东海盆地丽水凹陷有效烃源岩判定及分布预测

丽水凹陷作为东海陆架盆地具有较大勘探潜力的凹陷，其勘探程度较低，近年来钻探成果较小，因此亟需对烃源岩进行综合评价。通过烃源岩岩石热解实验，饱和烃气相色谱及饱和烃色质分析，对丽水凹陷烃源岩进行综合评价。结果表明，丽水凹陷烃源岩有机质类型以Ⅲ型为主，存在少量的Ⅱ₁及Ⅱ₂型。月桂峰组烃源岩处于成熟到过成熟阶段，灵峰组烃源岩处于成熟阶段，多数明月峰组烃源岩成熟度较低。根据烃源岩热解参数S₁及有机碳含量（TOC）的关系确定月桂峰组有效烃源岩w（TOC）下限为0.7%，灵峰组有效烃源岩w（TOC）下限为1.0%，明月峰组有效烃源岩w（TOC）下限为0.9%。生标参数显示丽水凹陷烃源岩有机质具有混合来源特征，沉积于海陆过渡环境中。有效烃源岩平面分布预测显示，丽水凹陷有效烃源岩的分布较为局限，丽水凹陷西次凹的东北部为有效烃源岩的集中分布区。月桂峰组及灵峰组烃源岩具有较大的产气潜力，应加大丽水凹陷西次凹东北部的气藏勘探力度。      

渤中凹陷西南洼东营组烃源岩地球化学特征及环境指示意义

东营组烃源岩在渤中凹陷广泛分布,明确该套烃源岩特征及其形成的古环境对于推动渤中凹陷常规-非常规油气勘探具有重要意义。通过对渤中凹陷西南洼东营组烃源岩样品进行有机、无机地球化学实验,分析该套烃源岩品质、有机质来源和古沉积环境,并与凹陷内主力烃源岩沙河街组进行对比分析。结果显示：(1)东营组不同层段烃源岩特征差异显著,且与沙一二段烃源岩呈现明显不同。东二下段与东三段有机质丰度高,已达到成熟-高成熟阶段,东营组整体有机质类型均以Ⅱ型为主;(2)通过Pr/nC₁₇-Ph/nC₁₈等图版以及干酪根类型判断东营组有机质来源为混合型,与沙一二段的低等藻类输入明显不同;(3)综合Sr/Cu、Mn/Fe等16种元素含量或比值以及Pr/Ph、伽马蜡烷指数分析烃源岩形成时期的古环境,与沙一二段烃源岩干旱气候下强还原咸化湖盆的形成环境所不同,东营组整体形成于温湿气候下,伴随较强陆源输入,受控于弱氧化淡水环境;纵向上,从东三段-东一段古气候变化不大,水体盐度基本一致,但水深逐渐变浅,水体氧化条件呈现逐渐增强的趋势;(4)利用Co、La含量定量恢复东营组沉积时的古水深,...     

渤海湾盆地渤中凹陷古近系烃源岩生物标志物特征及其地质意义

渤中凹陷位于渤海湾盆地中东部, 主要发育沙三、沙一和东三段烃源岩层, 具有良好的油气勘探前景, 前期对渤中凹陷有机地球化学特征的研究主要基于岩屑样品, 对岩心样品生物标志物特征的研究比较薄弱。本次研究综合利用岩心和岩屑样品, 通过有机碳、岩石热解、氯仿沥青"A"、族组分饱和烃色谱-质谱等有机地球化学分析测试, 重点对渤中凹陷古近系东营组三段和沙河街组一段、三段烃源岩的有机质丰度、类型、成熟度及母质来源与沉积环境进行研究, 明确了渤中凹陷三套泥页岩的地球化学特征及发育控制因素, 并建立了区分3套烃源岩的典型生物标志化合物组合特征, 以期望为进一步厘清该区域优质烃源岩发育模式及时空分布提供一定的理论依据, 进而有利于该区油气的勘探。研究结果表明: 3套烃源岩的生烃潜力具有显著差异, 沙三段>沙一段>东三段。沙三段烃源岩有机质丰度最高, 为好-极好烃源岩, 有机质类型为Ⅰ-Ⅱ₁型, 处于成熟阶段; 沙一段次之, 为中等-好烃源岩, 有机质类型为Ⅱ₁-Ⅱ₂型, 整体处于成熟阶段; 东三段稍差, 为中等烃源岩, 有机质类型以Ⅱ₁-Ⅱ₂型为主, 处于低熟-成熟阶段。岩心样品的生物标志化合物中姥植比(Pr/Ph)、伽马蜡烷指数(Ga/C₃₀H)、C₂₇-C₂₈-C₂₉规则甾烷含量、4-甲基甾烷指数(4-MS/C₂₉甾烷)等参数表明母质输入和沉积环境是控制3套湖相烃源岩差异的主控因素, 淡水藻源输入和良好的保存条件是沙三段优质烃源岩发育的关键, 低等水生生物输入和强还原的保存条件是沙一段优质烃源岩发育的关键, 混源输入和良好的保存条件是东三段优质烃源岩发育的关键。      

