U–Pb (zircon) and geochemical constraints on the age,origin, and evolution of Paleozoic arc magmas in the Oyu Tolgoi porphyry Cu–Au district,southern Mongolia

Uranium–Pb (zircon) ages are linked with geochemical data for porphyry intrusions associated with giant porphyry Cu–Au systems at Oyu Tolgoi to place those rocks within the petrochemical framework of Devonian and Carboniferous rocks of southern Mongolia. In this part of the Gurvansayhan terrane within the Central Asian Orogenic Belt, the transition from Devonian tholeiitic marine rocks to unconformably overlying Carboniferous calc-alkaline subaerial to shallow marine volcanic rocks reflects volcanic arc thickening and maturation. Radiogenic Nd and Pb isotopic compositions (ε_Nd(t) range from + 3.1 to + 7.5 and ²⁰⁶Pb/²⁰⁴Pb values for feldspars range from 17.97 to 18.72), as well as low high-field strength element (HFSE) contents of most rocks (mafic rocks typically have < 1.5% TiO₂) are consistent with magma derivation from depleted mantle in an intra-oceanic volcanic arc. The Late Devonian and Carboniferous felsic rocks are dominantly medium- to high-K calc-alkaline and characterized by a decrease in Sr/Y ratios through time, with the Carboniferous rocks being more felsic than those of Devonian age. Porphyry Cu–Au related intrusions were emplaced in the Late Devonian during the transition from tholeiitic to calc-alkaline arc magmatism. Uranium–Pb (zircon) geochronology indicates that the Late Devonian pre- to syn-mineral quartz monzodiorite intrusions associated with the porphyry Cu–Au deposits are ~ 372 Ma, whereas granodiorite intrusions that post-date major shortening and are associated with less well-developed porphyry Cu–Au mineralization are ~ 366 Ma. Trace element geochemistry of zircons in the Late Devonian intrusions associated with the porphyry Cu–Au systems contain distinct Th/U and Yb/Gd ratios, as well as Hf and Y concentrations that reflect mixing of magma of distinct compositions. These characteristics are missing in the unmineralized Carboniferous intrusions. High Sr/Y and evidence for magma mixing in syn- to late-mineral intrusions distinguish the Late Devonian rocks associated with giant Cu–Au deposits from younger magmatic suites in the district.     

Stratigraphy and facies development of the marine Late Devonian near the Boulongour Reservoir,northwest Xinjiang,China

Late Devonian to Early Carboniferous stratigraphic units within the ‘Zhulumute’ Formation, Hongguleleng Formation (stratotype), ‘Hebukehe’ Formation and the Heishantou Formation near the Boulongour Reservoir in northwestern Xinjiang are fossil-rich. The Hongguleleng and ‘Hebukehe’ formations are biostratigraphically well constrained by microfossils from the latest Frasnian linguiformis to mid-Famennian trachytera conodont biozones. The Hongguleleng Formation (96.8 m) is characterized by bioclastic argillaceous limestones and marls (the dominant facies) intercalated with green spiculitic calcareous shales. It yields abundant and highly diverse faunas of bryozoans, brachiopods and crinoids with subordinate solitary rugose corals, ostracods, trilobites, conodonts and other fish teeth. The succeeding ‘Hebukehe’ Formation (95.7 m) consists of siltstones, mudstones, arenites and intervals of bioclastic limestone (e.g. ‘Blastoid Hill’) and cherts with radiolarians. A diverse ichnofauna, phacopid trilobites, echinoderms (crinoids and blastoids) together with brachiopods, ostracods, bryozoans and rare cephalopods have been collected from this interval. Analysis of geochemical data, microfacies and especially the distribution of marine organisms, which are not described in detail here, but used for facies analysis, indicate a deepening of the depositional environment at the Boulongour Reservoir section. Results presented here concern mainly the sedimentological and stratigraphical context of the investigated section. Additionally, one Late Devonian palaeo-oceanic and biotic event, the Upper Kellwasser Event is recognized near the section base.     

Petrogenesis of ore-forming and pre/post-ore granitoids from the Kounrad,Borly and Sayak porphyry/skarn Cu deposits,Central Kazakhstan

Ore-forming porphyries and barren granitoids from porphyry Cu deposits differ in many ways, particularly with respect to their adakitic affinity and calc-alkaline characteristics. In this study, zircon U–Pb and molybdenite Re–Os dating, whole rock geochemistry, whole rock Sr–Nd–Pb and zircon O–Hf isotopic analyses were carried out on the ore-forming granitoids from the Kounrad, Borly and Sayak deposits, and also on pre-ore and post-ore granitoids in adjacent regions of Central Kazakhstan. Geochronology results indicate that pre-ore magmatism occurred in the Late Devonian to Early Carboniferous (361.3–339.4 Ma), followed by large scale Cu mineralization (325.0–327.3 Ma at Kounrad, 311.4–315.2 Ma at Borly and 309.5–311.4 Ma at Sayak), and finally, emplacement of the Late Carboniferous post-ore barren granitoids (305.0 Ma). The geochemistry of these rocks is consistent with calc-alkaline arc magmatism characterized by strong depletions in Nb, Ta and Ti and enrichments in light rare earth elements and large ion lithophile elements, suggesting a supra-subduction zone setting. However, the ore-forming rocks at Kounrad and Sayak show adakitic characteristics with high Sr (517.5–785.3 ppm), Sr/Y (50.60–79.26), (La/Yb)_N (9.37–19.62) but low Y (6.94–11.54 ppm) and Yb (0.57–1.07 ppm), whereas ore-forming rocks at Borly and barren rocks from northwest of Borly and Sayak have normal arc magma geochemical features. The Sr–Nd–Hf–O isotopic compositions show three different signatures: (1) Sayak granitoids have very young juvenile lower crust-derived compositions ((⁸⁷Sr/⁸⁶Sr)_i = 0.70384 to 0.70451, ɛ_Nd (t) = + 4.9 to + 6.0; T_DM2 (Nd) = 580 to 670 Ma, ɛ_Hf (t) = + 11.3 to + 15.5; T_DM^C (Hf) = 330 to 600 Ma, δ¹⁸O = 6.0 to 8.1‰), and were probably generated from depleted mantle-derived magma with 5–15% sediment melt addition in the magma source; (2) the Kt-1 granite from northwest of Sayak shows extremely enriched Sr–Nd isotopic compositions ((⁸⁷Sr/⁸⁶Sr)_i = 0.71050, ɛ_Nd (t) = − 7.8, T_DM2 (Nd) = 1700 Ma), likely derived from partial melting of ancient continental crust; (3) other granitoids have transitional Sr–Nd compositions between the Sayak and Kt-1 samples, indicating a juvenile lower crust source with the addition of 10–30% of ancient crustal material. The pre-ore magmatism was probably related to partial melting of juvenile lower crust due to northward subduction of the Junggar–Balkhash Ocean, whereas the ore-forming adakitic rocks at Aktogai, Kounrad and Sayak formed by partial melting of thickened lower crust which subsequently delaminated. The ore-forming rocks at Borly, and the later post-ore barren granites, formed by partial melting of juvenile lower crust with normal thickness. This tectonic setting supports the existence of an Andean-type magmatic arc in the Devonian to the Late Carboniferous, resulting from the subduction of the Junggar–Balkhash oceanic plate. The link between whole rock geochemistry and scale of mineralization suggests a higher metallogenic potential for adakitic rocks than for normal arc magmatism.     

