Aerosol properties at gosan in Korea during two pollution episodes caused by contrasting weather conditions

We analyzed aerosol optical and chemical properties over Northeast Asia for two pollution episodes caused by contrasting weather conditions, stagnant anticyclone (November, 2011) and fastmoving continental outflow associated with migratory cyclone/anticyclone (February, 2003). Pollution levels were significantly high and even comparable with heavily polluted urban cities in China and Korea even though these levels were from the episodic measurements since Gosan is an internationally well-known remote background site. Space-borne MODIS measurements clearly show that the pollution plume with high aerosol optical depth (AOD) overlaid and very slowly moved over Northeast Asia during the stagnation episode. On the other hand, a strong synoptic wind transported the plume from eastern China to its downwind regions during the continental outflow episode. The two pollution episodes showed discriminative aerosol chemical compositions associated with different source characteristics. Concentrations of nss (non-sea-salt)-sulfates and ammonium in the continental outflow episode were almost two times higher than those in the stagnation episode due to the influence of anthropogenic emissions from China. A higher fraction of nitrate, accompanied with an increase of carbonaceous species in the stagnation episode, was attributable to vehicular emissions originated from Korea.     

On Eastern Asian Dust Storm

In this paper, the characteristics of eastern Asian dust storm are examined with emphasis on the satellite measurements of aerosol optical thickness. The reflectivity of solar radiation from the earth’s atmosphere depends on the optical thickness. The satellite measurement of radiance of sunlight, scattered by the earth and its atmosphere, is used to derive the properties of aerosol on oceanic surfaces. This paper involves the following: (1) investigation of the measurement of dust storm over the oceanic surface by GMS satellite; (2) investigation of the measurement of dust storm over the land surface by ground-based instruments such as actinometer, lidar, etc.; (3) for comparison, de-riving an atmospheric aerosol size distribution over the oceanic surface of calm weather through measurements of NOAA satellite; and (4) the weather process and its mass load of eastern Asian dust storm.     

Compositions and source apportionments of atmospheric aerosol during Asian dust storm and local pollution in central Taiwan

A study has been carried out on water soluble ions, trace elements, as well as PM_2.5 and PM_2.5–10 elemental and organic carbon samples collected daily from Central Taiwan over a one year period in 2005. A source apportionment study was performed, employing a Gaussian trajectory transfer coefficient model (GTx) to the results from 141 sets of PM_2.5 and PM_2.5–10 samples. Two different types of PM₁₀ episodes, local pollution (LOP) and Asian dust storm (ADS) were observed in this study. The results revealed that relative high concentrations of secondary aerosols (NO₃⁻, SO₄²⁻ and NH₄⁺) and the elements Cu, Zn, Cd, Pb and As were observed in PM_2.5 during LOP periods. However, sea salt species (Na⁺ and Cl⁻) and crustal elements (e.g., Al, Fe, Mg, K, Ca and Ti) of PM_2.5–10 showed a sharp increase during ADS periods. Anthropogenic source metals, Cu, Zn, Cd, Pb and As, as well as coarse nitrate also increased with ADS episodes. Moreover, reconstruction of aerosol compositions revealed that soil of PM_2.5–10 elevated approximately 12–14% in ADS periods than LOP and Clear periods. A significantly high ratio of non-sea salt sulfate to elemental carbon (NSS-SO₄²⁻/EC) of PM_2.5–10 during ADS periods was associated with higher concentrations of non-sea-salt sulfates from the industrial regions of China. Source apportionment analysis showed that 39% of PM₁₀, 25% of PM_2.5, 50% of PM_2.5–10, 42% of sulfate and 30% of nitrate were attributable to the long range transport during ADS periods, respectively.     

