawaiian, and attributed to the interaction between the oceanic lithosphere and respectively weak and strong plumes, terms used to denote penetrative capacity and not necessarily size or buoyancy flux. Many other plumes may display characteristics intermediate between these extremes. The state of stress and temperature within the oceanic lithosphere in the region of an ascending diapir is also likely to exert a strong control on the geochemical evolution of OIB suites.     

Geochemistry of Heard Island (Southern Indian Ocean): Characterization of an Enriched Mantle Component and Implications for Enrichment of the Sub-Indian Ocean Mantle

Lavas from Heard Island, located on the Kerguelen Plateau inthe southern Indian Ocean, exhibit the largest range (e.g.,⁸⁷Sr/⁸⁶Sr=0.7047–0.7079) of isotopic compositions yetobserved on a single oceanic island. Isotopic compositions arewell correlated and are accompanied by systematic changes inincompatible trace element ratios, particularly those involvingNb. These variations are interpreted as resulting from mixingbetween two components. One is characterized by high ⁸⁷Sr/⁸⁶Sr,low ²⁰⁶Pb/²⁰⁴Pb and ¹⁴³Nd/¹⁴⁴Nd ratios, and negative Nb andEu anomalies, and is derived ultimately from the upper continentalcrust. The other has lower ⁸⁷Sr/⁸⁶Sr, and higher ²⁰⁶Pb/²⁰⁴Pband ¹⁴³Nd/¹⁴⁴Nd ratios, and lacks the depletions in Nb and Eu.Two possible compositions are considered for the low-⁸⁷Sr/⁸⁶Srcomponent of the source. The first is at the low-⁸⁷Sr/⁸⁶Sr endof the Heard Island data array, represented most closely bylavas from the Laurens Peninsula. However, trace element variationssuggest that these lavas might not be representive of the Heardplume. The second is close to the low-⁸⁷Sr/⁸⁶Sr end of the isotopicarray for lavas from the main volcano. In this case a lithosphericmantle origin is suggested for the Laurens Peninsula lavas.The relationships between isotopic data, major element compositions,and incompatible trace element ratios indicate that the continent-derivedmaterial is probably present in the mantle source, where itmakes a maximum contribution of <4 wt.% for all but one HeardIsland sample. However, if the Kerguelen Plateau is a submergedcontinental block, shallow-level contamination cannot be ruledout. The binary mixing model developed to explain the Heard Islandgeochemical variations is extended to include other Indian Oceanoceanic island and mid-ocean ridge basalts (OIB and MORB). Weshow that isotopic compositions of Indian Ocean OIB are consistentwith sampling of a regional reservoir in which the same twocomponents exist in variable proportions (generally 1–5wt.% of the continent-derived component). The distinctive isotopiccompositions of Indian Ocean MORB are consistent with mixingof a similar component into an Atlantic-or Pacific-like MORBmantle source. The relatively unradiogenic ²⁰⁶Pb/²⁰⁴Pb isotopiccompositions of these ‘enriched’ Indian Ocean mantlecomponents are unlike any present-day marine sediments and indicatethat their source has had ²³⁸U/²⁰⁴Pb ratios (µ) much lowerthan typical upper continental crust for > 1 Ga. These agespre-date the formation of Gondwana (600-130 Ma) and thereforedo not support sediment subduction beneath Gondwana as the causeof enrichment in the sub-Indian Ocean mantle. We propose thatthe enrichment of Indian Ocean OIB sources was due to subductionof upper-crustal material beneath a Proterozoic precursor ofGondwana at 1–2 Ga. The enrichment of the Indian OceanMORB sources could have had a similar origin, or could havebeen derived from sub-continental lithospheric mantle returnedto the asthenospheric mantle, perhaps during the break-up ofGondwana (200–130 Ma).     

