Le cordon sableux Limani-Yagoua, extrême-nord Cameroun, et son rôle hydraulique

The Limani-Yagoua mega sand-ridge, covering an area of 330,000 km² is well know in the extreme north of Cameroun. Similar structures have also been described in the Chad Republic (Bongor-Koro-Toro), Niger (Tal) and Nigeria (Bama). Two possible origins can be considered: (i) circum-lacustrine around the Lake Chad Basin, interpreted as a Holocene or Pleistocene palæo-shoreline, or (ii) æolian accumulation as a mega sand dune in an area of basin subsidence. The sand-ridge in northern Cameroun is an extremely permeable aquifer with discharge rates of 3–6 m³ h⁻¹. High nitrate levels (27–127 mg l⁻¹) have been observed in several boreholes. Tritium at 4.1 ut indicates recent groundwater recharge, suggesting infiltration of rainfall damned by the sand-ridge.     

Groundwater recharge estimation using chloride,stable isotopes and tritium profiles in the sands of northwestern Senegal

A study of environmental chloride, deuterium, oxygen-18, and tritium in deep sand profiles (35 m) has been carried out in order to estimate their relative value for measuring average groundwater recharge. The investigation was located at a 0.1-km² site in Quaternary sands near the northwestern coast of Senegal in a zone of rainfed agriculture. By using a steady-state model for duplicate unsaturated zone chloride profiles, the long-term average recharge at the site was estimated to be 30 mm yr^–1 or around 10% of the average precipitation (290 mm). The chloride concentration of adjacent shallow groundwater was relatively uniform and comparable to the unsaturated zone average, while the spatial variability in the depth distribution of Cl^– in the unsaturated zone was considerable. Stable isotope (deuterium and oxygen-18) data show that there is some isotopic enrichment due to direct evaporation through the soil surface. The degree of heavy isotope enrichment is proportional to the extent of evaporative loss and there is good correspondance with the chloride enrichment. Nevertheless, stable isotopes cannot be used quantitatively to estimate the recharge. The excellent preservation of the peak in thermonuclear tritium in precipitation in the unsaturated zone at depths between 12 and 20 m enables an estimated annual recharge of 24 mm yr^–1 in this area to be calculated, using the piston flow model. Agreement therefore between Cl and³H as tools for recharge measurement is reasonable over the site.     

Assessment of surface water potential and groundwater recharge in ungauged watersheds: a case study in Tamil Nadu,India

Many of the states in India have been facing water scarcity for more than 2 decades due to increased demand, because of the increase in population and higher living standards. Consequently, many states have almost fully utilized the available surface water resources and are exploiting groundwater to augment water supplies. Investigations were carried out in the upper Thurinjalar watershed of Ponnaiyar basin in Tamil Nadu to determine the availability of surface water and to investigate the potential for enhancing groundwater recharge to support the water demand in the watershed. Increasing the water availability would also enable the community to convert the 46% of the land area in the watershed that is currently underutilised into productive uses. The surface water potential for the upper Thurinjalar watershed was assessed by applying the USDA–NRCS model with daily time steps. This modelling exercise indicated that the annual runoff from the 323 km² area of the watershed is 61 million m³. Groundwater recharge in the watershed was assessed by carrying out daily water balance method and indicated that about 43 million m³ of water from recharge is available on an annual basis or about 14% of annual rainfall. A simple regression model was developed to compute groundwater recharge from rainfall based on water balance computations and this was statistically verified. The modelling indicated that there is sufficient water available in the watershed to support current land uses and to increase the productivity of underutilised land in the area. The study also demonstrates that simple regression models can be used as an effective tool to compute groundwater recharge for ungauged basins with proper calibration.     

Groundwater flow modelling of Hindon-Yamuna interfluve region, Western Uttar Pradesh