The Zhaheba ophiolite complex in Eastern Junggar (NW China): Long lived supra-subduction zone ocean crust formation and its implications for the tectonic evolution in southern Altaids

The composite Zhaheba ophiolite complex, exposed in Eastern Junggar in the Southern Altaids, records an unusually long record of oceanic crust and magmatic arc evolution. The Zhaheba ophiolite complex consists of ultramafic rocks, gabbro, diorite, basalt and chert intruded by diabase dikes and diorite porphyry. These rocks are overlain by a several-km-thick section of tuffaceous rocks, volcaniclastic sedimentary rocks, and intermediate volcanic rocks. The igneous rocks of the ophiolite complex show negative Nb and Ta anomalies and LREE enrichment relative to HREE, suggesting the influence of fluids derived from a subducting oceanic slab. The LA-ICPMS U–Pb age of zircons from gabbro is 495.1 ± 3.5 Ma. Zircon ages from diorite and basalt are 458.3 ± 7.2 Ma and 446.6 ± 6.0 Ma, respectively. The basalt is locally overlain by bedded chert. Diabase dikes and diorite porphyry yield the U–Pb ages of 421.5 ± 4.1 Ma and 423.7 ± 6.5 Ma, respectively. The age of stratigraphically lower part of the overlying volcanic–volcaniclastic section is constrained to be about 410 Ma, the maximum depositional age of the tuffaceous sandstone from U–Pb detrital zircon ages. Late rhyolite at the top of the stratigraphic section yielded a U–Pb zircon age of 280.3 ± 3.7 Ma. The age and stratigraphic relationships for the Zhaheba ophiolite complex and related rocks suggest that the period of ~ 70 Ma of initial supra-subduction magmatism was followed by construction of a mature island arc that spanned an additional 140 Ma. Many other ophiolites in the southern Altaids appear to record similar relationships, and are represented as substrates of oceanic island arcs covered by island arc volcanism in supra-subduction zone. The occurrence of the Zhaheba ophiolite complex with tuffaceous and intermediate to felsic volcanic rocks is different from the rock association of classic Tethyan SSZ ophiolites but similar to some ophiolites in North America. Although the Zhaheba ophiolite belt is flanked by the Dulate arc in the north and Yemaquan arc in the south, it cannot stand a suture between two arcs. It is suggested that Devonian–Carboniferous Dulate arc was built on the late Cambrian–middle Ordovician Zhaheba supra-subduction oceanic crust. The late Carboniferous rocks and early Permian rocks in Dulate arc are interpreted to form in the extensional process within Zhaheba–Dulate arc composite system.     

The missing Rheic Ocean magmatic arcs: Provenance analysis of Late Paleozoic sedimentary clastic rocks of SW Iberia

Early Carboniferous turbiditic sedimentary rocks in synorogenic basins located on both sides of the Rheic suture in SW Iberia were studied for provenance analysis. An enigmatic feature of this suture, which resulted from closure of the Rheic Ocean with the amalgamation of Pangea in the Late Carboniferous, is that there are no recognizable mid- to Late Devonian subduction-related magmatic rocks, which should have been generated during the process of subduction, on either side of it. U–Pb LA–ICP-MS geochronology of detrital zircons from Early Carboniferous turbidites in the vicinity of the Rheic suture in SW Iberia, where it separates the Ossa–Morena Zone (with Gondwana continental basement) to the north from the South Portuguese Zone (with unknown/Meguma? continental basement) to the south, reveals the abundance of mid- to Late Devonian (51–81%) and Early Carboniferous (13–25%) ages. The Cabrela and Mértola turbidites of the Ossa–Morena and South Portuguese zones, respectively, are largely devoid of older zircons, differing from the age spectra of detrital zircons in the oldest (Late Devonian) strata in the underlying South Portuguese Zone, which contain abundant Cambrian and Neoproterozoic ages. Mid- to Late Devonian zircons in the Cabrela Formation (age cluster at c. 391 Ma, Eifelian–Givetian transition) and Mértola Formation (age clusters at c. 369 Ma and at c. 387 Ma, Famennian and Givetian respectively) are attributable to a source terrane made up of magmatic rocks with a simple geological history lacking both multiple tectonic events and older continental basement. The terrane capable of sourcing sediments dispersed on both sides of the suture is interpreted to have been completely removed by erosion in SW Iberia. Given that closure of the Rheic Ocean required subduction of its oceanic lithosphere and the absence of significant arc magmatism on either side of the Rheic suture, we suggest: 1) the source of the zircons in the SW Iberia basins was a short-lived Rheic ocean magmatic arc, and 2) given the lack of older zircons in the SW Iberia basins, this short-lived arc was probably developed in an intra-oceanic environment.     

