North American microtektites from the Caribbean Sea and their fission track age

Over 6000 microscopic glass spherules between 125 μm and 1 mm in diameter were found in a sediment core (RC9-58) from the Caribbean Sea. These glassy objects are mostly confined to a zone ～ 40 cm thick at a depth of ～ 250 cm. We believe that the microscopic glass objects are microtektites belonging to the North American strewnfield, based on their geographical location, appearance, physical properties, stratigraphic age (middle Upper Eocene), fission track age (～34.6 my) and major element compositions. The occurrence of North American microtektites in the Caribbean Sea indicates that the North American strewnfield is two to three times larger than previously indicated. An estimate on the abundance of microtektites in core RC9-58 indicates that the North American strewnfield may contain greater than 10¹⁷ g of tektite material.     

Trapped solar and cosmogenic noble gas abundances in Apollo 15 and 16 deep drill samples

Abundances and isotopic compositions of all the stable noble gases have been measured in 19 different depths of the Apollo 15 deep drill core, 7 different depths of the Apollo 16 deep drill core, and in several surface fines and breccias. All samples analyzed from both drill cores contain large concentrations of solar wind implanted gases, which demonstrates that even the deepest layers of both cores have experienced a lunar surface history. For the Apollo 15 core samples, trapped⁴He concentrations are constant to within a factor of two; elemental ratios show even greater similarities with mean values of⁴He/²²Ne= 683±44,²²Ne/³⁶Ar= 0.439±0.057,³⁶Ar/⁸⁴Kr= 1.60±0.11·10³, and⁸⁴Kr/¹³²Xe= 5.92±0.74. Apollo 16 core samples show distinctly lower⁴He contents,⁴He/²²Ne(567±74), and²²Ne/³⁶Ar(0.229±0.024), but their heavy-element ratios are essentially identical to Apollo 15 core samples. Apollo 16 surface fines also show lower values of⁴He/²²Ne and²²Ne/³⁶Ar. This phenomenon is attributed to greater fractionation during gas loss because of the higher plagioclase contents of Apollo 16 fines. Of these four elemental ratios as measured in both cores, only the²²Ne/³⁶Ar for the Apollo 15 core shows an apparent depth dependance. No unambiguous evidence was seen in these core materials of appreciable variations in the composition of the solar wind. Calculated concentrations of cosmic ray-produced²¹Ne,⁸⁰Kr, and¹²⁶Xe for the Apollo 15 core showed nearly flat (within a factor of two) depth profiles, but with smaller random concentration variations over depths of a few cm. These data are not consistent with a short-term core accretion model from non-irradiated regolith. The Apollo 15 core data are consistent with a combined accretion plus static time of a few hundred million years, and also indicate variable pre-accretion irradiation of core material. The lack of large variations in solar wind gas contents across core layers is also consistent with appreciable pre-accretion irradiation. Depth profiles of cosmogenic gases in the Apollo 16 core show considerably larger concentrations of cosmogenic gases below ～65 cm depth than above. This pattern may be interpreted either as an accretionary process, or by a more recent deposition of regolith to the upper ～70 cm of the core. Cosmogenic gas concentrations of several Apollo 16 fines and breccias are consistent with ages of North Ray Crater and South Ray Crater of ～50·10⁶ and ～2·10⁶ yr, respectively.     

Topographic correlations with soil and regolith thickness from shallow‐seismic refraction constraints across upland hillslopes in the Valles Caldera,New Mexico

