假蓝宝石(Sapphirine)的矿物学特征及其在超高温变质作用研究中的应用

假蓝宝石是Mg-Al质麻粒岩中一种特殊的高温矿物,对超高温变质作用的研究有重要的意义。本文通过对全球66个超高温麻粒岩中47个含假蓝宝石麻粒岩地区的文献调研,总结了几种最常见的含假蓝宝石矿物组合产出的结构位置和变质反应关系,以及假蓝宝石的矿物化学特征。假蓝宝石的化学成分一般位于7∶9∶3端元左右,X_(Mg)大于0. 7,XFe_(3+)变化范围很宽,为0～0. 7。含假蓝宝石矿物组合的形成和演化指示了岩石经历的P-T轨迹。岩石中保留的假蓝宝石取代尖晶石、Grt/Opx+Sil取代Spr+Qz组合,以及随后的Spr+Crd±Opx后成合晶取代Grt/Opx+Sil组合的结构,一般可能指示了逆时针P-T轨迹中冷却和随后减压的部分;岩石中Grt/Opx+Sil/Ky或富Mg十字石反应形成Spr+Qz组合的结构可能指示了顺时针P-T轨迹中减压升温的部分。超高温变质岩不同的P-T轨迹暗示着它们的成因机制并不单一,前者可能是幔源基性岩浆底侵或增生作用的结果,后者可能与长期的热造山作用相关。     

Low-grade regional metamorphism in the Mesozoic-Cenozoic volcanic sequences of the Central Andes

ABSTRACT All the Mesozoic and Cenozoic volcanic rocks of the Central Andes (from southern Ecuador to central Chile), except Recent ones, have been affected by episodes of regional metamorphism, without change in texture and structure. The metamorphism, which ranges from low zeolite to greenschist facies, can be classified as burial metamorphism because there is an overall increase in metamorphic grade with stratigraphic depth in the individual volcanic sequences separated by regional unconformities. Some sequences display metamorphic patterns transitional to ocean-floor and to geothermal field types, reflecting variations along and across the Andes in tectonic setting and thermal gradients. Volcanism was closely followed by metamorphism during each cycle characterizing the geological history of the Central Andes. The episodic nature of the metamorphism has led to breaks in metamorphic grade at regional unconformities and repetition of facies series, where strata of higher grade may even overlie those of lower grade. The existence of permeability-controlled distribution patterns of secondary minerals within individual flows shows that gradients of chemical activity, rate of reaction and P_fluid were acting, in addition to temperature and P,_tot overall gradients, during the regional metamorphism. The alteration is accompanied by chemical changes and disturbances of the K-Ar and Rb-Sr isotope systems. Similarities between Mesozoic facies series in the western and eastern flanks of the Andes are consistent with a mechanism of ensialic spreading-subsidence.     

Exsolution textures in orthopyroxene in aluminous granulites as indicators of UHT metamorphism: New evidence from the Eastern Ghats Belt, India

Highly aluminous orthopyroxene, coexisting with sapphirine, cordierite, sillimanite, quartz and garnet in various combinations, constitute granoblastic mosaic peak metamorphic assemblages in aluminous granulites from three localities in the Eastern Ghats Belt, India. Orthopyroxene contains four types of intergrowths: (a) involving sapphirine with or without cordierite, (b) involving spinel, but without sapphirine, (c) involving cordierite, but without sapphirine and spinel, and (d) involving garnet, without sapphirine, spinel or cordierite. On the basis of textural and compositional data, origin of the intergrowths is ascribed to breakdown of Mg-Tschermak component, locally also involving Fe- and Ti-Tschermak. An attempt is made to compute the “pre-breakdown” compositions of orthopyroxene by image analysis, which shows maximum Al₂O₃ content of 13.4 wt.% in the pristine orthopyroxene. Geothermometry, phase equilibria consideration and application of existing experimental data on alumina solubility in orthopyroxene coexisting with sapphirine and quartz, collectively indicate extreme thermal conditions of metamorphism (> 1000 °C) for the studied assemblages. This re-affirms the notion that Al₂O₃ solubility in orthopyroxene is the most powerful indicator of UHT metamorphism (Harley, S.L., 2004. Extending our understanding of ultrahigh temperature crustal metamorphism. J. Mineral. Petrol. Sci. 99, 140–158). The intergrowths are considered to have formed due to cooling from the thermal peak spanning a temperature range of approximately 150 °C. Appearance of diverse types of intergrowths is probably related to subtle differences in bulk composition, particularly Fe:Mg ratios.     

