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1.
High Potential Regions for Enhanced Geothermal Systems in Canada   总被引:1,自引:0,他引:1  
Previous estimates of geothermal energy potential in Canada give an indication of available heat to be ‘farmed’ at depth. This article examines in more detail depth–temperature relationships near large population centers in western Canada, as well as remote communities in northern Canada, in order to provide a first order assessment of Enhanced Geothermal Systems (EGS) potential for electrical generation. Quantities of EGS thermal power output and electrical generation are dependent on output temperature and flow rate. We relate these potential power rates as a whole to drilling and installation cost for the doublet systems and triplet system. Results show areas with significant EGS potential in northern Alberta, northeastern British Columbia, and southern Northwest Territories related to high heat flow and thermal blanketing of thick sedimentary cover. Estimated installation costs in 2008 dollars are under 2 mln$/MWe. We also estimate significant reductions in CO2 emissions by conversion to geothermal electric production.  相似文献   

2.
青藏高原北部五道梁地表热量平衡方程中各分量特征   总被引:4,自引:0,他引:4  
利用青藏高原北部五道梁地区实测的太阳辐射及气象资料,计算分析了高原北部地面热量平衡方程中各分量特征,定义了一个无量纲参量土壤热平衡系数k。结果显示:五道梁地区地表净辐射及地面加热场强度表现为夏季大,冬季小,地表净辐射累年平均通量为65.5 W/m2;土壤热通量自1997年来有增大的趋势;土壤热平衡系数有增大的趋势,平均值为1.17;感热及潜热是地面热平衡方程中的大项,其中感热居首位,潜热居其次;暖季感热、潜热以相反的趋势变化,Bowen比β值有下降的趋势。  相似文献   

3.
We developed an inference model to infer dissolved organic carbon (DOC) in lakewater from lake sediments using visible-near-infrared spectroscopy (VNIRS). The inference model used surface sediment samples collected from 160 Arctic Canada lakes, covering broad latitudinal (60–83°N), longitudinal (71–138°W) and environmental gradients, with a DOC range of 0.6–39.6 mg L−1. The model was applied to Holocene lake sediment cores from Sweden and Canada and our inferences are compared to results from previous multiproxy paleolimnological investigations at these two sites. The inferred Swedish and Canadian DOC profiles are compared, respectively, to inferences from a Swedish-based VNIRS-total organic carbon (TOC) model and a Canadian-based diatom-inferred (Di-DOC) model from the same sediment records. The 5-component Partial Least Squares (PLS) model yields a cross-validated (CV) RCV2 R_{CV}^{2}  = 0.61 and a root mean squared error of prediction (RMSEP CV ) = 4.4 mg L−1 (11% of DOC gradient). The trends inferred for the two lakes were remarkably similar to the VNIRS-TOC and the Di-DOC inferred profiles and consistent with the other paleolimnological proxies, although absolute values differed. Differences in the calibration set gradients and lack of analogous VNIRS signatures in the modern datasets may explain this discrepancy. Our results corroborate previous geographically independent studies on the potential of using VNIRS to reconstruct past trends in lakewater DOC concentrations rapidly.  相似文献   

4.
Sieving samples for chironomid analysis with a 150 μm mesh was shown to greatly reduce sample preparation time, and use of only larger specimens did not affect chironomid-inferred salinities in African lakes. Here, we tested if this method is suitable for temperature reconstruction in colder lakes at higher latitudes. Removal of specimens <150 μm in two training sets, one from Canada and one from Sweden, had little impact on the performance statistics of the calibration models. Chironomid abundance, however, decreased greatly because more than half of the head capsules in assemblages were <150 μm. This had major impacts on the temperature reconstructions. Inferences were on average 2°C warmer with the modified models (all specimens >150 μm) than those obtained with the full model (all specimens >100 μm). General patterns of temperature change were also altered. For Lake 7 on Southampton Island, Canada, a cooling trend was reconstructed with the full Canadian model while the modified Canadian model yielded a warming trend. When only specimens >150 μm were used, two to three times more wet sediment was needed to obtain a sufficient number of head capsules. These results indicate that, in cold lakes (mean July/August air temperature ≤11°C), large proportions of head capsules are <150 μm, and sieving the samples in a 150 μm mesh leads to altered temperature reconstructions.  相似文献   

