Isotopic composition of strontium and neodymium in potassic rocks of the Little Murun complex, Aldan Shield, Siberia

This paper presents the first data on the isotopic composition of Nd and Sr in ultrapotassic rocks of the Little Murun complex, Aldan Shield, Siberia. The samples analysed include a Sr---Ba-carbonatite and rocks belonging to the biotite pyroxenite-shonkinite series. The latter are representative of rocks termed “lamproites” by previous investigators of the complex. The rocks have isotopic compositions that indicate derivation from ancient sources that have higher Rb/Sr and lower Sm/Nd ratios than those of bulk Earth. The samples define an array on a Sr---Nd correlation diagram, suggesting that the isotopic composition of Sr and Nd in the rocks is a mixture of two components: a dominant one derived from an ancient lithospheric mantle source that has been isolated from convecting mantle, and a minor component of asthenospheric origin. We do not consider that any of the samples analysed are lamproites, although our isotopic data suggest that conditions in the lithospheric mantle in this region are suitable for the generation of lamproites. The potassic rocks from the Aldan shield have isotopic compositions that are similar to those of potassic rocks in the Wyoming craton. It is proposed that the geochemical evolution of the two shields was broadly similar.     

俄罗斯北极地区前寒武纪岩相古地理特征

本文基于大量文献资料,系统研究俄罗斯北极地区前寒武纪的岩相古地理。俄罗斯北极地区前寒武纪共识别出半深海-深海区、浅海区、滨海区、冲积区和隆起剥蚀区5种古地理单元,其中,隆起剥蚀区沉积记录缺失;冲积区以砾岩+砂岩+泥岩和变质碎屑岩+碳酸盐岩为主;滨浅海区沉积则以变质碎屑岩+碳酸盐岩、蒸发岩+碳酸盐岩、砂岩+泥岩+碳酸盐岩3种岩性组合为主,局部有蒸发岩、砾岩+砂岩+泥岩发育;而半深海-深海区为大洋。俄罗斯北极地区前寒武纪古地理以滨浅海区为主,主要分布在东西伯利亚台地、西西伯利亚盆地、鄂霍茨克地块、楚科奇板块和巴伦支海北部地区;半深海-深海区的分布仅次于滨浅海区,此时西西伯利亚盆地尚未完全形成,其东侧为半深海-深海区;隆起剥蚀区分布范围小于半深海-深海区,主要分布在波罗的地盾及其周缘地区,以及东西伯利亚台地的阿纳巴尔地块和阿尔丹地盾地区;冲积区分布范围最为局限,仅在蒂曼-柏朝拉盆地中部发育。研究表明,俄罗斯北极地区广泛发育前寒武纪地层,岩性以碳酸盐岩和变质碎屑岩为主,部分构造单元中的前寒武纪地层已成为陆壳基底,前寒武纪岩相古地理特征研究可为前寒武纪地质研究提供依据,为其余地质时期的岩相古地理研究奠定基础。     

Early Precambrian granite-gneiss complexes in the Central Aldan Shield

The central portion of the Aldan Shield hosts very widely spread Archean and Early Proterozoic granitoids, much of which are granite-gneisses. Geochemical lines of evidence, data on inclusions in minerals, and Sm-Nd isotopic geochemical data suggest that the protoliths of granite-gneisses in the central part of the Aldan Shield were granitoids that had various composition, age, and were derived from distinct sources and under different parameters and were then emplaced in different geodynamic environments. The granitoids belong to at least two types of different composition that occur within spatially separated areas. The protoliths of granite-gneisses in the western part of the Western Aldan Megablock and the junction zone of the Chara-Olekma and Aldan geoblocks (granite-gneisses of type I) had the same age and affiliated to the same associations as the within-plate granitoids of the Nelyukinskii Complex. Their parental melts were derived at 2.4–2.5 Ga by the melting of Archean tonalite-trondhjemite orthogneisses of the Olekma and Aldan complexes. The protolith of granite-gneisses in the eastern portion of the Western Aldan Megablock (granite-gneisses of type II) can be subdivided into two groups according to their composition: granitoids with geochemical characteristics of subduction- and collision-related rocks. The protoliths of the type-II granite-gneisses with geochemical characteristics of subduction granitoids were produced simultaneously with the development of the Fedorovskaya island arc (at 2003–2013 Ma), whereas the protoliths of the type-II granite-gneisses with geochemical characteristics of collision granitoids were formed in the course of accretion of the Fedorovskaya island arc and the Olekma-Aldan continental microplate at 1962–2003 Ma, via the melting of magmatic rocks of the Fedorovskaya unit and older continental crustal material.     