How rock is weathered physically and chemically into transportable material is a fundamental question in critical‐zone science. In addition, the distribution of weathered material (soil and intact regolith) across upland landscapes exerts a first‐order control on the hydrology of watersheds. In this paper we present the results of six shallow seismic‐refraction surveys in the Redondo Mountain region of the Valles Caldera, New Mexico. The P‐wave velocities corresponding to soil (≤ 0.6 km s^?1) were inferred from a seventh seismic survey where soil‐thickness data were determined by pit excavation. Using multivariable regression, we quantified the relationships among slope gradient, aspect, and topographic wetness index (TWI) on soil and regolith (soil plus intact regolith) thicknesses. Our results show that both soil and regolith thicknesses vary inversely with TWI in all six survey areas while varying directly with slope aspect (i.e. thicker beneath north‐facing slopes) and inversely with slope gradient (i.e. thinner beneath steep slopes) in the majority of the survey areas. An empirical model based on power‐law relationships between regolith thickness and its correlative variables can fit our inferred thicknesses with R² ‐values up to 0.880 for soil and 0.831 for regolith in areas with significant topographic variations. These results further demonstrate the efficacy of shallow seismic refraction for mapping and determining how soil and regolith variations correlate with topography across upland landscapes. Copyright © 2016 John Wiley & Sons, Ltd.     

Provenance and thermal history of the Bayan Har Group in the western-central Songpan–Ganzi–Bayan Har terrane: Implications for tectonic evolution of the northern Tibetan Plateau

Triassic turbidites dominate the Songpan–Ganzi–Bayan Har (SGBH) terrane of the northern Tibetan Plateau. U‐Pb dating on single detrital zircon grains from the Triassic Bayan Har Group turbidites yield peaks at 400–500 m.y., 900–1000 m.y., 1800–1900 m.y., and 2400–2500 m.y., These results are consistent with recently published U‐Pb zircon ages of pre‐Triassic bedrock in the East Kunlun, Altyn, Qaidam, Qilian and Alaxa areas to the north, suggesting that provenance of the Bayan Har Group may include these rocks. The similarities in the compositions of the lithic arkosic sandstones of the Bayan Har Group with the sandstones of the Lower‐Middle Triassic formations in the East Kunlun terrane to the north also suggests a common northern provenance for both. A well exposed angular unconformity between the Carboniferous–Middle Permian mélange sequences and the overlying Upper Permian or Triassic strata indicates that regional deformation occurred between the Middle and Late Permian. This deformation may have been the result of a soft collision between the Qiangtang terrane and the North China Plate and the closure of the Paleo‐Tethyan oceanic basin. The Bayan Har Group turbidites were then deposited in a re‐opened marine basin on a shelf environment. Fission‐track dating of detrital zircons from the Bayan Har Group sandstones revealed pre‐ and post‐depositional age components, suggesting that the temperatures did not reach the temperatures necessary to anneal retentive zircon fission tracks (250–300°C). A 282–292 m.y. peak age defined by low U concentration, retentive zircons likely reflects a northern granitic source. Euhedral zircons from two lithic arkoses with abundant volcanic fragments in the southern area yielded a ～237 m.y. zircon fission track (ZFT) peak age, likely recording the maximum age of deposition. A dominant post‐depositional 170–185 m.y. ZFT peak age suggests peak temperatures were reached in the Early Jurassic. Some samples appear to record a younger thermal event at ～140 m.y., a short lived event that apparently affected only the least retentive zircons.     

Depth distribution of calcareous sediments in the Mesozoic and Cenozoic North Atlantic Ocean

The upper Mesozoic and Cenozoic distribution of calcareous, biogenic particles which are produced by planktonic foraminifers and nannoplankton and which are the most important components of pelagic sediments since mid-Mesozoic times, has been reconstructed using data from North Atlantic deep-sea drill sites. Two phases of sedimentation of carbonate-rich sediments are separated by an interval from 100 to 80 m.y. B.P. when CaCO₃ particles were diluted by chiefly terrigenous material. Prior to 100 m.y. B.P. the highest concentrations of calcareous matter were confined to the deepest part of the then 4–4.5 km deep North Atlantic. After 80 m.y. B.P. sediments with high concentrations of calcareous matter have been deposited above 3 km paleodepth, but during the last 25 m.y. also between 4 and 5.5 km paleo-water depth. The latter occurrence is associated with indications of downslope displacement of calcareous material into the abyssal plains of the deepest parts of the North Atlantic.     

