<Superscript>40</Superscript>Ar-<Superscript>39</Superscript>Ar dating of lamprophyre dykes in the Baimazhai nickel deposit,Yunnan Province,China, and its geological significance

The Baimazhai nickel deposit, Yunnan Province, China, is located in the southern part of the Sanjiang （Tri-river） alkali-rich intrusive rock belt （Sanjiang ARIR）. In this paper was conducted ^40Ar-^39Ar dating of two phlogopites in lamprophyres which are, as dikes, widely distributed in the orefield, and two plateau ages were acquired, i.e., 32.46±0.62 Ma and 32.01±0.60 Ma, respectively （averaging 32.23±0.60 Ma）. The ages are obviously younger than those of the ore-hosted complex and mineralization of the Baimazhai nickel deposit. In combination with the characteristics, it is indicated that lamprophyres in the orefield and those in the Sanjiang ARIR are similar in tectonic setting, mineral assemblage and geochemistry. It is considered that lamprophyres in the orefield are the important component of the Sanjiang ARIR, and the lamprophyres and ore-hosted complex in the orefield represent the products of two times of different magmatic activity from different mantle sources. On the other hand, the age of lamprophyres in the orefield is older than that of the strike-slip shearing of the Ailaoshan-Honghe fault belt, suggesting that the strike-slip shearing of the Ailaoshan-Honghe fault belt is not the factor leading to magmatic activity of lamprophyres in the orefield, while it is more possible that magmatic activity of the Sanjiang ARIR promoted strike-slip shearing of the fault belt.     

New <Superscript>40</Superscript>Ar/<Superscript>39</Superscript>Ar age constraints on the Late Palaeozoic tectonic evolution of the western Tianshan (Xinjiang,northwestern China), with emphasis on Permian fluid ingress

Laser-probe dating of mylonite whole-rock samples from the North Tianshan—Main Tianshan fault zone that cross-cuts the North Tianshan domain’s southern margin yielded ⁴⁰Ar/³⁹Ar spectra with 255–285 Ma ages. Biotite from an undeformed, Early Carboniferous granite, which cuts the steep mylonitic foliation in the Proterozoic basement of the Yili arcs’s southern margin, gave a 263.4 ± 0.6 Ma plateau age (1σ). Pre-Carboniferous metasediments overlying this basement yielded plateau ages (1σ) of 253.3 ± 0.3 (muscovite) and 252.3 ± 0.3 (biotite) Ma. The Permian ages of mylonites date movement on these ductile, dextral strike-slip shear zones, whereas the mica ages are interpreted by recrystallisation as a result of fluid flow around such transcurrent faults. We propose that the Tianshan’s Permian syn-tectonic bimodal magmatism was created in a non-plume-related Yellowstone-like extensional–transtensional tectonic regime. Gold mineralisation, tracing aqueous flow in the crust, peaked in Permian time and continued locally into the Triassic. The picture is emerging that a convective fluid system partly driven by magmatic heat, existed in a strongly fractured and weakened crust with an elevated heat flow, leading to regional-scale isotope resetting. We suggest that surprisingly young isotopic ages in the literature for early orogenic (ultra)high-pressure metamorphism are similarly due to fluid-mediated recrystallisation.     

^3He／^4He Ratios and Heat Flow in the Continental Rift—valley,Eastern China

Heat flow and the origin of helium in natural gases from fault basins of the continental rift-valley in eastern China are discussed in terms of helium isotope geochemistry.³He/⁴He ratios in natural gases from the rift-valley range from 2.23 × 10⁻⁷ to 7.21 × 10⁻⁶, which are directly proportional to the concentration of helium and ΣNHC/ΣHC ratio in natural gases. Geological and isotope geochemical data suggest that helium in natural gases consists predominantly of crustal radio-genic and upper mantle-derived helium. In a simple mixing pattern between crustal He and mantle-derived He, mantle-derived helium in natural gases would account for 10–60%. Calculated values for heat flow (Q) range from 59.7 to 82.4mWm⁻², of which about 60 percent in the rift-valley is derived from the upper mantle. Natural helium reservoirs would be found in the areas where the upper mantle uplifted greatly and heat flow is large in the continental rift-valley. The project is financially supported by the National Natural Science Foundation of China.     

