Correlation between Loess profiles on the basis of mineralogical,malacological, and anthropogenic indicators: A case study from Moravany-Lopata,western Slovakia

Moravany-Lopata, located in the complex of sites in the middle Vah basin, dates to the period immediately preceding the LGM. The authors use this site to demonstrate the usefulness of mineralogical, sedimentological, palaeomalacological, and anthropogenic criteria for the correlation of loess profiles. This analysis is especially concerned with sites in loess territories where the loess layers covering archaeological levels are not thick. Such sites occur frequently on the plateaus of the northern part of Central Europe, though they appear most notably in the areas in which the last loess cover, corresponding to the period after the last Pleniglacial and/or Late Glacial postloess sediments, is absent. The archaeological levels dated to before or directly after the LGM occur in the upper portion of the loess, overlain by the Holocene soil. The investigations at the Moravany-Lopata site have confirmed the usefulness of the anthropogenic indicators in the 0.1–1.0 mm fraction for the identification of occupation levels extending even beyond the area of occurrence of macrofinds and evident type structures. On this basis, a relationship could be established between two occupational levels and two ice-wedge generations in the period from 21.4 to 20 ky. Gravettian settlement in western Slovakia seems to have persisted up to the maximum of the LGM. Population groups representing the end of the shouldered points horizon (pointes à cran) appeared in western Slovakia in the intervals between the formation of large networks of ice wedges. The next settlement phase in that territory falls at about 18–17 ky B.P. This is the Epigravettian settlement, which is culturally unrelated to the shouldered points horizon. © 1998 John Wiley & Sons, Inc.     

Palaeogeography of radiolarite and organic-rich deposits in Mesozoic Tethys

Siliceous and marine organic-rich deposits are sometimes associated, sometimes separate in space and time; however, both are generally accepted to be the result of high planktonic productivity. Among the siliceous marine deposits, the phtanite family facies is distinguished from the radiolarite family facies by several characteristics: They contain organic material and as a result are blackish (vs red/green for radiolarite facies), their time of deposition corresponds with strong faunal modifications and they are deposited generally in shallower environments. A palaeogeographic analysis of locations of Tethyan biosiliceous and marine organic-rich rocks, both resulting from a high planktonic palaeoproductivity, for three Mesozoic high sea-level intervals, Toarcian, Kimmeridgian and Cenomanian, show: (a) during Jurassic times these Tethyan deposits were dissociated, the siliceous deposits being closer to open ocean waters than the organic-rich ones. This is a common disposition in modern upwelling systems and suggests a common process; (b) during Cretaceous times these Tethyan deposits were often associated, i.e. both occur at the same site, and are probably the result of a different process from that in the Jurassic.     

广东曲江-仁化地区早二叠世“当冲层”的放射虫岩

放射虫岩是指主要由放射虫壳体堆积的一种“化学-生物化学岩”。放射虫吸收海水中的硅质组成以含水的SiO₂为成分的壳体。在放射虫岩中,常常还有海绵骨针和硅藻等生物遗迹。卡洛瑞（Carozzi,A.V.1960）把已发现的放射虫岩分为四种:砂质放射虫岩、钙质放射虫岩、铁质放射虫岩（红放射虫岩）和炭质放射虫岩（黑放射虫岩）。实际上放射虫岩主要是硅质为主。广东曲江-仁化地区早二叠世“当冲层”的放射虫岩是一种硅质放射虫岩,本文试就其成因、古地理环境的变迁及与成矿和古构造活动的联系作一初步探讨。     

High-technology metals as emerging contaminants: Strong increase of anthropogenic gadolinium levels in tap water of Berlin,Germany, from 2009 to 2012

