Crack Coalescence in Molded Gypsum and Carrara Marble: Part 2—Microscopic Observations and Interpretation

Experimental uniaxial compression loading tests were conducted on molded gypsum and Carrara marble prismatic specimens to study the cracking and coalescence processes between pre-existing artificial flaws. The study showed that material had an influence on the cracking and coalescence processes (see the companion paper in this issue). As reported in the companion paper, one of the pronounced features as observed in the high-speed video recordings was the development of macroscopic white patches prior to the development of observable cracks in marble, but not in gypsum. This paper (part 2) deals with the microscopic aspects of the study. Specifically, the scanning electron microscope (SEM) and the environmental scanning electron microscope (ESEM) imaging techniques were used to study the microscopic development of white patches and their evolution into macroscopic tensile cracks and shear cracks in marble, and the microscopic initiation of hair-line tensile cracks and their evolution into macroscopic tensile cracks in gypsum. The microscopic imaging study in marble showed that the white patches were associated with extensive microcracking zones (process zones), while the extent of process zone development in gypsum was limited. The comparison of the macroscopic and microscopic results indicates that the different extent of microcracking zone development, related to the material textural properties, is a key factor leading to different macroscopic cracking behavior in gypsum and marble.

Hydrogen and carbon isotope studies on the graphite-bearing metapelites in the northern Kiso district of central Japan

Measurements were made of the hydrogen isotope ratios of hydrous silicates (mica and amphibole) and whole rocks, and the carbon isotope ratios of graphite and carbonaceous matter in the metamorphic rocks from the northern Kiso district in central Japan.D values of hydrous silicates in the graphite-bearing metapelites are always higher than those in graphite-free schists, even though the sample localities of the two rock-types are very close. Hydrogen isotopic equilibrium has been attained between the coexisting minerals.D/H ratios of water in the metamorphic fluids seem to depend strongly on the presence or absence of graphite and seem to be not constant throughout the district. The district is divided into three areas of low (metamorphic zones I, II), medium (zones IIIa–V) and high ¹³C_gr value (zones VIa–VII) areas. In the high ¹³C_gr values area, the carbon contents of the graphite-bearing rocks decrease slightly from zones VIa to VII, whereas the ¹³C_gr values increase sharply from the upper part of zone VIa to VIb. TheD values of biotite in these graphite-bearing rocks are higher than those in the medium ¹³C_gr area. This suggests that methane enriched inH and¹²C is produced and liberated by the devolatilization reactions between muscovite, graphite and water. The fluid produced is composed of water, methane and a subordinate amount of carbon dioxide, and its logfO₂ value is deduced to be about 1.2 lower than that defined by the FMQ buffer. In the medium ¹³C_gr area, the ¹³C values of graphite are nearly constant (–20.8), while the Fe₂O₃/(Fe₂O₃ + FeO) ratio of the graphite-bearing rocks apparently decreases with increasing metamorphic grade.D differences in hydrous silicates between graphite-bearing and graphite-free rocks are observed. These facts are interpreted to mean that methane was produced in addition to water and carbon dioxide, and that its generation ( ratio of the fluid was about 2) had practically no isotope effect on the graphite. In the low ¹³C_gr area, the carbon contents of the rocks decrease clearly from zones I to IIIa. TheD and ¹³C_gr values of the non-metamorphosed shales are much lower than those of the low grade graphite-bearing metapelites. This suggests that methane is produced and liberated from the rocks even at the incipient stage of metamorphism.     

Assessment of suffosion-related hazards in karst areas using GIS technology

This paper describes an application of the geographic information system (GIS) technology to a ground stability assessment in the karst area of Dzerzhinsk, Russia. In the stability analysis, the groundwater level changes in the karst aquifer could cause suffosion sinkholes when the gravitational force was greater than the soil strength. The GIS technology was used to combine various data and to delineate the zones of potential gravitational collapse and suffosion collapse in the area.

