Products of meteoric metal ion chemistry within planetary atmospheres. 1. Mg at Titan

We report results of quantum chemical calculations of Mg⁺/ligand bond dissociation energies involving ligands identified as major constituents of Titan's upper atmosphere. Trends identified in these results allow elucidation of the important bimolecular and termolecular reactions of Mg⁺, and of simple molecular ions containing Mg⁺, arising from meteoric infall into Titan's atmosphere. Our study highlights, and includes calculated rate coefficients for, crucial ligand-switching and ligand-stripping reactions which ensure that a dynamic equilibrium exists between atomic and molecular ions of Mg⁺. Neutralization of ionized meteoric Mg is expected to produce the radical MgNC in high yield. The highly polar MgNC radical should provide an excellent nucleation site for condensation of polar (e.g., HCN, CH₃CN, and HC₃N) and highly unsaturated (e.g., C₂H₂, C₄H₂, and C₂N₂) neutrals at comparatively high altitude, leading to precipitation of Mg-doped tholin-like material. The implications for Titan's prebiotic chemical evolution, of the surface deposition of such material (which may feasibly contain magnesium porphyrins, or other bioactive Mg-containing complexes) remain to be assessed.     

A photochemical model of Titan's atmosphere and ionosphere

A global-mean model of coupled neutral and ion chemistry on Titan has been developed. Unlike the previous coupled models, the model involves ambipolar diffusion and escape of ions, hydrodynamic escape of light species, and calculates the H₂ and CO densities near the surface that were assigned in some previous models. We tried to reduce the numbers of species and reactions in the model and remove all species and reactions that weakly affect the observed species. Hydrocarbon chemistry is extended to C₁₂H₁₀ for neutrals and C₁₀H⁺₁₁ for ions but does not include PAHs. The model involves 415 reactions of 83 neutrals and 33 ions, effects of magnetospheric electrons, protons, and cosmic rays. UV absorption by Titan's haze was calculated using the Huygens observations and a code for the aggregate particles. Hydrocarbon, nitrile, and ion chemistries are strongly coupled on Titan, and attempt to calculate them separately (e.g., in models of ionospheric composition) may result in significant error. The model densities of various species are typically in good agreement with the observations except vertical profiles in the stratosphere that are steeper than the CIRS limb data. (A model with eddy diffusion that facilitates fitting to the CIRS limb data is considered as well.) The CO densities are supported by the O⁺ flux from Saturn's magnetosphere. The ionosphere includes a peak at 80 km formed by the cosmic rays, steplike layers at 500-700 and 700-900 km and a peak at 1060 km (SZA = 60°). Nighttime densities of major ions agree with the INMS data. Ion chemistry dominates in the production of bicyclic aromatic hydrocarbons above 600 km. The model estimates of heavy positive and negative ions are in reasonable agreement with the Cassini results. The major haze production is in the reactions C₆H + C₄H₂, C₃N + C₄H₂, and condensation of hydrocarbons below 100 km. Overall, precipitation rate of the photochemical products is equal to 4-7 kg cm⁻² Byr⁻¹ (50-90 m Byr⁻¹ while the global-mean depth of the organic sediments is ∼3 m). Escape rates of methane and hydrogen are 2.9 and 1.4 kg cm⁻² Byr⁻¹, respectively. The model does not support the low C/N ratio observed by the Huygens ACP in Titan's haze.     

Model-data comparisons for Titan's nightside ionosphere

Solar and X-ray radiation and energetic plasma from Saturn's magnetosphere interact with the upper atmosphere producing an ionosphere at Titan. The highly coupled ionosphere and upper atmosphere system mediates the interaction between Titan and the external environment. A model of Titan's nightside ionosphere will be described and the results compared with data from the Ion and Neutral Mass Spectrometer (INMS) and the Langmuir probe (LP) part of the Radio and Plasma Wave (RPWS) experiment for the T5 and T21 nightside encounters of the Cassini Orbiter with Titan. Electron impact ionization associated with the precipitation of magnetospheric electrons into the upper atmosphere is assumed to be the source of the nightside ionosphere, at least for altitudes above 1000 km. Magnetospheric electron fluxes measured by the Cassini electron spectrometer (CAPS ELS) are used as an input for the model. The model is used to interpret the observed composition and structure of the T5 and T21 ionospheres. The densities of many ion species (e.g., CH⁺₅ and C₂H⁺₅) measured during T5 exhibit temporal and/or spatial variations apparently associated with variations in the fluxes of energetic electrons that precipitate into the atmosphere from Saturn's magnetosphere.     