40^Ar／39^Ar Ages of Auriferous Quartz Veins from the Fengyang and Zhangbaling Regions and Their Geological Significance

Geotectonically the Fengyang and Zhangbaling regions belong to the North China craton and the Dabie-Sulu oragene, respectively. Neo-Archean gneiss and amphibolite and metamor-phosed sea-facies sodic volcanic rocks axe the main outcrops in the two regions, respectively. The Zhangbaling terrane strike-skipped along the Tancheng-Lujiang fault zone in Mesozoic and Cenozo-ic eras and got close to the Fengyang terrane. Mesozoic Yanshanian intrusions occur broadly in thetwo regions. Gold-beating quartz veins occur in the metamorphic rocks in the Fengyang region and in the granodiorite and metamorphosed sea-facies sodic volcanic rocks in the Zhanghaling region.Generally, the formation of the auriferous quartz veins involved three stages. At the first stage,gold-poor sulfide quartz veins were formed; at the second stage gold-rich quartz sulfide veins wereformed; and at the third stage gold-poor barite and/or carbonate veins were formed. The 40^Ar/29^Ar step-heating plateau ages of the first-stage and the second-stage quartz aggregates from the Zhuding, Maoshan and Shangeheng gold deposits range between 116.1 0.6 Ma and 118.3 0.5 Ma and are pretty close to their least apparent ages and isoehronal ages, respectively. All plat-eau, least apparent and isoehronal ages range between 113.4 0.4 Ma and 118.3 0.5 Ma,which are considered as the formation age range of the quartz. It is reasonable and reliable to takethe 40^Ar/39^Ar age range of the quartz as the formation age range of gold-bearing quartz veins onthe basis of spatial relationship between gold-bearing quartz veins and their country rocks. Thegold deposits in the two regions were formed in Aptian, Cretaceous, when the Tancheng-Lujiangfault zone moved as a normal fault with slightly right-lateral strike-skip, was extensional and expe-rienced very strong magnmtic process. It is shown that the magnmtic hydrothermal fluid is a veryimportant part of the gold ore-forming hydrothermal fluid in the Fengyang and Zhanghaling re-gions. The formation of the gold ore deposits in the Fengyang and Zhanghaling regions had genetic relations with the extensional movement of the Tancheng-Lujiang fault zone and magmatic activities and took place under the extensional dynamic condition in Late Cretaceous. Therefore, the exten-sional movement of the Tancheng-Lujiang fault zone presented the energy and space for magmatic and gold ore-forming processes.     

Mesozoic rift magmatism in the North Sea region: <Superscript>40</Superscript>Ar/<Superscript>39</Superscript>Ar geochronology of Scanian basalts and geochemical constraints

