High resolution seafloor images in the Gulf of Cadiz, Iberian margin

In the Gulf of Cadiz, the hydrodynamic process acting on particle transport and deposition is a strong density-driven bottom current caused by the outflow of the saline deep Mediterranean water at the Strait of Gibraltar: the Mediterranean Outflow Water (MOW). New high resolution acoustic data including EM300 multibeam echo-sounder, deep-towed acoustic system SAR and very high resolution seismic, completed by piston cores collected during the CADISAR cruise allow to improve the understanding of the hydrodynamics of the MOW in the eastern part of the Gulf of Cadiz. Interpretation of data corrects the previous model established in this area and allows, for the first time, the accurate characterization of various bedforms and erosive structures along the MOW pathway and the precise identification of numerous gravity instabilities. The interaction between the MOW, the seafloor morphology and the Coriolis force is presently the driving force of the sedimentary distribution pattern observed on the Gulf of Cadiz continental slope.     

A predictive numerical model for potential mapping of the gas hydrate stability zone in the Gulf of Cadiz

This paper presents a computational model for mapping the regional 3D distribution in which seafloor gas hydrates would be stable, that is carried out in a Geographical Information System (GIS) environment. The construction of the model is comprised of three primary steps, namely: (1) the construction of surfaces for the various variables based on available 3D data (seafloor temperature, geothermal gradient and depth-pressure); (2) the calculation of the gas function equilibrium functions for the various hydrocarbon compositions reported from hydrate and sediment samples; and (3) the calculation of the thickness of the hydrate stability zone. The solution is based on a transcendental function, which is solved iteratively in a GIS environment.The model has been applied in the northernmost continental slope of the Gulf of Cadiz, an area where an abundant supply for hydrate formation, such as extensive hydrocarbon seeps, diapirs and fault structures, is combined with deep undercurrents and a complex seafloor morphology. In the Gulf of Cadiz, the model depicts the distribution of the base of the gas hydrate stability zone for both biogenic and thermogenic gas compositions, and explains the geometry and distribution of geological structures derived from gas venting in the Tasyo Field (Gulf of Cadiz) and the generation of BSR levels on the upper continental slope.     

Seismic crustal structure in the Gulf of Cadiz (SW Iberian Peninsula)

The sedimentary structure in the Gulf of Cadiz has been extensively studied by oil exploration companies. However, up to now little is known about its deep crustal structure. Moreover, the total thickness of the sedimentary layers remains unknown in large areas. The purpose of this paper is the crustal-scale interpretation of deep seismic near-vertical reflection and refraction/wide-angle reflection data obtained during the IAM (Iberian Atlantic Margins) project, carried out in 1993. Our results indicate that a continental type crust is underlying the entire Gulf of Cadiz, with progressive thinning from east to west. The sedimentary cover shows a great thickness, reaching 8 km in the center of the Gulf. Three main sedimentary units can be recognized: Jurassic-Cretaceous calcareous rocks, continuation of Algarve outcrops; the Allochthonous Units of Guadalquivir/Gulf of Cadiz, the offshore continuation of the inland Carmona nappe; and sub-horizontal post-Miocene marine sediments. The crystalline crust is divided into three main layers: the upper crust is characterized by P-wave velocity values of 5.7–6.1 km/s; the middle crust shows values of 6.3–6.4 km/s; the lower crust has a mean vertical velocity gradient of 0.02 km/s/km, with velocities between 6.9 to 7.1 km/s. The total crustal thickness varies from 27 km for the eastern part of the studied area, to 20 km for the westernmost part. The crustal thinning is more pronounced in a N-S direction than in an E-W direction. No major structures related with a defined Iberia-Africa plate boundary could be found. This revised version was published online in November 2006 with corrections to the Cover Date.     

