Hydrochemical and isotopic investigation of a sandstone aquifer groundwater in a semi arid region,El Ma El Abiod,Algeria

This work present results of the hydrochemical and isotopic studies on groundwater samples from the study area. Chemical and environmental isotope data are presented and discussed in terms of the origin of dissolved species and of groundwater. All of the investigated groundwater are categorized into two chemical types: low and relatively high mineralized waters type. Interpretation of chemical data, based on both thermodynamic calculations and stability diagrams, suggests that the chemical evolution of groundwater is primarily controlled by water-rock interactions. Interpretation of ¹⁸O and ²H suggests that the recharge of the investigated groundwater may result from differents mechanisms     

Variographic analysis of chemical and piezometric data from the sandstone aquifer of Ain Oussera, Algeria

The perturbation of piezometric level and the bad water quality in Ain Oussera plain represents a serious problem for local authorities and water resources managers. The spatial distribution of piezometric level and chemical data was analyzed by applying geostatistical methods, which provide an indication of the uncertainty of the estimation using the computer software VARIOWIN 2.2 (Pannatier 1996). In this paper, the evolution of the piezometric level and hydrochemical data by referring to other research campaigns was studied. Two campaigns were chosen; September 2001 and May 2008 for pizometric level and 1994 and 2004 for chemical data. In the beginning, elementary statistics has been carried out to understand the statistical distribution and performed an analysis of variance for comparison between two campaigns. Geostatistics for modeling and cartography were applied. The results showed that piezometric levels admit spherical model that the direction of groundwater flow is from southwest to northeast. High nugget effect characterizes piezometric data and chemical data, linked to the presence of microregions due to excessive pumping and local evaporitics formations. Anisotropy is observed in the northeast-southeast direction from which a spatial continuity in this direction can be deduced.     

Groundwater geochemistry of Ain Azel area,Algeria

Hydrogeochemical data for 18 groundwater samples and 11 hydrochemical parameters were subjected to Q- and R-mode cluster analysis and inverse geochemical modeling. Q-mode cluster analysis resulted in three distinct water types (brackish water type, saline water type and highly saline water type). R-mode cluster analysis led to the conclusion that the water–rock interaction is the major source of contamination for the groundwater in the area. Geochemical modeling results show that carbonates, gypsum, halite, carbon dioxide (gas), and chlorite are dissolving, whereas Ca-montmorillonite, gibbsite, illite, K-mica, kaolinite, and quartz are mostly precipitating along different flow paths in the groundwater system of the area.     

Hydrogeochemistry of groundwaters in a semi-arid region. El Ma El Abiod aquifer, Eastern Algeria

In this work, we present results of the hydrogeochemical and isotopic studies on groundwater samples from the El Ma El Abiod Sandstone aquifer, in Tébessa, Algeria. Chemical and environmental isotope data are presented and discussed in order to identify the geochemical processes and their relation with groundwater quality as well as to get an insight into the hydrochemical evaluation, in space and time, of groundwater and of the origin of dissolved species. A combined hydrogeologic and isotopic investigation have been carried out using chemical and isotopic data to deduce a hydrochemical evaluation of the aquifer system based on the ionic constituents, water types, hydrochemical facies, and factors controlling groundwater quality. All of the investigated groundwaters are categorized into two chemical types: low mineralized water type and relatively high mineralized water type. Interpretation of chemical data, based on thermodynamic calculations and geochemical reaction models of selected water groups constructed using PHREEQC, suggest that the chemical evolution of groundwater is primarily controlled by water–rock interactions, involving (1) acidic weathering of aluminosilicates, (2) dissolution of secondary carbonate minerals, and (3) cation exchange of Na⁺ for Ca²⁺. However, the original composition of groundwater may have been modified by further secondary processes such as mixing of chemically different water masses. The combined use of SI and mass-balance modeling has shown to be a useful approach in interpreting groundwater hydrochemistry in an area where large uncertainties exist in the understanding of the groundwater flow system. Interpretation of ¹⁸O and ²H, suggest that the recharge of the investigated groundwaters may result from different mechanisms.     