南岭科学钻中与两种岩浆岩有关的矿床成矿系列——年代学、地球化学、Hf同位素证据

南岭科学钻(SP-NLSD-1)位于南岭成矿带与武夷山成矿带的交汇部位——赣南银坑矿田。该钻孔总进尺2967.83 m,钻遇了流纹岩、花岗斑岩、花岗闪长斑岩、辉长闪长玢岩等四种岩浆岩。流纹岩为银坑矿田新揭露的岩石类型,LA-ICP-MS锆石U-Pb定年表明其形成于(381.0±3.1)Ma,补充完善了本区海西期岩浆活动的记录;花岗斑岩、花岗闪长斑岩、辉长闪长玢岩的成岩时代为101.3~161.0 Ma,为燕山期岩浆活动的产物。流纹岩与花岗斑岩具有相似的地球化学特征,球粒陨石标准化稀土元素配分曲线为两翼近平坦的海鸥型,有明显的Eu负异常,显著富集大离子亲石元素,轻微富集高场强元素,锆石εHf(t)值分别为–10.8~–7.1、–23.4~–8.7;花岗闪长斑岩与辉长闪长玢岩的地球化学特征相似,球粒陨石标准化稀土元素配分曲线为右倾型,Eu负异常不明显,显著富集大离子亲石元素,轻微富集高场强元素,花岗闪长斑岩的锆石εHf(t)值为–17.9~–1.9。岩相学、年代学和地球化学研究结果表明,流纹岩、花岗斑岩、花岗闪长斑岩、辉长闪长玢岩应该均为古元古代地壳物质重熔形成的壳源岩浆岩,花岗闪长斑岩和辉长闪长玢岩在形成过程中可能继承了幔源物质。流纹岩与银坑矿田内已知的成矿作用无直接关系,花岗斑岩与钨铋铀矿化有关,花岗闪长斑岩与铜铅锌金银矿化有关。银坑矿田处于特殊的构造部位,即南岭成矿带与武夷山成矿带交汇部位,深达地幔的线型断裂和切入地壳的网格状断裂同时在此处发育,不同的构造环境导致在燕山期形成花岗闪长斑岩和花岗斑岩,分别对应铜铅锌金银矿化和钨多金属矿化,形成两个相对独立的成矿系列。     

Rapid Change of Lava Composition from 1998 to 2002 at Piton de la Fournaise (Reunion) Inferred from Pb Isotopes and Trace Elements: Evidence for Variable Crustal Contamination

After an unusually long quiet period of nearly 6 years, in 1998the Piton de la Fournaise volcano started a new cycle of intensevolcanic activity. We report geochemical data on the first nineevents (53 samples), from the long-lived initial eruption (sixand a half months) of 1998 to the high-flux picritic eruptionof January 2002. Pb isotopes and trace elements display systematic,coupled variations, which are mostly confined to the beginningand the end of the period. Two well-defined binary mixing trendsare shown by Pb–Pb and Pb–trace element relationships.These trends indicate a change of end-member components betweenMarch and June 2001 that coincides with the transition fromsteady-state basalts to picrites. A three-component mixing modelinvolving a homogeneous plume and two contaminants successfullyexplains the data. The Pb–Pb relationship requires thattwo mixing processes occur successively: plume-derived magmainteracts first with altered oceanic crust, and the resultinghybrid product then interacts at shallower level with the oldlavas constituting the base of the volcanic edifice. Assimilationof edifice material decreased continuously from 1998 to 2002,whereas assimilation of oceanic crust drastically increasedduring the late-stage picritic eruption. These results suggestthat picrites may have resided for an unusually long time atan oceanic crustal level before ascending rapidly through thevolcanic edifice with little interaction with channel walls. KEY WORDS: assimilation; lead isotopes; picrites; Piton de la Fournaise; trace elements     

High Field Strength Element Fractionation in the Upper Mantle: Evidence from Amphibole-Rich Composite Mantle Xenoliths from the Kerguelen Islands (Indian Ocean)

A basanite dyke in the Kerguelen Archipelago contains abundantcomposite mantle xenoliths consisting of spinel-bearing dunitescross-cut by amphibole-rich veins. Two types of veins (thickand thin) have been distinguished: the thick veins representalmost complete crystallization products of highly alkalinemelts similar to the host basanites, whereas thin veins areprecipitates from fractionates of the parental melts to thethick veins. These fractionated fluids are enriched in H₂O relativeto the parental melts. The amphiboles in the thin veins arelower in Ti and higher in Nb, Ta, Zr and Hf than amphibolesin the thick veins. This fractionation of high field strengthelements (HFSE) is consistent with a combination of the changingcomposition of the fractionated fluids and the change in intrinsicamphibole–fluid partition coefficients for HFSE in fluidswith higher a_H2O and lower a_TiO2. The trace element contentof amphiboles disseminated in dunitic wall-rocks is closelyrelated to the composition of adjacent veins and thus theseamphiboles are precipitates from fluids percolating into thedunite from the veins. Disseminated amphibole reflects the compositionof the percolating melt, which is similar to that of the associatedveins. KEY WORDS: mantle amphibole; Kerguelen; HFSE fractionation; mantle HFSE; mantle xenoliths     

冀中地热区深部热水微生物群落组成及其功能预测

了解深部微生物群落组成和功能对探索早期生命起源和利用其独特功能均有重要意义.地热区深部碳酸盐岩岩溶-裂隙热储环境中微生物群落组成和功能特性仍然不清.为了探测冀中地热区深部热水微生物群落组成与功能特性,以浅层水和土壤为参照,利用冀中地热区地热科学钻探孔抽水试验,采集深部热水样,同时采集每个钻孔上方附近的大田农灌井浅层水和...     

