Climate model sensitivity to atmospheric CO2 concentrations for the middle Miocene

We present results of the first middle Miocene climate modelling study using the latest NCAR Community Atmosphere Model (CAM v.3.1) and Community Land Model (CLM v.3.0) coupled to a slab ocean. We examine the sensitivity of the middle Miocene climate to varying concentrations of atmospheric carbon dioxide (180, 355 and 700 ppm). Model simulations are forced with realistic Miocene boundary conditions for continental geometry, topography and vegetation. Global annual mean surface temperature increases by 2.2 °C with each successive doubling of CO₂ which is consistent with climate sensitivity of previous paleoclimate studies and estimates for future climate. In addition to growing evidence that tropical sea surface temperatures were higher than suggested by proxy-data, our understanding of middle to high latitude warming mechanisms is still incomplete. We compare our results to the late Miocene study of Steppuhn et al. [Steppuhn, A., Micheels, A., Bruch, A., Uhl, D., Utescher, T., Mosbrugger, V., 2007. The sensitivity of ECHAM4/ML to a double CO₂ scenario for the Late Miocene and the comparison to terrestrial proxy data. Global and Planetary Change, 57, 189–212] to explore the dependence of paleoclimate model sensitivities on different software systems and boundary conditions. Our comparison shows climate sensitivity to be overall quite robust — this is as significant, as it is often unclear to what extent simulation behaviour and outputs are dependent on a particular model implementation and initial/boundary conditions. Some distinct differences in model outputs, such as our reduced latitudinal surface temperature gradient and stronger Asian monsoon system, compared to the late Miocene study of Steppuhn et al. [Steppuhn, A., Micheels, A., Bruch, A., Uhl, D., Utescher, T., Mosbrugger, V., 2007. The sensitivity of ECHAM4/ML to a double CO₂ scenario for the Late Miocene and the comparison to terrestrial proxy data. Global and Planetary Change, 57, 189–212] are shown to be closely linked to the choice of topography, vegetation and ocean heat flux.     

The texture of condensed CO2 on the martian polar caps

The widespread deposition of CO₂ ice on the martian polar caps in winter is readily visible from Earth and has been extensively studied from orbit. As the surface cools during polar night, CO₂ condenses directly out of the atmosphere at a rate that establishes equilibrium between radiative loss and latent heat of condensation. Since radiative loss is strongly geometry-dependent, the CO₂ frost will grow most rapidly on exposed surfaces and more slowly in depressions. Positive feedback will cause a dramatic enhancement of the relief of the underlying topography and a corresponding reduction in the average bulk density. The resulting surface will be highly textured and riddled with perforations.     

Concatenation of HRSC colour and OMEGA data for the determination and 3D-parameterization of high-altitude CO2 clouds in the Martian atmosphere

We used Mars Express HRSC and OMEGA data to investigate mesospheric cloud features observed in the equatorial belt of Mars from December 2007 until early March 2008. This period corresponds to early northern spring of Martian year 29. The reflection peak at 4.26 μm in OMEGA data identifies the clouds as CO₂ ice clouds. HRSC observed the clouds together with OMEGA in five orbits. Cloud features are most prominent in the shortwave HRSC colour channels with wavelength centers at 440 and 530 nm, but rarely visible in all other channels. In the period of Ls 0-36°, OMEGA and HRSC together detected mesospheric CO₂ ice clouds in 40 orbits. They occur in a latitude belt of ±20° around the equator and at longitudes between 240°E (Tharsis) in the West and 30°E (Sinus Meridiani) in the East. The clouds were observed between 3 and 5 p.m. local time with mainly ripple-like to filamentary cloud forms. The viewing angles of the HRSC blue and green colour channels differ by 6.6° and the resulting parallax can be used to directly measure cloud heights by means of ray intersection. 17 HRSC data takes were found to exhibit clouds with heights from 66 to 83 km with an accuracy of 1-2 km. The pushbroom imaging technique also yields a time delay for the two observations in the order of 5-15 s close to periapsis, and therefore time-related cloud movements can be detected. A method was developed to determine the across-track cloud displacements, which can directly be translated to wind velocities. Zonal cloud movements could be measured in 13 cases and were oriented from East to West. Related wind speeds range between 60 and 93 m/s with an accuracy of 10-13 m/s.     