The distribution of rare earth elements (REE) in tap water sampled in December 2012 in Berlin, Germany, is characterized by anomalously high levels of gadolinium (Gd). While the western districts of the city show strong anthropogenic positive Gd anomalies in REE distribution patterns, the eastern districts are (almost) unaffected. This contamination with anthropogenic Gd results from Gd-based contrast agents used in Magnetic Resonance Imaging, that enter rivers, groundwater and eventually tap water via the clear water effluent from wastewater treatment plants. While the spatial distribution of anthropogenic Gd in 2012 confirms results of an earlier study in 2009 (Kulaksiz and Bau, 2011a), anthropogenic Gd concentrations have increased between 1.5- and 11.5-fold in just three years. This confirms predictions based upon the increase of anthropogenic Gd concentrations in the Havel River over the past two decades and the time it takes the water to migrate from the Havel River to the groundwater production wells. Anomalously high levels of anthropogenic Gd in tap water, which are not confined to Berlin but have also been observed in London, U.K., and in German cities in the Ruhr area and along the Rhine River, reveal that high-technology metals have become emerging contaminants. While non-toxic at the observed concentrations, the anthropogenic Gd is a microcontaminant that may be used as a conservative pseudo-natural tracer for wastewater-derived xenobiotics such as pharmaceuticals, food additives and personal care products. Our results suggest that monitoring the concentrations of such substances in Berlin’s drinking water can be restricted to a few central and western districts of the city, demonstrating that implementation of anthropogenic Gd as a tracer in monitoring programs can contribute to significant cost savings.     

Heavy metal history from cores in Wellington Harbour,New Zealand

Analysis of ten heavy metals (Ag, Cd, Cr, Cu, Fe, Mn, Ni, Pb, Sb, Zn) in six sediment cores from Wellington Harbour show both anthropogenic enrichments and diagenetic modifications. Absolute concentrations determined by two methods, x-ray fluorescence and acid leaching for bioavailability, are not comparable. However, vertical trends in concentrations of the cored sediment are comparable. To assess levels of anthropogenic pollution, enrichment factors (enriched concentrations in upper core divided by background levels in lower core) are preferred over index of accumulation (I _geo) values because preindustrial or background levels of heavy metals are well constrained. The ten metals are placed into three groups: (1) Cu, Pb, and Zn, which show the most anthropogenic enrichment; (2) As, Cd, Cr, Ni, and Sb, which are often associated with anthropogenic pollution but show only minor enrichment; and (3) Fe and Mn, which are diagenetically enriched. Assuming harbor waters are well mixed, anthropogenic enrichments of Cu, Pb, and Zn, are time correlative, but the degree of enrichment depends on the method of analysis and core location. Levels of As, Cd, Pb, and Zn show small variations in preindustrial sediments that are not related to changes in grain size and probably result from changes in the oxidation-reduction potential of the sediments and salinity of the pore waters.     

Arcellaceans (thecamoebians): new tools for monitoring long- and short-term changes in lake bottom acidity

 James Lake, northeastern Ontario, Canada, has been impacted by the dumping of waste rock from a pyrite mine. High levels of Fe, Al and SO₄, and low pH (2.0–5.5) are recorded in the lake. Lake configuration and current direction result in contaminated areas being restricted to the southwestern portion of the lake. Near neutral pH and low metal levels are recorded elsewhere. Analysis of arcellacean faunas from the lake indicate that one species, Arcella vulgaris, is able to thrive in even the most hostile areas of the lake. The absence of other arcellaceans indicative of contaminated substrates in higher pH lakes, such as centropyxids and Difflugia protaeiformis strains, suggests that pH is the dominant control on the distribution of this assemblage. Analysis of arcellaceans from a core at the site indicates that contamination and acidification (pH values <5.5) problems in James Lake have existed for at least 1300 years, clearly predating mining activity. Prior to that time high proportions of centropyxid species indicate less acid conditions (pH>5.5) prevailed, but a stressed environment existed for several thousand years. The recognition that Arcellacean faunas can now be used to characterize industrially, and naturally contaminated environments of both low and high pH, provides an important new paleolimnological tool. Received: 6 October 1998 · Accepted: 23 February 1999     

Surface Geophysical Methods used to Verify the Karst Geological Structure in the Built-up Area: A Case Study of Specific Engineering-Geological Conditions

This article presents a research study of complex limestone karst engineering-geological conditions in the municipality Valaská near Banská Bystrica in Slovakia. The aim of the study is to demonstrate the impossibility of spatial identification of cave spaces using surface geophysical methods due to the specific engineering-geological conditions of a thick surface layer of anthropogenic fill containing highly heterogeneous anthropogenic material. Its maximum thickness is 3 m. Another specificific condition of the study area is its location in the built-up area, due to which the applicability of geophysical methods was limited. The article contains methodological recommendations to be used in analogous geological conditions with karst structures topped with anthropogenic fill, which complicates the identification of cave spaces. The recommended solution herein is the identification of the cave system using underground mapping of the karst and its projection onto the surface for which surface geophysical methods have been combined.     