中国阿尔泰造山带花岗岩Pb同位素组成特征:幔源成因佐证及陆壳生长意义

为进一步对阿尔泰造山带花岗岩进行物源示踪研究,本文选择几个较典型的同造山和后造山不同类型的花岗岩以及相伴生的基性岩进行长石Pb同位素的测定。结果显示花岗岩206Pb/204Pb范围为17.997~18.921,平均值为18.269;207Pb/204Pb范围为15.460~15.599,平均值为15.528;208Pb/204Pb范围为37.661~38.262,平均值为37.954;其μ值为9.19~9.71,集中于9.30~9.60,与典型的壳源花岗岩明显不同。在源岩判别图解上,主要落在洋岛玄武岩和岛弧玄武岩的范围内,所有点远离上地壳、下地壳和深海沉积物,其源区性质类似于洋岛玄武岩和岛弧玄武岩,与花岗岩同时代的伴生基性岩Pb同位素也具有相似的特征,说明两者可能具有相似的物源特征,即幔源组分。这与报道的Sr、Nd同位素的特征相一致,进一步证明阿尔泰花岗岩具有幔源组分。这种特点与其他造山带(如华南、喜马拉雅)明显不同,显示阿尔泰花岗岩的特殊性。该研究从另一个侧面证明中亚造山带存在一定规模的显生宙陆壳生长。     

Vertical fault systems in the tectonosphere geoelectrical section in petroliferous domains of Sakhalin Island (Russia) and Gulf of Tonkin (Vietnam): Evidence from magnetotelluric sounding

The transverse current anomalies evident from magnetotelluric sounding (MTS) data in the transition zone from the Asian continent to the Pacific Ocean and a geoelectrical model suitable for explaining these effects are discussed. Using simulation results and new MTS data on Sakhalin and northern Vietnam, ultra-deep fluid–fault system (UDFFS) models are constructed, comprising steeply dipping low-resistivity and high-resistivity linear bodies which penetrate through the whole section of the lithosphere, continuing deep into the asthenosphere. The structure of these systems reflects the development of deep and ultra-deep fault zones, along which mantle-originated fluids may migrate through sediments to reach the surface. This allows the anisotropic–conductive fractured structures adjacent to these faults to be considered as being most favorable for hydrocarbon accumulations.     

Variable Phanerozoic thermal history in the Southern Canadian Shield: Evidence from an apatite fission track profile at the Underground Research Laboratory (URL), Manitoba

Analysis of a 1.15 km deep apatite fission track (AFT) thermochronology profile at the Underground Research Laboratory (URL), in the southwestern Canadian Shield suggests two Phanerozoic heating and cooling episodes indicating significant, previously unsuspected, Phanerozoic heat flow variations. Phanerozoic temperature and heat flow variations are temporally associated with burial and erosion of the Precambrian crystalline shield and its overlying Phanerozoic successions, which are now eroded completely. Maximum Phanerozoic temperatures occurred in the late Paleozoic when the geothermal gradient is estimated to have been ~ 40-50 °C/km (compared to a present day gradient of ~ 14 ± 2 °C/km) and the sedimentary cover was ~ 800-1100 m thick. Our thermal history models, confirm regional stratigraphic relationships that suggest that the Paleozoic succession was completely eroded prior to beginning of Mesozoic sedimentation. A second heating phase occurred during Late Cretaceous-Paleogene burial when the geothermal gradient is estimated to have been ~ 20-25 °C/km and the Mesozoic and Cenozoic succession was ~ 1200 to 1400 m thick. The Phanerozoic thermal history at the URL site shows a pattern similar to that inferred previously for the epicratonic Williston Basin, the centre of which lies several 100 km to the west. This implies a common regional thermal history for cratonic rocks underlying both the basin and the currently exposed shield. It is suggested that the morphotectonic differences between the Williston Basin and the exposed shield at the URL are due to a dissimilar thermomechanical response to a common, but more complicated than previously inferred, Phanerozoic geodynamic history. The two Phanerozoic periods of variations in geothermal gradient (heat flow) were coeval with epeirogenic movements related to the deposition and erosion of sediments. These paleogeodynamic variations are tentatively attributed to far-field effects of orogenic processes occurring at the plate margin (i.e. the Antler and the Cordilleran orogenies) and the associated accumulation of cratonic seaway sedimentary sequences (Kaskaskia and Zuni sequences).     

