High-resolution seismic imaging of crooked two-dimensional profiles in greenstone belts of the Canadian shield: results from the Swayze area,Ontario, Canada

In 2017, the Metal Earth multi-disciplinary exploration project acquired a total of 921 km of regional deep seismic reflection profiles and 184 km of high-resolution seismic reflection profiles in the Abitibi and Wabigoon greenstone belts of the Superior province of Canada. The Abitibi belt hosts several world-class mineral deposits, whereas the Wabigoon has sparse economic mineral deposits. Two high-resolution surveys in the Swayze area, a poorly endowed part of the western Abitibi greenstone belt, served as pioneer surveys with which to better understand subsurface geology and design a strategy to process other surveys in the near future. Swayze seismic data were acquired with crooked survey geometries along roads. Designing an effective seismic processing flow to address these geometries and complex geology required straight common midpoint lines along which both two-dimensional prestack dip-moveout correction and poststack migration processing were applied. The resulting seismic sections revealed steeply dipping and subhorizontal reflections; some correlate with folded surface rocks. An interpreted fault/deformation zone imaged in Swayze north would be a target for metal endowment if it extends the Porcupine–Destor structure. Because of the crooked line geometry of the surveys, two-dimensional /three-dimensional prestack time migration and swath three-dimensional processing were tested. The prestack time migration algorithm confirmed reflections at the interpreted base of the Abitibi greenstone belt. The swath three-dimensional images provided additional spatial details about the geometries of some reflections, but also had less resolution and did not detect many reflectors observed in two dimensions. Geological contacts between felsic, mafic and ultramafic greenstone rock layers are thought the main cause of reflectivity in the Swayze area.     

浙江大桥坞铀矿床铅、氢、氧同位素研究

浙江大桥坞矿床是赣杭火山岩铀成矿带重要的铀矿床之一。本文通过对大桥坞铀矿床铅、氢和氧同位素及前人资料的综合研究,探讨了矿床成矿流体和成矿物质来源。结果表明花岗斑岩、凝灰岩、辉绿岩、矿石中黄铁矿、蚀变围岩中黄铁矿的Ph同位素组成变化较小,可能指示它们具有相似的源区。在铅同位素构造环境判别图解中,铅同位素投影点分布范围较广,但多数集中于地幔和造山带演化线之间,偏向造山带,反映了铅的来源与岩浆活动有关。氢、氧同位素组成显示,成矿流体主要来自大气降水。成矿物质来源于壳幔混合源。     

Rock coast inheritance: an example from Galicia,northwestern Spain

A shore platform on the western coast of Galicia in northwestern Spain has been inherited from interglacial stages when sea level was similar to today. The wide, gently sloping intertidal platform is backed in places by supratidal rock ledges, and in other places by a steeper and narrower supratidal ramp. The gradient of the intertidal platform is consistent with the relationship between platform gradient and tidal range, but the slope of the ramp is much too high. The abandoned and degraded sea cliff is grass-covered along most of this coast, and the ledges and the ramp, which extend up to several metres above the highest tides, are covered by lichen and, in places, by salt-tolerant plants. Radiocarbon-dated sediments in the cliff, which range up to 36 000 years in age, lie on top of an ancient beach deposit. The former beach, remnants of which are found in situ on the ramp and rock ledges, as well as two caves that are filled with the dated sediments, are probably last interglacial in age. The morphological and sedimentary evidence suggests that the supratidal ramp and ledges were also formed during the last interglacial stage, whereas the wider intertidal platform is probably the product of several older interglacials, when sea level was generally similar to today. A general model is proposed for the inheritance of shore platforms in macro- and microtidal environments. Copyright © 1999 John Wiley & Sons, Ltd.     

