Late Mesozoic to Paleogene stratigraphy of the Salar de Atacama Basin, Antofagasta, Northern Chile: Implications for the tectonic evolution of the Central Andes

The Salar de Atacama basin, the largest “pre-Andean” basin in Northern Chile, was formed in the early Late Cretaceous as a consequence of the tectonic closure and inversion of the Jurassic–Early Cretaceous Tarapacá back arc basin. Inversion led to uplift of the Cordillera de Domeyko (CD), a thick-skinned basement range bounded by a system of reverse faults and blind thrusts with alternating vergence along strike. The almost 6000-m-thick, upper Cretaceous to lower Paleocene sequences (Purilactis Group) infilling the Salar de Atacama basin reflects rapid local subsidence to the east of the CD. Its oldest outcropping unit (Tonel Formation) comprises more than 1000 m of continental red sandstones and evaporites, which began to accumulate as syntectonic growth strata during the initial stages of CD uplift. Tonel strata are capped by almost 3000 m of sandstones and conglomerates of western provenance, representing the sedimentary response to renewed pulses of tectonic shortening, which were deposited in alluvial fan, fluvial and eolian settings together with minor lacustrine mudstone (Purilactis Formation). These are covered by 500 m of coarse, proximal alluvial fan conglomerates (Barros Arana Formation). The top of the Purilactis Group consists of Maastrichtian-Danian alkaline lava and minor welded tuffs and red beds (Cerro Totola Formation: 70–64 Ma K/Ar) deposited during an interval of tectonic quiescence when the El Molino–Yacoraite Late Cretaceous sea covered large tracts of the nearby Altiplano-Puna domain. Limestones interbedded with the Totola volcanics indicate that this marine incursion advanced westwards to reach the eastern CD slope. CD shortening in the Late Cretaceous was accompanied by volcanism and continental sedimentation in fault bounded basins associated to strike slip along the north Chilean magmatic arc to the west of the CD domain, indicating that oblique plate convergence prevailed during the Late Cretaceous. Oblique convergence seems to have been resolved into a highly partitioned strain system where margin-parallel displacements along the thermally weakened arc coexisted with margin-orthogonal shortening associated with syntectonic sedimentation in the Salar de Atacama basin. A regionally important Early Paleocene compressional event is echoed, in the Salar de Atacama basin by a, distinctive, angular unconformity which separates Paleocene continental sediments from Purilactis Group strata. The basin also records the Eocene–Early Oligocene Incaic transpressional episode, which produced, renewed uplift in the Cordillera de Domeyko and triggered the accumulation of a thick blanket of syntectonic gravels (Loma Amarilla Formation).     

Evolution of the West Andean Escarpment at 18°S (N. Chile) during the last 25 Ma: uplift, erosion and collapse through time

The geological record of the Western Andean Escarpment (WARP) reveals episodes of uplift, erosion, volcanism and sedimentation. The lithological sequence at 18°S comprises a thick pile of Azapa Conglomerates (25–19 Ma), an overlying series of widespread rhyodacitic Oxaya Ignimbrites (up to 900 m thick, ca. 19 Ma), which are in turn covered by a series of mafic andesite shield volcanoes. Between 19 and 12 Ma, the surface of the Oxaya Ignimbrites evolved into a large monocline on the western slope of the Andes. A giant antithetically rotated block (Oxaya Block, 80 km×20 km) formed on this slope at about 10–12 Ma and resulted in an easterly dip and a reversed drainage on the block's surface. Morphology, topography and stratigraphic observations argue for a gravitational cause of this rotation. A “secondary” gravitational collapse (50 km³), extending 25 km to the west occurred on the steep western front of the Oxaya Block. Alluvial and fluvial sediments (11–2.7 Ma) accumulated in a half graben to the east of the tilted block and were later thrust over by the rocks of the escarpment wall, indicating further shortening between 8 and 6 Ma. Flatlying Upper Miocene sediments (<5.5 Ma) and the 2.7 Ma Lauca–Peréz Ignimbrite have not been significantly shortened since 6 Ma, suggesting that recent uplift is at least partly caused by regional tilting of the Western Andean slope.     

