Nd–Sr–Hf–O isotope provinciality in the northernmost Arabian–Nubian Shield: implications for crustal evolution

Multi-isotope study including whole-rock Nd–Sr, single zircon Hf, and SIMS δ¹⁸O analyses of zircons sheds light on magma sources in the northernmost Arabian–Nubian Shield (ANS) during ~820–570 Ma. Reconnaissance initial Nd and Sr isotope data for the older rocks (~820–740 Ma) reaffirms previous estimates that early crustal evolution in this part of the shield involved some crustal contamination by pre-ANS material. Prominent isotope provinciality is displayed by post-collisional calc-alkaline and alkaline igneous rocks of ~635–570 Ma across a NW-SE transect across basement of the Sinai Peninsula (Egypt) and southern Israel. Silicic rocks of the NW-region are characterized by lower εNd(T)–εHf(T) and higher Sr_i and δ¹⁸O compared with rocks of the SE-region, and the transition between the regions is gradual. Within each region isotope ratios are independent of the extent of magma fractionation, and zircon cores and rims yield similar δ¹⁸O values. Comparison with southern segments of the ANS shows that the source for most ~635–570 Ma rocks can be modeled as the isotopically aged lower-intermediate crust in the ANS core (SE-region) and its northern, more contaminated ANS margins (NW-region). Nevertheless, Nd–Sr isotope enrichment of the lithospheric mantle is indicated by some basic magmas of the NW-region displaying the most enriched Nd–Sr isotope compositions. Comparison of Nd and Hf depleted mantle model ages for rocks of the SE-region may indicate that crustal formation events in the ANS geographical core took place at 1.1–1.2 Ga and were followed by crustal differentiation starting at ~0.9 Ga.     

Pan-African adakitic rocks of the north Arabian–Nubian Shield: petrological and geochemical constraints on the evolution of the Dokhan volcanics in the north Eastern Desert of Egypt

The Precambrian basement of Egypt is part of the Red Sea Mountains and represents the north-western part of the Arabian–Nubian Shield (ANS). Five volcanic sections are exposed in the Egyptian basement complex, namely El Kharaza, Monqul, Abu Had, Mellaha and Abu Marwa. They are located in the north Eastern Desert (ED) of Egypt and were selected for petrological and geochemical studies as they represent the Dokhan volcanics. The volcanics divide into two main pulses, and each pulse was frequently accompanied by deposition of immature molasse type sediments, which represent a thick sequence of the Hammamat group in the north ED. Compositionally, the rocks form a continuum from basaltic andesite, andesite, dacite (lower succession) to rhyodacite and rhyolite (upper succession), with no apparent compositional gaps. These high-K calc-alkaline rocks have strong affinities to subduction-related rocks with enriched LILEs (Rb, Ba, K, Th, Ce) relative to high field strength elements (Nb, Zr, P, Ti) and negative Nb anomalies relative to NMORB. The lower succession displays geochemical characteristics of adakitic rocks with SiO₂ >53 wt%, Al₂O₃ >15 wt%, MgO >2.5 wt%, Mg# >49, Sr >650 ppm, Y <17 ppm, Yb <2 ppm, Ni >25 ppm, Cr >50 ppm and Sr/Y >42.4. They also have low Nb, Rb and Zr compared to the coexisting calc-alkaline rhyodacites and rhyolites. The highly fractionated rhyolitic rocks have strong negative Eu anomalies and possess the geochemical characteristics of A-type suites. Trace element geochemical signatures indicate a magma source consistent with post-collisional suites that retain destructive plate signatures associated with subduction zones. The adakitic rocks in the northern ANS are generated through partial melting of delaminated mafic lower crust interacting with overlying mantle-derived magma. The Dokhan volcanics were likely generated by a combination of processes, including partial melting, crystal fractionation and assimilation.     