Aerosol absorption optical depth of fine-mode mineral dust in eastern China

由气溶胶自动观测网(AERONET)反演的细模态气溶胶的吸收光学厚度(AAOD)通常被认为是黑碳气溶胶的AAOD,并且通过这种方法得到的黑碳AAOD已经被用在计算黑碳辐射强迫的研究中。但是这种方法是基于如下假设:直径小于1μm的细模态气溶胶和直径大于1μm的粗模态气溶胶对光的吸收主要分别归功于黑碳和沙尘。为了定量描述细模态沙尘气溶胶对全部细模态气溶胶的AAOD的贡献,我们利用地球系统交互模式(CESM)模拟了中国东部(104–122°E,29–41°N)细模态沙尘气溶胶的AAOD。其中,我们根据9个中国气象局大气观测网(CAWNET)站点观测的细模态沙尘地表浓度调整了模拟的细模态沙尘气溶胶的浓度。结果显示,模拟的中国东部年平均细模态沙尘气溶胶的AAOD的值为3.6×10-3,其中AAOD的最大和最小值分别出现在春季和冬季。细模态沙尘气溶胶对总的细模态气溶胶(细模态沙尘、黑碳和有机碳气溶胶的总和)的AAOD的贡献在春季、夏季、秋季和冬季分别为3.4%、25.2%、12.5%和14.9%,其年平均值为15.1%。这些结果显示当利用AERONET反演得到的细模态气溶胶的AAOD来计算中国东部BC气溶胶的辐射强迫时,去除细模态沙尘粒子的影响显得尤为重要。     

南亚地区黑碳气溶胶对亚洲夏季风的影响

利用NCAR的全球大气模式CAM3,模拟了南亚地区黑碳气溶胶对亚洲夏季风的影响.结果表明:晚春时期,南亚地区黑碳气溶胶强烈吸收太阳辐射,加热低层大气,造成孟加拉湾及沿岸地区雨季的提前,可能导致南亚夏季风提前爆发.夏季,被加热的大气沿青藏高原南坡爬升,在高空形成一个稳定的加热层.高空的持续加热,引起局地的深对流活动,使得印度洋和南亚大陆之间产生一个北升南降的经圈环流,导致印度洋洋面上的向北运动加强,从而使南亚夏季风的强度增大.但是,南亚地区黑碳气溶胶通过影响表面气压、垂直运动、降水和850 hPa风场等减弱了东亚夏季风,且导致西太平洋副热带高压北移西伸,使我国梅雨带位置向东北方向移动.     

Vertically resolved dust optical properties during SAMUM: Tinfou compared to Ouarzazate

Vertical profiles of dust key optical properties are presented from measurements during the Saharan Mineral Dust Experiment (SAMUM) by Raman and depolarization lidar at two ground-based sites and by airborne high spectral resolution lidar. One of the sites, Tinfou, is located close to the border of the Sahara in Southern Morocco and was the main in situ site during SAMUM. The other site was Ouarzazate airport, the main lidar site. From the lidar measurements the spatial distribution of the dust between Tinfou and Ouarzazate was derived for 1 d. The retrieved profiles of backscatter and extinction coefficients and particle depolarization ratios show comparable dust optical properties, a similar vertical structure of the dust layer, and a height of about 4 km asl at both sites. The airborne cross-section of the extinction coefficient at the two sites confirms the low variability in dust properties. Although the general picture of the dust layer was similar, the lidar measurements reveal a higher dust load closer to the dust source. Nevertheless, the observed intensive optical properties were the same. These results indicate that the lidar measurements at two sites close to the dust source are both representative for the SAMUM dust conditions.     

The recent characteristics of Asian dust and haze events in Seoul, Korea

Summary The study on the characteristics of aerosol in Seoul during springtime from 1998 to 2003 is performed by the size-resolved number concentrations of aerosol. Asian dust events occur in spring most frequently, but it has been often observed in wintertime since 1999. Since 2000, the number of Asian dust days has been increasing, and the intensity has been more severe until 2002. However, there were only 3 dust days in Seoul during the spring of 2003, since the synoptic cyclone was relatively not intense enough to rise and transport dust to Korean peninsula, and the air stream was usually tiled to north of Korean peninsula. In addition, the precipitation was relatively plentiful and the air temperature was cold enough not to keep dry soil condition.Haze is the suspended particles in the air, reducing visibility by scattering light, and it is often a mixture of aerosols and photochemical smog. Dry particles with diameters of the order of 0.1µm, are small enough to scatter short wavelengths of light. Haze occurs well in winter and spring, and severe haze is observed in the afternoon. The occurrence frequency of haze has been decreasing since 2000 except in May of 2003.During Asian dust events from 1998 to 2003, the number concentration of aerosol with diameters from 0.3µm to 0.5µm decreases notably, but that larger than 1µm increases rapidly. On the other hand, for the haze events the number concentration from 0.3µm to 0.5µm increases notably, but that larger than 1µm decreases.     