Factors triggering landslide occurrence on the Zemun loess plateau,Belgrade area,Serbia

Among the numerous factors that trigger landslide events, the anthropogenic impact caused by inadequate planning and faulty land use in urban areas is increasing. The Zemun settlement on the northern outskirts of Belgrade has experienced a number of landslides in the last three decades, endangering buildings and roads, and claiming human lives, particularly in the case of the 2010/2011 landslides. Selected meteorological parameters were used to calculate rainfall erosivity indices such as Precipitation Concentration Index and Modified Fournier Index over the period 1991–2015. Drought indices, Lang aridity index and Palfai Drought Index were calculated as well. Mann–Kendall trend test was applied to identify potential rising and/or declining trends both in meteorological parameters and calculated indices. Trend analysis of the annual and seasonal scales yielded a statistically significant trend in the spring time series. Stable arid and pronounced drought conditions were recorded. The modified Fournier index based on monthly mean values yields moderate aggressiveness, with several extreme values indicating very high erosivity classes, especially for 2010/2011. The geological substrate is predominantly loess and hence highly susceptible to erosion and slope failure when climatological conditions are suitable. Accelerated urbanization at the end of the last century reduced vegetation cover, intensified pressure on the vertical loess slope, and lacked suitable rain drainage systems so that surface-water runoff was directed into the porous loess, thereby endangering slope stability. We proposed a geomorphic model to describe the nature of the erosional processes on the loess cliffs of the Zemun loess plateau. Results from this study have implications for mitigation strategies.     

Formation processes of cemented features in karstic cave sites revealed using stable oxygen and carbon isotopic analyses: A case study at middle paleolithic Amud Cave,Israel

Hearths are important archaeological features, serving to infer past practices related to hominin subsistence and social behaviors. The identification of hearths is not always straightforward due to post‐depositional processes. In karstic cave environments in particular it is not always easy to distinguish, in the field or in the laboratory, between geogenic and anthropogenic cemented features because both are composed of calcite. Here we present a novel study in which bulk oxygen and carbon isotopic analyses were used in order to unequivocally identify anthropogenic calcite derived from hearths in the Neanderthal site of Amud Cave (Israel). We demonstrate that the isotopic composition of wood ash is distinctively different from that of geogenic calcite. The linear relationship observed between carbon and oxygen isotopic compositions of the various sediment types in Amud Cave is interpreted as a mixing line between wood ash and geogenic calcite, thus enhancing our understanding of the origins of sedimentological variability at the site and showing that not all of the cemented sediments in Amud Cave should be regarded as hearths. Our study suggests that the relative abundance of validated hearths in the various areas of the cave may be associated with Neanderthal use of space in Amud Cave. © 2008 Wiley Periodicals, Inc.     

The Collapse of Gran Dolina cave,Sierra de Atapuerca,Spain: Site formation processes of layer TD10‐1

The last hominin occupations of Gran Dolina cave at Atapuerca are represented by layer TD10‐1. This layer has yielded high densities of anthropogenic bone and lithic remains that suggest the existence of a referential hominin campsite. Micromorphological analysis was carried out in order to reconstruct site formation processes and to find traces of hominin activity in the sediments. Results show that TD10‐1 is an autochthonous deposit whose components are derived from a local, degraded cave entrance environment. The base of TD10‐1 represents a moist, semi‐sheltered environment associated with anthropogenic input and low sedimentary rates, while the rest of the deposit represents a non‐anthropogenic, more open environment with higher rates of sedimentation. The TD10‐1 archaeological assemblages have not undergone long transport or strong postdepositional disturbance. Further interdisciplinary analyses are needed to characterize the types and intensity of the hominin activities recorded in TD10‐1. © 2008 Wiley Periodicals, Inc.     