Coupled U–Pb–Hf of detrital zircons of Cambrian sandstones from Morocco and Sardinia: Implications for provenance and Precambrian crustal evolution of North Africa

U–Pb–Hf of detrital zircons from diverse Cambrian units in Morocco and Sardinia were investigated in order to clarify the sandstone provenance and how it evolved with time, to assess whether the detrital spectra mirror basement crustal composition and whether they are a reliable pointer on the ancestry of peri-Gondwanan terranes. Coupled with Hf isotopes, the detrital age spectra allow a unique perspective on crustal growth and recycling in North Africa, much of which is concealed below Phanerozoic sediments.In Morocco, the detrital signal of Lower Cambrian arkose records local crustal evolution dominated by Ediacaran (0.54–0.63 Ga) and Late-Paleoproterozoic (1.9–2.2 Ga; Eburnian) igneous activity. A preponderance of the Neoproterozoic detrital zircons possess positive ε_Hf(t) values and their respective Hf model ages (T_DM) concentrate at 1.15 Ga. In contrast, rather than by Ediacaran, the Neoproterozoic detrital signal from the Moroccan Middle Cambrian quartz-rich sandstone is dominated by Cryogenian-aged detrital zircons peaking at 0.65 Ga alongside a noteworthy early Tonian (0.95 Ga) peak; a few Stenian-age (1.0–1.1 Ga) detrital zircons are also distinguished. The majority of the Neoproterozoic zircons displays negative ε_Hf(t), indicating the provenance migrated onto distal Pan-African terranes dominated by crustal reworking. Terranes such as the Tuareg Shield were a likely provenance. The detrital signal of quartz–arenites from the Lower and Middle Cambrian of SW Sardinia resembles the Moroccan Middle Cambrian, but 1.0–1.1 Ga as well as ~ 2.5 Ga detrital zircons are more common. Therefore, Cambrian Sardinia may have been fed from different sources possibly located farther to the east along the north Gondwana margin. 1.0–1.1 Ga detrital zircons abundant in Sardinia generally display negative ε_Hf(t) values while 0.99–0.95 Ga detrital zircons (abundant in Morocco) possess positive ε_Hf(t), attesting for two petrologically-different Grenvillian sources. A paucity of detrital zircons younger than 0.6 Ga is a remarkable feature of the detrital spectra of the Moroccan and Sardinian quartz-rich sandstones. It indicates that late Cadomian orogens fringing the northern margin of North Africa were low-lying by the time the Cambrian platform was deposited. About a quarter of the Neoproterozoic-aged detrital zircons in the quartz-rich sandstones of Morocco (and a double proportion in Sardinia) display positive ε_Hf(t) values indicating considerable juvenile crust addition in North Africa, likely via island arc magmatism. A substantial fraction of the remaining Neoproterozoic zircons which possess negative ε_Hf(t) values bears evidence for mixing of old crust with juvenile magmas, implying crustal growth in an Andean-type setting was also significant in this region.     

Neoproterozoic diamictite in the Eastern Desert of Egypt and Northern Saudi Arabia: evidence of ~750 Ma glaciation in the Arabian–Nubian Shield?

The Neoproterozoic Atud diamictite in Wadi Kareim and Wadi Mobarak in the Eastern Desert of Egypt and the Nuwaybah formation in NW Saudi Arabia consist of poorly sorted, polymictic breccia, with clasts up to 1 m of granitoid, quartz porphyry, quartzite, basalt, greywacke, marble, arkose, and microconglomerate in fine-grained matrix. Stratigraphic relations indicate that the diamictite was deposited in a marine environment. Integrated field investigation, petrographic study and U–Pb SHRIMP zircon ages demonstrate that the Atud and Nuwaybah are correlative. The distribution of zircon ages indicate that ~750 Ma ages are dominant with a significant component of older materials, characterized by minor Mesoproterozoic and more abundant Paleoproterozoic and Neoarchean ages. Some matrix and metasedimentary clast zircons yield ages that are a few 10s of Ma younger than the age of the youngest clast (754 ± 15 Ma), suggesting Atud/Nuwaybah diamictite deposition ~750 Ma or slightly later, broadly consistent with being deposited during the Sturtian glaciation (740–660 Ma). The Paleoproterozoic and Neoarchean clasts have no source within the ensimatic Arabian–Nubian Shield. The distribution of the pre-Neoproterozoic ages are similar to the distribution of the pre-Neoproterozoic ages in Yemen and Saharan Metacraton, suggesting that these clasts have been transported hundreds of kilometers, maybe by ice-rafting. The Atud diamictite may represent important evidence for Cryogenian “Snowball Earth” in the Arabian–Nubian Shield.     