Vertical distributions of aerosol optical properties during haze and floating dust weather in Shanghai

A comparative study on the vertical distributions of aerosol optical properties during haze and floating dust weather in Shanghai was conducted based on the data obtained from a micro pulse lidar.There was a distinct difference in layer thickness and extinction coefficient under the two types of weather conditions.Aerosols were concentrated below 1 km and the aerosol extinction coefficients ranged from 0.25 to 1.50km^-1 on haze days.In contrast,aerosols with smaller extinction coefficients(0.20 0.35 km^-1) accumulated mainly from the surface to 2 km on floating dust days.The seasonal variations of extinction and aerosol optical depth（AOD） for both haze and floating dust cases were similar greatest in winter,smaller in spring,and smallest in autumn.More than 85%of the aerosols appeared in the atmosphere below 1 km during severe haze and floating dust weather.The diurnal variation of the extinction coefficient of haze exhibited a bimodal shape with two peaks in the morning or at noon,and at nightfall,respectively.The aerosol extinction coefficient gradually increased throughout the day during floating dust weather.Case studies showed that haze aerosols were generated from the surface and then lifted up,but floating dust aerosols were transported vertically from higher altitude to the surface.The AOD during floating dust weather was higher than that during haze.The boundary layer was more stable during haze than during floating dust weather.     

Chemical Composition Based Aerosol Optical Properties According to Size Distribution and Mixture Types during Smog and Asian Dust Events in Seoul,Korea

This study investigated the optical properties of aerosols involved in different meteorological events, including smog and Asian dust days. Carbonaceous components and inorganic species were measured in Seoul, Korea between 25 and 31 March 2012. Based on the measurements, the optical properties of aerosols were calculated by considering composition, size distribution, and mixing state of aerosols. To represent polydisperse size distributions of aerosols, a lognormal size distribution with a wide range of geometric mean diameters and geometric standard deviations was used. For the optical property calculations, the Mie theory was used to compute single-scattering properties of aerosol particles with varying size and composition. Analysis of the sampled data showed that the water-soluble components of organic matter increased on smog days, whereas crustal elements increased on dust days. The water content significantly influenced the optical properties of aerosols during the smog days as a result of high relative humidity and an increase in the water-soluble component. The absorption coefficients depended on the aerosol mixture type and the aerosol size distributions. Therefore, to improve our knowledge on radiative impacts of aerosols, especially the regional impacts of aerosols in East Asia, accurate measurements of aerosols, such as size distribution, composition, and mixture type, under different meteorological conditions are required.     

Vertical structures of atmospheric properties in Southeast Tibet during the South Asian summer monsoon in 2013

In June 2013, a field experiment was conducted in Southeast Tibet in which the air temperature, moisture, and wind were measured by using a GPS sounding system. In the present study, based on these observations and ERA-Interim reanalysis data, the vertical structures of these atmospheric properties and the possible influence of the South Asian summer monsoon (SASM) were investigated. On average, the temperature had a lapse rate of 6.8℃km^?1 below the tropopause of 18.0 km. A strong moisture inversion occurred at the near-surface, with a strength of 1.7 g kg^?1 (100 m)^?1 for specific humidity. During the observation period, the SASM experienced a south phase and a north phase in the middle and by the end of June, respectively. The monsoon’s evolution led to large changes in convection and circulation over Southeast Tibet, which further affected the local thermal, moisture, and circulation conditions. The strong convection resulted in an elevated tropopause height over Southeast Tibet during the north phase of the SASM, and the large-scale warm and wet air masses delivered by the monsoon caused high local temperature and moisture conditions.     