UHT metamorphism on Seram,eastern Indonesia: reaction microstructures and P–T evolution of spinel‐bearing garnet–sillimanite granulites from the Kobipoto Complex

The island of Seram, part of the northern limb of the Banda Arc in eastern Indonesia, exposes an extensive Mio‐Pliocene granulite facies migmatite complex (the Kobipoto Complex) comprising voluminous leucosome‐rich diatexites and scarcer Al–Fe‐rich residual granulites. The migmatites are intimately associated with ultramafic rocks of predominantly lherzolitic composition that were exhumed by substantial lithospheric extension beneath low‐angle detachment faults; heat supplied by the lherzolites was evidently a major driver for the granulite facies metamorphism and accompanying anatexis. Residual garnet–sillimanite granulites sampled from the Kobipoto Mountains, central Seram, contain scarce garnet‐hosted inclusions of hercynite spinel (~1.5 wt% ZnO) + quartz (± ilmenite) in direct grain‐boundary contact – an assemblage potentially indicative of metamorphism under ultrahigh‐temperature (UHT) conditions. thermocalc ‘Average P–T’ reactions and melanosome‐specific thermocalc , T–M_O, and P–T pseudosections in the Na₂O–CaO–K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O–TiO₂–Fe₂O₃ (NCKFMASHTO) chemical system, supported by Ti‐in‐garnet thermobarometry, are permissive of the rock having experienced a clockwise P–T path peaking at 925 °C and 9 kbar – thus narrowly reaching UHT conditions – before undergoing near‐isothermal decompression to ~750 °C and ~4 kbar. Spinel + quartz assemblages are interpreted to have formed at or just after the metamorphic peak from localized reactions between sillimanite, ilmenite and surrounding garnet. Further decompression of the rock resulted in the formation of complex reaction microstructures comprising cordierite ± plagioclase coronae around garnet, and symplectic intergrowths of cordierite + spinel + ilmenite around sillimanite. Small grains of sapphirine + corundum developed subsequently within spinel by localized quartz‐absent reactions. The post‐peak evolution of the granulites may be related to previously published U–Pb zircon and ⁴⁰Ar/³⁹Ar ages of c. 16 Ma, further substantiating the claim for the Kobipoto Complex granulites having recorded Earth's youngest‐identified episode of UHT metamorphism, albeit at slightly lower temperature and higher pressure than previously inferred. The Kobipoto Complex granulites demonstrate how UHT conditions may be achieved in the ‘modern’ Earth by extreme lithospheric extension, which, in this instance, was driven by slab rollback of the Banda Arc.     

Sapphirine + quartz assemblage in contrasting textural modes from the Eastern Ghats Belt, India: Implications for stability relations in UHT metamorphism and retrograde processes

Stability of the assemblage sapphirine + quartz in Mg–Al-rich granulites implies ultrahigh temperature (UHT) condition of metamorphism but their direct contact is rarely preserved in natural rocks. The present study shows contrasting textural relations between sapphirine and quartz in different parts of the same occurrence of a Mg–Al-rich granulite, Eastern Ghats Belt, India. Textural data suggest stabilization of the assemblage sapphirine + quartz with orthopyroxene and cordierite during the metamorphic peak. Thermometric estimates yield temperature exceeding 950 °C for the stability of this assemblage. Most of such sapphirine grains (Spr₁) are texturally separated from quartz and cordierite grains by double corona of sillimanite + orthopyroxene that results due to isobaric cooling during the post-peak stage. Sapphirine (Spr₂) also forms a symplectic intergrowth with quartz and orthopyroxene at the fringe of coarse orthopyroxene. This textural feature can be explained by the breakdown of (Fe, Mg)-Tschermak components of orthopyroxene during the same isobaric cooling episode from UHT peak condition. The preservation of grain contact of this intergrown sapphirine and quartz can be attributed to a problem in reaction kinetics. In the other mode, sapphirine (Spr₃) occurs with quartz with a thin skin of cordierite near a quartz vein. Such texture could result from isothermal decompression of the cooled crust. Alternatively and more possibly, cordierite could form from ingress of CO₂–H₂O rich fluid during terminal stage of cooling. Finally, sapphirine (Spr₄) and quartz show direct contact close to the quartz vein. Direct contact of such sapphirine and quartz represents textural disequilibrium as this particular quartz is introduced as a vein much later than the peak metamorphism but prior to the major foliation-forming deformation. Coarse sapphirine and vein quartz, therefore, accidentally came in contact with each other and persisted metastably. Therefore, though coexistence of sapphirine and quartz is considered to be a strong evidence for ultrahigh temperature condition, care should be taken to decipher their stable coexistence. Different types of textural relations involving this mineral pair could originate in a single rock, probably in different stages of its metamorphic history.     