5.
《Polar Science》2014,8(2):166-182
The larch forests on the permafrost in northeastern Mongolia are located at the southern limit of the Siberian taiga forest, which is one of the key regions for evaluating climate change effects and responses of the forest to climate change. We conducted long-term monitoring of seasonal and interannual variations in hydrometeorological elements, energy, and carbon exchange in a larch forest (48°15′24′′N, 106°51′3′′E, altitude: 1338 m) in northeastern Mongolia from 2010 to 2012. The annual air temperature and precipitation ranged from −0.13 °C to −1.2 °C and from 230 mm to 317 mm. The permafrost was found at a depth of 3 m. The dominant component of the energy budget was the sensible heat flux (H) from October to May (H/available energy [Ra] = 0.46; latent heat flux [LE]/Ra = 0.15), while it was the LE from June to September (H/Ra = 0.28, LE/Ra = 0.52). The annual net ecosystem exchange (NEE), gross primary production (GPP), and ecosystem respiration (RE) were −131 to −257 gC m−2 y−1, 681–703 gC m−2 y−1, and 423–571 gC m−2 y−1, respectively. There was a remarkable response of LE and NEE to both vapor pressure deficit and surface soil water content.  相似文献   

6.
Defining temperature at depth to identify geothermal resources relies on the evaluation of the Earth heat flow based on equilibrium temperature measurements as well as thermal conductivity and heat generation rate assessment. Such high-quality geothermal data can be sparse over the region of interest. This is the case of the St. Lawrence Lowlands sedimentary basin covering 20,000 km2 to the south of Québec, Canada, and enclosing only three wells up to a depth of 500 m with equilibrium heat flow measurements. However, more than 250 oil and gas exploration wells have been drilled in this area, providing for this study (parce que c'est 93 sinon) 81 locations with bottom-hole temperature up to a depth of 4300 m, however, not at equilibrium. Analyzing these data with respect to the deep geothermal resource potential of this sedimentary basin requires evaluating the thermal conductivity and heat generation rate of its geological units to properly extrapolate temperature downward. This was done by compiling literature and recent thermal conductivity measurements in outcrop and core samples as well as new heat generation rate estimates from spectral gamma ray logs to establish a first thermal assessment of geological units deep down into the basin. The mean thermal conductivity of the thermal units varies from 2.5 to 6.3 W/m·K, with peak values in the basal sandstones, while the heat generation rate varies from 1.6 to 0.3 µW/m3, decreasing from the upper caprocks toward the base of the sequence. After correcting the bottom-hole temperatures for drilling disturbance with the Harrison correction and subsequently for paleoclimate variations, results indicate a mean geothermal gradient of 23.1 °C/km, varying from 14 to 40 °C/km. Evaluating the basin thermal state from oil and gas data is a significant challenge facilitated by an understanding of its thermal properties.  相似文献   