Carbonate alteration of ophiolitic rocks in the Arabian–Nubian Shield of Egypt: sources and compositions of the carbonating fluid and implications for the formation of Au deposits

Ultramafic portions of ophiolitic fragments in the Arabian–Nubian Shield (ANS) show pervasive carbonate alteration forming various degrees of carbonated serpentinites and listvenitic rocks. Notwithstanding the extent of the alteration, little is known about the processes that caused it, the source of the CO₂ or the conditions of alteration. This study investigates the mineralogy, stable (O, C) and radiogenic (Sr) isotope composition, and geochemistry of suites of variably carbonate altered ultramafics from the Meatiq area of the Central Eastern Desert (CED) of Egypt. The samples investigated include least-altered lizardite (Lz) serpentinites, antigorite (Atg) serpentinites and listvenitic rocks with associated carbonate and quartz veins. The C, O and Sr isotopes of the vein samples cluster between ?8.1‰ and ?6.8‰ for δ¹³C, +6.4‰ and +10.5‰ for δ¹⁸O, and ⁸⁷Sr/⁸⁶Sr of 0.7028–0.70344, and plot within the depleted mantle compositional field. The serpentinites isotopic compositions plot on a mixing trend between the depleted-mantle and sedimentary carbonate fields. The carbonate veins contain abundant carbonic (CO₂±CH₄±N₂) and aqueous-carbonic (H₂O-NaCl-CO₂±CH₄±N₂) low salinity fluid, with trapping conditions of 270–300°C and 0.7–1.1 kbar. The serpentinites are enriched in Au, As, S and other fluid-mobile elements relative to primitive and depleted mantle. The extensively carbonated Atg-serpentinites contain significantly lower concentrations of these elements than the Lz-serpentinites suggesting that they were depleted during carbonate alteration. Fluid inclusion and stable isotope compositions of Au deposits in the CED are similar to those from the carbonate veins investigated in the study and we suggest that carbonation of ANS ophiolitic rocks due to influx of mantle-derived CO₂-bearing fluids caused break down of Au-bearing minerals such as pentlandite, releasing Au and S to the hydrothermal fluids that later formed the Au-deposits. This is the first time that gold has been observed to be remobilized from rocks during the lizardite–antigorite transition.     

The Wadi Zaghra metasediments of Sinai,Egypt: new constraints on the late Cryogenian–Ediacaran tectonic evolution of the northernmost Arabian–Nubian Shield

ABSTRACT

The La Tinta mélange is a small but singular ultramafic mélange sheet that crops out in eastern Cuba. It is composed of dolerite-derived amphibolite blocks embedded in a serpentinite matrix. The amphibolite blocks have mid-ocean ridge basalt (MORB)-like composition showing little if any imprint of subduction zone component, similar to most forearc and MOR basalts worldwide. Relict Cr-spinel and olivine mineral chemistry of the serpentinized ultramafic matrix suggest a forearc position for these rocks. These characteristics, together with a hornblende ⁴⁰Ar/³⁹Ar age of 123.2 ± 2.2 Ma from one of the amphibolite blocks, suggest that the protoliths of the amphibolite blocks correspond to forearc basalt (FAB)-related rocks that formed during the earlier stage of subduction initiation of the Early Cretaceous Caribbean arc. We propose that the La Tinta amphibolites correspond to fragments of sills and dikes of hypoabyssal rocks formed in the earlier stages of a subduction initiation scenario in the Pacific realm (ca. 136 Ma). The forearc dolerite-derived amphibolites formed by partial melting of upwelling fertile asthenosphere at the beginning of subduction of the Proto-Caribbean (Atlantic) slab, with no interaction with slab-derived fluids/melts. This magmatic episode probably correlates with Early Cretaceous basic rocks described in Hispaniola (Gaspar Hernandez serpentinized peridotite-tectonite). The dikes and sills cooled and metamorphosed due to hydration at low pressure (ca. 3.8 kbar) and medium to high temperature (up to 720ºC) and reached ca. 500ºC at ca. 123 Ma. At this cooling stage, serpentinite formed after hydration of the ultramafic upper mantle. This process might have been favoured by faulting during extension of the forearc, indicating an early stage of dike and sill fragmentation and serpentinite mélanges formation; however, full development of the mélange likely took place during tectonic emplacement (obduction) onto the thrust belt of eastern Cuba during the latest Cretaceous.     