Forebulge dynamics and environmental control in Western Amazonia: The case study of the Arch of Iquitos (Peru)

The Iquitos Arch corresponds to a broad topographic high in the Western Amazonia. Morphostructural and geophysical data and flexural modeling show that the Iquitos Arch is the present-day forebulge of the Northwestern Amazonian foreland basin. A detailed tectono-sedimentary study of the Neogene and Quaternary deposits of the Iquitos area has been carried out in order to circumscribe the timing of the forebulge uplift and its environmental consequences. The Neogene and Quaternary sedimentary succession of the Iquitos Arch consists of six formations that evolved from tidal to fluvial environments. The first three formations exhibit Late Miocene gliding features and synsedimentary normal faults. Such soft-sediment deformations bear witness to tectonic activity ascribed to the growth of the forebulge. Regional erosive surfaces that separate the Neogene and Quaternary formations recorded the progressive forebulge emersion and the evolution of Amazonian drainage system. This uplift is related to an increase in tectonic activity within the Andes, which has provoked the eastern propagation of the orogenic wedge and caused an orogenic loading stage in the Amazonian foreland basin system. The emersion of the forebulge induced the retreat of the Pebas “marine megalake” nearby the Iquitos area and consequently caused important environmental changes in the Amazonian basin. From the end of the Late Miocene to the Pliocene, the forebulge acted as a barrier inducing the deposition of fluvial deposits in the forebulge depozone and the deposition of the “White Sand” deposits in the backbulge depozone. Since about 6 Ma, the forebulge is incised and crossed over by the modern Amazon River. The Iquitos forebulge is still growing as shown by the faulted Holocene terrace deposits.     

Cenozoic uplift and subsidence in the North Atlantic region: Geological evidence revisited

The topographic evolution of the “passive” margins of the North Atlantic during the last 65 Myr is the subject of extensive debate due to inherent limitations of the geological, geomorphological and geophysical methods used for studies of uplift and subsidence. We have compiled a database of sign, time and amplitude (where possible) of topographic changes in the North Atlantic region during the Cenozoic (65–0 Ma). Our compilation is based on published results from reflection seismic studies, AFT (apatite fission track) studies, VR (vitrinite reflectance) trends, maximum burial, sediment supply studies, mass balance calculations and extrapolation of seismic profiles to onshore geomorphological features. The integration of about 200 published results reveal a clear pattern of topographic changes in the North Atlantic region during the Cenozoic: (1) The first major phase of Cenozoic regional uplift occurred in the late Palaeocene–early Eocene (ca 60–50 Ma), probably related to the break-up of the North Atlantic between Europe and Greenland, as indicated by the northward propagation of uplift. It was preceded by middle Palaeocene uplift and over-deepening of some basins of the North Sea and the surrounding areas. (2) A regional increase in subsidence in the offshore marginal areas of Norway, the northern North Sea, the northern British Isles and west Greenland took place in the Eocene (ca 57–35 Ma). (3) The Oligocene and Miocene (35–5 Ma) were characterized by regional tectonic quiescence, with only localised uplift, probably related to changes in plate dynamics. (4) The second major phase of regional uplift that affected all marginal areas of the North Atlantic occurred in the Plio-Pleistocene (5–0 Ma). Its amplitude was enhanced by erosion-driven glacio-isostatic compensation. Despite inconclusive evidence, this phase is likely to be ongoing at present.     

Geomorphic expression of the southern Central Andes forebulge (37°S,Argentina)

We present a geomorphologic analysis of an east‐west transect located east of the southern Andes of Argentina (~37°S). We observe a succession of zones that underwent erosion and deposition during the Pleistocene. If the proximal Andean foothills are incised, a proximal depozone receives sediments feeding the megafan of the Rio Colorado on the Chadileuvú plain. More distally, the abandoned palaeo‐valleys and bending of the valley floors reflect a localized uplift. Further to the east, another depozone corresponds to the Pampa Deprimida lowland. This pattern is consistent with the presence of a classical flexural geometry of the lithosphere. The distal uplift of the foreland corresponds in terms of location, length (150 km) and amplitude (240 m) to the Andean forebulge modelled by a geophysical approach. In this study, we identify the morphological imprint of this bulge and show its effect on the fluvial activity.     