Ion chemistry and N-containing molecules in Titan's upper atmosphere

High-energy photons, electrons, and ions initiate ion-neutral chemistry in Titan's upper atmosphere by ionizing the major neutral species (nitrogen and methane). The Ion and Neutral Mass Spectrometer (INMS) onboard the Cassini spacecraft performed the first composition measurements of Titan's ionosphere. INMS revealed that Titan has the most compositionally complex ionosphere in the Solar System, with roughly 50 ions at or above the detection threshold. Modeling of the ionospheric composition constrains the density of minor neutral constituents, most of which cannot be measured with any other technique. The species identified with this approach include the most complex molecules identified so far on Titan. This confirms the long-thought idea that a very rich chemistry is actually taking place in this atmosphere. However, it appears that much of the interesting chemistry occurs in the upper atmosphere rather than at lower altitudes. The species observed by INMS are probably the first intermediates in the formation of even larger molecules. As a consequence, they affect the composition of the bulk atmosphere, the composition and optical properties of the aerosols and the flux of condensable material to the surface. In this paper, we discuss the production and loss reactions for the ions and how this affects the neutral densities. We compare our results to neutral densities measured in the stratosphere by other instruments, to production yields obtained in laboratory experiments simulating Titan's chemistry and to predictions of photochemical models. We suggest neutral formation mechanisms and highlight needs for new experimental and theoretical data.     

Negative ion chemistry in Titan's upper atmosphere

The Electron Spectrometer (ELS), one of the sensors making up the Cassini Plasma Spectrometer (CAPS) revealed the existence of numerous negative ions in Titan's upper atmosphere. The observations at closest approach (∼1000 km) show evidence for negatively charged ions up to ∼10,000 amu/q, as well as two distinct peaks at 22±4 and 44±8 amu/q, and maybe a third one at 82±14 amu/q. We present the first ionospheric model of Titan including negative ion chemistry. We find that dissociative electron attachment to neutral molecules (mostly HCN) initiates the formation of negative ions. The negative charge is then transferred to more acidic molecules such as HC₃N, HC₅N or C₄H₂. Loss occurs through associative detachment with radicals (H and CH₃). We attribute the three low mass peaks observed by ELS to CN⁻, C₃N⁻/C₄H⁻ and C₅N⁻. These species are the first intermediates in the formation of the even larger negative ions observed by ELS, which are most likely the precursors to the aerosols observed at lower altitudes.     

A fast computation of the diurnal secondary ion production in the ionosphere of Titan

We propose an analytic model that allows rapid computation of the secondary ion production due to electron impact from the primary photo-production in the ionosphere of Titan. The model parameters are given for each of the 5 major ion productions (N⁺₂, CH⁺₄, N⁺, CH⁺₃, N⁺⁺₂) as well as for the electron production.     

Detection of CH3D on Titan

We report the detection of ¹³CH₃D in Titan's stratosphere from Cassini/CIRS infrared spectra near 8.7 μm. Fitting simultaneously the ν₆ bands of both ¹³CH₃D and ¹²CH₃D and the ν₄ band of CH₄, we derive a D/H ratio equal to and a ¹²C/¹³C ratio in deuterated methane of , consistent with that measured in normal methane.     

Coupled ion and neutral rotating model of Titan's upper atmosphere

A one-dimensional composition model of Titan's upper atmosphere is constructed, coupling 36 neutral species and 47 ions. Energy inputs from the Sun and from Saturn's magnetosphere and updated temperature and eddy coefficient parameters are taken into account. A rotating technique at constant latitude and varying local-time is proposed to account for the diurnal variation of solar inputs. The contributions of photodissocation, neutral chemistry, ion-neutral chemistry, and electron recombination to neutral production are presented as a function of altitude and local time. Local time-dependent mixing ratio and density profiles are presented in the context of the TA and T₅ Cassini data and are compared in detail to previous models. An independent and simplified ion and neutral scheme (19-species) is also proposed for future 3D-purposes. The model results demonstrate that a complete understanding of the chemistry of Titan's upper atmosphere requires an understanding of the coupled ion and neutral chemistry. In particular, the ionospheric chemistry makes significant contributions to production rates of several important neutral species.     