中国大陆科学钻探主孔100~2000 m测井磁化率和磁三分量分析

对比分析了中国大陆科学钻探(CCSD)主孔100~2 000 m测井磁化率与岩心样本磁化率的测量结果,二者具有较好的一致性。测井磁化率统计结果表明CCSD主孔100~2 000 m超高压变质岩的磁化率从高至低依次为:蛇纹岩、石英榴辉岩、金红石榴辉岩、正片麻岩、退变质榴辉岩、多硅白云母榴辉岩、副片麻岩、绿泥石角闪岩、角闪岩。由CCSD主孔100~2 000 m磁三分量测量数据得到磁异常的△BZ、△BH和△BT值,结合前人所做的岩石学研究分析发现:主孔530~575 m的磁异常主要由岩石的金红石矿化、钛磁铁矿化和磁铁矿化引起,604~643 m和652~678 m的磁异常主要由岩石的蛇纹石化引起;钻孔中岩层的磁化率对磁三分量异常起着主要的决定作用,高磁化率岩层都表现出较大的磁三分量异常。     

The central Qiangtang Metamorphic Belt in northern Tibet is an in-situ Paleo-Tethys Ocean: Evidence from newly discovered Late Devonian radiolarians

The paleogeographic position of the North Qiangtang Block, as well as the origin of the Central Qiangtang Metamorphic Belt (CQMB) have subjected to considerable debate that hampers the understanding of the early evolution of the Paleo-Tethys Ocean. This study reports a new radiolarian fauna of a Famennian age (Late Devonian) from the ophiolitic mélange south of Gangtang Co, northern Tibet, including Callela parvispinosa Won, Entactinia foveolata Nazarov, and Plenoentactinia pinguis Won. The discovery of Devonian radiolarians in the CQMB strongly supports the model that the Longmu Co–Shuanghu suture zone represents the main branch of the Paleo-Tethys Ocean. A correlation of the Late Devonian radiolarian in Tethys realm reveals that the Longmu Co–Shuanghu suture zone was connected to the Changning–Menglian suture zone in western Yunnan, the Chiang Mai–Inthanon and Chanthaburi suture zones in Thailand, and the Bentong–Raub suture zone in Malay Peninsula. The synchronous advent of Late Devonian radiolarians suggests that the Paleo-Tethys Ocean may have opened during that time.     

Platinum-group minerals in dolerites from Alexandra Land Island: (Franz Josef Land Archipelago)

Lavas in Alexandra Land Island of the Franz Josef Land Archipelago bear Au-Cu-Pd-type mineralization. The found mineral species belong to the Cu-Au-Pd and Pd-Cu-(Te + Sb + S + As) systems being, respectively, (i) cuproauride (Au(Cu, Pd)) and auricupride (Au(Cu,Pd)₃) and (ii) phases similar to skaergaardite (PdCu), nielsenite (PdCu₃), and numerous S-Te-Sb-Pd-Cu phases of various compositions. The morphology of PGM existing as tiny grains and films along the boundaries of plagioclase and clinopyroxene and in cracks, their crystallization at low temperatures predicted by experimental data, and the presence of native copper with sulfur impurity are signatures of postmagmatic origin. The Alexandra Land tholeiitic basalts and dolerites were, most likely, produced by the hotspot which may be the source of PGE-bearing intrusions in eastern Greenland that contain PGM similar to those discussed in the paper.     

