Archaean greenstone belt from the Central African Republic (Equatorial Africa)

The Bandas belt, one of two prominent Archaean greenstone belts in the Central African Republic (Equatorial Africa), is ca. 250 km long. At the southernmost part of the belt, a metasedimentary—metavolcanic rock suite is preserved only in brachysynclines. The suite can be divided into two lithostratigraphic units. The lower unit is composed predominantly of volcanic rocks, while the upper one contains mainly metasedimentary rocks. The volcanic rocks, which are part of a sequence ca. 3600 m thick, can be sub-divided according to stratigraphic position, lithology and geochemistry into three groups. The lowermost group includes low-K tholeiitic basalts depleted in light REE. The second group consists of tholeiitic basalts with light REE-enriched patterns and the third, uppermost, group includes andesites, which are similar in several respects to Recent calc-alkaline andesites.The tholeiitic basalts of the first two groups are probably related to different upper mantle sources. The andesites of the third group were produced either by fractional crystallization from a basaltic magma enriched in light REE or equilibrium melting of eclogite or garnet amphibolite.     

Geochemistry of Archean Metavolcanic Rocks from Kadiri Schist Belt, Andhra Pradesh, India

The basic volcanic group exposed in the Kadiri schist belt includes high Mg-basalt, basalt, basaltic andestite and dacite. The basalts are tholeiitic in composition and high Mg-basalts, basaltic andesites and dacites show calc-alkaline affinity. Major and trace element characteristics suggest that the volcanic suite has been derived from an initial tholeiitic magma which has given rise to an early basaltic type and a later calc-alkaline type of rocks. An island arc and active continental margin tectonic setting was inferred for these rocks.     

An Ordovician intra-oceanic subduction system influenced by ridge subduction in the West Junggar,Northwest China

We report elemental and Nd–Sr isotopic data for three types of Ordovician volcanic and gabbroic rocks from the Sharburti Mountains in the West Junggar (Xinjiang), Northwest China. Gabbros and Type I lavas occur in the Early Ordovician Hongguleleng ophiolite whereas Type II and III lavas are parts of the Middle Ordovician Bulukeqi Group. Gabbros and Type I lavas are tholeiites with a depleted light rare earth element (LREE) and mid-oceanic ridge basalt (MORB)-like signature with a crystallization sequence of plagioclase–clinopyroxene, suggesting formation at a mid-oceanic ridge. Type II lavas are Nb-enriched basalts (NEBs, Nb = 14–15 ppm), which have E-MORB-like REE patterns and Nb/Yb and Th/Yb ratios. They come from mantle metasomatized by slab melts. Type III lavas are further divided into two sub-types: (1) Type IIIa is tholeiitic to calc-alkaline basalts and andesites, with REE patterns that are flat or slightly LREE enriched, and with a negative Nb anomaly and Th/Yb enrichment, indicating that they were generated above a subduction zone; (2) Type IIIb is calc-alkaline basalts and andesites, which are strongly enriched in LREE with a marked negative Nb anomaly and Th/Yb enrichment, suggesting generation in a normal island-arc setting. The initial ⁸⁷Sr/⁸⁶Sr ratios of Type III lavas range from 0.70443 to 0.70532 and ?Ndt ranges from +1.5 to +4.5, suggesting that these melts were derived from mantle wedge significantly modified by subducted material (enriched mantle I (EMI)) above a subduction zone. Contemporary tholeiitic to calc-alkaline basalt–andesite and NEB association suggest that the NEBs erupted during development of the tholeiitic to calc-alkaline arc. We propose a model of intra-oceanic subduction influenced by ridge subduction for the Ordovician tectono-magmatic evolution of the northern West Junggar.     

