Emission spectrographic determination of volatile trace elements in geologic materials by a carrier distillation technique

Trace levels of chalcophile elements that form volatile sulfide minerals are determined in stream sediments and in the nonmagnetic fraction of a heavy-mineral concentrate of stream sediments by a carrier distillation emission spectrographic method. Photographically recorded spectra of samples are visually compared with those of synthetic standards for the two sample types. Rock and soil samples may also be analyzed by comparison with the stream-sediment standards. A gallium oxide spectrochemical carrier/buffer enhances the early emission of the volatile elements.Detection limits in parts per million attained are: Sb 5, As 20, Bi 0.1, Cd 1, Cu 1, Pb 2, Ag 0.1, Zn 2, and Sn 0.1. A comparison with other methods of analysis, total-burn emission and atomic absorption spectroscopy, shows good correlation for standard reference for materials and samples from a variety of geologic terranes.     

Gondwanaland origin, dispersion, and accretion of East and Southeast Asian continental terranes

East and Southeast Asia is a complex assembly of allochthonous continental terranes, island arcs, accretionary complexes and small ocean basins. The boundaries between continental terranes are marked by major fault zones or by sutures recognized by the presence of ophiolites, mélanges and accretionary complexes. Stratigraphical, sedimentological, paleobiogeographical and paleomagnetic data suggest that all of the East and Southeast Asian continental terranes were derived directly or indirectly from the Iran-Himalaya-Australia margin of Gondwanaland. The evolution of the terranes is one of rifting from Gondwanaland, northwards drift and amalgamation/accretion to form present day East Asia. Three continental silvers were rifted from the northeast margin of Gondwanaland in the Silurian-Early Devonian (North China, South China, Indochina/East Malaya, Qamdo-Simao and Tarim terranes), Early-Middle Permian (Sibumasu, Lhasa and Qiangtang terranes) and Late Jurassic (West Burma terrane, Woyla terranes). The northwards drift of these terranes was effected by the opening and closing of three successive Tethys oceans, the Paleo-Tethys, Meso-Tethys and Ceno-Tethys. Terrane assembly took place between the Late Paleozoic and Cenozoic, but the precise timings of amalgamation and accretion are still contentious. Amalgamation of South China and Indochina/East Malaya occurred during the Early Carboniferous along the Song Ma Suture to form “Cathaysialand”. Cathaysialand, together with North China, formed a large continental region within the Paleotethys during the Late Carboniferous and Permian. Paleomagnetic data indicate that this continental region was in equatorial to low northern paleolatitudes which is consistent with the tropical Cathaysian flora developed on these terranes. The Tarim terrane (together with the Kunlun, Qaidam and Ala Shan terranes) accreted to Kazakhstan/Siberia in the Permian. This was followed by the suturing of Sibumasu and Qiangtang to Cathaysialand in the Late Permian-Early Triassic, largely closing the Paleo-Tethys. North and South China were amalgamated in the Late Triassic-Early Jurassic and finally welded to Laurasia around the same time. The Lhasa terrane accreted to the Sibumasu-Qiangtang terrane in the Late Jurassic and the Kurosegawa terrane of Japan, interpreted to be derived from Australian Gondwanaland, accreted to Japanese Eurasia, also in the Late Jurassic. The West Burma and Woyla terranes drifted northwards during the Late Jurassic and Early Cretaceous as the Ceno-Tethys opened and the Meso-Tethys was destroyed by subduction beneath Eurasia and were accreted to proto-Southeast Asia in the Early to Late Cretaceous. The Southwest Borneo and Semitau terranes amalgamated to each other and accreted to Indochina/East Malaya in the Late Cretaceous and the Hainanese terranes probably accreted to South China sometime in the Cretaceous.     

