Late glacial and Holocene environmental change in the Lake Baikal region documented by oxygen isotopes from diatom silica

We investigate late glacial and Holocene climate change recorded in Lake Baikal using the oxygen isotope composition of diatom silica (δ¹⁸O_DIAT). Evaporation from the lake is minor, and the temperature fractionations of δ¹⁸O are unable to explain variations in the δ¹⁸O_DIAT record alone. Isotopically, low meltwater input from glaciers may have some influence on δ¹⁸O_DIAT, but the assumed periods of climatic warming and wastage do not coincide with large shifts in δ¹⁸O_DIAT. There is a gradual oxygen isotope lowering from 27.0‰ to 20.6‰ over the late glacial, while, during the Holocene, δ¹⁸O_DIAT values return to relatively high values. Previous studies of the modern oxygen and hydrogen isotope composition of Lake Baikal's inputs reveal that fluvial input to the lake's North Basin are isotopically lower than fluvial input from South Basin rivers. This north–south gradient of river δ¹⁸O and δD is mainly due to the greater input from isotopically low winter precipitation in the north and isotopically higher summer precipitation in the south. As a result, the δ¹⁸O_DIAT record from Lake Baikal can at least in part be explained by varying input from these sources related to seasonal changes in precipitation. Changes in atmospheric conditions may have a role in altering seasonality and the distribution of precipitation over Lake Baikal's catchment. A feedback mechanism is well known linking higher Eurasian spring snow cover extent (ESSC) to the development of anticyclonic conditions and low precipitation the following summer in the areas south of Lake Baikal. A simultaneous increase in the importance of depleted water (snowmelt) input from the north and decreased enriched summer precipitation in the south is needed to explain depletions in δ¹⁸O of lake water and subsequently δ¹⁸O_DIAT during colder periods. The opposite of this situation is required to enrich lake water during warmer periods. The analysis of δ¹⁸O from diatom silica is a useful proxy for environmental change, especially in lakes, like Lake Baikal, where carbonates are absent or diluted. However, analysis must be based on near pure diatom samples as even trace amounts of silt can have a dominating effect on δ¹⁸O_DIAT values.     

Mid Pleistocene climate instability in the subtropical northwestern Atlantic

We present Globigerinoides ruber, G. sacculifer and Neogloboquadrina dutertrei oxygen isotope records from northwestern subtropical Atlantic Site 1058 spanning the mid Pleistocene ( 600 to 400 ka). The high temporal resolution of these records ( 800 yr) allows us to compare millennial-scale climate signals during one of the most extreme glacial periods of the Pleistocene (Marine Isotope Stage (MIS) 12) to an earlier, less extreme glacial (MIS 14), as well as to two full interglacial intervals (MIS 13 and MIS 15). We observe excellent agreement in the timing and amplitude of variations between the surface-most dwelling species G. ruber and Northern Hemisphere insolation during the two interglacial periods. There is some expression of Northern Hemisphere insolation during glacial MIS 14; however, during the more extreme glacial MIS 12 Northern Hemisphere insolation patterns are not apparent in any of the planktonic foraminiferal δ¹⁸O records. Insolation remains relatively high, but δ¹⁸O values increase toward the characteristic δ¹⁸O maximum of MIS 12 in all three of the records. On the millennial-scale, all three species display their highest amplitude δ¹⁸O variations (with a period between 4–6 kyr) during glacial MIS 12. Suborbital-scale variability is also statistically significant during glacial MIS 14, but the amplitude is smaller. These results support hypotheses linking millennial-scale climate fluctuations to the extent of continental glaciation. We propose that the relatively high degree of sea surface instability during one of the most extreme glacial periods of the Pleistocene arises from the competing effects of strong atmospheric winds related to the presence of a large ice sheet to the north and persistently high incident solar radiation during this interval of time.     

Vegetation and climate variability during the Last Interglacial evidenced in the pollen record from Lake Baikal

