Episodic Cenozoic volcanism and tectonism in the Andes of Peru

Radiometric and geologic information indicate a complex history of Cenozoic volcanism and tectonism in the central Andes. K-Ar ages on silicic pyroclastic rocks demonstrate major volcanic activity in central and southern Peru, northern Chile, and adjacent areas during the Early and Middle Miocene, and provide additional evidence for volcanism during the Late Eocene. A provisional outline of tectonic and volcanic events in the Peruvian Andes during the Cenozoic includes: one or more pulses of igneous activity and intense deformation during the Paleocene and Eocene; a period of quiescence, lasting most of Oligocene time; reinception of tectonism and volcanism at the beginning of the Miocene; and a major pulse of deformation in the Middle Miocene accompanied and followed through the Pliocene by intense volcanism and plutonism. Reinception of igneous activity and tectonism at about the Oligocene-Miocene boundary, a feature recognized in other circum-Pacific regions, may reflect an increase in the rate of rotation of the Pacific plate relative to fixed or quasifixed mantle coordinates. Middle Miocene tectonism and latest Tertiary volcanism correlates with and probably is genetically related to the beginning of very rapid spreading at the East Pacific Rise.     

2.8-Ma ash-flow caldera at Chegem River in the northern Caucasus Mountains (Russia), contemporaneous granites, and associated ore deposits

Diverse latest Pliocene volcanic and plutonic rocks in the north-central Caucasus Mountains of southern Russia are newly interpreted as components of a large caldera system that erupted a compositionally zoned rhyolite-dacite ash-flow sheet at 2.83 ± 0.02 Ma (sanidine and biotite ⁴⁰Ar/³⁹Ar). Despite its location within a cratonic collision zone, the Chegem system is structurally and petrologically similar to typical calderas of continental-margin volcanic arcs. Erosional remnants of the outflow Chegem Tuff sheet extend at least 50 km north from the source caldera in the upper Chegem River. These outflow remnants were previously interpreted by others as erupted from several local vents, but petrologic similarities indicate a common origin and correlation with thick intracaldera Chegem Tuff. The 11 × 15 km caldera and associated intrusions are superbly exposed over a vertical range of 2,300 m in deep canyons above treeline (elev. to 3,800 m). Densely welded intracaldera Chegem Tuff, previously described by others as a rhyolite lava plateau, forms a single cooling unit, is > 2 km thick, and contains large slide blocks from the caldera walls. Caldera subsidence was accommodated along several concentric ring fractures. No prevolcanic floor is exposed within the central core of the caldera. The caldera-filling tuff is overlain by andesitic lavas and cut by a 2.84 ± 0.03-Ma porphyritic granodiorite intrusion that has a cooling age analytically indistinguishable from that of the tuffs. The Eldjurta Granite, a pluton exposed low in the next large canyon (Baksan River) 10 km to the northwest of the caldera, yields variable K-feldspar and biotite ages (2.8 to 1.0 Ma) through a 5-km vertical range in surface and drill-hole samples. These variable dates appear to record a prolonged complex cooling history within upper parts of another caldera-related pluton. Major W-Mo ore deposits at the Tirniauz mine are hosted in skarns and hornfels along the roof of the Eldjurta Granite, and associated aplitic phases have textural features of Climax-type molybdenite porphyries in the western USA. Similar ⁴⁰Ar/³⁹Ar ages, mineral chemistry, and bulk-rock compositions indicate that the Chegem Tuff, intracaldera intrusion, and Eldjurta Granite are all parts of a large magmatic system that broadly resembles the middle Tertiary Questa caldera system and associated Mo deposits in northern New Mexico, USA. Because of their young age and superb three-dimensional exposures, rocks of the Chegem-Tirniauz region offer exceptional opportunities for detailed study of caldera structures, compositional gradients in volcanic rocks relative to cogenetic granites, and the thermal and fluid-flow history of a large young upper-crustal magmatic system.     