Determination of electrical resistivity,its anisotropy and heterogeneity on drill cores: a new method1

This paper presents a new method for the measurement on core samples of their electrical resistivity, its anisotropy and heterogeneity. The equipment used has been developed in the field laboratory of the German Continental Deep Drilling program KTB in the north-east of Bavaria on the western rim of the Bohemian Massif. The apparatus measures the resistivity at a fixed frequency as a function of the drill core azimuth and along the core by moving point electrode configurations. From these azimuth and depth dependences, mean values of resistivity and additional information about its anisotropy and heterogeneity are determined. Geometrical averaging is used, because the resistivity data follows a log normal distribution. The quantitative parameters ‘azimuth factor’, corresponding to horizontal anisotropy, and ‘heterogeneity factor’ are introduced. The depth logs of resistivity, azimuth factor and heterogeneity factor, measured on cores obtained from the KTB main drill hole (gneisses and amphibolites) at depths between 4150 m and 8080 m are presented. The geometrically averaged mean values of resistivity of gneisses and amphibolites are in the same range (? 10³Ωm). The resistivities tend to decrease with depth. The stress release of the drill cores during recovery produces microcracks which may partially account for this effect. Reduced resistivities (down to 150 Ωm) within an amphibolite core correlate with an alteration zone. One sample of this core displays alteration from fresh to completely altered. This sample is also electrically heterogeneous (heterogeneity factor ? 2). Other samples with uniform low alteration are more homogeneous heterogeneity factor ? 1.4). In general, higher anisotropies are observed in gneisses (mean azimuth factor 2.8), lower anisotropies in amphibolites (mean azimuth factor 1.3). Examples of isotropic and homogeneous samples, as well as anisotropic and heterogeneous samples are also presented.     

合肥盆地构造热演化的裂变径迹证据

运用裂变径迹分析方法,探讨分析了合肥盆地中新生代的构造热演化特征. 上白垩统和古近系下段样品的磷灰石裂变径迹（AFT）数据主体表现为靠近部分退火带顶部温度(±65℃)有轻度退火,由此估算晚白垩世至古近纪早期合肥盆地断陷阶段的古地温梯度接近38℃/km,高于盆地现今地温梯度(275℃/km).下白垩统、侏罗系及二叠系样品的AFT年龄(975～25Ma)和锆石裂变径迹(ZFT)年龄(118～104Ma)均明显小于其相应的地层年龄,AFT年龄－深度分布呈现冷却型曲线形态,且由古部分退火带、冷却带或前完全退火带及其深部的今部分退火带组成,指示早白垩世的一次构造热事件和其随后的抬升冷却过程. 基于AFT曲线的温度分带模式和流体包裹体测温数据的综合约束,推算合肥盆地早白垩世走滑压陷阶段的古地温梯度接近67℃/km. 径迹年龄分布、AFT曲线拐点年龄和区域抬升剥蚀时间的对比分析结果表明,合肥盆地在早白垩世构造热事件之后的104Ma以来总体处于抬升冷却过程,后期快速抬升冷却事件主要发生在±55Ma.     

Ancient solar wind in lunar microbreccias

The Apollo 11 soil breccias are samplers of the ancient lunar environment due to their history in the regolith and their efficient closure to addition of recent solar wind upon compaction. These breccias contain the lowest¹⁵N/¹⁴N isotopic ratio yet reported for any lunar sample (in fact, for any natural sample). This extends the range of variation of¹⁵N/¹⁴N of the solar wind to greater than 30%, from a δ¹⁵N of ?190‰ in the past to +120‰ at present. No mechanism is yet known that is capable of accounting for such a large change in the¹⁵N/¹⁴N ratio without producing a substantial concomitant change in the¹³C/¹²C ratio, although some sort of nuclear reaction in the sun appears to be required. Apollo 11 soil breccias and 15086 are all formed by meteoritic impacts which compact the lower regolith against the basement rock without much heating. Rock 15086 formed from the layer of regolith between 100 and 200 cm depth, as shown by the close agreement between the nitrogen content and isotopic ratios of 15086 and those of the Apollo 15 deep drill core. Cosmic ray exposure ages, based on spallation-produced¹⁵N, are 2.3 ± 0.4 b.y. for Apollo 11 breccias. This age is much greater than the estimate from cosmogenic²¹Ne, presumably due to diffusive loss of neon.     