Zircon U–Pb ages and Hf isotopic compositions from the Sin Quyen Formation: the Precambrian crustal evolution of northwest Vietnam

The location of the suture zone between the South China and Indochina blocks in northwest Vietnam has been under debate for decades. Generally, the boundary between these blocks has been placed along (1) the Ailaoshan–Red River zone or (2) the Song Ma zone. The Sin Quyen Formation, lying between these zones, was previously regarded as a Palaeo- and Mesoproterozoic sequence. It comprises its provenance and tectonic affinity. We analysed detrital zircons from two paragneisses and one migmatite of the Sin Quyen Formation employing laser ablation inductively coupled plasma mass spectrometry U–Pb dating techniques. U–Pb ages of these zircons show three main periods of zircon formation: ～2.7–3.0, ～2.2–2.5, and ～1.8 Ga, suggesting that Sin Quyen rocks were mainly derived from Palaeoproterozoic and Archaean basement units. Inasmuch as the South China basement comprises rocks of similar ages, we conclude that the Sin Quyen Formation belongs to that block. Our new data strengthen the view that the suture between the South China and Indochina blocks is located within the Song Ma zone. In addition, zircons with U–Pb ages >3.0 thousand million years represent the oldest minerals reported in northwest Vietnam so far, indicating the existence of Mesoarchaean crustal remnants in this region.     

Tonian–Ediacaran Tectonometamorphic History of the Sa’al Complex, Sinai (Egypt): Implications for the Tectonostratigraphic Framework of the Northern Arabian–Nubian Shield

The Sa''al Metamorphic Complex (SMC; southern Sinai) encompasses the oldest arc rocks in the Arabian–Nubian Shield, comprising two non-consanguineous metavolcanic successions (the Agramiya Group and the Post-Ra''ayan Formation) separated by the metasediments of the Ra''ayan Formation. It experienced three distinct deformational events (D1–D3) and two low-medium grade regional metamorphic events (M1–M2). The Agramiya Group and the Ra''ayan Formation experienced all tectonometamorphic events (D1–D3 and M1–M2), whereas the Post-Ra''ayan volcanic rocks were only affected by the D3 and M2 events. D1 is an extensional event and is connected to the late Rodinia break-up (~Tonian; 900–870 Ma). The M1 metamorphism variably affected the older Agramiya Group, the rhyolitic tuffs experiencing lower to upper greenschist facies conditions and the basic and intermediate volcanic rocks undergoing amphibolite facies metamorphism. The Ra''ayan Formation metasediments experienced upper greenschist to amphibolite facies metamorphism. The upper greenschist facies M2 affected the youngest Post-Ra''ayan volcanic rocks and other stratigraphic successions. The compressive D2 and D3 events were coeval with the accretion of dismembered terranes in the assembly of Gondwana. D2 can be linked to the Tonian–Cryogenian arc-arc assembly (~880–760 Ma; in Elat and Sinai), whereas D3 and the accompanying M2 is constrained to 622–600 Ma (Ediacaran).     

U–Pb TIMS age constraints on the evolution of the Neoproterozoic Meatiq Gneiss Dome,Eastern Desert,Egypt

Ages are used to constrain the temporal evolution of the Meatiq Gneiss Dome, Eastern Desert, Egypt, by dating (ID-TIMS) pre-, syn-, and post-tectonic igneous rocks in and around the dome. The Um Ba’anib Orthogneiss, comprising the deepest exposed structural levels of the dome, has a crystallization age of 630.8 ± 2 Ma. The overlying mylonites are interpreted to be a thrust sheet/complex (Abu Fannani Thrust Sheet) of highly mylonitized metasediments (?), migmatitic amphibolites, and orthogneisses with large and small tectonic lenses of less-deformed intrusives. Two syn-tectonic diorite lenses in this complex have crystallization ages of 609.0 ± 1.0 and 605.8 ± 0.9 Ma, respectively. The syn-tectonic Abu Ziran diorite, cutting across the tectonic contact between mylonite gneisses of the Abu Fannani Thrust Sheet and a structurally overlying thrust sheet of eugeoclinal rocks (“Pan-African nappe”), has a magmatic emplacement age of 606.4 ± 1.0 Ma. Zircons from a gabbro (Fawakhir ophiolite) within the eugeoclinal thrust sheet yielded a crystallization age of 736.5 ± 1.2 Ma. The post-tectonic Fawakhir monzodiorite intrudes the ophiolitic rocks and has an emplacement age of 597.8 ± 2.9 Ma. Two other post-tectonic granites, the Arieki granite that intrudes the foliated Um Ba’anib Orthogneiss, and the Um Had granite that cuts the deformed Hammamat sediments, have emplacement ages of 590 ± 3.1 and 596.3 ± 1.7 Ma, respectively. We consider formation of the Meatiq Gneiss Dome to be a young structural feature (<631 Ma), and our preferred tectonic interpretation is that it formed as a result of NE–SW shortening contemporaneous with folding of the nearby Hammamat sediments around 605–600 Ma, during oblique collision of East and West Gondwana.     