Magmatism-related localized deformation in the mantle: a case study

A deformed composite peridotite-pyroxenite xenolith in Pliocene alkali basalts from the Pannonian Basin (Szentbékkálla, Bakony—Balaton Highland Volcanic Field) has been studied in detail. A narrow shear zone of intense deformation marked by porphyroclast elongation and recrystallization runs along the peridotite-pyroxenite contact. The xenolith contains a large volume of euhedral olivine neoblasts and tablet grains of olivine away from the shear zone interpreted as products of annealing and recrystallization in the presence of grain boundary fluid. Estimates of the time required for growth of recrystallized olivine grains suggest that the annealing took place in situ in the mantle and not during transport of the xenolith in the basalt magma. The grain boundary fluid present during recrystallization was a vapor rich silicate-melt different from the host basaltic melt that entrained the xenolith. This study demonstrates that high-stress deformation zones and associated fluid-assisted recrystallization, which are common features in kimberlite mantle xenoliths, also occur in some mantle xenoliths from alkali basalts. The suggested high-stress deformation zones in the mantle beneath the Pannonian Basin may be produced by paleoseismic events in the lithosphere associated with faulting related to the ascent of basalt magma.Editorial responsibility: J. Hoefs

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Characterizing vertical contaminant distribution in a thick unconfined aquifer,Hanford site,Washington, USA

Drilling-intensive aquifer characterization techniques have been used to obtain depth-discrete water samples from a thick, hydrogeologically continuous unconfined aquifer system; groundwater results indicate that carbon tetrachloride contamination is widespread and extends deeper and at concentrations much higher than detected in monitoring networks at the water table. Carbon tetrachloride, a legacy waste, was used in the plutonium extraction process at the Hanford site in south-central Washington State. Vertical, depth-discrete groundwater samples were collected during well drilling throughout a 28-km² region to determine the concentration of carbon tetrachloride present as a dissolved phase in the aquifer. Results indicate that high concentrations of carbon tetrachloride, three orders of magnitude above the allowable regulatory limit, are present at depths greater than 25 m beneath the water table. In support of future efforts to remediate the carbon tetrachloride contamination, it is imperative to locate the remaining chemical inventory, determine the vertical as well as the lateral distribution of this contaminant and its physical form. Depth-discrete aquifer characterization throughout the uppermost-unconfined aquifer system is providing this information and improving the understanding of the contaminant distribution and the hydrogeologic framework through which it moves.

夹皮沟剪切带化学成分演化研究

野外地质填图及室内工作表明,夹皮沟剪切带可以划分为早期韧性剪切带(>2500Ma)和晚期脆—韧性剪切带(2000～1600Ma).韧性剪切作用是在角闪岩相条件下形成,以位错、扩散蠕变变形为主,体系内岩石成分与体积基本保持不变,为封闭体系,与矿化关系不密切.脆—韧性剪切作用形成一系列片糜岩,岩石以微破裂及溶解—沉淀变形为主,体系内岩石成分与体积都发生变化,为开放体系,与矿化关系密切.韧性及脆—韧性剪切带的基础岩石是长英质片麻岩,但脆—韧性剪切带被韧性剪切带所限定,并在韧性剪切带基础上形成.     

Sex offenders,housing and spatial restriction zones

Sex offenders are currently a major focus of crime control policies at the local, regional, state and federal levels throughout the United States. In part, the perceived threat of offender recidivism has motivated legislators to launch stringent community notification programs and to establish spatial restriction zones (SRZs) around schools, daycare facilities and public parks. The purpose of these restriction zones is to help protect children and minimize their exposure to convicted sex offenders living in the community. In addition to the concern that the implementation of SRZs dramatically reduces viable housing options for registered sex offenders, there are concerns that offenders will be forced to reside in socially disorganized areas that may encourage recidivism. The purpose of this paper is to explore the demographic and socioeconomic differences between areas inside and outside SRZs. Implications of these results for sex offender policies are discussed.

Implications of subsurface thermal–hydraulic–mechanical processes associated with glaciation on Shield flow system evolution and performance assessment

A deep geologic repository (DGR) situated on the Canadian Shield will be subject to long-term climate change that will markedly alter surface conditions as a result of glaciation and permafrost penetration. Systematic, two-dimensional and three-dimensional coupled thermal–hydraulic–mechanical finite-element simulations with varying degrees of coupling, including depth-dependent salinity (represented as a change in groundwater density) and temperature-dependent density and viscosity, were undertaken to address the implications of glaciation on groundwater flow system dynamics as it could affect DGR performance. The modelling domain consisted of a 1.6-km deep sub-regional scale (≈100 km²) fractured Shield flow system. Initial and transient thermal, hydraulic and mechanical boundary conditions were developed from two realizations of the University of Toronto Glacial Systems Model of the last Laurentide glaciation. Results indicate that during the glacial loading/unloading cycle, for this particular conceptual model, there is limited penetration of glacial meltwaters to depth and small residual anomalous hydraulic head. During glacial coverage, the mechanical factor of safety increases in the moderately fractured and sparsely fractured rock mass, but principal effective stress reorientation also occurs. Given the assumed nonglacial in situ state of stress and mechanical properties, the fracture zones were predicted to be less stable under glacial conditions.