The study area Hindon -Yamuna interfluve region is underlain by a thick pile of unconsolidated Quaternary alluvial deposits and host multiple aquifer system. Excessive pumping in the last few decades, mainly for irrigation, has resulted in a significant depletion of the aquifer. Therefore, proper groundwater management of Hindon-Yamuna interfluve region is necessary. For effective groundwater management of a basin it is essential that careful zone budget study should be carried out. Keeping this in view, groundwater flow modelling was attempted to simulate the behavior of flow system and evaluate zone budget. Visual MODFLOW, pro 4.1 is used in this study to simulate groundwater flow. The model simulates groundwater flow over an area of about 1345 km² with a uniform grid size of 1000 m by 1000 m and contains three layers, 58 rows and 37 columns. The horizontal flows, seepage losses from unlined canals, recharge from rainfall and irrigation return flows were applied using different boundary packages available in Visual MODFLOW, pro 4.1. The river — aquifer interaction was simulated using the river boundary package. Simulated pumping rates of 500 m³/day, 1000 m³/day and 1500 m³/day were used in the pumping well package.The zone budget for the steady state condition of study area indicated that the total annual direct recharge is 416.10 MCM and the total annual groundwater draft through pumping is of the order of 416.63 MCM. Two scenarios were considered to predict aquifer system response under different conditions. Sensitivity analysis on model parameters was conducted to quantitatively evaluate the impact of varying model inputs. Based on the results obtained from the sensitivity analysis, it was found that the model is more sensitive to hydraulic conductivity and recharge parameter. Present study deals with importance of groundwater modelling for planning, design, implementation and management of groundwater resources.     

Use of chloride-mass balance and environmental isotopes for evaluation of groundwater recharge in the alluvial aquifer, Wadi Tharad, western Saudi Arabia

Groundwater recharge estimation has become a priority issue for humid and arid regions, especially in regions like Saudi Arabia, where the precipitation varies over space and time as a result of topography and seasonality. Wadi Tharad is a typical arid area in western Saudi Arabia. Within its drainage area of 400 km², the groundwater system shows a graded hydrochemical zonation from the hydrocarbonate in the upper reach to the chloride zone in the lower reach. The saturation index (SI) varies depending on the concentrations of carbonate minerals; the mean for calcite and dolomite is about in equilibrium (e.g., zero value). As halite and gypsum indices are negative, it is undersaturated. Isotopic compositions of H and O in the groundwater show that the groundwater recharge resources are mainly from meteoric water. The chloride-mass balance method was refined to estimate the amount of recharge, which is probably 11% of the effective annual rainfall. These results can be used to improve the accuracy of future groundwater management and development schemes.     

Evaluating the impact of artificial groundwater recharge structures using geo-spatial techniques in the hard-rock terrain of Rajasthan,India

Groundwater levels in hard-rock areas in India have shown very large declines in the recent past. The situation is becoming more critical due to a paucity of rainfall, limited surface water resources and an increasing pattern of groundwater extraction in these areas. Consequently, the Ground Water Department with the aid of World Bank has implemented the water structuring programme to mitigate groundwater scarcity and to develop a viable solution for sustainable development in the region. The present study has been undertaken to assess the impact of artificial groundwater recharge structures in the hard-rock area of Rajasthan, India. In this study groundwater level data (pre-monsoon and post-monsoon) of 85 dug-wells are used, spread over an area of 413.59 km². The weathered and fractured gneissic basement rocks act as major aquifer in the area. Spatial maps for pre- and post-monsoon groundwater levels were prepared using the kriging interpolation technique with best fitted semi-variogram models (Spherical, Exponential and Gaussian). The groundwater recharge is calculated spatially using the water level fluctuation method. The entire study period (2004–2011) is divided into pre- (2004–2008) and post-intervention (2009–2011) periods. Based on the identical nature of total monsoon rainfall, two combinations of average (2007 and 2009) and more than average (2006 and 2010) rainfall years are selected from the pre- and post-intervention periods for further comparisons. All of the water harvesting structures are grouped into the following categories: as anicuts (masonry overflow structure); percolation tanks; subsurface barriers; and renovation of earthen ponds/nadis. A buffer of 100 m around the intervention site is taken for assessing the influence of these structures on groundwater recharge. The relationship between the monsoon rainfall and groundwater recharge is fitted by power and exponential functions for the periods of 2004–2008 and 2008–2011 with R ² values of 0.95 and 0.98, respectively. The average groundwater recharge is found to be 18% of total monsoon rainfall prior to intervention and it became 28% during the post-intervention period. About 70.9% (293.43 km²) of the area during average rainfall and more than 95% (396.26 km²) of the area during above-average rainfalls show an increase in groundwater recharge after construction of water harvesting structures. The groundwater recharge pattern indicates a positive impact within the vicinity of intervention sites during both average and above-average rainfall. The anicuts are found to be the most effective recharge structures during periods of above-average rainfall, while subsurface barriers are responded well during average rainfall periods. In the hard-rock terrain, water harvesting structures produce significant increases in groundwater recharge. The geo-spatial techniques that are used are effective for evaluating the response of different artificial groundwater recharge techniques.     