Half-widths, their temperature dependence, and line shifts for the HDO-CO2 collision system for applications to CO2-rich planetary atmospheres

Measurements of water vapor in the atmospheres of Venus or Mars by spectroscopic techniques in the infrared range are being made routinely by instruments onboard the Venus Express and the Mars Reconnaissance Orbiter. The interpretation of these measurements in the 2250-4450 cm⁻¹ region is being complicated by the presence of HDO lines absorbing radiation in this region. These spectra cannot be modeled properly because line shape parameters for CO₂ broadening (principal gas in these atmospheres) of HDO are not available. Here semi-classical line shape calculations for the HDO-CO₂ collision system are made using the Robert-Bonamy formalism for some 2300 rotational band transitions of HDO. From these calculations, the half-width, its temperature dependence, and the line shift are determined to aid in the reduction of the measured spectra. These data will greatly reduce the uncertainty of the reduced profiles from the Venus and Mars measurements and will also allow better estimates of the D/H ratio on these planets.     

An experimental study of the reaction kinetics of C2(XΣg) with hydrocarbons (CH4, C2H2, C2H4, C2H6 and C3H8) over the temperature range 24-300 K: Implications for the atmospheres of Titan and the Giant Planets

The reactivity of C₂(X¹Σ⁺_g) with simple saturated (CH₄, C₂H₆ and C₃H₈) and unsaturated (C₂H₂ and C₂H₄) hydrocarbons has been studied in the gas phase over the temperature range 24-300 K using the CRESU (Cinétique de Réaction en Ecoulement Supersonique Uniforme or Reaction Kinetics in a Uniform Supersonic Flow) technique. All reactions have been found to be very rapid in this temperature range and the rate coefficients are typically ?10⁻¹⁰ cm³ molecule⁻¹ s⁻¹ with the exception of methane for which the rate coefficient is one order of magnitude lower: ∼10⁻¹¹ cm³ molecule⁻¹ s⁻¹. These results have been analyzed in terms of potential destruction sources of C₂(X¹Σ⁺_g) in the atmospheres of Titan and the Giant Planets. It appears that the rate coefficient of the reaction ¹C₂ + CH₄ should be updated with our new data and that reactions with C₂H₂, C₂H₄ and C₂H₆ should also be included in the existing photochemical models.     

Simulated responses of Pinus halepensis forest productivity to climatic change and CO2 increase using a statistical model

Tree ring chronologies provide long-term records of growth in natural environmental conditions and may be used to evaluate impacts of climatic change and CO₂ increase on forest productivity. This study focuses on 21 Pinus halepensis forest stands in calcareous Provence (in the south-east of France). A chronology of net primary productivity (NPP) both for the 20th century and for each stand was estimated using tree ring data (width and density). The response of each stand to climate in terms of NPP was statistically modelled using response functions. Anomalies between estimated NPP and NPP reconstructed by response functions were calculated to evaluate the fertilising effect of CO₂ increase on tree growth. The changes in anomalies during the 20th century were attributed to the effect of CO₂ increase. A multiplying factor (β) linking CO₂ concentration and stand productivity was then calculated, on the basis of the trend observed during the 20th century. In this study, the value of the β factor obtained under natural conditions (β=0.50) is consistent with those from controlled CO₂ enrichment experiments. Both response functions and the β factor were used to predict NPP changes for a 2×CO₂ scenario. The 2×CO₂ climate was obtained using predictions from Météo France's ARPEGE atmospheric general circulation model (AGCM) downscaled to Marseilles meteorological station. NPP increased significantly for nine stands solely when the climatic effect was taken into account. The main factors responsible for this enhancement were increased winter and early spring temperatures. When the fertilising effect of the CO₂ increase was added, NPP was significantly enhanced for 14 stands (i.e. NPP enhancement ranged from 8% to 55%). Although the effects of global change were slightly detectable during the 20th century, their acceleration is likely to lead to great changes in the future productivity of P. halepensis forests.     

