氨氮在弱透水层中的渗透迁移规律研究

通过渗透试验、吸附试验和高压动态土柱试验对氨氮在弱透水层中的渗透、迁移转化规律进行研究。试验结果表明,弱透水层对氨氮具有很强的吸附能力;弱透水层中生物作用微弱,弱透水层对氨氮的去除主要是非生物作用的结果;硬度或其他交换性离子的作用会影响氨氮在弱透水层的穿透时间和吸附稳定性。此研究对揭示深层地下水的氮污染规律及探索地下水污染修复提供理论支持。     

不同Eh条件下弱透水层中硝酸盐截留能力

为了研究硝酸盐在不同Eh条件下通过弱透水层的迁移机理及转化形式,用天然黏土作为渗透介质弱透水层,在高渗透压条件下进行室内实验,模拟地下水中硝酸盐通过弱透水层的迁移转化过程。结果表明：单位质量黏土截污容量为1.45 mg/g,阻截率R=92%,不同Eh条件下（Eh分别为0、-100、-200 mV）弱透水层对硝酸盐的阻截能力都很强;低氧化还原电位有利于弱透水层吸附硝酸盐。弱透水层中硝酸盐的转化途径表明,弱透水层对硝酸盐的阻截能力很强,是微孔隙截留作用、机械过滤、离子吸附、协同吸附以及较弱的微生物共同作用的结果。     

深部弱透水层固结变形模型建议

地面沉降模型是地面沉降研究的重要内容,由于弱透水层的变形量占地层全部变形量的比重较大,因此对弱透水层固结模型的研究是地面沉降模型研究中的重要部分。笔者通过对深部弱透水层中粘性土孔隙水类型进行分析,得出深度弱透水层中孔隙水类型并对该类型孔隙水变形特性进行了研究,总结出深部弱透水层固结机理。在机理分析的基础上,提出采用非达西流计算模式对深部弱透水层计算模型进行了修正,并提出了深部弱透水层固结计算模型建议：孔隙水类型主要为扩散层内结合水时,可以采用利用非达西流修正的太沙基固结方程对深部弱透水层变形进行计算,可以参考给出的采用非达西定律修正过的一维固结方程 孔隙水类型主要为吸附结合水时,可以利用弹性本构关系模型对深部弱透水层进行变形计算。     

黏性土弱透水层压实作用:原理、技术及其水文地质意义

弱透水层与含水层相互作用是国际水文地质学界关注的热点问题,特别是黏性土弱透水层与孔隙含水层的相互作用。近年来,在自然沉积、过量开采地下水、现代化农业机械与建筑业重型机械应用等自然与人为活动影响下,黏土弱透水层会发生有效应力增加、孔隙结构变形和孔隙度减少、渗透性降低、溶解氧和贮水能力减少以及侧向和垂向排水等的压实作用,导致地下水污染、地面沉降等环境问题的发生。本文重点介绍了黏性土弱透水层压实作用的原理,分析了地下水系统中4种不同状态下沉积物压实与孔隙流体压力的关系,基于压实物理模拟和数值模拟两个方面对压实作用的研究方法与技术进行了系统总结,随后探讨了压实作用下黏性土弱透水层对地下水水量与水质的影响,并对此研究的发展趋势及其在地球科学、环境科学等研究领域的潜在应用提出了展望。     

黏性岩土的化学渗透效应及其研究进展

化学渗透现象引起的"耦合流"研究,已广泛应用于地球科学、环境科学和土木工程等多个领域。回顾了自20世纪50年代以来化学渗透以及黏土半透膜效应的研究进展。分别从理论基础、试验研究和数值模型等3个方面综述了黏土岩土的化学渗透效应的理论及其研究进展,重点阐述了化学渗透现象及其黏土半透膜效应的室内试验、场地试验及野外证据以及化学渗透"耦合流"的不连续模型和连续模型。指出今后应重点研究黏性土化学渗透效应对地下水流及溶质运移的影响研究。这将有利于我国进一步开展考虑化学渗透效应的地下水数值模拟研究。     

