东疆地区原油芳烃地球化学特征及其意义

在对东疆地区(包括吐哈盆地和三塘湖盆地)原油饱和烃生物标志物地球化学特征研究基础上,对原油芳烃馏分进行全面分析及地球化学特征研究;通过深入剖析原油芳烃系列组成,明确东疆地区原油类型划分,根据烷基奈、"三芴"系列及卡达烯、惹烯等化合物的分布特征,进一步揭示三塘湖盆地石炭系原油母源沉积水体盐度低、还原性弱,成油母质中包含丰...     

油藏地球化学原理及其在油气勘探与油藏评价中的应用

综合评述了近年来油藏地球化学基础研究方面的主要进展,包括油气藏内流体非均质性成因、烃充注成藏及混合作用模式、储层内流体与岩石相互作用、油藏内烃的地球化学变化等,阐述了烃族群划分及其地球化学意义。结合实例介绍了油藏地球化学在油气勘探、油藏评价与油田生产管理中的主要应用领域与研究现状。在油气勘探领域的应用主要包括烃运移方向的地球化学研究、烃成藏时间及期次的确定、古油水界面的判别等;在油藏评价和油田生产管理方面的应用主要有油藏流体的连通性和分隔性研究、混合开采油藏单层产能贡献研究以及油、水、干层的地球化学识别等。     

储层定量荧光技术及其在油气成藏研究中的应用

储层定量荧光技术,包括储层颗粒定量荧光(QGF)、储层萃取液定量荧光(QGF-E)、储层颗粒内部油包裹体定量荧光(QGF+)、全息扫描荧光(TSF)和油包裹体萃取液全息扫描荧光(iTSF)等系列技术,已广泛应用于现今油层(含残留油层)和古油层识别、油气成藏历史恢复、油气运移路径追踪以及原油性质测定等.与其他岩矿和有机地化方法相比,储层定量荧光技术具有快速、低成本、分辨率高和易操作等优势.详细介绍了储层定量荧光技术的原理、处理流程、参数意义及其在油气成藏研究中的具体应用实例:(1) 利用QGF和QGF-E技术可有效识别古油层和残留油层,重建油气藏演化历史;(2) 利用QGF-E技术可有效识别测井资料难以识别的致密油层,指导致密油勘探开发;(3) TSF、iTSF、QGF+光谱参数与地化参数之间有一定的内在联系,可以用来检测原油、储层萃取烃和烃类包裹体的地化特征,建立烃类包裹体之间及与原油的联系.还指出了储层定量荧光技术在应用中需要注意的问题以及在其他方面的应用前景.      

Isotope and geochemical parameters of hydrocarbon gases in bottom sediments of the shelf of the East Siberian Sea

The research results on gas geochemistry of hydrocarbon gases in bottom sediments of the East Siberian Sea are presented. The key isotope and geochemical parameters of syn- and epigenetic hydrocarbon gases are determined. The correlations between the molecular masses of hydrocarbon fractions and the carbon isotope composition on hydrocarbon gases of various origin are revealed.     

Reservoir geochemistry of the Tazhong oilfield in the Tarim Basin, China, Part I. Geochemical characteristics and genetic classification of crude oils

1 Introduction Since the 1990’s of the 20th century, oil & gas geochemists have shifted their research focus on hydrocarbon source rocks in the past to that on reservoir rocks and oil reservoirs at present; their research field has been expanded from oil & gas exploration to the assessment of oil reservoirs and production & management. Therefore, reservoir geochemistry as a branch disciplinary of organic geochemistry is now attracting great concern of many oil & gas explorers and oilfield en…     

Study of the biodegradation levels of oils from the Orinoco Oil Belt (Junin area) using different biodegradation scales

This work presents a study of the molecular composition of the saturated and aromatic hydrocarbon fractions of crude oils from the Orinoco Oil Belt (Junín area) in the Eastern Venezuelan Basin, with the purpose of classifying these samples following two distinct biodegradation assessment schemes: the PM scale [Peters, K.E., Moldowan, J.M., 1993. The Biomarker Guide: Interpreting Molecular Fossils in Petroleum and Ancient Sediments. Prentice Hall, Englewood Cliffs, New Jersey, p. 363] and the Manco scale [Larter, S., Huang, H., Adams, J., Bennett, B., Snowdon, L.R., 2012. A practical biodegradation scale for use in reservoir geochemical studies of biodegraded oils. Organic Geochemistry 45, 66–76]. Both scales agree on the presence of different levels of biodegradation for the analyzed oils, although they are based on different groups of compounds. The PM scale uses mainly compounds from the saturated hydrocarbon fractions (e.g., n-alkanes, acyclic isoprenoids, terpanes and steranes) as well as aromatic steroids. On the other hand, the Manco scale considers other compounds (e.g., alkyltoluenes, naphthalene, methylnaphthalene, phenanthrene, alkylphenanthrenes and methyldibenzothiophenes) not included in the PM biodegradation scale. Thus, the combined use of these two scales allows the determination of the level of biodegradation of both saturated and aromatic compound classes. Dibenzothiophene (DBT), which was not included for the Manco score determination, also shows variations in peak intensity when compared to C₄-alkylnaphthalenes, presumably associated with the process of biological alteration. The differences in the biodegradation levels observed in the present study may be attributed to variations in parameters that control biodegradation rates laterally across the study area or the existence of varying communities of microorganisms, among other possible factors.     

