The atmospheric distribution of lead over a number of marine regions

A data base of 111 filter-collected marine atmospheric particulates is used to describe the distribution of lead over the North and South Atlantic, the Mediterranean Sea, the Red Sea, the Gulf of Aden and the northern and central Arabian Sea. The distribution of atmospheric Pb is assessed in terms of enrichment factor diagrams, and it is shown that over the marine regions studied in both the Northern and Southern Hemispheres the distribution of Pb in the atmosphere is controlled by the mixing of a background component, or components, with crustal material within certain concentration limits. For the Northern Hemisphere samples used in the investigation there is a reasonably well-defined Pb concentration minimum of ～ 0.6 ng m^?3 of air; however, this will be severely decreased in more remote Northern Hemisphere marine regions. Geometric average Pb atmospheric concentrations vary from one marine region to another, ranging from ～ 0.98 ng m^?3 of air for the South Atlantic westerlies to ～ 15 ng m^?3 of air in the North Atlantic westerlies; although the latter reduces to ～ 7 ng m^?3 of air when ‘polluted’ samples are excluded. Lead sea-surface deposition fluxes are calculated on the basis of two deposition velocities (0.25 and 1 cm s^?1), the largest flux (220 ng Pb cm^?2 yr^?1) being found for the westerlies over the eastern margins of the North Atlantic. The distribution of lead over the North Atlantic is assessed in terms of the global lead budget and it is estimated that a maximum of ～ 24% of the total ‘natural’ lead injected annually into the World atmosphere, and ～ 3.5% of the anthropogenic lead injected annually into the Northern Hemisphere atmosphere, are deposited over the North Atlantic sea surface.     

南大洋大气有机胺分布及来源特征研究

依托中国第36次南极科学考察,利用船载走航气溶胶及气体组分在线分析仪对南大洋大气中气态和颗粒态有机胺进行了在线观测。获得了南大洋开阔海域及普里兹湾大气中高分辨气态和颗粒态有机胺的组成及分布,并对其来源特征进行了分析。结果表明：南大洋大气有机胺以气态三甲胺（TMA）和二甲胺（DMA）为主要存在形态,其均值分别为(104.0±285.2)、(3.5±6.0) ng/m3。普里兹湾大气中有机胺的平均浓度显著高于南大洋开阔海域,气态TMA和DMA均值分别达到(289.0±396.6)、(5.6±16.1) ng/m3。南大洋大气中气态TMA、DMA和氨气（NH3）在不同区域内均具有良好的线性关系,表明三者具有同源性。从来源分析,南大洋大气有机胺主要受到海洋生物活动的影响,但在海冰边缘区及南极近岸海域,企鹅等动物的生物活动会导致大气中有机胺的浓度显著升高。     

Variability of the meridional transport processes in the Southern Ocean and its possible relation to El Niño

The article deals with the influence of wind and atmospheric pressure on the barotropic variability of the Antarctic Circumpolar Current (ACC). This effect is studied using a global barotropic model under idealized and realistic atmospheric forcings. The results of barotropic modeling demonstrate that variations in the wind forcing over the ACC, together with the effects of the topography and coastline, lead to the variability in the meridional water flux in the Southern Ocean. The variability of these fluxes is negatively correlated with the wind strength over the ACC. A possible link between the short-period variability of the water flux in the Pacific sector of the Southern Ocean and El Niño is demonstrated using 3D ocean modeling and correlation analysis. It is shown that the variability of the meridional water flux caused by atmospheric perturbations over the ACC can lead to short-period density anomalies in the Southern Ocean north of 47°S, which later can be transferred to low latitudes by means of the wave mechanism described in [15] and strongly influence the tropical region.     