东昆仑巴颜喀拉浊积盆地二叠纪火山岩

东昆仑巴颜喀拉浊积盆地内沿扎拉依-哥琼尼洼断裂带及约古宗列断裂带的断夹块内出露有一套二叠纪马尔争组火山岩, 火山岩呈构造岩片形式产出, 扎拉依-哥琼尼洼断裂带火山岩岩石组合主要为玄武岩、玄武安山岩, 少量玄武岩具枕状构造, 岩石SiO₂含量均匀, TiO₂的含量较高, ALK的含量较低, 为拉斑系列的玄武岩, 玄武岩稀土总量较高, 稀土配分曲线为轻稀土富集型, 与洋岛型火山岩的稀土配分曲线相一致, 火山岩大离子亲石元素较富集, 高场强元素及重稀土元素较平坦, 稀土、微量元素特征及构造环境判别显示其形成于较富集的洋岛环境, 少数为洋中脊的构造环境.约古宗列断裂带火山岩岩石组合为玄武岩、玄武安山岩, 岩石SiO₂含量较高, TiO₂含量较低, 均 < 1%, 为钙碱性系列火山岩, 玄武安山岩的稀土配分曲线与扎拉依-哥琼尼洼断裂带一致, 而英安岩的轻稀土富集程度高, 与岛弧高钾安山岩的稀土配分曲线相吻合, 构造环境判别显示其形成于岛弧构造环境.根据扎拉依-哥琼尼洼断裂带两侧火山岩成分的差异以及断裂带两侧巴颜喀拉群碎屑物成分的差异, 可以把巴颜喀拉山三叠纪浊积盆地进一步划分为北亚带和南亚带.      

Rare-earth elements in high-alumina basaltic rocks from Sardinia

High-alumina basalts and basic andesites, which represent the most “primitive” magma types of the Cenozoic andesitic series of Sardinia, show a spatial chemical zonation with respect to REE. The basaltic rocks from the northern and south-central part of the island have REE patterns typical of calc-alkaline rocks with an enrichment of light REE and fractionation of heavy REE. In contrast, those from the southernmost part have a pattern similar to typical continental tholeiites with only a small light-REE enrichment and unfractionated heavy REE.The present data suggest that basaltic rocks may be formed by anatexis of upper-mantle material with mineral assemblages containing either garnet (calc-alkaline rocks) or spinel (rocks of tholeiitic affinities). The presence of garnet or spinel could merely reflect mineral phase transformation and indicates a different depth of fusion for the various types of basaltic rocks with those of tholeiitic affinities originating at a shallower depth than the calcalkaline rocks. The REE data are consistent with the generation of the basaltic rocks by partial melting of mantle peridotite overlying a subducted plate.     

内蒙古锡林浩特岩群岩相学、地球化学特征及构造环境分析

锡林浩特岩群是内蒙古中东部锡林郭勒微地块内原锡林郭勒杂岩的重要组成部分,由一套片麻岩夹层状斜长角闪岩、磁铁石英岩和变粒岩等变质岩组成,形成于中元古代［1］。岩群中片麻岩样品显示轻稀土元素富集的中等分异特征((La/Yb)N=4.71~7.97),斜长角闪岩具有平坦型((La/Yb)N=0.74~0.95)和轻稀土元素微弱富集型((La/Yb)N=1.06~3.63)两种稀土元素配分模式。在微量元素N MORB标准化图解中,斜长角闪岩显示出洋中脊玄武岩和岛弧玄武岩的过渡类型特征。同时结合岩相学和岩石地球化学图解分析,推断片麻岩原岩为富含泥质的亚杂砂岩,而斜长角闪岩原岩为一套具有拉斑质到钙碱性过渡型特征的玄武岩;变质沉积岩形成于活动大陆边缘大陆岛弧环境;变质基性火山岩形成于岛弧弧后盆地。二者指示锡林浩特岩群形成于活动大陆边缘体系。     

Chemostratigraphy of lava sequences from the Rio Itapicuru Greenstone Belt,Bahia State,Brazil

The Rio Itapicuru greenstone terrain of north-central Bahia State consists of belts of supracrustal rocks surrounding granitic plutons and domes. The basal supracrustal rocks are predominantly massive metabasalts with minor amounts of intercalated chemical sedimentary rocks and mafic tuffs. They are overlain by a middle unit of intermediate to acid pyroclastic rocks, lavas, and volcaniclastic sediments, and an upper unit of greywackes, sandstones and conglomerates.A geochemical study of major and trace elements of the volcanic rocks indicates the existence of a chemical discontinuity between the basaltic and the acid to intermediate members. The basalts are typical tholeiites with Ti, Zr, Sr, Y and Nb contents analogous to those of modern ocean-floor tholeiites or, alternatively, low-K tholeiites of primitive island arcs. In contrast, compositional variations of the hornblende-bearing andesites and dacites fall along indisputably calc-alkaline trends of low FeO and TiO₂ contents which decrease with increasing differentiation. The lithostratigraphic and chemical variations within lavas of the Rio Itapicuru greenstone are comparable to those described from the Western Australian greenstone belts. Only in greenstone belts of the Canadian type do thick calc-alkaline sequences containing abudant basaltic andesites overlie conformably and transitionally the underlying tholeiitic basalts. Elsewhere the calc-alkaline sequences, if present, do not contain basaltic andesites and are chemically unrelated to the underlying basalts.     