Recycling oceanic crust for continental crustal growth: Sr–Nd–Hf isotope evidence from granitoids in the western Junggar region,NW China

The juvenile component of accretionary orogenic belts has been declining since the Archean. As a result, there is often controversy regarding the contribution of oceanic basalts to Phanerozoic crustal growth, as in the case of the Central Asian Orogenic Belt (CAOB). Here we report on three groups of Late Carboniferous (316–305 Ma) granitoids in the western Junggar region of northern Xinjiang, NW China, which is part of the southwestern CAOB. They consist of adakites and I and A-type granites, and as a whole have the most depleted isotopic compositions (ε_Nd(t) = + 6–+9, (⁸⁷Sr/⁸⁶Sr)_i = 0.7030–0.7045, and ε_Hf(t) = + 12–+16) among the granitoids of the CAOB. These features are nearly identical to those of pre-Permian ophiolites in northern Xinjiang, and are clearly different from those of Carboniferous basalts in the western Junggar region. These relationships indicate that the granitoids were mainly derived from recycled oceanic crust by melting of subducted oceanic crust (e.g., adakites), and of the middle–lower crust of intra-oceanic arc that mainly consisted of oceanic crust (e.g., I and A-type granites). Based on evidence from the CAOB, we suggest that recycling of oceanic crust has made a significant contribution to continental crustal growth and evolution during the Phanerozoic.     

The contribution of the young Cretaceous Caribbean Oceanic Plateau to the genesis of late Cretaceous arc magmatism in the Cordillera Occidental of Ecuador

The eastern part of the Cordillera Occidental of Ecuador comprises thick buoyant oceanic plateaus associated with island-arc tholeiites and subduction-related calc-alkaline series, accreted to the Ecuadorian Continental Margin from Late Cretaceous to Eocene times. One of these plateau sequences, the Guaranda Oceanic Plateau is considered as remnant of the Caribbean–Colombian Oceanic Province (CCOP) accreted to the Ecuadorian Margin in the Maastrichtien.Samples studied in this paper were taken from four cross-sections through two arc-sequences in the northern part of the Cordillera Occidental of Ecuador, dated as (Río Cala) or ascribed to (Macuchi) the Late Cretaceous and one arc-like sequence in the Chogòn-Colonche Cordillera (Las Orquídeas). These three island-arcs can clearly be identified and rest conformably on the CCOP.In all four localities, basalts with abundant large clinopyroxene phenocrysts can be found, mimicking a picritic or ankaramitic facies. This mineralogical particularity, although not uncommon in island arc lavas, hints at a contribution of the CCOP in the genesis of these island arc rocks.The complete petrological and geochemical study of these rocks reveals that some have a primitive island-arc nature (MgO values range from 6 to 11 wt.%). Studied samples display marked Nb, Ta and Ti negative anomalies relative to the adjacent elements in the spidergrams characteristic of subduction-related magmatism. These rocks are LREE-enriched and their clinopyroxenes show a tholeiitic affinity (FeO_T–TiO₂ enrichment and CaO depletion from core to rim within a single crystal).The four sampled cross-sections through the island-arc sequences display homogeneous initial Nd, and Pb isotope ratios that suggest a unique mantellic source for these rocks resulting from the mixing of three components: an East-Pacific MORB end-member, an enriched pelagic sediment component, and a HIMU component carried by the CCOP. Indeed, the ankaramite and Mg-basalt sequences that form part of the Caribbean-Colombian Oceanic Plateau are radiogenically enriched in ²⁰⁶Pb/²⁰⁴Pb and ²⁰⁷Pb/²⁰⁴Pb and contain a HIMU component similar to that observed in the Gorgona basalts and Galápagos lavas. The subduction zone that generated the Late Cretaceous arcs occurred far from the continental margin, in an oceanic environment. This implies that no terrigenous detrital sediments interacted with the source at this period. Thus, the enriched component can only result from the melting of subducted pelagic sediments.We have thus defined the East-Pacific MORB, enriched (cherts, pelagic sediments) and HIMU components in an attempt to constrain and model the genesis of the studied island-arc magmatism, using a compilation of carefully selected isotopic data from literature according to rock age and paleogeographic location at the time of arc edification.Tripolar mixing models reveal that proportions of 12–15 wt.% of the HIMU component, 7–15 wt.% of the pelagic sediment end-member and 70–75 wt.% of an East-pacific MORB end-member are needed to explain the measured isotope ratios. These surprisingly high proportions of the HIMU/CCOP component could be explained by the young age of the oceanic plateau (5–15 Ma) during the Late Cretaceous arc emplacement. The CCOP, basement of these arc sequences, was probably still hot and easily assimilated at the island-arc lava source.     

Late Paleozoic–Mesozoic tectonic evolution of the Trans-Altai and South Gobi Zones in southern Mongolia based on structural and geochronological data