甘蒙地区北山盆地群中口子盆地侏罗系烃源岩特征及评价

北山盆地群侏罗系是我国西北地区潜在的油气勘探新领域,为深化其石油地质认识,进一步明确资源潜力,优选北山盆地群中勘探程度相对较高的中口子盆地侏罗系为研究对象,以有机质丰度、类型及成熟度等有机地球化学分析数据为基础,分析了侏罗系烃源岩基础特征,并基于生物标志化合物资料,探讨了该区侏罗系烃源岩的有机质来源及沉积环境。结果表明,中口子盆地侏罗系烃源岩有机质丰度较高,生烃潜力较好,主要为中等-好烃源岩,干酪根类型以Ⅱ2型为主,生烃母质主要是陆源高等植物,主要形成于氧气量适中的弱氧化-弱还原古环境,靠近或位于凹陷中心的烃源岩形成环境还原性稍强,较有利于有机质保存。区内黑帐房凹陷烃源岩已经成熟,而南泉凹陷烃源岩主要为低熟。因此建议黑帐房凹陷中心或者临近中心区域,寻找保存条件好的油藏是取得下步油气勘探突破的重点。这些认识可供西北地区侏罗系沉积古环境和资源潜力研究时对比参考。     

渤海海域渤东凹陷烃源岩特征与勘探潜力

近年来渤东凹陷内油气勘探因一直未取得重大突破而陷入低谷,主力烃源岩不明确是制约该区油气勘探的核心问题。结合地震、钻井、测井和分析化验等资料,对渤东地区烃源岩地球化学指标、分布特征及成因环境进行了分析,借助盆地模拟和油源对比结果,明确了渤东凹陷的主力烃源岩层系和勘探潜力。渤东凹陷发育东三段、沙一段、沙三段和沙四段4套烃源岩,其中,沙三段烃源岩有机质类型好、丰度高,为很好的烃源岩,其生烃量占凹陷总生烃量的61%,是渤东凹陷的主力烃源岩。地质分析表明,PL9-1油田的油气主要来自渤东凹陷,预示渤东凹陷具备较大的勘探潜力。油源对比结果表明,PL9-1油田75%的原油来自于沙三段烃源岩,渤东凹陷及周缘地区今后的勘探应以寻找沙三段烃源岩生成的油气为主。      

Geochemical characteristics of Early Cretaceous source rocks in Boli Basin

The Early Cretaceous deposits are composed of important source rocks in Boli Basin. The types of the source rocks include black mudstones and coal (with carbonaceous mudstone). By the organic geochemical analysis methods, the authors discussed the organic petrological characters, abundance of organic matter, degree of maturity and the type of source rocks. The main micro-component of black mudstone is exinite or vitrinite, and the content of vitrinite is high in coal. The weathering of the outcrop is very serious. The abundance of organic matter in source rock reaches the poor to better rank. The major kerogens in mudstone are type-Ⅲ, type-Ⅱ2 and some type-Ⅱ1; the organic type of coal is type-Ⅲ. The thermal evolution of the source rocks in every structural unit is very different, from low-maturity to over-maturity. The depositional environment is reductive, which is good for the preservation of organic matter. The organic matter in source rocks is mainly from aquatic organisms and terrigenous input.     