7.
The apparent isotope enrichment factor εmacrophyte of submerged plants (εmacrophyte–DIC = δ13Cmacrophyte − δ13CDIC) is indicative of dissolved inorganic carbon (DIC) supply in neutral to alkaline waters and is related to variations in aquatic productivity (Papadimitriou et al. in Limnol Oceanogr 50:1084–1095, 2005). This paper aims to evaluate the usage of εmacrophyte inferred from isotopic analyses of submerged plant fossils in addition to analyses of lake carbonate as a palaeolimnological proxy for former HCO3 concentrations. Stable carbon isotopic analysis of modern Potamogeton pectinatus leaves and its host water DIC from the Tibetan Plateau and Central Yakutia (Russia) yielded values between −23.3 and +0.4‰ and between +14.0 and +6.5‰, respectively. Values of ε Potamogeton–DIC (range −15.4 to +1.1‰) from these lakes are significantly correlated with host water HCO3 concentration (range 78–2,200 mg/l) (r = −0.86; P < 0.001), thus allowing for the development of a transfer function. Palaeo-ε Potamogeton–ostracods values from Luanhaizi Lake on the NE Tibetan Plateau, as inferred from the stable carbon isotope measurement of fossil Potamogeton pectinatus seeds (range −24 to +2.8‰) and ostracods (range −7.8 to +7.5%) range between −14.8 and 1.6‰. Phases of assumed disequilibrium between δ13CDIC and δ13Costracods known to occur in charophyte swards (as indicated by the deposition of charophyte fossils) were excluded from the analysis of palaeo-ε. The application of the ε Potamogeton–DIC-HCO3 transfer function yielded a median palaeo-HCO3 -concentration of 290 mg/l. Variations in the dissolved organic carbon supply compare well with aquatic plant productivity changes and lake level variability as inferred from a multiproxy study of the same record including analyses of plant macrofossils, ostracods, carbonate and organic content.  相似文献   

8.
We analyzed surface-sediment samples collected along transects from three sub-basins of a relatively large (~115 ha), bathymetrically complex lake, in northwest Ontario, Canada, to assess the reproducibility of diatom species habitats and diversity along a water-depth gradient. Transects displayed different orientations with respect to prevailing wind direction and varied in complexity and degree of slope along the lake bottom. Each transect consisted of three replicate samples at a resolution of ~1 m water depth from ~1 to 30 m for the two deep-basin transects and from ~1 to 18 m in the shallower basin. Distinct diatom assemblages were identified in all transects: (1) a near-shore community composed largely of attached life-forms and some motile benthic taxa, (2) a mid-depth community composed largely of motile life-forms and other benthic taxa that are adapted to lower light conditions (e.g. Staurosirella pinnata), and (3) a deep-water community dominated by planktonic taxa. Species richness was highest in the benthic zones (<9 m), with greatest species evenness in the mid-depth zone (~3–9 m). Species richness and evenness were highly correlated across the three transects (r = 0.89–0.93, p < 0.01). Diatom-inferred depth models were developed from the individual transects to assess reproducibility and applicability for down-core analyses using modern analog (MAT) and weighted-averaging (WA-PLS) approaches. Coefficients of determination (r 2) for these models ranged from 0.80 to 0.98, and RMSEP ranged from 1.2 to 4.2 m. The models developed from the transect with the highest resolution sampling, gentlest non-complex slope and shallowest maximum depth were the strongest ( r\textMAT2 = 0.97 r_{\text{MAT}}^{2} = 0.97 ; r\textWA - PLS2 = 0.98 r_{\text{WA - PLS}}^{2} = 0.98 ) and had the lowest RMSEP (MAT = 1.2 m, WA-PLS = 1.3 m). These inference models can be used to infer past fluctuations in the depth of the benthic/planktonic boundary from cores retrieved near this ecotone and provide a sensitive record of the past change in location of the benthic zone. These types of data can be used to assess past variability in droughts and lake levels to better plan for potential future extremes. Such records incorporate more realistic estimates of natural variability than the ~100-year instrumental records currently used by water resource managers.  相似文献   