Study on the optimal development method for offshore buried hill fractured reservoirs

In order to understand the percolation mechanism and development regulation in offshore buried hill fractured reservoir, similarity criteria of physical simulation on water flooding in the fractured reservoirs were established by using similarity and flow theory. Based on the similarity theory and Warren–Root model, a large-scale (1 m?×?1 m?×?0.5 m) physical similarity model was built. By conducting the similar physical experiments, the behavior and mechanism of fluid flow in the reservoir in different development modes were studied, together with the optimal development program selected. The physical simulation results show that the stereoscopic staggered horizontal well pattern can give full play to the function of oil–water gravitational differentiation and reduce the rising rate of water cut. Flooding mechanisms vary from mode to mode: The sweep efficiency of cold water flooding is higher, whereas the oil displacement efficiency in the fracture and oil recovery in the matrix are lower in the affected area. The hot water flooding can improve the oil–water flow ratio of the mainstream line, reduce the seepage resistance, and improve the oil displacement efficiency in the fracture and the oil recovery of the matrix in the area. However, due to poor heat transfer efficiency, the difference of seepage resistance between the mainstream line and other regional increases results in decreased sweep efficiency. Surfactant flooding reduces oil–water interfacial tension and improves flooding efficiency in the area, yet degenerates oil recovery for the matrix.     

用储层岩石抽提物的饱和烃色谱指纹识别油气层

利用储层岩石抽提物的饱和烃色 质总离子图的指纹特征判识储层的流体（油、气）类型。油层或油饱和的储层,饱和烃色 质总离子流图的特征是正构烷烃碳数分布宽,碳数分布在C₁₅～C₃₈之间,与原油样品的正构烷烃碳数分布相似;凝析气层的正构烷烃碳数分布略窄一些,碳数分布在C₁₅～C₃₅之间,低碳数（小于C₂₁）的正构烷烃相对于油层富集,高碳数（大于C₂₁）的正构烷烃丰度明显低于油层;干气层的正构烷烃碳数分布最窄,碳数分布在C₁₅～ C₂₈之间,只有低碳数的正构烷烃,高碳数的正构烷烃丰度极低。据此可用来识别油层、凝析气层和干气层,也可用于一些测井资料不全或测井质量差的老井的油气层复查、测井难以识别的火成岩油气层的识别,还可用于地层评价,为油气酸化层位的优选提供科学依据。     

层序地层地球化学及其在油气勘探中的作用

层序地层地球化学主要研究基于层序地层格架下的烃源层空间分布特征和源岩有机质的地球化学性质随层序、体系域的变化规律。以大民屯凹陷为实例的研究结果表明,层序地层地球化学研究在油气勘探中具有4个方面的主要作用:(1)预测未钻井或未取心地区烃源层空间分布特征和源岩有机质地球化学性质;(2)通过细化烃源岩评价单元,提高资源量计算中烃源岩体积估算和有机质性质评价的精度;(3)为基于层序地层格架的油气成藏系统研究提供“油气源”和“资源量”的要素;(4)可以作为盆地沉积充填分析的线索,并对已建立的层序地层格架进行检验和校正。层序地层地球化学研究不仅对中国东部老油田隐蔽油气藏的勘探工作具有重要的意义,对勘探程度低、钻井少、源岩取心少的西部含油气盆地中的烃源岩评价工作更为有效。     

Geochemical Characteristics of Crude Oils from Zao-V Oil Measures in Shenjiapu Oilfield

The geochemical characteristics of crude oils from Zao-V oil measures in the Shen-jiapu oilfield are systematically described in terms of the fractional composition of crude oils, GC characteristics of saturated hydrocarbon fraction of crude oils and the characteristics of their bio-markers. The deposifional environment, type and evolution of the biological source are also discussed. All pieces of evidence such as low saturated hydrocarbon fraction, high resin and asphalt, high isoprenoid alkane, weak odd-carbon number predominance ( CPI ranging from 1.23 to 1,29, OEP ranging from 1.14 to 1.16) and low sterane and terpane maturity parameters show these crude oils are immature oils. Low Pr/Ph ratios (0.66 -0.88) and high gammacer-ante/C31 hopane ratios ( 0.59 - 0.86 ) indicate the source rocks were formed in a slightly saline to brackish reducing lake depositional environment. Gas chromatographic characteristics of the saturated hydrocarbon fraction and the predominance of C30 hopane in terpane series and C29 sterane in sterane series indicate the biological source of the crude oils is composed mainly of bacterial and algal organic matter, and some algae are perhaps the main contributor of organic matter to the source rocks.     