CO2 production by ion irradiation of H2O ice on top of carbonaceous materials and its relevance to the Galilean satellites

In this work we report on new experiments of ion irradiation of water ice deposited on top of solid carbonaceous materials to study the production of CO₂ at the interface ice/refractory material and discuss the possibility that this mechanism accounts for the quantity of CO₂ ice detected on the surfaces of the Galilean satellites. The used experimental technique has been in situ infrared spectroscopy. We have irradiated thin films of H₂O frost on carbonaceous layers with 200 keV of He⁺ and Ar⁺, and 30 keV of He⁺ at 16 and 80 K. The used carbonaceous layers have been asphaltite, a natural bitumen, and solid organic residues obtained by irradiation of frozen benzene. In both cases the results show that CO₂ is produced very efficiently after irradiation obtaining a maximum quantity of the order of . These results are, also quantitatively similar, to those recently obtained for water ice deposited on amorphous carbon films [Mennella, V., Palumbo, M.E., Baratta, G.A., 2004. Formation of CO and CO₂ molecules by ion irradiation of water ice covered hydrogenated carbon grains. Astrophys. J. 615, 1073-1080]. Thus we suggest that, whatever is the carbonaceous residue, CO₂ will be produced efficiently by the studied process. These results have interest in the context of the surfaces of the icy Galilean satellites in which CO₂ has been detected mainly trapped in the non-ice material, not in the pure water ice. We suggest that radiolysis of mixtures of water ice and refractory carbonaceous materials is the primary formation mechanism responsible for the CO₂ formation on the surfaces of the Galilean satellites.     

The radiolysis of SO2 and H2S in water ice: Implications for the icy jovian satellites

Spectra of Europa, Ganymede, and Callisto reveal surfaces dominated by frozen water, hydrated materials, and minor amounts of SO₂, CO₂, and H₂O₂. These icy moons undergo significant bombardment by jovian magnetospheric radiation (protons, electrons, and sulfur and oxygen ions) which alters their surface compositions. In order to understand radiation-induced changes on icy moons, we have measured the mid-infrared spectra of 0.8 MeV proton-irradiated SO₂, H₂S, and H₂O-ice mixtures containing either SO₂ or H₂S. Samples with H₂O/SO₂ or H₂O/H₂S ratios in the 3-30 range have been irradiated at 86, 110, and 132 K, and the radiation half-lives of SO₂ and H₂S have been determined. New radiation products include the H₂S₂ molecule and HSO⁻₃, HSO⁻₄, and SO²⁻₄ ions, all with spectral features that make them candidates for future laboratory work and, perhaps, astronomical observations. Spectra of both unirradiated and irradiated ices have been recorded as a function of temperature, to examine thermal stability and phase changes. The formation of hydrated sulfuric acid in irradiated ice mixtures has been observed, along with the thermal evolution of hydrates to form pure sulfuric acid. These laboratory studies provide fundamental information on likely processes affecting the outer icy shells of Europa, Ganymede, and Callisto.     

Methane on Uranus: The case for a compact CH4 cloud layer at low latitudes and a severe CH4 depletion at high-latitudes based on re-analysis of Voyager occultation measurements and STIS spectroscopy

Lindal et al. (Lindal, G.F., Lyons, J.R., Sweetnam, D.N., Eshleman, V.R., Hinson, D.P. [1987]. J. Geophys. Res. 92 (11), 14987-15001) presented a range of temperature and methane profiles for Uranus that were consistent with 1986 Voyager radio occultation measurements of refractivity versus altitude. A localized refractivity slope variation near 1.2 bars was interpreted to be the result of a condensed methane cloud layer. However, models fit to near-IR spectra found particle concentrations much deeper in the atmosphere, in the 1.5-3 bar range (Sromovsky, L.A., Irwin, P.G.J., Fry, P.M. [2006]. Icarus 182, 577-593; Sromovsky, L.A., Fry, P.M. [2010]. Icarus 210, 211-229; Irwin, P.G.J., Teanby, N.A., Davis, G.R. [2010]. Icarus 208, 913-926), and a recent analysis of STIS spectra argued for a model in which aerosol particles formed diffusely distributed hazes, with no compact condensation layer (Karkoschka, E., Tomasko, M. [2009]. Icarus 202, 287-309). To try to reconcile these results, we reanalyzed the occultation observations with the He volume mixing ratio reduced from 0.15 to 0.116, which is near the edge of the 0.033 uncertainty range given by Conrath et al. (Conrath, B., Hanel, R., Gautier, D., Marten, A., Lindal, G. [1987]. J. Geophys. Res. 92 (11), 15003-15010). This allowed us to obtain saturated mixing ratios within the putative cloud layer and to reach above-cloud and deep methane mixing ratios compatible with STIS spectral constraints. Using a 5-layer vertical aerosol model with two compact cloud layers in the 1-3 bar region, we find that the best fit pressure for the upper compact layer is virtually identical to the pressure range inferred from the occultation analysis for a methane mixing ratio near 4% at 5°S. This strongly argues that Uranus does indeed have a compact methane cloud layer. In addition, our cloud model can fit the latitudinal variations in spectra between 30°S and 20°N, using the same profiles of temperature and methane mixing ratio. But closer to the pole, the model fails to provide accurate fits without introducing an increasingly strong upper tropospheric depletion of methane at increased latitudes, in rough agreement with the trend identified by Karkoschka and Tomasko (Karkoschka, E., Tomasko, M. [2009]. Icarus 202, 287-309).     