More than 100 volcanic necks composed of basanites and melanephelinites occur in Scania, southern Sweden, at the junction of two major tectonic lineaments, the Phanerozoic Sorgenfrei-Tornquist Zone (STZ) and the Proterozoic Protogine Zone. New ⁴⁰Ar/³⁹Ar isotope analyses of whole rock fragments of nine selected basalt necks suggest that the Mesozoic alkaline volcanism in the Scanian province commenced earlier than previously reported and comprised three separate volcanic episodes that span a total period of ca. 80 Myr: a first Jurassic (191–178 Ma), a second at the Jurassic/Cretaceous boundary (ca. 145 Ma), and a final middle Cretaceous episode (ca. 110 Ma). The new results allow for precise time correlations between eruption events in the Scanian and those in the North Sea volcanic provinces. The older, early Jurassic event in Scania is largely synchronous with that in the Egersund Basin and the Forties field whereas the event at ca. 145 Ma is correlated with activity in the Central Graben. These volcanic episodes also correlate in age with Kimmerian tectonic activity. Volcanic activity in the middle Cretaceous period has also been dated in the triple junction in the North Sea and offshore in the Netherland Sector. The correlation of basalt volcanism in Scania with the Egersund nephelinites strongly suggest that volcanism was triggered by repeated tectonic activity along the STZ. Geochemical data of alkaline mafic rocks in the Scanian and the North Sea volcanic provinces imply that different provinces have largely unique geochemical signatures in favour of a heterogeneous mantle in the North Sea volcanic region. However, basalts of different generations in one and the same province cannot be readily separated on the basis of geochemistry, suggesting that the same lithospheric mantle was the source of repeated volcanism over time in each province. The data suggest a low degree of melting of a volatile-bearing mantle lherzolite enriched in incompatible elements with the exception of the Forties basalts in the rift centre, produced by larger degree of melting and evolved by fractional crystallization.     

Geodynamic interpretation of the <Superscript>40</Superscript>Ar/<Superscript>39</Superscript>Ar dating of ophiolitic and arc-related mafics and metamafics of the northern part of the Anadyr-Koryak region

Isotope datings of amphibole-bearing mafics and metamafics in the northern part of the Anadyr-Koryak region allow clarification of the time of magmatic and metamorphic processes, which are synchronous with certain stages of the geodynamic development of the northwest segment of the Pacific mobile belt in the Phanerozoic. To define the ⁴⁰Ar/³⁹Ar age of amphiboles, eight samples of amphibole gabbroids and metamafics were selected during field work from five massifs representing ophiolites and mafic plutons of the island arc. Rocks from terranes of three foldbelts: 1) Pekulnei (Chukotka region), 2) Ust-Belaya (West Koryak region), and 3) the Tamvatnei and El’gevayam subterranes of the Mainits terrane (Koryak-Kamchatka region), were studied. The isotope investigations enabled us to divide the studied amphiboles into two groups varying in rock petrographic features. The first was represented by gabbroids of the Svetlorechensk massif of the Pekulnei Range and by ophiolites of the Tamvatnei Mts.; their magmatic amphiboles show the distribution of argon isotopes in the form of clearly distinguished plateau with an age ranging within 120–129 Ma. The second group includes metamorphic amphiboles of metagabbroids and apogabbro amphibolites of the Ust-Belaya Mts., Pekulnei and Kenkeren ranges (El’gevayam subterranes). Their age spectra show loss of argon and do not provide well defined plateaus the datings obtained for them are interpreted as minimum ages. Dates of amphiboles from the metagabbro of the upper tectonic plate of the Ust-Belaya allochthon points to metamorphism in the suprasubduction environment in the fragment of Late Neoproterozoic oceanic lithosphere in Middle-Late Devonian time, long before the Uda-Murgal island arc system was formed. The amphibolite metamorphism in the dunite-clinopyroxenite-metagabbro Pekulnei sequence was dated to occur at the Permian-Triassic boundary. The age of amphiboles from gabbrodiorites of the Kenkeren Range was dated to be Early Jurassic that confirmed their assignment to the El’gevayam volcanic-plutonic assemblage. These data are consistent with geological concepts and make more precise the available age dates. Neocomian-Aptian ⁴⁰Ar/³⁹Ar age of amphibolites from the Pekulnei and Tamvatnei gabbroids make evident that mafics of these terranes (varying in geodynamic formation settings and in petrogenesis) were generated in later stages of the development of the West Pekulnei and Mainits-Algan Middle-Late Jurassic-Early Cretaceous island arc systems, presumably due to breakup of island arcs in the Neocomian.     