Petrogenesis of the highly potassic 1.42 Ga Barrel Spring pluton,southeastern California,with implications for mid-Proterozoic magma genesis in the southwestern USA

Syenites from the Barrel Spring pluton were emplaced in the Early Proterozoic Mojave crustal provine of southeastern California at 1.42 Ga. All rocks, even the most mafic, are highly enriched in incompatible elements (e.g. K₂O 4–12 wt%, Rb 170–370 ppm, Th 12–120 ppm, La 350–1500xchondrite, La/Yb_n 35–100). Elemental compositions require an incompatible element-rich but mafic (or ultramafic) source. Trace element models establish two plausible sources for Barrel Spring magmas: (1) LREE enriched garnet websterite with accessory apatite±rutile (enriched lithospheric mantle), and (2) garnet amphibolite or garnet-hornblende granulite with enriched alkali basalt composition, also with accessory apatite±rutile (mafic lower crust). Nd and Pb isotopic ratios do not distinguish a crust vs mantle source, but eliminate local Mojave province crust as the principal one, and indicate that generation of the enriched source occurred several hundred million years before emplacement of the Barrel Spring pluton. 1.40–1.44 Ga potassic granites are common in southeastern California, suggesting a genetic link between the Barrel Spring pluton and the granites; however, although the same thermal regime was probably responsible for producing both the granitic and syentic magmas, elemental and isotopic compositions preclude a close relationship. Isotopic similarity of the Barrel Spring pluton to 1.40–1.44 Ga granites emplaced in the Central Arizona crustal province to the east may imply that a common component was present in the lithosphere of these generally distinct regions.     

Sr isotopic chemostratigraphy of Precambrian carbonate rocks in the Amderma Rise,Pai-Khoi Ridge

The Sr and C isotopic compositions of Precambrian carbonate rocks are determined for Amderma Rise, in the northeastern margin of Pai-Khoi Ridge. Based on the Sr isotopic chemostratigraphy, it is established for the first time that the Amderma Formation is referred to the Early Vendian, while the Morozovsk Formation is Late Riphean in age. This conclusion along with detailed mapping proves that the Precambrian “section” of the Amderma Rise is a series of tectonic plates combined in a nonchronostratigraphic order. Volcanic and sedimentary rocks of the Morozovsk and Sokolninsk formations make up the allochthon proper, while carbonate rocks of the Amderma Formation make up the para-autochthon. The high values of δ¹³С (up to +9.5‰) identified in limestones of both formations suggest a considerable distance of the Pai-Khoi paleobasin from the passive margin of the Baltic Region upon facies similarity to the Laurentia active margins.     

Banded iron formations of the calciphyre-metabasite-gneiss association in the East European Craton

The paper presents characteristics of the least studied iron formations of the East European Craton (Archean banded iron formations of the calciphyre-metabasite-gneiss association), a typical member of granulite complexes of the Ukrainian Shield, Belarussian-Baltic region, and Voronezh crystalline massif. They are mainly composed of diverse metasedimentary rocks: aluminous gneisses; silicate-magnetite, magnetite, and barren quartzites; eulysites; calciphyres; and marbles associated with metavolcanic rocks. Data on chemical compositions of the metasedimentary rocks are summarized for the first time and their possible primary mineral composition has been reconstructed using the MINLITH software. It is shown that they could be formed from a lithogenetic series of sediments linked by gradual transitions and geochemical commonness of sediments: from fine-grained terrigenous insufficiently mature sediments to chemogenic sediments depleted in terrigenous material (ferruginous-siliceous, ferruginous-siliceous-carbonate, siliceous-carbonate, and carbonate sediments). The inferred primary mineral assemblage indicates sedimentation in the central parts of large paleobasins in a reducing environment characterized by deficit of oxygen and excess of carbon dioxide. Lithological specifics of the banded iron formations in different regions presumably reflect different distances of sedimentation zones from submarine hydrothermal discharge sites and sources of terrigenous material. The banded iron formations at the present-day erosion section of basement represent metamorphosed fragments of the lateral-facies zoning of rocks of the Archean sedimentary basins (or a single basin) of the East European Craton. Unlike other Early Precambrian banded iron formations of the East European Craton, rocks of the calciphyre-metabasite-gneiss association are marked by a high Mn content.     