Recharge processes during snowmelt: An isotopic and hydrometric investigation

Results from hydrometric and isotopic investigations of unsaturated flow during snowmelt are presented for a hillslope underlain by well-sorted sands. Passage of melt and rainwater through the vadose zone was detected from temporal changes in soil water ²H concentrations obtained from sequential soil cores. Bypassing flow was indicated during the initial snowmelt phase, but was confined to the near-surface zone. Recharge below this zone was via translatory flow, as meltwater inputs displaced premelt soil water. Estimates of premelt water fluxes indicate that up to 19 per cent of the premelt soil water may have been immobile. Average water particle velocities during snowmelt ranged from 6.2 × 10^?7 to 1.1 × 10^?6 ms^?1, suggesting that direct groundwater recharge by meltwater during snowmelt was confined to areas where the premelt water table was within 1 m of the ground surface. Soil water ²H signatures showed a rapid response to isotopically-heavy rain-on-snow inputs late in the melt. In addition, spatial variations in soil moisture content at a given depth induced a pronounced lateral component to the predominantly vertical transport of water. Both factors may complicate isotopic profiles in the vadose zone, and should be considered when employing environmental isotopes to infer recharge processes during snowmelt.     

The extent of lunar regolith mixing

The activity of solar cosmic-ray-produced⁵³Mn has been measured as a function of depth in the upper 100 g/cm² (～55 cm) of lunar cores 60009–60010 and 12025–12028. Additional samples which supplement our earlier work were analyzed from the Apollo 15 and 16 drill stems. These data, taken in conjunction with our previously published results and the²²Na and²⁶Al data of the Battelle Northwest group, indicate that in at least three of the four cases studied the regolith has been measureably disturbed within the last 10 m.y. In one case gardening to 19 g/cm² is required. Activities measured in the uppermost 2 g/cm² indicate frequent mixing within this depth range. No undisturbed profiles were observed nor were any major discontinuities observed in the profiles. The Monte Carlo gardening model of Arnold has been used to derive profiles for the gardened moon-wide average of⁵³Mn and²⁶Al as a function of depth. The⁵³Mn and²⁶Al experimental results are compared with these theoretical predictions. Agreement is good in several respects, but the calculated depths of disturbance appear to be too low.     

Depth and character of rock weathering across a basaltic‐hosted climosequence on Hawai‘i

Using field observations and geochemical and digital terrain analyses, we describe the structure and thickness of the regolith across a climosequence on the island of Hawai‘i to gain insight into the relative roles of precipitation and the near‐surface hydrologic structure in determining weathering patterns. In the wet portion of the climosequence, where the long‐term water balance is positive, the regolith thickness reaches an observed maximum of ~40 m and appears limited by the geomorphic base‐level of the landscape. However, even within this thick regolith, distinct units of varying weathering intensity occur; the vertical ordering of which largely reflects differences in the initial permeability structure of the basalt flows rather than a systematic decrease in weathering intensity downwards from the ground surface. In the dry portion of the climosequence, where the long‐term water balance is negative, the regolith thickness is confined to ~1 m, is highly dependent on the inferred permeability structure of the basalt flows, and is independent of geomorphic base‐level. Weathering intensity also varies according to permeability structure and decreases in this thin regolith with distance beneath the ground surface. The abrupt change in regolith depth and character that coincides with the transition from net‐positive to net‐negative long‐term water balance implies that small changes in precipitation rates around a neutral water balance result in large changes in the distribution and depth of weathering. Together our observations indicate that the distribution and depth of weathering in basalts (and probably other lithologies) might be best understood by considering how precipitation interacts with the complicated near‐surface permeability structure over regolith‐forming timescales to weather rock in the vadose zone. Copyright © 2013 John Wiley & Sons, Ltd.     