Heat flow anomalies in the Gulf of Cadiz and off Cape San Vincente,Portugal

Heat flow anomalies provide critical information in active tectonic environments. The Gulf of Cadiz and adjacent areas are affected by the plate convergence between Africa and Europe, causing widespread deformation and faulting. Active thrust faults cause lateral movement and advection of heat that produces systematic variations in surface heat flow. In December 2003 new heat flow data were collected during the research vessel Sonne cruise SO175 in the Gulf of Cadiz over two sites of recent focused research activity: (i) the Gulf of Cadiz sedimentary prism and (ii) the Marques de Pombal escarpment. Both features have also been discussed as potential source areas of the Great Lisbon earthquake and tsunami of 1755. Background heat flow at the eastern terminus of the Horseshoe abyssal plain is about 52–59 mW/m². Over the Gulf of Cadiz prism, heat flow decreases from ∼57 mW/m² to unusually low values of 45 mW/m² roughly 120 km eastward. Such low values and the heat flow trend are typical for active thrusting, supporting the idea of an east-dipping thrust fault. Slip rates are 10 ± 5 mm per year, assuming that the fault dips at 2°. A fault dipping at 5°, however, would result into slip rates of 1.5–5 mm per year, suggesting that subduction has largely ceased. Based on seismic data, the Marques de Pombal fault is interpreted as part of an active fault system located ∼100 km westward of Cape San Vincente. Heat flow over the fault is affected by refraction of heat caused by the 1 km high escarpment. Thermal models suggest that the slip rate along the fault must either be small or shear stresses acting on the fault are rather high. With respect to other fault zones, however, it is reasonable to assume that the fault's slip rate is small.     

Trace metal composition of and accumulation rates of sediments in the Upper Gulf of Thailand

Sediment cores and grab samples were collected in the Upper Gulf of Thailand to determine sedimentation rates and to determine if metal concentrations reflect anthropogenic inputs.Accumulation rates of sediments in the Upper Gulf measured using the ²¹⁰Pb method, appear to vary from ca. 4 to 11 mm yr^?1. Sediment budgets suggest that little of the sediment delivered to the Upper Gulf by the major rivers is ultimately transported to the Lower Gulf. Metal concentrations in Upper Gulf sediments appear to be dominantly controlled by natural inputs.     

Seismic stacking pattern of the Faro-Albufeira contourite system (Gulf of Cadiz): a Quaternary record of paleoceanographic and tectonic influences

A Quaternary stratigraphic stacking pattern on the Faro-Albufeira drift system has been determined by analysing a dense network of high-resolution single-channel seismic reflection profiles. In the northern sector of the system an upslope migrating depositional sequence (elongate separated mounded drift) parallel to the margin has been observed associated with a flanking boundary channel (Alvarez Cabral moat) that depicts the zone of Mediterranean Outflow Water (MOW) acceleration and/or focussing. A consequent erosion along the right hand border and deposition on the left hand flank is produced in this sector. The sheeted aggrading drift is the basinward prolongation of the elongate separated mounded drift, and developed where the MOW is more widely spread out. The overall sheeted contourite system is separated into two sectors due to the Diego Cao deep. This is a recent erosional deep that has steep erosional walls cut into Quaternary sediments. Two major high-order depositional sequences have been recognised in the Quaternary sedimentary record, Q-I and Q-II, composed of eight minor high-order depositional sequences (from A to H). The same trend in every major and minor depositional sequence is observed, especially in the elongate mounded drift within Q-II formed of: A) Transparent units at the base; B) Smooth, parallel reflectors of moderate-high amplitude units in the upper part; and C) An erosional continuous surface of high amplitude on the top of reflective units. This cyclicity in the acoustic response most likely represents cyclic lithological changes showing coarsening- upward sequences. A total of ten minor units has been distinguished within Q-II where the more representative facies in volume are always the more reflective and are prograding upslope with respect to the transparent ones. There is an important change in the overall architectural stacking of the mounded contourite deposits from a more aggrading depositional sequence (Q-I) to a clear progradational body (Q-II). We suggest that Q-I and Q-II constitute high-order depositional sequences related to a 3rd-order cycle at 800 ky separated by the most prominent sea-level fall at the Mid Pleistocene Revolution (MPR), 900–920 ky ago. In more detail the major high-order depositional sequences (from A to H) can be associated with asymmetric 4th-order climatic and sea-level cycles. In the middle slope, the contourite system has a syn-tectonic development with diapiric intrusions and the Guadalquivir Bank uplift. This syn-tectonic evolution affected the overall southern sheeted drift from the A to F depositional sequences, but G and H are not affected. These last two depositional sequences are less affected by these structures with an aggrading stacking pattern that overlaps the older depositional sequences of the Guadalquivir Bank uplift and diapiric intrusions.     