Detailed <Superscript>40</Superscript>Ar/<Superscript>39</Superscript>Ar dating of geologic events associated with the Mantos Blancos copper deposit,northern Chile

The ⁴⁰Ar/³⁹Ar geochronological method was applied to date magmatic and hydrothermal alteration events in the Mantos Blancos mining district in the Coastal Cordillera of northern Chile, allowing the distinction of two separate mineralization events. The Late Jurassic Mantos Blancos orebody, hosted in Jurassic volcanic rocks, is a magmatic-hydrothermal breccia-style Cu deposit. Two superimposed mineralization events have been recently proposed. The first event is accompanied by a phyllic hydrothermal alteration affecting a rhyolitic dome. The second mineralization event is related to the intrusion of bimodal stocks and sills inside the deposit. Because of the superposition of several magmatic and hydrothermal events, the obtained ⁴⁰Ar/³⁹Ar age data are complex; however, with a careful interpretation of the age spectra, it is possible to detect complex histories of successive emplacement, alteration, mineralization, and thermal resetting. The extrusion of Jurassic basic to intermediate volcanic rocks of the La Negra Formation is dated at 156.3 ± 1.4 Ma (2σ) using plagioclase from an andesitic lava flow. The first mineralization event and associated phyllic alteration affecting the rhyolitic dome occurred around 155–156 Ma. A younger bimodal intrusive event, supposed to be equivalent to the bimodal stock and sill system inside the deposit, is probably responsible for the second mineralization event dated at ca. 142 Ma. Other low-temperature alteration events have been dated on sericitized plagioclase at ca. 145–146, 125, and 101 Ma. This is the first time that two distinct mineralization events have been documented from radiometric data for a copper deposit in the metallogenic belt of the Coastal Cordillera of northern Chile. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Stable isotope analyses (δ<Superscript>15</Superscript>N and δ<Superscript>13</Superscript>C) of the trophic relationships of<Emphasis Type="Italic">Callinectes sapidus</Emphasis> in two North Carolina estuaries

The present study focused on detecting variations in trophic relationships among blue crab (Callinectes sapidus) consumers according to water quality along two estuaries in North Carolina. Stable isotope (δ¹⁵N and δ¹³C) analyses of particulate organic matter and bivalve(Rangia cuneata andCorbicula fluminea) food sources were examined in combination with an Isosource mixing model. Results suggest that blue crab δ¹³C values increased significantly with increasing salinity from upper to lower sites along the Neuse River estuary (NRE; R2 = 0.87, p < 0.01) and Alligator River estuary (R² = 0.92, p < 0.01). There was a positive relationship between blue crab δ¹⁵N values and nitrate concentrations for the NRE (R² = 0.48, p = 0.12). This study found that blue crab δ¹³C values increased with salinity from upper to lower regions along both estuaries. Results suggest that blue crab production may have used alternative food sources that were isotopically (δ¹³C) depleted, especially in the upper NRE, and enriched sources in the mid to lower regions of both estuaries. Consumers sampled from the upper NRE may be influenced by higher nitrogen input from urban land use and municipal wastewater.     

Mechanisms of oxygen isotopic exchange and isotopic evolution of <Superscript>18</Superscript>O/<Superscript>16</Superscript>O-depleted periclase zone marbles in the Alta aureole,Utah: insights from ion microprobe analysis of calcite

