Degassing and microlite crystallization during pre-climactic events of the 1991 eruption of Mt. Pinatubo, Philippines

 Dacite tephras produced by the 1991 pre-climactic eruptive sequence at Mt. Pinatubo display extreme heterogeneity in vesicularity, ranging in clast density from 700 to 2580 kg m^–3. Observations of the 13 surge-producing blasts that preceded the climactic plinian event include radar-defined estimates of column heights and seismically defined eruptive and intra-eruptive durations. A comparison of the characteristics of erupted material, including microlite textures, chemical compositions, and H₂O contents, with eruptive parameters suggests that devolatilization-induced crystallization of the magma occurred to a varying extent prior to at least nine of the explosive events. Although volatile loss progressed to the same approximate level in all of the clasts analyzed (weight percent H₂O=1.26-1.73), microlite crystallization was extremely variable (0–22%). We infer that syn-eruptive volatile exsolution from magma in the conduit and intra-eruptive separation of the gas phase was facilitated by the development of permeability within magma residing in the conduit. Correlation of maximum microlite crystallinity with repose interval duration (28–262 min) suggests that crystallization occurred primarily intra-eruptively, in response to the reduction in dissolved H₂O content that occurred during the preceding event. Detailed textural characterization, including determination of three-dimensional shapes and crystal size distributions (CSD), was conducted on a subset of clasts in order to determine rates of crystal nucleation and growth using repose interval as the time available for crystallization. Shape and size analysis suggests that crystallization proceeded in response to lessening degrees of feldspar supersaturation as repose interval durations increased. We thus propose that during repose intervals, a plug of highly viscous magma formed due to the collapse of vesicular magma that had exsolved volatiles during the previous explosive event. If plug thickness grew proportionally to the square root of time, and if magma pressurization increased during the eruptive sequence, the frequency of eruptive pulses may have been modulated by degassing of magma within the conduit. Dense clasts in surge deposits probably represent plug material entrained by each subsequent explosive event. Received: 4 December 1997 / Accepted: 13 September 1998     

The Middle Scoria sequence: A Holocene violent strombolian, subplinian and phreatomagmatic eruption of Okmok volcano, Alaska

The Middle Scoria deposit represents an explosive eruption of basaltic andesite magma (54 wt. % SiO₂) from Okmok volcano during mid-Holocene time. The pattern of dispersal and characteristics of the ejecta indicate that the eruption opened explosively, with ash textural evidence for a limited degree of phreatomagmatism. The second phase of the eruption produced thick vesicular scoria deposits with grain texture, size and dispersal characteristics that indicate it was violent strombolian to subplinian in style. The third eruptive phase produced deposits with a shift towards grain shapes that are dense, blocky, and poorly vesicular, and intermittent surge layers, indicating later transitions between magmatic (violent strombolian) to phreatomagmatic (vulcanian) eruptive styles. Isopach maps yield bulk volume estimates that range from 0.06 to 0.43 km³, with ~ 0.04 to 0.25 km³ total DRE. The associated column heights and mass discharge values calculated from isopleth maps of individual Middle Scoria layers are 8.5 – 14 km and 0.4 to 45 × 10⁶ kg/s. The Middle Scoria tephras are enriched in plagioclase microlites that have the textural characteristics of rapid magma ascent and relatively high degrees of effective undercooling. Those textures probably reflect the rapid magma ascent accompanying the violent strombolian and subplinian phases of the eruption. In the later stages of the eruption, the plagioclase microlite number densities decrease and textures include more tabular plagioclase, indicating a slowing of the ascent rate. The findings on the Middle Scoria are consistent with other explosive mafic eruptions, and show that outside of the two large caldera-forming eruptions, Okmok is also capable of producing violent mafic eruptions, marked by varying degrees of phreatomagmatism.     

Crystallization of microlites and degassing during magma ascent: Constraints on the fluid mechanical behavior of magma during the Tenjo Eruption on Kozu Island, Japan