Identification of potential groundwater recharge zones in Vaigai upper basin,Tamil Nadu,using GIS-based analytical hierarchical process (AHP) technique

Groundwater recharge is an important process for the management of both surface and subsurface water resources. The present study utilizes the application of analytical hierarchical process (AHP) on geospatial analysis for the exploration of potential zones for artificial groundwater recharge along Vaigai upper basin in the Theni district, Tamil Nadu, India. The morphology of earth surface features such as geology, geomorphology, soil types, land use and land cover, drainage, lineament, and aquifers influence the groundwater recharge in either direct or indirect way. These thematic layers are extracted from Landsat ETM+ image, topographical map, and other collateral data sources. In this study, the multilayers were weighed accordingly to the magnitude of groundwater recharge potential. The AHP technique is a pair-wise matrix analytical method was used to calculate the geometric mean and normalized weight of individual parameters. Further, the normalized weighted layers are mathematically overlaid for preparation of groundwater recharge potential zone map. The results revealed that 21.8 km² of the total area are identified as high potential for groundwater recharge. The gentle slope areas in middle-east and central part have been moderately potential for groundwater recharge. Hilly terrains in south are considered as unsuitable zone for groundwater recharge processes.     

Karst groundwater management by defining protection zones based on regional geological structures and groundwater flow fields

In a semiarid region, the karst aquifer generally forms a large groundwater reservoir that can play an important role in regional water supply. But because of the specific physical properties of karst aquifers, they are vulnerable to pollution and anthropogenic impacts. Karst groundwater management strategies are vital. As representative of karst springs in a semiarid area, Niangziguan Springs is located in the east of Shanxi Province, China with an annual average rate of discharge of 10.34 m³/s (1956–2003) (Y. Liang, unpublished data). The Niangziguan Spring Basin covers an area of 7,394 km² with an annual average precipitation of 535 mm (1958–2003) (Hao et al. in Carsologica Sinica 23(1):43–47, 2004). Over the past three decades, accelerated groundwater exploitation has caused water-table decline in the aquifer, reduction of the spring discharge, and deterioration of water quality. In this study, three protection zones were defined to ensure the quality and capacity of this resource. The confluence of the 11 spring systems and the discharge areas were defined as I protection zone, the recharge basin was II protection zone, and the slack water area where there is little surface recharge was the III protection zone. Management strategies for each zone were suggested and evaluated to provide a scientific foundation for sustainable utilization.     

Numerical Modeling of the Seasonal Dynamic Characteristics of the Koxkar Glacier,in West Tianshan,China

Landslides commonly occurs in hilly areas and causes an enormous loss iof life and property every year. National highway-1D (NH-1D) is the only road link between the two districts (Kargil and Leh) of Ladakh region that connects these districts with Kashmir valley. The landslide failure record of the recent past along this sector of the highway is not available. The present study documents landslide susceptible zones and records occurrence of 60 landslides during the last 4 years showing an increasing trend in the occurrence of landslides over these years in this sector. The landslide susceptibility zonation map has been prepared based on the numerical rating of ten major factors viz. slope morphometry, lithology, structure, relative relief, land cover, landuse, rainfall, hydrological conditions, landslide incidences and Slope Erosion, categorised the area in different zones of instability based on the intensity of susceptibility. The landslide susceptibility map of the area encompassing 73.03 km² is divided into 150 facets. Out of the total of 150 facets, 85 facets fall in low susceptibility zone covering 43.56 km2 which constitute about 59.65% of the total area under investigation with a record of 5 landslides; 40 facets fall in the moderate susceptibility zone covering 16.94km² which constitutes about 23.19% of the study area with a record of 20 landslides; and 25 facets fall in the high susceptibility zone covering 12.53 km² which constitute about 17.15% of the study area with a record of 35 landslides. Most of the facets which fall in HSZ are attributed to slope modification for road widening.     

Recharge mechanism and processes controlling groundwater chemistry in a Precambrian sedimentary terrain: a case study from Central India