Geochemical evidence for a brooks range mineral belt, Alaska

Geochemical studies in the central Brooks Range, Alaska, delineate a regional, structurally controlled mineral belt in east—west-trending metamorphic rocks and adjacent metasedimentary rocks. The mineral belt extends eastward from the Ambler River quadrangle to the Chandalar and Philip Smith quadrangles, Alaska, from 147° to 156°W. longitude, a distance of more than 375 km, and spans a width from 67° to 69°N. latitude, a distance of more than 222 km. Within this belt are several occurrences of copper and molybdenum mineralization associated with meta-igneous, metasedimentary, and metavolcanic rocks; the geochemical study delineates target areas for additional occurrences.A total of 4677 stream-sediment and 2286 panned-concentrate samples were collected in the central Brooks Range, Alaska, from 1975 to 1979. The −80 mesh (< 177 μm) stream sediment and the heavy (specific gravity > 2.86) nonmagnetic fraction of the panned concentrates from stream sediment were analyzed by semiquantitative spectrographic methods.Two geochemical suites were recognized in this investigation; a base-metal suite of copper-lead-zinc and a molybdenum suite of molybdenum-tin-tungsten. These suites suggest several types of mineralization within the metamorphic belt. Anomalies in molybdenum with associated Cu and W suggest a potential porphyry molybdenum system associated with meta-igneous rocks. This regional study indicates that areas of metaigneous rocks in the central metamorphic belt are target areas for potential mineralized porphyry systems and that areas of metavolcanic rocks are target areas for potential massive sulfide mineralization.     

Association of specific organic matter compounds in size fractions of soils under different environmental controls

Inherent chemical recalcitrance and association of organic matter (OM) with minerals are mechanisms responsible for the long term preservation of OM in soils. The structural characteristics of OM are also believed to control specific interactions between OM and soil minerals. However, the extent of the relationship between recalcitrance and mineral protection and the specificity of these chemically driven interactions are not clearly understood at the molecular level. To measure chemical patterns of OM sequestration in sand-, silt-, clay-size and light fractions, we analyzed three soils, which mainly differed in carbon content and overlying vegetation, but have similar clay mineralogy, using biomarker analysis and nuclear magnetic resonance (NMR). Despite differences in environmental controls, long chain aliphatic compounds generally accumulated in the fine fractions of all soils. This accumulation is likely due to the strong interaction between recalcitrant forms of OM and soil minerals. For example, polymethylene and >C₂₀ organic acids accumulated in fine fractions, while lignin-derived phenols were protected from oxidation in silt-size fractions. Diffusion edited solution state ¹H NMR suggested that contributions from microbial-derived OM was greater in finer fractions, which is likely due to the accumulation of microbial-derived compounds or higher microbial activity in clay micro-sites. Our data suggest that, for these Prairie soils, the specific structure of OM and not environmental factors is responsible for long term preservation of OM in mineral fractions. Further research is necessary to understand the interplay between these preservation mechanisms such that the long term fate of OM can be further elucidated.     

The Grenville orogenic cycle of southern Laurentia: Unraveling sutures,rifts, and shear zones as potential piercing points for Amazonia