北部湾东北部表层沉积物主微量元素空间分布特征

A multi-index analysis including grain size, major and trace elements is performed on the surface sediments from the northeastern Beibu Gulf to trace the sources of the sediments and to understand the controlling factors for elements distribution. The mean grain size exhibits a wide variation ranging from 0.09Φ to 8.05Φ with an average value of 5.33Φ. The average contents of major elements descend in an order of c(SiO_2)c(Al_2O_3)c(Fe_2O_3)c(CaO)c(MgO)c(K_2O)c(Na_2O)c(TiO_2)c(P_2O_5)c(MnO), while those of trace elements exhibit a descending order of c(Sr)c(Rb)c(V)c(Zn)c(Cr)c(Pb)c(Ni)c(Cu)c(As). On the basis of elementary distribution characteristics and statistical analyses, the study area is divided into the four zones: Zone I is located in the northeastern coastal area of the gulf, which receives large amount of fluvial materials from local rivers in Guangxi and Guangdong, China, and the Qiongzhou Strait; Zone Ⅱ is located in the center of the study area, where surface sediments exhibits a multiple source; Zone Ⅲ is located in the Qiongzhou Strait, where surface sediments are dominated by materials from the Zhujiang River and Hainan; Zone IV is located in the southwest of the study area, where surface sediments are mainly originated from the Red River and Hainan. The statistical analyses of sediment geochemical characteristics reveal that the grain size, which is mainly influenced by hydrodynamics and mineral composition of terrigenous materials, is the leading factor controlling the elementary distribution.Meanwhile, impacts from anthropogenic activities and marine biogenic process will also be taken into consideration.     

Molecular weight and chemical reactivity of dissolved trace metals (Cd,Cu, Ni) in surface waters from the Mississippi River to Gulf of Mexico

It is generally assumed that estuarine mixing is continuous for metals from terrestrial sources, gradually decreasing towards the open ocean endmember. Here we show that, chemical reactivity, determined by ion exchange method, and molecular weight distributions, obtained using cross-flow ultrafiltration, of dissolved Cd, Cu, and Ni in the surface waters of the Gulf of Mexico varied systematically across the estuarine mixing zone of the Mississippi River. Most size or chemical affinity fractions of dissolved metals (<0.4 μm) were linearly related to salinity (10.8–36.6), suggesting that the distribution of these elements was mainly controlled by continuous mixing processes. Dissolved concentrations across the salinity gradient ranged for Cd: 87–187 pM; Cu: 1.4–18.3 nM; and Ni: 2.6–18.8 nM, with highest values near the Mississippi river mouth, and lowest concentrations in a warm core ring in the Gulf of Mexico. Dissolved Cd was mostly present as a truly dissolved (<10 kDa, 97 ± 1%) and cationic fraction (Chelex-100 extractable, 94 ± 4%). A novel observation across the estuarine mixing zone was that colloidal metal concentrations were identical to either inert (for Cu, Ni) or AMPG-labile anionic (Cu, Cd) fractions. The difference in behavior between Cu and the other two metals might indicate differences in the biopolymeric nature of the metal–organic chelates. In particular, the anionic-organic Cd fractions accounted for just 3 ± 1%, on average. However, for Cu, it was 24 ± 4%, and for Ni, it was 9 ± 6%. The fractions of the total dissolved metal fractions that were “inert” averaged 31 ± 10% for Cu and 29 ± 12% for Ni. Small but noticeable amounts (6 ± 3%) of dissolved inert Cd fractions were also present. Apparent non-local transport processes, likely associated with cross-shelf sediment resuspension processes, could have been responsible for the relatively high concentrations of ‘inert’ and ‘anionic’ metal fractions in high salinity coastal waters, and accounting for the persistence of metals bound to humic substances in the Gulf of Mexico.     