9.
This paper describes an assessment of the enhanced geothermal system (EGS) resource base of the conterminous United States, using constructed temperature at depth maps. The temperature at depth maps were computed from 3 to 10 km, for every km. The methodology is described. Factors included are sediment thickness, thermal conductivity variations, distribution of the radioactive heat generation and surface temperature based on several geologic models of the upper 10 km of the crust. EGS systems are extended in this paper to include coproduced geothermal energy, and geopressured resources. A table is provided that summarizes the resource base estimates for all components of the EGS geothermal resource. By far, the conduction-dominated components of EGS represent the largest component of the U.S. resource. Nonetheless, the coproduced resources and geopressured resources are large and significant targets for short and intermediate term development. There is a huge resource base between the depths of 3 and 8 km, where the temperature reaches 150–250°C. Even if only 2% of the conventional EGS resource is developed, the energy recovered would be equivalent to roughly 2,500 times the annual consumption of primary energy in the U.S. in 2006. Temperatures above 150°C at those depths are more common in the active tectonic regions of the western conterminous U.S., but are not confined to those areas. In the central and eastern U.S. there are identified areas of moderate size that are of reasonable grade and probably small areas of much higher grade than predicted by this analyses. However because of the regional (the grid size is 5′ × 5′) scale of this study such potentially promising sites remain to be identified. Several possible scenarios for EGS development are discussed. The most promising and least costly may to be developments in abandoned or shut-in oil and gas fields, where the temperatures are high enough. Because thousands of wells are already drilled in those locations, the cost of producing energy from such fields could be significantly lowered. In addition many hydrocarbon fields are producing large amounts of co-produced water, which is necessary for geothermal development. Although sustainability is not addressed in this study, the resource is so large that in at least some scenarios of development the geothermal resource is sustainable for long periods of time.  相似文献   

10.
We inferred late Pleistocene and early Holocene (24–10 ka BP) environmental conditions in and around Lago Petén Itzá, Guatemala from ostracode remains in the lake sediments. Multivariate statistics were run on autecological information for 29 extant ostracode species collected in 63 aquatic ecosystems on the Yucatán Peninsula along a steep, increasing NW–S precipitation gradient and across a large altitudinal range. Conductivity and water depth are the most important factors that shape ostracode communities. Transfer functions were developed and applied to fossil ostracode assemblages in a ~76-m sediment core (PI-6, ~85 ka) taken in 71 m of water from Lago Petén Itzá, to infer past shifts in conductivity and water level. Results suggest climate was cold and wet during the Last Glacial Maximum (LGM). Alternating dry and wet conditions characterized the deglacial. Early Holocene climate was warmer and wetter. The LGM was characterized by low ostracode species richness (4 spp.) and abundance (<940 valves g−1), dominance of benthic over nektobenthic taxa, abundant Physocypria globula, conductivity as low as 190 μS cm−1, and clay-rich sediments with relatively high total organic carbon and low C/N ratios (<14), suggesting relatively deeper water at the core site associated with abundant precipitation. Greatest water depth at the core site during the LGM occurred late in the period and was ~50 m. The deglacial was characterized by drier conditions, higher ostracode species richness (6 spp.) and abundances up to 18,115 valves g−1, dominance of nektobenthic species, and presence of shallow-water and littoral-zone indicators such as Heterocypris punctata and Strandesia intrepida, conductivity up to 550 μS cm−1, C/N ratios as high as 37, and gypsum deposition. Lowest inferred lake depth at the core site during the deglacial was ~20 m. The early Holocene was characterized by high numbers of ostracode remains, up to 25,500 valves g−1, and the presence of L. opesta and P. globula. Cytheridella ilosvayi was absent from late Pleistocene sediments, suggesting it colonized northern Central America during the Holocene.  相似文献   

11.
Summary. A non-steady-state theoretical model is used to predict the present variation of temperature with depth in two boreholes in the Devon Island ice cap, Arctic Canada. The boreholes are 300 m apart and one of them reaches bedrock. The heat transfer equation is solved numerically with the record of past temperatures obtained from measurements of the variations of oxygen—isotope ratio with depth in the cores as surface boundary condition. The effects of ice advection, refreezing of meltwater percolating from the surface (the amount of which is recorded in the cores), heating due to firn compaction and ice deformation, and heat flow in the bedrock below the ice sheet are all included in the model. The free parameters are geothermal heat flux, present surface temperature and heat loss at the surface which depends on the depth of meltwater penetration and other factors. Agreement between observed and predicted temperature—depth profiles is very close. Latent heat released by percolating meltwater is the predominating factor in determining the temperature distribution in the upper half of each borehole. The temperature distribution is insensitive to the value of the factor used to convert oxygen—isotope ratio to temperature.  相似文献   