Geology of the peralkaline volcano at Pantelleria,Strait of Sicily

Situated in a submerged continental rift, Pantelleria is a volcanic island with a subaerial eruptive history longer than 300 Ka. Its eruptive behavior, edifice morphologies, and complex, multiunit geologic history are representative of strongly peralkaline centers. It is dominated by the 6-km-wide Cinque Denti caldera, which formed ca. 45 Ka ago during eruption of the Green Tuff, a strongly rheomorphic unit zoned from pantellerite to trachyte and consisting of falls, surges, and pyroclastic flows. Soon after collapse, trachyte lava flows from an intracaldera central vent built a broad cone that compensated isostatically for the volume of the caldera and nearly filled it. Progressive chemical evolution of the chamber between 45 and 18 Ka ago is recorded in the increasing peralkalinity of the youngest lava of the intracaldera trachyte cone and the few lavas erupted northwest of the caldera. Beginning about 18 Ka ago, inflation of the chamber opened old ring fractures and new radial fractures, along which recently differentiated pantellerite constructed more than 25 pumice cones and shields. Continued uplift raised the northwest half of the intracaldera trachyte cone 275 m, creating the island's present summit, Montagna Grande, by trapdoor uplift. Pantellerite erupted along the trapdoor faults and their hingeline, forming numerous pumice cones and agglutinate sheets as well as five lava domes. Degassing and drawdown of the upper pantelleritic part of a compositionally and thermally stratified magma chamber during this 18-3-Ka episode led to entrainment of subjacent, crystal-rich, pantelleritic trachyte magma as crenulate inclusions. Progressive mixing between host and inclusions resulted in a secular decrease in the degree of evolution of the 0.82 km³ of magma erupted during the episode.The 45-Ka-old caldera is nested within the La Vecchia caldera, which is thought to have formed around 114 Ka ago. This older caldera was filled by three widespread welded units erupted 106, 94, and 79 Ka ago. Reactivation of the ring fracture ca. 67 Ka ago is indicated by venting of a large pantellerite centero and a chain of small shields along the ring fault. For each of the two nested calderas, the onset of postcaldera ring-fracture volcanism coincides with a low stand of sea level.Rates of chemical regeneration within the chamber are rapid, the 3% crystallization/Ka of the post-Green Tuff period being typical. Highly evolved pantellerites are rare, however, because intervals between major eruptions (averaging 13–6 Ka during the last 190 Ka) are short. Benmoreites and mugearites are entirely lacking. Fe-Ti-rich alkalic basalts have erupted peripherally along NW-trending lineaments parallel to the enclosing rift but not within the nested calderas, suggesting that felsic magma persists beneath them. The most recent basaltic eruption (in 1891) took place 4 km northwest of Pantelleria, manifesting the long-term northwestward migration of the volcanic focus. These strongly differentiated basalts reflect low-pressure fractional crystallization of partial melts of garnet peridotite that coalesce in small magma reservoirs replenished only infrequently in this continental rift environment.     

Identification of the source caldera for the Middle Miocene ash-flow tuffs in the Kii Peninsula based on apatite trace-element composition

A large caldera cluster consisting of at least four calderas (Omine, Odai, Kumano-North and Kumano calderas) existed in the central–southern part of the Kii Peninsula approximately 14–15 Ma. On the other hand, thick Middle Miocene ash-flow tuffs, referred to as the Muro Ash-flow Tuff and the Sekibutsu Tuff Member, are distributed in the northern part of the Kii Peninsula. Although these tuffs are considered to have erupted from the caldera cluster in the central-southern Kii Peninsula, identifying the source caldera in the cluster has been controversial because of similarities in the petrological characteristics and identical radiometric ages of the volcaniclastic rocks of these calderas. We successfully discriminated the characteristics of the eruptive products of each caldera in the caldera cluster based on the apatite trace-element compositions of the pyroclastic dikes and ash-flow tuffs of the calderas. We also demonstrated that the source caldera of at least the lower main part of the Muro Ash-flow Tuff and the Sekibutsu Tuff Member was the Odai Caldera, which is located in the central Kii Peninsula. Our findings show possible correlations among the pyroclastic conduits and ash-flow tuffs of the caldera-fill and/or outflow deposits, even in cases where they have been densely welded and diagenetically altered. This method is useful for the study of deeply eroded ancient calderas.     