Zircon Hf–isotopic mapping for understanding crustal architecture and metallogenesis in the Eastern Qinling Orogen

The Eastern Qinling Orogen (EQO) is a major composite collisional zone located between the North China and the Yangtze cratons. This contribution combines geological and Hf–isotopic data from magmatic rocks associated with mineralization to gain insights into links between the crust architecture and metallogeny, and to focus exploration in the orogen.The new zircon U–Pb dates reported in this study are 434 ± 2 Ma for diorite, 433 ± 2 and 436 ± 2 Ma for monzogranite, and 454 ± 2 Ma for granodiorite in the Nanzhao area; 225 ± 2 Ma for syenite and 160 ± 1 Ma for monzogranite at Songxian; and 108 ± 1 and 102 ± 1 Ma for syenogranite in eastern Fangcheng. Combining our data with those from the entire EQO reveals seven major magmatic events since the Cambrian. These magmatic events took place during the Cambrian–Silurian associated with subduction, Early Devonian magmatism related to a collisional event, Early Permian to Late Triassic magmatism related to subduction, Late Triassic collisional magmatism, Late Triassic to Early Jurassic post–collision magmatism, and Jurassic–Cretaceous magmatism during intra–continental subduction.Lu-Hf isotopic data collected from granitic rocks for this study give εHf(t) values of: − 1.4 to 10.9 for diorite and monzogranite at Nanzhao; − 27.1 to − 15.6 for syenite and − 27.5 to − 25.1 for monzogranite at Songxian; and − 12.9 to − 3.4 for syenogranite in the eastern Fangcheng. Combining Hf isotopic data for the EQO from previous studies, we have evaluated the spatio–temporal distribution of Hf isotopic compositions. The resultant Hf isotopic maps highlight the location of the Kuanping Suture as an important tectonic boundary between the North China and the Yangtze cratons, which separates the EQO into a north part with an old and reworked lower crust and a southern part representing a juvenile lower crust.The Hf isotopic mapping of the EQO also provides information on the distribution of mineral deposits. Porphyry and porphyry–skarn Mo(–W) deposits are associated with magmatic rocks were emplaced in zones with low–εHf and high T_DM^c values representing old and reworked crustal components. In contrast, porphyry and porphyry–skarn Cu(–Mo) deposits are associated with magmatic rocks emplaced in domains with variable εHf and T_DM^c values characterized by dominantly reworked old crustal components with minor juvenile material. The magmatic source for the intrusions is characterized by low–εHf and high T_DM^c values, which are granite–related Mo or Pb–Zn–Ag mineralization.     

Tectonostratigraphy and depositional history of the Neoproterozoic volcano-sedimentary sequences in Kid area,southeastern Sinai,Egypt: Implications for intra-arc to foreland basin in the northern Arabian–Nubian Shield

This paper presents a stratigraphic and sedimentary study of Neoproterozoic successions of the South Sinai, at the northernmost segment of the Arabian–Nubian Shield (ANS), including the Kid complex. This complex is composed predominantly of thick volcano-sedimentary successions representing different depositional and tectonic environments, followed by four deformational phases including folding and brittle faults (D₁–D₄). The whole Kid area is divisible from north to south into the lower, middle, and upper rock sequences. The higher metamorphic grade and extensive deformational styles of the lower sequence distinguishes them from the middle and upper sequences. Principal lithofacies in the lower sequence include thrust-imbricated tectonic slice of metasediments and metavolcanics, whereas the middle and upper sequences are made up of clastic sediments, intermediate-felsic lavas, volcaniclastics, and dike swarms. Two distinct Paleo- depositional environments are observed: deep-marine and alluvial fan regime. The former occurred mainly during the lower sequence, whereas the latter developed during the other two sequences. These alternations of depositional conditions in the volcano-sedimentary deposits suggest that the Kid area may have formed under a transitional climate regime fluctuating gradually from warm and dry to warm and humid conditions.Geochemical and petrographical data, in conjunction with field relationships, suggest that the investigated volcano-sedimentary rocks were built from detritus derived from a wide range of sources, ranging from Paleoproterozoic to Neoproterozoic continental crust. Deposition within the ancient Kid basin reflects a complete basin cycle from rifting and passive margin development, to intra-arc and foreland basin development and, finally, basin closure. The early phase of basin evolution is similar to various basins in the Taupo volcanics, whereas the later phases are similar to the Cordilleran-type foreland basin. The progressive change in lithofacies from marine intra-arc basin to continental molasses foreland basin and from compression to extension setting respectively, imply that the source area became peneplained, where the Kid basin became stabilized as sedimentation progressed following uplift. The scenario proposed of the study area supports the role of volcanic and tectonic events in architecting the facies and stratigraphic development.     