The magnetic anomaly map of North America serves as a useful base from which to attempt palinspastic reconstruction of terranes accreted during the Elzevirian orogeny (1250–1200 Ma); the Shawinigan (1200–1150 Ma), Ottawan (1080–1020 Ma), and Rigolet (1020–1000 Ma) phases of the Grenvillian orogeny; and post-Grenvillian magmatism (760–600 Ma) and deformation prior to Iapetan rifting at 565 Ma. Accreted terranes had unique histories prior to amalgamation and share common tectonic events afterwards. Comparisons with magnetic signatures of the Paleozoic craton–craton suture, sutures of accreted terranes, and the Jurassic rifted-margin for the southern-central Appalachians provide a basis for discriminating among alternative Grenvillian sutures beneath the Appalachian orogen.The Elzevirian suture is partially preserved beneath the Appalachians where it separates the Reading Prong terrane from Laurentia (i.e., Adirondacks and composite-arc terrane and Canadian Grenville Province). The Shawinigan suture is partially preserved in the Llano area (Texas), but separated the now-fragmented and allochthonous Amazonian (as indicated from Pb-isotope data) blocks of the outboard Blue Ridge terrane from the Reading Prong terrane in the Appalachians. Isolated blocks of the Sauratown Mountains terrane are interpreted as outboard of the Blue Ridge terrane, but were also accreted during the Shawinigan phase. Within present-day Laurentia, the only fragment of a terrane believed to have been accreted during the main Ottawan phase is the Mars Hill terrane (North Carolina–Tennessee). This suggests that the outboard Ottawan suture may have served as the locus of Iapetan rifting along much of Laurentia. The Rigolet phase (1020–1000 Ma) is characterized by widespread “Basin and Range” type extension (NW–SE) associated with sinistral or dextral movement on the NY-AL lineament, mobilization of core-complexes (Adirondack Highlands), and AMCG magmatism along the outboard flank of the extensional region. Following the Rigolet phase, the Appalachian region continued to be characterized by NW–SE extension during the passage of a possible hotspot along a NE-track (760–600 Ma) across the Blue Ridge and other terranes, and during initial Iapetan rifting (565 Ma). The palinspastic rifted-margin of Laurentia crosses many of these terranes and sutures as well as the possible region of Rigolet extension and the possible hotspot track, thus providing many potential piercing points within the Grenville orogen for comparison with Paleozoic terranes like the Precordillera in South America.     

Physical protection of lignin by organic matter and clay minerals from chemical oxidation

The role of organic matter (OM) concentration, structure and composition and how these relate to mineral protection is important for the understanding of long term soil OM dynamics. Various OM–clay complexes were constructed by sequential sorption of lignin and dodecanoic acid to montmorillonite. Humic acid–montmorillonite complexes were prepared at pH 4 and 7 to vary OM conformation prior to sorption. Results obtained with constructed OM–clay complexes were tested with isolated mineral fractions from two soils. Oxidation with an acidic NaClO₂ solution was used to chemically oxidize lignin in the OM–clay complexes, sand-, silt- and clay-size soil fractions to test whether or not it can be protected from chemical attack. Gas chromatography–mass spectrometry was used to analyze lignin-derived phenols, cutin OH–acid (after CuO oxidation), fatty acid and n-alkanol concentrations and composition. We found that carbon content was not solely responsible for lignin stability against chemical oxidation. Lignin was protected from chemical oxidation through coating with dodecanoic acid and sorption of humic acid to clay minerals in a stretched conformation at pH 7. Therefore, interactions between OM constituents as well as OM conformation are important factors that protect lignin from chemical oxidation. Lignin-derived phenol dimers in the Grassland-Forest Transition soil fractions were protected from chemical oxidation to a greater extent compared to those in Grassland soil fractions. Therefore, although lignin was protected from degradation through mineral association, the extent of this protection was also related to OM content and the specific stability of lignin components.     

The effect of filtration on analyses of surface water samples. A study from the Salars of Coipasa and Uyuni,Bolivian Altiplano

Analyses by inductively coupled plasma atomic emission spectrometry (ICP-AES), inductively coupled plasma mass spectrometry (ICP-MS) and cold vapour atomic absorption (for Hg, CVAA) of a wide range of elements in some 300 surface water samples from the Salar de Uyuni and Salar de Coipasa catchments of the Bolivian Altiplano have been undertaken. Comparison of analyses of acidified aliquots of unfiltered sample water with water filtered at 0.45 μm reveals that the following elements are not affected significantly by filtration in this high-pH environment: B, Ca, Li, Mg, K, Si, Na, Sr, S. The following elements appear to experience significantly elevated concentrations in unfiltered samples, relative to filtered: Al, (As to a minor extent), Ba, Be, Cd, Cr, Co, Cu, Fe, Pb, Mn, Hg, Ni, P, Ag, Tl, Ti, V. The effect appears to be related to the presence, and subsequent dissolution in acid preservative, of Fe-, Al-or Mn-oxyhydroxide flocs (or coatings on silicate particles) in unfiltered samples, and their retention or precipitation on filters.     