Slip rate of trench‐parallel normal faulting along the Mejillones Fault (Atacama Fault System): Relationships with the northern Chile subduction and implications for seismic hazards

The recent tectonics of the arid northern Chile Andean western forearc is characterized by trench‐parallel normal faults within the Atacama Fault System (AFS). Since the 1995‐Mw 8.1 Antofagasta earthquake, the mechanism driving this recent and localized extension is considered to be associated with the seismic cycle within the subduction zone. Analyzing morphotectonic patterns along these faults allows examining the seismic potential associated with the subduction zone. Using field Digital Elevation Models and in situ‐produced cosmogenic ¹⁰Be, we determined a 0.2 mm/a long‐term slip rate along the Mejillones Fault, one of the most prominent structures within the AFS. This result suggests that the AFS corresponds to slow slip rate faults despite the rapid subduction context. However, the size of coseismic slips observed along the AFS faults suggests that larger subduction earthquakes (Mw > 8.1) may occur episodically in the area.     

Applying sandstone petrofacies to unravel the Upper Carboniferous evolution of the Paganzo Basin, northwest Argentina

A compositional study of sandstones belonging to the lower section of the Paganzo Group (Middle Carboniferous–Early Permian) in the Paganzo Basin (northwestern Argentina) helps unravel the stratigraphic and paleogeographic evolution of the basin. Three morphotectonic units constitute the complex basement of the basin: (1) to the east, the igneous–metamorphic basement of the Sierras Pampeanas and Famatina systems; (2) to the west, the Precordillera, made up of Early and Middle Paleozoic sedimentary rocks; and (3) the Upper Paleozoic volcanic arc along the western boundary with the Río Blanco Basin. On the basis of sandstone detrital modes of the Lagares, Malanzán, Loma Larga, Guandacol, Tupe, Punta del Agua, and Río del Peñón formations, seven petrofacies are distinguished: quartzofeldespathic (QF), quartzofeldespathic-metamorphic enriched (QF-Lm), quartzofeldespathic-sedimentary enriched (QF-Ls), mixed quartzolithic (QL), quartzolithic-volcanic (QLv), volcanolithic-quartzose (LvQ), and volcanolithic (Lv). The spatial and temporal distribution of these petrofacies suggest an evolutive model for the Upper Paleozoic sedimentary filling of the basin that includes three “petrosomes”: (1) the basement petrosome, a clastic wedge of arkosic composition that diachronically prograded and thinned from east to west; (2) the recycled orogen petrosome, revealing the Protoprecordillera as a positive element in the western Paganzo Basin during the Namurian; and (3) the volcanic arc petrosome, recording volcanic activity along the western margin of Gondwana during the Westphalian.     

Stratigraphy and sedimentation rates of Upper Cretaceous deep-water systems of the Rhenodanubian Group (Eastern Alps, Germany)

In the Bavarian Alps (Germany), west of the Isar River, the abyssal deposits of the Lower Barremian to Upper Campanian Rhenodanubian Group consist of siliciclastic and calcareous turbidites alternating with hemipelagic non-calcareous mudstones. The up to 1500-m-thick succession, deposited in the Penninic Basin to the south of the European Plate, is characterized by a low mean sedimentation rate (c. 25 mm kyr⁻¹) over 60 million years. Palaeocurrents and turbidite facies distribution patterns suggest that sedimentation occurred on a weakly inclined abyssal plain. The highest sedimentation rates (up to 240 mm kyr⁻¹) were associated with the calcareous mud turbidites of the newly defined Röthenbach Subgroup, which includes the Piesenkopf, Kalkgraben and Hällritz formations (Middle Coniacian to Middle Campanian). These calcareous turbidites prograded from the west, and interfinger towards the east with red hemipelagic claystone. A high sea level presumably favoured pelagic carbonate production and accumulation on the shelves and on internal platforms in the western part of the basin, whereas siliciclastic shelves with steep slope angles have bordered the eastern part of the basin, where a dearth of turbidite sedimentation and increased Cretaceous oceanic red beds deposition occurred. In contrast to the eustatically-induced Middle Coniacian to Lower Campanian Cretaceous oceanic red beds (calcareous nannoplankton zones CC14 to CC18), red hemipelagites of Early Cenomanian age (upper part of calcareous nannoplankton zone CC9) and early Late Campanian age (upper part of zone CC21 and zone CC22) are interpreted as the result of regional tectonic activity.     