Elemental and Sr–Nd–Pb isotopic geochemistry of Late Paleozoic volcanic rocks beneath the Junggar basin, NW China: Implications for the formation and evolution of the basin basement

The basement beneath the Junggar basin has been interpreted either as a micro-continent of Precambrian age or as a fragment of Paleozoic oceanic crust. Elemental and Sr–Nd–Pb isotopic compositions and zircon Pb–Pb ages of volcanic rocks from drill cores through the paleo-weathered crust show that the basement is composed mainly of late Paleozoic volcanic rock with minor shale and tuff. The volcanic rocks are mostly subalkaline with some minor low-K rocks in the western Kexia area. Some alkaline lavas occur in the central Luliang uplift and northeastern Wulungu depression. The lavas range in composition from basalts to rhyolites and fractional crystallization played an important role in magma evolution. Except for a few samples from Kexia, the basalts have low La/Nb (<1.4), typical for oceanic crust derived from asthenospheric melts. Zircon Pb–Pb ages indicate that the Kexia andesite, with a volcanic arc affinity, formed in the early Carboniferous (345 Ma), whereas the Luliang rhyolite and the Wucaiwan dacite, with syn-collisional to within-plate affinities, formed in the early Devonian (395 and 405 Ma, respectively). Positive ε_Nd(t) values (up to +7.4) and low initial ⁸⁷Sr/⁸⁶Sr isotopic ratios of the intermediate-silicic rocks suggest that the entire Junggar terrain may be underlain by oceanic crust, an interpretation consistent with the juvenile isotopic signatures of many granitoid plutons in other parts of the Central Asia Orogenic Belt. Variation in zircon ages for the silicic rocks, different Ba, P, Ti, Nb or Th anomalies in the mafic rocks, and variable Nb/Y and La/Nb ratios across the basin, suggest that the basement is compositionally heterogeneous. The heterogeneity is believed to reflect amalgamation of different oceanic blocks representing either different evolution stages within a single terrane or possibly derivation from different terranes.     

Metallogeny and lead isotopic composition of base metal sulfide deposits in the Rappen area,northern Sweden

Early Proterozoic volcanic and sedimentary rocks of the Rappen district in northern Sweden were deposited at a destructive plate margin to the south of the Archaean craton of the western Baltic Shield. The volcano-sedimentary suite was intruded by two generations of early Proterozoic granites at ca. 1.89–1.85 Ga and ca.1.82–1.78 Ga, respectively, and metamorphosed at upper amphibolite facies conditions. Small stratabound iron, copper, and zinc deposits occur in felsic to mafic tuffs and arkosic sediments. Small deposits of molybdenum, tungsten, and uranium formed during the emplacement of the younger granites. The lead isotopic compositions of sulfide trace lead from the various deposits are highly heterogeneous. In the ²⁰⁶Pb/²⁰⁴Pb–²⁰⁷Pb/²⁰⁴Pb diagram they fall on mixing arrays between little evolved early Proterozoic lead and highly radiogenic Caledonian lead. The least radiogenic lead isotopic compositions from the various deposits have a wide range of ²⁰⁷Pb/²⁰⁴Pb ratios and thus indicate variable involvement of Archaean crustal lead in the Proterozoic deposits. Deposits hosted by siliciclastic rocks have higher ²⁰⁷Pb/²⁰⁴Pb ratios than deposits hosted in mafic to felsic tuffites. The lead isotopic heterogeneity suggests that the lead in the various deposits was locally derived and, furthermore, that the sedimentary rocks in part originated from the Archaean craton to the north. Lead mixing arrays in the ²⁰⁶Pb/²⁰⁴Pb–²⁰⁷Pb/²⁰⁴Pb diagram demonstrate that in Paleozoic time radiogenic lead was mobilized and transported in the basement. Source ages calculated from the mixing arrays (ca.1.9 Ga and ca.1.8 Ga) correspond to the age of the Early Proterozoic volcanism and metamorphism respectively. One group of deposits includes lead from at least three sources and illustrates that radiogenic lead was multiply mobilized and transported in the Proterozoic basement. It occurs in deposits that occur in zones that became permeable during the reactivations of the basement.     