Dynamic Stress Drop of Recent Earthquakes: Variations within Subduction Zones

—Stress drop is a fundamental parameter of earthquakes, but it is difficult to obtain reliable stress drop estimates for most earthquakes. Static stress drop estimates require knowledge of the seismic moment and fault area. Dynamic stress drop estimates are based entirely upon the observed source time functions. Based on analytical formulas that I derive for the crack and slip-pulse rupture models, the amplitude and time of the initial peak in source time functions can be inverted for dynamic stress drop. For multiple event earthquakes, this method only gives the dynamic stress drop of the first event. The Michigan STF catalog provides a uniform data base for all large earthquakes that have occurred in the past four years. Dynamic stress drops are calculated for the nearly 200 events in this catalog, and the resultant estimates scatter between 0.1 and 100 MPa. There is some coherent tectonic signal within this scatter. In the Sanriku (Japan) and Mexico subduction zones, underthrusting earthquakes that occur at the up-dip and down-dip edges of the seismogenic zone have correspondingly low and high values of stress drop. A speculative picture of the stress state of subduction zones emerges from these results. A previous study found that the absolute value of shear stress linearly increases down the seismogenic interface to a value of about 50 MPa at the down-dip edge. In this study, the dynamic stress drop of earthquakes at the up-dip edge is about 0.2 MPa, while large earthquakes at the down-dip edge of the seismogenic plate interface have dynamic stress drops of up to 5 MPa. These results imply that (1) large earthquakes only reduce the shear stress on the plate interface by a small fraction of the absolute level; and thus (2) most of the earthquake energy is partitioned into friction at the plate interface.     

Source and distribution of lead in the surface sediments from the South China Sea as derived from Pb isotopes

Rapid economic development in East Asian countries has inevitably resulted in environmental degradation in the surrounding seas, and concern for the environment and its protection against pollutants is increasing. Identification of sources of contaminants and evaluation of current environmental status are essential to environmental pollution management, but relatively little has been done in the South China Sea (SCS). In order to investigate the abundance, distribution, and sources of Pb within the SCS, stable Pb isotopes and their ratios were employed to assess the contamination status and to differentiate between natural and anthropogenic origins of Pb in the surface sediments. The total Pb concentrations in sediments varied from 4.18 to 58.7 mg kg⁻¹, with an average concentration of 23.6 ± 8.9 mg kg⁻¹. The observed Pb isotope ratios varied from 18.039 to 19.211 for ²⁰⁶Pb/²⁰⁴Pb, 15.228 to 16.080 for ²⁰⁷Pb/²⁰⁴Pb, 37.786 to 39.951 for ²⁰⁸Pb/²⁰⁴Pb, 1.176 to 1.235 for ²⁰⁶Pb/²⁰⁷Pb, and 2.468 to 2.521 for ²⁰⁸Pb/²⁰⁷Pb. The majority of these ratios are similar to those reported for natural detrital materials. Combined with Pb enrichment factor values, our results show that Pb found within most of the SCS sediments was mainly derived from natural sources, and that there was not significant Pb pollution from anthropogenic sources before 1998. Further studies are needed to reconstruct deposition history and for trend analysis.     

The origin of Samoa: new evidence from Sr, Nd, and Pb isotopes

We report Sr, Nd and Pb isotope ratios and parent and daughter element concentrations in 34 volcanic rocks from Samoa. The highly undersaturated post-erosional volcanics, which have erupted in Recent to Historic time along a 250-km-long fissure, have isotopic compositions that define fields distinct from those of the tholeiitic to alkalic lavas of the older Samoan shield volcanoes. Most shield lavas have²⁰⁶Pb/²⁰⁴Pb of 18.9–19.4,⁸⁷Sr/⁸⁶Sr of 0.7045–0.7055 and⁸⁷Sr/⁸⁶Sr (to 0.7075). In general, isotopic compositions of the shield lavas are similar to those of the Marquesas and Society Islands. Post-erosional samples have lower²⁰⁶Pb/²⁰⁴Pb and¹⁴³Nd/¹⁴⁴Nd and higher⁸⁷Sr/⁸⁶Sr than most shield lavas. The most striking feature of the post-erosional data is a negative correlation between²⁰⁷Pb/²⁰⁴Pb and²⁰⁶Pb/²⁰⁴Pb. This suggests that post-erosional lavas are derived from mixtures of the shield source and a high-²⁰⁷Pb/²⁰⁴Pb,⁸⁷Sr/⁸⁶Sr, low-²⁰⁶Pb/²⁰⁴Pb and¹⁴³Nd/¹⁴⁴Nd post-erosional source which may contain recycled ancient sediment. This enriched mantle domain may also underlie the Ontong-Java and Manihiki Plateaus to the north and west. Although both the Samoan shield and post-erosional lavas show chemical characteristics often associated with mantle plumes, only the shield volcanism can plausibly be related to a plume. The post-erosional eruptions appear to be the result of flexure and rifting due to plate bending at the northern termination of the Tonga Trench.     