The Saharan Metacraton

This article introduces the name “Saharan Metacraton” to refer to the pre-Neoproterozoic––but sometimes highly remobilized during Neoproterozoic time––continental crust which occupies the north-central part of Africa and extends in the Saharan Desert in Egypt, Libya, Sudan, Chad and Niger and the Savannah belt in Sudan, Kenya, Uganda, Congo, Central African Republic and Cameroon. This poorly known tract of continental crust occupies 5,000,000 km² and extends from the Arabian-Nubian Shield in the east to the Tuareg Shield to the west and from the Congo craton in the south to the Phanerozoic cover of the northern margin of the African continent in southern Egypt and Libya. The term “metacraton” refers to a craton that has been remobilized during an orogenic event but is still recognizable dominantly through its rheological, geochronological and isotopic characteristics. Neoproterozoic remobilization of the Saharan Metacraton was in the forms of deformation, metamorphism, emplacement of igneous bodies, and probably local episodes of crust formation related to rifting and oceanic basin development. Relics of unaffected or only weakly remobilized old lithosphere are present as exemplified by the Archean to Paleoproterozoic charnockites and anorthosites of the Uweinat massif at the Sudanese/Egyptian/Libyan boarder. The article explains why the name “Saharan Metacraton” should be used, defines the boundaries of the metacraton, reviews geochronological and isotopic data as evidence for the presence of pre-Neoproterozoic continental crust, and discusses what happened to the Saharan Metacraton during the Neoproterozoic. A model combining collisional processes, lithospheric delamination, regional extension, and post-collisional dismembering by horizontal shearing is proposed.     

Late Triassic fluvial and marine shelf succession, Quebrada Doña Inés Chica, Atacama region, northern Chile

A 400-meter-thick volcanic and fine-grained clastic sedimentary succession in Quebrada Doña Ines Chica (26°07′S latitude; 69°20'W longitude) provides a record of Late Triassic deposition in the Atacama region of northern Chile. The strata are conformably overlain by fossiliferous marine limestones and sandstones of Late Triassic to Early Jurassic (Sinemurian) age which contain the oldest ichthyosaur remains known from Central and South America. The clastic succession is interpreted as coastal fluvial deposits, with the overlying limestones representing shelf deposits.     

A Triassic large igneous province in the Pontides, northern Turkey: geochemical data for its tectonic setting

A strongly deformed and metamorphosed Triassic oceanic seamount(s) and plateau succession extends as an east–west belt for 1100 km along the Pontides of northern Turkey. This succession, known widely as the Nilüfer unit, consists mainly of metabasic lava and tuff–marble–phyllite association including tectonic slices of ultramafic rock and gabbro. According to the conodont findings the unit formed during the Early to Mid-Triassic, and the isotopic age data indicate that it underwent high-pressure greenschist facies metamorphism during the latest Triassic period. The metavolcanic rocks form over 80% of the sequence. The Nilüfer unit covers an area of 120,000 km², with the volume of mafic lava estimated as 2×10⁵ km³. Such a huge volcanic pile has erupted rapidly in a relatively short period during the Early to Mid-Triassic (approx. 10 Ma). Hypotheses for the origin of the Nilüfer unit include a ‘seamount’, ‘intra-arc and/or fore-arc basin’, ‘oceanic plateau’, and ‘Early Triassic rift’. The geochemistry of metabasites and that of relict magmatic clinopyroxenes indicate that there are two main mafic rock groups in the Nilüfer unit displaying tholeiitic and alkaline affinities. No metabasite and clinopyroxene sample display typical orogenic basalt affinity or a subduction signature. Geochemical data obtained in this study are consistent with the derivation of the metabasites from the topmost extrusive layers of an oceanic plateau (LIP) together with the volcanic rocks of seamount(s).     

Sedimentary architecture and glacial hydrodynamic significance of the stratified Oak Ridges Moraine,southern Ontario,Canada