Elemental Concentrations in Nine New GSJ Rock Reference Samples "Sedimentary Rock Series"

Nine new rock reference samples of the "Sedimentary rock series", Chert JCh-1, Dolomite JDo-1, Lake sediment JLk-1, Limestone JLs-1, Stream sediments JSd-1 to JSd-3, and Slates JS1-1 and JSl-2 have been prepared by the Geological Survey of Japan(GSJ). Thirty major, minor and trace elements were determined using atomic absorption spectrometry, flame emission spectrometry, infrared absorption spectrometry and wet chemical techniques. The results of homogeneity tests showed that almost all elements, with a few exceptions, are considered to be distributed homogeneously in each reference sample.     

The nature of geomagnetic anomalies in metamorphosed chromite-bearing dunites: a case study of the southern Klyuchevskoy complex,Central Urals

Chromite mineralization in metamorphosed dunites from the southern Klyuchevskoy dunite-harzburgite ultramafic complex (Central Urals) has been investigated using geomagnetic surveys along with laboratory studies of ore-forming and accessory spinels of the same genetic type. Magnetization in the study area is carried mainly by accessory Fe-Cr-spinel of a variable Fe^2 +(Cr_2 -xFe_x^3 +)O₄ composition. Metamorphism caused changes in element contents and in both crystal and magnetic structure of the primary nonmagnetic accessory spinel, unlike the almost fresh ore-forming spinel. Thus, ore bodies stand against their host rocks, which is a prerequisite for the use of geomagnetic surveys for exploration of podiform chromite deposits in dunite-harzburgite complexes. Ground magnetic surveys at a test site composed of faulted rocks bearing disseminated chromite mineralization in metamorphosed dunites resolved a chromite ore zone and a fault block boundary showing up as geomagnetic anomalies. Laboratory studies using high technologies (thermomagnetic analysis at 4 to 1000 K, as well as magnetic resonance and magnetic force spectroscopy) revealed, for the first time, magnetic clusters (superparamagnetic phases) in primary nonmagnetic accessory spinel, which are responsible for the magnetic properties of the host rocks. Microscale variations in Cr-spinel correlate with the geomagnetic anomalies recorded by field surveys at the test site._{© 2015, V.S. Sobolev IGM, Siberian Branch of the RAS. Published by Elsevier B.V. All rights reserved.}     

Shear strength of soils containing amorphous clay-size materials in a slow-moving landslide

The shear behavior of soils rich in amorphous clay-size materials was not well reported in the literature. This study analyzed the direct shear and ring shear test data of soil samples containing 55–74% amorphous materials in the clay fraction from a slow-moving landslide in eastern Honolulu, HI. The direct shear test results showed that the undisturbed soil samples when not sheared internally had peak cohesion (c) of about 50 kPa and internal friction angle (Ø) of about 10°. This implies that the amorphous clay-size materials provided strong interparticle bonds for the soils. Breaking of the bonds during the softening process and redistribution of the amorphous clay-size materials were primarily responsible for the drop from the peak strength to the residual strength (c=0, Ø=10° from back calculation with SLOPE/W and c=0, Ø=5–7° from the ring shear test). The drained residual failure envelope is stress dependent due to the interaction of the gel-like amorphous clay-size materials with crystalline silt- and sand-sized particles. The amorphous clay-size materials act as the contact between crystalline particles. The contact increases with increasing consolidation stress, resulting in a decrease in the shear strength and the residual friction angle.     

Paleozoic accretionary terranes in Northern Tianslian, NW China

During the paleozoic,the Northern Tianshan region of China in Central Asia consists of 7 allochthonous terranes which were situated in the ancient sino-Mongolian Ocean as volcanic arcs and splitted continental fragments.The tectonic framework was similar to that of Southwest pacific today,In the Late Paleozoic,these terranes started mutual amalgamation to cause strong thrusting.At thd end of Carboniferous,the Sino-mongolian ocean including several inter-terrane small sea basins closed and these terranes accreted on the margins of the Siberian and Tarim continents,The 6 ophiolitic zones zomong the terranes recorded this collision event.     