Unplanned and unsustainable extraction has created stress on groundwater resources in many parts of India. The stress symptoms are more pronounced in hard rock areas, where the aquifer potentials are comparatively low. Present research targeted an area of 3000 km² in the interstream region between the Kharun and Seonath rivers, which is one such region in Central India. In spite of being a water-stressed area, so far, little is understood about processes of recharge, amount of recharge and processes controlling chemical quality, which are key inputs for groundwater management in the area. This study presents an appraisal of recharge mechanism, recharge rate and prevailing water–rock interactions in the study area. Stable isotope composition of groundwater when compared to that of rainfall indicates monsoon rainfall as the primary source of groundwater recharge. Winter rains, which are characteristically enriched in heavier isotopes, do not contribute notably to groundwater recharge. Recharge is rapid with minor or no evaporative enrichment before recharge. Further, analysis of stable isotopes show that ‘macropore recharge’ is dominant in limestone or calcareous shale, covering more than 70% of the study area. Also apparent is the vertical connectivity amongst the aquifers. However, active intermixing of surface water and groundwater is not a predominant process. Annual groundwater recharge from rainfall, as derived from chloride mass balance, is 105.26 million cubic metre. Groundwater is predominantly of bicarbonate type, irrespective of its hydrostratigraphic (lithology) setting. Dissolution of carbonates and gypsum (occurring as veins), weathering of feldspar and ion exchange of clay minerals are amongst the most likely processes controlling the regional groundwater chemistry.     

Using CRD method for quantification of groundwater recharge in the Gaza Strip, Palestine

Rainfall is the main source of groundwater recharge in the Gaza Strip area in Palestine. The area is located in the semi-arid zone and there is no source of recharge other than rainfall. Estimation of groundwater recharge from rainfall is not an easy task since it depends on many uncertain parameters. The cumulative rainfall departure (CRD) method, which depends on the water balance principle, was used in this study to estimate the net groundwater recharge from rainfall. This method does not require much data as is the case with other classical recharge estimation methods. The CRD method was carried out using optimisation approach to minimise the root mean square error (RMSE) between the measured and the simulated groundwater head. The results of this method were compared with the results of other recharge estimation methods from literature. It was found that the results of the CRD method are very close to the results of the other methods, but with less data requirements and greater ease of application. Based on the CRD method, the annual amount of groundwater recharge from rainfall in the Gaza Strip is about 43 million m³. An erratum to this article can be found at     

Conflicts between wetland conservation and groundwater exploitation: Two case histories in Spain

The problems in two Spanish national parks located on wetlands are analyzed. The hydrogeological and ecological characteristics of the two parks are somewhat different as are their respective degrees of deterioration. The Tablas de Daimiel National Park is located on the Central Plateau of Spain. It used to consist of a marshy area of about 20 km² around the confluence of two relatively small rivers. The area was marshy mainly because it was the natural discharge zone for a Tertiary aquifer system about 100 m thick extending over an area of some 5,000 km², composed of calcareous and detrital material of continental origin. The average annual recharge has been estimated at approximately 350 hm³/yr. Current groundwater withdrawal is around 450 hm³/yr, mainly used to irrigate a surface area of some 1,000 km². This overdevelopment has led to a continuous depletion of the regional water table and eventually to the drying out of the marshy area. Spontaneous combustion or fires caused by man have occurred in about 10 km² of the desiccated areas since the spring of 1986. The Doñana National Park is located on the estuary of the River Guadalquivir. The aquifer system of the Lower Guadalquivir estuary consists essentially of a permeable formation of unconsolidated Plioquaternary materials with an area of some 3,000 km². Under the marshy area (about 1,800 km²) the aquifer system is confined below low-permeability estuary deposits which can be over 100 m thick. Around most of the marshland the aquifer crops out and is recharged by rain. The Doñana National Park is over 700 km² in size, part of which is in the marshland and part in the recharge area where the aquifer is phreatic. In the 1970s Spain's largest irrigation project using groundwater, covering a surface area of 240 km², was planned in an area bordering on the national park. The initial project has been scaled down considerably as a result of protests by conservation groups. However, it seems likely that the water table depletion as a result of pumpage for irrigation could cause a large part of the ecotone situated at the contact-line between the marshland and the phreatic aquifer to disappear. This ecotone exists because it is a natural groundwater dischange area.     

Geochemical approach to estimate the quality of water entering abandoned underground coalmines

Geochemical modeling was employed to estimate the chemistry of water infiltrating into abandoned underground flooded and unflooded coalmines of the Uniontown syncline, Fayette County, Pennsylvania. This was done to help evaluate factors governing the long-term evolution of coalmine discharge water quality in the Uniontown syncline area. The subsurface structure and lithology was delineated using borehole, mine shaft, and stratigraphic information. Hydrogeologic analyses indicated that most of the recharge to mine voids occurs in the zones of shallow overburden cover of less than 20 m in thickness. The water–rock contact period in the recharge areas of the overburden was estimated to be 5 days or greater for the flooded mines, and a day or less for the unflooded mines. Flow-through reaction-path models were applied to the topsoil and shale–sandstone lithological units identified in the recharge areas. The model predicted water entering the flooded mines at a pH of 6.65, alkalinity of 6.92 mequiv. l^–1 and a total sulfate concentration of 7.33 mM, and the unflooded mines at a pH of 6.68, alkalinity of 6.99 mequiv. l^–1 and a total sulfate concentration of 3.08 mM. The model predictions for the flooded and unflooded mines are consistent with groundwater data from the study site, indicating the usefulness of this approach in evaluating the contribution of overburden chemistry to the evolution of mine discharge quality.     