The Trans-Altai Zone in southern Mongolia is characterized by thrusting of greenschist-facies Silurian oceanic rocks over Devonian and Lower Carboniferous volcano-sedimentary sequences, by E–W directed folding affecting the early Carboniferous volcanic rocks, and by the development of N–S trending magmatic fabrics in the Devonian–Carboniferous arc plutons. This structural pattern is interpreted as the result of early Carboniferous thick-skinned E–W directed nappe stacking of oceanic crust associated with syn-compressional emplacement of a magmatic arc. The southernmost South Gobi Zone represents a Proterozoic continental domain affected by shallow crustal greenschist-facies detachments of Ordovician and Devonian cover sequences from the Proterozoic substratum, whereas supracrustal Carboniferous volcanic rocks and Permian sediments were folded into N–S upright folds. This structural pattern implies E–W directed thin-skinned tectonics operating from the late Carboniferous to the Permian, as demonstrated by K–Ar ages ranging from ~ 320 Ma to 257 Ma for clay fractions separated from a variety of rock types. Moreover, the geographical distribution of granitoids combined with their geochemistry and SHRIMP U–Pb zircon ages form distinct groups of Carboniferous and Permian age that record typical processes of magma generation and increase in crustal thickness. The field observations combined with clay ages, the geochemical characteristics of the granitoids and their ages imply that the E–W trending zone affected by tectonism migrated southwards, leaving the Trans Altai Zone inactive during the late Carboniferous and Permian, suggesting that the two units were tectonically amalgamated along a major E–W trending strike slip fault zone. This event was related to late Carboniferous subduction that was responsible for the vast volume of granitoid magma emplaced at 300–305 Ma in the South Gobi and at 307–308 Ma in the Trans-Altai Zones. The formation and growth of the crust was initially due only to subduction and accretion processes. During the post-collisional period from 305 to 290 Ma the addition of heat to the crust led to the generation of (per-) alkaline melts. Once amalgamated, these two different crustal domains were affected by N–S compression during the Triassic and early Jurassic (185–173 Ma), resulting in E–W refolding of early thrusts and folds and major shortening of both tectonic zones.     

An Early Devonian to Early Carboniferous volcanic arc in North Tianshan,NW China: Geochronological and geochemical evidence from volcanic rocks

The Late Paleozoic volcanic and sedimentary rocks are widespread in the North Tianshan along the north margin of the Yili block. They consist of basalt, basaltic andesite, andesite, trachyandesite, dacite, rhyolite, tuff, and tuffaceous sandstone. According to zircon sensitive high-resolution ion microprobe (SHRIMP) dating, the age of the Late Paleozoic volcanic rocks in Tulasu basin in western part of North Tianshan is constrained to be Early Devonian to Early Carboniferous (417–356 Ma), rather than Early Carboniferous as accepted previously. Geochemical characteristics of the Early Devonian to Early Carboniferous volcanic rocks are similar to those of arc volcanic rocks, which suggest that these volcanic rocks could be the major constituents of a continental arc formed by the southward subduction of North Tianshan Oceanic lithosphere. Geochemical studies indicate that the magma source of the volcanic rocks might be the mantle wedge mixed with subduction fluid, which is geochemically enriched than primitive mantle but depleted than E-MORB. The calculation shows that the basalt could be formed by ∼10% partial melting of subduction fluid modified mantle wedge. Andesites with high initial ⁸⁷Sr/⁸⁶Sr (0.7094–0.7104) and negative εNd(t) (−4.45 to −4.79) values reveal the contribution of continental crust to its source. The calculation of assimilation–fractional crystallization (AFC) shows that the fractional crystallization process of the basaltic magma, which was accompanied with assimilation by different degree of continental crust, produced andesite (7–9%), dacite (∼12%) and rhyolite (>20%).     

Middle to Late Ordovician arc system in the Kyrgyz Middle Tianshan: From arc-continent collision to subsequent evolution of a Palaeozoic continental margin

New geological, geochronological and isotopic data reveal a previously unknown arc system that evolved south of the Kyrgyz Middle Tianshan (MTS) microcontinent during the Middle and Late Ordovician, 467–444 Ma ago. The two fragments of this magmatic arc are located within the Bozbutau Mountains and the northern Atbashi Range, and a marginal part of the arc, with mixed volcanic and sedimentary rocks, extends north to the Semizsai metamorphic unit of the southern Chatkal Range. A continental basement of the arc, indicated by predominantly felsic volcanic rocks in Bozbutau and Atbashi, is supported by whole-rock Nd- and Hf-in-zircon isotopic data. ε_Nd(t) of + 0.9 to − 2.6 and ε_Hf(t) of + 1.8 to − 6.0 imply melting of Neo- to Mesoproterozoic continental sources with Nd model ages of ca. 0.9 to 1.2 Ga and Hf crustal model ages of ca. 1.2 to 1.7 Ga. In the north, the arc was separated from the MTS microcontinent by an oceanic back-arc basin, represented by the Karaterek ophiolite belt. Our inference of a long-lived Early Palaeozoic arc in the southwestern MTS suggests an oceanic domain between the MTS microcontinent and the Tarim craton in the Middle Ordovician.The time of arc-continent collision is constrained as Late Ordovician at ca. 450 Ma, based on cessation of sedimentation on the MTS microcontinent, the age of an angular unconformity within the Karaterek suture zone, and the age of syncollisional metamorphism and magmatism in the Kassan Metamorphic Complex of the southern Chatkal Range. High-grade amphibolite-facies metamorphism and associated crustal melting in the Kassan Metamorphic Complex restricts the main tectonic activity in the collisional belt to ca. 450 Ma. This interpretation is based on the age of a synkinematic amphibolite-facies granite, intruded into paragneiss during peak metamorphism. A second episode of greenschist- to kyanite–staurolite-facies metamorphism is dated between 450 and 420 Ma, based on the ages of granitoid rocks, subsequently affected or not affected by this metamorphism. The latest episode is recorded by greenschist-facies metamorphism in Silurian sandstones and granodiorites and by retrogression of the older, higher-grade rocks. This may have occurred at the Silurian to Devonian transition and reflects reorganization of a Middle Palaeozoic convergent margin.Late Ordovician collision was followed by initiation of a new continental arc in the southern MTS. This arc was active in the Early Silurian, latest Silurian to Middle Devonian, and Late Carboniferous, whereas during the Givetian through Mississippian (ca. 385–325 Ma) this area was a passive continental margin. These arcs, previously well constrained west of the Talas-Ferghana Fault, continued eastwards into the Naryn and Atbashi areas and probably extended into the Chinese Central Tianshan. The disappearance of a major crustal block with transitional facies on the continental margin and too short a distance between the arc and accretionary complex suggest that plate convergence in the Atbashi sector of the MTS was accompanied by subduction erosion in the Devonian or Early Pennsylvanian. This led to a minimum of 50–70 km of crustal loss and removal of the Ordovician arc as well as the Silurian and Devonian forearcs in the areas east of the Talas-Ferghana Fault.     