12.
Freshwater Lake Ulubat (z mean = 1.5–2.0 m and Area = ~138 km2), NW Anatolia, Turkey was filled in by fine-to-medium-grain silts during the late Holocene. Deposition in Lake Ulubat has been 1.6 cm year−1 for the last 50 years, but the sedimentation rate over the last ~1,600 years was lower (0.37 mm year−1). The organic matter and carbonate contents of the infill show cyclic changes that reflect environmental fluctuations. The silt-dominated lithology and the vertically uniform heavy metal distributions are probably due to wind-controlled sedimentation in the lake. Heterogeneous mud, derived from a large, mountainous drainage basin, is deposited in the lake mostly during summer, June to October, when conditions are hot and calm. Winter months are stormier and sediments are re-suspended due to the shallow water depth and the effect of waves on the lake bottom. It is likely that re-suspended sediments, particularly fine-grained particles, together with the heavy metals, are transported out of the lake via the outlet, especially during periods of high lake level. This resuspension and removal process probably caused the lake sediments to become silt-dominated and depleted in heavy metals. The role of broad shallow lakes in sequestering sediments and heavy metals can be described more accurately when wind data are considered. Such information may also be helpful for land-use planning in downstream areas.  相似文献   

13.
采用哈尔滨市1989,2001,2007年Landsat TM遥感影像资料,利用单窗算法对地面温度进行反演,分析哈尔滨市热场的分布情况,并与20世纪90年代地形图结合来分析道路系统间的温度情况及其与城市热岛的关系。结果表明:铁路和公路温度差异显著且处于不同温度区的铁路温度也有显著的差异;铁路沿线地区热岛效应比较显著,铁路能使周围一定区域温度升高;公路系统作为一种特殊的廊道系统,对城市热岛有一定的阻隔、减缓作用;哈尔滨市铁路对热岛的影响范围不超过300 m,公路对城市热岛的降温作用最大值不超过0.4℃,在120 m以外降低作用很小或没有;绿化率的不同也影响道路对城市热岛的作用效果。  相似文献   

14.
Geothermal exploration is typically limited to high-grade hydrothermal reservoirs that are usually found in the western United States, yet large areas with subsurface temperatures above 150°C at economic drilling depths can be found east of the Rocky Mountains. The object of this paper is to present new heat flow data and to evaluate the geothermal potential of Texas and adjacent areas. The new data show that, west of the Ouachita Thrust Belt, the heat flow values are lower than east of the fault zone. Basement heat flow values for the Palo Duro and Fort Worth Basins are below 50 mW/m2 while, in the frontal zone of the belt, they can exceed 60 mW/m2. Further east, along the Balcones fault system the heat flow is in general higher than 55 mW/m2. The eastern most heat flow sites are in Louisiana and they show very high heat flow (over 80 mW/m2), which is associated with the apparently highly radioactive basement of the Sabine uplift. The geothermal resource in this area is large and diverse, and can be divided in high grade (temperature above 150°C) convective systems, conductive based enhanced geothermal systems and geothermal/geopressured systems. One of the most attractive areas east of the cordillera extends from eastern Texas across Louisiana and Arkansas to western Mississippi. Here temperatures reach exploitation range at depths below 4 km, and tapping such a resource from shut in hydrocarbon fields is relatively easy. The initial costs of the development can be greatly reduced if existing hydrocarbon infrastructure is used, and therefore using shut-in hydrocarbon fields for geothermal purposes should not be neglected.  相似文献   

15.
主要利用2003年和2008年两次夏季北极科学考察的CTD数据处理了加拿大海盆上层海洋的热含量(这里上层海洋指的是200m以上的海洋),定量分析了热含量随深度的变化,并比较分析了这两年在夏季海冰融化期间热含量的垂向差异变化,以及影响热含量变化的因素,给出了上层海洋热含量在加拿大海盆的空间分布。2008年与2003年相比最显著的变化是在加拿大海盆开阔水域的增加,这将导致太阳辐射能进入海洋中的能量增加,同时海冰的大量融化带来了大量淡水,这些变化改变了上层海洋的温盐性质。海冰大量融化主要产生两个效应:一是上层海洋的普遍增暖,二是太平洋入流水体的下移。文中还分析了近年来在加拿大海盆中变化显著的次表层暖水现象,由于次表层暖水蕴含着不小的热含量,其在上层海洋热量平衡中的作用不容忽视。  相似文献   