Oxygen isotope ratios have been measured by ion microprobe and millimeter-scale dental drill along detailed sampling traverses across the boundary between periclase-bearing (δ¹⁸O = 11.8‰) and periclase-free (δ¹⁸O = 17.2‰) marble layers in the periclase (Per) zone of the Alta Stock aureole, Utah. These data define a steep, coherent gradient in δ¹⁸O that is displaced a short distance (~4 cm) into the periclase-free (Cal + Fo) layer. SEM and ion microprobe analyses show two isotopically and texturally distinct types of calcite at the grain scale. Clear (well polished) calcite grains are isotopically homogeneous (within analytical uncertainty; ±0.27‰, 2SD). More poorly polished (pitted), texturally retrograde ‘turbid’-looking calcite has lower and more variable δ¹⁸O values, and replaces clear calcite along fractures, cleavage traces or grain boundaries. Despite significant lowering of the δ¹⁸O values in calcite throughout both layers during prograde metamorphism, ion microprobe analyses indicate that individual clear calcite grains are now isotopically homogeneous across the entire gradient in δ¹⁸O. Diffusion calculations indicate that conservative time scales required for isotopic homogenization of calcite grains by volume diffusion, 30,000–62,000 years at 575–600°C, exceed significantly the timescale (~1,250 years) estimated for the prograde development of the δ¹⁸O gradient at the boundary between these two marble layers. The ion microprobe data and these diffusion calculations suggest instead that surface reaction mechanisms accompanying recrystallization are responsible for the observed oxygen isotope homogeneity of these calcite grains. Thus, the ion microprobe data are consistent with the formation of calcite in oxygen isotope exchange equilibrium with infiltrating fluid during prograde reaction and recrystallization. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Tracing sources of carbon in urban groundwater using δ<Superscript>13</Superscript>C<Subscript>TDIC</Subscript> ratios

Total dissolved inorganic carbon (TDIC) and its stable isotope ratio δ¹³C_TDIC are used to trace the evolution of the carbon system of groundwater in three UK Permo-Triassic sandstone aquifers. Samples were collected from multilevel piezometers, open boreholes and sewer sampling points in the British Midlands (Nottingham, Birmingham and Doncaster) to evaluate both local and regional variations in δ¹³C_TDIC. δ¹³C samples of matrix and pore water have also been analysed in each aquifer to further constrain the interpretations. Combining δ¹³C_TDIC ratios with measurements of TDIC and pH clearly distinguishes the principal processes underlying the geochemical evolution of groundwater in Triassic sandstone aquifers, where processes can be both natural (e.g. carbonate dissolution) and anthropogenic (sewer-derived recharge). The paper shows that δ¹³C_TDIC resolves ambiguities that arise from the interpretation of TDIC and pH measurements in isolation. Field measurements demonstrate that, under natural conditions, the carbonate system evolves similarly in each aquifer. An open-system evolution during recharge largely saturates the groundwater with carbonate depending upon its availability in the sandstone matrix. The contribution of sewer exfiltration to urban recharge is readily distinguished by lower pH and higher TDIC values without significant changes in δ¹³C_TDIC.     

Triassic <Superscript>40</Superscript>Ar/<Superscript>39</Superscript>Ar ages from the Sakaigawa unit,Kii Peninsula,Japan: implications for possible merger of the Central Asian Orogenic Belt with large-scale tectonic systems of the East Asian margin

The 218.4 ± 0.4, 228.8 ± 0.9 and 231.9 ± 0.7 Ma ⁴⁰Ar/³⁹Ar laser probe pseudo-plateau ages (2σ; 49–63% ³⁹Ar-release) of very low-grade meta-pelitic whole-rocks from the Sakaigawa unit date high-P/T metamorphism. We argue that this event occurred in a subduction–accretion complex, not along the East Asian continental margin, but on the Pacific side of the proto-Japan superterrane. Proto-Japan was a Permian magmatic arc, presently dispersed in the Japanese islands, which also contained older subduction–accretion complexes. The arc system was fringing but not yet part of the Eurasian continent. The Middle to Late Triassic high-P/T tectono-metamorphic event was partly coeval with proto-Japan’s collision with proto-Eurasia along the southward extension of the Central Asian Orogenic Belt, causing the main metamorphism in the Hida-Oki terrane. It is possible that this system continued via the Cathaysia block (China) to Indochina. The Late Permian to Middle Triassic Indosinian event might stem from docking of Pacific-derived terranes with Southeast Asia’s continental margin. The concept of the proto-Japan superterrane implies that the Qinling-Dabie-Sulu suture zone joined the Central Asian Orogenic Belt to the east of the North China craton and did not continue to Japan, as commonly assumed.     