New insights into marine hydrocarbon geological conditions in the South Yellow Sea Basin: evidence from borehole CSDP-2

The South Yellow Sea Basin(SYSB) has multiple sets of proven source rocks and good hydrocarbon prospects,but no industrial oil and gas has been explored at present.To solve this puzzle for petroleum geologists,we systematically investigated the marine hydrocarbon geological conditions based on cores and testing data from borehole CSDP-2,the first exploration well with continuous coring in SYSB.The qualities of source rocks are evaluated in detail according to organic matter abundance,type,and maturity.The reservoir characterization mainly includes porosity,permeability,and reservoir space.Displacement pressure test and stratum thickness are the main foundations for defining the caprocks.Then,the oil-source rock correlation in the Permian and stratum model are analyzed to determine the favorable source-reservoir-caprock assemblages.The results show that three sets of effective source rocks(the Lower Triassic,Upper Permian,and Lower Permian),two sets of tight sandstone re servoirs(the Upper Permian and Lower Silurian-Upper Devonian),and two sets of caprocks(the Lower Triassic and Carboniferous) combine to constitute the hydrocarbon reservoir-forming as se mblages of "lower-ge neration and upper-accumlation" and "self-generation and self-accumlation",thus laying a solid foundation for promising petroleum prospects.The three sets of marine source rocks are characterized by successive generation and expulsion stages,which guarantees multistage hydrocarbon accumulation.Another three sets of continental source rocks distributed across the Middle Jurassic,Upper Cretaceous,and Paleogene depression areas,especially in the Northern Depression,may supplement some hydrocarbons for the Central Uplift through faults and the Indosinian unconformity.The favorable Permian exploration strata have been identified in the Central Uplift of SYSB.First,the Lower Permian and Upper Permian source rocks with high organic matter abundance and high thermal maturity supply sufficient hydrocarbons.Secondly,the interbedding relationship between the source rocks and sandstones in the Upper Permian strata ensures that hydrocarbons have been migrated into the nearby Upper Permian sandstones,reflecting near-source hydrocarbon accumulation.Finally,the good sealing property of the Lower Triassic Qinglong Formation caprocks plays an indispensable role in hydrocarbon preservation of the Permian reservoirs.This conclusion is supported by direct oil shows,gas logging anomalous layers,and hydrocarbon-bearing fluid inclusions.     

涠西南凹陷流沙港组烃源岩生产力及发育模式

涠西南凹陷是中国近海北部湾盆地已证实的富烃凹陷,始新统流沙港组是该凹陷主要烃源岩层系.为深入认识涠西南凹陷流沙港组烃源岩的生产力和发育特征,采用有机地球化学与地球生物学相结合、定性分析与定量计算相结合的方法正演恢复了涠西南凹陷不同次洼流沙港组不同层段烃源岩的古生产力、有机质埋藏效率和有机碳埋藏生产力,进而建立了研究区流沙港组烃源岩形成的地球生物学模式.结果表明,涠西南凹陷流沙港组烃源岩的古生产力、有机质埋藏效率及有机碳埋藏生产力在横向不同次洼和纵向不同层段上均存在差异,横向上以B次洼最优,纵向上以流二段最高;涠西南凹陷流沙港组烃源岩发育超营养湖高埋藏效率高埋藏生产力、富营养湖中等埋藏效率中等埋藏生产力及富营养湖低埋藏效率低埋藏生产力3种代表性的地球生物学模式.     

东海盆地西湖凹陷平湖组煤系烃源岩条件及成烃模式

西湖凹陷是中国近海最重要的煤成油气凹陷。近年来，油气勘探证实平湖组煤系烃源岩为西湖凹陷提供了丰富的油气资源。与陆上其他中生代煤成油气盆地不同，近海新生代海陆过渡相平湖组煤系烃源岩在母质来源、生烃条件和演化特征上都有其独特性。研究表明，平湖组煤和炭质泥岩具有富含树脂体、高I_H指数、Ⅱ₁-Ⅱ₂型干酪根、广覆式分布特点；煤系烃源岩富含三环二萜异海松烷、四环二萜β-扁植烷和五环三萜奥利烷，指示了针叶类裸子植物、蕨类植物和被子植物多植被母质来源；有机质组成差异、"内热外冷"地温和差异的沉积沉降速率造成了煤和泥岩在不同构造带成烃演化具有明显不同。这种差异决定了煤成油气资源具有"油气并举、东气西油"的分布格局，烃源岩成烃演化表现为"早期有利生油，晚期持续生气"模式。      