The Lower Changjiang (Yangzi/Yangtze River) metallogenic belt, east central China: intrusion- and wall rock-hosted Cu–Fe–Au, Mo, Zn, Pb, Ag deposits

The lower valley of Changjiang, from Wuhan of the Hubei Province in the west to Zhenjiang of the Jiangsu Province in the east, contains more than 200 polymetallic (Cu–Fe–Au, Mo, Zn, Pb, Ag) deposits and is one of the most important metallogenic belts in China. This metallogenic belt, situated at the northern margin of the Yangzi craton and bordered by the Dabieshan ultrahigh pressure metamorphic belt to the north, consists mainly of Cambrian–Triassic marine clastic sedimentary rocks and carbonate and evaporite rocks, which overlay a Precambrian basement and are intruded by Yanshanian (205 to 64 Ma) granitoid intrusions and subvolcanic complexes. Repeated tectonism from Late Proterozoic to Triassic resulted in extensively developed networks of faults and folds involving the Cambrian–Triassic sedimentary strata and the Precambrian basement. The Yanshanian granitoid intrusions and subvolcanic complexes in the Lower Changjiang metallogenic belt are characterized by whole-rock δ¹⁸O of +8‰ to +10‰, initial ⁸⁷Sr/⁸⁶Sr of 0.704 to 0.708, and εNd^t from −10 to −17 and have been interpreted to have originated from mixing between juvenile mantle and old crustal materials. Also, the Yanshanian granitoids exhibit eastward younging and increase in alkalinity (i.e., from older calc–alkaline in the west to younger subalkaline–alkaline in the east), which are related to oblique collision between the Yangzi and Sino-Korean cratons and tectonic evolution from early compressional to late extensional or rifting regimes. Most polymetallic deposits in the Lower Changjiang metallogenic belt are clustered in seven districts where the Yanshanian magmatism is particularly extensive: from west to east, Edong, Jiurui, Anqing–Guichi, Luzhong, Tongling, Ningwu and Ningzhen. Mineralization is characterized by the occurrence of three distinct types of orebodies in individual deposits: orebodies in Yanshanian granitoid intrusions, skarn orebodies at the contact zones between the Yanshanian intrusions and Late Paleozoic–Early Mesozoic sedimentary rocks, and stratabound massive sulfide orebodies in the Late Paleozoic–Early Mesozoic sedimentary strata. The most important host sedimentary strata are the Middle Carboniferous Huanglong Formation, Lower Permian and Lower–Middle Triassic carbonate and evaporite rocks. The intrusion-hosted and skarn orebodies exhibit well-developed zonation in alteration assemblages, metal contents, and isotopic compositions within individual deposits, and apparently formed from hydrothermal activities related to the Yanshanian magmatism. The stratabound massive sulfide orebodies in the Late Paleozoic–Early Mesozoic sedimentary strata have long been suggested to have formed from sedimentary or volcano-sedimentary exhalative processes in shallow marine environments. However, extensive research over the last 40 years failed to produce unequivocal evidence for syngenetic mineralization. On the basis of geological relationships and isotope geochemical characteristics, we propose a carbonate-hosted replacement deposit model for the genesis of these stratabound massive sulfide orebodies and associated skarn orebodies. This model suggests that epigenetic mineralization resulted from interactions between magmatic fluids evolved from the Yanshanian intrusions with carbonate and evaporite wall rocks. Mineralization was an integral but distal part of the larger hydrothermal systems that formed the proximal skarn orebodies at the contact zones and the intrusion-hosted orebodies. The stratabound massive sulfide deposits of the Lower Changjiang metallogenic belt share many features with the well-studied, high-temperature, carbonate-hosted replacement deposits of northern Mexico and western United States, particularly with respect to association with small, shallow granitoid complexes, structural and stratigraphic controls on mineralization, alteration assemblages, geometry of orebodies, metal association, metal zonation and isotopic systematics.     

Sources and fluid regime of quartz-carbonate veins at the Sukhoi Log gold deposit,Baikal-Patom Highland