Lu–Hf constraints on pre-, syn,and post-collision associations of the Gurupi Belt,Brazil: Insights on the Rhyacian crustal evolution

The Gurupi Belt (together with the São Luís cratonic fragment), in north-northeastern Brazil, has been described in previous studies that used extensive field geology, structural analysis, airborne geophysics, zircon U–Pb dating, and whole-rock Sm–Nd isotope and geochemical data as a polyphase orogenic belt, with the Rhyacian being the main period of crust formation. This was related to a 2240 Ma to 2140 Ma accretionary processes that produced juvenile crust, which has subsequently been reworked during a collisional event at 2100 ± 20 Ma, with little evidence of Archean crust. In this study, we use Lu–Hf isotopic data in zircon from granitoids (including gneiss) of variable magmatic series, and amphibolite to improve the knowledge of this scenario, and investigate additional evidence of recycling of Archean basement. Pre-collisional high Ba-Sr and ferroan granitoids and amphibolite formed in island arc (2180–2145 Ma), show only zircons with suprachondritic εHf values (ca. +1 to +8) indicating the large predominance of juvenile magmas. Only 10% of the data show slightly negative εHf values (0 to ?4), which have been observed in granodiorite-gneiss formed in continental arc (2170–2140 Ma), and in strongly peraluminous collisional granites (2125–2070 Ma), indicating the rework of older Paleoproterozoic to Archean components (Hf_TDM = 2.11–3.69 Ga). A two-component mixing model using both Hf and published Nd isotope data are in line with this interpretation and indicate more than 90% of juvenile material, and less influence of Archean materials. Comparing with other Rhyacian terranes that are interpreted to have been close to Gurupi in a pre-Columbia configuration (ca. 2.0 Ga), our results differ from those of SE-Guiana Shield, which show strong influence of Archean protoliths, and are very similar to those of the central-eastern portion of the Baoulé-Mossi Domain of the West African Craton, which has also been formed largely by juvenile magmas in an accretionary-collisional orogen.     

U–Pb ID-TIMS dating of igneous and metaigneous rocks from the El-Sibai area: time constraints on the tectonic evolution of the Central Eastern Desert,Egypt

This paper presents new ID-TIMS U–Pb zircon and titanite ages from the El-Sibai gneiss complex in the Eastern Desert of Egypt. The zircon data support previous studies, indicating that the protoliths of the gneissic (oldest) units in the area were emplaced during the East African orogeny, and do not represent an older pre-Neoproterozoic, reworked cratonic basement. The crystallization ages of three compositionally distinct orthogneiss protoliths are c. 685, 682 and 679 Ma, respectively. A U–Pb titanite age from one orthogneiss overlaps with the protolith age, indicating that the gneisses did not undergo post-magmatic high-temperature metamorphism. The gneissic textures of the rocks are therefore interpreted to reflect syn-emplacement deformation. This, and evidence for static amphibolite facies metamorphism in country-rock metavolcanics, lead us to conclude that the gneisses of El-Sibai do not represent an exhumed middle crustal gneiss dome, but are part of the island arc affined allochthon into which they were emplaced synchronously with NW-ward nappe translation. We also report ages from rocks cross-cutting the gneisses and the surrounding island arc affined assemblages that yield the hitherto youngest robust pre-Cretaceous intrusive ages in the Eastern Desert. The dated rocks are an anorthosite and a cross-cutting syenogranite giving ages of c. 541 and 540 Ma, respectively. We consider this late magmatic pulse to be anorogenic, most likely reflecting a separate extensional event involving asthenospheric upwelling and decompression melting of the mantle.     