Harmonization check of M w within the central, northern, and northwestern European earthquake catalogue (CENEC)

Large data sets covering large areas and time spans and composed of many different independent sources raise the question of the obtained degree of harmonization. The present study is an analysis of the harmonization with respect to the moment magnitude M _w within the earthquake catalogue for central, northern, and northwestern Europe (CENEC). The CENEC earthquake catalogue (Grünthal et al., J Seismol, 2009) contains parameters for over 8,000 events in the time period 1000–2004 with magnitude M _w ≥ 3.5. Only about 2% of the data used for CENEC have original M _w magnitudes derived directly from digital data. Some of the local catalogues and data files providing data give M _w, but calculated by the respective agency from other magnitude measures or intensity. About 60% of the local data give strength measures other than M _w, and these have to be transformed by us using available formulae or new regressions based on original M _w data. Although all events are thus unified to M _w magnitude, inhomogeneity in the M _w obtained from over 40 local catalogues and data files and 50 special studies is inevitable. Two different approaches have been followed to investigate the compatibility of the different M _w sets throughout CENEC. The first harmonization check is performed using M _w from moment tensor solutions from SMTS and Pondrelli et al. (Phys Earth Planet Inter 130:71–101, 2002; Phys Earth Planet Inter 164:90–112, 2007). The method to derive the SMTS is described, e.g., by Braunmiller et al. (Tectonophysics 356:5–22, 2002) and Bernardi et al. (Geophys J Int 157:703–716, 2004), and the data are available in greater extent since 1997. One check is made against the M _w given in national catalogues and another against the M _w derived by applying different empirical relations developed for CENEC. The second harmonization check concerns the vast majority of data in CENEC related to earthquakes prior to 1997 or where no moment tensor based M _w exists. In this case, an empirical relation for the M _w dependence on epicentral intensity (I ₀) and focal depth (h) was derived for 41 master events, i.e., earthquakes, located all over central Europe, with high-quality data. To include also the data lacking h, the corresponding depth-independent relation for these 41 events was also derived. These equations are compared with the different sets of data from which CENEC has been composed, and the goodness of fit is demonstrated for each set. The vast majority of the events are very well or reasonably consistent with the respective relation so that the data can be said to be harmonized with respect to M _w, but there are exceptions, which are discussed in detail.     

High-resolution estimates of lithospheric thickness from Missouri to Massachusetts, USA

This paper presents a new three-dimensional (3-D) model, NA00, of the S-velocity of the upper mantle beneath North America. The model differs from its predecessor NA95 in that it exploits seismograms recorded by a recent dense, broadband array, MOMA, and from independent measurements of North American crustal thickness. Model NA00 is derived by fitting the waveforms of broadband seismic S and surface waves recorded by the MOMA array and inverting them together with the database of waveform fits used for NA95 and the crustal thickness estimates. It is demonstrated that including data from the dense, broadband MOMA array yields a resolving power beneath the array that is of unprecedented quality and relatively constant over a large depth range. This improved resolution provides a unique opportunity for quantifying the structure of the upper mantle in and below the lower, thick Precambrian lithosphere. The high-resolution seismic structure of the imaged high-velocity lithosphere is compared with the thermal structure (estimated from heat flow), compositional structure (estimated from xenoliths and electrical conductivity) and the elastic structure (estimated from gravity and topography). There is a remarkable agreement between the seismic, thermal, and compositional estimates. The seismic lithosphere is 180 km thick below Missouri and Illinois, 200 km thick below Indiana, Ohio and Pennsylvania, practically undefined below New York, and 80 km below Massachusetts and the Atlantic continental shelf. The thick lithosphere is underlain by a layer with lower S-velocities that could represent a relatively low-viscosity channel. However, the S-velocities in this layer are much higher than those of typical oceanic asthenosphere.     