Study on the geochemical characteristics of arc-volcanic rocks in the Chiang Rai-Lampang belt of northern Thailand

On the basis of the petrographic characteristics, rock assemblages, petrochemistry, REEs, trace elements and geotectonic settings, the authors described the characteristics of continental marginal arc-volcanic rocks in the Late Permian-Early Triassic (P2-T1) volcanic rocks distributed on the eastern side of the ocean-ridge/oceanic island basalts in the Chiang Mai belt. The volcanic rock assemblage is basaltic andesite-andesite-rhyolite. The volcanic series is dominated by the calc-alkaline series, with the tholeitic series coming next. The chemical composition of the volcanic rocks is characterized by high Al2O3; the REE distribution patterns are of the LREE-enrichment rightward incline type; the large cation elements are highly enriched, and the volcanic rocks are generally enriched in U and Th and depleted in Ti, Cr and P. The petrochemical plot falls within the field of island-arc volcanic rocks, in consistency with the projected points of continental marginal arc-volcanic rocks in the Lancangjiang belt. These continental mar-ginal arc-volcanic rocks, together with ocean-ridge/oceanic island-type volcanic rocks in the Chiang Mai belt, con-stitute the ocean-ridge volcanic rock-arc magmatic rock belts distributed in pairs, indicative of eastward subduction of the oceanic crust in the Chiang Mai belt. This result is of great importance in exploring the evolution of the pa-leo-Tethys in the Chiang Mai belt.     

A review of new interpretations of the tectonostratigraphy,geochemistry and evolution of the Onverwacht Suite,Barberton Greenstone Belt,South Africa

The Paleoarchean (ca. 3.5–3.3 Ga) Onverwacht Suite (OS) of the Barberton Greenstone Belt consists of a 15‐km thick imbricate tectonic stack of seven complexes consisting predominantly of volcanic rocks and intrusions. Tectonostratigraphically from base to top they are the Sandspruit, Theespruit, Komati, Hooggenoeg, Noisy, Kromberg and Mendon Complexes. The Hooggenoeg and Noisy Complexes in the middle of the OS are separated by a significant unconformity resulting from the uplift of the submarine lavas and deep erosion, demonstrating the onset of tectonic accretion prior to 3455 Ma. The basic lavas of the tectonostratigraphic lower (Theespruit, Sandspruit and Komati) and upper (Mendon) complexes are composed of komatiite, komatiitic basalt and high-MgO basalt, whereas those in the middle part (Hooggenoeg and Kromberg) are predominantly high- to low-MgO tholeiitic basalts. Felsic volcanic rocks and intrusions are important in two of the complexes (Theespruit and Noisy). The ultramafic to basaltic lavas show REE patterns that are almost flat and resemble those of modern MORB, whereas those of the felsic rocks are flat from Lu to Gd and moderately to strongly enriched in LREE, similar to modern arcs. Average ε_{Nd (T)} values are close to depleted mantle growth curves. In MORB-normalised multi-element diagrams, the komatiitic to basaltic rocks exhibit flat patterns from Lu through La and consistent relative enrichment in the elements Pb, U, Th, Ba and Cs. Apart from the Komati Complex, the majority of the lavas show significant negative Nb and Ta anomalies. Enrichment in non-conservative incompatible elements (Cs, Ba, Th, LREE) relative to conservative elements (Ta, Nb, Zr, Hf, Ti, Y, HREE) shows that the komatiitic to basaltic magmas were generated from metasomatised mantle above subducting altered oceanic crust. The geochemistry of the felsic rocks indicates an origin by melting of subducted amphibolite and eclogite. The tectonostratigraphy and the geochemical characteristics of the lavas and intrusions are consistent with successive obduction and accretion of segments of oceanic crust formed in back-arc basins and volcanic arcs.     