Contourite drift construction influenced by capture of Mediterranean Outflow Water deep-sea current by the Portimão submarine canyon (Gulf of Cadiz, South Portugal)

The margin of the Gulf of Cadiz is swept by the deep current formed by the Mediterranean Outflow Water (MOW) flowing from the Mediterranean to the Atlantic. On the northern margin of the Gulf (Algarve Margin, South Portugal), the MOW intensity is low and fine-grained contourite drifts are built up with an alongslope development. From new sedimentological data, this study emphasizes the presence of two types of contourite drifts separated only by a deep submarine canyon incising the slope with a north-south orientation (Portimão Canyon). High-resolution seismic and bathymetry interpretation shows that on the eastern side of the canyon, the MOW forms a thick and large detached drift (Albufeira Drift) prograding toward both north and west, as shown in seismic profiles, with a high sedimentation rate. On this side of the canyon, the MOW intensity is high enough to erode the slope forming a moat channel (Alvarez Cabral). On the western side of Portimão Canyon, the MOW energy is lower, preventing moat channel erosion. Only flat and thin drift develops (Portimão and Lagos Drifts) with slow aggradation and a low sedimentation rate. This difference in drift development is due to the presence of the canyon which generates an important change in hydrodynamic of the MOW, confirmed by temperature-density measurements showing that MOW flows down Portimão Canyon. The canyon is responsible for the deviation of the direction of the MOW as it partly catches the deep-sea current flowing westward (i.e. capture phenomenon). It creates, thus, a decrease of the flow energy, competency and capacity between the east and west sides of the canyon. Through this phenomenon of MOW deep-sea current capture, the canyon constitutes a morphologic feature generating an important change in the contourite deposition pattern.In addition to already known climatic and oceanographic influences, our results show the role of canyons on contourite drift building. This study provides new elements on autocyclic factors influencing the contourite sedimentation, which are important to consider in future sedimentary paleo-reconstruction interpretations.     

Reconstructions of the Mediterranean Outflow Water during the quaternary based on the study of changes in buried mounded drift stacking pattern in the Gulf of Cadiz

Contourite deposits in the central sector of the middle slope of the Gulf of Cadiz have been studied using a comprehensive acoustic, seismic and core database. Buried, mounded, elongated and separated drifts developed under the influence of the lower core of the Mediterranean Outflow Water are preserved in the sedimentary record. These are characterised by depositional features in an area where strong tectonic and erosive processes are now dominant. The general stacking pattern of the depositional system is mainly influenced by climatic changes through the Quaternary, whereas changes in the depositional style observed in two, buried, mounded drifts, the Guadalquivir and Huelva Drifts, are evidence of a tectonic control. In the western Guadalquivir Drift, the onset of the sheeted drift construction (aggrading QII unit) above a mounded drift (prograding QI unit) resulted from a new Lower Mediterranean Core Water hydrodynamic regime. This change is correlated with a tectonic event coeval with the Mid Pleistocene Revolution (MPR) discontinuity that produced new irregularities of the seafloor during the Mid- to Late-Pleistocene. Changes in the Huelva Drift from a mounded to a sheeted drift geometry during the Late-Pleistocene, and from a prograding drift (QI and most part of QII) to an aggrading one (upper seismic unit of QII), highlight a new change in oceanographic conditions. This depositional and then oceanographic change is associated with a tectonic event, coeval with the Marine Isotope Stage (MIS) 6 discontinuity, in which a redistribution of the diapiric ridges led to the development of new local gateways, three principal branches of the Mediterranean Lower Core Water, and associated contourite channels. As a result, these buried contourite drifts hold a key palaeoceanographic record of the evolution of Mediterranean Lower Core Water, influenced by both neotectonic activity and climatic changes during the Quaternary. This study is an example of how contourite deposits and erosive elements in the marine environment can provide evidence for the reconstruction of palaeoceanographic and recent tectonic changes.     