弱透水层中有机污染物(菲)的衰减研究

本文以高渗透压渗流试验装置模拟已被污染的浅层地下水越流通过弱透水层污染深层地下水的过程,研究了有机污染物(菲)通过饱和粘性土弱透水层时的自然衰减特征,以及非生物因子-配位体对于弱透水层中菲迁移转化的影响作用。研究表明,菲的衰减曲线明显分为三阶段:初期吸附截留显著期,中期微生物降解旺盛期,后期微生物降解稳定期;溶液中共存离子HCO 3-、Ca2+与菲形成络合物,SO42-参与菲的生物降解;溶液中主要配位体不同时,菲与阴、阳离子之间相互作用的方式也不同,以络合作用为主。渗透水中菲含量有99%以上被衰减,仅有极少量菲穿透弱透水层。     

滨海多层含水层系统中海潮引起的地下水位波动

通过对一个滨海多层含水层系统的考察,该含水层系统由上、下弱透水层和介于中间的承压含水层组成,海底露头处被淤泥层覆盖.建立了描述该系统中地下水水头随潮汐波动的数学模型,并得到其解析解.该解析解与六个基本参数有关,分别是承压含水层的海潮传播参数,淤泥层的无量纲透水系数,上下弱透层与承压含水层贮水率的比率 (无量纲)和上下弱透层的无量纲越流.当这些参数取某些特殊值时,我们的解便化简为前人考虑的几种简单情形对应的解.分析表明,承压含水层中地下水水头波幅是上、下弱透水层贮水率和越流系数的减函数,是淤泥层相对透水系数的增函数;波动相位(时滞)是上、下弱透水层贮水率和越流系数的增函数,是淤泥层相对透水系数的减函数.     

弱透水层饱和粘性土中水分渗透规律研究

本文利用渗压仪,对弱透水层一饱和粘性土类的原状土样,进行不同水头差作用下的渗透试验,获得水在弱透水层不同孔隙类型中的渗透规律:V—I关系曲线及V—I关系方程等,为地下水资源评价提供了理论依据,具有重要的理论与实际意义。     

基于多源数据的弱透水层水文地质参数反演研究

弱透水层是含水层系统的重要组成部分,其水文地质参数的准确获取一直以来都是研究难点,传统室内试验难以克服应力状态及环境变化对土层参数的影响,因此如何在原位状态下评价其水文地质参数有着重要意义。选取呼和浩特盆地某淤泥层为研究对象,基于抽水试验和溶质运移试验获得的多源数据,采用基于控制体积有限差分法的非结构化网格（Unstructured Grid）方法,建立三维地下水流-溶质运移耦合模型,对弱透水层水文地质参数进行反演。结果显示:模型计算的抽水井中水位和溶质浓度变化规律与实际观测数据能够较好拟合,模型识别出的抽水含水层渗透参数（4.8 m/d）与通过解析法计算得出的结果（4.17 m/d）相近,建立的数值模型符合实际水文地质条件;反演得到淤泥质弱透水层垂向渗透系数为1.2×10?4 m/d、储水率为1.0×10?5 m?1。基于多源数据的参数反演方法可为弱透水层参数研究提供借鉴。     

土工膜-防渗墙-弱透水层联合防渗的有效性分析

深厚覆盖层坝基往往都是强弱互层结构,坝基中存在弱透水层。弱透水层既是隔水层又是软弱夹层,是否利用其作为控渗依托层关系到工程难度、进度及成本。绝大多数工程都将全封闭式防渗体作为控渗首选方案,保守的设计理念导致采用半封闭式防渗体控渗的工程少之又少。西藏多布水电站采用土工膜-防渗墙-弱透水层三位一体半封闭式联合防渗体,在国内外少见,具有一定代表性,其防渗效果具有重要的参考价值和借鉴意义。本文基于详细的地质构造资料,以非饱和土体渗流、比奥固结理论和土体的非线性流变理论为基础,考虑土体水力学及土力学参数随双场耦合的动态变化关系,借助ADINA建立流固耦合模型,全方位分析多布水电站的渗流场、应力场,以及弱透水层的承载力和液化性。研究表明:土工膜-防渗墙-弱透水层三位一体半封闭式防渗体能有效降低渗透速度、渗流量和抑制渗透坡降,各渗流参量满足控渗要求;大坝及防渗墙的水平位移、沉降和应力相对悬挂式防渗体有一定增大,需提高防渗墙的强度。弱透水层是防渗体系中最重要的部分,经分析弱透水层承载力满足要求,且不会发生液化。对比分析三种防渗体系,多布水电站现采取的土工膜-防渗墙-弱透水层三位一体半封闭式联合防渗体是最佳方案,可减小防渗墙深度近193m。该研究成果对类似工程具有重要的参考价值和借鉴意义。     