Carboniferous magmatism and mineralization in the area of the Fuxing Cu deposit,Eastern Tianshan,China: Evidence from zircon U–Pb ages,petrogeochemistry, and Sr–Nd–Hf–O isotopic compositions

The newly discovered Fuxing porphyry Cu deposit is located in the Dananhu–Tousuquan arc, adjacent to the Tuwu–Yandong Cu deposits of Eastern Tianshan, in the southern Central Asian Orogenic Belt. The Fuxing deposit is hosted by volcanic rocks (basalt and dacite) in the Early Carboniferous Qi'eshan Group and Carboniferous felsic intrusions (plagiogranite porphyry, monzogranite, and quartz diorite). New SIMS zircon U–Pb dating indicates that the plagiogranite porphyry and monzogranite emplaced at 332.1 ± 2.2 Ma and 328.4 ± 3.4 Ma, respectively. The basalts are characterized by low SiO₂ contents (47.47–54.90 wt.%), a lack of Eu anomalies, strong depletion of Na, Ta, and Ti elements but positive Sr, U, and Pb anomalies, high Y (20.8–28.2 ppm) and HREE concentrations (Yb = 2.23–3.06 ppm), and relatively low (La/Yb)_N (2.20–3.92) values; the dacite samples have high SiO₂ contents (66.13–76.93 wt.%), clearly negative Eu anomalies, high Mg^# values (36–51), and high Y (41.8–54.9 ppm) and Yb (5.76–8.98 ppm) concentrations. The basalts and dacites exhibit similar signatures as normal arc rocks, and were considered to be derived from partial melting of mantle-wedge peridotite that was previously metasomatized by slab melts. In contrast, the plagiogranite porphyry, monzogranite, and quartz diorite show the same geochemical affinity with modern adakites, which are characterized by high SiO₂ contents (67.55–79.00 wt.%), minor negative to positive Eu anomalies, strong depletion of heavy rare earth elements (Yb = 0.17–1.19 ppm) and Y (1.86–10.1 ppm), positive K, Rb, Sr, and Ba but negative Nb, Ta, Th, and Ti anomalies, and high (La/Yb)_N ratios and Mg^# values. Moreover, these adakitic felsic intrusions display relatively high positive zircon ε_Hf(t) values (+ 11.4 to + 18.3), low ⁸⁷Sr/⁸⁶Sr (0.706080–0.711239), high ¹⁴³Nd/¹⁴⁴Nd (0.512692–0.512922) ratios, and consistent zircon δ¹⁸O values (4.41‰–5.48‰), suggesting that their parental magma were most likely derived from partial melting of the subducted oceanic crust followed by mantle peridotite interaction. Based on the whole-rock geochemical and Sr–Nd–Hf–O isotopic data, as well as detailed petrographic analyses, we further suggest that the Fuxing igneous rocks and associated porphyry Cu mineralization were generated by the northward subduction of the paleo-Tianshan oceanic plate beneath the Dananhu–Tousuquan island arc during the Early Carboniferous.     

Phanerozoic amalgamation of the Alxa Block and North China Craton: Evidence from Paleozoic granitoids,U–Pb geochronology and Sr–Nd–Pb–Hf–O isotope geochemistry

The North China Craton (NCC) has been considered to be part of the supercontinent Columbia. The nature of the NCC western boundary, however, remains strongly disputed. A key question in this regard is whether or not the Alxa Block is a part of the NCC. It is located in the vicinity of the inferred boundary, and therefore could potentially resolve the issue of the NCC's relationship to the Columbia supercontinent. Some previous studies based on the Alxa Block's geological evolution and detrital zircon ages suggested that it is likely not a part of the NCC. The lack of evidence from key igneous rock units, however, requires further constraints on the tectonic affinity of the western NCC and Alxa Block and on the timing of their amalgamation.In this study, new zircon U–Pb age and Hf–O isotopes and whole-rock geochemical and Sr–Nd–Pb isotopic data for the Paleozoic granitoids in or near the eastern Alxa Block were used to constrain the petrogenesis of these rocks and the relationship between the Alxa Block and NCC. Secondary ion mass spectrometry (SIMS) U–Pb zircon dating indicates that the Bayanbulage, Hetun, Diebusige and South Diebusige granitoids were formed at ca. 423 Ma, 345 Ma, 345 Ma and 337 Ma, respectively. The Late Silurian (Bayanbulage) quartz diorites have variable SiO₂ (58.0–67.9 wt.%), and low Sr/Y (20–24) values, while the Early Carboniferous (Hetun, Diebusige and South Diebusige) monzogranites have high SiO₂ (71.5–76.7 wt.%) and Sr/Y (40–94) values. The Late Silurian quartz diorites display relatively homogeneous and high zircon δ¹⁸O (8.5–9.1‰) and ε_Hf(t) (− 8.6 to − 5.3) values, high whole-rock ε_Nd(t) values (− 9.2 to − 7.6) and highly radiogenic Pb isotopes (²⁰⁶Pb/²⁰⁴Pb = 18.13–18.25), whereas the Early Carboniferous monzogranites exhibit relatively low and variable zircon δ¹⁸O (5.7–7.2‰) and ε_Hf(t) (− 23.1 to − 7.4) values, low whole-rock initial ⁸⁷Sr/⁸⁶Sr (0.7043–0.7070) and ε_Nd(t) (− 19.1 to − 13.5) values and variable Pb isotopes (²⁰⁶Pb/²⁰⁴Pb = 16.06–18.22). The differences in whole rock Nd model ages and Pb isotope compositions of the Paleoproterozoic–Permian rocks in either side of the west fault of the Bayanwulashan–Diebusige complexes suggest that the Alxa Block is not a part of the NCC, and that the western boundary of the NCC is probably located on this fault. Furthermore, the linear distribution of the Early Paleozoic–Early Carboniferous granitoids, the high zircon δ¹⁸O values of the Late Silurian quartz diorites, the Early Devonian metamorphism and the foreland basin system formed during the collision between the Alxa Block and the NCC indicate that a Paleozoic cryptic suture zone likely existed in this area and records the amalgamation of the Alxa Block and North China Craton. Together with detrital zircon data, the initial collision was considered to have possibly occurred in Late Ordovician.     