Hydrous aluminosilicate metasomatism in an intra-oceanic subduction zone: Implications from the Kurancali (Turkey) ultramafic-mafic cumulates within the Alpine Neotethys Ocean

The Kurancali ultramafic-mafic cumulate body, an allochthonous ophiolitic sliver in central Anatolia, is characterized by the presence of abundant hydrous phases (phlogopite, pargasite) besides augitic diopside, plagioclase, and accessory amounts of rutile, sphene, apatite, zircon, and calcite. Based on modes of the essential minerals, the olivine-orthopyroxene-free cumulates are grouped as clinopyroxenite, hydrous clinopyroxenite, phlogopitite, hornblendite, layered gabbro, and diorite. Petrographical, mineralogical and geochemical features of the rocks infer crystallization from a hydrous magma having high-K calc-alkaline affinity with slightly alkaline character, and point to metasomatised mantle as the magma source. Our evidence implies that the metasomatising component, which modified the composition of the mantle wedge source rock in an intra-oceanic subduction zone, was a H₂O, alkali and carbonate-rich aluminosilicate fluid and/or melt, probably derived from a subducted slab. We suggest that the metasomatic agents in the subarc mantle led to the generation of a hydrous magma, which produced the Kurancali cumulates in an island-arc basement in a supra-subduction-zone setting during the closure of the Izmir-Ankara-Erzincan branch of the Alpine Neotethys Ocean.     

Deep root of a continent-continent collision belt: Evidence from the Chinese Continental Scientific Drilling (CCSD) deep borehole in the Sulu ultrahigh-pressure (HP-UHP) metamorphic terrane, China

The Chinese Continental Scientific Drilling (CCSD) deep borehole, which reached a depth of 5158 m in the Sulu ultrahigh-pressure (UHP) metamorphic terrane, provides a new window into the deep root of a continent-continent collision belt, and the tectonic processes by which supracrustal material is recycled into the mantle by subduction and then uplifted to the surface. Major research themes of the CCSD project were to: (1) determine the three-dimensional composition, structure and geophysical character of the deep root of this orogenic belt; (2) investigate the nature and timing of the UHP metamorphism; (3) investigate the processes of crust-mantle interaction involved in the formation and exhumation of the UHP rocks; (4) study the process of fluid circulation and mineralization during subduction and exhumation; (5) study the rheological properties of the various rocks during subduction and exhumation; (6) develop and refine dynamic models for deep subduction and exhumation of crustal rocks, and (7) establish a long-term, natural laboratory for the study of present-day crustal dynamics (e.g., stress, strain, fluid activity). The CCSD has developed precise oriented profiles of the main borehole in terms of lithology, geochemistry, oxygen isotopes, zircon SHRIMP U-Pb ages, ⁴⁰Ar-³⁹Ar ages, deformation, rheology, mineralization, physical properties of the rocks, petrophysical logs, seismic reflections and underground fluids. The present paper summarizes the integrated research results of this project, especially the new findings concerning the deep root of a continent-continent collision.     

Geochemistry and petrology of lavas from the submarine flanks of Réunion Island (western Indian Ocean): implications for magma genesis and the mantle source

Summary Major and trace element data as well as Sr and Nd isotope compositions for submarine lavas from the flanks of Réunion island are reported. The submarine basalts of the island have major and trace element compositions similar to those of the subaerial basaltic rocks. This implies that no compositional change occurs in the shield-building magmas of the two Réunion volcanoes. Fractional crystallization of lavas from both Piton de la Fournaise and Piton des Neiges begin well within the mantle at pressures up to 1 GPa which is significantly deeper than the crust-mantle boundary at about 12 km depth. The Réunion primary magmas form at an average depth of about 4 GPa in agreement with the thickness of the plate beneath the island. Lavas from both Réunion volcanoes have similar trace element compositions with the exception of lower Th/Ba for Piton des Neiges which implies a relatively homogeneous plume source during, at least, the last 2 Ma. The lack of any variation in the partial melting processes during this time span implies a thermal steady state of the plume centre. The Réunion lavas form either from a source that was enriched by partial melting or that contains recycled enriched MORB. Based on MORB- like Ce/Pb and Nb/U ratios an influence by fluid-metasomatized mantle, sediment or continental crustal material in the Réunion source appears unlikely. Received August 15, 2000; revised version accepted June 21, 2001     

Evidence of magmatic CO2-rich fluids in peraluminous graphite-bearing leucogranites from Deep Freeze Range (northern Victoria Land,Antarctica)