Global distribution and atmospheric transport of chlorinated hydrocarbons: HCH (BHC) isomers and DDT compounds in the Western Pacific,Eastern Indian and Antarctic Oceans

Concentrations of chlorinated hydrocarbons such as HCH isomers and DDT compounds were determined in air and surface water samples taken from the Western Pacific, Eastern Indian and Antarctic Oceans. The most interesting finding was their presence in measurable concentrations in the Antarctic Ocean. Chlorinated hydrocarbon pesticides are widely distributed in the open ocean environment over both the northern and southern hemispheres, and some characteristic distribution patterns of pesticide species in different oceanic regions were observed both in air and water samples. HCH residues found in the northern hemisphere were much higher in concentration than those in the southern hemisphere. On the other hand, higher concentrations of DDT residues were found in the tropical regions, but their levels were not so different between both the northern and southern hemispheres. HCH isomers found in the northern hemisphere had the following order of concentrations:-HCH> HCH>-HCH, while in the southern hemisphere-HCH was apparently dominant. DDT compound compositions were rather uniform in all the oceans surveyed, and more than 50% wasp,p-DDT. These facts can be explained by the world wide situation regarding pesticide use and the physicochemical properties of the pesticides such as their vapor pressures and water solubilities. In addition, the meridional circulation of the atmosphere, particularly the mass flows of the Hadley and Ferrel cells in the troposphere, also contributes to the atmospheric transport and global distribution of these pesticides.     

Air-sea carbon fluxes and their controlling factors in the Prydz Bay in the Antarctic

The Prydz Bay in the Antarctic is an important area in the Southern Ocean due to its unique geographic feature. It plays an important role in the carbon cycle in the Southern Ocean. To investigate the distributions of carbon dioxide in the atmosphere and surface seawater and its air-sea exchange rates in this region, the Chinese National Antarctic Research Expedition （CHINARE） had set up several sections in the Prydz Bay. Here we present the results from the CHINARE-XVI cruises were presented onboard R/V Xue/ong from November 1999 to April 2000 and the main driving forces were discussed controlling the distributions of partial pressure of carbon dioxide. According to the partial pressure of carbon dioxide distributions, the Prydz Bay can be divided into the inside and outside regions. The partial pressure of carbon dioxide was low in the inside region but higher in the outside region during the measurement period. This distribution had a good negative correlation with the concentrations of ehlorophyll-a in general, suggesting that the partial pressure of carbon dioxide was substantially affected by biological production. The results also indicate that the biological produetion is most likely the main driving force in the marginal ice zone in the Southern Ocean in summer. However, in the Antarctic divergence sector of the Prydz Bay （about 64°S）, the hydrological processes become the controlling factor as the sea surface partial pressure of carbon dioxide is much higher than the atmospheric one due to the upwelling of the high DIC CDW, and this made the outside of Prydz Bay a source of carbon dioxide. On the basis of the calculations, the CO2 flux in January （austral summer） was -3.23 mmol/（m^2 · d） in the inner part of Prydz Bay, i.e. , a sink of atmospheric CO2, and was 0.62 mmol/（m^2 · d） in the outside part of the bay, a weak source of atmospheric CO2. The average air-sea flux of CO2 in the Prydz Bay was 2.50 mmol/（m^2 · d）.     

Numerical simulation of the response of general circulation of the middle atmosphere to spatial inhomogeneities of orographic waves

We have developed a parameterization of the dynamical and thermal effects of stationary orographic waves (SOWs) generated by the earth’s surface topography and included it into the general circulation model of the middle and upper atmosphere. We have analyzed the sensitivity of atmospheric general circulation at tropospheric to thermospheric altitudes to the impact of SOWs propagating from the troposphere. Changes in atmospheric circulation due to variations in the SOW generation and propagation have been considered for different seasons. It has been shown that, during solstices, the main dynamical and thermal impacts the middle atmosphere of winter hemispheres, where the SOW-induced changes in the velocity of zonal circulation can reach 30%. During equinoxes, the SOW impact is distributed more homogeneously between the Northern and Southern hemispheres, and the relative changes in the velocity of zonal circulation of the middle atmosphere may constitute 10%.     