http://www.sciencedirect.com/science/article/pii/S1674987111001125

<正>Greenstone belts of the eastern Dharwar Craton,India are reinterpreted as composite tectonostratigraphic terranes of accreted plume-derived and convergent margin-derived magmatic sequences based on new high-precision elemental data.The former are dominated by a komatiile plus Mg-tholeiitic basalt volcanic association,with deep water siliciclastic and banded iron formation(BIF) sedimentary rocks.Plumes melted at90 km under thin rifted continental lithosphere to preserve inlraoceanic and continental margin aspects.Associated alkaline basalts record subduction-recycling of Mesoarchean oceanic crust,incubated in the asthenosphere.and erupted coevally with Mg basalts from a heterogeneous mantle plume.Together.komaliites-Mg basalts-alkaline basalts plot along the Phanerozoic mantle array in Th/Yb versus Nb/Yb coordinate space,representing zoned plumes,establishing that these reservoirs were present in the Neoarchean mantle. Convergent margin magmatic associations are dominated by tholeiitic to calc-alkaline basalts eompositionally similar to recent intraoceanic arcs.As well,boninitic flows sourced in extremely depleted mantle are present,and the association of arc basalts with Mg-andesites-Nb enriched basalts-adakites documented from Cenozoic arcs characterized by subduction of young(20 Ma),hot,oceanic lithosphere. Consequently.Cenozoic style "hot" subduction was operating in the Neoarchean.These diverse volcanic associations were assembled to give composite terranes in a subduction-accretion orogen at～2.1 Ga,coevally with a global accretionary orogen at ~2.7 Ga,and associated orogenic gold mineralization. Archean lithospheric mantle,distinctive in being thick,refractory,and buoyant,formed complementary to the accreted plume and convergent margin terranes.as migrating arcs captured thick plumeplateaus. and the refractory,low density.residue of plume melting coupled with accreted imbricated plume-arc crust.     

环境样品中钼的测定方法进展

根据多年来国内对钼的测定方法的研究报道,对环境样品中钼的主要测定方法进行总结,常用方法有分光光度法、催化极谱法、原子吸收分光光度法、ICP—AES法及ICP-MS等,分析了它们的优缺点,有利于选择适宜的测定方法。     

Cryptic tectonic domains of the Klamath Mountains, California and Oregon

Numerous fragments of oceanic crust and island arcs make up the Klamath Mountains province. These fragments were joined together (amalgamated) in an oceanic setting during Paleozoic and Mesozoic collisional events and were accreted to North America as a composite unit during latest Jurassic or earliest Cretaceous time. The roughly arcuate and concentric distribution of the terranes of the Klamath Mountains does not now seem to be a result of simple oroclinal bending as earlier believed. Although commonly described as a west-facing arcuate structure, the province is cut diagonally by a vaguely defined NW-trending zone of discontinuity, or hinge line, that divides the province into NE and SW tectonic domains. The zone of discontinuity is marked by a number of lithic and structural anomalies, and particularly by the distribution of a remarkable series of belts of plutonic rocks. The terranes, regional structures, and plutonic belts of the NE domain trend NE and are generally wider and more coherent than the narrow NW-trending terranes and plutonic belts of the SW domain. Most plutonic belts of the NE domain do not have equivalents in the SW domain. Paleomagnetic evidence suggests that all the plutonic belts, except possibly the youngest (the earliest Cretaceous Shasta Bally belt), were emplaced before the Klamath Mountains terranes finally accreted to North America.     

无机多元素现代仪器分析技术

本文重点介绍地质领域目前广泛应用的无机多元素现代仪器分析技术,包括电感耦合等离子体原子发射光谱(ICP-AES)、电感耦合等离子体质谱(ICP-MS)、X射线荧光光谱(XRF)、原子吸收光谱(AAS)、原子荧光光谱(AFS)、电子探针分析技术和共享平台的建立、激光剥蚀等离子体质谱(LA-ICP-MS)微区原位分析技术以...     