Raman spectroscopic study of hydrous <Emphasis Type="Italic">γ</Emphasis>-Mg<Subscript>2</Subscript>SiO<Subscript>4</Subscript> to 56.5 GPa

 Raman spectra of a single-crystal fragment of hydrous γ-Mg₂SiO₄, synthesized in a multianvil press, have been measured in a diamond-anvil cell with helium as pressure-transmitting medium to 56.5 GPa at room temperature. All five characteristic spinel Raman modes shift continuously up to the highest pressure, showing no evidence for a major change in the crystal structure despite compression well beyond the stability field of ringwoodite in terms of pressure. At pressures above ∼30 GPa a new mode on the low-frequency site of the two silicate-stretching modes is clearly identifiable, indicating a modification in the spinel structure which is reversible on pressure release. The frequency of the new mode (802 cm⁻¹ extrapolated to 1 bar) suggests the presence of Si–O–Si linkages and/or a partial increase in the coordination of Si. Direct determination of the subtle structural change causing the new Raman mode would require high-pressure, single-crystal synchrotron X-ray diffraction experiments. The Raman modes of hydrous and anhydrous Mg-end-member ringwoodite are nearly identical up to 20 GPa, suggesting that protonation has only minor effect on the lattice dynamics over the entire pressure stability range for ringwoodite in the mantle. Received: 7 December 2001 / Accepted: 16 April 2002     

Metallogenic features of Miocene porphyry Cu and porphyry-related mineral deposits in Ecuador revealed by Re-Os, <Superscript>40</Superscript>Ar/<Superscript>39</Superscript>Ar,and U-Pb geochronology

Mineralization and alteration events at ten Miocene porphyry Cu and porphyry-related epithermal mineral deposits in southern, central, and northern Ecuador were dated by means of molybdenite Re-Os, biotite and alunite ⁴⁰Ar/³⁹Ar, and titanite U-Pb geochronology. Most of these hydrothermal events show a spatio-temporal correlation with porphyry intrusion emplacement as constrained by zircon U-Pb ages. The total age range for these events spans the 23.5–6.1 Ma period, without displaying systematic along- or across-arc age distribution trends. While epithermal deposits tend to be spatially associated with volcanic rocks of a similar age, porphyry Cu deposits in Ecuador are frequently spatially associated with deeper-seated basement units and batholith-scale precursor intrusive systems assembled over ≥5 m.y. time periods. In most cases, formation of the porphyry Cu deposits is related to the youngest magmatic (-hydrothermal) event in a given area, postdating batholith construction at a regional scale. The majority of Miocene deposits occurs in southern Ecuador where areally extensive, post-mineralization (late Miocene to recent) volcanic sequences with the potential to conceal mineralization at depth are lacking. Only few Miocene deposits occur in northern-central Ecuador, where they mainly crop out in the Western Cordillera, west of the productive present-day volcanic arc. The surface distribution of post-mineralization arc volcanism reflects along-arc variations in subducting slab geometry. Porphyry Cu and epithermal deposits in Ecuador define a Miocene metallogenic belt broadly continuous with its coeval counterpart in northern-central Peru. Although both belt segments were formed in an overall similar tectonomagmatic and metallogenic setting, their respective metal endowments differ significantly.     

Hg<Superscript>0</Superscript>(liq)-Hg<Superscript>0</Superscript>(solution) equilibrium and solubility of elementary mercury in water

The solubility metallic mercury in water and its dominating forms were studied. The prevalence of the Hg_aq⁰ form in the high-temperature range was confirmed and the reaction constant Hg_liq⁰ ai Hg_aq⁰ (logK = logm = −8.01) at 25°C with the predominance of oxidized forms of mercury for the 20–80°C area of low temperatures was found.     