A pollen record from the core sediments collected in the northern part of Lake Baikal represents the latest stage of the Taz (Saale) Glaciation, Kazantsevo (Eemian) Interglacial (namely the Last Interglacial), and the earliest stage of the Zyryanka (Weichselian) Glaciation. According to the palaeomagnetic-based age model applied to the core, the Last Interglacial in the Lake Baikal record lasted about 10.6 ky from 128 to 117.4 ky BP, being more or less synchronous with the Marine Isotope Stage 5e. The reconstructed changes in the south Siberian vegetation and climate are summarised as follows: a major spread of shrub alder (Alnus fruticosa) and shrub birches (Betula sect. Nanae/Fruticosae) in the study area was a characteristic feature during the late glacial phase of the Taz Glaciation. Boreal trees e.g. spruce (Picea obovata) and birch (Betula sect. Albae) started to play an important role in the regional vegetation with the onset of the interglacial conditions. Optimal conditions for Abies sibirica–P. obovata taiga development occurred ca. 126.3 ky BP. The maximum spread of birch forest-steppe communities took place at the low altitudes ca. 126.5–125.5 ky BP and Pinus sylvestris started to form forests in the northern Baikal area after ca. 124.4 ky BP. Re-expansion of the steppe communities, as well as shrubby alder and willow communities and the disappearance of forest vegetation occurred at about 117.4 ky BP, suggesting the end of the interglacial succession. The changes in the pollen assemblages recorded in the sediments from northern Baikal point to a certain instability of the interglacial climate. Three phases of climate deterioration have been distinguished: 126–125.5, 121.5–120, and 119.5–119 ky BP. The penultimate cooling signal may be correlated with the cool oscillation recorded in European pollen records. However, such far distant correlation requires more careful investigation.     

A late Quaternary lake record from the Qilian Mountains (NW China): evolution of the primary production and the water depth reconstructed from macrofossil, pollen, biomarker, and isotope data

The history (45–0 ka BP) of the aquatic vegetation composition of the shallow alpine Lake Luanhaizi from the NE Tibetan Plateau is inferred from aquatic plant macrofossil frequencies and aquatic pollen and algae concentrations in the sediments. C/N (range: 0.3–100), δ¹³C (range: −28 to −15‰), and n-alkane measurements yielded further information on the quantitative composition of sedimentary organic matter. The inferred primary production of the former lake ecosystem has been examined in respect of the alternative stable state theory of shallow lakes [Scheffer, M., 1989. Alternative stable states in eutrophic, shallow freshwater systems: a minimal model. Hydrobiological Bulletin 23, 73–83]. Switches between clear and turbid water conditions are explained by a colder climate and forest decline in the catchment area of Lake Luanhaizi. The macrofossil-based reconstruction of past water depth and salinity ranges, as well as other organic matter (OM) proxies allowed climatic inferences of the summer monsoon intensity during the late Quaternary. Around 45 ka BP, conditions similar to or even moister than present-day climate occurred. The Lake Luanhaizi record is further evidence against an extensive glaciation of the Tibetan Plateau and its bordering mountain ranges during the Last Glacial Maximum. Highest lake levels and consequently a strong summer monsoon are recorded for the early Holocene period, while gradually decreasing lake levels are reconstructed for the middle and late Holocene.     

1000 years of climate variability in central Asia: assessing the evidence using Lake Baikal (Russia) diatom assemblages and the application of a diatom-inferred model of snow cover on the lake

The mainly endemic phytoplankton record of Lake Baikal has been used in this study to help interpret climate variability during the last 1000 years in central Asia. The diatom record was derived from a short core taken from the south basin and has been shown to be free from any sedimentary heterogeneities. We employ here a diatom-based inference model of snow accumulation on the frozen lake for the first time (r²_boot=0.709; RMSEP=0.120 log cm). However, palaeoenvironmental reconstructions have been improved by the use of correction factors, specifically developed for the dominant phytoplankton (Aulacoseira baicalensis, Aulacoseira skvortzowii, Cyclotella minuta, Stephanodiscus meyerii and Synedra acus) in the south basin of Lake Baikal. Cluster analysis identifies three significant zones in the core, zone 1 (c. 880 AD–c. 1180 AD), zone 2 (c. 1180–1840 AD) and zone 3 (c. 1840–1994 AD), coincident with the Medieval Warm Period (MWP), the Little Ice Age (LIA) and the period of recent warming, respectively. Our results indicate that S. acus dominated the diatom phytoplankton within zone 1 coincident with the MWP. S. acus is an opportunistic species that is able to increase its net growth when A. baicalensis does not. During this period, conditions are likely to have been unfavourable for the net increases in A. baicalensis growth due to the persistence of warm water in the lake, together with an increased length of summer stratification and delay in timing of the autumnal overturn. In zone 2, spring diatom crops blooming under the ice declined in abundances due in part to increased winter severity and snow cover on the lake. Accumulating snow on the lake is likely to have arisen from increased anticyclonic activity, resulting in prolonged winters expressed during the LIA. Thick, accumulating snow cover inhibits light penetration through the ice, thereby having negative effects on cell division rate and extent of turbulence underneath the ice. Consequently, only taxa whose net growth occurs during autumn overturn (C. minuta) predominate in the lake at this time. Diatom census data and reconstructions of snow accumulation suggest that warming in the Lake Baikal region started as early as c. 1750 AD, with a shift from taxa that bloom during autumn overturn to assemblages that begin to grow underneath the frozen lake in spring. Very recent increases and subsequent decline of S. acus in the surface sediments of the lake mirror monitoring records of this species over the last 50 years. Our study confirms that, over the last 1000 years, physical processes are important in determining planktonic diatom populations in the lake and highlights the value of integrated plankton, trap, and sediment studies for improving quantitative palaeoenvironmental reconstructions from fossil material.     