Radiative decay of the 4d5(6S)5p z5,7Po states in Tc ii: comparison along the homologous and isoelectronic sequences. Application to astrophysics

Using three independent theoretical approaches (CA, HFR + CP, AUTOSTRUCTURE), oscillator strengths have been calculated for a set of Tc  ii transitions of astrophysical interest and the reliability of their absolute scale has been assessed. The examination of the spectra emitted by some Ap stars has allowed the identification of Tc  ii transitions in HD 125248. This Tc  ii detection should however await confirmation from spectral synthesis relying on dedicated model atmospheres. New partition functions are also provided for Tc  i , Tc  ii and Tc  iii for temperatures ranging between 4000 and 13 000 K.     

The high-pressure phase relation of the MgSO4-H2O system and its implication for the internal structure of Ganymede

We have determined the phase relation of the MgSO₄-H₂O binary system using an externally heated diamond anvil cell in the compositional range of 0-30 wt.% MgSO₄, and under temperature and pressure conditions from 298 to 500 K and up to 4.5 GPa. Using our experimental results, we were able to estimate the composition of the ice mantle of the large icy satellites of Jupiter, such as Ganymede.In our experiments, we identified the following phases in the MgSO₄-H₂O system up to 4 GPa at 298 K: Ices VI and VII, magnesium heptahydrate, MgSO₄·7H₂O, and a liquid phase. The present phase relations suggest that there may be a deep internal ocean down to a depth about 800 km in the interior of Ganymede.     

On the properties of O and O2 ions in a hybrid model and in Mars Express IMA/ASPERA-3 data: A case study

We have performed a numerical simulation to analyze the energy spectra of escaping planetary O⁺ and O₂⁺ ions at Mars. The simulated time-energy spectrograms were generated along orbit no. 555 (June 27, 2004) of Mars Express when its Ion Mass Analyzer (IMA)/ASPERA-3 ion instrument detected escaping planetary ions. The simulated time-energy spectrograms are in general agreement with the hypothesis that planetary O⁺ and O₂⁺ ions far from Mars are accelerated by the convective electric field. The HYB-Mars hybrid model simulation also shows that O⁺ ions originating from the ionized hot oxygen corona result in a high-energy (E>1 keV) O⁺ ion population that exists very close to Mars. In addition, the simulation also results in a low-energy (E<0.1 keV) planetary ion population near the pericenter. In the analyzed orbit, IMA did not observe a clear high-energy planetary ion or a clear low-energy planetary ion population near Mars. One possible source for this discrepancy may be the Martian magnetic crustal anomalies because MEX passed over a strong crustal field region near the pericenter, but the hybrid model does not include the magnetic crustal anomalies.     

A comparison of modeled and observed intensity profiles for C2, CN, and the blue continuum for Comet Bradfield (1987s)

Intensity profiles were obtained for the C₂ and CN emission and blue continuum of Comet Bradfield (1987s), from observations obtained over a 10 week period starting shortly before perihelion. Model intensity profiles were produced and then fitted to the observed profiles, and used to put constraints on some of the dust and gas parameters. Most of these parameters, including the gas and dust outflow speeds from the cometary nucleus and the molecular lifetimes, were consistent with expected values. The best fitting models incorporate significant dust particle fragmentation and extended emission of CN from dust, both occurring in the inner coma. In addition, although there may have been enhancement of gas and dust emission on the sunward side of the cometary nucleus, it appears that the tailward side maintained a significant level of activity.