Separation of rifting and lithospheric folding signatures in the NW-Alpine foreland

The development of the Alpine mountain belt has been governed by the convergence of the African and European plates since the Late Cretaceous. During the Cenozoic, this orogeny was accompanied with two major kinds of intraplate deformation in the NW-European foreland: (1) the European Cenozoic Rift System (ECRIS), a left-lateral transtensional wrench zone striking NNE-SSW between the western Mediterranean Sea and the Bohemian Massif; (2) long-wavelength lithospheric folds striking NE and located between the Alpine front and the North Sea. The present-day geometry of the European crust comprises the signatures of these two events superimposed on all preceding ones. In order to better define the processes and causes of each event, we identify and separate their respective geometrical signatures on depth maps of the pre-Mesozoic basement and of the Moho. We derive the respective timing of rifting and folding from sedimentary accumulation curves computed for selected locations of the Upper Rhine Graben. From this geometrical and chronological separation, we infer that the ECRIS developed mostly from 37 to 17 Ma, in response to north-directed impingement of Adria into the European plate. Lithospheric folds developed between 17 and 0 Ma, after the azimuth of relative displacement between Adria and Europe turned counter-clockwise to NW–SE. The geometry of these folds (wavelength = 270 km; amplitude = 1,500 m) is consistent with the geometry, as predicted by analogue and numerical models, of buckle folds produced by horizontal shortening of the whole lithosphere. The development of the folds resulted in ca. 1,000 m of rock uplift along the hinge lines of the anticlines (Burgundy–Swabian Jura and Normandy–Vogelsberg) and ca. 500 m of rock subsidence along the hinge line of the intervening syncline (Sologne–Franconian Basin). The grabens of the ECRIS were tilted by the development of the folds, and their rift-related sedimentary infill was reduced on anticlines, while sedimentary accumulation was enhanced in synclines. We interpret the occurrence of Miocene volcanic activity and of topographic highs, and the basement and Moho configurations in the Vosges–Black Forest area and in the Rhenish Massif as interference patterns between linear lithospheric anticlines and linear grabens, rather than as signatures of asthenospheric plumes.

Ab initio study of the high-pressure behavior of CaSiO3 perovskite

Using density functional simulations, within the generalized gradient approximation and projector-augmented wave method, we study structures and energetics of CaSiO₃ perovskite in the pressure range of the Earths lower mantle (0–150 GPa). At zero Kelvin temperature the cubic CaSiO₃ perovskite structure is unstable in the whole pressure range, at low pressures the orthorhombic (Pnam) structure is preferred. At 14.2 GPa there is a phase transition to the tetragonal (I4/mcm) phase. The CaIrO₃-type structure is not stable for CaSiO₃. Our results also rule out the possibility of decomposition into oxides.

Determining the equivalent permeability tensor for fractured rock masses using a stochastic REV approach: Method and application to the field data from Sellafield,UK

A numerical procedure to determine the equivalent permeability tensor of a fractured rock is presented, using a stochastic REV (Representative Elementary Volume) concept that uses multiple realizations of stochastic DFN (Discrete Fracture Network) models. Ten square DFN models are generated using the Monte Carlo simulations of the fracture system based on the data obtained from a site characterization program at Sellafield, Cumbria, UK. Smaller models with varying sizes of from 0.25 m×0.25 m to 10 m×10 m are extracted from the generated DFN models and are used as two-dimensional geometrical models for calculation of equivalent permeability tensor. The DFN models are also rotated in 30º intervals to evaluate the tensor characteristics of calculated directional permeability. Results show that the variance of the calculated permeability values decreases significantly as the side lengths of the DFN models increase, which justifies the existence of a REV. The REV side length found in this analysis is about 5 m and 8 m with 20% and 10% acceptable variations, respectively. The calculated directional permeability values at the REV size have tensor characteristic that is confirmed by a close approximation of an ellipse in a polar plot of the reciprocal of square roots of the directional permeability.