Asian dust depositions over the Asian region during March 2010 estimated by ADAM2

The Asian Dust Aerosol Model 2 with the MM5 meteorological model has been employed to estimate the dust emission, dust concentration, and wet and dry deposition of dust in the Asian region for the month of March in 2010. It is found that the model simulates quite reasonably the dust (PM₁₀) concentrations both in the dust source region and the downstream region of Korea. The starting and ending times of most dust events and their peak concentration occurrence times are well simulated. The monthly mean maximum surface dust concentration (PM₁₀) is found to be 267???g?m^?3 in the domain of central northern China (CNC). Monthly total maximum dust emission of more than 32?t km^?2 and that of deposition of more than 25.4?t km^?2 (dry deposition of 24?t km^?2 and wet deposition of 1.4?t km^?2) are found to occur in the domain CNC, whereas the monthly mean minimum surface dust concentration (PM₁₀) is found to be 0.2???g?m^?3 in the domain of the Tibetan Plateau, where the monthly total dust emission (4?kg?km^?2) and the monthly total dust deposition (9?kg?km^?2) are found to be minimum. This monthly total dust deposition of 9?kg?km^?2 (dry deposition of 7?kg?km^?2 and wet deposition of 2?kg?km^?2) is as large as 2.25 times of that of emission (4?kg?km^?2), suggesting net dust influx toward the Tibetan Plateau from the surrounding dust source regions. It is also found that the ratio of the total dust deposition to the total dust emission in the source region increases toward the downstream direction from 0.4 in the upstream source region of Taklimakan to 0.80 in the downstream source region of northeastern China. More than 90% of the total dust deposition is found to be contributed by dry deposition due to the lack of precipitation in the dust source region. The monthly mean dust concentration (PM₁₀) is found to decrease with distance away from the dust source region. The monthly mean dust concentration of 62???g?m^?3 over the Yellow Sea (YES) decreases to 4.3???g?m^?3 over the Northwestern Pacific Ocean (NWP). The monthly total dust deposition in the downstream region is also found to decrease away from the source region from 2.33?t km^?2 (dry deposition of 1.36?t km^?2 and wet deposition of 0.97?t km^?2) over the domain YES to 1.45?t km^?2 (dry deposition of 0.16?t km^?2 and wet deposition of 1.30?t km^?2) over the domain NWP. A large amount of the total dust deposition over the seas is contributed by wet deposition (more than 90%), causing a small decreasing rate of the total dust deposition with distance from the source region. The estimated dust deposition could adversely impact the eco-environmental system significantly in the downstream regions of the Asian dust source region, especially over the seas.     

Physicochemistry and Mineralogy of Storm Dust and Dust Sediment in Northern China

Dust sediments collected from 1995 to 1998 in Beijing, Dunhuang, Inner Mongolia, Kashi, the Kunlun Mountains, Lanzhou, Ningxia, the Taklimakan Desert, and Xi‘an, China, were characterized in terms of their physical, chemical, and mineralogical properties. Most aerosols and dust analysed ranged in texture from silty clay to clay loam. Their median particle diameters (Mds) generally ranged between 5 to 63μm,coinciding with those of loess from central China and the finest sand from northwestern China. The dust sediments were characterized by a predominance of SiO2 and Al2O3, followed by K2O. Their SiO2/Al2O3and K2O/SiO2 molar ratios ranged from 5.17 to 8.43 and from 0.009 to 0.0368, respectively. The mass concentration spectrum during a dust storm showed a single peak, rather than the triple peak generally observed under clear sky conditions. The dominant minerals were chlorite, illite, calcite, and dolomite.These physical, chemical, and mineralogical properties were consistent with those of aeolian soils and loess in western and central China. The results suggest that aerosols and fine-gained fractions of dust sediments collected in northern China are mainly composed of soil material transported from the arid and semiarid regions of China and Mongolia by prevailing winds. The rate of deposition and properties of dust falling on eastern China were strongly influenced by meteorological conditions, season, latitude, longitude, and altitude of the sampling sites.     

Statistical guidance on seasonal forecast of Korean dust days over South Korea in the springtime

This study aimed to develop the seasonal forecast models of Korean dust days over South Korea in the springtime. Forecast mode was a ternary forecast (below normal, normal, above normal) which was classified based on the mean and the standard deviation of Korean dust days for a period of 30 years (1981-2010). In this study, we used three kinds of monthly data: the Korean dust days observed in South Korea, the National Center for Environmental Prediction in National Center for Atmospheric Research (NCEP/NCAR) reanalysis data for meteorological factors over source regions of Asian dust, and the large-scale climate indices offered from the Climate Diagnostic Center and Climate Prediction Center in NOAA. Forecast guidance consisted of two components; ordinal logistic regression model to generate trinomial distributions, and conversion algorithm to generate ternary forecast by two thresholds. Forecast guidance was proposed for each month separately and its predictability was evaluated based on skill scores.     