Bubble and crystal textures provide information with regard to the kinetics of the vesiculation and crystallization processes. They also provide insights into the fluid mechanical behavior of magma in a conduit. We performed textural (bubble and crystal) and compositional analyses of pyroclasts that were obtained from the Tenjo pyroclastic flow, which resulted on account of the eruption in 838 A.D. on Kozu Island, about 200 km south of Tokyo, Japan. Pyroclasts in one flow unit (300∼2,060 kg/m³; average density 1330 kg/m³) can be classified into three types on the basis of vesicle textures. Type I pyroclasts have small isolated spherical bubbles with higher vesicularities (67–77 vol.%) and number density (10.8–11.7 log m⁻³). Type II pyroclasts have vesicularities similar to type I (61–69 vol.%), but most bubbles exhibit evidences of bubble coalescence, and lower number densities than type I (8.9–9.5 log m⁻³). Type III pyroclasts contain highly deformed bubbles with lower vesicularities (16–34 vol.%) and number densities (8.2–9.0 log m⁻³). The microlite volume fraction (DRE converted) also changes consistently across type I, type II, and type III as 0.06, 0.08, and 0.10–0.15, respectively. However, the number density of the microlites remains nearly invariant in all the pyroclast types. These facts indicate that the variation in the microlite volume fraction is controlled not by the number density (i.e., nucleation process), but by the size (i.e., growth process); the growth history of each type of microlite was different. Water content determinations show that the three types of pumices have similar H₂O contents (2.6±0.2 wt%). This fact implies that all three types were quenched at nearly the same depth (35±5 MPa, assuming that the magma was water-saturated) in the conduit. If the crystal sizes are limited only by growth time, a variation in this parameter can be related to the residence time, which is attributed to the flow heterogeneity in the conduit. By assuming a laminar Poiseuille-type flow, these textural observations can be explained by the difference in ascent velocity and shearing motion across the conduit, which in turn results in the differences in growth times of crystals, degrees of deformation, and bubble coalescence. Consequently, for crystals in the inner part of the conduit, the crystal growth time from nucleation to quenching is shorter than that near the conduit wall. The vesicle texture variation of bubbles in types I, II, and III results from the difference in the deformation history, implying that the effect of degassing occurred primarily towards the conduit wall.     

Abrupt transitions during sustained explosive eruptions: examples from the 1912 eruption of Novarupta, Alaska

Plinian/ignimbrite activity stopped briefly and abruptly 16 and 45 h after commencement of the 1912 Novarupta eruption defining three episodes of explosive volcanism before finally giving way after 60 h to effusion of lava domes. We focus here on the processes leading to the termination of the second and third of these three episodes. Early erupted pumice from both episodes show a very similar range in bulk vesicularity, but the modal values markedly decrease and the vesicularity range widens toward the end of Episode III. Clasts erupted at the end of each episode represent textural extremes; at the end of Episode II, clasts have very thin glass walls and a predominance of large bubbles, whereas at the end of Episode III, clasts have thick interstices and more small bubbles. Quantitatively, all clasts have very similar vesicle size distributions which show a division in the bubble population at 30 μm vesicle diameter and cumulative number densities ranging from 10⁷–10⁹ cm^–3. Patterns seen in histograms of volume fraction and the trends in the vesicle size data can be explained by coalescence signatures superimposed on an interval of prolonged nucleation and free growth of bubbles. Compared to experimental data for bubble growth in silicic melts, the high 1912 number densities suggest homogeneous nucleation was a significant if not dominant mechanism of bubble nucleation in the dacitic magma. The most distinct clast populations occurred toward the end of Plinian activity preceding effusive dome growth. Distributions skewed toward small sizes, thick walls, and teardrop vesicle shapes are indicative of bubble wall collapse marking maturation of the melt and onset of processes of outgassing. The data suggest that the superficially similar pauses in the 1912 eruption which marked the ends of episodes II and III had very different causes. Through Episode III, the trend in vesicle size data reflects a progressive shift in the degassing process from rapid magma ascent and coupled gas exsolution to slower ascent with partial open-system outgassing as a precursor to effusive dome growth. No such trend is visible in the Episode II clast assemblages; we suggest that external changes involving failure of the conduit/vent walls are more likely to have effected the break in explosive activity at 45 h.     

Petrology and chemistry of two “large” granite clasts from the moon

Pristine granite clasts in Apollo-14 breccias 14321 and 14303 have estimated masses of 1.8 and 0.17 g, respectively. The 14321 clast is ～ 60% K-feldspar and 40% quartz, with traces of extremely Mg-poor mafic silicates and ilmenite. The 14303 clast is roughly 33% plagioclase, 32% K-feldspar, 23% quartz, 11% pyroxene, and 1% ilmenite; pyroxene and ilmenite are moderately Mg-rich; plagioclase and pyroxene are strongly zoned. Both clasts are severely brecciated, but monomict (pristine). Both have abundant graphic intergrowths of K-feldspar with quartz. Unlike the majority of similar Earth rocks, both clasts are devoid of hydrous phases. The bulk composition of the 14321 clast is similar to those of several other lunar granitic samples, but the 14303 clast is unique: it bears as close a resemblance to KREEP as it does to other lunar granites. Silicate liquid immiscibility may explain why the granites are low in REE relative to KREEP.     