南极绕极流的经向输运

南极绕极流(ACC)是南大洋中最显著的流动，流量超过130×106m3/s (Nowlin et al.，1986)。传统认为，由于以东向运动为主的ACC的存在极大地阻碍了南大洋中上层的南北向物质和能量的交换，绕极流区的经向输运是非常小的。但是近些年的研究发现，穿过ACC的通量并不是可以忽略不计的，它对维持南极和亚南极区的动力和热力平衡起着重要作用，在全球气候系统中也有着深刻的影响(Doos et al.，1994)。     

Western Indian Ocean SST signal and anomalous Antarctic sea-ice concentration variation

Teleconnection between El Nino/La Nina-Southern Oscillation (ENSO) phenomenon and anomalous Antarctic sea-ice variation has been studied extensively.In this study,impacts of sea surface temperature in the Indian Ocean on Antarctic sea-ice change were investigated during Janaury 1979 and October 2009.Based on previous research results,sea areas in the western Indian Ocean (WIO;50°–70°E,10 °–20 °S) are selected for the resreach.All variables showed 1-10 year interannual timescales by Fast Founer Tranaform (FFT) transformation.Results show that i) strong WIO signals emerged in the anomalous changes of Antarctic sea-ice concentration;ii) significant positive correlations occurred around the Antarctic Peninsula,Ross Sea and its northwest peripheral sea region iii) negative correlation occurred in the Indian Ocean section of the Southern Ocean,Amundsen Seas,and the sea area over northern Ross Sea;and iv) the atmospheric anomalies associated with the WIO including wind,meridional heat flux,and surface air temperature over southern high latitudes were the possible factors for the teleconnection.     

Modeling of El Niño events using a simple model

In this paper, we present the results of modeling of El Niño events using a simple model of a classical oscillator with decay under external forcing. The sea surface temperature in the East Pacific and the mean thermocline depth in the Equatorial Pacific correspond to the roles of the momentum and position, respectively. The external forcing of the system is determined by two factors: the short-period meridional mass fluctuations in the Pacific sector of the Southern Ocean due to the joint effect of the atmospheric variability over the Antarctic Circumpolar Current, bottom topography, and coastlines; and the variability of western winds in the tropics. Under such conditions, oscillations of El Niño type arise in the model as a result of propagation of signals generated in the Southern Ocean (due to the fluctuations of meridional transport fluxes and the variability of western winds in the tropics). These signals propagate over the Equatorial Pacific as fast wave processes. It is shown that external forcing is the main factor in establishing the oscillation pattern of the model characteristics variability.     

Cyclone formation and development in the Antarctic Prydz Bay

Using meteorological data of field observation in 1990 - 2000, especially polar orbit high-resolution NOAA satellite cloud maps received from the Antarctic expedition vessel since 1997, the formation and development of the Prydz Bay cyclone are studied in this paper. Some new viewpoints are suggested such as: when surround-polar cyclone enters the Prydz Bay, it can also intensify and develop in summer; cyclone can also develop in the easterlies in this bay. These view points revise old uncom-plete view point that the Prydz Bay is a burial ground of cyclone, and also further consummate formation-development theory of surround-cyclone in the Antarctic westerlies and cyclone in the Antarctic easterlies. In this paper, the mechanism of ice-air-sea interaction in the Prydz Bay is studied, and the physical process of cyclone formation-development is explained. By use of wholly dynamic transportation method, an energy exchange case of a cyclone, which explosively developed after entering the Prydz Bay, is calcu     

Climatic variability of transport in the upper layer of the Antarctic Circumpolar Current from hydrological and satellite data