The retrieval of the Asian dust depolarization ratio in Korea with the correction of the polarization-dependent transmission

The linear particle depolarization ratios were retrieved from the observation with a multiwavelength Raman lidar at the Gwangju Institute of Science and Technology (GIST), Korea (35.11°N, 126.54°E). The measurements were carried out in spring (March to May) 2011. The transmission ratio measurements were performed to solve problems of the depolarization-dependent transmission at a receiver of the lidar and applied to correct the retrieved depolarization ratio of Asian dust at first time in Korea. The analyzed data from the GIST multiwavelength Raman lidar were classified into three categories according to the linear particle depolarization ratios, which are pure Asian dust on 21 March, the intermediate case which means Asian dust mixed with urban pollution on 13 May, and haze case on 10 April. The measured transmission ratios were applied to these cases respectively. We found that the transmission ratio is needed to be used to retrieve the accurate depolarization ratio of Asian dust and also would be useful to distinguish the mixed dust particles between intermediate case and haze. The particle depolarization ratios of pure Asian dust were approximately 0.25 at 532 nm and 0.14 at 532 nm for the intermediate case. The linear particle depolarization ratios of pure Asian dust observed with the GIST multiwavelength Raman lidar were compared to the linear particle depolarization ratios of Saharan dust observed in Morocco and Asian dust observed both in Japan and China.     

Influence of South Asian Biomass Burning on Ozone and Aerosol Concentrations Over the Tibetan Plateau

In this work, the influence of South Asian biomass burning emissions on O₃ and PM_2.5 concentrations over the Tibetan Plateau (TP) is investigated by using the regional climate chemistry transport model WRF-Chem. The simulation is validated by comparing meteorological fields and pollutant concentrations against in situ observations and gridded datasets, providing a clear perspective on the spatiotemporal variations of O₃ and PM_2.5 concentrations across the Indian subcontinent, including the Tibetan Plateau. Further sensitivity simulations and analyses show that emissions from South Asian biomass burning mainly affect local O₃ concentrations. For example, contribution ratios were up to 20% in the Indo-Gangetic Plain during the pre-monsoon season but below 1% over the TP throughout the year 2016. In contrast, South Asian biomass burning emissions contributed more than 60% of PM_2.5 concentration over the TP during the pre-monsoon season via significant contribution of primary PM_2.5 components (black carbon and organic carbon) in western India that were lofted to the TP by westerly winds. Therefore, it is suggested that cutting emissions from South Asian biomass burning is necessary to alleviate aerosol pollution over the TP, especially during the pre-monsoon season.     

The effect of Arabian Sea optical properties on SST biases and the South Asian summer monsoon in a coupled GCM

This study examines the effect of seasonally varying chlorophyll on the climate of the Arabian Sea and South Asian monsoon. The effect of such seasonality on the radiative properties of the upper ocean is often a missing process in coupled general circulation models and its large amplitude in the region makes it a pertinent choice for study to determine any impact on systematic biases in the mean and seasonality of the Arabian Sea. In this study we examine the effects of incorporating a seasonal cycle in chlorophyll due to phytoplankton blooms in the UK Met Office coupled atmosphere-ocean GCM HadCM3. This is achieved by performing experiments in which the optical properties of water in the Arabian Sea—a key signal of the semi-annual cycle of phytoplankton blooms in the region—are calculated from a chlorophyll climatology derived from Sea-viewing Wide Field-of-View Sensor (SeaWiFS) data. The SeaWiFS chlorophyll is prescribed in annual mean and seasonally-varying experiments. In response to the chlorophyll bloom in late spring, biases in mixed layer depth are reduced by up to 50% and the surface is warmed, leading to increases in monsoon rainfall during the onset period. However when the monsoons are fully established in boreal winter and summer and there are strong surface winds and a deep mixed layer, biases in the mixed layer depth are reduced but the surface undergoes cooling. The seasonality of the response of SST to chlorophyll is found to depend on the relative depth of the mixed layer to that of the anomalous penetration depth of solar fluxes. Thus the inclusion of the effects of chlorophyll on radiative properties of the upper ocean acts to reduce biases in mixed layer depth and increase seasonality in SST.     