Significance of adakites in petrogenesis of early Silurian magmatism at the Yudai copper deposit in the Kalatag district,NW China

Yudai is a newly discovered copper deposit associated with a porphyritic quartz diorite, in the Kalatag district of the eastern Tianshan, China. SHRIMP U-Pb dating of zircons from the diorite yielded an age of 432 ± 3 Ma. The diorite is peraluminous (ASI = 0.98–1.10), calc-alkaline to tholeiitic with high Al₂O₃ of 16.6–17.7 wt% and Mg^# of 57.4–67.4. Trace element characteristics of the diorite show it is enriched in Ba, K and Sr, and depleted in Nb, Ta, Ti, with a positive Eu anomaly and high Sr/Y and La/Yb ratios. This diorite has positive ε_Nd(t) values ranging from 6.2 to 8.4 with low initial ⁸⁷Sr/⁸⁶Sr ratios of 0.704336 to 0.704450. These geochemical and isotopic characteristics indicate that the adakite-like diorite, associated with the copper mineralization, was emplaced in an island arc setting and resulted from partial melting of subducted oceanic plate in a mantle wedge.     

The Yanbian Terrane (Southern Sichuan Province,SW China): A Neoproterozoic arc assemblage in the western margin of the Yangtze Block

The magmatic and tectonic history of the Yangtze Block and its possible affinity with other Neoproterozoic arc terranes are important elements in the reconstruction of Neoproterozoic plate tectonics. The Yanbian Terrane in the western margin of the Yangtze Block is a typical arc assemblage composed of a flysch-type sedimentary sequence intruded by gabbroic and granodioritic plutons. The sedimentary sequence consists chiefly of tuffaceous material with interlayered chert, sandstone, and pillow basalts. Laser ablation ICP-MS U–Pb dating of detrital zircons from the sandstones yield ages as young as 840 Ma. The Gaojiacun and Lengshuiqing mafic intrusions are dated at 812 ± 3 Ma and 806 ± 4 Ma, respectively, using the SHRIMP zircon U–Pb technique. Geochemical data show that both the Gaojiacun and Lengshuiqing intrusions have arc signatures, with ɛNd(t) values of +1.5 to +6.0, initial ⁸⁷Sr/⁸⁶Sr ratios of 0.705–0.706 and pronounced negative Nb–Ta and Zr–Hf anomalies. Their geochemical variations are best explained by fractional crystallization without major crustal contamination. The Yanbian Terrane represents a typical arc assemblage formed on the western edge of the Yangtze Block during Neoproterozoic time. The sedimentary sequence was deposited in an oceanic setting, probably in a back arc basin environment. The depleted, subduction-modified lithospheric mantle wedge above the subduction zone was the source of melts from which the mafic plutons were crystallized. This scenario suggests subduction of oceanic lithosphere eastward (present-day orientation) underneath the Yangtze Block.     

U–Pb ages of detrital zircons within the Inthanon Zone of the Paleo-Tethyan subduction zone,northern Thailand: New constraints on accretionary age and arc activity

U–Pb dating of detrital zircons was performed on mélange-hosted lithic and basaltic sandstones from the Inthanon Zone in northern Thailand to determine the timing of accretion and arc activity associated with Paleo-Tethys subduction. The detrital zircons have peak ages at 3400–3200, 2600–2400, 1000–700, 600–400, and 300–250 Ma, similar to the peaks ages of detrital zircons associated with other circum-Paleo-Tethys subduction zones. We identified two types of sandstone in the study area based on the youngest detrital zircon ages: Type 1 sandstones have Late Carboniferous youngest zircon U–Pb ages of 308 ± 14 and 300 ± 16 Ma, older than associated radiolarian chert blocks within the same outcrop. In contrast, Type 2 sandstones have youngest zircon U–Pb ages of 238 ± 10 and 236 ± 15 Ma, suggesting a Middle Triassic maximum depositional age. The youngest detrital zircons in Type 1 sandstones were derived from a Late Carboniferous–Early Permian ‘missing’ arc, suggesting that the Sukhothai Arc was active during sedimentation. The data presented within this study provide information on the development of the Sukhothai Arc, and further suggest that subduction of the Paleo-Tethyan oceanic plate beneath the Indochina Block had already commenced by the Late Carboniferous. Significant Middle Triassic arc magmatism, following the Late Carboniferous–Early Permian arc activity, is inferred from the presence of conspicuous detrital zircon U–Pb age peaks in Type 2 sandstones and the igneous rock record of the Sukhothai Arc. In contrast, only minimal arc activity occurred during the Middle Permian–earliest Triassic. Type 1 sandstones were deposited between the Late Permian and the earliest Triassic, after the deposition of associated Middle–Late Permian cherts that occur in the same mélanges and during a hiatus in Sukhothai Arc magmatism. In contrast, Type 2 sandstones were deposited during the Middle Triassic, coincident with the timing of maximum magmatism in the Sukhothai Arc, as evidenced by the presence of abundant Middle Triassic detrital zircons. These two types of sandstone were probably derived from discrete accretionary units in an original accretionary prism that was located along the western margin of the Sukhothai Arc.     