Geochemical constraints on the genesis of the volcanic rocks in the southeast of Isfahan area, Iran

Late Miocene–Pliocene to Quaternary calc-alkaline lava flows and domes are exposed in southeast of Isfahan in the Urumieh Dokhtar magmatic belt in the Central Iran structural zone. These volcanic rocks have compositions ranging from basaltic andesites, andesites to dacites. Geochemical studies show these rocks are a medium to high K calc-alkaline suite and meta-aluminous. Major element variations are typical for calc-alkaline rocks. The volcanic rocks have SiO₂ contents ranging between 53.8% and 65.3%. Harker diagrams clearly show that the dacitic rocks did not form from the basaltic andesites by normal differentiation processes. They show large ion lithophile elements- and light rare earth elements (LREE)-enriched normalized multielement patterns and negative Nb, Ti, Ta, and P. Condrite-normalized REE patterns display a steep decrease from LREE to light rare earth elements without any Eu anomaly. These characteristics are consistent with ratios obtained from subduction-related volcanic rocks and in collision setting. The melting of a heterogeneous source is possible mechanism for their magma genesis, which was enriched in incompatible elements situated at the upper continental lithospheric mantle or lower crust. The geochemical characteristics of these volcanic rocks suggested that these volcanic rocks evolved by contamination of a parental magma derived from metasomatized upper lithospheric mantle and crustal melts.     

Middle Paleozoic basic magmatism of the northwestern Vilyui Rift: Composition, sources, and geodynamics

Middle Paleozoic magmatism at the eastern Siberian platform was related to riftogenic processes, which were most clearly expressed in the Vilyui Rift and led to the formation of rift depressions filled with sedimentary-volcanogenic rocks and extended basaltic dike belts in rift shoulders. Two fields of diamondiferous kimberlites were found along with basaltic dikes in the Vilyui-Markha dike belt surrounding rift in the northwest. Active subalkali basaltic magmatism predated the emplacement of kimberlite bodies, which occasionally (Nyurba pipe) are cut by dikes of potassium alkali basalts. Based on geochemical and Sr-Nd isotopic characteristics, deep-seated sources were determined for the intrusive and volcanic basalts of the northwestern shoulder of the Vilyui rift. The REE distribution patterns of the studied rocks normalized to the primitive mantle are close to that of OIB, except for somewhat higher HREE. In the diagrams of indicator ratios of trace and rare-earth elements, the basalts are also plotted in the OIB field, being located between the end member of plume composition (FOZO) and enriched mantle sources. The rocks have positive ε_Sr (+3.5 and +28.6) and ε_Nd (+1.3 and +5.3). In a diagram ε_Nd(T)-ε_Sr(T), two fields with distinct content of radiogenic Sr are distinguished, which can be regarded as derived by mixing of the moderately depleted PREMA-type mantle and a source enriched in radiogenic Sr. Available isotope-geochemical data confirm that OIB type basalts of the region were generated by plume activity. The geodynamic setting of Middle Paleozoic magmatism and rifting in the eastern part of the Siberian platform is considered in light of plume-lithosphere interaction. The sequence of tectonomagmatic events during evolution of the Vilyui rift is consistent with the model of plume-lithosphere interaction or the model of active rifting.     

新疆甜水海地块种羊场石炭纪火山岩年代学和地球化学:岩石成因和地质意义

甜水海地块西段的种羊场地区发育一套互层状产出的玄武岩-玄武安山岩-流纹岩,本文对其进行了岩石学、同位素年代学和地球化学研究。结果表明,流纹岩LA-ICP-MS锆石U-Pb定年获得三组年龄:343.5±4.1Ma表明火山岩的形成时代为早石炭纪,2439±26Ma和1988±36Ma说明甜水海地块存在前寒武纪结晶基底。其中玄武质岩石岩性从拉斑系列、钙碱性系列向碱性系列过渡,呈现出E-MORB(OIB)、大陆板内拉张和岛弧的混合特征,与典型弧后盆地Okinawa玄武岩有一定的差异,表明其可能是异常陆缘弧后盆地拉张裂解的产物。玄武质岩石和流纹岩的主量元素、稀土元素和微量元素比值对的差异表明它们不是同源岩浆演化的产物,玄武质岩石的源区为类似E-MORB(OIB)的岩石圈地幔,且发生了部分熔融,原始岩浆上升过程中经历了矿物分离结晶和地壳混染作用。流纹岩属于高硅高碱的钙碱性火山岩,是上地壳部分熔融的产物。种羊场早石炭纪火山岩可能代表了古特提洋西端早期扩张的记录,为西昆仑-喀喇昆仑地区晚古生代多岛洋格局提供了新的证据。     