Impacts of wastewater irrigation in arid and semi arid regions: case of Sidi Abid region,Tunisia

Impacts of irrigation with treated wastewater effluents on soils and groundwater aquifer in the vicinity of Sidi Abid Region (Tunisia) are evaluated. The groundwater aquifer was monitored by several piezometers, where monthly water levels were registered and groundwater salinity was evaluated. This resulted in characterizing the spatial and temporal evolution of the hydrochemical and hydrodynamic properties of the aquifer, showing thereby the impact of artificial recharge. Piezometric maps for pre-recharge and post-recharge situations were developed and a comparison study of both piezometric situations was considered. The piezometric evolution map showed a generalized rise of the piezometric level in the vicinity of the irrigation zone. The extent of recharge was shown to increase with time as the groundwater level increase, which was localized in the vicinity of the irrigation area, reached more extended zones. Several groundwater samples were withdrawn from wells and piezometers and analyzed. Examining the corresponding physical and chemical parameters showed an increase in the concentrations of nutrients (28 mg/l for NO₃ and 3.97 mg/l for NH₄) in the groundwater aquifer below the irrigation zone, which confirms again the infiltration of treated wastewater effluents. The evolution of soil salinity was examined through chemical analysis of soil samples. Electric conductivities of soils were generally shown to be less than 4 mS/cm while the irrigation water has an electric conductivity that may reach 6.63 mS/cm. This might be explained by the phenomenon of dilution and the capacity of soils to evacuate salts downward.     

Hydrochemistry and salt-water intrusion in the Van aquifer,east Turkey

Groundwater in the Van coastal aquifer is one of the main sources of potable, industrial and irrigational water in Van City, because of its semi-arid climate. Groundwater extraction has been in excess of replenishment owing to increased agricultural and economic activities and a growing population during the last 20 years. A hydrochemical survey of the Van aquifer provided data on the groundwater chemistry patterns and the main mineralization processes. The main processes influencing the groundwater chemistry are salinisation from salt-water intrusion, silicate mineral dissolution, cation exchange and human activity. Deterioration in water quality has resulted from intrusion of the salt water of Lake Van along the coastal regions into the Van plain. At present, the mixing rate of salt water in the Van aquifer is between 1 and 5.5% and salt water has already invaded about 5 km inland in the iskele and the airport region.     

Drainage morphometry and its influence on hydrology in an semi arid region: using SRTM data and GIS

An attempt has been made to study drainage morphometry and its influence on hydrology of Peddavanka watershed, South India. Drainage networks for the sub-basins were derived from topographical map (1:50,000) and Shuttle Radar Topographic Mission (SRTM) Digital Elevation Model (DEM) data used for preparing elevation, slope and aspects maps. Geographical information system (GIS) was used in evaluation of linear, areal and relief aspects of morphometric parameters. The study reveals that SRTM DEM and GIS-based approach in evaluation of drainage morphometric parameters and their influence on hydrological characteristics at watershed level is more appropriate than the conventional methods. The mean Bifurcation ratio (R _b) of the entire basin is 3.88 which indicate that the drainage pattern is not much influenced by geological structures. VIII sub-basin have high elongation ratio (R _e), basin relief (B _h), Ruggedness number (Rn) and time of concentration (T _c). It indicates that the erosion and peak discharges are high in these basins. Therefore, the construction of the check dams and earth dams will help in reducing peak discharge on the main channel. These studies are very useful for implementing rainwater harvesting and watershed management.     