<Superscript>226</Superscript>Ra, <Superscript>232</Superscript>Th and <Superscript>40</Superscript>K activities in soils of Cuihua Mountain National Geological Park,China

Gamma activity from the naturally occurring radionuclides namely, ²²⁶Ra, ²³²Th, the primordial radionuclide ⁴⁰K was measured in the soil of Cuihua Mountain National Geological Park, China using γ-ray spectrometry technique. The mean activity of ²²⁶Ra, ²³²Th and ⁴⁰K were found to be 27.2 ± 6.5, 43.9 ± 6.2 and 653.1 ± 127.6 Bq kg⁻¹, respectively. The concentrations of these radionuclides were compared with the typical world values and the average activities of Chinese soil. The radium equivalent activity, the air absorbed dose rate, the annual effective dose rate, and the external hazard index were evaluated and compared with the internationally approved values. All the soil samples have Ra_eq lower than the limit of 370 Bq kg⁻¹ and H _ex less than unity. The overall mean outdoor terrestrial gamma dose rate is 66.3 nGy h⁻¹ and the corresponding outdoor annual effective dose is 0.081 mSv.     

First <Superscript>40</Superscript>Ar/<Superscript>39</Superscript>Ar age determinations on the Malkhan granite-pegmatite system: Geodynamic implications

The Malkhan granite-pegmatite system located in Central Transbaikalia, in the southwestern portion of the Malkhan-Yablonovy structure-formational zone of the Caledonian folding comprises two granite massifs (Bolsherechensk and Oreshny) and a miarolitic pegmatite field of the same name, which adjoins the Chikoi deep-seated fault and Lower Cretaceous Chikoi rift depression in the north. The first ⁴⁰Ar/³⁹Ar data were obtained on porphyritic biotite granites of the Oreshny massif and on K-feldspar, muscovite, and lepidolite from the Oktyabrskaya pegmatite vein. According to these data, the age of the granitepegmatite system is 123.8–127.6 Ma, which is consistent with the age of Lower Cretaceous rocks from the Chikoi depression. The intimate spatial relationship and isochronism between the Chikoi depression and the Malkhan granite-pegmatite system are strongly suggestive of a rift regime that affected its evolution, thus highlighting the need to regard the evolution of this system as being intimately related to depression development. Such a model can easily be realized within the framework of the concept of a metamorphic core complex, which was used to explain the nature of Transbaikal-type rift depressions and conjugate granite-gneiss swells.     

Pre-Cenozoic intra-plate magmatism along the Central Andes (17–34°S): Composition of the mantle at an active margin

Sr–Nd–Pb isotope ratios of alkaline mafic intra-plate magmatism constrain the isotopic compositions of the lithospheric mantle along what is now the eastern foreland or back arc of the Cenozoic Central Andes (17–34°S). Most small-volume basanite volcanic rocks and alkaline intrusive rocks of Cretaceous (and rare Miocene) age were derived from a depleted lithospheric mantle source with rather uniform initial ¹⁴³Nd/¹⁴⁴Nd ( 0.5127–0.5128) and ⁸⁷Sr/⁸⁶Sr ( 0.7032–0.7040). The initial ²⁰⁶Pb/²⁰⁴Pb ratios are variable (18.5–19.7) at uniform ²⁰⁷Pb/²⁰⁴Pb ratios (15.60 ± 0.05). A variety of the Cretaceous depleted mantle source of the magmatic rocks shows elevated Sr isotope ratios up to 0.707 at constant high Nd isotope ratios. The variable Sr and Pb isotope ratios are probably due to radiogenic growth in a metasomatized lithospheric mantle, which represents the former sub-arc mantle beneath the early Palaeozoic active continental margin. Sr–Nd–Pb isotope signatures of a second mantle type reflected in the composition of Cretaceous (one late Palaeozoic age) intra-plate magmatic rocks (¹⁴³Nd/¹⁴⁴Nd  0.5123, ⁸⁷Sr/⁸⁶Sr  0.704, ²⁰⁶Pb/²⁰⁴Pb  17.5–18.5, and ²⁰⁷Pb/²⁰⁴Pb  15.45–15.50) are similar to the isotopic composition of old sub-continental lithospheric mantle of the Brazilian Shield.