Modelling of mineral equilibria in ultrahigh-temperature metamorphic rocks from the Anápolis–Itauçu Complex, central Brazil

A new quantitative approach to constraining mineral equilibria in sapphirine‐bearing ultrahigh‐temperature (UHT) granulites through the use of pseudosections and compatibility diagrams is presented, using a recently published thermodynamic model for sapphirine. The approach is illustrated with an example from an UHT locality in the Anápolis–Itauçu Complex, central Brazil, where modelling of mineral equilibria indicates peak metamorphic conditions of about 9 kbar and 1000 °C. The early formed, coarse‐grained assemblage is garnet–orthopyroxene–sillimanite–quartz, which was subsequently modified following peak conditions. The retrograde pressure–temperature (P–T) path of this locality involves decompression across the FeO–MgO–Al₂O₃–SiO₂ (FMAS) univariant reaction orthopyroxene + sillimanite = garnet + sapphirine + quartz, resulting in the growth of sapphirine–quartz, followed by cooling and recrossing of this reaction. The resulting microstructures are modelled using compatibility diagrams, and pseudosections calculated for specific grain boundaries considered as chemical domains. The sequence of microstructures preserved in the rocks constrains a two‐stage isothermal decompression–isobaric cooling path. The stability of cordierite along the retrograde path is examined using a domainal approach and pseudosections for orthopyroxene–quartz and garnet–quartz grain boundaries. This analysis indicates that the presence or absence of cordierite may be explained by local variation in a_H2O. This study has important implications for thermobarometric studies of UHT granulites, mainly through showing that traditional FMAS petrogenetic grids based on experiments alone may overestimate P–T conditions. Such grids are effectively constant a_H2O sections in FMAS‐H₂O (FMASH), for which the corresponding a_H2O is commonly higher than that experienced by UHT granulites. A corollary of this dependence of mineral equilibria on a_H2O is that local variations in a_H2O may explain the formation of cordierite without significant changes in P–T conditions, particularly without marked decompression.     

Geochronological and isotopical review of pre-Devonian crustal basement of the Colombian Andes

Under the flatlands east of the Andes, the crustal basement is exposed in a few places, composed mainly of the Mitú migmatitic complex and the Parguaza granite, whose ages range between 1.78 and 1.45 Ga. Extensive outcrops of high-grade metamorphic rocks are found in several places. Two metamorphisms are dated between 1.2–1.1 and 1.0–0.9 Ga. They are considered blocks that formed during the Grenville orogeny and have Sm–Nd T_DM model ages of 1.87–1.47. The Andaquí terrane is formed mainly by the Garzón Massif, composed of granulites, migmatites, and granites, and the metamorphic rocks of the Sierra de la Macarena, which are covered by undeformed Cambrian sediments. It is believed that after the Grenville orogeny, this unit remained attached to the Amazonic Craton. All the other areas grouped in the Chibcha terrane, though they formed during the Grenville orogeny, are believed to have remained either as part of another continental block or dispersed islands to be amalgamated to the Amazonic Craton during the Lower Paleozoic orogeny, which in the Quetame Massif is dated between the Silurian and Devonian and is named the Quetame orogenic event.     