致密油油藏空气泡沫调驱机理实验

以长庆某致密油井区取心样品、注入水与地层水、优选的空气泡沫体系等为基础,利用一维长岩心驱替实验装置开展了致密油储层基质与裂缝岩心分别注入纯泡沫液、空气与空气泡沫的注入能力实验,揭示在实际储层条件下,空气泡沫体系无法直接进入致密油基质岩心,但由于泡沫剂受到储层吸附,消泡后的纯泡沫液与气体可以顺利注入致密油基质岩心实现稳定驱替。设计并开展了基质渗透率级差为10、基质与裂缝双重发育的三管并联岩心驱替实验,明确了空气泡沫封堵裂缝调驱机理。泡沫流体主要进入裂缝岩心并有效封堵裂缝,部分泡沫消泡后形成的泡沫液与空气进入并驱替基质中的剩余油,最终空气泡沫驱残余油饱和度比水驱降低了21.12%,驱油效率提高了32.89%,改善水驱后开发效果明显;为避免暴性水淹的低效阶段,应在含水90%以前尽早转入空气泡沫驱,提高采油速度与经济效益。     

Field-ionization mass spectrometry: application to geochemical analysis

The thiourea adduct, thiourea non-adduct and aromatic fractions from a series of Alberta oil sand bitumens have been subjected to field ionization mass spectrometric analyses. Field ionization mass spectra feature little fragmentation and the molecular weight distributions of compounds in the fractions are readily obtained. Using this method, the various acyclic and cyclic saturated hydrocarbons and the hydrocarbon and thiophenic aromatic materials may be distinguished by compound type and number of carbon atoms. The effect of biodegradation on crude oils is illustrated in the results from the series of oil sand bitumens and their asphaltene pyrolysis products. Field ionization mass spectrometry is potentially an important new analytical tool in organic geochemistry.     

碱/聚合物驱油藏剩余油饱和度定量监测技术研究

碱／聚合物二元复合驱是一种大幅度提高老油田采收率的三次采油方法．室内研究、试验表明，可比水驱提高采收率10％～18％左右．通过开展玻璃钢套管完井技术研究、玻璃钢套管测井方法研究和厚油层细分技术研究，在碱／聚合物二元复合驱先导实验区建立玻璃钢套管井时间推移感应测井和时间推移C／O测井系统，定量监测碱／聚合物二／C复合驱注入过程中剩余油饱和度的变化，通过8年的矿场试验，成功建立了剩余油饱和度定量研究的动态监测预测系统，同时，测井资料表明，碱／聚合物二元复合驱有效提高了波及体积和驱油效率．     

塔里木盆地北部塔河油田原油分子地球化学特征及成因类型划分

GC、GC-MS、GC-MS-MS分析表明,塔河17区块各油藏原油饱和烃、芳烃生物标志物组成和稳定碳同位素特征具有同源性,即塔河原油来自相同的烃源灶（或烃源层）。然而,对原油物性特征、成熟度特征、生物降解特征及原油馏分碳同位素组成等的深入研究发现,塔河原油属于早、晚两次充注成藏:早期充注为一般成熟型原油,相当于Ro值0.70%0.80%成熟阶段的生排烃产物,遭受生物降解后具有重、稠油特征,主要分布在4、6、7区下奥陶统储层中;晚期成藏原油相当于Ro值0.80%1.00%的高成熟阶段的生烃产物,表现为正常油、甚至轻质油或凝析油,在塔河油田广泛分布,并可以与早期充注油藏原油的生物降解残留成分进行充分混合,呈现复杂的地球化学特征。      

川东北飞仙关组储层固体沥青地球化学特征及其气源指示意义

运用有机岩石学、有机地球化学、催化加氢热解、GC—IRMS等方法和技术,深入研究了川东北飞仙关组储层固体沥青及可能烃源岩的地球化学特征。研究认为,飞仙关组储层固体沥青反射率高,双反射明显,为非均质结构储层焦沥青;在碳酸盐岩储层的各种孔隙中,呈脉状、球粒状、角片状或块状等他形充填,具有中间相结构和镶嵌状结构特征,反映其高温热变质成因;元素组成有S/C高、H/C低的特点,其固体碳同位素组成与长兴组烃源岩干酪根相似。储层固体沥青的可能烃源岩发育于还原—弱氧化咸水沉积环境,有机质来源于水生藻类;氯仿沥青“A”饱和烃甾萜类生物标志物对比表明,上二叠长兴组烃源岩是主要来源,飞仙关组、下志留统烃源岩亦有贡献;催化加氢产物饱和烃及其正构烷烃单体碳同位素组成显示,坡2井飞仙关组储层固体沥青与罐5井飞仙关组烃源岩具有明显的亲缘关系,这也可作为飞仙关组海槽相烃源岩对飞仙关组气藏有贡献的佐证。     