Embedded Behavior: Human Activities and the Construction of the Mesolithic Shellmound of Cabeço da Amoreira,Muge, Portugal

Shellmound formation processes are greatly influenced by human inputs associated with an intensive exploitation of marine and estuarine resources. The complex stratigraphy of shellmounds has been difficult to decipher and few studies have focused on the microstratigraphic record of midden formation, especially in European Mesolithic contexts. Cabeço da Amoreira is a long‐known Mesolithic shellmound located on the shores of the Muge River, a tributary of the Tagus River in central Portugal. The abundance of shellfish refuse favors an intricate and laterally variable stratigraphic succession of layers and lenses, which results in an extensive artificial mound. Here, we use micromorphological and microfacies analysis to investigate aspects pertaining to site formation, and the nature of individual anthropogenic activities at the site. This methodology allowed for a distinction between primary activities (e.g., discrete shell tossing events, trampled occupational surfaces, and activity areas), and secondary position of the sediments in intentionally raked‐up and dumped deposits. Nondepositional hiatuses and discrete geogenic sedimentation are associated with periods of abandonment. The complex superposition of events seen at Cabeço da Amoreira underlines the role of micromorphology for the identification of behavioral signatures and its relevance in deciphering shellmound adaptations.     

Geochemical evidence of terrigenous influence in sediments of Buckingham canal,Ennore, Southeast coast of India

Five sediment cores were collected in July 2008 from Buckingham Canal, Ennore, India, a water body that is influenced by domestic and industrial effluents. Downcore variations in trace metal concentrations—Ni, Pb, Mn and Zn at every 2.5 cm increment was determined through acid extraction (hydro fluoric acid, nitric acid and sulphuric acid) and analysed by atomic emission spectrophotometer. The sandy clay environment is composed mostly of medium sized grains. Among the four trace metals studied in five cores, Mn and Ni are the highest and the least occurring metals respectively. Quantitative indices such as geoaccumalation index, anthropogenic factor, enrichment factor, contamination factor and degree and pollution load indices were computed. All these analyses classify Ennore as uncontaminated or moderately contaminated. Zn has the highest anthropogenic factor (2.29) indicating the increasing concentration of Zn in the recent times. Zn enrichment is observed only at surface sediments (top 7.5 cm) C4.     

Factors influencing determination of shale classification indices and their correlation to mechanical properties

The influence of sample preparation procedure on the measured classification indices such as clay-size fraction, liquid limit, and plastic limit of shales was investigated. Shale samples covering a wide range of composition and plasticity were tested using standard and modified preparation procedures to yield quantitative data required for this investigation. The study specifies the range of shale plasticity in which the measured values of clay-size fraction and liquid limit are sensitive to hydrometer specimen size and rehydration time, respectively. The study also revealed that the degree of shale particle disaggregation has an important influence on the measured clay-size fraction and liquid limit. This influence is maximized for shales with intermediate plasticity and can be interpreted in terms of particle size and shape. Correlations were established between classification indices derived from standard and modified sample preparation procedures. It is recommended to use these correlations to adjust shale classification indices derived from standard sample preparation procedures usually utilized by commercial laboratories. Such correlations help in creating a universally followed procedure for better estimation of shale engineering properties and reliable interpretation of case histories involving shale formations.     

Potential ecological risk assessment,enrichment, geoaccumulation,and source identification of metals in the surface sediments of Choghakhor Wetland,Iran

This study reported the first comprehensive research on identification of metal concentrations (Fe, Mg, Mn, Pb, Cd, Cr) in order to provide baseline data for future studies, identify possible sources, determine degree of pollution, and identify potential ecological risks of metals in surface sediments from Iran’s Choghakhor Wetland. The order of metal concentration was as follows: Fe > Mg > Mn > Pb > Cd > Cr, with mean concentrations of 6140.35, 1647.32, 289.03, 1.10, and 0.45 µg/g of dry weight, respectively. These results reveal that Choghakhor Wetland is not heavily polluted compared to other regions. The results of enrichment factor (EF) and geoaccumulation index (I _geo) showed that Fe, Pb, Mg, Cr, and Mn presented low levels of contamination and probably originated from natural sources. On the other hand, the results of EF and I _geo indices suggested that Cd concentrations in sediments of Choghakhor Wetland originated from anthropogenic sources. Based on the results of three sets of sediment quality guidelines, only Cd concentration in sediments of Choghakhor Wetland is a threat for aquatic organisms of Choghakhor Wetland. The results of multivariate analysis such as principal component analysis and cluster analysis showed that Fe–Mn, Cr–Mg, and Pb groups originated from natural sources, while Cd concentrations in sediments of Choghakhor Wetland originated from both natural and anthropogenic sources (mainly chemical fertilizers). To our knowledge, this is the first study about metal concentrations in sediments of Choghakhor Wetland, and because of low levels of these metals, these concentrations can be considered background levels for future investigation.     