复合火山构造的高分辨率岸上地震成像:意大利武尔卡诺岛例子

火山口地下构造详细的地震成像对于增进这些高危险火山的构造和火山学的知识是必不可少的。然而,在火山地带,尤其是在岸上,很难获得高质量的地震数据。我们报道了拉福萨火山口(意大利武尔卡诺岛)西部地区的高分辨率地震剖面结果。利用高分辨率的振动源及交替采集和处理技术,我们能够克服由火山煤岩类型带来的大多数困难。本研究提供了火山堆积的地下分布和一些重要内部喷火山口构造的识别。我们确定了埋于拉福萨火山口下面的寄生火山口或玄武碎屑岩丘的位置,它在约1km的深度记录到地震的地方正在消散CO2。此外,在剖面最南部发现的变形模式与穹隆侵入后破火山口塌陷是一致的。结果表明,使用高分辨率振动源结合交替地震采集技术和非常规处理方法,可以帮助恢复火山地区浅层构造的详细信息。     

Geochemistry and isotopes of fluids from sulphur springs, Valles Caldera, New Mexico

Detailed geochemistry supported by geologic mapping has been used to investigate Sulphur Springs, an acid-sulfate hot spring system that issues from the western flank of the resurgent dome inside Valles Caldera. The most intense activity occurs at the intersection of faults offsetting caldera-fill deposits and post-caldera rhyolites. Three geothermal wells in the area have encountered pressures <1 MPa and temperatures of 200°C at depths of 600 to 1000 m. Hot spring and fumarole fluids may discharge at boiling temperatures with pH 1.0 and SO₄ 8000 mg/l. These conditions cause argillic alterations throughout a large area.Non-condensible gases consist of roughly 99% CO₂ with minor amounts of H₂S, H₂, and CH₄. Empirical gas geothermometry suggests a deep reservoir temperature of 215 to 280°C. Comparison of ¹³C and ¹⁸O between CaCO₃ from well cuttings and CO₂ from fumarole steam indicates a fractionation temperature between 200 and 300°C by decarbonation of hydrothermally altered Paleozoic limestone and vein calcite in the reservoir rocks. Tritium concentrations obtained from steam condensed in a mudpot and deep reservoir fluids (Baca #13, 278°C) are 2.1 and 1.0 T.U. respectively, suggesting the steam originates from a reservoir whose water is mostly >50 yrs old. Deuterium contents of fumarole steam, deep reservoir fluid, and local meteoric water are practically identical even though ¹⁸O contents range through 4‰, thus, precipitation on the resurgent dome of the caldera could recharge the hydrothermal system by slow percolation. From analysis of D and ¹⁸O values between fumarol steam and deep reservoir fluid, steam reaches the surface either (1) by vaporizing relatively shallow groundwater at 200°C or (2) by means of a two-stage boiling process through an intermediate level reservoir at roughly 200°C.Although many characteristics of known vapor-dominated geothermal systems are found at Sulphur Springs, fundamental differences exist in temperature and pressure of our postulated vapor-zone. We propose that the reservoir beneath Sulphur Springs is too small or too poorly confined to sustain a “true” vapor-dominated system and that the Sulphur Springs system may be a “dying” vapor-dominated system that has practically boiled itself dry.     

Rotational overthrusting of the northwestern Himalaya: further palaeomagnetic evidence from the Riasi thrust sheet, Jammu foothills, India

Thermal demagnetization results (316 samples) are presented for the Tertiary succession of the Riasi thrust sheet (Jammu foothills, northwestern Himalaya). Primary and secondary magnetization directions of Murree Group red beds (Miocene to Upper Eocene) sampled northeast of Jammu indicate, for this part of the Riasi thrust sheet, a clockwise rotation over about 45° with respect to the Indian shield since Late Eocene/Early Miocene time. This accords with clockwise rotations of similar magnitude observed in the Panjal Nappe and the Krol Belt, and is interpreted as representative for the northwestern Himalaya. Results from the western part of the Kalakot inlier, sampled northwest of Jammu, i.e. basal Murree claystone (Middle Eocene) and carbonate from the Subathu Group (lower Middle to Lower Eocene), indicate an aberrant 20–25° counterclockwise rotation which is of local importance only. Available observations on rotation of Himalayan thrust sheets with respect to the Indian shield, indicate that the Himalayan Arc has formed through oroclinal bending. This supports Powell and Conaghan's and Veevers et al.'s model of Greater India with large-scale intracontinental underthrusting along the Main Central Thrust beneath the Tibetan Plateau. Minimal magnitudes of underthrusting of 550 km in the Krol Belt and 650 km in the Thakkhola region are concluded. Palaeolatitude observations (herein and in [1[) agree with absolute positioning of the Indian plate based on India-Africa relative movement data fixed to a hotspot frame in the Atlantic Ocean, and with palaeolatitude observations from DSDP cores on the Indian plate. Collision-related secondary magnetic components observed both to the north and to the south of the Indus-Tsangpo Suture zone show palaeolatitudes between the equator and 7°N. Comparison of both datasets indicates that initial contact between Greater India and south-central Asia had been established in the Hindu Kush—Karakorum region by about 60 Ma ago whereas eastwards progressive suturing had advanced to the Lhasa Block segment of the Indus-Tsangpo Suture zone before 50 Ma ago.     