New constraints on UHT metamorphism in the Eastern Ghats Province through the application of phase equilibria modelling and in situ geochronology

High Mg–Al granulites from the Sunki locality in the central portion of the Eastern Ghats Province record evidence for the high-temperature peak and retrograde evolution. Peak metamorphic phase assemblages from two samples are garnet + orthopyroxene + quartz + ilmenite + melt and orthopyroxene + spinel + sillimanite + melt, respectively. Isochemical phase diagrams (pseudosections) based on bulk rock compositions calculated in the chemical system Na₂O–CaO–K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O–TiO₂–Fe₂O₃ (NCKFMASHTO) and Al contents in orthopyroxene indicate peak UHT metamorphic conditions in excess of 960 °C and 9.7 kbar. Microstructures and the presence of cordierite interpreted to record the post-peak evolution show that the rocks underwent decompression and minor cooling from conditions of peak UHT metamorphism to conditions of ~ 900 °C at ~ 7.5 kbar. In situ U–Pb isotope analyses of monazite associated with garnet and cordierite using the Sensitive High Resolution Ion Microprobe (SHRIMP) yield a weighted mean ²⁰⁷Pb/²³⁵U age of ca. 980 Ma, which is interpreted to broadly constrain the timing of high-temperature monazite growth during decompression and melt crystallization at ~ 900–890 °C and 7.5 kbar. However, the range of ²⁰⁷Pb/²³⁵U monazite ages (from ca. 1014 Ma to 959 Ma for one sample and ca. 1043 Ma to 922 Ma for the second sample) suggest protracted monazite growth during the high-temperature retrograde evolution, and possibly diffusive lead loss during slow cooling after decompression. The results of the integrated petrologic and geochronologic approach presented here are inconsistent with a long time gap between peak conditions and the formation of cordierite-bearing assemblages at lower pressure, as proposed in previous studies, but are consistent with a simple evolution of a UHT peak followed by decompression and cooling.     

极端条件下的变质作用——变质地质学研究的前沿

在简单回顾变质地质学形成和发展的不同历程的基础上,扼要地总结了近年来有关极端条件下的超高压变质作用、超高温变质作用和很低温变质作用研究的现状和存在的问题。根据峰期变质温度的不同,结合其矿物组合和地质产状特征,进一步提出将超高压变质作用划分为低温超高压变质作用(峰期变质温度低于600℃)、中温超高压变质作用(峰期变质温度介于600~900℃)和高温超高压变质作用(峰期变质温度大于900℃)。低温超高压变质作用与大洋板块的冷俯冲作用有关,其研究对于探讨俯冲带水流体的循环和地幔水流体的成因具有重要意义;中、高温超高压变质作用与大陆深俯冲作用相关,是目前超高压变质作用研究的热点领域;高温超高压变质作用的研究与探讨地球内(深)部组成和结构相关,一直是地质学家关注的前沿问题。超高温变质作用研究正在向深入发展,中国有关超高温变质作用的研究才刚刚起步;很低温变质作用的研究长期以来没有得到应有的重视,随着研究手段和方法的不断完善和提高,将会有大的发展。极端条件下的变质作用是近年来固体地球科学研究取得的重要进展,是目前变质地质学研究的前沿领域。     

High pressure-low temperature metamorphism in the Gran Paradiso basement, Western Alps

The Gran Paradiso basement complex of the French and Italian Alps is composed of metasediments, termed the gneiss minuti, and metabasic rocks, both of which are intruded by a late Hercynian granite. The Bonneval gneiss, which crops out at the western edge of the complex, is composed of highly deformed metasediments, volcanics and volcaniclastic rocks. Eclogites, now highly altered, occur in the metabasic rocks. Kyanite and blue-green amphibole are locally present in the gneiss minuti and aegirine plus riebeckite occur in the Bonneval gneiss. A moderately high pressure - low temperature metamorphic event of probable Alpine age occurred in the basement complex. This metamorphic event differs from that in the overlying Sesia unit and ophiolites of the Schistes lustrés nappe in being at lower pressures (below the ab = jd₁₀₀+ qz transition) and post-dating the major (D2_A) deformation. The origin of the metamorphism is discussed and interpreted as a probable consequence of the overlying nappe pile which was emplaced during the D2_A event. Subsequent greenschist facies metamorphism in the basement complex is a consequence of thermal relaxation during uplift.     