Complex (δ¹⁸O, δ¹³C, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, and REE composition) data were obtained on quartz-carbonate veins in metasedimentary rocks to elucidate the material sources and to evaluate fluid regime during low-sulfide gold-quartz ore mineralization at the Sukhoi Log deposit. In order to use an oxygen isotopic thermometry for quartz veins, we calibrated empirical dependence of fractionation factors between vein quartz and altered wall rocks. The temperature range of quartz equilibration with wall rocks was evaluated at 380–190°C. Independent temperatures obtained using this thermometer indicate that the vein ankerite can be both earlier and later than vein quartz. The isotopic systematics (δ¹³C and δ¹⁸O) of ankerite in the quartz-carbonate veins, carbonates in the ore-hosting shales of the Khomolkho and Imnyakh formations both within and outside mineralized zones at the deposit indicate that the ore-hosting rocks and veins in the mineralized zone contain incoming carbonate, which was most probably borrowed from the carbonate rocks of the Imnyakh Formation. REE composition of vein ankerite shows that these elements were transported by fluid as carbonate complexes. The behavior of the Eu/Eu* and (La/Yb)_n ratios and Mn of the vein ankerite suggest that during carbonate crystallization the system was closed with respect to fluid. Sr-Nd isotope systematics indicates that the isotopic parameters of the vein ankerite were formed with the participation of metasedimentary host rocks of both the Imnyakh and Khomolkho formations, which are contrastingly different in Nd isotopic composition. A fluid/rock ratio during metasomatic processes in the wall rocks was calculated for two scenarios of their thermal history: with a continuously operating heat source beneath the Sukhoi Log structure and with a linear cooling of the structure. The effective integral W/R ratios calculated lie within the range of 0.046–0.226 and suggest that the veins were produced with the metamorphic fluid. Low W/R ratios are inconsistent with the mechanism of vein quartz crystallization due to fluid oversaturation with respect to SiO₂ at decreasing temperature. We believe that the main mechanism responsible for the origin of these veins was variations of fluid oversaturation due to pressure variations (pressure solution mechanism). This hypothesis is consistent with the reported isotopic-geochemical characteristics of the wall rocks at the Sukhoi Log deposit.     

Nd, O and Sr isotopic constraints on the origin of Precambrian rocks, Southern Black Hills, South Dakota

The Nd, O and Sr isotopic characteristics of Precambrian metasedimentary, metavolcanic and granitic rocks from the Black Hills of South Dakota are examined. Two late-Archean granites (2.5-2.6 Ga) have T_dm ages of 3.05 and 3.30 Ga, suggesting that at least one of the granites was derived through the melting of significantly older crust. Early-Proterozoic metasedimentary rocks have T_dm ages that range from 2.32 to 2.45 Ga. These model ages, in conjunction with probable stratigraphic ages ranging from 1.9 to 2.2 Ga, indicate that mantle-derived material was added to the continental crust of this region during the early-Proterozoic. Previous studies of the Harney Peak Granite complex have reported U-Pb and Rb-Sr ages of about 1.71 Ga and most granite samples examined in this study have Sr isotopic compositions consistent with that age. Two granite samples taken from the same sill, however, give two-point Rb-Sr and Sm-Nd ages of 2.08 ±0.08 and 2.20 ±0.20 Ga (∑²²⁰⁰_Nd = −15.5), respectively. In addition, whole-rock and apatite samples of the spatially associated Tin Mountain pegmatite give a Sm-Nd isochron age of 2000 ±100 Ma (∑²²⁰⁰_Nd = −5.8 ±1.8).

The Sm-Nd, O and Rb-Sr isotopic systematics of these granitic rocks have been complicated to some degree by both crystallization and post-crystallization processes, and the age of the pegmatite and parts of the Harney Peak Granite complex remain uncertain. Processes that probably complicated the isotopic systematics of these rocks include derivation from heterogeneous source material, assimilation, mixing of REE between granite and country rock during crystallization via a fluid phase and post-crystallization mobility of Sr. The Nd isotopic compositions of the pegmatite and the Harney Peak Granite indicate that they were not derived primarily from the exposed metasedimentary rocks.     

Eozoic complexes of the U.S.S.R.