Geochemistry,petrogenesis and tectonic implication of Early Cretaceous A-type rhyolites in Hailar Basin,NE China

Early Cretaceous A-type rhyolites of the Shangkuli Formation in the Hailar Basin of NE China exhibit geochemical characteristics of high silicon, alkali, Fe/Mg, Ga/Al, Zr, Pb, HFSEs, and REE contents but low Ca, Ba, Sr and Eu, which meet the criteria of typical reduced A-type granite.The A-type rhyolites are most probably derived from magmatic underplating and partial melting of quartz-feldspathic lower crust, with the lithospheric mantle material involved, due to the extensional deformation of the Erguna-Hulun Fault.Although the A-type rhyolites show A1-type trace elements characteristics, they were formed in a post-orogenic extension-al background together with the coeval widespread bimodal volcanic rocks, metamorphic core complexes, vol-canic fault basins and metallogenic province in the Sino-Russia-Mongolia border tract.This extension event was related to the collapse of thickened region of the continental crust after the closure of the Mongol-Okhotsk Ocean.     

歧口凹陷沙一下亚段页岩形成环境及页岩油潜力综合评价

渤海湾盆地是目前我国主要的陆相页岩油资源开采区,歧口凹陷位于盆地腹地,是渤海湾盆地内典型的富油气凹陷之一,但长期以来缺少对不同层位页岩形成环境及页岩油潜力的综合评价。选取歧口凹陷沙一下亚段富有机质页岩为研究对象,综合运用地化录井技术和生排烃模拟技术,进行歧口凹陷沙一下亚段页岩沉积特征的描述和页岩油潜力的综合评价。研究结果显示,(1)歧口凹陷沙一下亚段沉积于水体盐度较高的还原-强还原环境,营养物质丰富,气候炎热湿润,适宜生物大量繁殖,生产力水平高;(2)结合生排烃模拟实验结果,研究区沙一下亚段页岩生烃能力强、生烃效率高、排油率较低,生成的原油仍大部分残留在页岩中,具有良好的勘探潜力;(3)研究区沙一下亚段页岩中含有适量碳酸盐矿物,在成岩过程中改善了储集条件,为页岩油提供了良好的储集场所。歧口凹陷西南缘海侵的发生从沉积环境、古生产力及对成岩作用影响等方面促进了沙一下亚段有机质的富集,而有机质富集、生烃强度高以及良好的储集条件共同控制了沙一下亚段页岩油的大面积分布。研究区沙一下亚段页岩油储层可分为碳酸盐岩和混合沉积岩2种类型,综合2种储层的含油性特征后发现,碳酸盐岩矿物含量和脆性指数对页岩含...     

Organic geochemistry and source rock potential assessment of Late Paleocene Patala Formation in Margalla Hill Range,North Pakistan

Black shales of the Paleocene Patala Formation are proven source rocks for conventional hydrocarbons in southern Potwar Basin of Pakistan and are assumed to be effective source rocks towards north in the Margalla Hill Range of Pakistan. In this regard, the current study focuses on source rock geochemistry of the Paleocene Patala Formation to assess its source rock potential, organic matter types and thermal maturity levels in the Mar-galla Hill Range of North Pakistan. Source rock generative potential, kerogen types and thermal maturation of the analysed rock samples were unraveled by using Rock-Eval pyrolysis Tmax, TOC (total organic carbon) and vitrinite reflectance ( R0 ) analyses. TOC analysis coupled with S2 yield revealed poor to fair source rock quality encountered within the formation. The pyrolysis Tmax vs Hydrogen Index ( HI) , showed mostly Type Ⅲ kerogen dominated by thermally immature to mature organic matter. The HI and genetic potential is low and revealed poor hydrocarbon generation potential of the formation. The S1 vs TOC plots confirm the indigenous nature of the hydrocarbons hosted by Patala Formation. The vitrinite reflectance outcomes indicated immature to mature source rock beds lying in dry gas zone. The HI and OI signatures and abundance of Type Ⅲ kerogen are indica-ting dominance of terrestrial organic matter within the formation. Overall, the investigated Patala Formation ex-posed at the studied section of Margalla Hill Range, Pakistan acts as a poor source rock unit for liquid hydrocar-bon generation but holds prospects for dry gas generation in the study area.     