Structure and metamorphism of the Gondwanan basement in the Bariloche region (North Patagonian Argentine Andes)

In the Bariloche region, the Gondwanan basement consists of metamorphic and deformed igneous rocks intruded by Mesozoic and Tertiary granitoids. Metasediments and amphibolites have been affected by three main deformation events (D1, D2 and D3). D1 (S1 foliation) is well shown preserved in the microlithons of the S2 regional foliation and in albite and garnet porphyroblasts. Both foliations have been folded by upright open folds with associated crenulation (S3) locally developed in the D3 folds hinge zones. An early-stage (syn-D1) subduction episode can be invoked based on evidence of high pressure (HP) metamorphism in schists and amphibolites as well as on the presence of pre-collisional I-type granitoids. D2–D3 developed under regional intermediate pressure–low pressure (IP–LP) metamorphic conditions. High temperature (HT) conditions were reached, as deduced from regional migmatization and the intrusion of syn- to late-orogenic S-type granitoids. The transition from HP to IP metamorphic conditions could be associated with the emplacement of NE directed crustal-scale thrusts during D2.     

Garnet–clinopyroxene intermediate granulites in the St. Leonhard massif of the Bohemian Massif: ultrahigh‐temperature metamorphism at high pressure or not?

Garnet–clinopyroxene intermediate granulites occur as thin layers within garnet–kyanite–K–feldspar felsic granulites of the St. Leonhard granulite body in the Bohemian Massif. They consist of several domains. One domain consists of coarser‐grained coexisting ternary feldspar, clinopyroxene, garnet, quartz and accessory rutile and zircon. The garnet has 16–20% grossular, and the clinopyroxene has 9% jadeite and contains orthopyroxene exsolution lamellae. Reintegrated ternary feldspar and the Zr‐in‐rutile thermometer give temperatures higher than 950 °C. Mineral equilibria modelling suggests crystallization at 14 kbar. The occurrence and preservation of this mineral assemblage is consistent with crystallization from hot dry melt. Between these domains is a finer‐grained deformed matrix made up of diopsidic clinopyroxene, orthopyroxene, plagioclase and K‐feldspar, apparently produced by reworking of the coarser‐grained domains. Embedded in this matrix, and pre‐dating the reworking deformation, are garnet porphyroblasts that contain clinopyroxene, feldspar, quartz, rutile and zircon inclusions. In contrast with the garnet in the coarser‐grained domains, the garnet generally has >30% grossular, the included clinopyroxene has 7–27% jadeite and the Zr content of rutile indicates much lower temperatures. Some of these high‐grossular garnet show zoning in Fe/(Fe + Mg), decreasing from 0.7 in the core to 0.6 and then increasing to 0.7 at the rim. These garnet are enigmatic, but with reference to appropriate pseudosections are consistent with localized new mineral growth from 650 to 850 °C and 10 to 17 kbar, or with equilibration at 20 kbar and 770 °C, modified by two‐stage diffusional re‐equilibration of rims, at 10–15 and 8 kbar. The strong pervasive deformation has obscured relationships that might have aided the interpretation of the origin of these porphyroblasts. The evolution of these rocks is consistent with formation by igneous crystallization and subsequent metamorphism to high‐T and high‐P, rather than an origin by ultrahigh‐T metamorphism. Regarding the petrographic complexity, combination of the high grossular garnet with the ternary feldspar to infer ultrahigh‐T metamorphism at high pressure is not justified.     

Structure and metamorphism of the Karakorum gneisses in the Braldu-Baltoro Valley (North Pakistan)

Abstract

The Karakorum gneisses outcrop north of the complex suture separating the Indian-Pakistan plate from the Europe-Asia block; they grade to deformed earlier members of the Karakorum batholith ranging in age from Cretaceous to Miocene and are cross-cut by its later members. The main interest of the region lies in the fact that very young high-grade gneisses (Miocene), outline the southern edge of the Europe-Asia Plate. The tectonic and metamorpic evolution of the Braldu-Baltoro region is interpreted here as resulting from a poly phased history. The following structural sequence has been defined : - (1) A Dl isoclinal folding was accompanied by subparallel healed shear zones and by intense boudinage, and cross-cut by a dense net of post-Dl hetero-geneous leucogranitic veins and stocks; - (2) a major phase of EW trending recumbent folds (D2), is followed by (3) large open D3 folds generating EW trending domai structures (Dassu and Panmah domes); and (4) a late set of brittle to locally more ductile structures such as the southern thrust contact of the Karakorum gneisses with the Shyok suture zone. The sequence proposed here differs from other interpretations (Rex et al. 1988). We consider that the Dl event only may be attributed to the main India-Asia collision and that the D2-D3 events, interpreted as having occurred in a continuum, correspond to a late reactivation of the major thrusts and sutures related to continuing continental subduction.