U–Pb and Lu–Hf isotopes in detrital zircon from Neoproterozoic sedimentary rocks in the northern Yangtze Block: Implications for Precambrian crustal evolution

A combined study of Lu–Hf isotopes and U–Pb ages for detrital zircons from sedimentary rocks can provide information on the crustal evolution of sedimentary provenances, and comparisons with potential source regions can constrain interpretations of paleogeographic settings. Detailed isotopic data on detrital zircons from Neoproterozoic sedimentary rocks in the northern part of the Yangtze Block suggest that these rocks have the maximum depositional ages of ~ 750 Ma, and share a similar provenance. In their source area, units of late Archean (2.45 to 2.55 Ga) to Paleoproterozoic (1.9 to 2.0 Ga) U–Pb ages made up the basement, and were overlain or intruded by magmatic rocks of Neoproterozoic U–Pb ages (740 to 900 Ma). Hf isotopic signatures of the detrital zircons indicate that a little juvenile crust formed in the Neoarchean; reworking of old crust dominates the magmatic activity during the Archean to Paleoproterozoic, while the most significant juvenile addition to the crust occurred in the Neoproterozoic. Only the Neoproterozoic zircon U–Pb ages can be matched with known magmatism in the northern Yangtze Block, while other age peaks cannot be correlated with known provenance areas. Similar zircon U–Pb ages have been obtained previously from sediments along the southeastern and western margins of the Yangtze Block. Thus, it is suggested that an unexposed old basement is widespread beneath the Yangtze Block and was the major contributor to the Neoproterozoic sediments. This basement had a magmatic activity at ~ 2.5 Ga, similar to that in North China; but zircon Hf isotopes suggest significant differences in the overall evolutionary histories between the Yangtze and North China.     

Paleo- to Eoarchean crustal evolution in eastern Hebei,North China Craton: New evidence from SHRIMP U–Pb dating and in-situ Hf isotopic study of detrital zircons from paragneisses

In the Caozhuang complex in eastern Hebei, North China Craton, the Paleo- to Eoarchean crustal evolution was earlier revealed by the preservation of detrital zircon grains older than (or as old as) 3.8 Ga in fuchsite-quartzite. In order to test if the Eoarchean antiquity is also preserved in rocks other than the fuchsite quartzite, we collected two paragneisses, a hornblende gneiss and a garnet–biotite gneiss, from Huangbaiyu village and dated their detrital zircon grains. The zircon dating of the hornblende gneiss yielded concordant ²⁰⁷Pb/²⁰⁶Pb ages ranging from 3684 to 3354 Ma. However, an older date of 3782 Ma with 18% discordancy was also obtained. Detrital zircon grains from the garnet–biotite gneiss gave a similar ²⁰⁷Pb/²⁰⁶Pb age range, from 3838 to 3342 Ma. The metamorphic domains of the zircon grains from both samples, including the strongly recrystallized cores and rims, recorded an overprinting metamorphism at ca. 2.5 Ga, which correlates with the most widespread tectono-thermal event in the North China Craton. In situ zircon Hf-isotope analyses on the dated zircon grains yielded a wide range of model ages (T_DM1) from 4.0 to 3.3 Ga with corresponding ε_Hf(T) from −36.0 to +4.8. This suggests that the evolution of the crustal segment in this area has involved multiple phases of juvenile crustal addition as well as recycling of older crustal rocks. The new geochronological results imply the presence of a significant amount of Eoarchean crustal fragments in the eastern Hebei area. The sedimentary protoliths of the paragneisses and other high-grade metamorphic rocks in the Caozhuang complex were probably deposited between 3.4 and 2.5 Ga.     

The U–Pb ages and Hf isotopes of detrital zircons from Hainan Island,South China: implications for sediment provenance and the crustal evolution

In situ U–Pb dating and Hf isotopic of detrital zircons from beach sediments of Yalong Bay were analyzed to trace sedimentary provenance and reveal the crustal evolution of Hainan Island in South China. The grain size distribution of the sediments displays a clear single-peak feature, indicating the sediments were formed under the same condition of hydrodynamic force. The detrital zircons had Th/U ratios of greater than 0.1, and REE pattern displayed a positive Ce anomaly and a negative Eu anomaly, indicating that these zircons are predominantly of magmatic origin. The U–Pb spectrum of detrital zircons mainly peaked at the Yanshanian (96–185 Ma), Hercynian–Indosinian (222–345 Ma) and Caledonian (421–477 Ma). A portion of the detrital zircons were of Neoproterozoic origin (728–1,003 Ma), which revealed that the basement in the eastern region of Hainan Island was mainly of Neoproterozoic, with rare Archean materials. The positive ε _Hf(t) values (0 to +10.1) of the Neoproterozoic detrital zircons indicated that the juvenile crust grew in the southeastern Hainan Island mainly during the Neoproterozoic period. The Neoproterozoic orogeny in the southeastern part of the island (0.7–1.0 Ga) occurred later than in the northwestern region of the island (1.0–1.4 Ga). Importantly, the Grenvillian orogeny in the southeastern area of Hainan Island shared the same timing with that of the western Cathaysia Block; i.e., both areas concurrently underwent this orogenic event, thereby forming a part of the Rodinia supercontinent. Afterwards, the crust experienced remelting and reworking during the Caledonian Hercynian–Indosinianand Yanshanian accompanied by the growth of a small amount of juvenile crust.     