Facies characteristics and magma–water interaction of the White Trachytic Tuffs (Roccamonfina Volcano, southern Italy)

 The Quaternary White Trachytic Tuffs Formation from Roccamonfina Volcano (southern Italy) comprises four non-welded, trachytic, pyroclastic sequences bounded by paleosols, each of which corresponds to small- to intermediate-volume explosive eruptions from central vents. From oldest to youngest they are: White Trachytic Tuff (WTT) Cupa, WTT Aulpi, WTT S. Clemente, and WTT Galluccio. The WTT Galluccio eruption was the largest and emplaced ∼ 4 km³ of magma. The internal stratigraphy of all four WTT eruptive units is a complex association of fallout, surge, and pyroclastic flow deposits. Each eruptive unit is organized into two facies associations, Facies Association A below Facies Association B. The emplacement of the two facies associations may have been separated by short time breaks allowing for limited reworking and erosion. Facies Association A consists of interbedded fallout deposits, surge deposits, and subordinate ignimbrites. This facies association involved the eruption of the most evolved trachytic magma, and pumice clasts are white and well vesiculated. The grain size coarsens upward in Facies Association A, with upward increases of dune bedform wavelengths and a decrease in the proportion of fine ash. These trends could reflect an increase in eruption column height from the onset of the eruption and possibly also in mass eruption rate. Facies Association B comprises massive ignimbrites that are progressively richer in lithic clast content. This association involved the eruption of more mafic magma, and pumice clasts are gray and poorly vesiculated. Facies Association B is interpreted to record the climax of the eruption. Phreatomagmatic deposits occur at different stratigraphic levels in the four WTT and have different facies characteristics. The deposits reflect the style and degree of magma–water interaction and the local hydrogeology. Very fine-grained, lithic-poor phreatomagmatic surge deposits found at the base of WTT Cupa and WTT Galluccio could record the interaction of the erupting magma with a lake that occupied the Roccamonfina summit depression. Renewed magma–water interaction later in the WTT Galluccio eruption is indicated by fine grained, lithic-bearing phreatomagmatic fall and surge deposits occurring at the top of Facies Association A. They could be interpreted to reflect shifts of the magma fragmentation level to highly transmissive, regional aquifers located beneath the Roccamonfina edifice, possibly heralding a caldera collapse event. Received: 26 August 1996 / Accepted: 27 February 1998     

High-temperature emplacement of the Cerro Galán and Toconquis Group ignimbrites (Puna plateau,NW Argentina) determined by TRM analyses

Estimates of pyroclastic flow emplacement temperatures in the Cerro Galán ignimbrite and Toconquis Group ignimbrites were determined using thermal remanent magnetization of lithic clasts embedded within the deposits. These ignimbrites belong to the Cerro Galán volcanic system, one of the largest calderas in the world, in the Puna plateau, NW Argentina. Temperature estimates for the 2.08-Ma Cerro Galán ignimbrite are retrieved from 40 sites in 14 localities (176 measured clasts), distributed at different distances from the caldera and different stratigraphic heights. Additionally, temperature estimates were obtained from 27 sample sites (125 measured clasts) from seven ignimbrite units forming the older Toconquis Group (5.60–4.51 Ma), mainly outcropping along a type section at Rio Las Pitas, Vega Real Grande. The paleomagnetic data obtained by progressive thermal demagnetization show that the clasts of the Cerro Galán ignimbrite have one single magnetic component, oriented close to the expected geomagnetic field at the time of emplacement. Results show therefore that most of the clasts acquired a new magnetization oriented parallel to the magnetic field at the moment of the ignimbrite deposition, suggesting that the clasts were heated up to or above the highest blocking temperature (T _b) of the magnetic minerals (T _b = 580°C for magnetite; T _b = 600–630°C for hematite). We obtained similar emplacement temperature estimations for six out of the seven volcanic units belonging to the Toconquis Group, with the exception of one unit (Lower Merihuaca), where we found two distinct magnetic components. The estimation of emplacement temperatures in this latter case is constrained at 580–610°C, which are lower than the other ignimbrites. These estimations are also in agreement with the lowest pre-eruptive magma temperatures calculated for the same unit (i.e., 790°C; hornblende–plagioclase thermometer; Folkes et al. 2011b). We conclude that the Cerro Galán ignimbrite and Toconquis Group ignimbrites were emplaced at temperatures equal to or higher than 620°C, except for Lower Merihuaca unit emplaced at lower temperatures. The homogeneity of high temperatures from proximal to distal facies in the Cerro Galán ignimbrite provides constraints for the emplacement model, marked by a relatively low eruption column, low levels of turbulence, air entrainment, surface–water interaction, and a high level of topographic confinement, all ensuring minimal heat loss.     