In quest of lunar regolith breccias of exotic provenance: a uniquely anorthositic sample from the Fra Mauro (Apollo 14) highlands

Polymict samples can be used to establish mass-balance constraints regarding the bulk composition of the lunar crust, and to gauge the degree of regional heterogeneity in the composition of the lunar crust. The most ideally polymict type of sample is finely-mixed regolith (lunar soil), or its lithified equivalent, regolith breccia. Fortunately, lunar regolith breccias can occasionally be found at great distances from their points of origin — most of the known lunar meteorites are regolith breccias. We are searching for examples of exotic regolith samples among the Apollo regolith breccia collection. Most of the 21 Apollo regolith breccias analyzed for this study strongly resemble the local soils over which they were collected. Nine regolith breccias from Apollo 16 are surprisingly mature compared to previously-analyzed Apollo 16 regolith breccias, and six of the seven from Apollo 16 Station 5 have lower, more local-soil-like,mg ratios than previously analyzed regolith breccias from this station. Several of the Apollo 14 regolith breccias investigated show significantly highermg, and lower Al, than the local soils.The most interesting sample we have investigated is 14076,1, from a lithology that constitutes roughly half of a 2.0-g pebble. The presence of spherules indicates a regolith derivation for 14076,1, yet its highly aluminous (30 wt.% Al₂O₃) composition is clearly exotic to the 1.6-km traverse surface over which the Apollo 14 samples were collected. This sample resembles soils from the Descartes (Apollo 16) highlands far more than it does any other polymict sample from the Fra Mauro (Apollo 14) region. The I/_sFeO maturity index is extremely low, but this may be a result of thermal annealing. A variety of siderophile elements occur in 14076,1 at typical regolith concentrations. The chemistry of the second most aluminous regolith sample from Apollo 14, 14315, can only be roughly approximated as a mixture of local regolith and 14076,1-like material. However, the low a priori statistical probability for long-distance horizontal transport by impact cratering, along with the relatively high contents of incompatible elements in 14076,1 (despite its high Al content), suggest that this regolith breccia probably originated within a few hundred kilometers of the Appollo 14 site. If so, its compositional resemblance to ferroan anorthosite tends to suggest that the regional crust is, or originally was, far richer in ferroan anorthosite than implied by the meager statistics for pristine rocks from this site. Thus, 14076,1 tends to strengthen the hypothesis that ferroan anorthosite originated as the flotation crust of a global magmasphere.     

Argon-lead isotopic correlation in samples from lunar maria: Records from the ancient lunar regolith

²⁰⁷Pb/²⁰⁶Pb of “low temperature sited” (LTS) lead as reported by Silver (1975) increases with⁴⁰Ar/³⁶Ar of trapped argon in thirteen samples from lunar maria. This strongly supports an earlier conclusion by (1972) that large (⁴⁰Ar/³⁶Ar)_T ratios represent ancient regolith records, and provides a rough (⁴⁰Ar/³⁶Ar)_T timescale.The erasure of (⁴⁰Ar/³⁶Ar)_T records in surface soils by the excavation of deep-seated, “fresh” bedrock and by erosion of particle surfaces via ion sputtering must have been counteracted by conserving processes in the regolith. Two such processes are relatively well understood: agglutinate formation and the excavation and comminution of soil breccias which have preserved an ancient (⁴⁰Ar/³⁶Ar)_T record. The frequency distribution of (⁴⁰Ar/³⁶Ar)_T in 82 “soils” from all Apollo missions suggests a third process, which requires that sizeable “pockets” of ancient regolith materials including soils have survived deep turnover for billions of years.Large-scale mobility of LTS lead throughout all of the regolith does not appear to occur.Inert gas ions with sufficient energy for trapping may have reached the lunar surface more than 3 b.y. ago.The Apollo 11 microbreccias appear to have been formed more than 3 b.y. ago from regoliththen extant on the surface.     