Multivariate analysis and geochemical investigations of groundwater in a semi-arid region,case of superficial aquifer in Ghriss Basin,Northwest Algeria

This study aims to investigate the hydrochemical characteristics of shallow aquifer in a semi-arid region situated in northwest Algeria, and to understand the major factors governing groundwater quality. The study area is suffering from recurring droughts, groundwater resource over-exploitation and groundwater quality degradation. The approach used is a combination of traditional hydrochemical analysis methods of multivariate statistical techniques, principal component analysis (PCA), and ratios of major ions, based on the data derived from 33 groundwater samples collected in February 2014. Results show that groundwater in the study area are highly mineralized and collectively has a high concentration of chloride (as Cl^?). The dominant water types are Na-Cl (27%), Mg-HCO₃ (24%) and Mg-Cl (24%). According to the (PCA) approach, salinization is the main process that controls the hydrochemical variability. The PCA analysis reveal the impact of anthropogenic factor especially the agricultural activities on the groundwater quality. The PCA highlighted two types of recharge: Superficial recharge from effective rainfall and excess irrigation water distinguished by the presence of nitrate and lateral recharge or vertical leakage from carbonate formations marked by the omnipresence of HCO₃^?. Additionally, three categories of samples were identified: (1) samples characterized by good water quality and receiving notable recharge from carbonate formations; (2) samples impacted by the natural salinization process; and (3) samples contaminated by anthropogenic activities. The major natural processes influencing water chemistry are the weathering of carbonate and silicate rocks, dissolution of evaporite as halite, evaporation and cation exchange. The study results can provide the basis for local decision makers to ensure the sustainable management of groundwater and the safety of drinking water.     

西北半干旱地区岩屑地球化学异常提取方法的研究

西北地区主要发育残山丘陵地貌。风成砂、急雨过后的黄土硬壳以及下伏膏岩层的普遍发育在一定程度上影响了地球化学勘查数据的代表性,也给异常的提取和解释带来了困难。针对这种特殊的自然景观和地质背景,以西北半干旱地区——阿拉善某地为例,介绍了工作区地质特征,用传统的统计学方法、趋势面法、滑动平均法提取相关元素地球化学异常,在此基础上结合地质矿产资料进行综合对比,探讨了较为适合半干旱地区地球化学勘查数据处理的方法。     

Hydrogeochemical processes and multivariate analysis for groundwater quality in the arid Maadher region of Hodna,northern Algeria

Acta Geochimica - This study focused on water quality and hydro-geochemical processes (evolution, origin) in the Maadher region, central Hodna in Algeria. In recent decades, the excessive...     

Hydrochemistry and origins of mineralized waters in the Puebla aquifer system,Mexico

Significant upward movement of mineralized water takes place in the Puebla aquifer system. Preferential groundwater flow paths related to the geological structure and the lowering of the potentiometric surface are suspected to be the prime factors for this intrusion. A combined approach of geochemical and isotope analyses was used to assess the sources of salinity and processes that are controlling the changes in groundwater chemical composition in the Puebla aquifer. Geochemical and isotope data indicate that the likely source of increased solutes is mineralized water from the dissolution of evaporites of the Cretaceous age at the base of the Upper deep aquifer, which is deeper than the intakes of the shallow wells. Dedolomitization and cation exchange seems also to occur along flow paths where sulphate concentrations tend to increase. The deep regional flow paths controls the chemical stratification of groundwater in response to decreased heads through interconnecting vertical and horizontal pathways, such as in the Fosa Atlixco. The results also suggest that high sulphate concentrations originating in the Lower deep aquifer are currently affecting shallow production wells. It is concluded that hydrodynamic aspects together with hydrogeochemical characteristics need to be taken into account to correctly explain the hydrochemical evolution in the stratified aquifer.     

The hydrogeochemical characterization of Morsott-El Aouinet aquifer, Northeastern Algeria

A study of the hydrogeochemical processes in the Morsott-El Aouinet aquifer was carried out with the objective of identifying the geochemical processes and their relation with groundwater quality as well as to get an insight into the hydrochemical evaluation of groundwater. The high salinity coupled with groundwater level decline pose serious problems for current irrigation and domestic water supplies as well as future exploitation. A combined hydrogeologic and isotopic investigation have been carried out using chemical and isotopic data to deduce a hydrochemical evaluation of the aquifer system based on the ionic constituents, water types, hydrochemical facies and factors controlling groundwater quality. The ionic speciation and mineral dissolution/precipitation was calculated by WATEQF package software. The increase in salinity is related to the dissolution and/or precipitation processes during the water–rock interaction and to the cationic exchange reactions between groundwater and clay minerals. The isotopic analysis of some groundwater samples shows a similarity with the meteoric waters reflect their short residence time and a lowest evaporation phenomenon of infiltrated groundwater.     