我国西北大气沙尘气溶胶的辐射效应

利用HEIFE地面辐射平衡观测资料和同期NOAA-11/AVHRR卫星遥感资料定量估算春季我国西北大气沙尘的辐射效应。大气沙尘减小地面净辐射冷却地面,对地-气系统和大气的辐射效应均与地表反照率有关,严重浑浊的沙尘大气在沙漠为短波加热和长波冷却,在绿洲则相反,但净效应都是加热。文中给出了4月大气浑浊度系数约由0.1增大到0.6,在沙漠和绿洲上空沙尘层（850～600 hPa）内大气的附加短波、长波和净加热/冷却率。     

PM10 data assimilation over south Korea to Asian dust forecasting model with the optimal interpolation method

A data assimilation (DA) system using ground PM₁₀ observation for Asian Dust Aerosol Model version 2 (ADAM2), which is the operational dust forecasting model of Korea Meteorological Administration (KMA), has been developed with the optimal interpolation (OI) method. The observations are provided by the PM₁₀ network operated by KMA. Three DA experiments are performed to simulate a dust event observed in Korea from 1 March to 31 May 2009 with different assimilation cycles of 24 (DA24), 12 (DA12), and 06 hours (DA06). 48-hour forecasts from the adjusted Initial Condition (IC) of dust concentration are compared with control simulation (CTL) and observation from independent stations. It is found that CTL simulates spatial patterns of dust emitted and transported associated with a developing low pressure system over the dust source regions quite well, compared with satellite measurement. However, it appears that there is considerable uncertainty in estimating the concentration of dust. With IC adjustment, the model simulates improved dust concentration, showing considerably reduced RMSE, particularly for the prediction within 12 hours of forecast. At the same time, it is shown that the time interval of DA affects the predictability of ADAM2, so that DA06 appears to have better predictability within a 12-hour simulation, reducing RMSE by 50% compared with CTL. This suggests that assimilating PM₁₀ to the dust prediction model using OI has the potential to predict air quality in Korea when the cycle of assimilation is sufficiently short.     

A simulation of Asian dust events observed from 20 to 29 December 2009 in Korea by using ADAM2

The Asian dust Aerosol Model 2 (ADAM2) with the MM5 meteorological model has been employed to study long-range transport process of Asian dust and to estimate dust emission, deposition (wet and dry) and concentration over the Asian dust source region and the downwind regions for dust events observed in Korea during the period of 20–29 December 2009, which is one of the dust events chosen by the 3^rd Meeting of Working Group for Joint Research on Dust Sand Storm among Mongolia, China, Japan and Korea to study intensively for the development of an early warning system in Asia. It is found that the model simulates quite well the starting and ending times of dust events and the peak dust concentrations with their occurrence times both in the source region and downwind regions. The dust emission in the dust source region is found to be associated with a developing synoptic weather system accompanied with strong surface winds over the source region that usually travels east to southeastward across the source region and then turns to move northeastward toward the north western Pacific Ocean. The dust emitted in the source region is found to be split into two parts: one is transported southeastward to the East China Sea in front of the surface high pressure system and experiencing enhanced deposition due to the sinking motion induced by the southeastward traveling the surface high pressure system whereas, the other moves northeastward toward the surface low pressure system and then lifted upward to form a upper-level high dust concentration layer that results in a favorable condition for the long-range transport of dust. It is also found that the maximum ten-day total dust emission of about 23 t km^?2 occurs in the domain Northwestern China (NWC). However, the maximum ten-day total dust deposition of 21 t km^?2 with the maximum mean surface concentration of 555 μg m^?3 and the column integrated mean concentration of 2.9 g m^?2 occurs in the domain Central-northern China (CNC). The column-integrated PM₁₀ concentration is found to increase toward northeastward especially in the domain North northeastern China (NNEC) due to the upper-level transported high PM₁₀ concentration. The ten-day total dust deposition, mean surface PM₁₀ and column integrated PM₁₀ concentrations in the downwind domains are found to decrease away from the source region from 2.44 t km^?2, 112 μg m^?3 and 1.68 g m^?2, respectively in the domain YES to 0.06 t km^?2, 2.1 μg m^?3 and 0.4 g m^?2, respectively in the domain Northwestern Pacific 1 (NWP1). Much of the total dust deposition is largely contributed by wet deposition in the far downwind region of the seas while that is contributed by dry deposition in the source region.