Fine-grained peraluminous synkinematic leuco-monzogranites (SKG), of Cambro-Ordovician age, occur as veins and sills (up to 20–30 m thick) in the Deep Freeze Range, within the medium to high-grade metamorphics of the Wilson Terrane. Secondary fibrolite + graphite intergrowths occur in feldspars and subordinately in quartz. Four main solid and fluid inclusion populations are observed: primary mixed CO₂+H₂O inclusions + Al₂SiO₅ ± brines in garnet (type 1); early CO₂-rich inclusions (± brines) in quartz (type 2); early CO₂+CH₄ (up to 4 mol%)±H₂O inclusions + graphite + fibrolite in quartz (type 3); late CH₄+CO₂+N₂ inclusions and H₂O inclusions in quartz (type 4). Densities of type 1 inclusions are consistent with the crystallization conditions of SKG (750°C and 3 kbar). The other types are post-magmatic: densities of type 2 and 3 inclusions suggest isobaric cooling at high temperature (700–550°C). Type 4 inclusions were trapped below 500°C. The SKG crystallized from a magma that was at some stage vapour-saturated; fluids were CO₂-rich, possibly with immiscible brines. CO₂-rich fluids (±brines) characterize the transition from magmatic to post-magmatic stages; progressive isobaric cooling (T<670°C) led to a continuous decrease off _{O 2} can entering in the graphite stability field; at the same time, the feldspars reacted with CO₂-rich fluids to give secondary fibrolite + graphite. Decrease ofT andf _{O 2} can explain the progressive variation in the fluid composition from CO₂-rich to CH₄ and water dominated in a closed system (in situ evolution). The presence of N₂ the late stages indicates interaction with external metamorphic fluids.Contribution within the network Hydrothermal/metamorphic water-rock interactions in crystalline rocks: a multidisciplinary approach on paleofluid analysis. CEC program: Human Capital and Mobility     

Platinum-group elements, S, Se and Cu in highly depleted abyssal peridotites from the Mid-Atlantic Ocean Ridge (ODP Hole 1274A): Influence of hydrothermal and magmatic processes

Highly depleted harzburgites and dunites were recovered from ODP Hole 1274A, near the intersection between the Mid-Atlantic Ocean Ridge and the 15°20′N Fracture Zone. In addition to high degrees of partial melting, these peridotites underwent multiple episodes of melt–rock reaction and intense serpentinization and seawater alteration close to the seafloor. Low concentrations of Se, Cu and platinum-group elements (PGE) in harzburgites drilled at around 35–85 m below seafloor are consistent with the consumption of mantle sulfides after high degrees (>15–20 %) of partial melting and redistribution of chalcophile and siderophile elements into PGE-rich residual microphases. Higher concentrations of Cu, Se, Ru, Rh and Pd in harzburgites from the uppermost and lowest cores testify to late reaction with a sulfide melt. Dunites were formed by percolation of silica- and sulfur-undersaturated melts into low-Se harzburgites. Platinum-group and chalcophile elements were not mobilized during dunite formation and mostly preserve the signature of precursor harzburgites, except for higher Ru and lower Pt contents caused by precipitation and removal of platinum-group minerals. During serpentinization at low temperature (<250 °C) and reducing conditions, mantle sulfides experienced desulfurization to S-poor sulfides (mainly heazlewoodite) and awaruite. Contrary to Se and Cu, sulfur does not record the magmatic evolution of peridotites but was mostly added in hydrothermal sulfides and sulfate from seawater. Platinum-group elements were unaffected by post-magmatic low-temperature processes, except Pt and Pd that may have been slightly remobilized during oxidative seawater alteration.     

Formation of Mud-Volcanic Fluids in Taman (Russia) and Kakhetia (Georgia): Evidence from Boron Isotopes

Temperatures of the formation of mud-volcanic waters are determined based on concentrations of some temperature-dependent components (Na–Li, Mg–Li). Estimates obtained for the Taman and Kakhetia regions are similar and range from 45 to 170°, which correspond to depths of 1–4.5 km. The calculated temperatures correlate with the chemical (Li, Rb, Cs, Sr, Ba, B, I, and HCO₃) composition of water and ¹³ (₂) and ¹³ (CH₄) values in spontaneous gases. The isotope values indicate that mechanisms of the formation of ¹³-rich gases, i.e., gases with high ¹³ values (up to +16.0 in ₂ and –23.4 in CH₄) in mud-volcanic systems of Taman and Kakhetia are governed by fluid-generation temperatures rather than the supply of abyssal gases. The ¹¹ value was determined for the first time in mud-volcanic products of the Caucasus region. This value ranges from +22.5 to +39.4 in the volcanic water of Georgia, from –1.2 to +7.4 in the clayey pulp of Georgia, and from –7.6 to +13.2 in the clayey pulp of Taman. It is shown that the ¹¹ value in clay correlates with the fluid-generation temperature and ¹¹ correlates with ¹³ in carbon-bearing gases. These correlations probably testify to the formation of different phases of mud-volcanic emanations in a single geochemical system and suggest the crucial role of temperature in the development of isotope-geochemical features.