Contrasting pyroclast density spectra from subaerial and submarine silicic eruptions in the Kermadec arc: implications for eruption processes and dredge sampling

Pyroclastic deposits from four caldera volcanoes in the Kermadec arc have been sampled from subaerial sections (Raoul and Macauley) and by dredging from the submerged volcano flanks (Macauley, Healy, and the newly discovered Raoul SW). Suites of 16–32?mm sized clasts have been analyzed for density and shape, and larger clasts have been analyzed for major element compositions. Density spectra for subaerial dry-type eruptions on Raoul Island have narrow unimodal distributions peaking at vesicularities of 80–85%, whereas ingress of external water (wet-type eruption) or extended timescales for degassing generate broader distributions, including denser clasts. Submarine-erupted pyroclasts show two different patterns. Healy and Raoul SW dredge samples and Macauley Island subaerial-emplaced samples are dominated by modes at ~80–85%, implying that submarine explosive volcanism at high eruption rates can generate clasts with similar vesicularities to their subaerial counterparts. A minor proportion of Healy and Raoul SW clasts also show a pink oxidation color, suggesting that hot clasts met air despite 0.5 to >1?km of intervening water. In contrast, Macauley dredged samples have a bimodal density spectrum dominated by clasts formed in a submarine-eruptive style that is not highly explosive. Macauley dredged pyroclasts are also the mixed products of multiple eruptions, as shown by pumice major-element chemistry, and the sea-floor deposits reflect complex volcanic and sedimentation histories. The Kermadec calderas are composite features, and wide dispersal of pumice does not require large single eruptions. When coupled with chemical constraints and textural observations, density spectra are useful for interpreting both eruptive style and the diversity of samples collected from the submarine environment.     

On the significance of CO2 inclusions in plagioclase microphenocrysts in tholeiite from Moeraki,New Zealand

Liquid plus vapour inclusions of CO₂ are widespread in plagioclase microphenocrysts in small tholeiitic intrusions and tephra of the Moeraki and adjacent areas of northeast Otago, New Zealand. They imply the presence of immiscible CO₂ droplets in the magma at depths of about 7–14 km. Their presence within 5 μm of the edges of microphenocrysts as little as 35 μm thick and 118 μm long indicates minimal feldspar crystal growth during the final ascent and quenching of the magma. Delicate branching clusters of lath-like microphenocrysts escaped disruption during this ascent. Such CO₂ inclusions are a potential source of ‘excess argon’ perturbing K-Ar age determinations. Received March 24, 1993/Accepted September 10, 1993     

Geochemical homogeneity of a long-lived,large silicic system; evidence from the Cerro Galán caldera,NW Argentina

By applying a number of analytical techniques across a spectrum of spatial scales (centimeter to micrometer) in juvenile components, we show that the Cerro Galán volcanic system has repeatedly erupted magmas with nearly identical geochemistries over >3.5 Myr. The Cerro Galán system produced nine ignimbrites (∼5.6 to 2 Ma) with a cumulative volume of >1,200 km³ (DRE; dense rock equivalent) of calc-alkaline, high-K rhyodacitic magmas (68–71 wt.% SiO₂). The mineralogy is broadly constant throughout the eruptive sequence, comprising plagioclase, quartz, biotite, Fe–Ti oxides, apatite, and titanite. Early ignimbrite magmas also contained amphibole, while the final eruption, the most voluminous Cerro Galán ignimbrite (CGI; 2.08 ± 0.02 Ma) erupted a magma containing rare amphibole, but significant sanidine. Each ignimbrite contains two main juvenile clast types; dominant “white” pumice and ubiquitous but subordinate “grey” pumice. Fe–Ti oxide and amphibole-plagioclase thermometry coupled with amphibole barometry suggest that the grey pumice originated from potentially hotter and deeper magmas (800–840°C, 3–5 kbar) than the more voluminous white pumice (770–810°C, 1.5–2.5 kbar). The grey pumice is interpreted to represent the parental magmas to the Galán system emplaced into the upper crust from a deeper storage zone. Most inter-ignimbrite variations can be accounted for by differences in modal mineralogy and crystal contents that vary from 40 to 55 vol.% on a vesicle-free basis. Geochemical modeling shows that subtle bulk-rock variations in Ta, Y, Nb, Dy, and Yb between the Galán ignimbrites can be reconciled with differences in amounts of crystal fractionation from the “grey” parent magma. The amount of fractionation is inversely correlated with volume; the CGI (∼630 km³) and Real Grande Ignimbrite (∼390 km³) return higher F values (proportion of liquid remaining) than the older Toconquis Group ignimbrites (<50 km³), implying less crystal fractionation took place during the upper-crustal evolution of these larger volume magmas. We attribute this relationship to variations in magma chamber geometry; the younger, largest volume ignimbrites came from flat sill-like magma chambers, reducing the relative proportion of sidewall crystallization and fractionation compared to the older, smaller-volume ignimbrite eruptions. The grey pumice clasts also show evidence of silicic recharge throughout the history of the Cerro Galán system, and recharge days prior to eruption has previously been suggested based on reversely zoned (OH and Cl) apatite phenocrysts. A rare population of plagioclase phenocrysts with thin An-rich rims in juvenile clasts in many ignimbrites supports the importance of recharge in the evolution and potential triggering of eruptions. This study extends the notion that large volumes of nearly identical silicic magmas can be generated repeatedly, producing prolonged geochemical homogeneity from a long-lived magma source in a subduction zone volcanic setting. At Cerro Galán, we propose that there is a zone between mantle magma input and upper crustal chambers, where magmas are geochemically “buffered”, producing the underlying geochemical and isotopic signatures. This produces the same parental magmas that are delivered repeatedly to the upper crust. A lower-crustal MASH (melting, assimilation, storage, and homogenization) zone is proposed to act as this buffer zone. Subsequent upper crustal magmatic processes serve only to slightly modify the geochemistry of the magmas.     

