萤石Sr、Nd同位素地球化学研究评述

本文通过大量实例综述了近年萤石Sr、Nd同位素在定年和示踪方面取得的进展，结果表明：萤石Sm－Nd同位素可以用于测定成矿作用的时代，但由于萤石Nd同位素初始值存在不均一性和受次生干扰的影响，所获数据最好用其它测年方法获得的数据加以验证；萤石Sr、Nd同位素组成是示踪成矿流体来源的有效方法，利用Sr、Nd同位素组成还可定量估算出形成成矿流体不同端元所占的比例。     

西天山前寒武纪天窗花岗片麻岩的锆石U—Pb年龄及Nd—Sr同位素特征

采用颗粒级锆石Ｕ－Ｐｂ定年方法,精确测定了西天山前寒武纪天窗花岗片麻岩的结晶锆石年龄为７９８Ｍａ,它代表了花岗质岩浆的结晶时代。花岗片麻岩具有较高的ＩＡＳ值（１．１７￣１．５５）和ＬＩＬＥ、ＬＲＥＥ含量,明显的Ｅｕ负异常（δＥｕ＝０．２４－０．３８）和Ｂａ、Ｓｒ、ｐ、Ｔｉ、Ｎｂ、Ｔａ的亏损,表明源岩为成熟度很高的陆壳物质。其负的εＮｄ（ｔ）值（－４．４￣－６．４）和较高的初始＾８７Ｓｒ／＾８６Ｓｒ     

苏北东海地区片麻岩的Nd—Sr同位素定年及其地质意义

苏北驼峰、牛山片麻岩的原岩是造山后拉张环境下形成的碱性花岗岩。其全岩Rb -Sr等时线法地质年龄为(80 4 8± 0 39)Ma、(797 7± 1 5 )Ma ,此值代表原岩的形成年龄 ,表明苏胶造山带于新元古代中期 (距今 80 0Ma± )已开始向裂解转化。由此推断碰撞造山运动应发生于新元古代早期 (距今 10 0 0Ma～ 90 0Ma)。其时代可与北美格林威尔造山带相当 ,应是Rodinia超大陆汇聚和裂解的组成部分。此外 ,其Nd模式年龄为 186 9Ma～ 1915Ma、1417Ma～ 144 0Ma ,揭示物质来源于前中元古代地壳重熔岩浆与上地幔物质的不同比例混合。     

Sr,Nd,Pb Isotope Geochemistry and Magma Evolution of the Potassic Volcanic Rocks,Wudalianchi,Northeast China

Wudalianchi volcanic rocks are the most typical Cenozoic potassic volcanic rocks in easten China.Compositional comparisons between whole rocks and glasses of various occurrences indicate that the magma tends to become rich in silica and alkalis as a result of crystal differentiation in the course of evolu-tion.They are unique in isotopic composition with more radiogenic Sr but less radiogenic Pb.^87Sr/^86Sr is higher and ^143Nd/^144Nd is lower than the undifferentiated global values.In comparison to continental pot-ash volcanic rocks,Pb isotopes are apparently lower.These various threads of evidence indicate that the rocks were derived from a primary enriched mantle which had not been subjected to reworking and shows no sign of incorporation of crustal material.The correlation between Pb and Sr suggests the regional heterogeneity in the upper mantle in terms of chemical composition.     

大别山地壳结构的Pb同位素地球化学示踪

研究了大别山东部北大别变质杂岩，南大别变质杂岩和白垩纪花岗岩的全岩Pb同位素组成，结果表明，北大别变质杂岩与南大别变质杂岩相比，前者以相对低放射成因Pb同位素组成为特征，按照Pb同位素组成在地壳垂向剖面上的变化模型，指出在大别山地壳垂向结构上，北大别变质杂岩应位于南大别变质杂岩之下，这一认识得到大别山不同构造岩石单元中产出的白垩纪花岗岩Pb同位素对岩浆源区示踪的有力支持，因此南大别超高压变质带是发育在北大别杂岩之上的一个构造岩片，这对进一步确定扬子克拉通向华北克拉通俯冲－碰撞的缝合线位置具有重要意义。     

大别造山带白马尖花岗岩体的钕，锶同位素地球化学研究

大别造山带白马尖花岗岩体属燕山期侵入岩，为中生代大别山区岩浆活动的产物，为碰撞后花岗岩，锶，钕，同位素数据及稀土元素数据表明，白马尖花岗岩体为壳幔混合型，1．2－1．7Ga的钕模式年龄为其源岩的平均地壳存留年龄，北大别花岗岩类岩石的物质来源并不一致。     