广东凡口铅锌矿区灰岩风化土壤指示元素富集粒度及存在形式研究

通过广东凡口铅锌矿区灰岩风化残积土壤指示元素富集粒度和存在形式的研究,证实了指示元素在粗、细两端元粒级富集的倾向。但小于200目的细粒级富集稳定性更好。建议将野外直接过200目筛网的土样送交分析。证实了铁锰氧化物是指示元素的主要载体相。锰氧化物比铁氧化物更富集成矿元素。采用土壤重砂的电磁性部分作为样品介质或采用部分提取的方法,均可提高土壤地球化学异常衬度和分析灵敏度。     

Geochemistry of stream sediments along the western coast of the Gulf of Elat (Aqaba)

One hundred twenty-eight samples of heavy-mineral fractions from sand-size sediments whose mineralogy was previously studied by A. Ayalon, were chosen for this geochemical study. The samples represent the stream sediments along the coastal belt from Elat to Sherm el-Sheikh. This study supplements the geochemical study of A. Zilberfarb and R. Bogoch on the Precambrian terrain of Sinai.The mineral composition of the samples was determined by X-ray diffraction and optical microscopy. In all samples, 14 elements were analyzed: B, Co, Cr, Cu, Ga, Mn, Mo, Nb, Ni, Pb, Sn, Ti, V and Zr. Seven magnetic fractions were separated from twenty of these samples and in these fractions 14 to 20 elements were analyzed, according to the sample. The chemical determinations were mainly by DC emission spectrography.The results were submitted to factor analysis and to association analysis (D. Gill and co-workers). Since the environment is typically arid, there is relatively little chemical weathering. The combined results of both statistical analyses show clearly that three types of source areas can be differentiated: sandstone, metamorphic and granitic terrain. Furthermore, a distinct Mn anomaly was found in the Sherm el-Sheikh area.     

泡塑吸附-电感耦合等离子体发射光谱法测定矿石中的金

试样在650℃烧制、王水溶解、泡塑振荡吸附、硫脲解脱,用电感耦合等离子体发射光谱法测定矿石中的金量,克服了原子吸收光谱法对低含量金测定稳定性和精密度差、对高含量金测定分取误差大和返工率高等不足,缩短了分析时间。方法经国家一级标准物质分析验证,结果与标准值相符。对二级标准物质测定的方法精密度(RSD,n=12)为6.45%。方法检出限为0.138μg/g,线性范围宽,适用于矿石中0.2μg/g以上金的测定。     

Precious metal enrichment in the Platreef,Bushveld Complex,South Africa: evidence from homogenized magmatic sulfide melt inclusions

Magmatic sulfide deposits are the most significant source of platinum-group elements (PGE) in the world. Key to understanding their genesis is determining the processes and timing of sulfide saturation, metal enrichment and crustal contamination. In this study, we have identified droplets of magmatic sulfide from the Platreef, South Africa, where droplets of sulfide have been trapped in the earliest crystallising phase, chromite. Due to their early entrapment at high temperatures, metal concentrations and ratios that they display are indicative of a very early-stage sulfide liquid in the system, as they will have cooled and fractionated within an essentially closed system, unlike interstitial blebs that crystallise in an open system as the magma cools. Analysis of these droplets in an opaque mineral like chromite by LA-ICP-MS is problematic as some of the fractionated inclusion is necessarily lost during cutting and polishing to initially identify the inclusion. This particularly affects the ability to representatively sample the most fractionated phases such as gold and platinum minerals. Here, using a novel technique whereby the inclusions are homogenized and quickly quenched, so that any cutting, polishing and subsequent LA-ICP-MS analysis samples a truly representative portion of the droplet. This has been used to show that early sulfide liquids in the Platreef were highly PGE-rich and had Pt/Pd ratios of close to unity that supports genetic models invoking sulfide saturation and metal enrichment prior to intrusion, with pre-enriched sulfides entrained within the Platreef magma.     

石英包裹体中液相成分的测定

文章简要介绍了石英包裹体样品的清洗、打开、成分的提取过程，列出采用离子色谱、原子吸收、感耦等离子体发射光谱、感耦等离子体质谱法测定液相各成分的流程及部分分析结果。