Eruptive style of the young high-Mg basaltic-andesite Pelagatos scoria cone,southeast of México City

The eruption of the Pelagatos scoria cone in the Sierra Chichinautzin monogenetic field near the southern suburbs of Mexico City occurred less than 14,000 years ago. The eruption initiated at a fissure with an effusive phase that formed a 7-km-long lava flow, and continued with a phase of alternating and/or simultaneous explosive and effusive activity that built a 50-m-high scoria cone on the western end of the fissure and formed a compound lava flow-field near the vent. The eruption ended with the emplacement of a short lava flow that breached the cone and was accompanied by weak explosions at the crater. Products consist of a microlite-rich high-Mg basaltic andesite. Samples were analyzed to determine the magma’s initial properties as well as the effects of degassing-induced crystallization on eruptive style. Although distal ash fallout deposits from this eruption are not preserved, a recent quarry exposes a large section of the scoria cone. Detailed study of exposed layers allows us to elucidate the mode of cone-building activity. Petrological and textural data, combined with models calibrated by experimental work and melt-inclusion analyses of similar magmas elsewhere, indicate that the magma was initially hot (>1,200°C), gas-rich (up to 5 wt.% H₂O), crystal-poor (~10 vol.% Fo₉₀ olivine phenocrysts) and thus poorly viscous (40–80 Pa s). During the early phase, low magma ascent velocity at the fissure vent allowed low-viscosity magma to degas and crystallize during ascent, producing lava flows with elevated crystal contents at T < 1,100°C, and blocky surfaces. Later, the closure of the fissure by cooling dikes focused the magma flow at a narrow section of the fissure. This led to an increased magma ascent velocity. Rapid and shallow degassing (<3 km deep) triggered ~40 vol.% microlite crystallization. Limited times for gas-escape and higher magma viscosity (6 × 10⁵–4 × 10⁶ Pa s) drove strong explosions of highly (60–80 vol.%) and finely vesicular magma. Coarse clasts broke on landing, which implies brittle behavior due to complete solidification. This requires sufficient time to cool and in turn implies ejection heights of over 1 km, which is much higher than “normal” Strombolian activity. Hence, magma viscosity significantly impacts eruption style at monogenetic volcanoes because it affects the kinetics of shallow degassing. The long-lasting eruptions of Jorullo and Paricutin, which produced similar magmas in western México, were more explosive. This can be related to higher magma fluxes and total erupted volumes. Implications of this study are important because basaltic andesites are commonly erupted to form monogenetic scoria cones of the Trans-Mexican Volcanic Belt.     

Lateral variations within coarse co-ignimbrite lithic breccias of the Kos Plateau Tuff, Greece