Local topography and erosion rate control regolith thickness along a ridgeline in the Sierra Nevada,California

The ridgelines of mountain ranges are a source of geomorphic information unadulterated by the arrival of sediment from upslope. Studies along ridgecrests, therefore, can help identify and isolate the controls on important regolith properties such as thickness and texture. A 1.5 km section of ridgeline in the Sierra Nevada (CA) with a tenfold decrease in erosion rate (inferred from ridgetop convexity) provided an opportunity to conduct a high‐resolution survey of regolith properties and investigate their controls. We found that regolith along the most quickly eroding section of the ridge was the rockiest and had the lowest clay concentrations. Furthermore, a general increase in regolith thickness with a slowing of erosion rate was accompanied by an increase in biomass, changes in vegetation community, broader ridgeline profiles, and an apparent increase in total available moisture. The greatest source of variation in regolith thickness at the 10–100 m scale, however, was the local topography along the ridgeline, with the deepest regolith in the saddles and the thinnest on the knobs. Because regolith in the saddles had higher surface soil moisture than the knobs, we conclude that the hydrological conditions primarily driven by local topography (i.e. rapid vs. slow drainage and water‐storage potential) provide the fundamental controls on regolith thickness through feedbacks incorporating physical weathering by the biota and chemical weathering. Moreover, because the ridgeline saddles are the uppermost extensions of first‐order valleys, we propose that the fluvial network affects regolith properties in the furthest reaches of the watershed. Copyright © 2015 John Wiley & Sons, Ltd.     

Post-deforestation soil loss from steepland hillslopes in Taranaki,New Zealand

Soil erosion on steepland hillslopes in Taranaki, New Zealand, where landsliding is the dominant erosion form, was investigated by comparing mean regolith depths between first-order basins that have had their forest cover removed for different periods of time. Regolith depth and slope angle data were collected along 19 profile lines and 30 profile lines from steepland basins that had been deforested for 10 and 85 years, respectively. These profile lines were subdivided into a total of 236 profile segments of relatively linear slope angle and uniform regolith depth, that averaged 17·5 m in length. The depth of pre-existing regolith on post-deforestation landslide sites is estimated from a regression of regolith depth on slope angle for undisturbed (non-landslide) profile segments. Regolith depletion on landslide sites is in turn estimated by subtracting the depth of regolith on landslide sites from the estimate of pre-existing regolith depth. Regolith depletion by post-deforestation landslides, averaged over the entire length of profile lines, gives an estimate of average surface lowering. For the area deforested for 85 years, average surface lowering by post-deforestation landslides is 0·15 ± 0·04 m, and is the same as the difference in mean depth of 0·15 ± 0·11 m between this area and the area deforested for 10 years. Erosion of regolith from hillslopes by processes other than landsliding appears to be minimal. The 0·15 m average surface lowering represents a regolith depletion rate of 1·8 ± 0±5 mm yr^?1. For hillslopes steeper than 28°, where all post-deforestation landslides occur, average surface lowering is 0·20 ± 0·05 m, and the regolith depletion rate is 2±4 · 0±6 mm yr^?1. Average surface lowering is greatest at 0·23 ± 0·07 m on hillslopes steeper than 32° where most post-deforestation landslides occur. Here, the regolith depletion rate is 2·7 ± 0·8 mm yr^?1. A large-magnitude, low-frequency storm in March 1990, produced an average surface lowering of 0·041 m. There were proportionately more landslides in the area deforested for 10 years, illustrating the importance of previous erosion history of hillslopes on the spatial distribution of landslides. There were also comparatively few landslides on steeper hillslopes because previous lower magnitude storms had already removed much of the deeper regolith.     