High-quality subsurface data provide new insights into the formation of Oak Ridges Moraine (ORM), an ~80 km³ sequence of stratified meltwater deposits resting >200 m above adjacent Lake Ontario. The ORM sedimentary succession comprises a three-part regional architecture: (i) ~north–south channel sand–gravel; (ii) channel-capping rhythmites; and (iii) east–west ridge sediments. The ORM depositional sequence overlies a regional unconformity with a cross-cutting channel network resulting from ~north–south meltwater floods that transitioned progressively (falling stage) from a ~NNE to ENE flow direction (parallels Lake Ontario depression). Seismic profiles delineate the channels and channel fill characteristics of bank-to-bank channel sedimentation of thick gradational gravel–sand–mud sequences. Channel-capping mud (~100–236 rhythmites) within multiple channels beneath the ORM landform mark a widespread interval of low-energy, seasonally controlled subglacial pond deposition. During this quiescent period ice-sheet thickness adjusted to flood-induced stretching/thinning and re-profiled slopes. New ice gradients led to east–west flow and deposition of the overlying third element, a sequence of high-energy confined esker–fan sediments along ORM ridge. Close, sequential timing (~329 varve years) of channel, basin and ridge-forming architectural elements supports naming this assemblage the ORM formation. Proposed ORM floods are analogous to Icelandic jökulhlaups based on the size, geometry and sedimentology. The observed rhythmite interval between flood events represents a short period (~236 years) of regional meltwater storage prior to east–west ORM flooding. The ORM channel and overlying esker-fan sediment ridge represent two closely timed meltwater drainage events rather than formation by coalescing ice streams. The scale and timing of the ORM flood events are linked to rapid sea-level rise, ~13.5 ka BP. This high-resolution ORM sedimentological record may provide insights into depositional and glaciogenic controls of other large, stratified moraines. The ORM data indicate deposition in response to hydrodynamic events (outbreak floods, re-profiled ice) rather than direct climate forcing.     

Stratigraphic and tectonic settings of Proterozoic glaciogenic rocks and banded iron-formations: relevance to the snowball Earth debate

Among Palaeoproterozoic glacial deposits on four continents, the best preserved and documented are in the Huronian on the north shore of Lake Huron, Ontario, where three glaciogenic formations have been recognized. The youngest is the Gowganda Formation. The glacial deposits of the Gowganda Formation were deposited on a newly formed passive margin. To the west, on the south side of Lake Superior, the oldest Palaeoproterozoic succession (Chocolay Group) begins with glaciogenic diamictites that have been correlated with the Gowganda Formation. The >2.2 Ga passive margin succession (Chocolay Group=upper Huronian) is overlain, with profound unconformity, by a >1.88 Ga succession that includes the superior-type banded iron-formations (BIFs). The iron-formations are therefore not genetically associated with Palaeoproterozoic glaciation but were deposited 300 Ma later in a basin that formed as a result of closure of the “Huronian” ocean. In Western Australia, Palaeoproterozoic glaciogenic deposits of the Meteorite Bore Member appear to have formed part of a similar basin fill. The glaciogenic rocks are, however, separated from underlying BIF by a thick siliciclastic succession. In both North America and Western Australia, BIF-deposition took place in compressional (possibly foreland basin) settings but the iron-formations are of greatly different age, suggesting that the most significant control on their formation was not oxygenation of the Earth’s atmosphere but rather, emplacement of Fe-rich waters (uplifted as a result of ocean floor destruction?) in a siliciclastic-starved environment where oxidation (biogenic?) could take place. Some of the Australian BIFs appear to predate the appearance of red beds in North American Palaeoproterozoic successions and are therefore unlikely to be related to oxygenation of the atmosphere.Neoproterozoic glaciogenic deposits are widespread on the world’s continents. Some are associated with iron-formations. Two theories have emerged to explain these enigmatic BIFs. According to the snowball Earth hypothesis (SEH), ice-covered oceans would have permitted buildup of dissolved Fe. Precipitation of Fe-rich sediments would have taken place following reoxygenation of the hydrosphere as the ice cover disappeared. A second theory involves glaciation of Red Sea rift-type basins. Fe-charged brines in such basins would have precipitated on being mixed with “normal” seawater as a result of glacially driven thermal overturn. Both theories provide an explanation of the hydrothermal imprint on the geochemistry of Neoproterozoic BIF but the restricted development of BIF (relative to glacial deposits), evidence of rift activity such as significant facies and thickness changes, and association with volcanic rocks, all favour deposition in a rift environment.Cap carbonates are one of the cornerstones of the SEH. Escape from the snowball condition is said to have resulted from buildup of atmospheric CO₂ while the weathering cycle was stopped. Under such conditions, the first siliciclastic deposits following glaciation, should be extremely weathered, and should be overlain by sedimentary rocks that show a gradual return to more “normal” compositions. Using a chemical index of alteration (CIA) it can be shown that, in the case of the Gowganda Formation, the CIA shows a gradual upward increase, opposite to that predicted by the SEH. The Earth underwent severe climatic perturbations both near the beginning and end of the Proterozoic Eon but whether it attained a totally frozen surface condition (as postulated under the SEH) remains speculative.     