Sensitive response of desert vegetation to moisture change based on a near-annual resolution pollen record from Gahai Lake in the Qaidam Basin, northwest China

We present a 50-year pollen record at near-annual resolution from Gahai Lake in the Qaidam Basin on the northeastern Tibetan Plateau. Chronology of a 22-cm short core was established by ²¹⁰Pb and ¹³⁷Cs analysis. The pollen results at 0.5 cm intervals show large changes in Artemisia/Chenopodiaceae (A/C) ratios from < 0.2 to 0.95 in the last 50 years. High (low) A/C ratios represent increase (decrease) in steppe pollen production, which correspond to high (low) relative humidity observed at nearby Delingha weather station. On the basis of good correspondence with instrumental records and carbonate content from Gahai Lake, we conclude that A/C ratio is sensitive to moisture change and can be a very useful index in reconstructing paleoclimate of arid regions. Comparison with pollen and snow accumulation data from Dunde ice core suggests that effective moisture at low and high elevations shows the opposite relationship when mountain precipitation was extremely high, possibly due to topography-induced uplifting and subsiding air dynamics.     

Preliminary study of fluxes of major lipid biomarker classes in the water column and sediments of Lake Baikal, Russia

The application of biomarker climate proxies to lacustrine settings requires a thorough understanding of those processes that give rise to and mediate in the burial and preservation of organic matter in the sediments. This information is to date missing for Lake Baikal in Central Asia. The biogeochemistry of the lake cannot be considered analogous to that in other lacustrine environments given its enormous size, depth, remote location and unique biology. The aim of this paper is to report on the main compound classes in the water column and sediments. As part of an ongoing evaluation of the inputs and fluxes of organic matter in Lake Baikal, we have found that there are significant differences in the inputs and preservation of organic matter between the North and South Basins. Both basins have dominant algal input and a contribution from the terrestrial plants of the lake edges and surrounding environments. However, the concentration of organic material in the sediment traps and sediments of the South Basin is much higher than that of the North Basin. In addition, the South Basin contains much higher proportions of the more labile material than does the North Basin. This is likely due to the South Basin being free of surface ice for a much longer time than the North, and in consequence, primary producers having an overall longer productive season. There is some evidence of microbial activity in the sediment traps and sediments from both the North and South Basins, but it does not appear to be more predominant in one basin than the other. It is probable that the differences in the composition and concentration of biomarkers in sediments between basins is due to the length of and the intensity of the productive season, which is in turn influenced by the climate.     

Effects of a 2 × CO2 climate on two large lake systems: Pyramid Lake, Nevada, and Yellowstone Lake, Wyoming

The possible effects of trace-gas induced climatic changes on Pyramid and Yellowstone Lakes are assessed using a model of lake temperature. The model is driven by years of hourly meteorological data obtained directly from the output of double-CO₂ experiments (2 × CO₂) conducted with a regional climate model nested in a general circulation model. The regional atmospheric model is the climate version of the National Center for Atmospheric Research/Pennsylvania State University mesoscale model, MM4.Average annual surface temperature of Pyramid Lake for the 2 × CO₂ climate is 15.5 ± 5.4°C (±1 σ), 2.8°C higher than the control. Annual overturn of the lake ceases as a result of these higher temperatures for the 2 × CO₂ climate. Evaporation increases from 1400 mm yr⁻¹ in the control to 1595 mm yr⁻¹ in the 2 × CO₂ simulation, but net water supplied to the Pyramid Lake basin increases from −6 mm yr⁻¹ in the control to +27 mm yr⁻¹ in the 2 × CO₂ simulation due to increased precipitation.For the open water periods, the average annual surface temperature of Yellowstone Lake is 13.2 ± 5.1°C for the 2 × CO₂ climate, a temperature 1.6°C higher than the control. The annual duration of ice cover on the lake is 152 days in the 2 × CO₂ simulation, a reduction of 44 days relative to the control. Warming of the lake for the 2 × CO₂ climate is mostly confined to the near-surface. Simulated spring overturn for the 2 × CO₂ climate occurs earlier in the year and fall overturn later than in the control. Evaporation increases from 544 mm yr⁻¹ to 600 mm yr⁻¹ in the 2 × CO₂ simulation, but net water supplied to the Yellowstone Lake basin increases from +373 mm yr⁻¹ in the control to +619 mm yr⁻¹ due to increased precipitation. The effects of these climatic changes suggest possible deterioration of water quality and productivity in Pyramid Lake and possible enhancement of productivity in Yellowstone Lake.     