Based on the satellite altimetry dataset of sea level anomalies, the climatic hydrological database World Ocean Atlas-2009, ocean reanalysis ECMWF ORA-S3, and wind velocity components from NCEP/NCAR reanalysis, the interannual variability of Antarctic Circumpolar Current (ACC) transport in the ocean upper layer is investigated for the period 1959–2008, and estimations of correlative connections between ACC transport and wind velocity components are performed. It has been revealed that the maximum (by absolute value) linear trends of ACC transport over the last 50 years are observed in the date-line region, in the Western and Eastern Atlantic and the western part of the Indian Ocean. The greatest increase in wind velocity for this period for the zonal component is observed in Drake Passage, at Greenwich meridian, in the Indian Ocean near 90° E, and in the date-line region; for the meridional component, it is in the Western and Eastern Pacific, in Drake Passage, and to the south of Africa. It has been shown that the basic energy-carrying frequencies of interannual variability of ACC transport and wind velocity components, as well as their correlative connections, correspond to the periods of basic large-scale modes of atmospheric circulation: multidecadal and interdecadal oscillations, Antarctic Circumpolar Wave, Southern Annual Mode, and Southern Oscillation. A significant influence of the wind field on the interannual variability of ACC transport is observed in the Western Pacific (140° E–160° W) and Eastern Pacific; Drake Passage and Western Atlantic (90°–30° W); in the Eastern Atlantic and Western Indian Ocean (10°–70° E). It has been shown in the Pacific Ocean that the ACC transport responds to changes of the meridional wind more promptly than to changes of the zonal wind.     

Simulation of the impact of thunderstorm activity on atmospheric gas composition

A chemistry-climate model of the lower and middle atmosphere has been used to estimate the sensitivity of the atmospheric gas composition to the rate of thunderstorm production of nitrogen oxides at upper tropospheric and lower stratospheric altitudes. The impact that nitrogen oxides produced by lightning have on the atmospheric gas composition is treated as a subgrid-scale process and included in the model parametrically. The natural uncertainty in the global production rate of nitrogen oxides in lightning flashes was specified within limits from 2 to 20 Tg N/year. Results of the model experiments have shown that, due to the variability of thunderstorm-produced nitrogen oxides, their concentration in the upper troposphere and lower stratosphere can vary by a factor of 2 or 3, which, given the influence of nitrogen oxides on ozone and other gases, creates the potential for a strong perturbation of the atmospheric gas composition and thermal regime. Model calculations have shown the strong sensitivity of ozone and the OH hydroxyl to the amount of lightning nitrogen oxides at different atmospheric altitudes. These calculations demonstrate the importance of nitrogen oxides of thunderstorm origin for the balance of atmospheric odd ozone and gases linked to it, such as ozone and hydroxyl radicals. Our results demonstrate that one important task is to raise the accuracy of estimates of the rate of nitrogen oxide production by lightning discharges and to use physical parametrizations that take into account the local lightning effects and feedbacks arising in this case rather than climatological data in models of the gas composition and general circulation of the atmosphere.     

跨南大洋经向断面的大气垂直剖面特征研究

基于中国第29次南极科学考察期间获取的GPS探空观测数据,分析了东南印度洋和西南太平洋经向断面大气垂直结构的基本特征、季节变化和纬向差异.不同断面的大气垂向结构差异显著,但也具有共同特征,4000 m以下低空的气温和湿度明显高于高空,而低空风速明显小于高空风速,8000 m以上高空各个观测要素的垂直变化较小,整个断面主...     

The WOCE-era 3-D Pacific Ocean circulation and heat budget

To address questions concerning the intensity and spatial structure of the three-dimensional circulation within the Pacific Ocean and the associated advective and diffusive property flux divergences, data from approximately 3000 high-quality hydrographic stations collected on 40 zonal and meridional cruises have been merged into a physically consistent model. The majority of the stations were occupied as part of the World Ocean Circulation Experiment (WOCE), which took place in the 1990s. These data are supplemented by a few pre-WOCE surveys of similar quality, and time-averaged direct-velocity and historical hydrographic measurements about the equator.An inverse box model formalism is employed to estimate the absolute along-isopycnal velocity field, the magnitude and spatial distribution of the associated diapycnal flow and the corresponding diapycnal advective and diffusive property flux divergences. The resulting large-scale WOCE Pacific circulation can be described as two shallow overturning cells at mid- to low latitudes, one in each hemisphere, and a single deep cell which brings abyssal waters from the Southern Ocean into the Pacific where they upwell across isopycnals and are returned south as deep waters. Upwelling is seen to occur throughout most of the basin with generally larger dianeutral transport and greater mixing occurring at depth. The derived pattern of ocean heat transport divergence is compared to published results based on air–sea flux estimates. The synthesis suggests a strongly east/west oriented pattern of air–sea heat flux with heat loss to the atmosphere throughout most of the western basins, and a gain of heat throughout the tropics extending poleward through the eastern basins. The calculated meridional heat transport agrees well with previous hydrographic estimates. Consistent with many of the climatologies at a variety of latitudes as well, our meridional heat transport estimates tend toward lower values in both hemispheres.     