Probability hazard map for future vent opening at the Campi Flegrei caldera,Italy

The Campi Flegrei caldera is a restless structure affected by general subsidence and ongoing resurgence of its central part. The persistent activity of the system and the explosive character of the volcanism lead to a very high volcanic hazard that, combined with intense urbanization, corresponds to a very high volcanic risk. One of the largest sources of uncertainty in volcanic hazard/risk assessment for Campi Flegrei is the spatial location of the future volcanic activity. This paper presents and discusses a long-term probability hazard map for vent opening in case of renewal of volcanism at the Campi Flegrei caldera, which shows the spatial conditional probability for the next vent opening, given that an eruption occurs. The map has been constructed by building a Bayesian inference scheme merging prior information and past data. The method allows both aleatory and epistemic uncertainties to be evaluated. The probability map of vent opening shows that two areas of relatively high probability are present within the active portion of the caldera, with a probability approximately doubled with respect to the rest of the caldera. The map has an immediate use in evaluating the areas of the caldera prone to the highest volcanic hazard. Furthermore, it represents an important ingredient in addressing the more general problem of quantitative volcanic hazards assessment at the Campi Flegrei caldera.     

Relationships between mineralization and silicic volcanism in the Central Andes

Studies of late Tertiary silicic volcanic centres in the Western and Eastern Cordilleras of the Central Andes show that three volcanic environments are appropriate sites for mineralization: (1) ring-fracture extrusions post-dating large calderas; (2) similar extrusions within ignimbrite shields; and (3) isolated, small silicic volcanoes. Subvolcanic tin mineralization in the Eastern Cordillera is located in silicic stocks and associated breccias of Miocene age. The Cerro Rico stock, Potosi, Bolivia, contains tin and silver mineralization and has an intrusion age apparently millions of years younger than that of the associated Kari Kari caldera. Similar age relationships between mineralization and caldera formation have been described from the San Juan province, Colorado. The vein deposits of Chocaya, southern Bolivia, were emplaced in the lower part of an ignimbrite shield, a type of volcanic edifice as yet unrecognized in comparable areas of silicic volcanism. The El Salvador porphyry copper deposit, Chile, is related to silicic stocks which may have been intruded along a caldera ring fracture. Cerro Bonete, Chile, provides a modern example of the volcanic superstructure which may have overlain isolated mineralized stocks and breccia pipes such as that of Salvadora at Llallagua, Bolivia.Existing models for the genesis of porphyry copper deposits suggest that they formed in granodioritic stocks located in the infrastructure of andesitic stratovolcanoes. Sites of porphyry-type subvolcanic tin mineralization in the Eastern Cordillera of Bolivia are distinguished by the absence of such andesitic structures. The surface expression of a typical subvolcanic porphyry tin deposit was probably an extrusive dome of quartz latite porphyry, sometimes related to a larger caldera structure. Evidence from the El Salvador porphyry copper deposit in the Eocene magmatic belt in Chile suggests that it too may be more closely related to a silicic volcanic structure than to an andesitic stratovolcano.The dome of La Soufriere, Guadeloupe is proposed as a modern analog for the surface expression of subvolcanic mineralization processes, the phreatic eruptions there suggesting the formation of hydrothermal breccia bodies in depth. Occurrence of mineralized porphyries, millions of years after caldera formation, does not necessarily indicate that intrusions and mineralization are not genetically related to the sub-caldera pluton, but may be a consequence of the long thermal histories (1–10 million years) of the lowermost parts of large plutons. Caldera formation can only inhibit mineralization by dispersal of ore metals when these are of magmatic origin, and ignimbrites should not be taken as being unlikely to be associated with porphyry mineralization. Whether ore metals are of wall rock or magmatic origin, the key to understanding the relationships between silicic volcanism and mineralization lies in the fractionation of trace elements within large zoned magma chambers during their igneous history, and their subsequent hydrothermal migration. Small, highly mineralized intrusions formed late in a caldera cycle (such as the Cerro Rico) may be due to the introduction of fresh supplies of mafic magma into the lower parts of the main pluton.     