Comparison of interglacial stages in the South Atlantic sector of the southern ocean for the past 450 kyr: implifications for Marine Isotope Stage (MIS) 11

Oxygen and carbon isotopic gradients in surface waters were reconstructed for the past 450 kyr by analysis of the planktic foraminifer Neogloboquadrina pachyderma in cores located at approximately 43°, 47°, and 54°S across the Polar Frontal Zone in the South Atlantic sector of the Southern Ocean. Comparison of the oxygen isotopic records for peak interglacial conditions during the past 450 kyr reveals that Marine Isotope Stage (MIS) 11 was not substantially warmer than other interglacials at high southern latitudes, although the period of warmth lasted longer. The carbonate and carbon isotope chemistry of surface and deep water represent the truly distinctive aspects of Stage 11 in the Southern Ocean. Peak carbonate production occurred at high southern latitudes during MIS 11, resulting in light-colored, high-carbonate sediments deposited throughout the Southern Ocean above the lysocline. Carbon isotopic values of benthic foraminifera in cores bathed by Circumpolar Deep Water (CPDW) were highest during MIS11, suggesting strong input of North Atlantic Deep Water (NADW) to the Southern Ocean. Planktic δ¹³C values at high southern latitudes were also highest during MIS 11, which may reflect upwelling of CPDW with a greater contribution of NADW, lower whole-ocean nutrient inventories, higher gas exchange rates, and/or lowered alkalinity of Antarctic surface waters (resulting from carbonate precipitation south of the Polar Front).     

Mid–late Holocene monsoon climate retrieved from seasonal Sr/Ca and δO records of Porites lutea corals at Leizhou Peninsula, northern coast of South China Sea

South China Sea (SCS) is a major moisture source region, providing summer monsoon rainfall throughout Mainland China, which accounts for more than 80% total precipitation in the region. We report seasonal to monthly resolution Sr/Ca and δ¹⁸O data for five Holocene and one modern Porites corals, each covering a growth history of 9–13 years. The results reveal a general decreasing trend in sea surface temperature (SST) in the SCS from 6800 to 1500 years ago, despite shorter climatic cycles. Compared with the mean Sr/Ca–SST in the 1990s (24.8 °C), 10-year mean Sr/Ca–SSTs were 0.9–0.5 °C higher between 6.8 and 5.0 thousand years before present (ky BP), dropped to the present level by 2.5 ky BP, and reached a low of 22.6 °C (2.2 °C lower) by 1.5 ky BP. The summer Sr/Ca–SST maxima, which are more reliable due to faster summer-time growth rates and higher sampling resolution, follow the same trend, i.e. being 1–2 °C higher between 6.8 and 5.0 ky BP, dropping to the present level by 2.5 ky BP, and reaching a low of 28.7 °C (0.7 °C lower) by 1.5 ky BP. Such a decline in SST is accompanied by a similar decrease in the amount of monsoon moisture transported out of South China Sea, resulting in a general decrease in the seawater δ¹⁸O values, reflected by offsets of mean δ¹⁸O relative to that in the 1990s. This observation is consistent with general weakening of the East Asian summer monsoon since early Holocene, in response to a continuous decline in solar radiation, which was also found in pollen, lake-level and loess/paleosol records throughout Mainland China. The climatic conditions 2.5 and 1.5 ky ago were also recorded in Chinese history. In contrast with the general cooling trend of the monsoon climate in East Asia, SST increased dramatically in recent time, with that in the 1990s being 2.2 °C warmer than that 1.5 ky ago. This clearly indicates that the increase in the concentration of anthropogenic greenhouse gases played a dominant role in recent global warming, which reversed the natural climatic trend in East Asian monsoon regime.     