A Dl-related intermediate pressure assemblage is preserved (Grt-St-Ky) in the upper levels of the tectonic pile; the estimated PT conditions determined are 10-4 Kb and 700°--525°C. In the core of the large D3 domes, late granoblastic recrystallization is widespread together with almost complete S1-S2 transposition, incipient melting and development of a low-pressure sillimanite-bearing assemblage where relicts of higher pressure minerals are locally preserved. Corresponding PT conditions are 650°-550°C and a lower pressure (5.5 to 2.5 Kb). As most of the observed structures at the lower levels (mineral lineations, boudinage) are clearly associated with (or reworked by) D2 and accentuated by D3 which was accompagnied by partial melting, D2 and D3 are interpreted as representing a continuum developed in the same PT field. It can be assumed also that the Baltoro granite was emplaced by the end of this combined D2-D3 event. From the Miocene ages published for the Baltoro granite (20 Ma to 8 Ma), the low-pressure evolution of the Karakorum gneisses may represent a very young high-grade assemblage. The age of Dl is less defined but at least older than 36 Ma old leucogranites.

The sharp contact along the Shyok Suture zone, interpreted as a large thrust (Main Karakorum Thrust - MKT) of this young high-grade metamorphic terrene against the older (older than 30-45 Ma from late undeformed intrusives) Kohistan-Ladakh island-arc domain, is interpreted, following Mattauer (1985), as resulting from the interaction between the still-ongoing northward movement of the Indo-Pakistan plate and an opposite southward continental subduction, seismically active, operating in Pamir.     

Grassroots scalar politics: Insights from peasant water struggles in the Ecuadorian and Peruvian Andes

Based on insights from peasant and indigenous communities’ struggles for water in Andean Peru and Ecuador, in this article we argue that the defense of grassroots interests -and with it the advancement of more equitable governance- greatly hinges on the capacity of these groups to engage in grassroots scalar politics. With increasing pressure on water resources in the Andes, the access to water of many rural peasant and indigenous communities is being threatened. The growing realization that their access to water and related interests are embedded in broader regional and national politics, legal frameworks and water policies, has led many communities and peasant water user associations to engage in networks and create alliances with other water users, governmental institutions and non-governmental actors. To better understand these (and other) grassroots struggles and strategies, in this contribution we develop the concept of grassroots scalar politics, which we use as a lens to analyze two case studies. In Ecuador we present how water users of the province of Chimborazo have defended their interests through the consolidation of the Provincial Water Users Associations’ Federation Interjuntas-Chimborazo and its networks. Then we focus on how with the support of Interjuntas-Chimborazo the Water Users Association of the Chambo irrigation system defended their historical water allocation. In Peru we analyze the conformation and achievements of the federative Water Users Association of Ayacucho (JUDRA) and present how the community of Ccharhuancho in the region of Huancavelica, managed to defend its waters and territory against the coastal irrigation sector of Ica.     

Three mechanisms of ore re-mobilisation during amphibolite facies metamorphism at the Montauban Zn–Pb–Au–Ag deposit

The relative importance of mechanical re-mobilisation, hydrothermal dissolution and re-precipitation, and sulphide melting in controlling redistribution of metals during concurrent metamorphism and deformation is evaluated at the middle amphibolite facies Montauban deposit in Canada. As at many other deposits, ductile deformation was important in driving mechanical re-mobilisation of massive sulphides from limb regions into hinge regions of large-scale folds and is thus the most important for controlling the economics of Pb and Zn distribution. Two possible stages of hydrothermally driven re-mobilisation are discussed, each of which produces characteristically different alteration assemblages. Prograde hydrothermal re-mobilisation is driven by pyrite de-sulphidation and concurrent chlorite dehydration and is thus an internally driven process. At Montauban, the H₂S-rich fluid generated through this process allowed re-mobilisation of gold into the wall rock, where it was deposited in response to sulphidation of Fe Mg silicates. Retrograde hydrothermal re-mobilisation is an externally driven process, whereby large volumes of fluids from outside the deposit may dissolve and re-precipitate metals, and cause hydration of silicate minerals. This second hydrothermally driven process is not recognised at Montauban. Sulphide melting occurred as temperatures neared the peak metamorphic conditions. Melting initiated in the massive sulphides through arsenopyrite breakdown, and a small volume of melt was subsequently re-mobilised into the wall rock. Trace element partitioning and fractional crystallisation of this melt generated a precious metal-rich fractionate, which remained mobile until well after peak metamorphism. Thus, prograde hydrothermal re-mobilisation and sulphide melting were the most important mechanisms for controlling the distribution of Au and Ag.     