内蒙古新巴尔虎右旗地区塔木兰沟组火山岩地球化学特征及其构造意义

新巴尔虎右旗地区塔木兰沟组火山岩为玄武岩-玄武粗安岩-玄武安山岩组合。该套火山岩属高硅钙碱性系列,偏铝质,镁指数小;富集大离子亲石元素(Rb、Ba、Sr)和轻稀土元素(LREE),亏损重稀土元素和高场强元素(Nb、Ta、Ti等),稀土元素配分模式呈左高右低缓倾斜分布,轻重稀土分馏较强,弱的Eu负异常(δEu=0.73~0.83)。综合前人及笔者同位素测年结果显示,塔木兰沟组火山岩形成于中侏罗世末期—晚侏罗世,成岩年龄为166~133 Ma。塔木兰沟组火山岩岩浆来源于受俯冲流体交代的大陆岩石圈地幔熔融,与地壳物质发生混染作用。结合区域构造演化,塔木兰沟组火山岩的形成与蒙古-鄂霍茨克洋闭合造山后岩石圈伸展有关。     

Major,trace and platinum group element (PGE) geochemistry of Archean Iron Ore Group and Proterozoic Malangtoli metavolcanic rocks of Singhbhum Craton,Eastern India: Inferences on mantle melting and sulphur saturation history

The geological and metallogenic history of the Singhbhum Craton of eastern India is marked by several episodes of volcanism, plutonism, sedimentation and mineralization spanning from Paleoarchean to Mesoproterozoic in a dynamic tectonic milieu. Distinct signatures of this Archean-Proterozoic geodynamic process are preserved in discrete crustal provinces that constitute the Singhbhum Craton. Here we report new major, trace and PGE geochemical data from the ~ 3.4 Ga Iron Ore Group (IOG) volcanic rocks of the Jamda-Koira basin, a part of the BIF-bearing volcano-sedimentary sequences of the Noamundi-Jamda-Koira iron ore basin in the western part of Singhbhum Granite (SBG), and ~ 2.25 Ga metavolcanic rocks of Malangtoli. The IOG and Malangtoli volcanic rocks are porphyritic basalts and despite belonging to different ages, they exhibit similar mineralogical composition marked by clinopyroxene, plagioclase (present as both phenocryst and groundmass), opaques and volcanic glass (restricted to groundmass). The igneous mineralogy of these rocks has been overprinted by greenschist to lower amphibolite grade of metamorphism. The Malangtoli samples show low and high MgO compositional varieties. Immobile trace element compositions classify the IOG samples as andesite having a calc-alkaline composition, whereas the Malangtoli rocks correspond to basalt and andesite displaying a tholeiitic to calc-alkaline trend. The IOG basalts show low to moderate PGE contents marked by 26.23–68.35 ppb of ΣPGE, whereas the Malangtoli basalts display a moderate to high concentration of PGE (ΣPGE = 43.01–190.43 ppb). The studied samples have relatively enriched ΣPPGE ranging from 24.1–63.3 ppb (IOG) and 34–227.3 ppb (Malangtoli) against 2.2–4.1 ppb and 1.9–8.9 ppb ΣIPGE contents respectively. PPGE/IPGE ratios for IOG and Malangtoli samples range from 7.7–17.6 and 4.8–59.9. HFSE, REE and PGE compositions suggest a low degree (< 1 to 1%) of partial melting in the garnet lherzolite domain for the generation of IOG volcanic rocks. The parental magma of the Malangtoli basalts were generated by lower to higher degrees (3–< 10%) of mantle melting at depths corresponding to spinel to garnet lherzolite regime. Trace element (Zr/Nb, Th/Ta, Th/Nb, Ni/Cu) and PGE (Pd/Ir, Pd/Pt, Cu/Pd, Ni/Pd, Cu/Ir) ratios corroborate a sulphide saturated and PGE depleted character of IOG volcanic rocks that underwent crustal assimilation. In contrast, the high MgO Malangtoli basalts exhibit sulphide undersaturated, PGE undepleted nature devoid of crustal contamination whereas the low MgO Malangtoli basalts are sulphide saturated, PGE depleted and crustally contaminated. The IOG volcanic rocks correspond to intraoceanic arc with polygenetic crustal signatures, and show affinity towards arc-generated calc-alkaline basalts. The low- and high MgO basalts of Malangtoli are affiliated to transitional arc to rift-controlled back arc tectonic setting in a basinal environment that developed proximal to an active convergent margin.     