Late Quaternary lake-level changes constrained by radiocarbon and stable isotope studies on sediment cores from Lake Titicaca, South America

We present and compare AMS-¹⁴C geochronologies for sediment cores recovered from Lake Titicaca, South America. Radiocarbon dates from three core sites constrain the timing of late Quaternary paleoenvironmental changes in the Central Andes and highlight the site-specific factors that limit the radiocarbon geochronometer. With the exception of mid-Holocene sediments, all cores are generally devoid of macrophyte fragments, thus bulk organic fractions are used to build core chronologies. Comparisons of radiocarbon results for chemically defined fractions (bulk decalcified, humate, humin) suggest that ages derived from all fractions are generally coherent in the post-13,500 yr BP time interval. In the pre-13,500 yr BP time interval, ages derived from humate extracts are significantly younger (300–7000 years) than ages from paired humin residues. Gross age incoherencies between paired humate and humin sub-fractions in pre-13,500 yr BP sediments from all core sites probably reflect the net downward migration of humates. Ages derived from bulk decalcified fractions at our shallow water (90 m) and deep water (230 m) core sites consistently fall between ages derived from humate and humin sub-fractions in the pre-13,500 yr BP interval, reflecting that the bulk decalcified fraction is predominantly a mixture of humate and humin sub-fractions. Bulk decalcified ages from the pre-13,500 yr BP interval at our intermediate depth core site (150 m) are consistently older than humate (youngest) and humin sub-fractions. This uniform, reproducible pattern can be explained by the mobilization of a relatively older organic sub-fraction during and after the re-acidification step following the alkaline treatment of the bulk sediment. The inferred existence of this ‘alkali-mobile, acid-soluble’ sub-fraction implies a different depositional/post-depositional history that is potentially associated with a difference in source material. While internally consistent geochronologies can be developed for the Lake Titicaca sequence using different organic fractions, mobile organic sub-fractions and fractions containing mobile sub-fractions should generally be avoided in geochronology studies. Consequently, we believe humin and/or bulk decalcified ages provide the most consistent chronologies for the post-13,500 yr BP interval, and humin ages provide the most representative ages for sedimentation prior to 13,500 yr BP interval.Using the age model derived from the deep water core site and a previously published isotope-based lake-level reconstruction, we present a qualitative record of lake level in the context of several ice-core records from the western hemisphere. We find the latest Pleistocene lake-level response to changing insolation began during or just prior to the Bølling/Allerød period. Using the isotope-based lake-level reconstruction, we also find the 85-m drop in lake level that occurred during the mid-Holocene was synchronous with an increase in the variability of ice-core δ¹⁸O from a nearby icecap, but was not reflected in any of the polar ice-core records recovered from the interior of Antarctica and Greenland.     

Greenhouse gas emissions from a managed grassland

Managed grasslands contribute to global warming by the exchange of the greenhouse gases carbon dioxide, nitrous oxide and methane. To reduce uncertainties of the global warming potential of European grasslands and to assess potential mitigation options, an integrated approach quantifying fluxes from all three gases is needed. Greenhouse gas emissions from a grassland site in the SE of Scotland were measured in 2002 and 2003. Closed static chambers were used for N₂O and CH₄ flux measurements, and samples were analysed by gas chromatography. Closed dynamic chambers were used for soil respiration measurements, using infrared gas analysis. Three organic manures and two inorganic fertilizers were applied at a rate of 300 kg N ha⁻¹ a⁻¹ (available N) and compared with a zero-N control on grassland plots in a replicated experimental design. Soil respiration from plots receiving manure was up to 1.6 times larger than CO₂ release from control plots and up to 1.7 times larger compared to inorganic treatments (p<0.05). A highly significant (p<0.001) effect of fertilizer and manure treatments on N₂O release was observed. Release of N₂O from plots receiving inorganic fertilizers resulted in short term peaks of up to 388 g N₂O–N ha⁻¹ day⁻¹. However losses from plots receiving organic manures were both longer lasting and greater in magnitude, with an emission of up to 3488 g N₂O–N ha⁻¹ day⁻¹ from the sewage sludge treatments. During the 2002 growing season the cumulative total N₂O flux from manure treatments was 25 times larger than that from mineral fertilizers. CH₄ emissions were only significantly increased (p<0.001) for a short period following applications of cattle slurry. Although soil respiration in manure plots was high, model predictions and micrometeorological flux measurements at an adjacent site suggest that all plots receiving fertilizer or manure acted as a sink for CO₂. Therefore in terms of global warming potentials the contribution of N₂O from manure treatments becomes particularly important. There were considerable variations in N₂O and CO₂ fluxes between years, which was related to annual variations in soil temperature and rainfall.     