Latitudinal transport by barotropic waves in Titan's stratosphere.: II. Results from a coupled dynamics-microphysics-photochemistry GCM

We present a 2D general circulation model of Titan's atmosphere, coupling axisymmetric dynamics with haze microphysics, a simplified photochemistry and eddy mixing. We develop a parameterization of latitudinal eddy mixing by barotropic waves based on a shallow-water, longitude-latitude model. The parameterization acts locally and in real time both on passive tracers and momentum. The mixing coefficient varies exponentially with a measure of the barotropic instability of the mean zonal flow. The coupled GCM approximately reproduces the Voyager temperature measurements and the latitudinal contrasts in the distributions of HCN and C₂H₂, as well as the main features of the zonal wind retrieved from the 1989 stellar occultation. Wind velocities are consistent with the observed reversal time of the North-South albedo asymmetry of 5 terrestrial years. Model results support the hypothesis of a non-uniform distribution of infrared opacity as the cause of the Voyager temperature asymmetry. Transport by the mean meridional circulation, combined with polar vortex isolation may be at the origin of the latitudinal contrasts of trace species, with eddy mixing remaining restricted to low latitudes most of the Titan year. We interpret the contrasts as a signature of non-axisymmetric motions.     

Latitudinal transport by barotropic waves in Titan's stratosphere.: I. General properties from a horizontal shallow-water model

We present a numerical study of barotropic waves in Titan's stratosphere based on a shallow-water model. The forcing of the zonal flow by the mean meridional circulation is represented by a relaxation towards a barotropically unstable wind profile. The relaxation profile is consistent with observations and with previous results from a 3D general circulation model. The time constant of the forcing that best matches the northward eddy-transport of zonal momentum from the 3D model is τ∼5 Titan days. The eddy wind field is a zonal wavenumber-2 wave with a peak amplitude about 10% of the mean wind speed. The latitudinal transport of angular momentum by the wave tends to keep the flow close to marginal stability by carrying momentum upgradient, from the core of the jets into the low latitudes. Although the strongest eddy motions occur at the latitudes of the wind maxima, the strongest mixing takes place at the barotropically unstable regions, close to ±30° and spanning about 30° in latitude. An eddy-mixing time constant of the order of 1 Titan day is inferred within these regions, and of a few tens of days within regions of stable flow. Horizontal gradients in transient tracer fields are less than 10% of the latitudinal gradient of the meridional tracer profile. Cassini's detection of such waves could provide a direct observation of wind speeds at stratospheric levels.     

Titan trace gaseous composition from CIRS at the end of the Cassini-Huygens prime mission

This paper reports on the results from an extensive study of all nadir-looking spectra acquired by Cassini/CIRS during the 44 flybys performed in the course of the nominal mission (2004-2008). With respect to the previous study (Coustenis, A., and 24 colleagues [2007]. Icarus 189, 35-62, on flybys TB-T10) we present here a significantly richer dataset with, in particular, more data at high northern and southern latitudes so that the abundances inferred here at these regions are more reliable. Our enhanced high-resolution dataset allows us to infer more precisely the chemical composition of Titan all over the disk. We also include improved spectroscopic data for some molecules and updated temperature profiles. The latitudinal distributions of all of the gaseous species are inferred. We furthermore test vertical distributions essentially for acetylene (C₂H₂) from CIRS limb-inferred data and from current General Circulation Models for Titan and compare our results on all the gaseous abundances with predictions from 1-D photochemical-radiative models to check the reliability of the chemical reactions and pathways.     

Dune-forming winds on Titan and the influence of topography

Numerous extended dunes on Saturn's moon Titan detected by the Cassini RADAR constrain the long-term pattern of surface winds. We analyse the statistics of surface wind speed and direction and their spatial and temporal variability predicted by a general circulation model (GCM) in order to constrain surface wind predictions of this GCM by dune observations. The model shows that modern winds are sufficient for saltation and dune formation at low latitudes, in agreement with the presence of dunes there. The best condition for the dune-forming wind occurs with a threshold friction speed of 0.02 m s⁻¹ or slightly less. The equatorial region is conducive to longitudinal dunes because of a combined effect of a high sand drift potential and obtuse bimodal wind pattern oblique to the equator caused by the seasonal reversal of the Hadley circulation. The cross-equatorial wind is steady, and is characterised by a high Weibull shape parameter (k∼4). The wind pattern at higher latitudes is more complex and gusty, and neither longitudinal nor transversal dunes would be able to form. Putative large-scale topography is found to have a profound influence on the near-surface wind pattern. Generally mountains cause a convergence and speeding up on the flank, while basins weaken the wind and cause a divergent flow. Longitudinal dunes can be deflected on the foot of mountains by up to 90°. If Xanadu is a hypothetical large mountain, a wind pattern converging in Xanadu that entirely disagrees with the dune observations is predicted. If instead Xanadu is a large basin, the wind arcs clockwise north of Xanadu and anti-clockwise west and southwest of Xanadu, in agreement with the dune orientations in the vicinity of Xanadu. The albedo pattern has comparatively little influence on the wind field. Isolated mountain chains cause only local-scale change in the wind pattern. However, the persistent surface easterlies in Belet, which are in conflict with the dune orientations, do not disappear by any combination of large-scale topography.     