Geochemistry of the shawmere anorthosite complex,kapuskasing structural zone,Ontario

The Archean Shawmere Anorthosite Complex, at the southern end of the Kapuskasing Structural Zone, consists dominantly of anorthosite (An_{65 –85}) with minor gabbroic and ultramafic units, which are completely enclosed and cut by tonalites. Both the anorthosites and the tonalites are themselves cut by narrow dikes of gabbroic anorthosite. All of the rocks have undergone high grade metamorphism and are recrystallized so that few igneous textures remain.The anorthosites, gabbros and ultramafic rocks of this complex are cumulates which contain calcic plagioclase (An_65–95) and have atomic Mg/(Mg + Fe²⁺) ratios (Mg#) greater than 0.6; less than 3 ppm Rb; 150–210 ppm Sr; and less than 60 ppm Ba. REE abundanees range from 0.2 to 10 times chondritic and exhibit both light-enriched and light-depleted REE patterns. The lower Mg^# for the samples having more enriched light REE indicates substantial fractions of ferromagnesian minerals crystallized in addition to plagioclase during fractional crystallization, suggesting that the parent magma was basaltic, and not anorthositic. The ranges in Sr, Ba and REE abundances required for the magmas are typical of those for tholeiitic basalts from Archean greenstone belts. Thus the Shawmere Anorthosite Complex may represent cumulates of a crustal-level magma chamber which could have been the immediate source of basic Archean volcanics.One gabbroic anorthositic dike sample has a steeply fractionalted REE pattern with heavy REE abundances less than chondrites and a large positive Eu anomaly. The proposed interpretations is that this rock formed by partial melting of mafic cumulates, perhaps those of the Shawmere Anorthosite Complex itself.     

Rare earth geochemistry of fused ophiolitic and alpine lherzolites—I. Othris,Lanzo and Troodos

Lherzolites from two Mediterranean peridotite masses have major and trace element data compatible with an origin as a fragment of relatively undepleted mantle. Field observations indicate a close association with in situ basaltic melt (gabbroic dikes and segregations) and a barren refractory residue (harzburgite) produced by the removal of the melt fraction.Two lherzolites Othris (ophiolite) and Lanzo (alpine¹ periodotite) have approximately chondritic rare earth abundances with a slight depletion in light rare earths. The refractory material is moderately to heavily depleted in light REE dependent on the efficiency of removal of basaltic melt. Lherzolite xenoliths from the Massif Central probably contain an interstitial light REE enriched fraction as the recalculated lherzolite is depleted and not light REE enriched like the actual whole rock. These basaltic xenoliths are similar in major, trace and REE profile to the Lanzo and Othris mantle lherzolites, giving some indication of source homogeneity in the Mediterranean area. Partial fusion calculations on the Othris and Lanzo peridotites reveal that tholeiitic liquids could be generated by 10–30% partial melting. Such tholeiitic liquids separated from the Othris mantle section and probably formed early sea floor in a small ocean basin. Alkalic basalts are also associated with the Othris ophiolite as an early rifting sequence, and such liquids could have been generated from the source Iherzolite but difficulties would occur in removing such a liquid from the refractory residue.     