Oxygen and carbon isotope ratios in the martian atmosphere

Oxygen and carbon isotope ratios in the martian CO₂ are key values to study evolution of volatiles on Mars. The major problems in spectroscopic determinations of these ratios on Mars are uncertainties associated with: (1) equivalent widths of the observed absorption lines, (2) line strengths in spectroscopic databases, and (3) thermal structure of the martian atmosphere during the observation. We have made special efforts to reduce all these uncertainties. We observed Mars using the Fourier Transform Spectrometer at the Canada–France–Hawaii Telescope. While the oxygen and carbon isotope ratios on Mars were byproducts in the previous observations, our observation was specifically aimed at these isotope ratios. We covered a range of 6022 to 6308 cm⁻¹ with the highest resolving power of ν/δν=3.5×10⁵ and a signal-to-noise ratio of 180 in the middle of the spectrum. The chosen spectral range involves 475 lines of the main isotope, 184 lines of ¹³CO₂, 181 lines of CO¹⁸O, and 119 lines of CO¹⁷O. (Lines with strengths exceeding 10⁻²⁷ cm at 218 K are considered here.) Due to the high spectral resolution, most of the lines are not blended. Uncertainties of retrieved isotope abundances are in inverse proportion to resolving power, signal-to-noise ratio, and square root of the number of lines. Laboratory studies of the CO₂ isotope spectra in the range of our observation achieved an accuracy of 1% in the line strengths. Detailed observations of temperature profiles using MGS/TES and data on temperature variations with local time from two GCMs are used to simulate each absorption line at various heights in each part of the instrument field of view and then sum up the results. Thermal radiation of Mars' surface and atmosphere is negligible in the chosen spectral range, and this reduces errors associated with uncertainties in the thermal structure on Mars. Using a combination of all these factors, the highest accuracy has been achieved in measuring the CO₂ isotope ratios: ¹³C/¹²C = 0.978 ± 0.020 and ¹⁸O/¹⁶O = 1.018 ± 0.018 times the terrestrial standards. Heavy isotopes in the atmosphere are enriched by nonthermal escape and sputtering, and depleted by fractionation with solid-phase reservoirs. The retrieved ratios show that isotope fractionation between CO₂ and oxygen and carbon reservoirs in the solid phase is almost balanced by nonthermal escape and sputtering of O and C from Mars.     

Geochemical record of the Holocene Jomon transgression and human activity in coastal lagoon sediments of the San'in district, SW Japan

Coastal lagoon muds were analyzed to evaluate changes in sedimentary environments by the Jomon transgression from the lower to middle Holocene age and human activities. Core samples from Lake Shinji, Southwest Japan were utilized, which cover the entire Holocene Nakaumi Formation (ca. 23-m thick), and comprise the Lower, Middle, Upper and Uppermost members. Total sulfur (TS) contents and Fe₂O₃/Al₂O₃ ratios increase from the boundary of Middle and Upper members, which is 1 m below the Kikai-Akahoya (K-Ah) volcanic ash of 6300 years BP. This change coincides to the pollen flora zone boundary of the Pinus–Abies and the Cyclobalanopsis–Castanopsis, suggesting transition to a warming climate. Chemical index of alteration (CIA) values [(ratio of Al to Al+Ca+Na+K)×100] and Rb/K ratios also show gradual increase from the middle part of the Upper member, due to its derivation from highly weathered source material probably formed under warming and rainy condition. Al₂O₃/TiO₂ and SiO₂/TiO₂ show little variation from the Lower to the Upper members, probably related to consistent feldspar composition in the source rocks, and homogeneously mixed clays. In the Uppermost member (from 1500 years), sharp increases in Ti/Zr and decreases in both Nb/Y and Zr/Y occurred, suggesting heavy mineral fractionation. This change was caused by iron sand processing called Kannanagashi and charcoal-making in the most mountainous regions. Soil erosion by these processes brought changes in mud composition, shown by the enrichment in Al₂O₃, and depletion in Zr and Cr. Human activities thus had severe impacts on sedimentary environments compared with the natural changes since the Jomon transgression.     