K-Ar geochronology of the late cenozoic volcanic rocks of the Cordillera Occidental, southernmost Peru

Twenty-four K-Ar radiometric ages are presented for late Cenozoic continental volcanic rocks of the Cordillera Occidental of southernmost Perú (lat. 16° 57′–17° 36′S). Rhyodacitic ignimbrite eruptions began in this transect during the Late Oligocene and continued episodically through the Miocene. The development of andesitic-dacitic strato volcanoes was initiated in the Pliocene and continues to the present.The earliest ignimbrite flows (25.3–22.7 Ma) are intercalated in the upper, coarsely-elastic member of the Moquegua Formation and demonstrate that this sedimentary unit accumulated in a trough, parallel to Andean tectonic trends, largely in the Oligocene. More voluminous ash-flow eruptions prevailed in the Early Miocene (22.8–17.6 Ma) and formed the extensively preserved Huaylillas Formation. This episode was coeval with a major phase of Andean uplift, and the pyroclastics overlie an erosional surface of regional extent incised into a Paleogene volcano-plutonic arc terrain. An age span of 14.2–8.9 Ma (mid-Late Miocene) is indicated for the younger Chuntacala Formation, which again comprises felsic ignimbrite flows, largely restricted to valleys incised into the pre-Huaylillas Formation lithologies, and, at lower altitudes, an extensive aggradational elastic facies. The youngest areally extensive ignimbrites, constituting the Sencca Formation, were extruded during the Late Miocene.In the earliest Pliocene, the ignimbrites were succeeded by more voluminous calcalkaline, intermediate flows which generated numerous large and small stratovolcanoes; these range in age from 5.3 to 1.6 Ma. Present-day, or Holocene, volcanism is restricted to several large stratovolcanoes which had begun their development during the Pleistocene (by 0.7 Ma).The late Oligocene/Early Miocene (ca. 22–23 Ma) reactivation of the volcanic arc coincided with a comparable increase in magmatic activity throughout much of the Cordilleras Occidental and Oriental of the Central Andes.     

Geochronology of Gran Canaria,Canary Islands: Age of shield building volcanism and other magmatic phases

Forty-six new K-Ar age determinations are presented on whole rock samples and mineral separates from volcanic and subvolcanic rocks of Gran Canaria. The main subaerial shield building basaltic volcanism with estimated volume of about 1000 km³ was confined to the interval about 13.7 m.y. to 13.5 m.y. ago in the middle Miocene. Substantial volume (～100 km³) of silicic volcanics (trachyte and peralkaline rhyolite) were erupted with no detectable time break following the basaltic volcanism, essentially contemporaneous with formation of a large collapse caldera at 13.4±0.3 m.y. ago. Trachytic to phonolitic volcanism continued intermittently in the waning states of activity until about 9 m.y. ago. Following a long hiatus there was resurgence of volcanism with eruption of about 100 km³ of basanitic to hauyne phonolitic rocks of the Roque Nublo Group between about 4.4 m.y. and 3.4 m.y. ago in the Pliocene. After a hiatus of less than 1.0 m.y., olivine nephelinite magmas were erupted and this activity continued intermittently until relatively recent times, the younger eruptives being mainly basanitic in composition. The volume of volcanic products in this phase probably does not exceed 10 km³. Thus the volume of all the resurgent volcanism comprises less than 10 percent of the subaerially exposed part of Gran Canaria. The results show that the subaerial main shield building phase of volcanism in Gran Canaria, consisting of mildly alkali to transitional basalts, occurred over a time interval that was less than 0.5 m.y. Magmatic evolution on Gran Canaria appears to be similar to that found on other basaltic volcanoes in oceanic regions. Thus volcanoes in the Hawaiian, Marquesas and Society Islands all were built by basaltic lavas in similar short-lived episodes of volcanism. In some Hawaiian volcanoes, a resurgent phase of volcanism of strongly undersaturated basalts of small volume is recognized following a long hiatus, again similar to that found on Gran Canaria. The relatively large volume of silicic lavas erupted in Gran Canaria immediately following the main basaltic shield building phase is, however, not matched in the Pacific volcanoes mentioned.     