Pliocene and Quaternary regional uplift in western Turkey: the Gediz River terrace staircase and the volcanism at Kula

Along the upper reaches of the Gediz River in western Turkey, in the eastern part of the Aegean extensional province, the land surface has uplifted by 400 m since the Middle Pliocene. This uplift is revealed by progressive gorge incision, and its rate can be established because river terraces are capped by basalt flows that have been K–Ar and Ar–Ar dated. At present, the local uplift rate is 0.2 mm a⁻¹. Uplift at this rate began around the start of the Middle Pleistocene, following a span of time when the uplift was much slower. This was itself preceded by an earlier uplift phase, apparently in the late Late Pliocene and early Early Pleistocene, when the uplift rate was comparable to the present. The resulting regional uplift history resembles what is observed in other regions and is analogously interpreted as the isostatic response to changing rates of surface processes linked to global environmental change. We suggest that this present phase of surface uplift, amounting so far to 150 m, is being caused by the nonsteady-state thermal and isostatic response of the crust to erosion, following an increase in erosion rates in the late Early Pleistocene, most likely as a result of the first large northern-hemisphere glaciation during oxygen isotope stage 22 at 870 ka. We suggest that the earlier uplift phase, responsible for the initial 250 m of uplift, resulted from a similar increase in erosion rates caused by the deterioration in local climate at 3.1 Ma. This uplift thus has no direct relationship to the crustal extension occurring in western Turkey, the rate and sense of which are thought not to have changed significantly on this time scale. Our results thus suggest that the present, often deeply incised, landscape of western Turkey has largely developed from the Middle Pleistocene onwards, for reasons not directly related to the active normal faulting that is also occurring. The local isostatic consequences of this active faulting are instead superimposed onto this “background” of regional surface uplift. Modelling of this surface uplift indicates that the effective viscosity of the lower continental crust beneath this part of Turkey is of the order of 10¹⁹ Pa s, similar to a recent estimate for beneath central Greece. The lower uplift rates observed in western Turkey, compared with central Greece, result from the longer typical distances of fluvial sediment transport, which cause weaker coupling by lower-crustal flow between offshore depocentres and eroding onshore regions that provide the sediment source.     

Superposed deposits of thick coal on the eastern edge of the Illinois Basin and their association with underlying geologic features

Comparison of maps produced from publicly available data (drillers' logs, electrical logs and mine maps) provides a basis for inferring a deep-seated influence on the distribution of superposed deposits of thick coal (>1.4 m) in four Middle Pennsylvania (Desmoinesian Series) coal beds in three mining districts of west-central Indiana. Thick sandstone (>18 m) is common in areas between and around the mining districts, but less than 3 percent of the study area (consisting of 3200 km²) is underlain by both thick coal and thick sandstone. Only thick sandstone associated with the Survant Coal Member (Linton Formation), and informally referred to by us “Survant sandstone”, exists in all of the thin-coal areas. After comparison with published maps by other authors, it is inferred that distribution of the Survant sandstone, which was deposited immediately after a long period of slow deposition associated with the Colchester Coal Member (Linton Formation), may reflect topographic expression of long-term subsidence associated with differential thinning of much deeper Silurian strata (580 m below).Although the findings of this study provide the basis for a conceptual geologic model with a hypothetical structure that is amenable to statistical testing, such analysis should be undertaken only after the data are analyzed for randomness, spatial autocorrelation, linearity and normality.     

Regional reconnaissance exploration rock geochemistry for massive sulphides, New Brunswick, Canada