 Coarse, co-ignimbrite lithic breccia, Ebx, occurs at the base of ignimbrite E, the most voluminous and widespread unit of the Kos Plateau Tuff (KPT) in Greece. Similar but generally less coarse-grained basal lithic breccias (Dbx) are also associated with the ignimbrites in the underlying D unit. Ebx shows considerable lateral variations in texture, geometry and contact relationships but is generally less than a few metres thick and comprises lithic clasts that are centimetres to a few metres in diameter in a matrix ranging from fines bearing (F2: 10 wt.%) to fines poor (F2: 0.1 wt.%). Lithic clasts are predominantly vent-derived andesite, although clasts derived locally from the underlying sedimentary formations are also present. There are no proximal exposures of KPT. There is a highly irregular lower erosional contact at the base of ignimbrite E at the closest exposures to the inferred vent, 10–14 km from the centre of the inferred source, but no Ebx was deposited. From 14 to <20 km from source, Ebx is present over a planar erosional contact. At 16 km Ebx is a 3-m-thick, coarse, fines-poor lithic breccia separated from the overlying fines-bearing, pumiceous ignimbrite by a sharp contact. This grades downcurrent into a lithic breccia that comprises a mixture of coarse lithic clasts, pumice and ash, or into a thinner one-clast-thick lithic breccia that grades upward into relatively lithic-poor, pumiceous ignimbrite. Distally, 27 to <36 km from source Ebx is a finer one-clast-thick lithic breccia that overlies a non-erosional base. A downcurrent change from strongly erosional to depositional basal contacts of Ebx dominantly reflects a depletive pyroclastic density current. Initially, the front of the flow was highly energetic and scoured tens of metres into the underlying deposits. Once deposition of the lithic clasts began, local topography influenced the geometry and distribution of Ebx, and in some cases Ebx was deposited only on topographic crests and slopes on the lee-side of ridges. The KPT ignimbrites also contain discontinuous lithic-rich layers within texturally uniform pumiceous ignimbrite. These intra-ignimbrite lithic breccias are finer grained and thinner than the basal lithic breccias and overlie non-erosional basal contacts. The proportion of fine ash within the KPT lithic breccias is heterogeneous and is attributed to a combination of fluidisation within the leading part of the flow, turbulence induced locally by interaction with topography, flushing by steam generated by passage of pyroclastic density currents over and deposition onto wet mud, and to self-fluidisation accompanying the settling of coarse, dense lithic clasts. There are problems in interpreting the KPT lithic breccias as conventional co-ignimbrite lithic breccias. These problems arise in part from the inherent assumption in conventional models that pyroclastic flows are highly concentrated, non-turbulent systems that deposit en masse. The KPT coarse basal lithic breccias are more readily interpreted in terms of aggradation from stratified, waning pyroclastic density currents and from variations in lithic clast supply from source. Received: 21 April 1997 / Accepted: 4 October 1997     

Constraints on eruption dynamics of basaltic explosive activity derived from chemical and microtextural study: The example of the Fontana Lapilli Plinian eruption,Nicaragua

The Fontana Lapilli deposit is one of very few examples of basaltic Plinian eruptions discovered so far. Juvenile clasts have uniform chemical composition and moderate ranges of density and bulk vesicularity. However, clast populations include two textural varieties which are microlite-poor and microlite-rich respectively. These two clast types have the same clast density range, making a distinction impossible on that base alone. The high bubble number density (～ 10⁷ cm^? 3) and small bubble population of the Fontana clasts suggest that the magma underwent coupled degassing following rapid decompression and fast ascent rate, leading to non-equilibrium degassing with continuous nucleation as it is common for silicic analogues. The Fontana products have lower microlite contents (10–60 vol.%) with respect to the other documented basaltic Plinian eruptions suggesting that the brittle fragmentation, implied for the other basaltic Plinian deposits, does not apply to the Fontana products and another fragmentation mechanism led the basaltic magma to erupt in a Plinian fashion.     

Rounding of pumice clasts during transport: field measurements and laboratory studies

Volcanic clasts in many pyroclastic density current deposits are notably more round than their counterparts in corresponding fall deposits. This increase in roundness and sphericity reflects different degrees of comminution, abrasion and breakup during transport. We performed experimental measurements to determine an empirical relationship between particle shape and mass loss caused by particle–particle interactions. We consider, as examples, pumice from four volcanoes: Medicine Lake, California; Lassen, California; Taupo, New Zealand; Mount St Helens, Washington. We find that average sample roundness reaches a maximum value once particles lose between 15% and 60% of their mass. The most texturally homogeneous clasts (Taupo) become the most round. Crystal-rich pumice abrades more slowly than crystal-free pumice of similar density. Abrasion rates also decrease with time as particles become less angular. We compare our experimental measurements with the shapes of clasts in one of the May 18, 1980 pyroclastic density current units at Mount St Helens, deposited 4–8 km from the vent. The measured roundness of these clasts is close to the experimentally determined maximum value. For a much smaller deposit from the 1915 Lassen eruption, clast roundness is closer to the value for pumice in fall deposits and suggests that only a few volume percent of material was removed from large clasts. In neither field deposit do we see a significant change in roundness with increasing distance from the vent. We suggest that this trend is recorded because much of the rounding and ash production occur in proximal regions where the density currents are the most energetic. As a result, all clasts that are deposited have experienced similar amounts of comminution in the proximal region, and similar amounts of abrasion as they settle through the dense, near-bed region prior to final deposition.     