聚驱后油藏剩余油分布数值模拟

通常聚合物驱的最终采收率在50%左右,聚合物驱后剩余油具有相当的开采潜力。以大庆长垣北部多段多韵律聚驱主力油藏为例,采用化学驱油藏数值模拟技术,系统研究并总结了典型油藏聚驱后平面及纵向剩余油的分布特征。结果表明,聚驱后油藏剩余油的分布系统可划分为2大成因、3大区域和7个部位。其中:存在受地质因素制约的剩余油,如废弃河道中部、砂体尖灭区、相对孤立的薄差砂体;也有开发因素控制的剩余油,如厚油层顶部剩余油、注采不完善部位、注入井间与生产井附近以及聚驱后高渗层内的残余油。聚合物驱后油藏剩余油主要富集于3大区域内,究其原因则主要源于水驱和后续聚驱波及程度的不同。     

鄂尔多斯盆地董志——正宁地区原油地球化学特征与成因

鄂尔多斯盆地董志—正宁地区是该盆地中生界油气勘探新区,对该地区原油的地球化学进行研究,了解原油的成因,可以为该地区石油勘探和开发提供科学依据。本研究首次对采集于董志—正宁地区原油和鄂尔多斯盆地烃源岩的烃类生物标志化合物进行了系统的分析,研究了它们的地球化学特征。原油中各类烃类生物标志化合物分布和组成特征指示了原油形成于...     

古流体研究的无机地球化学方法综述

研究与成藏过程相关的古流体活动有助于深入认识油气成藏过程,从经济目的出发预测储层质量,精确分析不同阶段古流体活动对油气成藏的影响具有重要意义。目前国内外石油地质学家主要利用同位素地球化学、元素地球化学、流体包裹体分析等无机地球化学方法分析古流体活动特征及其对油气成藏的影响。在归纳前人研究成果的基础上,总结了各种无机地球化学方法的最新研究进展,认为同位素地球化学方法有助于分析古流体来源与成因,元素地球化学方法可示踪烃类流体的运移,流体包裹体分析技术结合岩相学研究可分析油气运移的时间、期次、相态、通道和油气藏的富集规律,并指出油气运移和聚集的有利方向。在运用无机地球化学方法研究古流体活动时不应局限于单一方法,综合利用多种无机地球化学方法更有利于全面分析古流体活动特征。     

查干凹陷下白垩统稠油地球化学特征及成因分析

通过对稠油进行常规物性、碳同位素和有机地球化学分析,系统阐述了查干凹陷稠油地化特征及其形成的主控因素。查干凹陷存在原生和次生两类稠油,原生稠油非烃含量高于饱和烃含量,原油族组分富集轻碳同位素,C₂₉规则甾烷系列中以ααα构型为主,αββ构型甾烷含量低,没有重排甾烷。三环萜/五环萜值低,伽马蜡烷含量高,姥植比值低,其成烃母质沉积于高盐还原环境,多种地化参数表明原生稠油是巴音戈壁组烃源岩低熟演化阶段排烃的产物。次生稠油为油气运聚成藏之后,由于后期保存条件改变并经历次生改造作用形成的高密度、高黏度和低凝固点的原油。次生稠油埋深一般小于1200 m,主要为生物降解油,其中部分属于多期混源稠油。次生稠油正构烷烃损失严重,类异戊二烯烃不同程度遭受侵蚀,甾萜烷分布完整,表征原油达到中等降解程度。研究表明,原油稠化是多种稠化因素共同作用的结果,生物降解作用是研究区稠油形成的主要机制,查干凹陷后期的构造抬升为原油稠化提供了必要条件,活跃的水介质条件为浅层喜氧微生物活动提供了良好的氧化环境和营养物质。     

朝长地区原油中的有机含氮化合物及其应用

松辽盆地朝长地区 (朝阳沟—长春岭 )原油中含有丰富的吡咯类含氮化合物 ,其地球化学特征明显。与烃类化合物类似 ,非烃中吡咯类化合物可用于反映原油的成因类型。朝长地区原油中吡咯类化合物的分布特征及其运移效应为油气注入模型理论提供了很好的例证 ,表明吡咯类等非烃化合物在油藏地球化学理论与应用研究中具有广泛的前景。