A study on accumulation and distribution of gas in southern Songliao Basin

A number of isolated fault sags in Late Jurassic--Early Cretaceous were developed in the early stage of southern Songliao Basin,and unified to a depression basin in the late stage.Therefore,multiple isolated lower petroliferous systems were formed with fault sags as source rocks.The source rocks of fault sags in Late Jurassic--Early Cretaceous were mainly described with gas generation as favorable source rocks,leading to the southern Songliao Basin rich in natural gas resources combined with organic gas resources in Nenjiang Formation.A number of tectonic movements in southern Songliao Basin led to the formation of abundant structural traps and complex fault systems,and controlled the distribution strata and positions of sources rocks in Late Jurassic--Early Cretaceous fault sags.The oil-gas reservoirs can be divided into two types,i.e.,primary and secondary ones.The primary oil-gas reservoirs were distributed in the fault sag strata and the bottom of overlying depression strata(lower Quan-1 Member).The oil-gas reservoir accumulation depended on the trap development situation and the distance from source rocks.The preservation conditions of oil-gas reservoirs depended on the degree of reconstruction in the late tectonism.The secondary oil-gas reservoirs were distribution in the Quantou Formation of depression strata,where oil and gas reservoir accumulation depended on three conditions,i.e.,trap development situation,deep gas sources and the fault to connect the shallow traps and deep gas sources.The southern Songliao Basin is rich in lower coal type gas,upper oil-gas and biogas resources,which are important resources in the future.     

热液衍生石油及其有机质研究

石油与天然气的成因长期存在有机成因和无机成因的争议。近年来, 全球不同大洋洋底热液衍生石油的发现, 为更进一步探索油气成因提供了新的思考。在回顾有机生油假说和无机生油假说基本理论和二者争论的基础上，重点介绍了热液衍生石油及其有机质的特点和研究进展。然后结合三塘湖盆地、鄂尔多斯盆地烃源岩中热液喷流沉积的研究取得了以下重要认识:①热液衍生石油的有机质来源于陆源高等植物和洋底低等生物，该生物是围绕热液喷口生活的嗜热、嗜毒、耐高温生物；②热液衍生石油不需要埋藏来持续提供热量，海底热液活动为其提供了物质和热量；③在有机质与深源热物质流体发生物理化学作用的过程中，有机质“瞬时”(时间很短)热解成油，部分转化为类似于石油的产品。热液衍生石油及其有机质的研究不仅能进一步深化人们对油气成因的认识，而且对非常规石油的勘探开发具有重要意义。      

东非裂谷Albertine盆地上中新统-下上新统烃源岩地球化学特征与沉积环境

Albertine盆地是东非裂谷系重要的裂谷盆地,油气资源丰富,上中新统-下上新统烃源岩是盆地重要的生烃岩系,目前研究相对薄弱。综合利用地质学、岩石热解、元素地球化学等资料,对Albertine盆地上中新统和下上新统的烃源岩进行了评价,并分析了晚中新世-早上新世时期的古环境特征。研究表明,两套烃源岩处于成熟阶段,但有机质丰度和类型存在差异,下上新统烃源岩有机质丰度更高,属于中等-好烃源岩,干酪根类型主要是Ⅱ₁～Ⅱ₂型;上中新统烃源岩有机质丰度略低,属于差烃源岩,干酪根主要是Ⅱ₂～Ⅲ型。沉积环境是造成烃源岩差异的重要原因。晚中新世-早上新世时期,研究区属于还原性较强的淡水湖盆,水体逐渐加深,气候越来越温暖,细菌及微生物繁盛,有机质类型变好,同时,湖泊生产力提高,沉积速率有所加快,有机质能够更有效地保存,烃源岩的有机质丰度更高。研究结果对于Albertine盆地的油气勘探与开发具有重要的理论意义和实际意义。     