Timing of the terrestrial Permian-Triassic boundary biotic crisis: Implications from U-Pb dating of authigenic zircons

The Late Permian to Early Triassic transition represents one of the most important Phanerozoic mass extinction episodes. The cause of this event is still in debate between catastrophic and gradual mechanisms. This study uses the U-Pb method on zircons from the uppermost Permian/lowermost Triassic clay deposits at Chahe (Guizhou Province, SW China) to examine time constraints for this event. The results of both this and previous studies show that the ages of Bed 68a and 68c (the upper clay bed of the terrestrial Permian-Triassic boundary (PTB)) respectively are 252.6±2.8 and 247.5±2.8 Ma. This age (within the margin of error) almost accords with the upper clay bed (Bed 28) age of Meishan and the eruption age of Tunguss Basalt, and is so far the most accurate age obtained from terrestrial PTB. The claystone of Bed 68 was formed in the earliest Triassic. The biotic crisis occurred at nearly the same time in terrestrial and marine environments during Permian-Triassic interval; however the extinction patterns and processes are different. The extinction pattern of the terrestrial plants shows a major decline at the PTB after long-term evolution, followed by a retarded extinction of the relicts in the earliest Triassic.     

In-situ trace element analyses and Pb-Pb dating of zircons in granulite from Huangtuling, Dabieshan by LAM-ICP-MS

Zircon is an accessory mineral occurring in many types of rocks. For the rich content of U and low content of common Pb, it is the principal mineral used for U-Th-Pb dating. It can be sur-vived during weathering, transiting, high-grade metamorphism and ev…     

Further U-Pb dates on zircons from the early Precambrian rocks of the Godthaabsfjord area,West Greenland

U-Pb analyses of zircons from the Godthaabsfjord area in West Greenland yield dates of 2530 ± 30 m.y. for the Qo?rqut granite, 2820 ± 50 m.y. for the Nu?k gneiss, 2600–2900 m.y. for Malene-type supracrustal rocks, and >3800 m.y. for Isua supracrustal rocks. The zircon data are in accord with the stratigraphic sequence except for the Malene supracrustal zircons, which appear to have been variably affected by later metamorphism that did not reset the Nu?k or Amîtsoq zircons in the same area.     

Carbon isotopes,sulfur isotopes,and trace elements of the dolomites from the Dengying Formation in Zhenba area,southern Shaanxi: Implications for shallow water redox conditions during the terminal Ediacaran

Carbon isotope, sulfur isotope, and trace element(including Rare Earth Elements, REE) analyses were conducted on the carbonates of the Dengying Formation at Lianghekou section in southern Shaanxi to reconstruct the terminal Ediacaran shallow-water environment on the northwestern margin of the Yangtze Platform. At Lianghekou section, samples in the middle 50-m of the Beiwan Member show characteristics of low ΣREE concentrations, no MREE-enriched REE distribution patterns, high Ce/Ce* values close to 1, and enriched redox-sensitive elements, whereas samples in the lower 30-m and upper 10-m show opposite characteristics of high ∑REE concentrations, MREE-enriched REE distribution patterns, low Ce/Ce* values around 0.6, and no redox-sensitive elements enriched, indicating that oxygenation did occur in the shallow water on the northwestern margin of the Yangtze Platform and redox conditions of the shallow water fluctuated from relatively oxygenated to anoxic and then back to oxygenated again. We propose that the anoxia appeared in middle of the Beiwan time may associate with the anoxic upwelled water. On one hand, abundant nutrients were brought in by this upwelling event, which stimulated the photosynthetic carbon fixation and increased the organic carbon burial under this anoxic condition, causing a peak of 3.6‰ in δ 13 C. On the other hand, because the anoxic upwelled water replaced the oxic shallow water, together with the increasing organic matter in the water column, bacterial sulfate reduction was enhanced and therefore quickly reduced the sulfate concentration, which eventually caused δ 34 S increasing to 50‰. However, as the upwelling gradually disappeared, δ 13 C and δ 34 SCAS values decreased as well in the late Beiwan time, indicating the shallow water went back to suboxic or oxic again.     