Natural air–sea flux of CO2 in simulations of the NASA-GISS climate model: Sensitivity to the physical ocean model formulation

Results from twin control simulations of the preindustrial CO₂ gas exchange (natural flux of CO₂) between the ocean and the atmosphere are presented here using the NASA-GISS climate model, in which the same atmospheric component (modelE2) is coupled to two different ocean models, the Russell ocean model and HYCOM. Both incarnations of the GISS climate model are also coupled to the same ocean biogeochemistry module (NOBM) which estimates prognostic distributions for biotic and abiotic fields that influence the air–sea flux of CO₂. Model intercomparison is carried out at equilibrium conditions and model differences are contrasted with biases from present day climatologies. Although the models agree on the spatial patterns of the air–sea flux of CO₂, they disagree on the strength of the North Atlantic and Southern Ocean sinks mainly because of kinematic (winds) and chemistry (pCO₂) differences rather than thermodynamic (SST) ones. Biology/chemistry dissimilarities in the models stem from the different parameterizations of advective and diffusive processes, such as overturning, mixing and horizontal tracer advection and to a lesser degree from parameterizations of biogeochemical processes such as gravitational settling and sinking. The global meridional overturning circulation illustrates much of the different behavior of the biological pump in the two models, together with differences in mixed layer depth which are responsible for different SST, DIC and nutrient distributions in the two models and consequently different atmospheric feedbacks (in the wind, net heat and freshwater fluxes into the ocean).     

Comparison of airsea fluxes of CO2 in the Southern Ocean and the western Arctic Ocean

The data were collected during Chinese Arctic and Antarctic Expeditions in the western Arctic Ocean and the marginal sea ice zone (MSIZ) of the Southern Ocean, respectively in the boreal summer from July to September of 1999 and in the austral summer from December of 1999 to January of 2000. The concentrations of CO2 in surface water of the survey regions would mostly present lower than those in the atmosphere. A significant biological driving force could also been observed in summer waters in both of the above oceans. Air to sea CO2 fluxes were also calculated to compare oceanic uptake capacity of CO2 in both oceans with the world oceans using Liss, Wanninkhof, and Jacobs‘s methods. The averaged CO2 fluxes of air to sea in the western Arctic Ocean or in the MSIZ of the Southern Ocean doubled that in the world oceans.     

Variations in the total column amounts of carbon monoxide and methane in the Antarctic atmosphere

The results of measuring the total contents of carbon monoxide and methane via the method of solar-absorption spectroscopy are presented. The measurements were performed at the Molodezhnaya Station in 1977–1978, at the Mirny Observatory from 1982 to 1992, and at the Novolazarevskaya Station from 2003 to 2006. The character of seasonal variations in the contents of these gases in the Antarctic atmosphere is described and compared to the intra-annual variation of their surface concentrations measured at the Syowa Station (Japan). Synchronous intra-annual variations in the contents of carbon monoxide in the atmospheric column and in its surface concentrations are observed, while the spring maximum content of methane is observed three months after the maximum of its surface concentration. Synchronous seasonal variations in the total content of methane and ozone are observed, which makes it possible to suggest that the Antarctic circumpolar vortex has a significant influence on the characteristics of the vertical distribution of methane during Antarctic spring. Quantitative estimates of the parameters of multiyear variations in the contents of CO and CH₄ are given. The content of methane was increasing (although with different rates) during the entire observation period 1977–2006. The content of CO was observed to increase until 1992 and to decrease during 2003–2006.     