Analysis of Titan's neutral upper atmosphere from Cassini Ion Neutral Mass Spectrometer measurements

In this paper we present an in-depth study of the distributions of various neutral species in Titan's upper atmosphere, between 950 and 1500 km for abundant species (N₂, CH₄, H₂) and between 950 and 1200 km for other minor species. Our analysis is based on a large sample of Cassini/INMS (Ion Neutral Mass Spectrometer) measurements in the CSN (Closed Source Neutral) mode, obtained during 15 close flybys of Titan. To untangle the overlapping cracking patterns, we adopt Singular Value Decomposition (SVD) to determine simultaneously the densities of different species. Except for N₂, CH₄, H₂ and ⁴⁰Ar (as well as their isotopes), all species present density enhancements measured during the outbound legs. This can be interpreted as a result of wall effects, which could be either adsorption/desorption of these molecules or heterogeneous surface chemistry of the associated radicals on the chamber walls. In this paper, we provide both direct inbound measurements assuming ram pressure enhancement only and abundances corrected for wall adsorption/desorption based on a simple model to reproduce the observed time behavior. Among all minor species of photochemical interest, we have firm detections of C₂H₂, C₂H₄, C₂H₆, CH₃C₂H, C₄H₂, C₆H₆, CH₃CN, HC₃N, C₂N₂ and NH₃ in Titan's upper atmosphere. Upper limits are given for other minor species.The globally averaged distributions of N₂, CH₄ and H₂ are each modeled with the diffusion approximation. The N₂ profile suggests an average thermospheric temperature of 151 K. The CH₄ and H₂ profiles constrain their fluxes to be and , referred to Titan's surface. Both fluxes are significantly higher than the Jeans escape values. The INMS data also suggest horizontal/diurnal variations of temperature and neutral gas distribution in Titan's thermosphere. The equatorial region, the ramside, as well as the nightside hemisphere of Titan appear to be warmer and present some evidence for the depletion of light species such as CH₄. Meridional variations of some heavy species are also observed, with a trend of depletion toward the north pole. Though some of the above variations might be interpreted by either the solar-driven models or auroral-driven models, a physical scenario that reconciles all the observed horizontal/diurnal variations in a consistent way is still missing. With a careful evaluation of the effect of restricted sampling, some of the features shown in the INMS data are more likely to be observational biases.     

Titan solar occultation observed by Cassini/VIMS: Gas absorption and constraints on aerosol composition

A solar occultation by Titan's atmosphere has been observed through the solar port of the Cassini/VIMS instrument on January 15th, 2006. Transmission spectra acquired during solar egress probe the atmosphere in the altitude range 70 to 900 km at the latitude of 71° S. Several molecular absorption bands of CH₄ and CO are visible in these data. A line-by-line radiative transfer calculation in spherical geometry is used to model three methane bands (1.7, 2.3, 3.3 μm) and the CO 4.7 μm band. Above 200 km, the methane 2.3 μm band is well fit with constant mixing ratio between 1.4 and 1.7%, in agreement with in situ and other Cassini measurements. Under 200 km, there are discrepancies between models and observations that are yet fully understood. Under 480 km, the 3.3 μm CH₄ band is mixed with a large and deep additional absorption. It corresponds to the C-H stretching mode of aliphatic hydrocarbon chains attached to large organic molecules. The CO 4.7 μm band is observed in the lower stratosphere (altitudes below 150 km) and is well fit with a model with constant mixing ratio of 33±10 ppm. The continuum level of the observed transmission spectra provides new constraints on the aerosol content of the atmosphere. A model using fractal aggregates and optical properties of tholins produced by Khare et al. [Khare, B.N., Sagan, C., Arakawa, E.T., Suits, F., Callcott, T.A., Williams, M.W., 1984. Icarus 60, 127-137] is developed. Fractal aggregates with more than 1000 spheres of radius 0.05 μm are needed to fit the data. Clear differences in the chemical composition are revealed between tholins and actual haze particles. Extinction and density profiles are also retrieved using an inversion of the continuum values. An exponential increase of the haze number density is observed under 420 km with a typical scale height of 60 km.     