In the Bathurst District of New Brunswick there are more than 50 known occurrences of base metal sulphide mineralization within an area of Palaeozoic volcanic-sedimentary rocks approximately bounded by the Rocky Turn deposit in the north, the Key Anacon deposit in the east, the Heath Steele deposit in the south, and the Devil's Elbow deposit in the west. Only four of these occurrences are, or have been, producing mines; 19 are classed as “major occurrences”. The area is highly prospective for massive sulphide deposits of the Brunswick Mining and Smelting and Heath Steele type; it would obviously be of considerable importance to define the zones within the sequence where major occurrences should be sought.To determine whether exploration rock geochemistry could be used on a regional reconnaissance scale, 419 samples of rhyolite from an area of 2000 km² (at an average density of one sample per 5 km²) were analyzed for total content of Cu, Pb, Zn, Ca, Mg, K, Na, Fe, and Mn. The data were processed by calculating the geometric mean of all samples in cells of approximately 10 km². Contrary to the relations documented on a mine scale (within one kilometre of major deposits), where the clearest halos are given by major elements, it is the ore elements that give the best regional patterns.The producing mines and the most important of the known occurrences all lie in zones where rhyolite contains less than 10 ppm Cu. Element ratios considerably enhance anomalous relations. The Zn:Pb ratio of the sulphides in the main deposits is 2.4–2.8, regardless of grade. It is demonstrated that all present and past producing mines and the most important known major occurrences lie within well-defined zones of Zn:Pb ratios of 2.4–2.8. Similarly, zones where the Pb:Cu ratio is > 3.0 and the Zn:Cu ratio is > 7.0 also define the most important deposits. These ore-element relations derived from a low sample-density survey define priority zones for detailed exploration for significant major massive sulphide deposits.     

U-Pb ages of detrital and volcanic zircons of the Toro Negro Formation,northwestern Argentina: Age,provenance and sedimentation rates

The Toro Negro Formation is a foreland sequence in western La Rioja province, Argentina, which records the late-stage tectonic evolution of the Vinchina Basin. Together with the underlying Vinchina Formation, these two units represent one of the thickest and longest continually exposed foreland sections in northwest Argentina. The Vinchina basin is uniquely situated between the Toro Negro and Umango blocks of the Western Sierra Pampeanas to the north and south, the Precordillera to the west, and the Sierra de Famatina to the east. New U-Pb dating of volcanic tephra provides improved age constraints on the pace of sedimentation, and U-Pb ages of detrital zircons serve to strengthen existing provenance interpretations. We show that deposition of the Toro Negro Formation spans roughly 6.9 to 2.3 Ma: Late Miocene to Early Pleistocene. A high-relief, erosional unconformity with the underlying Vinchina Formation developed sometime between 9.3 and 6.9 Ma, although stratigraphic considerations suggest it spanned only the later part of this time interval (perhaps 7.5–6.9 Ma). Above this unconformity, undecompacted sedimentation rates are remarkably high at ∼1.2 mm/yr, slowing to ∼0.3 mm/yr after ∼6 Ma. An unconformity in the upper part of the section is constrained to occur sometime between 5.0 and 3.0 Ma, probably beginning not long after 5.0 Ma. The timing of both unconformities broadly Matches the timing of inferred tectonic events in the Sierra Famatina ∼50 km to the east, the Fiambalá basin to the north, and the Bermejo basin to the south, suggesting they May record regional tectonism at these times. Provenance interpretations of detrital zircon spectra are consistent with previous interpretations based on sediment petrography. They show that provenance did not change significantly during the course of Toro Negro deposition, precluding major tectonically-induced drainage reorganization events. Sediments were derived primarily from the north (Toro Negro Block) and west (Precordillera). The data are consistent with a subtle increase in sediment supply from the Precordillera beginning around 6.5 Ma.     

The use of “loam” concentrates in geochemical exploration in deeply weathered arid terrains

This paper reviews some aspects of the use of “loam” (soil) concentrates in geochemical surveys in arid, deeply weathered environments.An orientation survey at a small Ni-Cu-Co prospect in Western Australia has shown that discrimination between mineralized and unmineralized samples could be achieved using Ni, Cu, Co, Cr, Zn, As, Sn, Sc, Ti, Yb and Y in the coarse fraction of heavy concentrates. However, at the same prospect the best contrast for Ni, Cu and Co in surface samples was provided by analysis of the same fraction following a cold ammonium citrate/hydroxylamine hydrochloride digestion.At a nearby, larger prospect, some 54 km² in area, concentrates were separated, by jigging, from bulk soil samples, themselves composites of representative subsamples. Sampling at a density of 4 samples per km² revealed 1–2 km² size anomalies of Cu, Ni, Co, Cr, As and Au which could be related, variously, to known Ni-Cu and Au mineralization.In Botswana, analysis of concentrates, separated by tabling from samples collected at a density of 1 sample per 7.5 km² over an area of 5400 km², identified distinctive geochemical districts. Enhanced values of Au and of Cu-Ni in the concentrates were relatable to known mineralization and the results suggested that there were also Sn-W-Mo-Bi (granitoid) and Au-Pb-Zn-Bi-Sn (volcanogenic) associations which could lead to new prospecting targets. Anomalies of certain elements (for example, Cu in an ultramafic environment) may be more readily detected in surface material by “enrichment indexing” the concentrate data.     