Refining the P–T records of UHT crustal metamorphism

Ultra‐high‐temperature (UHT) metamorphism occurs when the continental crust is subjected to temperatures of greater than 900 °C at depths of 20–40 km. UHT metamorphism provides evidence that major tectonic processes may operate under thermal conditions more extreme than those generally produced in numerical models of orogenesis. Evidence for UHT metamorphism is recorded in mineral assemblages formed in magnesian pelites, supported by high‐temperature indicators including mesoperthitic feldspar, aluminous orthopyroxene and high Zr contents in rutile. Recent theoretical, experimental and thermodynamic data set constraints on metamorphic phase equilibria in FMAS, KFMASH and more complex chemical systems have greatly improved quantification of the P–T conditions and paths of UHT metamorphic belts. However, despite these advances key issues that remain to be addressed include improving experimental constraints on the thermodynamic properties of sapphirine, quantifying the effects of oxidation state on sapphirine, orthopyroxene and spinel stabilities and quantifying the effects of H₂O–CO₂ in cordierite on phase equilibria and reaction texture analysis. These areas of uncertainty mean that UHT mineral assemblages must still be examined using theoretical and semi‐quantitative approaches, such as P(–T)–μ sections, and conventional thermobarometry in concert with calculated phase equilibrium methods. In the cases of UHT terranes that preserve microtextural and mineral assemblage evidence for steep or ‘near‐isothermal’ decompression P–T paths, the presence of H₂O and CO₂ in cordierite is critical to estimates of the P–T path slopes, the pressures at which reaction textures have formed and the impact of fluid infiltration. Many UHT terranes have evolved from peak P–T conditions of 8–11 kbar and 900–1030 °C to lower pressure conditions of 8 to 6 kbar whilst still at temperature in the range of 950 to 800 °C. These decompressional P–T paths, with characteristic dP/dT gradients of ～25 ± 10 bar °C^?1, are similar in broad shape to those generated in deep‐crustal channel flow models for the later stages of orogenic collapse, but lie at significantly higher temperatures for any specified pressure. This thermal gap presents a key challenge in the tectonic modelling of UHT metamorphism, with implications for the evolution of the crust, sub‐crustal lithosphere and asthenospheric mantle during the development of hot orogens.     

Palaeoproterozoic metamorphism in the Jeori-Wangtu Gneissic Complex (JWGC), western Himalayas

The Jeori-Wangtu Gneissic Complex (JWGC) exposed as a tectonic window in the Lesser Himalayas represents one of the oldest Gneissic Complex of the Himalayas. Foliated granite and the metapelite constitute the dominant lithologies of the JWGC. The western margin of the JWGC is bounded by a brittle shear while in the east, the tectonic surface is a ductile shear zone.Kyanite schist, chloritoid schist, staurolite schist (St-1), garnet schist and staurolite schist (St-2) are present in a west to east sequence beginning from near to the Jhakhri thrust and up to the contact with the JWGC granite. Mica schist is intermittently present and is the dominant metapelite. Low to medium grade regional metamorphic conditions has been inferred for these rocks.Calc silicate enclaves within the JWGC granite preserve the contact metamorphic effects. These are reflected in development of narrow zones of disequilibrium assemblages of calcareous garnet (grs₅₃), clinopyroxene, K feldspar, calcic plagioclase (An₈₆), quartz, zoned sphene, zoned allanite, amphiboles, calcite and epidote.Recording of contact metamorphic assemblage of 1.80 Ga granite witin the enclave calc silicates and in the host metapelites over an earlier, relict low to medium grade assemblage indicates that the JWGC preserves palaeoproterozoic metamorphic imprints.     