Analysis of the spatial and temporal distributions of ecological variables and the nutrient budget in the Beibu Gulf

Based on a hydrodynamic-ecological model, the temperature, salinity, current, phytoplankton(Chl a),zooplankton, and nutrient(dissolved inorganic nitrogen, DIN, and dissolved inorganic phosphorous, DIP)distributions in the Beibu Gulf were simulated and the nutrient budget of 2015 was quantitatively analyzed. The simulated results show that interface processes and monsoons significantly influence the ecological processes in the gulf. The concentrations of DIN, DIP, phytoplankton and zooplankton are generally higher in the eastern and northern gulf than that in the western and southern gulf. The key regions affected by ecological processes are the Qiongzhou Strait in winter and autumn and the estuaries along the Guangxi coast and the Red River in summer.In most of the studied domains, biochemical processes contribute more to the nutrient budget than do physical processes, and the DIN and DIP increase over the year. Phytoplankton plays an important role in the nutrient budget; phytoplankton photosynthetic uptake is the nutrient sink, phytoplankton dead cellular release is the largest source of DIN, and phytoplankton respiration is the largest source of DIP. The nutrient flux in the connected sections of the Beibu Gulf and open South China Sea(SCS) inflows from the east and outflows to the south. There are 113 709 t of DIN and 5 277 t of DIP imported from the open SCS to the gulf year-around.     

Metal fluxes through the Strait of Gibraltar: the influence of the Tinto and Odiel rivers (SW Spain)

A large set of new data concerning dissolved metal concentrations has been acquired in the Gulf of Cadiz and in the Strait of Gibraltar from 1996 to 1999. These data, associated with models (hydrodynamic, tracer advection–dispersion and mixing), have been used to assess the influence of rivers draining the South Iberian Pyrite Belt on the Gulf of Cadiz and on the Atlantic inflow in the Strait of Gibraltar.Metal concentrations in surface waters from the Gulf of Cadiz are maximal near the mouth of the Tinto/Odiel rivers with values exceeding 50 nmol/kg (Mn), 5 nmol/kg (Ni), 30 nmol/kg (Cu), 100 nmol/kg (Zn), 0.9 nmol/kg (Cd) and 45 nmol/kg (As). From the Tinto/Odiel river, a plume of contamination follows the coast in the direction of the Strait of Gibraltar. The computation of a tracer advection–dispersion model confirms that the coastal currents carry the metals discharged from the Tinto and Odiel to the Strait of Gibraltar.From temperature–salinity and metal–salinity plots, four water masses can be recognised in the Gulf of Cadiz and in the Strait of Gibraltar: North Atlantic Surface Water (NASW), North Atlantic Central Water (NACW) and metal-enriched Spanish Shelf Waters from the Gulf of Cadiz (SSW). The Mediterranean Outflow Water (MOW) is also clearly seen at depths greater than 300 m.The chemical characteristics of these various water masses have been used in a mixing model to evaluate their relative contribution to the Atlantic inflow through the Strait of Gibraltar. These contributions are seasonally variable. In June 1997, the contribution was: 80±20%, 5±5% and 15±10% for NASW, NACW and SSW, respectively. In September, the SSW contribution was apparently negligible.Finally, these relative contributions allow the evaluation of the metal fluxes in the Strait of Gibraltar. The presence of SSW in the Strait increases the metal flux to the Mediterranean Sea by a factor of 2.3 (Cu), 2.4 (Cd), 3 (Zn) and 7 (Mn). It does not modify significantly As and Ni fluxes.     

渤海湾天津近岸海域水环境空间变异分析

由于海岸带的地理条件和海洋动力特性的复杂性以及人类开发活动对海岸带的影响,近岸海域的生态环境系统在空间分布上有很大的变异性.基于现场实测资料,建立系统的空间变异分析模型,对海岸带生态环境空间变化规律进行分析,可以充分了解不同区域的污染特征和变化趋势.应用所构建的空间变异分析模型对渤海湾天津近岸海域的水环境特性进行分析,结合对应年份的入海流量及其变化,分析了天津渤海湾海岸带污染的主因子和区域水环境的分布特征,结果可以对海洋功能区的划分和水环境综合评价结果进行验证和补充.     