Shishimuta caldera,the buried source of the Yabakei pyroclastic flow in the Hohi volcanic zone,Japan

Drill-hole, geochronologic, and gravity data identify the buried Shishimuta caldera beneath post-caldera lava domes and lacustrine deposits in the center of the Hohi volcanic zone. The caldera is the source of the Yabakei pyroclastic flow, which erupted 1.0 Ma ago with a bulk volume of 110 km³. The caldera is a breccia-filled funnel-shaped depression 8 km wide and > 3 km deep with a V-shaped negative Bouguer gravity anomaly up to 36 mgal. Neither ring vents nor resurgence was recognized; instead, post-caldera monogenetic volcanism in an extensional setting dominated the area. The andesitic breccia has a relatively low density and fills the caldera; it possibly formed by fragmentation of disrupted roof rock during the violent Yabakei eruption and related collapse. Fewer normal faults and shallow microearthquakes occur inside the caldera than around it, possibly because rocks beneath the caldera are structurally incoherent. A profile of Shishimuta caldera may be more elongated vertically, and have a more intensely fractured zone, than that of a Valles-type caldera.     

La Pacana caldera and the Atana Ignimbrite — a major ash-flow and resurgent caldera complex in the Andes of northern Chile

The recently discovered La Pacana caldera, 60 × 35 km, is the largest caldera yet described in South America. This resurgent caldera of Pliocene age developed in a continental platemargin environment in a major province of ignimbrite volcanism in the Central Andes of northern Chile at about 23° S latitude. Collapse of La Pacana caldera was initiated by the eruption of about 900 km³ of the rhyodacitic Atana Ignimbrite. The Atana Ignimbrite was erupted from a composite ring fracture system and formed at least four major ash-flow tuff units that are separated locally by thin air-fall and surge deposits; all four sheets were emplaced in rapid succession about 4.1 ± 0.4 Ma ago. Caldera collapse was followed closely by resurgent doming of the caldera floor, accompanied by early postcaldera eruptions of dacitic to rhyolitic lava domes along the ring fractures. The resurgent dome is an elongated, asymmetrical uplift, 48.5 × 12 km, which is broken by a complex system of normal faults locally forming a narrow discontinuous apical graben. Later, postcaldera eruptions produced large andesitic and dacitic stratocones along the caldera margins and dacitic domes on the resurgent dome beginning about 3.5 Ma ago and persisting into the Quaternary. Hydrothermally altered rocks occur in the eroded cores of precaldera and postcaldera stratovolcanoes and along fractures in the resurgent dome, but no ore deposits are known. A few warm springs located in salars within the caldera moat appear to be vestiges of the caldera geothermal system.     

New evidence on the hydrothermal system in Long Valley caldera, California, from wells, fluid sampling, electrical geophysics, and age determinations of hot-spring deposits

Data collected since 1985 from test drilling, fluid sampling, and geologic and geophysical investigations provide a clearer definition of the hydrothermal system in Long Valley caldera than was previously available. This information confirms the existence of high-temperature (> 200°C) reservoirs within the volcanic fill in parts of the west moat. These reservoirs contain fluids which are chemically similar to thermal fluids encountered in the central and eastern parts of the caldera. The roots of the present-day hydrothermal system (the source reservoir, principal zones of upflow, and the magmatic heat source) most likely occur within metamorphic basement rocks beneath the western part of the caldera. Geothermometer-temperature estimates for the source reservoir range from 214 to 248°C. Zones of upflow of hot water could exist beneath the plateau of moat rhyolite located west of the resurgent dome or beneath Mammoth Mountain. Lateral flow of thermal water away from such upflow zones through reservoirs in the Bishop Tuff and early rhyolite accounts for temperature reversals encountered in most existing wells. Dating of hot-spring deposits from active and inactive thermal areas confirms previous interpretations of the evolution of hydrothermal activity that suggest two periods of extensive hot-spring discharge, one peaking about 300 ka and another extending from about 40 ka to the present. The onset of hydrothermal activity around 40 ka coincides with the initiation of rhyolitic volcanism along the Mono-Inyo Craters volcanic chain that extends beneath the caldera's west moat.     