Characterising deep vadose zone water movement and solute transport under typical irrigated cropland in the North China Plain

Understanding the dynamics and mechanisms of soil water movement and solute transport is essential for accurately estimating recharge rates and evaluating the impacts of agricultural activities on groundwater resources. In a thick vadose zone (0–15 m) under irrigated cropland in the piedmont region of the North China Plain, soil water content, matric potential, and solute concentrations were measured. Based on these data, the dynamics of soil water and solutes were analysed to investigate the mechanisms of soil water and solute transport. The study showed that the 0–15‐m vadose zone can be divided into three layers: an infiltration and evaporation layer (0–2 m), an unsteady infiltration layer (2–6 m), and a quasi‐steady infiltration layer (6–15 m). The chloride, nitrate, and sulphate concentrations all showed greater variations in the upper soil layer (0–1 m) compared to values in the deep vadose zone (below 2 m). The average concentrations of these three anions in the deep vadose zone varied insignificantly with depth and approached values of 125, 242, and 116 mg/L. The accumulated chloride, sulphate, and nitrate were 2,179 ± 113, 1,760 ± 383, and 4,074 ± 421 kg/ha, respectively. The soil water potential and solute concentrations indicated that uniform flow and preferential flow both occurred in the deep vadose zone, and uniform flow was the dominant mechanism of soil water movement in this study. The piston‐like flow velocity of solute transport was 1.14 m per year, and the average value of calculated leached nitrate nitrogen was 107 kg/ha?year below the root zone. The results can be used to better understand recharge processes and improve groundwater resources management.     

Where fast weathering creates thin regolith and slow weathering creates thick regolith

Weathering disaggregates rock into regolith – the fractured or granular earth material that sustains life on the continental land surface. Here, we investigate what controls the depth of regolith formed on ridges of two rock compositions with similar initial porosities in Virginia (USA). A priori, we predicted that the regolith on diabase would be thicker than on granite because the dominant mineral (feldspar) in the diabase weathers faster than its granitic counterpart. However, weathering advanced 20× deeper into the granite than the diabase. The 20 × ‐thicker regolith is attributed mainly to connected micron‐sized pores, microfractures formed around oxidizing biotite at 20 m depth, and the lower iron (Fe) content in the felsic rock. Such porosity allows pervasive advection and deep oxidation in the granite. These observations may explain why regolith worldwide is thicker on felsic compared to mafic rock under similar conditions. To understand regolith formation will require better understanding of such deep oxidation reactions and how they impact fluid flow during weathering. Copyright © 2012 John Wiley & Sons, Ltd.     

Architecture of the deep critical zone in the Río Icacos watershed (Luquillo Critical Zone Observatory,Puerto Rico) inferred from drilling and ground penetrating radar (GPR)

In the critical zone, surficial bedrock interactions result in the formation of a mantle of chemically‐ and physically‐altered material defined here as regolith. In the watershed of the Río Icacos, an upland river draining the Luquillo Mountains in tropical Puerto Rico, we explored the influence of lithology (quartz diorite versus hornfels‐facies volcaniclastic rock) on weathering. Regolith profiles were studied by drilling boreholes and imaging the subsurface using ground penetrating radar (GPR). Overall, the regolith structure is not laterally continuous but rather is punctuated by zones of deep fractures that host in situ weathering, corestones, and colluvial material. GPR images of these vertical zones show reflectors at 15–20 m depth. Thus, the architecture of the critical zone in the upper Luquillo Mountains is highly dependent on lithology and its influence on fracture development. At the highest elevations where hornfels overlies quartz diorite, positive feedbacks occur when the water table drops so that oxidative weathering of biotite in the more felsic rock creates microfractures and allows deeper infiltration of meteoric waters. Such exposure results in some of the fastest weathering rocks in the world and may contribute to formation of the knickpoint in the Río Icacos watershed. This work represents the first study combining GPR and drilling to look at the structure of the deep critical zone and demonstrates: (1) the importance of combining direct methods (such as drilling) with indirect methods (such as GPR) to understand the architecture of the critical zone in tropical systems; (2) the interplay of the surficial stress regime, lithology and climate in dictating the architecture of weathering. Copyright © 2016 John Wiley & Sons, Ltd.     