大别山麻粒岩包体的氧同位素研究

对北大别变质杂岩中的麻粒岩包体进行详细的氧同位素地球化学研究,发现其全岩δ~(18)O值偏低,为3.3‰～4.4‰。在麻粒岩相变质条件下,大别山麻粒岩包体的共存矿物对之间达到并保存了氧同位素平衡,后期退变质作用未明显破坏这种平衡。由矿物氧同位素地质测温得到的顶峰变质温度800～875C,与一般麻粒岩相变质温度相吻合。在变质作用之前或顶峰变质作用过程中,大别山麻粒岩包体的原岩曾与一δ~(18)O值低于3‰的外来流体发生了高温水—岩交换作用,并且这种交换作用在一定范围内是相对均一的。     

Trace Elements and Sr, Nd Isotope Geochemistry of the Lajimiao Norite-Gabbro from the North Qinling Belt

The Lajimiao norite-gabbro complex, as a part of the ophiolites on the southern side of the North Qinling belt, consists of gabbro and norite-gabbro. They were derived from different magma series: the gabbro was derived from tholeiitic magma series with higher TiO2, REE abundance and Fe3+/Fe2+ ratio ; norite-gabbro was derived from calc-alkali magma series with lower TiO2, Fe3+/Fe2+ ratio and REE abundance and much lower HREE abundance, which suggests that the source of the norite-gabbro magma was deeper and controlled by eclogite facies. Geochemical characteristics of both plutonic rocks are similar to those of island-arc basalts, such as relatively high contents of Ba, Pb and Sr and relatively low contents of Nb, Zr and N j.The Sr, Nd isotopic characteristics of the Lajimiao norite-gabbro complex are similar to those of ophiolites. Its εNd values are constant, about+2; whereas εst values have wide variation from - 6.4 to +31.2 and positively correlate with Na2O, H2O+ and CO2 contents and the Fe3+/Fe     

Trace Elements and Sr,Nd Isotope Geochemistry of the Lajimiao Norite-Gabbro from the North Qinling Belt1

Abstract The Lajimiao norite-gabbro complex, as a part of the ophiolites on the southern side of the North Qinling belt, consists of gabbro and norite-gabbro. They were derived from different magma series: the gabbro was derived from tholeiitic magma series with higher TiO₂, REE abundance and Fe³⁺ / Fe²⁺ ratio; norite-gabbro was derived from calc-alkali magma series with lower TiO₂, Fe³⁺ / Fe²⁺ ratio and REE abundance and much lower HREE abundance, which suggests that the source of the norite-gabbro magma was deeper and controlled by eclogite facies. Geochemical characteristics of both plutonic rocks are similar to those of island-arc basalts, such as relatively high contents of Ba, Pb and Sr and relatively low contents of Nb, Zr and Ni. The Sr, Nd isotopic characteristics of the Lajimiao norite-gabbro complex are similar to those of ophiolites. Its 8_Nd values are constant, about +2; whereas 8_Sr values have wide variation from — 6.4 to +31.2 and positively correlate with Na₂O, H₂O⁺ and CO₂ contents and the Fe³⁺ / Fe²⁺ ratio. The ?_Nd—Nd / Th, ?_Nd—La/Nb and ?_Nd—Ba/Nb diagrams clearly show that there were significant components of terrigenous sediments in the mantle source of the Lajimiao norite-gabbro complex. It suggests that large amount of sediments had been carried into the mantle by the subducted ancient Qinling sea plate during the Palaeozoic.     

汉诺坝玄武岩中地幔岩捕掳体REE和Sr,Nd同位素地球化学

本文报道汉诺坝玄武岩中地幔岩捕掳体的ＲＥＥ丰度和Ｓｒ、Ｎｄ同位素组成。不同岩石类型的ＲＥＥ配分模式和同位素组成反映地幔部分熔融程度和交代作用过程。二辉橄榄岩亏损轻稀土,是原始地幔经不同程度部分熔融的残留体。方辉橄榄岩具Ｕ型ＲＥＥ配分模式,是强烈亏损的地幔岩被熔体非化学平衡交代的结果。二辉岩脉状体富轻、中稀土,它同与脉状体接触的二辉橄榄岩可达化学平衡或近于化学平衡,而二辉岩脉状体的形成与玄武岩岩浆无成因关系。据对二辉岩脉状体和不含脉状体橄榄岩的Ｓｍ－Ｎｄ同位素定年,这种脉状体形成于３００Ｍａ左右。     

Geochronological Study of Caledonian Granulite and High-Pressure Gneiss in the Dabie Mountains

Using the single-zircon evaporation technique and U-Pb method, the authors have conducted an isotope geochonological study of the Huilanshan granulite and Shima garnet-bearing plagioclase gneiss (" country rocks" of the Shima eclogite) in the Dabie Mountains. The study shows that these rocks have peak metamorphic ages of 443-455 Ma, which are essentially consistent with that of the Caledonian high-ultrahigh pressure eclogites. This indicates the existence of the Caledonian collisional orogeny in the Dabie Mountains.     