墨西哥湾陆坡区冷泉碳酸盐岩的烷烃分布特征

对墨西哥湾北部水深2200m的Alaminos Canyon645区块（AC645区）和水深540m的Green Canyon185区块（GC185区）冷泉碳酸盐岩的有机质进行了研究,结果显示深水和浅水区冷泉碳酸盐岩的有机质丰度和烷烃组成差别较大,下陆坡深水AC区样品有机质含量低,正构烷烃、萜烷、甾烷各组分的含量相对较高,正构烷烃以低碳数占绝对优势,并含有种类丰富的三环萜烷和五环三萜烷,且以17a（H）,21B（H）-藿烷为主峰碳,反映了深水区冷泉碳酸盐岩的有机质来源于细菌和低等藻类,有少量的深部油气藏有机质的渗漏输入,并受微弱的微生物作用改造。上陆坡浅水GC区样品有机质含量较高,其中正构烷烃含量较低,并且以难以分开的复杂混合物（UCM）为主,同样含有种类丰富的以17α（H）,21β（H）-降藿烷为主峰碳的三环萜烷和五环三萜烷,表明有机质主要来源于深部油气藏渗漏的有机质,并遭受了强烈的微生物降解。本文系统地研究了冷泉碳酸盐岩中正构烷烃、萜烷、甾烷的组成和分布特征,并探讨了有机质来源和冷泉渗漏的关系。     

Surface chlorophyll-a dynamics in the upper Gulf of Thailand revealed by a coupled hydrodynamic-ecosystem model

Although plankton bloom incidents in the upper Gulf of Thailand (UGoT) have been reported, no dynamic investigation of the phenomenon has been conducted. To address this need, a simple pelagic ecosystem model coupled with the Princeton Ocean Model (POM) was employed to investigate seasonal variations in surface chlorophyll-a (chl-a) distributions to clarify phytoplankton dynamics in this area. The results revealed patterns of seasonal chl-a distribution that correspond to local wind, water movement and river discharge. High chl-a patchiness was found to be concentrated near the western coast following westward circulation near the northern coast developed during the northeast monsoon. During the southwest monsoon high concentrations were observed around the northeastern coast due to eastward flow. The simulated results could explain the seasonal shifting of phytoplankton blooms, which typically arise along the western and eastern coasts during the northeast and the southwest monsoons, respectively. Sensitivity analyses of simulated chl-a distributions demonstrate that water stability, including wind-induced vertical currents and mixing, plays significant roles in controlling phytoplankton growth. Nutrients in the water column will not stimulate strong plankton blooms unless upwelling develops or vertical diffusivity is low. This finding suggests an alternative aspect of the mechanism of phytoplankton bloom in this region.     

Trace metal composition of colloidal organic material in marine environments

Marine colloidal material (1 kDa–0.2 μm) was isolated by cross-flow ultrafiltration followed by diafiltration and freeze-drying from surface waters of the Gulf of Mexico and the Middle Atlantic Bight (MAB), as well as from estuarine waters of Galveston Bay. Elemental characterization of isolated colloidal material included organic carbon (OC) and selected trace metal (Cu, Pb, Zn, Cd, Co, Ni, Cr, Be, Fe, Al, Mn, V, Ba, and Ti) determinations. It was found that levels of these metals in marine colloids ranged from <0.1 to 50 μg/g colloidal matter, except for Fe which generally had a concentration >120 μg/g. Most metals (Cu, Pb, Zn, Ni, Al, Mn, V, and Ti) had an average concentration >1 μg/g while concentrations of Cd, Co and Be were usually <1 μg/g. Metal concentrations (μg/g) in isolated colloids were, in general, higher in Galveston Bay than in the Gulf of Mexico, suggesting either high abundance of trace metals in estuarine waters or differences in organic matter composition. Higher colloidal metal concentrations in the MAB than in the Gulf of Mexico might be due to higher terrestrial inputs in the MAB. Colloidal metal concentrations (μg/g) were generally lower than those in average soils, continental crust and suspended particles. However, metal/aluminum ratios (Me/Al) in isolated marine colloids were significantly higher than those for average soils and continental crust. Most importantly, colloids had a metal composition and metal/OC ratio (Me/C) similar to humic substances and marine plankton, suggesting that marine colloids largely originate from planktonic sources and are composed of predominately organic components. The Me/C ratios of Galveston Bay colloids followed the sequence of Cu>Ni, Cr, Zn>Mn>Co>Pb, Cd, which is similar to the Irving–Williams order except for Mn, suggesting that the interaction of metals with marine colloids is determined by the affinity of metals for specific organic ligands.     