Age of the Taishu Group,southwestern Japan,and implications for the origin and evolution of the Japan Sea

The Taishu Group, a marine formation with a thickness of >5400 m, crops out on Tsushima Island, located in the southwestern Japan Sea. The group, which is generally regarded as early Eocene to early Miocene in age, provides important information about the tectonic setting of the Japan Sea. In this study, we present new SHRIMP U–Pb dates for igneous zircons from the Kunehama Tuff, which is in the basal part of the Taishu Group, and the Oobaura Tuff, which is in the uppermost part of the group. Results show that the Taishu Group was deposited rapidly, during the short interval of 17.9–15.9 Ma (early–middle Miocene), and is equivalent to other early–middle Miocene strata found in the Japan Sea region. Our results provide new constraints on the geological history of the Japan Sea and its islands.     

The geology and geophysics of the ambrym caldera,New Hebrides

Ambrym Island has an unusually large, well-preserved basaltic caldera 13 km across. The caldera occurs in the central region of an early broad composite cone, which formed a north-south line with three smailer volcanoes. Alter the caldera was formed volcanism occurred within it and along fissure lines running nearly east-west. Two volcanic cones are active almost continuously and historic fissure cruptions have been recorded. The caldera formed by quiet subsidence, or by subsidence accompanied by eruption of scoria lappili similar to that erupted prior and subsequent to caldera formation. The collapse was at least 600 metres and radiocarbon dating suggests it took place less than 2000 years ago. The caldera is detined by gravity anomalies 10 to 14 milligals lower than those at its rim suggesting predominantly ash infilling. Aeromagnetic anomalies show a prominent. nearly east-west lineation, with normally magnetised bipole anomalies over the centre of the caldera and over fissure lines east of it. The source of the present volcanic activity is believed to be located along dyke fissures, with a perched magma chamber beneath the caldera. The geophysical evidence on Ambrym, together with that of regional east trending magnetic anomalies and recent bathymetric results, suggests that the volcanic activity is localised by the intersection of an east-west fracture zone with the axis of the New Hebrides island are.     

Chronology of cenozoic igneous and tectonic events in the central Chilean Andes — latitudes 35° 30′ to 36°S

Sixty-six K---Ar dates from igneous rocks in the central Chilean Andes between 33° and 38°S are reported in this study. From these results and observed field relations, major Cenozoic volcanic and intrusive rock units are divided into chronologic groups representing igneous events.Volcanic units of Oligocene (33.3–27.9 m.y.) and Early Miocene (20.2 m.y.) age have been dated west of the present range at 33°S but neither the magnitude nor extent of these volcanic events has yet been established. Extensive Middle to Late Miocene volcanism (15.3–6.4 m.y.) followed by regional folding is recognized in the map area between 35° 20′ and 36°S. Partly contemporaneous Middle Miocene volcanism (18.4–13.7 m.y.) also followed by regional folding is recorded in the Andes between 37° 30′ and 38°S. General volcanic quiescence from 6.4 to 2.5 m.y. is observed in the map area but whether this volcanic hiatus is of regional significance is not known.The majority of the K---Ar dates document a history of nearly continuous volcanism throughout the last 2.5 m.y. in the map area. The abundant and diverse sequences of volcanic strata formed during this time, have been divided into four successive age groups which as map units show the evolution and distribution of latest volcanic activity.Landforms preserved by this volcanic series show that topographic relief similar to the present has prevailed during this time. Deep incision of rivers into young volcanic terrain, estimated to be on the order of 1–2 m/1000 years, has produced a complex volcanic and morphologic record.Four plutons dated in this study give ages of 62.0, 41.3, 19.5, and 7.0 m.y. No spatial pattern of emplacement is observed in the map area where three of these plutons are represented.Similarities in structural style, orientation and degree of deformation of Miocene and Mesozoic strata suggest that Late Miocene regional folding may have accounted for a significant part of the observed deformation in older basement strata previously ascribed to earlier orogenies.A regional comparison of ages of recognized igneous and tectonic event at different latitudes in the central and southern Andes shows the gross chronology of Cenozoic events which can be correlated with sea-floor spreading and subduction events.     