Soviet geologists consider the Precambrian to be divided into two groups — Archaean and Proterozoic; but such a division is unsatisfactory. A major unconformity separates Proterozoic volcanic and sedimentary formations from an underlying sequence that contains two supergroups of supercrustal formations. The oldest of these is unanimously considered to be Archaean. Rocks of that supergroup play an essential part in the composition of the Baltic, Ukrainian, Aldan and Anabar Shields and of the ancient fold belts of the East-European and Siberian platforms.Distinctive features in the composition, tectonic structure, metamorphism and metallogeny of Archaean complexes lead to the conclusion that they were formed in specifically mobile areas, different from geosynclinal areas.The other supergroup of high-grade metamorphic rocks has no clear place in the accepted two-fold stratigraphic scheme of the Precambrian, and it is considered sometimes to be Archaean and sometimes to be Early Proterozoic. We propose restoring the forgotten name “Eozoic” for that supergroup. Eozoic complexes are characterized by peculiarities of composition and inner structure, which signify changes in the tectonic regime of the earth at the lower and upper boundaries of the Eozoic Supergroup. These peculiarities give grounds for distinguishing the Eozoic Supergroup as an independent stratigraphic division.The Stanovoy Complex of the southern part of the Aldan Shield is a stratotype for the Eozoic Supergroup. Many well-known stratigraphic subdivisions of the Siberian Platform (e.g., the Eniseiskaya, the Birusinskaya series and others), the Taratash Complex of the Urals, the Goranskaya and Shahdarinskaya series of the South-West Pamir, the Tikitch complex and Aulskaya series of the Ukrainian Shield, and in part the Belomorsky Complex of the Baltic Shield, as well as some others, are also Eozoic.The Eozoic complexes are characterized by the following specific features: only some supercrustal formations are typical for them; the small number of rock types which have a total thickness about 5–6 km; relatively monotonous mineral composition of the rocks; variable quantitative ratios of rocks; absence of contrasting marker beds; regional metamorphism and ultrametamorphism in the amphibolite facies; wide development of ultrametamorphic granitoids and migmatites; distinct tectonic differentiations of the basin of sedimentation.Dates determined by isotopic analyses, which mostly reflect the metamorphism of the deposits, fall predominantly in the range 2600–3100 Ma.     

Isotopic composition of phanerozoic ore leads from the Swedish segment of the Fennoscandian Shield

95 analyses of ore lead isotope ratios from 23 Phanerozoic ore deposits from the Swedish segment of the Fennoscandian Shield form a marked linear trend on a ²⁰⁷Pb/²⁰⁴Pb versus ²⁰⁶Pb/²⁰⁴Pb diagram. The line may be interpreted in a two-stage model, the lead being derived from 1.8±0.15 Ga old Svecokarelian basement and mineralization occurring at 0.4±0.15 Ga. The initial composition of the Svecokarelian rock lead was similar to the lead in early Proterozoic volcanogenic sulfide ores in Sweden. — The large spread in the isotope ratios was caused by a combination of selective leaching of different minerals in the source rocks, mixing with less radiogenic Caledonian lead, and local or regional variations in the U, Th and Pb contents of the basement. As a consequence, conventional methods of identifying source rocks from lead isotopic data (e.g. mu-values, Th/U ratios) may not be directly applicable. Phanerozoic ore lead development in the Swedish section of the Fennoscandian Shield was ensialic. That is, the ore lead was almost entirely derived from the Precambrian basement, although this basement does not appear to be anomalously enriched in Pb. No juvenile or mantle lead was apparently contributed to this section of the crust after the Precambrian, except for that mechanically transported onto the western edge of the Shield by the Caledonian nappes. However, some of Europe's largest lead deposits are included in these Swedish Phanerozoic mineralizations, suggesting that it was the nature of the processes involved rather than the richness of the source, that determined their formation.     

Nd,Sr and Pb isotopic and REE geochemical study of some Miocene submarine hydrothermal deposits (Kuroko deposits) in Japan

Neodymium, Sr and Pb isotopic compositions, along with rare earth element (REE) concentrations were determined for twelve black ores and one yellow ore from twelve localities of the Kuroko deposits, Japan. The ores were generated by submarine hydrothermal activity during the Miocene age. Neodymium isotopic compositions of the ores (_Nd: –4.9 to +6.5) mostly overlap with spatially associated igneous rocks. On a Nd versus Sr isotopic correlation diagram, however, ⁸⁷Sr/⁸⁶Sr ratios are shifted from the associated igneous rocks towards the higher contemporaneous seawater ratio. REE patterns are highly variable, ranging from light REE enriched to depleted, and show no Ce anomalies, as would be expected if they were derived from seawater. These results suggest that the REEs contained in ores were mainly derived from the associated igneous rocks, but that the ore Sr is a mixture derived from both seawater and the igneous rocks. Most Pb isotopic compositions fall within the range defined by the associated igneous rocks (²⁰⁶Pb/²⁰⁴Pb=18.35–18.84, ²⁰⁷Pb/²⁰⁴Pb=15.59–15.97 and ²⁰⁸Pb/²⁰⁴Pb=38.53–39.90), although several samples have very radiogenic compositions that were most likely derived from basement rocks. Our new Pb isotopic results display greater variation, and have a larger range of more radiogenic compositions than has been noted previously for these ores. In addition, the black ore with the most radiogenic Pb isotopic composition also has the least radiogenic Nd isotopic composition. This suggests that at least some of the Pb contained in the ores was derived mainly from older basement rocks. The large positive Eu anomalies for some black ores are consistent with a high-temperature origin for the parental fluids, irrespective of the source rock. The single yellow ore examined, however, has a small negative Eu anomaly, which may indicate derivation from a lower temperature fluid. Previous studies suggested that the Kuroko ores were formed in the presence of organic materials in an anoxic basin. Combined Nd, Sr, Pb and Os isotopic and REE abundance data indicate that multiple sources were involved in the genesis of Kuroko ores.     