Erosion by pyroclastic flows on Lascar Volcano, Chile

 Pyroclastic flows generated in the 19–20 April 1993 eruption of Lascar Volcano, Chile, produced spectacular erosion features. Scree and talus were stripped from the channels and steep slopes on the flanks of the volcano. Exposed bedrock and boulders suffered severe abrasion, producing smoothed surfaces on coarse breccias and striations and percussion marks on bedrock and large boulders. Erosional furrows developed with wavelengths of 0.5–2 m and depths of 0.1–0.3 m. Furrows commonly nucleated downstream of large boulders or blocks, which are striated on the upstream side, and thereby produced crag-and-tail structures. Erosive features were produced where flows accelerated through topographic restrictions or where they moved over steep slopes. The pyroclastic flows are inferred to have segregated during movement into lithic-rich and pumice-rich parts. Lithic-rich deposits occur on slopes up to 14°, whereas pumice-rich deposits occur only on slopes less than 4°, and mainly at the margins and distal parts of the 1993 fan. The lithic-rich deposits contain large (up to 1 m) lithic clasts eroded from the substrate and transported from the vent, whereas pumice-rich deposits contain only small (typically <2 cm) lithic clasts. These observations suggest that lithic clasts segregated to the base of the flows and were responsible for much of the erosive phenomena. The erosive features, distribution of lithic clasts and deposit morphology indicate that the 1993 flows were highly concentrated avalanches dominated by particle interactions. In some places the flows slid over the bedrock causing abrasion and long striations which imply that large blocks were locked in fixed positions for periods of about 1 s. However, shorter striae at different angles, impact marks, segregation of the deposits into pumice- and lithic-rich parts, and mixing of bedrock-derived lithic clasts throughout the deposits indicate that clasts often had some freedom of movement and that jostling of particles allowed internal mixing and density segregation to occur within the flows. Received: 15 July 1996 / Accepted: 15 January 1997     

Quantitative textural analysis of Vulcanian pyroclasts (Montserrat) using multi-scale X-ray computed microtomography: comparison with results from 2D image analysis

X-ray computed microtomography (μCT) was carried out on four pyroclasts from the 1997 Vulcanian explosions of Soufrière Hills Volcano, Montserrat. Three-dimensional data from multiple image stacks with different spatial resolutions (0.37, 4–8, and 17.4 μm px⁻¹) were combined to generate size distributions of vesicles, inter-vesicle throats, crystals, and Fe–Ti oxides over a 3.4–860-μm size range, and to compare the results with those obtained by 2D image analysis on the same samples. Qualitative textural observations are in good agreement with those made in 2D, but μCT provides better resolution of textural features and spatial relationships. Calculation of size distributions requires automated decoalescence of the connected vesicle network. Problems related to this process, in part due to the high porosity of pumice, result in potential artefacts in the calculated size distributions, which are discussed in detail. The main modes of the 3D vesicle volume distributions are systematically shifted to larger sizes compared with those of the 2D distributions. Sample total vesicularities obtained in 3D are within 13 vol.% of those found in 2D, and within 10 vol.% of those measured by He-pycnometry. Total number densities of vesicles and Fe–Ti oxides from the two methods are consistent only to the first order, 3D values ranging from 37% to 309% of those in 2D. Vesicle coalescence, investigated by examining inter-vesicle throat size distributions, occurred in all pyroclasts between neighbouring vesicles of many sizes. The larger the vesicle, the more connected it is.     

Eruption dynamics of Hawaiian-style fountains: the case study of episode 1 of the Kīlauea Iki 1959 eruption

Hawaiian eruptions are characterized by fountains of gas and ejecta, sustained for hours to days that reach tens to hundreds of meters in height. Quantitative analysis of the pyroclastic products from the 1959 eruption of Kīlauea Iki, Kīlauea volcano, Hawai‘i, provides insights into the processes occurring during typical Hawaiian fountaining activity. This short-lived but powerful eruption contained 17 fountaining episodes and produced a cone and tephra blanket as well as a lava lake that interacted with the vent and fountain during all but the first episode of the eruption, the focus of this paper. Microtextural analysis of Hawaiian fountaining products from this opening episode is used to infer vesiculation processes within the fountain and shallow conduit. Vesicle number densities for all clasts are high (10⁶–10⁷ cm⁻³). Post-fragmentation expansion of bubbles within the thermally-insulated fountain overprints the pre-fragmentation bubble populations, leading to a reduction in vesicle number density and increase in mean vesicle size. However, early quenched rims of some clasts, with vesicle number densities approaching 10⁷ cm⁻³, are probably a valid approximation to magma conditions near fragmentation. The extent of clast evolution from low vesicle-to-melt ratio and corresponding high vesicle number density to higher vesicle-to-melt ratio and lower vesicle-number density corresponds to the length of residence time within the fountain.     