16.
The analysis of chironomid taxa and environmental datasets from 46 New Zealand lakes identified temperature (February mean air temperature) and lake production (chlorophyll a (Chl a)) as the main drivers of chironomid distribution. Temperature was the strongest driver of chironomid distribution and consequently produced the most robust inference models. We present two possible temperature transfer functions from this dataset. The most robust model (weighted averaging-partial least squares (WA-PLS), n = 36) was based on a dataset with the most productive (Chl a > 10 μg l−1) lakes removed. This model produced a coefficient of determination () of 0.77, and a root mean squared error of prediction (RMSEPjack) of 1.31°C. The Chl a transfer function (partial least squares (PLS), n = 37) was far less reliable, with an of 0.49 and an RMSEPjack of 0.46 Log10μg l−1. Both of these transfer functions could be improved by a revision of the taxonomy for the New Zealand chironomid taxa, particularly the genus Chironomus. The Chironomus morphotype was common in high altitude, cool, oligotrophic lakes and lowland, warm, eutrophic lakes. This could reflect the widespread distribution of one eurythermic species, or the collective distribution of a number of different Chironomus species with more limited tolerances. The Chl a transfer function could also be improved by inputting mean Chl a values into the inference model rather than the spot measurements that were available for this study.  相似文献   

17.
Salinity and sodicity of groundwater are the principal water quality concerns in irrigated areas of arid and semi-arid regions. The hydrochemical characteristics and sodicity of groundwater in the Shirin Sou area, western Iran were investigated in this study by chemical analyses of groundwater samples from 49 wells. Chemical analysis of the groundwater showed that the mean concentration of the cations was in the order: Na+ > Ca2+ > Mg2+ > K+, while that for anions was SO3 2− > Cl > HCO3  > NO3 . The most prevalent water type is Na–SO4 followed by water types Na–Cl and Ca–SO4. The chemical evolution of groundwater is primarily controlled by water–rock interactions: mainly weathering of aluminosilicates, dissolution of sulfate minerals, and cation exchange reactions. Sulfate dissolution and pyrite weathering may both contribute to the SO4 2− load of the groundwater. High Na+ concentrations in groundwater participate in ion-exchange processes, resulting in the displacement of base cations into solution and raised concentrations in groundwater. The principal component analysis (PCA) performed on groundwater identified three principal components controlling variability of groundwater chemistry. Electrical conductivity, Ca2+, Mg2+, Na+, SO4 2−, and Cl content were associated in the same component (PC1) (salinity), most likely linked to anthropogenic activities.  相似文献   