Petrology of the Rainy Lake area,Minnesota, USA-implications for petrotectonic setting of the archean southern Wabigoon subprovince of the Canadian Shield

The Rainy Lake area in northern Minnesota and southwestern, Ontario is a Late Archean (2.7 Ga) granite-greenstone belt within the Wabigoon subprovince of the Canadian Shield. In Minnesota the rocks include mafic and felsic volcanic rocks, volcaniclastic, chemical sedimentary rocks, and graywacke that are intrucded by coeval gabbro, tonalite, and granodiorite. New data presented here focus on the geochemistry and petrology of the Minnesota part of the Rainy Lake area. Igneous rocks in the area are bimodal. The mafic rocks are made up of three distinct suites: (1) low-TiO₂ tholeiite and gabbro that have slightly evolved Mg-numbers (63–49) and relatively flat rare-earth element (REE) patterns that range from 20–8 x chondrites (Ce/Yb_N=0.8–1.5); (2) high-TiO₂ tholeiite with evolved Mg-numbers (46–29) and high total REE abundances that range from 70–40 x chondrites (Ce/Yb_N=1.8–3.3), and (3) calc-alkaline basaltic andesite and geochemically similar monzodiorite and lamprophyre with primitive Mg-numbers (79–63), enriched light rare-earth elements (LREE) and depleted heavy rare-earth elements (HREE). These three suites are not related by partial melting of a similar source or by fractional crystallization of a common parental magma; they resulted from melting of heterogeneous Archean mantle. The felsic rocks are made up of two distinct suites: (1)low-Al₂O₃ tholeiitic rhyolite, and (2) high-Al₂O₃ calc-alkaline dacite and rhyolite and consanguineous tonalite. The tholeiitic felsic rocks are high in Y, Zr, Nb, and total REE that are unfractionated and have pronounced negative Eu anomalies. The calcalkaline felsic rocks are depleted in Y, Zr, and Nb, and the REE that are highly fractionated with high LREE and depleted HREE, and display moderate negative Eu anomalies. Both suites of felsic rocks were generated by partial melting of crustal material. The most reasonable modern analog for the paleotectonic setting is an immature island arc. The bimodal volcanic rocks are intercalated with sedimentary rocks and have been intruded by pre- and syntectonic granitoid rocks. However, the geochemistry of the mafic rocks does not correlate fully with that of mafic rocks in modern are evvironments. The low-TiO₂ tholeiite is similar to both N-type mid-ocean-ridge basalt (MORB) and low-K tholeiite from immature marginal basins. The calc-alkaline basaltic andesite is like that of low-K calc-alkaline mafic volcanic rocks from oceanic volcanic arcs; however, the high-TiO₂ tholeiite is most similar to modern E-type MORB, which occurs in oceanic rifts. The conundrum may be explained by: (1) rifting of a pre-existing immature arc system to produce the bimodal volcanic rocks and high-TiO₂ tholeiite; (2) variable enrichment of a previously depleted Archean mantle, to produce both the low- and high-TiO₂ tholeiite and the calc-alkaline basaltic andesite, and/or (3) enrichment of the parental rocks of the high-TiO₂ tholeiite by crustal contamination.     

Trace-Element Modeling and Source Constraints for Tholeiitic and Cale-alkaline Basalts from a Depleted Asthenospheric Mantle Source,Mt. Erciyes Stratovolcano,Turkey

The Mt. Erciyes stratovolcano was built up in an intraplate tectonic environment as a consequence of Eurasian and Afro-Arabian continental collision. However, the volcanic products generally exhibit a calc-alkaline character; minor amounts of tholeiitic basalts are also present. Tholeiitic basalts show high Fe₂O₃, MgO, CaO, low K₂O, and depleted Ba, Nb, and especially Rb (2.3-5.97 ppm) contents, low ⁸⁷Sr/⁸⁶Sr (0.703344-0.703964), and high ¹⁴³Nd/¹⁴⁴Nd (0.512920-0.512780) isotopic ratios. These compositional features show that they were derived from a depleted asthenospheric mantle source, possibly a MORB-like source component. In contrast, calc-alkaline basaltic rocks exhibit relatively high large-ion-lithophile and high-field-strength elements, high ⁸⁷Sr/⁸⁶Sr (0.704591-0.70507) and low ¹⁴³Nd/¹⁴⁴Nd (0.51272-0.512394) isotopic ratios.