Analysis of subsurface temperature data to quantify groundwater recharge rates in a closed Altiplano basin,northern Chile

Quantifying groundwater recharge is a fundamental part of groundwater resource assessment and management, and is requisite to determining the safe yield of an aquifer. Natural groundwater recharge in arid and semi-arid regions comprises several mechanisms: in-place, mountain-front, and mountain-block recharge. A field study was undertaken in a high-plain basin in the Altiplano region of northern Chile to quantify the magnitude of in-place and mountain-front recharge. Water fluxes corresponding to both recharge mechanisms were calculated using heat as a natural tracer. To quantify in-place recharge, time-series temperature data in cased boreholes were collected, and the annual fluctuation at multiple depths analyzed to infer the water flux through the unsaturated zone. To quantify mountain-front recharge, time-series temperature data were collected in perennial and ephemeral stream channels. Streambed thermographs were analyzed to determine the onset and duration of flow in ephemeral channels, and the vertical water fluxes into both perennial and ephemeral channels. The point flux estimates in streambeds and the unsaturated zone were upscaled to channel and basin-floor areas to provide comparative estimates of the range of volumetric recharge rates corresponding to each recharge mechanism. The results of this study show that mountain-front recharge is substantially more important than in-place recharge in this basin. The results further demonstrate the worth of time-series subsurface temperature data to characterize both in-place and mountain-front recharge processes.     

Geotechnical characterization of lignite-bearing horizons in the Afsin-Elbistan lignite basin, SE Turkey

The Afsin-Elbistan lignite deposit, with its 3.4 billion metric tons of reserves, is the biggest lignite basin and one of the most important resources for electrical energy production in Turkey. Kislakoy mining field was selected as the first opencast mine to feed four power station blocks of 300 MW each. Slope instability has been a continuing problem in the Kislakoy opencast mine. Particularly complex failures along a noncircular failure surface appearing at the final slope stage and covering large areas in the mine increase the importance of slope stability. This study outlines the geotechnical characteristics of the lignite-bearing horizons and describes the causes and mechanisms of slope instabilities, which threaten the safety of the mine. Quantitative X-ray diffraction (XRD) analyses were carried out using an interactive data processing system (SIROQUANT™) based on Rietveld interpretation methods. Parametric slope stability analysis and backanalysis were carried out for the failure that occurred at the northwestern final slope stage of the mine. The Spencer-Wright limiting state equilibrium method was used in order to determine with confidence the most representative values of regional shear strength parameters, to explain the failure mechanism, and to assess the conditions at the time of failure. In the analysis, phreatic and piezometric surfaces were considered.Site observations and numerous backanalyses of the slope failure reveal that a compound slide occurred where gyttja (contact zone) layers rest directly on the lignite. Gyttja (contact zone) contains the weakest material within the system. The analysis showed that the main cause of the northwestern slope instability was the presence of the groundwater flow within a Quaternary aquifer (through buried valleys), reducing the effective shear strength of the slope materials. It is also noted from backanalysis that the gyttja (contact zone) layer presents a shear strength at, or approaching, the residual value at the time of failure.     

Estimation of groundwater recharge using a GIS-based distributed water balance model in Dire Dawa, Ethiopia

Sustainable groundwater management requires knowledge of recharge. Recharge is also an important parameter in groundwater flow and transport models. Spatial variation in recharge due to distributed land-us.e, soil texture, topography, groundwater level, and hydrometeorological conditions should be accounted for in recharge estimation. However, conventional point-estimates of recharge are not easily extrapolated or regionalized. In this study, a spatially distributed water balance model WetSpass was used to simulate long-term average recharge using land-use, soil texture, topography, and hydrometeorological parameters in Dire Dawa, a semiarid region of Ethiopia. WetSpass is a physically based methodology for estimation of the long-term average spatial distribution of surface runoff, actual evapotranspiration, and groundwater recharge. The long-term temporal and spatial average annual rainfall of 626 mm was distributed as: surface runoff of 126 mm (20%), evapotranspiration of 468 mm (75%), and recharge of 28 mm (5%). This recharge corresponds to 817 l/s for the 920.12 km² study area, which is less than the often-assumed 1,000 l/s recharge for the Dire Dawa groundwater catchment.     