Origins of groundwater inferred from isotopic patterns of the Badain Jaran Desert, northwestern China

There are many viewpoints about the sources of groundwater in the Badain Jaran Desert (BJD), such as precipitation and snowmelt from the Qilian Mountains (the upper reaches [UR] of the Heihe River Basin [HRB]) and precipitation from the BJD and the Yabulai Mountains. To understand the source of the groundwater of the BJD and their possible associations with nearby bodies of water, we analyzed variations of stable isotope ratios (δD and δ(18) O) and the deuterium excess (d-excess) of groundwater and precipitation in the BJD, of groundwater, precipitation, river and spring water in the UR, and of groundwater and river water in the middle and lower reaches (MR and LR) of the HRB. In addition, the climatic condition under which the groundwater was formed in the BJD was also discussed. We found obvious differences in δD, δ(18) O, and d-excess among groundwater in the BJD, nearby water bodies and the HRB. The groundwater δD-δ(18) O equation for the BJD was δD = 4.509δ(18) O-30.620, with a slope and intercept similar to that of nearby areas (4.856 and -29.574), indicating a strong evaporation effect in the BJD and its surrounding areas. The equation's slope of the BJD was significantly lower than those of HRB groundwater (6.634), HRB river water (6.202), precipitation in the BJD and Youqi (7.841), and the UR of the HRB (7.839). The d-excess (-17.5‰) of the BJD was significantly lower than those of nearby groundwater (-7.4‰), HRB groundwater (12.1‰), precipitation in the BJD (5.7‰) and in the UR of the HRB (15.2‰), and HRB river water (14.4‰). The spatial patterns of δ(18) O and d-excess values in the BJD suggest mixing and exchange of groundwater between the BJD and neighboring regions, but no hydraulic relationship between the BJD groundwater and water from more distant regions except Outer Mongolia, which is north of the BJD. Moreover, we conclude that there is little precipitation recharge to groundwater because of the obvious d-excess difference between groundwater and local precipitation, low precipitation, and high evaporation rates. The abnormally negative d-excess values in groundwater of the BJD indicate that this water was formed in the past under higher relative humidity and lower temperatures than modern values.     

SHRIMP U–Pb ages of zircons from the Lengshuikeng ore field,North Wuyi Mountains,South China: Implications for dating volcaniclastic rocks

The Lengshuikeng Ag‐Pb‐Zn ore field is located in the North Wuyi Mesozoic volcanic belt south of the Qinzhou–Hangzhou suture zone between the Yangtze and Cathaysia paleo‐plates. Previous zircon U–Pb geochronological studies on ignimbrites and tuffs from this area have yielded conflicting ages of 157–161 Ma (Early Upper Jurassic) and 137–144 Ma (Early Lower Cretaceous). Volcanic rocks in the ore field have even been proposed to include both ages. Our SHRIMP zircon U–Pb dating of the ignimbrite and tuff samples from the ore field, along with field observations and results from geochronological work on other volcanic and sub‐volcanic rocks in the region, shows that two populations of magmatic zircons, one autocrystic and the other xenocrystic, are present in the pyroclastic rocks. The autocrystic zircons have ages suggesting formation/eruption at approximately 140 Ma, whereas the xenocrystic zircons give ages of 155–159 Ma, indicating intrusion of granitic porphyries in the Early Upper Jurassic. Therefore, the pyroclastic rocks in the Lengshuikeng Ag–Pb–Zn ore field formed in the Early Lower Cretaceous. The youngest zircon U–Pb ages from pyroclastic rocks may not represent the formation/eruption ages of the host rock, depending most likely on the existence and/or abundance of juvenile or vitric pyroclasts in the rocks.     