Processes affecting groundwater chemistry in a zone of saline intrusion into an urban sandstone aquifer

Samples have been collected from inflows into railway tunnels in the Triassic sandstone aquifer beneath Liverpool and the Mersey Estuary, England, U.K. These provide a profile through a saline–freshwater mixing zone. Analyses were made of major anions and cations, δ³⁴S and δ¹⁸O in SO₄, δ¹³C in dissolved inorganic C and ⁸⁷Sr/⁸⁶Sr. The data demonstrate that the presence of a low permeability fault exerts a strong control on the local groundwater chemistry. On the estuary side of the fault, groundwater chemistry is dominated by mixing of intruding estuary water, which is modified by SO₄ reduction and calcite dissolution, with fresh groundwater. The environment of SO₄ reduction in the tidal estuary is one of repeated reduction and re-oxidation of S in an open system and has resulted in virtually no change in S isotopic composition, but an enrichment in residual SO₄ δ¹⁸O of 1.5‰. Groundwater chemistry on the landward side of the fault is primarily the result of recharge in an urban environment. There is also evidence that saline water has been present in this region of the aquifer in the past and that this has now been flushed by fresh groundwaters. This saline water was either transported along the landward side of the fault from nearer the estuary or more probably transmitted across the fault. Both mechanisms would have been driven by large landward head gradients caused by heavy industrial abstraction earlier this century. This has produced a zone of groundwaters depleted in Ca and radiogenic Sr and enriched in Na as a result of ion exchange between the fresh groundwaters and the aquifer previously occupied by more saline water. Sulphur isotopic composition, however, shows no variation since SO₄ does not undergo significant ion exchange. A tracer test from a borehole to the tunnels showed multiple breakthroughs to some locations indicating a number of different flow paths through the aquifer. The maximum flow velocity recorded in this test was 140 m/d suggesting flow along fractures.     

Observations of the atmospheric surface layer parameters over a semi arid region during the solar eclipse of August 11th, 1999

This paper discusses the observations of the Atmospheric Surface Layer (ASL) parameters during the solar eclipse of August 11th, 1999. Intensive surface layer experiments were conducted at Ahmedabad (23‡21′N, 72‡36′E), the western part of India, which was close to the totality path. This rare event provided by nature is utilised to document the surface layer effects during the eclipse period using measurements of high frequency fluctuations of temperature, tri-axial wind components as well as mean parameters such as temperature, humidity, wind speed and subsoil temperature. Analysis showed that during the eclipse period, the turbulence parameters were affected leading to the suppression of the turbulence process, the main dynamic process in the atmospheric boundary layer, while the mean parameters showed variations within the natural variability of the observational period. The spectra of the wind components and temperature indicated decrease in spectral power by one order in magnitude during the eclipse period. The rate of dissipation of turbulent kinetic energy is found to decrease by more than one order during the eclipse period. The stability parameter showed a change from unstable to stable condition during the period of eclipse and back to unstable condition by the end of eclipse     