Geochemistry and U–Pb detrital zircon dating of Paleozoic graywackes in East Junggar,NW China: Insights into subduction–accretion processes in the southern Central Asian Orogenic Belt

The southern Central Asian Orogenic Belt (CAOB) is characterized by multiple and linear accretionary orogenic collages, including Paleozoic arcs, ophiolites, and accretionay wedges. A complex history of subduction–accretion processes makes it difficult to distinguish the origin of these various terranes and reconstruct the tectonic evolution of the southern CAOB. In order to provide constraints on the accretionary history, we analyzed major and trace element compositions of Paleozoic graywackes from the Huangcaopo Group (HG) and Kubusu Group (KG) in East Junggar. The HG graywackes have relatively low Chemical Index of Alteration (CIA) values (50 to 66), suggesting a source that underwent relatively weak chemical weathering. The identical average Index of Compositional Variability (ICV) values (~ 1.1) for both the KG and HG samples point to an immature source for the Paleozoic graywackes in East Junggar, which is consistent with an andesitic–felsic igneous source characterized by low La/Th ratios and relatively high Hf contents. These graywackes are geochemically similar to continental island arc sediments and therefore were probably deposited at an active continental margin. U–Pb dating of detrital zircons from the lower subgroup of the HG yielded a young age peak at ~ 440 Ma, indicating a post-Early Silurian depositional age. However, the youngest populations of detrital zircons from the KG graywackes and the upper subgroup of the HG yielded ²⁰⁶Pb/²³⁸U ages of ~ 346 Ma and ~ 355 Ma, respectively, which suggest a post-Early Carboniferous depositional age. Because of similarities of rock assemblages, these two units should be incorporated into the Early Carboniferous Nanmingshui Formation. The detrital zircon age spectrum of the Early Paleozoic HG graywackes resembles that of the Habahe sediments in the Chinese Altai, which suggests that the ocean between East Junggar and the Chinese Altai was closed before the deposition of the sediments and that the Armantai ophiolite was emplaced prior to the Early Devonian. The differences in age spectra for detrital zircons from the post-Early Carboniferous graywackes in East Junggar and the Harlik arc indicate that the emplacement of the Kalamaili ophiolite postdates the Early Carboniferous. Therefore, a long-lasting northward subduction–accretion process is suggested for the formation of East Junggar and the reconstruction of the Early Paleozoic evolution of the southern CAOB.     

A geotraverse across two paleo-subduction zones in Tien Shan,Tajikistan

We present first LA-ICP-MS U–Pb zircon ages as well as geochemical and Sr–Nd–Pb isotope data for 14 magmatic rocks collected along ca. 400 km profile across the Chatkal-Kurama terrane in the Mogol-Tau and Kurama ranges and the Gissar Segment of the Tien Shan orogen in Tajikistan. These new data from supra-subduction and post-collisional magmatic rocks of two Late Paleozoic active margins constrain a tectonic model for terrane motions across two paleo-subduction zones: (1) The 425 Ma old Muzbulak granite of the Mogol-Tau range formed in a supra-subduction setting at the northern margin of the Turkestan Ocean. The north-dipping plate was subducted from the Early Silurian to the earliest Middle Devonian. Thereafter the northern side of the Turkestan Ocean remained a passive margin until the Early Carboniferous. (2) In the Early Carboniferous, subduction under the northern margin of the Turkestan Ocean resumed and the 315 to 305 Ma old Kara-Kiya, Muzbek, and Karamazar intrusions formed in a supra-subduction setting in the Mogol-Tau and Kurama ranges. (3) At the same time, in the Early Carboniferous, rifting of the southern passive margin of the Turkestan Ocean formed the short-lived Gissar Basin, separated from the Turkestan Ocean by the Gissar micro-continent. North-dipping subduction in the Gissar Basin is documented by the 315 Ma Kharangon plagiogranite and the voluminous ca. 321–312 Ma Andean-type supra-subduction Gissar batholith. The Kharangon and Khanaka gabbro-plagiogranite intrusions of the southern Gissar range have geochemical and Sr–Nd isotopic compositions (⁸⁷Sr/⁸⁶Sr(t) 0.7047–0.7056, εNd of + 1.5 to + 2.3) compatible with mantle-derived origin typical for plagiogranites associated with ophiolites. The supra-subduction rocks from the Gissar batholith and from the Mogol-Tau Kurama ranges have variably mixed Sr–Nd–Pb isotopic signatures (⁸⁷Sr/⁸⁶Sr(t) 0.7057–0.7064, εNd of − 2.1 to − 5.0) typical for continental arcs where mantle-derived magmas interact with continental crust. (4) In the latest Carboniferous, the Turkestan Ocean and the Gissar Basin were closed. The Early Permian Chinorsay (288 Ma) and Dara-i-pioz (267 Ma) post-collisional intrusions, emplaced in the northern part of the Gissar micro-continent after a long period of amagmatic evolution, have intraplate geochemical affinities and isotopic Sr–Nd–Pb isotopic compositions (⁸⁷Sr/⁸⁶Sr(t) 0.7074–0.7086, εNd of − 5.5 to − 7.4) indicating derivation from Precambrian continental crust which is supported by old Nd model ages (1.5 and 1.7 Ga), and by the presence of inherited zircon grains with ages 850–500 Ma in the Chinorsay granodiorite. The post-collisional intrusions in the southern Gissar and in the Mogol-Tau and Kurama ranges (297–286 Ma), emplaced directly after supra-subduction magmatic series, have geochemical and isotopic signatures of arc-related magmas. The distinct shoshonitic affinities of post-collisional intrusions in the Mogol-Tau and Kurama ranges are explained by the interaction of hot asthenospheric material with subduction-enriched wedge of lithospheric mantle due to slab break-off at post-collisional stage. Despite origination from different tectonic environments, all magmatic rocks have relatively old Nd model ages (1.7–1.0 Ga) indicating a significant proportion of Paleoproterozoic or older crustal material in their sources and their model ages are similar to those of post-collisional intrusions from the Alai and Kokshaal Segments of the South Tien Shan.     