Widespread relics of high-pressure metamorphism confirm major terrane accretion in Ecuador: a new example from the Northern Andes

Metamorphic rocks from two sections through the North Andean Cordillera Real in Ecuador contain phengites as relics of high-pressure (HP) metamorphism. Their maximum Si contents per formula unit are (1) 3.25 in Al-rich metapelites, (2) 3.35 in ordinary metapelites and garnet-rich metabasites, and (3) 3.45 in garnet-bearing orthogneisses. Detailed pressure–temperature paths were derived by calculating P–T pseudosections. Garnet-bearing metapelite and metabasite yielded a P–T path starting at 1.4 GPa and 525°C. Peak temperature conditions were 560°C at <1.4 GPa. The retrograde path passed through 0.7–0.8 GPa at 500°C. An adjacent metagranitoid experienced a similar P–T evolution at slightly lower temperatures of about 30–50°C. This is the first reported occurrence of HP metamorphism in the Cordillera Real; it is widespread and evidently was the result of continental collision. We hypothesize that a single microcontinent collided with the South American continental margin in Early Cretaceous time. In contrast to our findings, previous models have simply suggested the amalgamation of several terranes in the late Mesozoic or earlier in the region of Ecuador. Therefore, we propose that a widespread search for HP relics should be undertaken. Such relics provide a general criterion for defining subducted terranes and their respective boundaries.     

东南极茹尔群岛梅瑟半岛富铁铝副片麻岩超高温变质作用：相平衡模拟与锆石U-Pb年龄

东南极梅瑟半岛出露大量的副片麻岩。本文以岩相学和矿物化学为基础,结合相平衡模拟、地质温度计及年代学分析方法对费拉副片麻岩中的含尖晶石榴夕线石片麻岩和梅瑟副片麻岩中的含堇青石榴夕线石片麻岩进行综合研究,结果显示片麻岩经历了超高温(UHT)麻粒岩相变质作用。两个样品峰期前阶段(M1)进变质条件为600~650℃和0.63~0.85GPa;峰期UHT阶段(M2)变质条件为930~1000℃和0.9~1GPa;峰期后变质重结晶阶段(M3)变质条件为610~780℃和0.3~0.39GPa。三个不同阶段的变质条件定义了一致的顺时针的P-T演化轨迹。锆石U-Pb年龄分析结果表明两个片麻岩样品的超高温变质和相关的深熔作用发生在990~920Ma期间的早新元古代格林威尔期,而流体改造与变质重结晶作用发生在~510Ma的早古生代泛非期。结合区域地质特征,超高温变质作用发生的构造背景可能与以放射性元素衰变为热源的大型热碰撞造山带相关。

     

Palaeozoic accretion of the microcontinent Chilenia,North Patagonian Andes: high-pressure metamorphism and subsequent thermal relaxation

Basement rocks of the Colohuincul Complex (CC) crop out in the eastern foothills of the North Patagonian Andes (latitude 41°S). We studied the chemical composition of mineral phases in a mica-schist and a migmatite of this complex and constructed P–T pseudosections contoured by various chemical parameters of minerals. The P–T metamorphic path of the mica-schist is characterized by a high-pressure, low-temperature event (1.8 GPa and 440°C) indicated by a spessartine-rich core in prograde-zoned garnet and phengite relicts with high Si contents (3.40 pfu). The increase of X_pyrope (from 0.02 to 0.08) towards the garnet rim and the decrease of Si (to 3.16) in phengite reflect decompression accompanied by heating to 580°C (1.1 GPa), followed by cooling to 570°C (0.9 GPa). In contrast, the migmatitic paragneiss underwent partial melting and subsequent P–T conditions of 610°C and 0.5 GPa. Thermal relaxation after crustal thickening deduced from the mica-schist is interpreted to be the result of collision as the microcontinent Chilenia was thrust under the western South American part of Gondwana. Mid-upper crustal P–T conditions of the migmatite reflect its location within the Gondwanan crust. Two populations of monazite Th–U–Pb ages in migmatites and schists of the Colohuincul Complex with weighted average peaks at 391.7 ± 4.0 Ma (2σ) and 350.4 ± 5.8 Ma (2σ) are ascribed to the collisional and a later retrograde event.