U–Pb ages and Hf isotopic record of zircons from the late Neoproterozoic and Silurian–Devonian sedimentary rocks of the western Yangtze Block: Implications for its tectonic evolution and continental affinity

The relationship of the Yangtze Block with other continental blocks of the Rodinia and Gondwana supercontinents is hotly debated. Here we report U–Pb and Lu–Hf isotopic data for zircons from the latest Neoproterozoic Yanjing Group and the overlying Silurian–Devonian rocks on the western margin of Yangtze Block, which provide critical constraints on the provenance of these sediments and further shed light on the crustal evolution and tectonic affinity of the western Yangtze Block in the context of Rodinia and the subsequent Gondwanaland. Mica schist from the middle part of the Yanjing Group contains dominant Neoproterozoic detrital zircons (0.72–0.80 Ga) with a pronounced age peak at 0.75 Ga. Based on the euhedral to subhedral shapes, high Th/U ratios and exclusively positive εHf(t) values (+ 6 to + 14) for the zircon crystals, and the lack of ancient zircons, we consider the sediments as products of proximal deposition near a Neoproterozoic subduction system in western Yangtze. Combined with the age of rhyolite from the lower part of the Yanjing Group, these strata were estimated to have been deposited in a period between 0.72 and 0.63 Ga. In contrast, the Silurian–Devonian sediments exhibit dominant Grenvillian ages (0.9–1.0 Ga), with middle Neoproterozoic (0.73–0.85 Ga), Pan-African (0.49–0.67 Ga) and Neoarchean (~ 2.5 Ga) age populations, suggesting a significant change of sedimentary provenance and thus a different tectonic setting. Although the shift occurred in the Silurian, the age spectra turn to be consistent along the western margin of the Yangtze Block until the Devonian, indicating persistence of the same sedimentary environment. However, the related provenance of these Paleozoic sediments cannot be found in South China. The presence of abundant Grenvillian, Pan-African and Neoarchean ages, along with their moderately to highly rounded shapes, indicates the possibility of exotic continental terrane(s) as a possible sedimentary provenance. Considering the potential source areas around the Yangtze Block when it was part of the Rodinia or Gondwana, we suggest that the source of these Paleozoic sediments had typical Gondwana affinities such as the Himalaya region, north India, which is also supported by their stratigraphic similarity, newly published paleomagnetic data and the tectono-thermal events of northwestern fragments of Gondwana. This implies that after a prolonged subduction in the Neoproterozoic, the western margin of the Yangtze Block began to incorporate into the assembly of the Gondwana supercontinent and was able to accept sediments from northwestern margin of Gondwanaland as a result of early Paleozoic orogeny.     

U–Pb and Lu–Hf isotope systematics of detrital zircons from the Songpan–Ganzi Triassic flysch,NE Tibetan Plateau: implications for provenance and crustal growth

We conducted in situ U–Pb and Lu–Hf isotope analyses of 401 detrital zircons collected from the Songpan–Ganzi Triassic turbidite complex in an attempt to understand the provenance variations of the siliciclastic rocks and the crustal growth history of central China. These detrital zircons exhibit a wide age spectrum with three major peaks at 1.7–2.0 Ga, 750–1050 Ma, and 210–500 Ma. They are dominated by negative ?_Hf(t) values with a large range. Synthesis of the zircon U–Pb and Lu–Hf isotopic data indicate that the Triassic Songpan–Ganzi turbiditic succession could have been derived dominantly from the Tibetan terrains + the Kunlun and Qinling orogens. Our samples are characterized by a common, prominent group of Hf crust formation model ages at 0.8–4.1 Ga with a peak at 2.7–3.4 Ga. This fact indicates that (1) Phanerozoic magmatism in central China could have been predominantly products of crustal reworking with insignificant formation of juvenile crust and (2) the Neoarchaean was an important period of continental growth in central China. In addition, our data set also reveal that three widespread tectonothermal events could have occurred in the region during the late Mesoproterzoic, Palaeozoic, and early Mesozoic, respectively.