混凝和膜分离联用处理制药废水二级出水中试试验

对东北制药总厂废水处理厂的二级出水采用混凝-超滤-反渗透膜工艺进行中试处理研究。试验结果表明：混凝工艺对浊度和COD的去除率分别在62.0％和22.3％以上;超滤工艺对浊度和COD的去除率分别在87.4％和54.5％以上;反渗透工艺产水脱盐率在97.6％以上。工艺出水满足循环用水水质指标,工艺运行稳定。     

HYDRATION SWELLING OF WATER-ABSORBING ROCKS: A CONSTITUTIVE MODEL

Water-absorbing rocks are formed from minerals that can hold water in their crystal structure or between grain boundaries. Such water absorption is often accompanied by a change in the crystal dimension that manifests itself as a swelling of the rock. Swelling is particularly pronounced in rocks containing phyllosilicates because of the ease with which these minerals hydrate; it is thus of geological and geotechnical relevance in shales, clay-rich soils and zeolitized tuffs. The model of hydration swelling that we present here is based on extended versions of the equations of poroelasticity and Darcy's transport law, which we derive using a non-equilibrium thermodynamics approach. Our equations account for the hydration reaction under the assumption that the reaction rate is fast in comparison with the rate at which hydraulic state changes are communicated through the rock, i.e. that local physico-chemical equilibrium persists. Using a finite-element scheme for solving numerically the governing equations of our model, we simulate the creep of shales during a routine swelling test and calculate the stress and strain distributions around wellbores drilled in shale formations that undergo swelling. We show that swelling effects promote tensile failure of the wellbore wall.     

Membrane effects during filtering investigation of membrane effects during filtering of natural surface waters in Missouri

Previous work has demonstrated that suspended clay accumulating on filter paper can act as a membrane and affect chemical concentrations in the filtered water. For this reason, we looked at the possibility of membrane effects altering water chemistry during filtering for Missouri Rivers. Membrane effects during filtering could cause an initial decrease in sample concentrations as the filter cake began acting as a membrane, with a corresponding increase of concentration as the concentration polarization layer was formed behind the filter cake. Samples from five Missouri rivers were tested: the Mississippi River at St. Louis, the Missouri River at Kansas City, the Gasconade River at Jerome, the Osage River at the junction of Highway 63 and 50, and the Meramec River one mile downstream from springs. Three 1-l samples were filtered from each river using a 0.45 m filter. An unfiltered sample from each river underwent dialysis to determine the actual ion concentrations of the overall sample. None of the filtered samples demonstrated a statistically significant alteration of water chemistry using current filtering techniques in this preliminary study, suggesting that membrane effects due to accumulation of clay particles on filter paper may not be a common problem in Missouri and similar regions.     

流量测井求取含水层渗透系数的方法及资料解释技术

论述了流量测井的基本理论，涡轮流量计的结构和响应特性，重点分析、讨论利用二次混合抽水二次降深所测得的流量测井曲线，求取含水层渗透系数和静止水位的方法，并以实例说明该方法的具体应用。     

海上勘探海水造浆装置设计

在海上进行工程地质钻探作业时,对砂粒、松散岩、风化岩等地层需采用泥浆护壁,采用淡水配置泥浆才能达到最佳效果。创建一种海水造浆双流程模型,一级流程装置输出的初纯水满足高性能泥浆用水标准;二级流程去除水中残存的盐类,制成适于饮用的超纯水。设计的实用海水造浆装置,包括海水预处理、反渗透装置、EDI分离器及维护控制系统等,从而突破了海上勘探受制于平台空间、载荷、淡水成本等因素制约,有效地降低了勘探成本。     

Alternatives to tap water: a case study of the Gaza Strip, Palestine

Gaza Strip is a highly populated, small area in which the groundwater is the main water source. During the last few decades, groundwater quality has deteriorated to a limit that the municipal tap water became brackish and unsuitable for human consumption in most parts of the strip. To overcome this serious situation, several attempts were made to replace the tap water or to improve its quality by water desalination applying the reverse osmosis (RO) technology, bottled water, importing water, and storm water harvesting. Water desalination, which is widely applied in the strip, has environmental and health risks. Brine water resulting from the RO systems has adverse environmental effects, whereas the produced fresh water with very low chemical concentrations may have harmful effects on human health. Therefore, introducing international water quality standards to delineate the harmless minimum limits is necessary. Storm water harvesting can provide a partial solution for the water problems in the strip.     