The bulk-rock chemistry of the tholeiitic basalts reflects the chemical composition of the extracted source component. Furthermore, trace-element concentrations may be calculated from an accepted mantle source component (starting composition) for different degrees of partial melting. These calculations also provide a sensitive approach to the origin of tholeiitic basalts. Modeled trace-element compositions of tholeiitic basalts are calculated from a primitive mantle composition. Calculated trace-element compositions imply that tholeiitic basalts are derived by minor fractional melting (1-1.5 %), in the absence of assimilation or deep-crustal melting. The calc-alkaline basalts were subsequently produced from initially tholeiitic basalts by the way of an AFC (assimilation-fractional crystallization) process, with a crustal assimilation of 10-15 %.

The geochemical data, partial melting, and AFC modeling all indicate that basaltic products have a complex evolutionary history involving partial melting from a MORB-like mantle source. The assimilation and fractional crystallization processes are considered as providing an example for the chemical evolution of basaltic products, from tholeiitic to calc-alkaline, in an intraplate environment.     

大别造山带南坡晚白垩世玄武岩源区地幔特征

大别造山带南坡中生代断陷盆地中出露大量晚白垩世碱性玄武岩类。因岩浆受结晶分异和陆壳混染影响微弱,其成分基本可代表本区原生玄武岩浆。在微量元素原始地幔标准化蛛网图上,本区玄武岩具有地壳富集组分Pb、K、Rb、Ba等的正异常和Nb、P、Hf等高场强元素的负异常。同位素和微量元素特征显示,玄武岩浆来自亏损地幔(DM)和富集地幔(EM+EM)混合源区。玄武岩源区地幔中Pb的富集和Nb、P、Hf等的亏损基本可由中国东部亏损地幔与榴辉岩的混合获得,由此揭示富集地幔端元组成特征可能与晚白垩世前造山带根部榴辉岩拆沉并参与地幔再循环有关。     

Geochemistry and Petrogenesis of Amphibolites, Kolar Schist Belt, South India: Evidence for Komatiitic Magma Derived by Low Percentages of Melting of the Mantle

The Kolar Schist Belt of the Dharwar Craton of South India isan Archean greenstone belt dominated by metavolcanic rocks.The mafic metavolcanic rocks occur as komatiitic and tholeiiticamphibolites. The komatiitic amphibolites occur along the marginsof the N–S trending, synformal belt. They are much lessabundant than the tholeiitic amphibolites and have 14 to 21–3wt. per cent MgO. The komatiitic amphibolites from the west/centralpart of the belt have two distinctive REE patterns: (1) thoseenriched in the middle to light REE but depleted in Ce relativeto Nd; and (2) those with patterns that are convex up, i.e.depleted in both light and heavy REE, although more depletedin the light REE. Associated tholeiites have light REE depletedto flat REE patterns. Komatiitic and tholeiitic amphibolitesfrom the eastern part of the belt have enriched light REE patterns. The tholeiitic amphibolites from the Kolar Schist Belt are similarto the TH I and TH II types of Archean tholeiites of Condie(1981). The komatiitic amphibolites are similar to komatiitesand komatiitic basalts of Barberton Mountainland, but have higherFeO and TiO2 abundances and lower Yb/Gd ratios. The petrogenetic interpretations for these rocks are based primarilyon a modification of the MgO-FeO diagram of Hanson & Langmuir(1978), and modelling of Zr, Ni and REE. All of the rocks haveundergone some fractionation. While the modelling does not giveaccurate temperatures, pressures, compositions and extents ofmelting of the mantle sources for the various amphibolites,it does present an approach which can be used for estimatingthese parameters. For example, the komatiitic amphibolites appearto be derived from melts generated by 10 to 25 per cent meltingof the mantle over a range of depths and temperatures greaterthan 80 km and 1575?C. The variation in the P-T conditions ofmagma generation is possibly due to adiabatic melting in mantlediapirs with a range of FeO/MgO ratios. If the tholeiitic amphibolitesare derived from similar mantle sources (it is not clear thatthey are), their parent melts may have been generated by similarextents of melting, but at depths of less than 80 km. The komatiiticamphibolites from the west central part of the belt were generatedfrom light REE depleted mantle, whereas those from the easternpart of the belt appear to have been generated from light REEenriched mantle. The sources for the komatiitic amphibolitesin both areas were significantly enriched in FeO relative topyrolite. Thus, a light REE depleted and a light REE enrichedsource appear to have provided mafic volcanics with similarmajor element chemistry to this belt during its evolution.