Heavy metal pollution assessment through comparison of different indices in sewage-fed fishery pond sediments at East Kolkata Wetland,India

The sediments of the raw sewage-fed fishpond system at East Kolkata Wetland (EKW) were analyzed for heavy metal content in a comprehensive way. Various indices of contamination like enrichment factor (EF), geo-chemical index (I _geo), modified degree of contamination (mD_C), and pollution load index (PLI) were assessed. In all cases, instead of literature values, the metal concentrations of less contaminated sites, separated by the statistical approach of the hierarchical cluster analysis, were used as baseline values. In the present study, about 70% of the pond sediments are found uncontaminated, 5% display low degree of contamination and 25% are designated as moderate degree of contamination. Both the EF and I _geo indices highlighted that the metals lead (Pb), cadmium (Cd), and chromium (Cr) are responsible for the contamination while there is little anthropogenic input in cases of Cu, Zn, and Ni. Most of the ponds situated near the main sewage flowing canals as well as the main traffic highway and close to the solid waste dumping areas recorded higher degree of metal contamination as evident from spatial variation of mD_C and PLI indices in the study area. Indices comparison study clearly indicates that although these are calculated using different methods, these may or may not produce the same indices values and hence the values should neither be compared nor be averaged. But all the above indices are directly related to a common term contamination factor (CF). Classification of contamination levels based on these CF values is found to be similar and this classification is only valid up to the level of high degree of contamination. Thus, the use of any one of these indices is sufficient to classify the degree of contamination of an area. However, to evaluate the contamination per metal, both I _geo and EF are effective while, to assess the composite effect of all the metals, PLI is preferable to mD_C.     

The upper cretaceous ophiolite complex of Masirah Island,Oman

Masirah Island is almost entirely composed of a highly faulted and unmetamorphosed folded ophiolite complex which is unconformably overlain by unfolded Eocene limestone and is correlated with the Upper Cretaceous Semail Complex of the Oman Mainland. The ophiolites include serpentine, basalt, pyroclastics and some radiolarite, and intrusive complexes largely composed of serpentine, peridotite, picrite, anorthosite, gabbro and granite, with transitional varieties. Emplacement structures within the intrusions are extremely complicated, with the gabbros full of blocks mostly of serpentine up to 1 km or more in diameter. There are also late stage veins, lenses and irregular bodies of granite. Ophiolites, probably derived from the mantle, are ultrabasic differentiates with soda metasomatism. Tectonic structures are largely pre-Eocene. They include fractures, some of which are parallel to the late Tertiary submarine Masirah fault which is related to continental drift.     

Influence of sediment provenance on background values of potentially toxic metals from near-surface sediments of Po coastal plain (Italy)

Systematic variability in metal concentrations is recorded in near-surface (1 m deep) Late Quaternary sediments of Po coastal plain, across the boundary between alluvial deposits of Apenninic provenance and a formerly active, now abandoned, delta lobe of the Po River. In the latter area, high Cr and Ni concentrations, exceeding the national standard limits, are attributed to sediment provenance from ultramafic source rocks of Po catchment basin, and not to anthropogenic impact. Spatial distribution of carbonate-related elements, such as Ca and Sr, displays consistent differences between the two areas, confirming a primary control of provenance domains on sediment composition. Accurate facies characterization of near-surface sediments, coupled with detailed information on sediment dispersal patterns, enable a reliable interpretation of the spatial variability of major elements and trace metals in the study area. Particularly, detailed reconstructions of source area composition and changes in flow directions through historical times allow precise correlation of apparently anomalous geochemical patterns with distinctive depositional events, such as shifts in channel course, crevasse splay formation and beach-ridge evolution. The findings of unusually high, natural (provenance-controlled) heavy metal concentrations in pre-industrial near-surface levels highlight the contribution of a sedimentological approach to a reliable interpretation of geochemical data. This should be taken into account when determining background values versus anthropogenic impact.     