Published Nd and Sr isotopic compositions of Mesozoic to Cenozoic arc-related magmatic rocks (18–40°S) represent the composition of the convective sub-arc mantle in the Central Andes and are similar to those of the Cretaceous (and rare Miocene) intra-plate magmatic rocks. The dominant convective and lithospheric mantle type beneath this old continental margin is depleted mantle, which is compositionally different from average MORB-type depleted mantle. The old sub-continental lithospheric mantle did not contribute to Mesozoic to Cenozoic arc magmatism.     

中国西南地区CO2释放点的He同位素分布不均一性及大地构造成因

在印度板块向欧亚大陆俯冲碰撞过程中,产生一系列深大断裂带,形成大量CO2释放脱气点。这些点除了释放大量的CO2、N2、H2S气体以外,还会附带释放CH4、He等各种各样的气体。释放出来的氦为惰性元素,是判识幔源气体最灵敏的地球化学示踪指标,He同位素随形成的构造部位不同而不均匀地分布,且与不同的大地构造成因关系密切。藏中及藏北区块在大地构造位置上属于班公湖-怒江断裂带发生了明显的地幔脱气作用,显示其与地幔相连通而且深度达到上地幔,为一条岩石圈深断裂带;但样品中幔源氦约占总氦的1.4%~1.7%,反映该断裂带深部的开放性程度较低,而闭合性程度相对较高,由此反映了该区处于强烈挤压的构造环境和地壳增厚的地质背景。在滇西南地区(重点在腾冲热海地区)地热流体逸出气体中含有大量幔源岩浆挥发组份,表明该区地壳浅部存在幔源岩浆侵入活动。该区怒江断裂带发生着明显的地幔脱气作用,显示该断裂带与地幔相连通且深度达到上地幔,为一条岩石圈深断裂带;同时所有样品中的幔源氦平均约占总氦的26.2%,最高可达48.8%以上。反映该裂谷带代表伸展性构造环境,且是地幔脱气作用最强烈的构造区之一,是俯冲碰撞的中心地带。而在滇中地区—小江断裂带却是另一番景象,该区样品中的幔源氦平均约占总氦的2.27%,最高也才8.9%。反映此区为印度板块向欧亚大陆以NNE方向碰撞影响到的最东缘。小江断裂带局限在地壳范围内,故而氦同位素显示出在此断裂带以西则明显存在幔源来源,而往东则幔源氦极微。氦同位素在自西至东由藏西到藏南(藏南西与藏南东)至滇西到滇中,R/Ra值由较低到较高再到较低到最高再降低的平面分布规律。川西—鲜水河断裂带则因特殊的构造部位,是中国“地质百慕大”;样品中幔源氦平均约占总氦的8.1%,平均值高于西藏各分区以及云南除滇西南以外的各区,但又远远小于滇西南—腾冲地区。说明鲜水河断裂带,部分地贯穿整个岩石圈,并有切割上地幔之趋势。     

Results of <Superscript>40</Superscript>Ar/<Superscript>39</Superscript>Ar dating of phlogopites from kelyphitic rims around garnet grains (Udachnaya-Vostochnaya kimberlite pipe)

⁴⁰Ar/³⁹Ar dating of phlogopite from kelyphitic rims around garnet grains from the Udachnaya–Vostochnaya kimberlite pipe in the Sakha (Yakutia) Republic (Russia) revealed that when this mineral has contact with a kimberlite melt its age corresponds (within error limits) to that of the formation of the kimberlite pipe, thus indicating that the method may be used for dating kimberlites and related rocks. In mantle xenoliths, kelyphitic phlogopites rimming garnet grains partially lose radiogenic Ar, which results in a complex age spectrum. Rejuvenation of the K/Ar system in them is determined by the thermal impact of the kimberlite melt on captured rocks.