Regional-scale Proterozoic IOCG-mineralized breccia systems: examples from the Wernecke Mountains, Yukon, Canada

A large scale Proterozoic breccia system consisting of numerous individual breccia bodies, collectively known as Wernecke Breccia, occurs in north-central Yukon Territory, Canada. Breccias cut Early Proterozoic Wernecke Supergroup sedimentary rocks and occur throughout the approximately 13 km thick deformed and weakly metamorphosed sequence. Iron oxide–copper–gold ± uranium ± cobalt mineralization is associated with the breccia bodies and occurs as veins and disseminations within breccia and surrounding rocks and locally forms the breccia matrix. Extensive sodic and potassic metasomatic alteration occurs within and around breccia bodies and is overprinted by pervasive calcite and dolomite/ankerite, and locally siderite, alteration, respectively. Multiple phases of brecciation, alteration and mineralization are evident. Breccia bodies are spatially associated with regional-scale faults and breccia emplacement made use of pre-existing crustal weaknesses and permeable zones. New evidence indicates the presence of metaevaporitic rocks in lower WSG that may be intimately related to breccia formation. No evidence of breccia-age magmatism has been found to date.

Modelling of rock temperatures for deep alpine tunnel projects

The construction of deep railway tunnels requires the prediction of natural temperatures at depth. Geothermal data for the Alps are presented and principles of previously employed methods to predict temperatures, using Andreae's analytical approach, are discussed. We then use a finite element numerical model based on pure conduction to calculate temperatures at depth. This method allows rock heterogeneity and anisotropy to be taken into account.This model is applied to the Maurienne-Ambin tunnel project, a 55 km long tunnel between St-Jean-de-Maurienne (France) and Susa (Italy), which will be the longest tunnel for the planned TGV (high speed train) Lyon-Torino link. Data from several deep boreholes (10 total, with 3>1000 m) are used to provide essential parameters for the model, i.e.:

A redox profile of the Slave mantle and oxygen fugacity control in the cratonic mantle

The authors report a redox profile based on Mössbauer data of spinel and garnet to a depth of 210 km from mantle xenoliths of the northern (N) and southeastern (SE) Slave craton (northern Canada). The profile transects three depth facies of peridotites that form segments of different bulk composition, represented by spinel peridotite, spinel–garnet peridotite, low-temperature garnet peridotite, high-temperature garnet peridotite, and pyroxenite. The shallow, more depleted N Slave spinel peridotite records lower oxygen fugacities compared to the deeper, less depleted N Slave spinel–garnet peridotite, consistent with their different spinel Fe³⁺ concentrations. Garnet peridotites show a general reduction in log fO₂ (FMQ)s with depth, where values for garnet peridotites are lower than those for spinel–garnet peridotites. There is a strong correlation between depletion and oxygen fugacity in the spinel peridotite facies, but little correlation in the garnet peridotite facies. The strong decrease in log fO₂ (FMQ) with depth that arises from the smaller partial molar volume of Fe³⁺ in garnet, and the observation of distinct slopes of log fO₂ (FMQ) with depth for spinel peridotite compared to spinel–garnet peridotite strongly suggest that oxygen fugacity in the cratonic peridotitic mantle is intrinsically controlled by iron equilibria involving garnet and spinel.

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Hydrology of the coastal sabkhas of Abu Dhabi, United Arab Emirates

Water fluxes were estimated and a water budget developed for the land surface and a surficial 10-m-deep section of the coastal sabkhas that extend from the city of Abu Dhabi, United Arab Emirates, west to the border with Saudi Arabia. The fluxes were estimated on the basis of water levels and hydraulic conductivities measured in wells and evaporation rates measured with a humidity chamber. In contrast with conceptual models proposed in earlier studies, groundwater inflow is estimated to be small, whereas the largest components of the water budget are recharge from rainfall and evaporation from the water table. Estimates within a rectilinear volume of sabkha, defined as 1 m wide by 10 km long by 10 m deep, indicate that about 1 m³/year of water enters and exits by lateral groundwater flow; 40–50 m³/year enters by upward leakage; and 640 m³/year enters by recharge from rainfall. Based on the water and solute fluxes estimated for the upward leakage into the sabkha, 7–8 pore volumes of brine have entered the sabkha from below since the time the sabkha became saturated (7,000 years ago) as a result of the last global sea-level rise.