Crustal structure of the Ruby Mountains and southern Carlin Trend region, Nevada, from magnetotelluric data

We have collected about 150 magnetotelluric (MT) soundings in northeastern Nevada in the region of the Ruby Mountains metamorphic core complex uplift and southern Carlin mineral trend, in an effort to illuminate controls on core complex evolution and deposition of world-class gold deposits. The region has experienced a broad range of tectonic events including several periods of compressional and extensional deformation, which have contributed to the total expression of electrical resistivity. Most of the soundings reside in three east–west profiles across increasing degrees of core uplift to the north (Bald Mountain, Harrison Pass, and Secret Pass latitudes). One short cross-line was also taken to assess an east–west structure to the north of the northern profile. Model resistivity cross-sections were derived from the MT data using a 2-D inversion algorithm, which damps departures of model parameters from an a priori structure. Geological interpretation of the resistivity combines previous seismic, potential field and isotope models, structural and petrological models for regional compression and extension, and detailed structural/stratigraphic interpretations incorporating drilling for petroleum and mineral exploration. To first order, the resistivity structure is one of a moderately conductive, Phanerozoic sedimentary section fundamentally disrupted by intrusion and uplift of resistive crystalline rocks. Late Devonian and early Mississippian shales of the Pilot and Chainman Formations together form an important conductive marker sequence in the stratigraphy and show pronounced increases in conductance (conductivity–thickness product) from east to west. These increases are attributed to graphitization caused by Elko–Sevier era compressional shear deformation and possibly by intrusive heating. The resistive crystalline central massifs adjoin the host stratigraphy across crustal-scale, steeply dipping fault zones. The zones provide pathways to the lower crust for heterogeneous, upper crustal induced, electric current flow. Resistive core complex crust appears steeply bounded under the middle of the neighboring grabens and not to deepen at a shallow angle to arbitrary distances to the west. The numerous crustal breaks imaged with MT may contribute to the low effective elastic thickness (T_e) estimated regionally for the Great Basin and exemplify the mid-crustal, steeply dipping slip zones in which major earthquakes nucleate. An east–west oriented conductor in the crystalline upper crust spans the East Humboldt Range and northern Ruby Mountains. The conductor may be related to nearby graphitic metasediments, with possible alteration by middle Tertiary magmatism. Lower crustal resistivity everywhere under the profiles is low and appears quasi one-dimensional. It is consistent with a low rock porosity (<1 vol.%) containing hypersaline brines and possible water-undersaturated crustal melts, residual to the mostly Miocene regional extension. The resistivity expression of the southern Carlin Trend (CT) in the Pinon Range is not a simple lineament but rather a family of structures attributed to Eocene intrusion, stratal deformation, and alteration/graphitization. Substantial reactivation or overprinting by core complex uplift or Basin–Range extensional events seems likely. We concur with others that the Carlin Trend may result in part from overlap of the large Eocene Northeast Nevada Volcanic Field with Precambrian–Paleozoic deep-water clastic source rocks thickening abruptly to the west of the Pinon Range, and projecting to the north–northwest.     

Archean sea-floor hydrothermal systems: The third dimension

Mafic to felsic predominantly marine volcanic members on the west flank of the major volcanic vent of the relatively unmetamorphosed and undeformed Archean upper Blake River Group of the Noranda area were sampled at approximately 100 m centres in a 100 km² area for whole-rock analysis as part of an integrated exploration program during 1977–1980. Automatic processing of the resulting approximately 2000 analyses yielded not only the expected improved definition of primary rock types but also synvolcanic alteration patterns of varying intensity. Essentially two-dimensional sea floor “weathering” on paleo-bedding surfaces and the more fully three-dimensional, hydrothermal, volcanogenic, footwall alteration systems were discovered. The data, when integrated with existing drill and mining information provide a unique insight into the hidden shape of the sub-sea-floor plumbing of the recently discovered active hydrothermal, biologic systems observed in two dimensions at crustal spreading centres on today's ocean floor.Polarized compositional gradients observed within the footwall alteration patterns are interpreted to be potent exploration guides to proximal, polymetallic, sulphide facies exhalite deposits and their associated “stringer” zones.