Particle track record in Apollo 15 deep core from 54 to 80 cm depths

Particle track measurements have been made in nearly 500 individual grains from 13 levels in the 54–80 cm depth range of the Apollo 15 deep core. They reveal a wide range of track densities at all depths and some systematic variations within layers, indicating that both predepositional mixing and subsequent layering are present and that separate sub-layers exist within larger regions where no sub-layers are visible. Minimum track densities are inferred to be useful measures of maximum residence times for undisturbed layers. Using the observed minimum track densities we conclude that the average deposition rate in this section of soil column was ≥ 0.4 cm/million years.     

A Comparison of Field Techniques for Confirming Dense Nonaqueous Phase Liquids

Dense nonaqueous phase liquids (DNAPLs) are immiscible fluids with a specific gravity greater than, water. When present, DNAPLs present a serious and long-term source of continued ground water and soil contamination (Pankow and Cherry 1996). Accurate characterization and delineation of DNAPL in the subsurface is critical for evaluating restoration potential and for remedy design at a site. However, obtaining accurate and definitive direct evidence of DNAPL is difficult. A field study was recently performed comparing several approaches to DNAPL characterization at a site where anecdotal and limited direct evidence of DNAPL exists. The techniques evaluated included a three-dimensional high-resolution seismic survey, field screening of soil cores with a flame ionization detector (FID)/organic vapor analyzer (OVA), hydrophobic (Sudan IV) dye-impregnated reactive FLUTe® (Flexible Liner Underground Technologies) liner material in combination with Rotasonic drill cores, centrifuged soil with Sudan IV dye, ultraviolet light (UV) fluorescence, a Geoprobe® Membrane Interface Probe (MIP®), and phase equilibrium partitioning evaluations based on laboratory analysis of soil samples. Sonic drilling provided reliable continuous cores from which minor soil structures could be evaluated and screened with an OVA, The screening provided reliable preliminary data for identifying likely DNAPL zones and for selecting samples for further analyses. The FLUTe liner material provided the primary direct evidence of the presence of DNAPL and reliable information on the thickness and nature of its occurrence (i.e., pooled or ganglia). The MIP system provided good information regarding the subsurface lithology and rapid identification and delineation of probable DNAPL areas. The three-dimensional seismic survey was of minimal benefit to this study, and the centrifuging of samples with Sudan IV dye and the use of UV fluorescence provided no benefit. Results of phase equilibrium partitioning concentration calculations for soil samples (to infer the presence of DNAPL) were in good agreement with the site screening data. Additionally, screening data compared well with previous ground water data and supported using 1% of the pure phase solubility limit of Freon 113 (2 mg/L) as an initial means to define the DNAPL study area. Based on the results of this study, the preferred approach for identifying and delineating DNAPL in the subsurface is to initially evaluate ground water data and define an area where dissolved concentrations of the target analyte(s) approach 1% of the pure phase solubility limit. Within this study area, the MIP device is used to more specifically identify areas and lithologic zones where DNAPL may have accumulated. Core samples (either Rotasonic or Geoprobe) are then collected from zones where MIP readings are indicative of the presence of DNAPL. Soil samples from the free-product portions of the core(s) are then submitted to a laboratory for positive analyte identification. Soil analyses are then combined with site-specific geotechnical information (i.e., fraction organic carbon, soil bulk density, and porosity) and equilibrium partitioning algorithms used to estimate concentrations of organic contaminants in soil samples that would be indicative of free product. Used in combination, the soil analysis and the MIP records appear to provide accurate DNAPL identification and delineation.