The post-terminator ionosphere of Venus

We have modeled the near and post-terminator thermosphere/ionosphere of Venus with a view toward understanding the relative importance of EUV solar fluxes and downward fluxes of atomic ions transported from the dayside in producing the mean ionosphere. We have constructed one-dimensional thermosphere/ionosphere models for high solar activity for seven solar zenith angles (SZAs) in the dusk sector: 90°, 95°, 100°, 105°, 110°, 115° and 125°. For the first 4 SZAs, we determine the optical depths for solar fluxes from 3 Å to 1900 Å by integrating the neutral densities numerically along the slant path through the atmosphere. For SZAs of 90°, 95°, and 100°, we first model the ionospheres produced by absorption of the solar fluxes alone; for 95°, 100°, and 105° SZAs, we then model the ion density profiles that result from both the solar source and from imposing downward fluxes of atomic ions, including O⁺, Ar⁺, C⁺, N⁺, H⁺, and He⁺, at the top of the ionospheric model in the ratios determined for the upward fluxes in a previous study of the morphology of the dayside (60° SZA) Venus ionosphere. For SZAs of 110°, 115° and 125°, which are characterized by shadow heights above about 300 km, the models include only downward fluxes of ions. The magnitudes of the downward ion fluxes are constrained by the requirement that the model O⁺ peak density be equal to the average O⁺ peak density for each SZA bin as measured by the Pioneer Venus Orbiter Ion Mass Spectrometer. We find that the 90° and 95° SZA model ionospheres are robust for the solar source alone, but the O⁺ peak density in the “solar-only” 95° SZA model is somewhat smaller than the average value indicated by the data. A small downward flux of ions is therefore required to reproduce the measured average peak density of O⁺. We find that, on the nightside, the major ion density peaks do not occur at the altitudes of peak production, and diffusion plays a substantial role in determining the ion density profiles. The average downward atomic ion flux for the SZA range of 90–125° is determined to be about 1.2 × 10⁸ cm⁻² s⁻¹.     

Clouds on Titan during the Cassini prime mission: A complete analysis of the VIMS data

We use data from the VIMS instrument on board the Cassini spacecraft to construct high sensitivity and high spatial-resolution maps of the locations of tropospheric clouds on Titan in the late northern winter season during which the Cassini prime mission took place. These observations show that, in this season, clouds on Titan are strongly hemispherically asymmetric. Mid-latitude clouds, in particular, occur only in the southern hemisphere and have not ever been observed in the north. Such an asymmetry is in general agreement with circulation models where sub-solar surface heating controls the locations of clouds and appears in conflict with models where perennial polar hazes prevent significant summertime polar heating from affecting the circulation. The southern mid-latitude clouds appear to be distributed uniformly in longitude, in contrast to some previous observations. Southern high-latitude clouds exhibit a significant concentration, however, between about 180° and 270°E longitude. A spatially and temporally uniform cloud always appears northward of ∼50°N latitude. This cloud appears unchanged over the course of the observations, consistent with the interpretation that it is caused by continuous ethane condensation as air subsides and radiatively cools through the tropopause. The location of this cloud likely provides a direct tracer of elements of north polar atmospheric circulation, potentially allowing continuous monitoring of circulation changes as Titan passes through equinox into north polar spring and summer. We show that a similar analysis of this dataset by Rodriguez et al. (2009) contains substantial errors and should not be used.     

Discharge experiments simulating chemical evolution on the surface of Titan

Saturn's moon Titan has been considered as one of the few places in our Solar System, where atmospheric and surface conditions could have produced organic compounds essential as precursors for an evolution of life. The Cassini-Huygens mission has provided new data on Titan's atmosphere and surface, which enabled us to simulate the chemical processes occurring under these conditions. Possible lightning events on Titan cannot only produce higher hydrocarbons, but also allow surface water ice to participate in the reaction scenario, resulting in CHO, CHN, and CHON compounds including several molecules relevant for the formation of amino acids and nucleic acids.     