Sr isotopic characteristic of neoproterozoic carbonate sediments from the southern Yenisei Ridge

This paper presents the first Sr isotopic data for the Late Precambrian carbonate rocks of the southern Yenisei Ridge. Their geochemical study allowed estimation of the degree of secondary alterations and gave the possibility to reveal rocks with a less disturbed Rb-Sr isotopic system. The Sr isotopic data indicated Neoproterozoic sedimentation of the rocks about 1070–750 Ma ago. Sr and C isotopic data showed that carbonate rocks of the Sukhoi Pit, Tungusik, and Shirokino groups are Late Riphean and could be comparable with sedimentary sequences of three Precambrian key sections of the Northern Eurasia: the subsequent Derevnino, Burovaya, and Shorikha formations from the Turukhansk Uplift, the Lakhanda Group from the Uchur-Maya region, and the Karatav Group from the South Urals. All studied carbonate rocks are older than 750 Ma and, according to the International Stratigraphic Chart, accumulated prior to global glaciations in the Cryogenian. This is evident from sedimentological study indicating the absence of tillite horizons in the studied sections. δ¹³C values in the sections vary from +0.4 up to +5.3‰, which testifies to the absence of periods of great cold.     

Diagenetic model of carbonate rocks of Guri Member of Mishan Formation (Lower to Middle Miocene) SE Zagros basin,Iran

In order to understand the post-depositional history of carbonate rocks of Guri Member (Lower to Middle Miocene), three stratigraphic sections were selected in north Bandar-Abbas in southeast of Iran. Sampling was carried out, analyzed for selective parameters such as oxygen and carbon isotopic compositions (δ¹⁸O and δ¹³C) and interpreted in the present study. We recognized several diagenetic processes including micritization, cementation, neomorphism, compaction, dissolution, silicification, dolomitization, fracturing and vein filling. Some of the diagenetic processes occurred at different conditions, so in order to achieve precise interpretation, samples from different carbonate components such as, micrite, fracture cement, solution pore cement, intergranular cement, and some biotic allochems were analyzed. In this study micrite samples were subdivided into two groups including micro-spary and micrite. They were recognized under Cathodoluminescence microscope. In addition, micrite samples were classified into five groups based on their depositional environments: supratidal, lagoon, coral bar, open sea, and open basin. There were minor changes in stable isotope ratios based on the sedimentary environments, stratigraphy successions, and micro-spary or micrite properties. In this study, similar calcite cements in petrography studies were differentiated by stable isotope data. Those calcite cements have formed in different diagenetic environments such as meteoric and burial cements. Paragenetic sequence of carbonate rocks were interpreted by integration of petrographic and isotopic studies. We have reconstructed diagenetic models of Guri Member into four stages including marine, meteoric, burial, and uplifting.     

Early precambrian A-granitoids in the Aldan Shield and adjacent mobile belts: Sources and geodynamic environments

Systematized geological, geochronologic, geochemical, and Sm-Nd isotopic geochemical data obtained over the past decade on A-granitoids in the Aldan Shield and in adjacent mobile belts surrounding it in the south make it possible to identify the sources from which the rocks were derived and the geodynamic environments in which they were generated. The territory in question provides evidence of five episodes of Early Precambrian within-plate magmatism, including the derivation of A-granites: at 2.62, 2.40?C2.52, 2.07, 1.87?C1.88, and 1.70?C1.74 Ga. Although all of the granitoids were derived within plates, the environments of their derivation were different: (i) postcollisional lithospheric extension at 2.64 and 1.87?C1.88 Ga in an anorogenic environment and (ii) in relation to the activity of mantle plumes at 2.40?C2.52, 2.07, 1.74?C1.70 Ga. The postcollisional magmatism generated only potassic granitoids of the subalkaline type, whereas the anorogenic magmatic rocks comprise both subalkaline granitoids (of K series) and alkaline granites (of Na series), which are intensely fractionated and strongly enriched in incompatible elements. A-granitoids in the Aldan Shield and its surrounding folded structures were derived from mixed mantle-crustal sources. The sources of the subalkaline granitoids were dominated by the material of the continental lower crust, while the alkaline granitoids were derived from mantle sources. Thereby the mantle source material of the anorogenic granitoids consisted of an OIB-type component, and the postcollisional granitoids were derived from MORB and OIB sources.     