Constraints of C–O–S–Pb isotope compositions and Rb–Sr isotopic age on the origin of the Tianqiao carbonate-hosted Pb–Zn deposit,SW China

The Tianqiao Pb–Zn deposit in the western Yangtze Block, southwest China, is part of the Sichuan–Yunnan–Guizhou (SYG) Pb–Zn metallogenic province. Ore bodies are hosted in Devonian and Carboniferous carbonate rocks, structurally controlled by a thrust fault and anticline, and carried about 0.38 million tons Pb and Zn metals grading > 15% Pb + Zn. Both massive and disseminated Pb–Zn ores occur either as veinlets or disseminations in dolomitic rocks. They are composed of ore minerals, pyrite, sphalerite and galena, and gangue minerals, calcite and dolomite. δ³⁴S values of sulfide minerals range from + 8.4 to + 14.4‰ and display a decreasing trend from pyrite, sphalerite to galena (δ³⁴S_pyrite > δ³⁴S_sphalerite > δ³⁴S_galena). We interpret that reduced sulfur derived from sedimentary sulfate (gypsum and barite) of the host Devonian to Carboniferous carbonate rocks by thermal–chemical sulfate reduction (TSR). δ¹³C_PDB and δ¹⁸O_SMOW values of hydrothermal calcite range from –5.3 to –3.4‰ and + 14.9 to + 19.6‰, respectively, and fall in the field between mantle and marine carbonate rocks. They display a negative correlation, suggesting that CO₂ in the hydrothermal fluid was a mixture origin of mantle, marine carbonate rocks and sedimentary organic matter. Sulfide minerals have homogeneous and low radiogenic Pb isotope compositions (²⁰⁶Pb/²⁰⁴Pb = 18.378 to 18.601, ²⁰⁷Pb/²⁰⁴Pb = 15.519 to 15.811 and ²⁰⁸Pb/²⁰⁴Pb = 38.666 to 39.571) that are plotted in the upper crust Pb evolution curve and overlap with that of Devonian to Carboniferous carbonate rocks and Proterozoic basement rocks in the SYG province. Pb isotope compositions suggest derivation of Pb metal from mixed sources. Sulfide minerals have ⁸⁷Sr/⁸⁶Sr ratios ranging from 0.7125 to 0.7167, higher than Sinian to Permian sedimentary rocks and Permian Emeishan flood basalts, but lower than basement rocks. Again, Sr isotope compositions are supportive of a mixture origin of Sr. They have an Rb–Sr isotopic age of 191.9 ± 6.9Ma, possibly reflecting the timing of Pb–Zn mineralization. C–O–S–Pb–Sr isotope compositions of the Tianqiao Pb–Zn deposit indicate a mixed origin of ore-forming fluids, which have Pb–Sr isotope homogenized before the mineralization. The Permian flood basalts acted as an impermeable layer for the Pb–Zn mineralization hosted in the Devonian–Carboniferous carbonate rocks.     

Provenance and origins of a Late Paleozoic accretionary complex within the Khangai–Khentei belt in the Central Asian Orogenic Belt,central Mongolia

We have investigated the petrography, geochemistry, and detrital zircon U–Pb LA-ICPMS dating of sandstone from the Gorkhi Formation of the Khangai–Khentei belt in the Ulaanbaatar area, central Mongolia. These data are used to constrain the provenance and source rock composition of the accretionary complex, which is linked to subduction of the Paleo-Asian Ocean within the Central Asian Orogenic Belt during the Middle Devonian to Early Carboniferous. Field and microscopic observations of the modal composition of sandstone and constituent mineral chemistry indicate that the sandstone of the Gorkhi Formation is feldspathic arenite, enriched in saussuritized plagioclase. Geochemical data show that most of the sandstone and shale were derived from a continental margin to continental island arc setting, with plutonic rocks being the source rocks. Detrital zircon ²⁰⁶Pb/²³⁸U ages of two sandstones yields age peaks of 322 ± 3 and 346 ± 3 Ma. The zircon ²⁰⁶Pb/²³⁸U age of a quartz–pumpellyite vein that cuts sandstone has a weighted mean age of 339 ± 3 Ma. Based on these zircon ages, we infer that the depositional age of sandstone within the Gorkhi Formation ranges from 320 to 340 Ma (i.e., Early Carboniferous). The provenance and depositional age of the Gorkhi Formation suggest that the evolution of the accretionary complex was influenced by the intrusion and erosion of plutonic rocks during the Early Carboniferous. We also suggest that spatial and temporal changes in the provenance of the accretionary complex in the Khangai–Khentei belt, which developed aound the southern continental margin of the Siberian Craton in relation to island arc activity, were influenced by northward subduction of the Paleo-Asian Ocean plate.     

Geochronology of the Hongniu-Hongshan porphyry and skarn Cu deposit,northwestern Yunnan province,China: Implications for mineralization of the Zhongdian arc

The Hongniu-Hongshan porphyry and skarn copper deposit is located in the Triassic Zhongdian island arc, northwestern Yunnan province, China. Single-zircon laser ablation inductively coupled plasma mass spectrometry U–Pb dating suggests that the diorite porphyry and the quartz monzonite porphyry in the deposit area formed at 200 Ma and 77 Ma, respectively. A Re–Os isotopic date of molybdenite from the ore is 78.9 Ma, which indicates that in addition to the known Triassic Cu–(Au) porphyry systems, a Late Cretaceous porphyry Cu–Mo mineralization event also exists in the Zhongdian arc. The quartz monzonite porphyry shows characteristics of a magnetite series intrusion, with a high concentration of Al, K, Rb, Ba, and Pb, low amount of Ta, Ti, Y, and Yb, and a high ratio of Sr/Y (average 26.42). The Cretaceous porphyry also shows a strong fractionation between light and heavy rare earth elements (average (La/Yb)_N 37.9), which is similar to those of the Triassic subduction-related diorite porphyry in the Hongniu-Hongshan deposit and the porphyry hosting the Pulang copper deposit. However, in contrast to the older intrusions, the quartz monzonite porphyry contains higher concentrations of large ion lithophile elements and Co, and lesser Sr and Zr. Therefore, whereas the Triassic porphyry Cu–(Au) mineralization is related to slab subduction slab in an arc setting, the quartz monzonite porphyry in the Hongniu-Hongshan deposit formed by the remelting of the residual oceanic slab combined with contributions from subduction-modified arc lithosphere and continental crust, which provided the metals for the Late Cretaceous mineralization.