18.
A next-generation drilling system, equipped with a thermal drilling device, is proposed for glacier ice. The system is designed to penetrate glacier ice via melting of the ice and continuously analyze melt-water in a contamination-free sonde. This new type of drilling system is expected to provide analysis data in less time and at less cost than existing systems. Because of the limited number of parameters that can be measured, the proposed system will not take the place of conventional drilling systems that are used to obtain ice cores; however, it will provide a useful method for quickly and simply investigating glacier ice.An electro-thermal drilling device is one of the most important elements needed to develop the proposed system. To estimate the thermal supply required to reach a target depth in a reasonable time, laboratory experiments were conducted using ice blocks and a small sonde equipped solely with heaters. Thermal calculations were then performed under a limited range of conditions. The experiments were undertaken to investigate the effects of the shape and material of the drill head and heater temperature on the rate of penetration into the ice. Additional thermal calculations were then performed based on the experimental results.According to the simple thermal calculations, if the thermal loss that occurs while heat is transferred from the heater to ice (in melting the ice) is assumed to be 50%, the total thermal supply required for heaters in the sonde and cable is as follows: (i) 4.8 kW (sonde) plus 0 W (cable) to penetrate to 300 m depth over 10 days into temperate glacier ice for which the temperature is 0 °C at all depths and to maintain a water layer along 300 m of cable; (ii) 10 kW (sonde) plus 19–32 kW (cable) to penetrate to 1000 m depth over 1 month into cold glacier ice for which the temperature is −25 °C at the surface and 0 °C at 1000 m depth and to maintain a water layer along 1000 m of cable; and (iii) 19 kW (sonde) plus 140–235 kW (cable) to penetrate to 3000 m depth over 2 months into an ice sheet for which the temperature is −55 °C at the surface and 0 °C at 3000 m depth and to maintain a water layer along 3000 m of cable. The thermal supply required for the cable is strongly affected by the thickness of the water layer, cable diameter, and the horizontal distance from the ice wall at which the ice temperature was maintained at its initial temperature. A large thermal supply is required to heat 3000 m of cable in an ice sheet (scenario (iii) above), but penetration into glacier ice (scenarios (i) and (ii) above) could be realistic with the use of a currently employed generator.  相似文献   

19.
Groundwater is the major source of drinking water in Nahavand city. However, the groundwater quality at the agricultural areas has been deteriorating in recent years. Ground water quality monitoring is a tool which provides important information for water management and sustainable development of the water resources in Nahavand. Hydrochemical investigations were carried out in an agricultural area in Nahavand, western Iran, to assess chemical composition of groundwater. In this study, 64 representative groundwater samples were collected from different irrigation wells and analyzed for pH, electrical conductivity, major ions, and nitrate. The results of the chemical analysis of the groundwater showed that concentrations of ions vary widely and the most prevalent water type is Ca–Mg–HCO3, followed by other water types: Ca–HCO3, Ca–Na–HCO3, and Na–Cl, which is in relation with their interactions with the geological formations of the basin, dissolution of feldspars and chloride and bicarbonate minerals, and anthropogenic activities. Thirty-seven percent of the water samples showed nitrate (NO3 ) concentrations above the human affected value (13 mg L−1). The phosphorous (P) concentration in groundwater was between 0.11 and 0.90 mg L−1, with an average value of 0.30 mg L−1, with all of the samples over 0.05 mg L−1. The most dominant class C2-S1 (76.5%) was found in the studied area, indicating that sodicity is very low and salinity is medium, and that these waters are suitable for irrigation in almost all soils. Agronomic practices, such as cultivation, cropping, and irrigation water management may decrease the average NO3 concentration in water draining from the soil zone.  相似文献   

20.
The northern Great Plains of Canada stretch from the Precambrian Shield near Winnipeg, Manitoba, westward for ∼1,700 km to the Rocky Mountains foothills. This vast region of flat to gently rolling terrain contains a very large number of salt lakes. Major ion chemical data on ∼500 of them are available. Although the average brine (salinity, 37 ppt) is a Na+−SO4 2− type of water, the lakes exhibit a wide range of salinities and ionic compositions. This diversity is confirmed by Q-mode cluster analysis; it identified thirteen major water chemistry types. Most ions display distinct trends, both spatially and with increasing salinity. All dissolved components increase with increasing salinity, but at different rates. The relative proportions of Ca2+ and HCO3 +CO3 2− ions show a strong decrease with increasing brine salinity, whereas SO4 2− ions increase with increasing salinity. The ionic proportions of Na+, Mg2+, K+ and Cl exhibit no significant relationship with salinity. R-mode factor analysis of the lake water chemistry, combined with selected environmental parameters, identifies groundwater composition, climate, and the elevation of the lake within the drainage system as most important in controlling brine chemistry and salinity on a regional basis. Variability in source of ions, reaction processes and products are undoubtedly key factors in helping to explain brine chemistry of an individual basin or variation from a local perspective, but these factors are generally poorly understood and not quantified on a regional basis. Palliser Triangle Global Change Project Contribution Number 3.  相似文献   

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