Volatile-induced magma differentiation in the plumbing system of Mt. Etna volcano (Italy): evidence from glass in tephra of the 2001 eruption

Mount Etna volcano was shaken during the summer 2001 by one of the most singular eruptive episodes of the last centuries. For about 3 weeks, several eruptive fractures developed, emitting lava flows and tephra that significantly modified the landscape of the southern flank of the volcano. This event stimulated the attention of the scientific community especially for the simultaneous emission of petrologically distinct magmas, recognized as coming from different segments of the plumbing system. A stratigraphically controlled sampling of tephra layers was performed at the most active vents of the eruption, in particular at the 2,100 m (CAL) and at the 2,550 m (LAG) scoria cones. Detailed scanning electron microscope and energy dispersive x-ray spectrometer (SEM-EDS) analyses performed on glasses found in tephra and comparison with lava whole rock compositions indicate an anomalous increase in Ti, Fe, P, and particularly of K and Cl in the upper layers of the LAG sequence. Mass balance and thermodynamic calculations have shown that this enrichment cannot be accounted for by “classical” differentiation processes, such as crystal fractionation and magma mixing. The analysis of petrological features of the magmas involved in the event, integrated with the volcanological evolution, has evidenced the role played by volatiles in controlling the magmatic evolution within the crustal portion of the plumbing system. Volatiles, constituted of H₂O, CO₂, and Cl-complexes, originated from a deeply seated magma body (DBM). Their upward migration occurred through a fracture network possibly developed by the seismic swarms during the period preceding the event. In the upper portion of the plumbing system, a shallower residing magma body (ABT) had chemical and physical conditions to receive migrating volatiles, which hence dissolved the mobilized elements producing the observed selective enrichment. This volatile-induced differentiation involved exclusively the lowest erupted portion of the ABT magma due to the low velocity of volatiles diffusion within a crystallizing magma body and/or to the short time between volatiles migration and the onset of the eruption. Furthermore, the increased amount of volatiles in this level of the chamber strongly affected the eruptive behavior. In fact, the emission of these products at the LAG vent, towards the end of the eruption, modified the eruptive style from classical strombolian to strongly explosive.     

Petrologic evidence of a complex plumbing system feeding the July–August 2001 eruption of Mt. Etna,Sicily, Italy

After the major 1991–1993 eruption, Mt. Etna resumed flank activity in July 2001 through a complex system of eruptive fissures cutting the NE and the S flanks of the volcano and feeding effusive activity, fire fountains, Strombolian and minor phreatomagmatic explosions. Throughout the eruption, magmas with different petrography and composition were erupted. The vents higher than 2,600 m a.s.l. (hereafter Upper vents, UV) erupted porphyritic, plagioclase-rich trachybasalt, typical of present-day summit and flank activity. Differently, the vents located at 2,550 and 2,100 m a.s.l. (hereafter Lower vents, LV) produced slightly more primitive trachybasalt dominated by large clinopyroxene, olivine and uncommon minerals for Etna such as amphibole, apatite and orthopyroxene and containing siliceous and cognate xenoliths. Petrologic investigations carried out on samples collected throughout the eruption provided insights into one of the most intriguing aspects of the 2001 activity, namely the coeval occurrence of distinct magmas. We interpret this evidence as the result of a complex plumbing system. It consists in two separate magma storage systems: a shallow one feeding the activity of the UV and a deeper and more complex storage related to the activity of LV. In this deep storage zone, which is thermally and compositionally zoned, the favourable conditions allow the crystallization of amphibole and the occurrence of cognate xenoliths representing wall cumulates. Throughout 2001 eruption, UV and LV magmas remain clearly distinct and ascended following different paths, ruling out the occurrence of mixing processes between them. Furthermore, integrating the 2001 eruption in the framework of summit activity occurring since 1995, we propose that the 2001 magma feeding the vents lower than 2,600 m a.s.l. is a precursor of a refilling event, which reached its peak during the 2002–2003 Etna flank eruption.     

The contemporaneous emission of low-K and high-K trachybasalts and the role of the NE Rift during the 2002 eruptive event,Mt. Etna,Italy

Mount Etna volcano erupted almost simultaneously on its northeastern and southern flanks between October 27 and November 3, 2002. The eruption on the northeastern flank lasted for 8 days, while on the southern flank it continued for 3 months. The northeastern flank eruption was characterized by the opening of a long eruptive fracture system between 2,900 and 1,900 m.a.s.l. A detailed survey indicates that the fractures’ direction shifted during the opening from N10W (at the NE Crater, 2,900 m) to N45E (at its lowest portion, 1,900 m) and that distinct magma groups were erupted at distinct fracture segments. Based on their petrological features, three distinct groups of rocks have been identified. The first group, high-potassium porphyritic (HKP), is made up of porphyritic lavas with a Porphyritic Index (P.I.) of 20–32 and K₂O content higher than 2 wt%. The second group is represented by lavas and tephra with low modal phenocryst abundance (P.I. < 20) named here oligo-phyric (low-phyric), and K₂O content higher than 2 wt% (HKO, high-potassium oligophyric). The third group, low-potassium oligophyric (LKO), consists of tephra with oligophyric texture (P.I. < 20) but K₂O content < 2 wt%. K-rich magmas (HKP and HKO) are similar to the magma erupted on the southern flank, and geochemical variations within these groups can be accounted for by a variable degree of fractionation from a single parent magma. The K-poor magma (LKO), erupted only in the upper segment of the fracture, cannot be placed on the same liquid line of descent of the HK groups, and it is similar to the magmas that fed the activity of Etna volcano prior to the eruption of 1971. This is the first time since then that a magma of this composition has been documented at Mt. Etna, thus providing a strong indication for the existence of distinct batches of magma whose rise and differentiation are independent from the main conduit system. The evolution of this eruption provides evidence that the NE Rift plays a very active role in the activity of Mt. Etna volcano, and that its extensional tectonics allows the intrusion and residence of magma bodies at various depths, which can therefore differentiate independently from the main open conduit system.