Dust influx reconstruction during the last 26,000 years inferred from a sedimentary leaf wax record from the Japan Sea

We obtained the high-resolution record of terrestrial biomarkers (C₂₉ and C₃₁ n-alkanes) for the last 26,000 years from Oki Ridge in the south Japan Sea that enabled us to discuss millennial scale climate changes. Our sampling resolution for the biomarker during the major deglaciation period (10–19.5 cal ka BP) is 300 years and for the elemental analyses (total organic carbon and total nitrogen) is as good as ca 200 years. The estimated mass accumulation rate of these molecules during the last glacial period is substantially higher than during the Holocene. They also exhibited two distinct peaks at 17.6 cal ka BP and 11.4 cal ka BP, which are coincident with Heinrich Event 1 and the latest stage of the Younger Dryas, respectively. The unique oceanographic setting of the Japan Sea tends to preferentially preserve organic material of aeolian origin. The nature of our biomarker record in fact suggests a strong aeolian signal, and hence their flux to the Japan Sea potentially reflects the climate conditions of the dust source regions and transport intensity. Our results are consistent with previously reported monsoon variations based on other proxies that is indicative of a strong linkage between North Atlantic climate and Asian monsoon intensity.     

Primary production and microbial activity in the euphotic zone of Lake Baikal (Southern Basin) during late winter

Three years of regular weekly/biweekly monitoring of seasonal changes in temperature, transparency, chlorophyll a (CHL) and bacteria [erythrosine-stained microscopic counts and cultivable colony forming units (CFUs)] at the vertical profile in the South basin of Lake Baikal (51°54′195″N, 105°04′235″E, depth 800 m) were evaluated. In more detail, the structure and function of phytoplankton and the microbial loop in the euphotic layer at the same site were investigated during the late-winter–early-spring period under the ice. The depth of euphotic zone (up to 1% of surface irradiation) was 35 to 40 m. Primary production was measured three times a week with the ¹⁴C method in 2, 10, 20, 30 and 40 m. Maximum production was found in 10 m, with lower values towards the surface (light inhibition) and towards the lower layers. The total production in cells larger than 1 μm in the column (0–40 m) was 204–240 mg C d⁻¹ m⁻², 30–40% of it being in cells 1–3 μm (mostly picocyanobacteria), which represented roughly 9% of the total chlorophyll a (estimated from pigment analyses). A major part of phytoplankton biomass was formed by diatoms (Synedra acus Hust., Asterionella formosa Hass. and Stephanodiscus meyerii Genkal & Popovskaya). Total production (including extracellular, dissolved organic matter) was 235–387 mg C day⁻¹ m⁻², and the exudates were readily used by bacteria (particles 0.2–1 μm). This part amounted to 1–5% of cellular production in 2 to 20 m and 11–77% of cellular production in 20–40 m, i.e., in light-limited layers. From 0 to 30 m, chlorophyll a concentration was 0.8 to 1.3 μg l⁻¹, wherefrom it decreased rapidly to 0.1 μg l⁻¹ towards the depth of 40 m. Bacteria (DAPI-stained microscopic counts) reached 0.5–1.4×10⁶ ml⁻¹; their cell volumes measured via image analysis were small (average 0.05 μm⁻³), often not well countable when erythrosine stain was used. Bacterial biomasses were in the range of 6–21 μg C l⁻¹. Numbers of colony forming units (CFUs) on nutrient fish-agar were c. 3–4 orders lower than DAPI counts. The amounts of heterotrophic protists were low, whereby flagellates reached 6 to 87 ml⁻¹ and ciliates, 0.2–1.2 ml⁻¹ (mostly Oligotrichida). Bacterial production was measured in the same depths as primary production using ³H-thymidine (Thy) and ¹⁴C-leucine (Leu) uptake. Consistently, bacterial abundances, biomasses, thymidine and leucine production were higher by 30–50% in layers 2, 10 and 20 m compared with that in the deeper 30 and 40 m, where cellular primary production was negligible. Leucine uptake in the deeper layers was even three times lower than in the upper ones. From the comparison of primary and bacterial production, bacteria roughly use 20–40% of primary production during 24 h in the layers 2 to 20 m.     

Extreme Ultraviolet Emission Lines of ca xv in Solar and Laboratory Spectra

New R-matrix calculations of electron impact excitation rates in Caxv are used to derive theoretical electron density diagnostic emission line intensity ratios involving 2s ²2p ²–2s2p ³ transitions, specifically R ₁=I(208.70 Å)/I(200.98 Å), R ₂=I(181.91 Å)/I(200.98 Å), and R ₃=I(215.38 Å)/I(200.98 Å), for a range of electron temperatures (T _e=10^6.4–10^6.8 K) and densities (N _e=10⁹–10¹³ cm^–3) appropriate to solar coronal plasmas. Electron densities deduced from the observed values of R ₁, R ₂, and R ₃ for several solar flares, measured from spectra obtained with the Naval Research Laboratory's S082A spectrograph on board Skylab, are found to be consistent. In addition, the derived electron densities are in excellent agreement with those determined from line ratios in Caxvi, which is formed at a similar electron temperature to Caxv. These results provide some experimental verification for the accuracy of the line ratio calculations, and hence the atomic data on which they are based. A set of eight theoretical Caxv line ratios involving 2s ²2p ²–2s2p ³ transitions in the wavelength range 140–216 Å are also found to be in good agreement with those measured from spectra of the TEXT tokamak plasma, for which the electron temperature and density have been independently determined. This provides additional support for the accuracy of the theoretical line ratios and atomic data.     