反渗透技术在宁夏南部山区人饮工程中的应用及发展

分析了反渗透膜的分离机理、特性及影响膜性能的主要因素,对反渗透系统在宁夏南部山区人饮工程中的应用做了分析与评价,并对其在未来的应用和发展提出自己的看法。     

构造煤中煤层气扩散-渗流特征及其机理

煤层气产出一般要经过解吸、扩散和渗流三个阶段,而煤层气在变形较强的构造煤中的扩散过程不同于在原生结构煤或变形较弱的煤体中的扩散。外界压力的变化只是构造煤吸附与解吸整个过程的一种外在因素,构造煤的变形和结构变化以及吸附势场的转换才是构造煤吸附与解吸的内在因素,是导致解吸过程不可逆性的根本原因。当构造煤体与CH4等多元气体间的吸附平衡状态遭到破坏时,变形较强的构造煤在降压后会产生解吸滞后现象;而变形较弱的煤,分子结构中的气体会很快解吸,第一阶段是气体解吸作用,第二阶段是游离气体从微孔向较大孔隙扩散的过程,气体扩散速率主要由第二阶段决定。构造煤气体扩散机理主要是由孔隙形状、大小、连通性和多元气体性质和状态所决定的。韧性变形煤的微孔隙比较发达,所以韧性变形煤以Knudsen扩散为主,脆性变形煤的中、大孔隙所占比例较大,而且脆性变形煤的孔隙之间具有很好的连通性,所以脆性变形煤以Fick型扩散为主,脆-韧性变形煤以及接近脆-韧性变形煤的脆性变形煤和韧性变形煤均以过渡型扩散为主。在试井渗透率比较中,一定变形程度的脆性变形煤>韧性变形煤,脆性变形煤中以过渡孔为主,其余为微孔,测不出亚微孔和极微孔,脆性变形还增加了各孔隙之间的相互连通性。韧性变形煤中过渡孔比表面积所占比例下降,微孔和亚微孔增高,扩散主要发生在微孔和过渡孔中,所以韧性变形煤的试井渗透率低于脆性变形煤的试井渗透率。     

提水试验在含水层渗透系数求取中的应用——以黄岛地下水封石油洞库为例

在利用水文地质试验求取渗透系数的过程中,对于低渗透性含水介质,由于水量小,一般难于实施抽水试验方法,而提水试验能够很好地解决这一问题。以黄岛地下水封石油洞库为例,首先对提水试验的特点、步骤进行了简单介绍,然后根据裘布依稳定潜水井流原理求解渗透系数,并对库区渗透系数平面分布规律进行了分析,将含水层渗透性划分为三个区域。     

Hyperfiltration of Nacl Solutions Using a Simulated Clay/Sand Mixture at Low Compaction Pressures

It is widely recognized that clays and shales can demonstrate membrane properties. When a hydraulic head differential exists across a membrane-functioning clay-rich barrier, some of the solute is rejected by the membrane. This process is known as hyperfiltration. Some shallow geologic environments, including aquitards bounding shallow perched aquifers and unconfined aquifers, some river and stream beds, and some lake bottoms contain clay–soil mixes. Many engineering structures such as landfill liners, mixed soil augered barriers, and retention pond liners also consist of soil–clay mixes. No previous testing has been performed to investigate the likelihood that hyperfiltration may occur in such mixed soils. Therefore, we performed five experiments using different mixes of Na-bentonite and glass beads (100, 50, 25, 12 and 0% clay) to determine if any of these mixes exhibited membrane properties and to investigate what effect clay content had upon the membrane properties of the soil. Each mixture was compacted to 345 kPa and the sample mixtures were 0.58–0.97 mm thick. All the experiments used an approximately 35 ppm Cl⁻ solution under an average 103 kPa hydraulic head. Experimental results show that all the simulated clay–sand mixtures do exhibit measurable membrane properties under these conditions. Values of the calculated reflection coefficient ranged from a low of 0.03 for 12% bentonite to 0.19 for 100% bentonite. Solute rejection ranged from 5.2% for 12% clay to a high of over 30% for the 100% clay. The 100% glass bead sample exhibited no membrane properties.