Temporal variations and trends of CFC11 and CFC12 surface-water saturations in Antarctic marginal seas: Results of a regional ocean circulation model

The knowledge of chlorofluorocarbon (CFC11, CFC12) concentrations in ocean surface waters is a prerequisite for deriving formation rates of, and water mass ages in, deep and bottom waters on the basis of CFC data. In the Antarctic coastal region, surface-layer data are sparse in time and space, primarily due to the limited accessibility of the region. To help filling this gap, we carried out CFC simulations using a regional ocean general circulation model (OGCM) for the Southern Ocean, which includes the ocean–ice shelf interaction. The simulated surface layer saturations, i.e. the actual surface concentrations relative to solubility-equilibrium values, are verified against available observations. The CFC surface saturations driven by concentration gradients between atmosphere and ocean are controlled mainly by the sea ice cover, sea surface temperature, and salinity. However, no uniform explanation exists for the controlling mechanisms. Here, we present simulated long-term trends and seasonal variations of surface-layer saturation at Southern Ocean deep and bottom water formation sites and other key regions, and we discuss differences between these regions. The amplitudes of the seasonal saturation cycle vary from 22% to 66% and their long-term trends range from 0.1%/year to 0.9%/year. The seasonal surface saturation maximum lags the ice cover minimum by two months. By utilizing observed bottle data the full seasonal CFC saturation cycle can be determined offering the possibility to predict long-term trends in the future. We show that ignoring the trends and using instead the saturations actually observed can lead to systematic errors in deduced inventory-based formation rates by up to 10% and suggest an erroneous decline with time.     

基于大气参数拟合的GF-1多光谱影像大气校正

针对大气校正常使用的基于查找表的方法建表速度缓慢、查找精度低等问题,提出在6S大气校正模型的基础上,以气溶胶厚度为自变量对大气参数进行拟合的算法,使用该算法对GF-1多光谱影像进行大气校正研究。对半球反射率、路径辐射项等效反射率、大气透过率3个大气参数使用三次多项式进行拟合,拟合后的决定系数都达到了0. 999 8;根据拟合结果使用MODIS气溶胶产品作为输入,逐像元计算大气参数,并对影像进行大气校正,将校正结果与FLAASH模型校正结果进行对比。结果表明,该算法能有效校正大气对GF-1多光谱影像的影响,并与FLAASH校正结果具有很好的一致性。     

Geographical and temporal variation in levels of organochlorine contaminants in marine mammals

The interpretation of the spatial and temporal patterns of variation in organochlorine concentrations in marine mammal populations is complex because of the lack of wide-scale, long-term surveys. Therefore the results from several surveys must be combined and this causes undesired heterogeneity due to differences in the sampling and analytical techniques used and in the biological characteristics of the individuals sampled. Moreover, information is not homogeneously distributed in either space or in time. Most research is concentrated in western Europe, northern America and certain areas of Asia, while it is extremely limited or non-existent in Africa and most regions of the southern hemisphere. Marine mammals from the temperate fringe of the northern hemisphere, particularly fish-eating species which inhabit the mid-latitudes of Europe and North America, show the greatest organochlorine loads; noteworthy are the extremely high levels found in the Mediterranean Sea and certain locations on the western coasts of the United States. Concentrations in the tropical and equatorial fringe of the northern hemisphere and throughout the southern hemisphere are low or extremely low. The polar regions of both hemispheres showed the lowest concentrations of DDTs and PCBs, although levels of HCHs, chlordanes and HCB were moderate to high in the cold waters of the North Pacific. During recent decades, concentrations have tended to decrease in the regions where pollution was initially high but they have increased in regions located far from the pollution source as a consequence of atmospheric transport and redistribution. It is expected that the Arctic and, to a lesser extent, the Antarctic, will become major sinks for organochlorines in the future; this process may already be significant for some compounds such as HCB and HCHs. Effort should be devoted to both assessment of organochlorine trends in the now highly polluted populations of the temperate fringe of the northern hemisphere and to the implementation of long-term monitoring of marine mammal populations inhabiting polar regions.