Turkey Lakes Watershed,Ontario, Canada: 40 years of interdisciplinary whole-ecosystem research

The Turkey Lakes Watershed (TLW) study is a federal, interdepartmental study established in 1979 to investigate the effects of acid rain on terrestrial and aquatic ecosystems. The 10.5 km² watershed, located in the Eastern Temperate Mixed Forest on the Canadian Shield, has been the site of multidisciplinary studies on biogeochemical and ecological processes conducted across plot to catchment scales. The whole-ecosystem investigative approach was adopted from the outset and has allowed research to evolve from its original (and continuing) acidification focus to include investigations on the effects of climate change, forest harvesting and other forest ecosystem perturbations. The extensive scientific and support infrastructure allows for collection of a comprehensive data record essential for understanding long-term environmental trends. Data include atmospheric deposition, meteorology, stream hydrology and chemistry, soil, pore and ground water properties, understory and overstory vegetation, lake and outflow physical and chemical properties, and aquatic macroinvertebrate and fish community composition and abundance. These data have contributed to over 400 published research papers and graduate theses. The watershed has also figured prominently in many continent-wide comparisons advancing fundamental watershed theory. The knowledge gained at TLW has influenced pollutant emission and natural resource management policies provincially, nationally and internationally.     

Single-grain optically stimulated luminescence dating of quartz temper from prehistoric Intermountain Ware ceramics,northwestern Wyoming,USA

This study applies single-grain optically stimulated luminescence (SG OSL) dating of quartz sand temper to Intermountain Ware ceramics recovered from four archaeological sites in northwestern Wyoming, USA. We show that SG OSL dating can strengthen and further refines existing archaeological site chronologies in certain settings. The SG OSL results are compared to multi-grain infrared stimulated luminescence (IRSL) dating of the polymineral (feldspar and quartz) silt fraction in the ceramic paste of the same sherds. Results from the two methods are statistically indistinguishable, although coarse-grained quartz SG OSL ages have consistently lower standard error terms due to higher relative sensitivity and avoidance of anomalous fading calculations. Moreover, the SG OSL results produced precision at two-sigma standard error greater than or equal to associated calibrated radiocarbon ages. SG OSL dating of quartz temper from Intermountain Ware ceramics provides more reliable site occupation timing than radiocarbon dating, which can be conditioned by incorporation of old wood and contamination from young soil carbon. This study highlights the importance of SG OSL dating on sherds from buried contexts when exposure to wildfires may have occurred, as ceramics recovered from the ground surface of one site after a high-intensity fire produced near-modern apparent ages, suggesting they were thermally reset during the fire. We suggest SG OSL should be applied to date similar ceramics with quartz temper to determine site age and bolster regional chronologies.     

Translocation and distribution of mercury in biomasses from subtropical forest ecosystems: evidence from stable mercury isotopes

To understand its source,distribution,storage,and translocation in the subtropical forest ecosystems,mercury(Hg) concentrations and stable isotopes in forest biomass tissues(foliage,branch,bark,and trunk) were investigated at Ailao Mountain National Nature Reserve,Southwest China.The total Hg(THg) concentrations in the samples show the following trend:mature foliage(57 ± 19 ng g~(-1)) bark(11 ± 4.0 ng g~(-1)) branch(5.4 ± 2.5 ng g~(-1)) trunk(1.6 ± 0.7 ng g~(-1)).Using the measured THg concentrations and the quantity of respective biomasses,the Hg pools in the forest are:wood(60 ± 26 μg m~(-2)) bark(51 ± 18 μg m~(-2)) foliage(41 ± 11 μg m~(-2)) branch(26 ± 8.3 μg m~(-2)).The tree biomasses displayed negative δ~(202)Hg(-1.83‰ to-3.84‰) and Δ~(199)Hg(-0.18‰ to-0.62‰).The observed Δ~(200)Hg(-0.08‰ to 0.04‰) is not significantly from zero.A Δ~(199)Hg/Δ~(201)Hg ratio of 1.05 was found in tree biomasses,suggesting that mercury has undergone Hg~((Ⅱ)) photoreduction processes.A Hg-isotope based binary mixing model suggests that Hg in the tree biomasses mainly originated from foliage uptake of atmospheric Hg~0,constituting 67%,80%,and 77% of Hg in wood,branch,and bark,respectively.Our study sheds new light on the transportation and sources of Hg in the subtropical forest ecosystems.