Apoyo caldera, Nicaragua: A major quaternary silicic eruptive center

Apoyo caldera, near Granada, Nicaragua, was formed by two phases of collapse following explosive eruptions of dacite pumice about 23,000 yr B.P. The caldera sits atop an older volcanic center consisting of lava flows, domes, and ignimbrite (ash-flow tuff). The earliest lavas erupted were compositionally homogeneous basalt flows, which were later intruded by small andesite and dacite flows along a well defined set of N—S-trending regional faults. Collapse of the roof of the magma chamber occurred along near-vertical ring faults during two widely separated eruptions. Field evidence suggests that the climactic eruption sequence opened with a powerful plinian blast, followed by eruption column collapse, which generated a complex sequence of pyroclastic surge and ignimbrite deposits and initiated caldera collapse. A period of quiescence was marked by the eruption of scoria-bearing tuff from the nearby Masaya caldera and the development of a soil horizon. Violent plinian eruptions then resumed from a vent located within the caldera. A second phase of caldera collapse followed, accompanied by the effusion of late-stage andesitic lavas, indicating the presence of an underlying zoned magma chamber. Detailed isopach and isopleth maps of the plinian deposits indicate moderate to great column heights and muzzle velocities compared to other eruptions of similar volume. Mapping of the Apoyo airfall and ignimbrite deposits gives a volume of 17.2 km³ within the 1-mm isopach. Crystal concentration studies show that the true erupted volume was 30.5 km³ (10.7 km³ Dense Rock Equivalent), approximately the volume necessary to fill the caldera. A vent area located in the northeast quadrant of the present caldera lake is deduced for all the silicic pyroclastic eruptions. This vent area is controlled by N—S-trending precaldera faults related to left-lateral motion along the adjacent volcanic segment break. Fractional crystallization of calc-alkaline basaltic magma was the primary differentiation process which led to the intermediate to silicic products erupted at Apoyo. Prior to caldera collapse, highly atypical tholeiitic magmas resembling low-K, high-Ca oceanic ridge basalts were erupted along tension faults peripheral to the magma chamber. The injection of tholeiitic magmas may have contributed to the paroxysmal caldera-forming eruptions.     

Geologic evolution of the Donguinyó-Huichapan caldera complex,central Mexican Volcanic Belt,Mexico

The Donguinyó-Huichapan caldera complex is located 110 km to the NNW of Mexico City, in the central sector of the Mexican Volcanic Belt. It is a 10 km in diameter complex apparently with two overlapping calderas, each one related to an ignimbrite sequence that contrasts in composition, mineralogy, welding, distribution, and physical aspect. The geologic evolution of this complex includes the following phases, 1) A first caldera formed at 5.0 ± 0.3 Ma, with the eruption of several discrete pulses of andesitic to trachydacitic pyroclastic flows that produced a series of densely welded ignimbrites; 2) At 4.6 ± 0.3 Ma, several small shield volcanoes and cinder cones built the rim of this caldera and erupted basaltic-andesite and andesitic lava flows; 3) At 4.2 ± 0.2 Ma, a second caldera was formed associated to the eruption of the Huichapan Tuff, which is a rhyolitic pyroclastic sequence consisting of minor unwelded ignimbrites, pumice fall and surge deposits, and a voluminous welded ignimbrite; 4) Also yielding an age of 4.2 ± 0.2 Ma, several trachydacitic lava domes were extruded along the new ring fracture and formed the rim of the Huichapan caldera, as well as five intra-caldera domes of dacitic and trachydacitic composition. Peripheral volcanism includes a large 2.5 ± 0.1 Ma shield volcano that was emplaced on the Huichapan caldera rim.The two calderas that form the Donguinyó-Huichapan complex have contrasting differences in volcanic styles that were apparently due to their differences in composition. Products erupted by the Donguinyó caldera are basaltic-andesite to trachydacitic in composition, whereas Huichapan caldera products are all high-silica rhyolites.     