Middle Eocene ostracoda from the Tadkeshwar lignite mine, Cambay Basin, Gujarat

Previous work on the fauna and flora of the Cambay shale underlying as well as inter-bedded within the lignite seams of Vastan lignite mine, Gujarat allows the shale to be assigned a Lower Eocene age. However, there is no record of occurrence of any fossil from the sedimentary beds succeeding the shale-lignite sequence that might fix upper age limit of the Cambay shale. We record a characteristic Middle Eocene ostracod assemblage from the Nummulitic marl/limestone, immediately overlying the shale-lignite sequence from the Tadkeshwar lignite mine close to the Vastan lignite mine. The assemblage comprises 22 species, many of which widely occur in the Middle Eocene beds of Kachchh, Rajasthan and adjacent areas of Pakistan.     

Groundwater potential for irrigation in the East Oweinat area,Western Desert Egypt

The Nubia Sandstone aquifer system is one of the most extensive groundwater systems in North Africa, covering an area of about 2,000,000 km², including parts of Egypt, Libya, Sudan, and Chad. In the Western Desert of Egypt, the Nubian formation has a thermal gradient of 1.1–5°C 100 m^–1 with the exception of the East Oweinat area, located in the southern part of the Western Desert. This is the only part of this huge system where ground-water occurs under unconfmed conditions in an area where the Nubian sandstone crops out and is underlain by shallow basement rocks; in this area groundwater has no thermal characteristics. The aquifer system in the East Oweinat area attains a relatively high hydraulic conductivity. The direction of groundwater flow is generally northeastwards but is distorted at faults and fracture zones. Chemical analyses of groundwater in the area indicate a low salt content and suitability for irrigation purposes. As the estimated recharge to the area is low compared with the foreseen irrigation water requirement, the development of groundwater in the East Oweinat should be based on groundwater mining. Although the evaluation of the groundwater resources in East Oweinat has indicated that groundwater can be extracted at a rate of 4.7×10⁶ m³ d^–1, the long-term economics of extraction that can sustain large-scale development projects has to be assessed.     

Groundwater recharge history and hydrogeochemical evolution in the Minqin Basin, North West China

The Minqin Basin is a type area for examining stress on groundwater resources in the Gobi Desert, and has been investigated here using a combination of isotopic, noble gas and chemical indicators. The basin is composed of clastic sediments of widely differing grain size and during the past half century over 10 000 boreholes have been drilled with a groundwater decline of around 1 m a⁻¹. Modern diffuse recharge is unlikely to exceed 3 mm a⁻¹, as determined using unsaturated zone profiles and Cl⁻ mass balance. A small component of modern (<50 a) groundwater is identified in parts of the basin from ³H–³He data, probably from irrigation returns. A clear distinction is found between modern waters with median δ¹⁸O values of 6.5 ± 0.5‰ and most groundwaters in the basin with more depleted isotopic signatures. Radiocarbon values as pmc range from 0.6% to 85% modern, but it is difficult to assign absolute ages to these, although a value of 20% modern C probably represents the late Pleistocene to Holocene transition. The δ¹³C compositions remain near-constant throughout the basin (median value of −8.1‰ δ¹³C) and indicate that carbonate reactions are unimportant and also that little reaction takes place. There is a smooth decrease in ¹⁴C activity accompanied by a parallel increase in ⁴He accumulations from S–N across the basin, which define the occurrence of a regional flow system. Noble gas temperatures indicate recharge temperatures of about 5.6 °C for late Pleistocene samples, which is some 2–3 °C cooler than the modern mean annual air temperature and the recharge temperature obtained from several Holocene samples. Groundwaters in the Minqin Basin have salinities generally below 1 g/L and are aerobic, containing low Fe but elevated concentrations of U, Cr and Se (mean values of 27.5, 5.8 and 5.3 μg L⁻¹, respectively). Nitrate is present at baseline concentrations of around 2 mg L⁻¹ but there is little evidence of impact of high NO₃ from irrigation returns. Strontium isotope and major ion ratios suggest that silicate reactions predominate in the aquifer. The results have important implications for groundwater management in the Minqin and other water-stressed basins in NW China – a region so far destined for rapid development. The large proportion of the water being used at present is in effect being mined and significant changes are urgently needed in water use strategy.