Melonite group minerals and other tellurides from three Cu–Ni–PGE prospects, Eastern Desert, Egypt

Melonite group minerals and other tellurides are described from three Cu–Ni–PGE prospects in the Eastern Desert of Egypt: Gabbro Akarem, Genina Gharbia and Abu Swayel. The prospects are hosted in late Precambrian mafic–ultramafic rocks and have different geologic histories. The Gabbro Akarem prospect is hosted in dunite pipes where net-textured and massive sulfides are associated with spinel and Cr-magnetite. Michenerite, merenskyite, Pd–Bi melonite and hessite occur mainly as inclusions in sulfides. Typical magmatic textures indicate a limited role of late- and post-magmatic hydrothermal processes. At Genina Gharbia, ore forms either disseminations in peridotite or massive patches in hornblende-gabbro in the vicinity of metasedimentary rocks. Actinolitic hornblende, epidote, chlorite and quartz are common secondary silicates. Sulfide textures and host rock petrography suggest a prolonged late-magmatic hydrothermal event. Michenerite, merenskyite, Pd–Bi melonite, altaite, hessite, tsumoite, sylvanite and native Te are mainly present in secondary silicates. The Abu Swayel prospect occurs in conformable, lens-like mafic–ultramafic rocks in metasedimentary rocks and along syn-metamorphic shear zone. The sulfide ore and host rocks are metamorphosed (amphibolite facies; 550 to 650 °C, 4 to 5 kbar) and syn-metamorphically sheared. Melonite group minerals are represented by merenskyite and Pd–Bi melonite. Other tellurides comprise hessite, altaite and joséite-B. Melonite group minerals and tellurides occur as inclusions in mobilized sulfides and along cracks in metamorphic garnet and plagioclase.The different geological history of the three prospects permits an examination of the role played by magmatic, late-magmatic and metamorphic processes on the mineralogy of melonite group minerals and diversity of tellurides. The contents of PGE and Te in the ore and temperature of crystallization control the mineralogy and compositional trends of the melonite group minerals. Crystallization of the melonite group minerals over a wide range of temperatures in a Te-rich environment enhances the elemental substitutions. Merenskyite dominates the mineralogy of the group at low Te activity, while Pd–Bi melonite is the common phase at high Te activity.     

Provenance of Paleozoic–Mesozoic sedimentary rocks in the Inner Zone of Southwest Japan: An evaluation based on Nd model ages

Nd model ages using depleted mantle (TDM) values for the sedimentary rocks in the Inner Zone of the SW Japan and western area of Tanakura Tectonic Line in the NE Japan allow classification into five categories: 2.6–2.45, 2.3–2.05, 1.9–1.55, 1.45–1.25, and 1.2–0.85 Ga. The provenance of each terrane/belt/district is interpreted on the basis of the TDMs, ¹⁴⁷Sm / ¹⁴⁴Nd vs. ¹⁴³Nd / ¹⁴⁴Nd relation, Nd isotopic evolution of the source rocks in East China and U–Pb zircon ages. The provenance of 2.6–1.8 Ga rocks, which are reported from Hida–Oki and Renge belts and Kamiaso conglomerates, is inferred to be the Sino–Korean Craton (SKC). The 2.3–1.55 Ga rocks, mostly from Ryoke, Mino and Ashio belts, are originally related with the SKC and/or Yangtze Craton (YC). The provenances of the sedimentary rocks with 1.45–0.85 Ga, from the Suo belt, Higo and some districts in the Mino and Ashio belts, are different from the SKC and YC. Especially, the Higo with 1.2–0.85 Ga is considered as a fragment of collision zone in East China. Akiyoshi belt probably belongs to the youngest age category of 1.2–0.85 Ga.Some metasedimentary rocks from the Ryoke belt have extremely high ¹⁴⁷Sm / ¹⁴⁴Nd and ¹⁴³Nd / ¹⁴⁴Nd ratios, whose main components are probably derived from mafic igneous rocks within the Ryoke belt itself and from the adjacent Tamba belt.