New data on the Neoproterozoic – Cambrian geotectonic setting of the Teplá-Barrandian volcano-sedimentary successions: geochemistry,U-Pb zircon ages,and provenance (Bohemian Massif,Czech Republic)

The Teplá-Barrandian unit (TBU) of the Bohemian Massif was a part of the Avalonian-Cadomian belt at the northern margin of Gondwana during Neoproterozoic and Early Cambrian times. New detrital zircon ages and geochemical compositions of Late Neoproterozoic siliciclastic sediments confirm a deposition of the volcano-sedimentary successions of the TBU in a back-arc basin. A change in the geotectonic regime from convergence to transtension was completed by the time of the Precambrian-Cambrian boundary. The accumulation of around 2,500 m Lower Cambrian continental siliciclastics in a Basin-and-Range-type setting was accompanied by magmatism, which shows within-plate features in a few cases, but is predominantly derived from anatectic melts displaying the inherited island arc signature of their Cadomian source rocks. The geochemistry of clastic sediments suggests a deposition in a rift or strike-slip-related basin, respectively. A marine transgression during Middle Cambrian times indicates markedly thinned crust after the Cadomian orogeny. Upper Cambrian magmatism is represented by 1,500 m of subaerial andesites and rhyolites demonstrating several geochemical characteristics of an intra-plate setting. Zircons from a rhyolite give a U-Pb-SHRIMP age of 499±4 Ma. The Cambrian sedimentary and magmatic succession of the TBU records the beginning of an important rifting event at the northern margin of Gondwana.

Using resistivity measurements for dam safety evaluation at Enemossen tailings dam in southern Sweden

Internal erosion is a major reason for embankment dam failures. Resistivity measurements is an essentially non-destructive technique, which may have the possibility of detecting internal erosion processes and anomalous seepage at an early stage before the safety of the dam is at stake. This paper presents results from part of a dam safety investigation conducted at the Enemossen tailings dam in southern Sweden. Longitudinal resistivity sections, 2D measurements along the dam crest, provided an overview of the whole dam and served to detect anomalous zones. In selected areas, additional cross-sectional 2D surveys gave detailed information about the geo-electrical situations in the embankments. This information is valuable for similar investigations as information about resistivity in embankment construction material is scarce. Known problem areas were associated with low resistivities, even though the resistivity measurements alone did not provide enough information to confidently come to a decision about the status of the dams.

Identification of sinkhole development mechanism based on a combined geophysical study in Nahal Hever South area (Dead Sea coast of Israel)

Seismic refraction, magnetic resonance sounding (MRS), and the transient electromagnetic (TEM) method were applied to investigate the geological and hydrogeological conditions in the Nahal Hever South sinkhole development area at the Dead Sea (DS) coast of Israel. Microgravity and MRS results reliably reveal large karst cavity in the central part of investigated area. The map of the seismic velocity shows that sinkholes in Nahal Hever can be divided into two major groups: sinkholes close to the salt edge and sinkholes over compact salt formations between a few tens to a hundred meters from the major cavern. The present study shows that the formation of sinkholes of the first group is caused by soil collapsing into the cavern. In the area occupied by sinkholes of the second group, karst was not detected either by MRS or by seismic diffraction methods. TEM results reveal shallow clay layer saturated with DS brine underlain sinkholes of this group. It allows suggestion that the water drainage and intensive water circulation during rain events wash out fine rock particles from the unsaturated zone into the pre-existing cavern, initiating the formation of sinkholes of the second group. Karst development takes place at a very low bulk resistivity (<1 Ω m) of the DS aquifer, attesting to the fact that pores are filled with a highly saline solution. Refilling of the karstic cavities with collapsing and flushed soil slows down sinkhole development in the area. The sinkhole formation cycle at the site is estimated at 10 years. Sinkhole development throughout the studied area is triggered by a drop in the level of the DS, which reduces the head of the confined aquifer and the strength of the overlain sediments.

Mapping flood pressure points: assessing vulnerability of the UK Fire Service to flooding

A vulnerability index for the Fire Service in the UK has been designed to identify vulnerable locations during episodes of severe floods. Taking recent case studies with the UK Fire Service, the patterns of vulnerability, in terms of demand on time and resources, can be explained by investigating the environmental causes and their interaction with the adaptive capacity of the response agencies.

Predicting environmental conditions to minimise salt damage at the Tower of London: a comparison of two approaches

The paper compares the results of two studies of salt damage at the Wakefield Tower, Tower of London. The first, in 1993, was based on semi-quantitative salt analysis and hygroscopicity measurements. The second was based on quantitative analysis and a thermodynamic model, ECOS. Both studies aimed to predict environmental conditions that would minimise salt damage to the interior stonework. Their predictions are markedly different, and this paper examines the reasons for the differences. It is shown that hygroscopicity alone is not a reliable indicator of crystallisation from mixed salt solutions.