Mgix and Sixi line ratios in the sun

New theoretical emission line ratios for the Be-sequence ions Mgix and Sixi are presented. A comparison with observational data for two solar flares and an active region loop obtained with the Harvard EUV spectrometer and NRL XUV spectroheliograph aboard Skylab reveals that these plasmas are in ionization equilibrium at coronal temperatures. Unfortunately most of the density diagnostics are not particularly useful under solar plasma conditions, as they vary only slightly over the electron density range 10⁸–10¹³cm^–3. However the Sixi ratioI(³ P ^e ₂ -³ P ^o ₂)/I(³ P ^o ₁ –¹ S ^e ₀) is density sensitive in the range 10⁸ to 10¹⁰cm^–3, which is representative of electron densities found in solar active regions or small flares.     

Stable carbon isotope ratios in tree rings of co-occurring species from semi-arid tropics in Africa: Patterns and climatic signals

Although several proxies have been proposed to trace the course of environmental and climatological fluctuations, precise paleoclimate records from the tropics, notably from Africa are still sorely lacking today. Stable carbon isotopes (δ¹³C) in tree rings are an attractive record of climate. In this study, the patterns and climatic signals of δ¹³C ratios were determined on tree rings of deciduous (Acacia senegal, Acacia tortilis, Acacia seyal) and an evergreen (Balanites aegyptiaca) species, from a semi-arid Acacia Woodland in Ethiopia. δ¹³C inter-annual patterns are synchronous among the co-occurring species. A declining trend with time was observed in δ¹³C, notably for B. aegyptiaca, which could be due to anthropogenic increases in atmospheric CO₂ concentration and decrease in atmospheric δ¹³C. Tree ring δ¹³C values of all the species revealed significant negative correlation with precipitation amount but not with temperature and relative humidity. The δ¹³C series of the deciduous species shows a higher correlation (r = − 0.70 to − 0.78) with precipitation than the evergreen species (r = − 0.55). A master δ¹³C series, composed of the average of the three Acacia species, displayed stronger significant correlation (r = − 0.82) than any of the individual species δ¹³C series. The weak relationship between temperature and δ¹³C in this study indicates that photosynthetic rate is not a significant factor. Moisture stress, however, may have a direct impact on the stomatal conductance and explain the strong negative relationship between δ¹³C and precipitation. The results demonstrate the potential of δ¹³C in tree rings to reflect physiological responses to environmental changes as a vehicle for paleoclimatic reconstruction, which is important to understand tree response to past and future climate change.     

Theoretical Siiv line ratios compared to extreme ultraviolet solar observations

New theoretical electron temperature sensitive emission line ratios in Siiv involving the 3d ² D – 3p ² P and 4s ² S – 3p ² P multiplets at 1125 and 816 Å, respectively, are derived using recent R-matrix electron excitation rate calculations. A comparison of these with observational data for a solar active region at the limb obtained with the Harvard S-055 spectrometer on board Skylab reveals that there is good agreement between theory and observation for ratios that include the ² D _{3/2, 5/2} – ² P _3/2 transition at 1128.3 Å. This is in contrast to the findings of Keenan, Dufton, and Kingston (1986) and provides support for the atomic data adopted in the calculations. However, the ² D _3/2 – ² P _1/2 line at 1122.5 Å appears to be severely blended, as suggested previously by Burton and Ridgeley (1970) and Feldman and Doschek (1977), as it leads to electron temperature estimates that differ significantly from that expected in ionisation equilibrium. The fact that the I(1122.5 Å)/I(1128.3 Å) intensity ratios determined from several flare spectra are closer to theory than that for the active region indicates that the blending is probably due to species with relatively low ionization potentials, as noted by Flower and Nussbaumer (1975). Electron temperatures deduced for a sunspot are much lower than that predicted from ionisation balance calculations, in agreement with earlier results, and imply that a cooling flow may be present.