Hydrochemistry in coastal aquifer of southwest Bangladesh: origin of salinity

In the coastal region of Bangladesh, groundwater is mainly used for domestic and agricultural purposes, but salinization of many groundwater resources limits its suitability for human consumption and practical application. This paper reports the results of a study that has mapped the salinity distribution in different aquifer layers up to a depth of 300 m in a region bordering the Bay of Bengal based on the main hydrochemistry and has investigated the origin of the salinity using Cl/Br ratios of the samples. The subsurface consists of a sequence of deltaic sediments with an alternation of more sandy and clayey sections in which several aquifer layers can be recognized. The main hydrochemistry shows different main water types in the different aquifers, indicating varying stages of freshening or salinization processes. The most freshwater, soft NaHCO₃-type water with Cl concentrations mostly below 100 mg/l, is found in the deepest aquifer at 200–300 m below ground level (b.g.l.), in which the fresh/saltwater interface is pushed far to the south. Salinity is a main problem in the shallow aquifer systems, where Cl concentrations rise to nearly 8000 mg/l and the groundwater is mostly brackish NaCl water. Investigation of the Cl/Br ratios has shown that the source of the salinity in the deep aquifer is mixing with old connate seawater and that the saline waters in the more shallow aquifers do not originate from old connate water or direct seawater intrusion, but are derived from the dissolution of evaporite salts. These must have been formed in a tidal flat under influence of a strong seasonal precipitation pattern. Long dry seasons with high evaporation rates have evaporated seawater from inundated gullies and depressions, leading to salt precipitation, while subsequent heavy monsoon rains have dissolved the formed salts, and the solution has infiltrated in the subsoil, recharging groundwater.     

Hydrochemistry of surface water and groundwater from a fractured carbonate aquifer in the Helwan area,Egypt

Groundwater is an important water resource in the Helwan area, not only for drinking and agricultural purposes, but also because several famous mineral springs have their origin in the fractured carbonate aquifer of the region. The area is heavily populated with a high density of industrial activities which may pose a risk for groundwater and surface water resources. The groundwater and surface water quality was investigated as a basis for more future investigations. The results revealed highly variable water hydrochemistry. High values of chloride, sulphate, hardness and significant mineralization were detected under the industrial and high-density urban areas. High nitrate contents in the groundwater recorded in the southern part of the study area are probably due to irrigation and sewage infiltrations from the sewage treatment station. The presence of shale and marl intercalation within the fissured and cavernous limestone aquifer promotes the exchange reactions and dissolution processes. The groundwater type is sodium, sulphate, chloride reflecting more mineralized than surface water. The results also showed that water in the study area (except the Nile water) is unsuitable for drinking purposes, but it can be used for irrigation and industrial purposes with some restrictions.     

Geotechnical and geophysical characterization of the Bouira-Algiers Highway (Ain Turck,Algeria) landslide

The Ain Turck (Bouira) landslide, in north-center Algeria, is one of the numerous instabilities recorded along the Lakhdaria-Bouira section of the 1200-km-long east-west Algerian highway. The locality of Ain Turck is known for its unstable slopes characterized by a very rough morphology with steep slopes (20 to 25%). This slide threatens the inhabitants of the Ibournanen village, located down the unstable slope, where parts of some houses have fallen into ruin, while others are cracked. It is characterized by an active movement extending over a more or less important slope, of the order of a hundred meters. The land mobilized by this movement corresponds to the layer of shale clays and clays overlaid by a backfill, placed there following the east-west highway works. Geological, geomorphologic, and geotechnical analysis allows determining the soil instability probably related to earthworks during the construction of the highway section a few years earlier, followed by a particularly rainy season in 2012. Acquisitions of ambient seismic noise and H/V ratio processing, as well as the acquisition of an electrical resistivity profile at the instability site, have reinforced our preliminary interpretations of depth and geometry of the sliding surface.     

Statistical categorization geochemical modeling of groundwater in Ain Azel plain (Algeria)

Water analysis data of 54 groundwater samples from 18 uniformly distributed wells were collected during three campaigns (June, September and December 2004). Q-mode hierarchical cluster analysis (HCA) was employed for partitioning the water samples into hydrochemical facies. Interpretation of analytical data showed that the abundance of major ions was identified as follows: Ca ? Mg > Na > K and HCO₃ ? Cl > SO₄. Three major water facies are suggested by the HCA analysis. The samples from the area were classified as recharge area waters (Ca–Mg–HCO₃ water), transition area waters (Mg–Ca–HCO₃–Cl water), and discharge area waters (Mg–Ca–Cl–HCO₃ water). Inverse geochemical modeling suggests that relatively few phases are required to derive the water chemistry in the area. In a broad sense, the reactions responsible for the hydrochemical evolution in the area fall into two categories: (1) evaporite weathering reactions and (2) precipitation of carbonate minerals.