Using winter flounder growth rates to assess habitat quality across an anthropogenic gradient in Narragansett Bay, Rhode Island

We used growth rates of juvenile winter flounderPseudopleuronectes americanus to assess anthropogenic influence on habitat quality at three sites in Narragansett Bay, Rhode Island. The upper bay site, Gaspee Point, had the highest population density and concentration of total nitrogen; human inputs decreased down bay. Growth rates of individually marked fish were measured in three 15-d experiments from June 8 to July 6, 1998 in 1-m² cages placed at upper, middle, and lower bay sites. Water temperature, salinity, dissolved oxygen (DO), and benthic food were also measured. Stable isotopes of nitrogen and carbon were measured in experimental fish as possible indicators of nutrient enrichment and to identify organic carbon sources. Growth rates were 0.22–0.60 mm d⁻¹, with the highest average at the mid-bay site. Growth was initially fastest at Gaspee Point, but dropped off as DO concentrations fell. Step-wise multiple regression indicated that location (upper, middle, or lower bay) explained most of the variability in fish growth (40%). Coefficients of other significant variables indicated that fish grew faster at lower salinities, smaller sizes, and with decreased time that DO was below 2.3 mg l⁻¹. Benthic prey varied among sites and there was significantly less food and fewer species at Gaspee Point.Polydora cornuta was a favored food at all sites and was found in over half the stomachs. Values of δ¹⁵N in fish and sediments did not reflect differences in total nitrogen concentrations recorded near the sites. We suggest that anthropogenic influences, such as nutrients and sewage, affected habitat quality by reducing DO, which lowered fish growth rates.     

Anthropogenic Rare Earth Element in rivers: Gadolinium and lanthanum. Partitioning between the dissolved and particulate phases in the Rhine River and spatial propagation through the Rhine-Meuse Delta (the Netherlands)

In this study, we report for the first time lanthanum and gadolinium anomalies at the catchment scale (Rhine-Meuse River system) together with the partitioning of their anthropogenic contents between the dissolved and the particulate phases. We compare the dissolved and total REE patterns of samples taken at 9 locations in the Rhine Branches including Lobith (situated at the German–Dutch border where the Rhine is not yet divided in three Branches), in surface water fed by the Rhine Branches (canals and lake IJsselmeer and Ketelmeer) and 3 locations where the water is derived from the river Meuse (originating from Belgium and France).We demonstrate that the anthropogenic input of lanthanum in the German part of the Rhine River identified by Kulaksiz and Bau (2011) can be traced in the complex Rhine-Meuse Delta up to the North Sea. In the Dutch Branches of the Rhine River, in contrast to the German part of the Rhine River, the anthropogenic lanthanum (La_ANTHRO) is mainly present in the particulate phase (SPM) and not in the dissolved phase (defined as the <0.45 μm fraction). In the Meuse River no anthropogenic lanthanum was found. The amount of La_ANTHRO transported by the Rhine River at the Lobith station (German–Dutch border) varies from 2008 to 2010 between 3.7 and 5.2 tons/y in the dissolved phase, and between 28.8 and 37.4 tons/y in the particulate phase. However, a big discrepancy is evidenced when we compare the La_ANTHRO load calculated on bases of the total water samples with the La_ANTHRO load calculated as the sum of the particulate and dissolved load: the total La_ANTHRO load is roughly 2 times larger than the La_ANTHRO load calculated as the sum of the dissolved and particulate La_ANTHRO load. The difference between the two calculated fluxes is most likely caused by not sampling the finest fraction of the particulate pool in the SPM samples with an overflow centrifuge.The anthropogenic gadolinium identified by high gadolinium anomalies in the REE patterns originates from numerous point sources (waste water treatment plant effluents) and can thus be considered as diffuse pollution when compared to anthropogenic lanthanum clearly resulting from a single source. The amount of anthropogenic gadolinium measured in the dissolved phase (main carrier of Gd) increases or decreases along the Rhine and Meuse Rivers depending whether or not the mixing water contains anthropogenic gadolinium, i.e. receives waste water effluents.