Geochemical Characteristics and Genesis of the Granitic Gneisses from the Southeastern Dabie Mountains

The granitic gneisses from the ultrahigh-pressure (UHP) metamorphic terrain of the southeastern Dabie Mountains encompass two types: monzonitic granitic gneiss and alkali-feldspar granitic gneiss, which are characterized by rich alkalis, poor CaO, high FeO/MgO, particularly high Ba, Rb, Th, Ta, REE (except Eu), Ga, Nb and Zn, and low Sr, Eu, Cr, Co and Ni. The gneisses, particularly the alkali-feldspar granitic gneiss, have typical chemical characteristics of A-type granites. They resulted from partial melting of crustal materials existing in the rift zone along the northern margin of the South China block during the Neoproterozoic. These gneisses might not have undergone UHP metamorphism during the late Triassic, but were involved into UHP rocks by the tectonic mixing process and kept the exhumation message of the UHP rocks from the middle and upper crust.     

大别山北部漫水河灰色片麻岩的锆石UPb年龄及其地质意义

北大别杂岩主要由灰色片麻岩和斜长解闪岩组成。通过对大别山北部霍山漫水河花岗闪长片麻岩的锆石U-Pb年龄测定，得到中元古代、早三叠世和晚侏罗世3组年龄数据。中元古代的年龄老于灰色片麻岩集中在新元古代的锆石U-Pb上交点年龄，指示漫水河北部片麻岩中有古老锆石捕掳晶；早三叠世年龄指示该片麻岩中有印支期变质作用形成的锆石；晚侏罗世年龄表明灰色片麻岩中有燕山早期形成的岩浆锆石。根据北大别杂岩的构造背景、变质作用及地球化学特征，认为北大别杂岩中的部分灰色片麻岩形成于燕山早期的花岗闪长岩，它们可能源自或混染了经过早三叠世变质作用的扬子陆块俯冲基底。本文的结果表明，北大别杂岩既不是形成于白垩纪的岩浆杂岩，也不完全是形成于新元古代的TTG岩系，其中的部分灰色片麻岩为形成于燕山早期的花岗闪长岩，即在白垩纪大规模岩浆作用前的燕山早期，北大别曾有过一次岩浆作用。     

中国北方中生代富碱侵入岩钕、锶、铅同位素特征及其意义

本文根据作者近些年来对中国北方中生代富碱侵入岩钕、锶、铅同位素研究并结合前人工作得出 :在华北地台区富碱侵入岩的εNd(t)均为负值 ;而兴蒙地槽区的εNd(t)则全为正值εNd(t) εSr(t)图解上 ,前者投影点主要落在了富集地幔演化趋势线附近 ,而后者投影点主要落在了亏损地幔演化线附近。在地球不同区域铅模式图上 ,地台区钾长石铅投影点大部落在了地幔演化线附近 ,而地槽区的则落在了地幔与造山带演化线之间。以上事实说明华北地台区富碱侵入岩的物质来源与富集地幔关系密切 ,而地槽区的则与亏损地幔关系密切。同时也揭示出中生代华北地台区上地幔具有富集性 ,而兴蒙地槽区上地幔则具亏损性。     

大别山北缘中生代火山—侵入岩锶—钕同位素组成特征及其物质来源

报道了大别山北缘中生代（早白垩世）不同成因系列火山－侵入岩的14个Rb-Sr,Sm-Nd同位素分析数据，其中正长岩类ISr值为0．70943－0．71014，εNd值为－14．7－15．8，亏损地幔两阶段模式年龄TDM为2．12－2．20Ga；高钾钙碱性系列岩石ISr值为0．70750－0．71054，εNd值为－17．2－－19．1，TDM为2．32－2．48Ga，橄榄安粗岩系列岩石ISr值为0．70873－0．70912，εNd值为－20．7－21．7，TDM为2．60－2．68Ga。通过与基底变质岩Sm-Nd同位素组成对比，认为高钾钙碱性系列主要由类似于大别群的地壳岩石衍生而成，正长岩类是由大别群和少量较年轻地壳岩石（卢镇关群和佛子岭群？）衍生而成的，而橄榄安粗岩系列则来源于富集地幔并可能混入少量更古老的类似于泰山群的地壳组分。