Strontium isotope evidence for crustal contamination of calc-alkaline volcanic rocks from Cerro Galan,northwest Argentina

The Pampean Ranges of northwest Argentina are a basin-and-range tectonic province with a late Precambrian to Paleozoic basement and extensive Miocene-Recent calc-alkaline volcanism. The volcanoes include the large resurgent Cerro Galan caldera, and Recent scoria cones and lava flows. Miocene-Recent volcanic rocks of basalt to dacite composition from the Cerro Galan area exhibit a range of Rb/Sr ratios of 0.043–1.092 and initial⁸⁷Sr/⁸⁶Sr ratios of 0.7057–0.7115 with a clear positive correlation between⁸⁷Sr/⁸⁶Sr and⁸⁷Rb/⁸⁶Sr, indicating an apparent age of ca. 130 Ma. This relationship is interpreted to indicate that the Sr isotope variation in the Cerro Galan volcanic rocks results from mixing of a mantle-derived component with low⁸⁷Sr/⁸⁶Sr (<0.7057) and high Sr (>700 ppm) with a crustal component characterized by higher⁸⁷Sr/⁸⁶Sr (>0.7115) and lower Sr (<240 ppm). It is concluded that the mixing is best explained as a result of a small degree of selective crustal Sr contamination (ca. 10%) of a range of subsequently erupted magmas produced largely by fractional crystallization within the continental crust. We propose that the mantle-derived end-member is derived by partial melting of sub-Andean mantle with an⁸⁷Sr/⁸⁶Sr ratio of ca. 0.704, and that such an Sr isotope ratio characterizes the source region for calc-alkaline volcanic rocks throughout the Andes.     

Sources of two large ignimbrites in the central andes: Some landsat evidence

Sources of large-volume ignimbrites in the Central Andes are difficult to identify by conventional means. MSS band 7 LANDSAT imagery of the region was obtained with the specific objective of using the synoptic view to identify large ignimbrites and their sources. Two are described. The Guataquina ignimbrite covers some 2300 km² and probably has a volume of some 70 km³. It appears to have a source in Cerro Guacha, a complex caldera-graben structure 25 km across. The Cerro Galan ignimbrite covers an area of some 2000 km' on the flanks of a major resurgent caldera some 30 km by 20 km across. Younger volcanic rocks have been erupted from two points on the caldera wall, and the structure appears to have had a geological history broadly similar to that of the Valles caldera.     

Petrogenesis and tectonic setting of bimodal volcanism in the Sakoli Mobile Belt, Central Indian shield

The Sakoli Mobile Belt comprises bimodal volcanic rocks that include metabasalt, rhyolite, tuffs, and epiclastic rocks with metapelites, quartzite, arkose, conglomerate, and banded iron formation (BIF). Mafic volcanic rocks are tholeiitic to quartz‐tholeiitic with normative quartz and hypersthene. SiO₂ shows a large compositional gap between the basic and acidic volcanics, depicting their bimodal nature. Both the volcanics have distinct geochemical trends but display some similarity in terms of enriched light rare earth element–large ion lithophile element characteristics with positive anomalies for U, Pb, and Th and distinct negative anomalies for Nb, P, and Ti. These characteristics are typical of continental rift volcanism. Both the volcanic rocks show strong negative Sr and Eu anomalies indicating fractionation of plagioclases and K‐feldspars, respectively. The high Fe/Mg ratios for the basic rocks indicate their evolved nature. Whole rock Sm–Nd isochrons for the acidic volcanic rocks indicate an age of crystallization for these volcanic rocks at about 1675 ± 180 Ma (initial ¹⁴³Nd/¹⁴⁴Nd = 0.51017 ± 0.00017, mean square weighted deviate [MSWD] = 1.6). The εNd_t (t = 2000 Ma) varies between ?0.19 and +2.22 for the basic volcanic rock and between ?2.85 and ?4.29 for the acidic volcanic rocks. Depleted mantle model ages vary from 2000 to 2275 Ma for the basic and from 2426 to 2777 Ma for the acidic volcanic rocks, respectively. These model ages indicate that protoliths for the acidic volcanic rocks probably had a much longer crustal residence time. Predominantly basaltic magma erupted during the deposition of the Dhabetekri Formation and part of it pooled at crustal or shallower subcrustal levels that probably triggered partial melting to generate the acidic magma. The influence of basic magma on the genesis of acidic magma is indicated by the higher Ni and Cr abundance at the observed silica levels of the acidic magma. A subsequent pulse of basic magma, which became crustally contaminated, erupted as minor component along with the dominantly acidic volcanics during the deposition of the Bhiwapur Formation.