Low temperature (39-298 K) kinetics study of the reactions of the C4H radical with various hydrocarbons observed in Titan's atmosphere

The reaction kinetics of the butadinyl radical, C₄H, with various hydrocarbons detected in the atmosphere of Titan (methane, ethane, propane, acetylene, ethene and methylacetylene) are studied over the temperature range of 39-298 K using the Rennes CRESU (Cinétique de Réaction en Ecoulement Supersonique Uniforme) apparatus. Kinetic measurements were made using the pulsed laser photolysis—laser induced fluorescence technique. The rate coefficients, except for the reaction with methane, all show a negative temperature dependence and can be fitted with the following expressions over the temperature range of this study: ; ; , , . These expressions are not intended to be physically meaningful but rather to provide an easy way to introduce experimental results in photochemical models. They are only valid over the temperature range of the experiments. Possible channels of these reactions are discussed as well as possible consequences of these results for the production of large molecules and hazes in the atmosphere of Titan. These results should also be considered for the photochemistry of Giant Planets.     

Impact of atmospheric gravity waves on the jovian ionosphere

We investigate the effects of atmospheric gravity waves on the vertical and horizontal structure of the ionosphere of Jupiter. The presented non-linear, two-dimensional model of the jovian ionosphere allows for spatially and temporally varying neutral wind and temperature fields and tracks the time evolution of six ionospheric species, , and . An analytical approach is used to validate the model results for linear, small-amplitude waves and to elucidate the mechanisms that leads to perturbations in the density of the main ion species, H⁺ and . We demonstrate that the long-lived H⁺ ions are perturbed directly by wave dynamics whereas short-lived ions such as are perturbed by chemical interactions with other perturbed ion species. The model is then applied using larger gravity wave amplitudes consistent with observations. Atmospheric gravity waves propagating at high altitudes create layers of enhanced electron density similar to the system of layers observed during the J0-ingress radio occultation of the Galileo spacecraft. Our best fit to the J0-ingress observation is achieved using an 82 min period forcing wave with horizontal and vertical wavelengths of 500 km and 60 km respectively, and peaks at 510 km above the 1 bar pressure level. We further investigate the effects of the wave-induced ion flux on the background ionospheric structure and demonstrate that in the presence of a gravity wave the background density profiles of the H⁺ and ions are significantly modified. We also find that the column density of has variations that can exceed 10% as the wave propagates.     

Titan's atmospheric chemistry: Photolysis of gas mixtures containing hydrogen cyanide and carbon monoxide at 185 and 254 nm

The formation of organic compounds in the atmosphere of Titan is an ongoing process of the generation of complex organics from the simplest hydrocarbon, methane. Solar radiation and magnetosphere electrons are the main energy sources that drive the reactions in Titan's atmosphere. Since energy from solar radiation is 200 times greater than that from magnetosphere electrons, we have investigated the products formed by the action of UV radiation (185 and 254 nm) on a mixture of gases containing nitrogen, methane, hydrogen, acetylene, ethylene, and cyanoacetylene, the basic gas mixture (BGM) that simulates aspects of Titan's atmosphere using a flow reactor [Tran, B.N., Ferris, J.P., Chera, J.J., 2003a. Icarus 162, 114-124; Tran, B.N., Joseph, J.C., Force, M., Briggs, R.G., Vuitton, V., Ferris, J.P., 2005. Icarus 177, 106-115]. The present research extends these studies by the addition of carbon monoxide and hydrogen cyanide to the BGM. Quantum yields for the loss of reactants and the formation of volatile products were determined and compared with those measured in the absence of the hydrogen cyanide and carbon monoxide. The GCMS analyses of the volatile photolysis products from the BGM, with added hydrogen cyanide, had a composition similar to that of the BGM while the photolysis products of the BGM with added carbon monoxide contained many oxygenated compounds. The infrared spectrum of the corresponding solid product revealed the absorption band of a ketone group, which was probably formed from the reaction of carbon monoxide with the free radicals generated by photolysis of acetylene and ethylene. Of particular interest was the observation that the addition of HCN to the gas mixture only resulted in a very small change in the C/N ratio and in the intensity of the CN frequency at 2210 cm⁻¹ in the infrared spectrum suggesting that little HCN is incorporated into the haze analog. The C/N ratio of the haze analogs was found to be in the 10-12 range. The UV spectra of the solid products formed when HCN or CO added to the BGM is similar to the UV absorption formed from the BGM alone. This result is consistent with absence of additional UV chromophores to the solid product when these mixtures are photolyzed. The following photoproducts, which were not starting materials in our photochemical studies, have been observed on Titan: acetonitrile, benzene, diacetylene, ethane, propene, propane, and propyne.