Nutrient fluxes from deep sediment support nutrient budget in the oligotrophic waters of the Gulf of Aqaba

The role of deep sediment in supporting nutrient budget in the Gulf of Aqaba has been investigated by estimating the flux of inorganic nitrogen, phosphate and silicate. Fluxes were calculated directly by pore water profiles and indirectly by chamber incubations carried out onboard the RV Meteor cruise. The results showed that maximum potential fluxes calculated by chamber incubations were higher than those calculated by porewater profiles for all nutrients (6.4–28.5 fold). This has been attributed to the additional flux due to bioturbation and flux from advective porewater exchange in the case of chamber incubation, while porewater fluxes represent diffusive ones. Using a rough estimation considering flux results in addition to the sediment area and water mass of the Gulf of Aqaba, we estimate that 3.3 × 10⁵, 6.4 × 10⁴ and 6.5 × 10⁶ kg year⁻¹ of inorganic nitrogen, phosphate and silicate respectively are effused from deep sediments to the water column. This quanitity would certainly support the primary productivity in the oligotrophic water in the Gulf of Aqaba.     

A Study on Residual Flow in the Gulf of Tongking

On the basis of observations of water temperature, salinity and wind during winter (December to following February) and summer (June to August) in the Gulf of Tongking, a robust diagnostic three-dimensional model has established that reveals the seasonal variation in residual flow, including wind-driven current, density-driven current and tide-induced residual current. It is shown that in the Gulf of Tongking the wind-driven current plays the most important role in the seasonal variation of residual flow field. Due to strong NE monsoon (9 m/s) during winter the residual flow (reaches 30 cm/s) is stronger than that in summer. At the surface the residual flow direction during winter is basically westward or southwestward, while during summer it is almost reversed.     

因子克里格分析支持的重金属元素空间多尺度变化特征——以北部湾东北部海域为例

将因子克里格分析方法应用于海底沉积物重金属元素空间多尺度变化的研究中,分析了北部湾东北部表层沉积物中7种重金属元素,Ni、Cu、Zn、Pb、Cr、As和Cd的空间多尺度结构特征,识别并分离了重金属元素不同尺度的空间变化,并探讨了各个尺度上重金属的物源及控制因素。结果显示,研究区重金属存在块金效应、变程为30km的球状结构(短变程尺度)和变程为140km的球状结构(长变程尺度)等三种尺度的空间结构,并拟合了研究区7种重金属元素的线性协同区域化模型。短变程尺度上,7种重金属元素的空间分布表现为"点状"或"条带状"的局部尺度的空间变化特征;长变程尺度上,7种重金属元素的空间分布反映出"片状"的区域尺度的空间变化特征。局部尺度上,Zn、Cr、Ni、Cu、Pb和Cd等元素主要源于海南岛、雷州半岛、广西大陆等陆地母岩物质,其空间分布特征受到了沉积物粒度的控制作用;而As主要受到海南岛、雷州半岛的人为污染成分的影响。区域尺度上,Zn、Cr、Ni和Cu主要来源于雷州半岛、海南岛的母岩物质,其次为广西大陆;As主要来源于海南岛的母岩物质,其次为雷州半岛、广西大陆。这些重金属元素在北部湾终年逆时针大环流的控制下,进行搬运、迁移并沉积在"汇聚中心",形成了研究区重金属元素区域尺度上NWW-NNW向的分布格局;而As不同于其他元素的亲陆的NNW向分布特征,主要源于其不同的地球化学行为。