陆相页岩气的泥页岩评价——以延长下寺湾区上三叠统延长组长7段为例

以鄂尔多斯盆地的延长下寺湾区中生界延长组长7段陆相泥页岩为研究对象,在样品实验数据分析和单井岩心观察的基础上,根据泥页岩的发育与分布特点和有机地球化学特征对陆相页岩气的泥页岩进行评价.结果表明:延长下寺湾区延长组长7段泥页岩主要为浅湖—深湖相沉积,泥页岩累计厚度适宜,有机质类型以Ⅱ1为主,有机质丰度较高,具备页岩气生成的物质基础,有机质演化主要处于成熟阶段.分析美国海相产气页岩与中国陆相产气页岩的综合特征,长7段泥页岩脆性矿物质量分数大于25%,有利于储层的后期改造.相对美国储层物性较好的页岩,根据现场解析法测得的长7段泥页岩含气量较高(平均为4.5m3/t),埋深适中,分布稳定,具有勘探潜力和开发前景.     

珠江口盆地惠州凹陷烃源岩发育的主控因素分析

根据烃源岩地球化学、岩石学、沉积学等特征,分析惠州凹陷2套烃源岩的地球化学特征及烃源岩发育的主控因素.结果表明:文昌组中深湖相烃源岩形成于缺氧的还原环境,母质输入主要为低等水生生物和菌藻类,生烃潜力较好;恩平组河沼相煤系泥岩母质输入以陆源高等植物为主,生油潜力不及文昌组中深湖相泥岩;文昌组时期的表层水中浮游植物繁盛和湖底贫氧环境有利于优质烃源岩的形成,同时烃源岩的非均质性受沉积相和基准面旋回升降变化的控制,在最大湖泛面附近容易形成优质烃源岩.     

Current Situation and Application in Coal- Generated Hydrocarbons

The characteristics and research methods of terrigenous organic hydrocarbon - generated source rock in coal measures are studied in this thesis. After abundance of organic matters, pyrolysis parameter of rocks and hydrocarbon generated capacity of macerals are basically discussed in coal measures of the Cretaceous Muleng- Chengzihe formation in Suibin depression in Sanjang basin, the hydrocarbon generated grade in coal- generated source rock is ascertained in this depression. At last, we think that it is a main attack prospect in coal - generated hydrocarbons study in the future to research the macerals of coal measures organic source rock and to build a criterion to classify the coal- generated hydrocarbons in Northeast region.     

川西坳陷须三段致密砂岩气藏源储特征及成藏模式

川西坳陷须家河组致密气藏已成为拓展油气勘探、发现新储量的重要领域,致密气藏发育特征及其成藏机理成为目前亟需解决的关键科学问题之一。运用地球化学、地球物理和沉积学等分析方法,对须三段源储特征及成藏模式进行了系统分析,对高效烃源岩和优质储层进行了判别和预测,厘定了致密气藏成藏期次和成藏模式。得出以下结论:①须三段发育成熟-高成熟湖相烃源岩,以Ⅲ型干酪根为主,局部偶见Ⅱ₂型干酪根。发育于须三下亚段最大湖泛面附近,泥页岩体积分数在65%以上或者单层厚度较大、且1.50% ≤ w（TOC）≤ 10%时,属于高效烃源岩。②基于砂岩粒度中值识别出4期（S1,S2,S3和S4）优质储层,都属于低孔低渗-特低孔特低渗致密储层,中砂-细砂,粒度分布范围为0.5~0.062 5 mm,厚度一般5~10 m。主要发育于三角洲前缘和前三角洲。③烃源岩生排烃时间持续较长,中侏罗世开始生烃,一直持续至晚白垩世;从晚侏罗世开始排烃,早白垩世达到高峰。优质储层经历早期天然气持续充注和晚期凝析气充注,天然气充注时间要早于凝析气充注时间。形成了"断层垂向输导,先聚集后致密,晚期改造调整"的致密气藏成藏模式。      

三门海游构造火山盆地之火山─沉积岩系层位归属讨论

本文根据天台测区1：5万区域地质调查工作成果，综合测区构造，岩石组合，岩石化学、化石，接触关系特征等资料分析，对三门海游构造火山盆内龙珠山─下路朱一带及芹溪、三门中学等地出露约70km2的火山─沉积岩系地层，进行层位归属讨论。指出海游盆地内龙珠山、里金、下路朱一带及芹溪、三门中学等地出露的火山─沉积岩地层，其层位应归属下白垩统永康群馆头组和朝川组，系属北北东向展布的早白垩世临海断陷地的组成部分。