Depositional features and transportation mechanism of valley-filling Iwasegawa and Kaida debris avalanches, Japan

 The depositional features of two valley-filling debris avalanche deposits were studied to reveal their transportation and depositional mechanisms. The valley-filling Iwasegawa debris avalanche deposit (ca. 0.1 km³) is distributed along the valleys at the southeastern foot of Tashirodake Volcano, northern Honshu, Japan. Debris-avalanche blocks range in size from <35 m proximally to <10 m in the distal zone and consist dominantly of fragile materials. Debris-avalanche matrix percentages increase from 35–60% in the proximal zone to 95% in the distal zone. The debris-avalanche matrix is greater in volume (80–90%) at the bottom and margins of the deposit. Normal grading of large clasts and reverse grading of wood logs and branches occur within the debris-avalanche matrix. Preferred orientation of 311 wood logs and branches within the deposit coincide with the interpreted local flow direction. The basal part of the deposit is characterized by (1) erosional features and incorporated clasts of underlying material; (2) a higher proportion (30–50%) of incorporated clasts than the upper part; and (3) reverse grading of clasts. The valley-filling Kaida debris avalanche deposit (50 000 y B.P., >0.3 km³) is distributed along the valleys at the eastern-southeastern foot of Ontake Volcano, central Japan. Debris-avalanche blocks range in size from <25 m proximally to <7 m in the medial zone. Debris-avalanche matrix percentages increase from 50–70% in the proximal zone to 80% in the distal zone. The debris-avalanche matrix is more abundant (80–90%) at the bottom part of the deposit. Deformation structures observed in the debris-avalanche blocks include elongation, folding, conjugate reverse faults, and numerous minor faults in unconsolidated materials. Lithic components within the debris-avalanche matrix tend to have a higher percentage of plucked clasts from the adjacent underlying formations. A Bingham "plug flow" model is consistent with the transportation and depositional mechanisms of the valley-filling debris avalanches. In the plug of the debris avalanche, fragile blocks were transported without major rupturing due to relatively small shear stresses in regions of small strain rate. The debris-avalanche matrix was mainly produced by shearing at the bottom and margins of the avalanche. Valley-filling debris avalanches tend to have smaller debris-avalanche blocks and larger amounts of debris-avalanche matrix than do unconfined debris avalanches. These differences may be due to disaggregation of debris-avalanche blocks by shearing against valley walls and interaction between debris-avalanche blocks and valley walls. Oriented wood logs and branches, reverse grading of clasts at the base, and a higher proportion of incorporated clasts at the base are interpreted to result from shearing along the bottom and valley walls. Received: 25 March 1998 / Accepted: 10 October 1998     

Progressive assembly of a massive layer of ignimbrite with a normal-to-reverse compositional zoning: the Zaragoza ignimbrite of central Mexico

The Zaragoza ignimbrite and two enclosing rhyodacite pumice fall layers were emplaced during the 15 km³ (DRE), ∼0.1 Ma Zaragoza eruption from Los Humeros volcanic centre, 180 km east of Mexico City. The ignimbrite comprises several massive flow-units, the largest of which locally exceeds 20 m in thickness and is regionally traceable. It comprises massive lapilli-ash with vertical elutriation pipes, and has a fine-grained inverse-graded base and a pumice concentration zone at the top. It also exhibits an unusual gradational ‘double’ vertical compositional zonation that is widely traceable. A basal rhyodacitic (67.6–69 wt% SiO₂) zone grades up via a mixed zone into a central andesitic (58–62 wt% SiO₂) zone, which, in turn, grades up into an upper rhyodacitic (67.6–69 wt% SiO₂) zone. Zoning is also defined by vertical variations in lithic clast populations. We infer that pyroclastic fountaining fed initially rhyodacite pumice clasts to a sustained granular fluid-based pyroclastic density current. The composition of the pumice clasts supplied to the current then gradually changed, first to andesite and then back to rhyodacite. Inverse grading at the base of the massive layer may reflect initial waxing flow competence. The pumice concentration at the top of the massive layer is entirely rhyodacitic and was probably deposited during waning stages of the current, when the supply of andesitic pumice clasts had ceased. The return to rhyodacitic composition may have been the result of eruption-conduit modification during collapse of Los Potreros caldera, marked in the ignimbrite by a widespread influx of hydrothermally altered lithic blocks, and/or a decrease in draw-up depth from a compositionally stratified magma chamber as the eruptive mass flux waned. The massive layer of ignimbrite thins locally to less than 2 m, yet it still shows the double zonation. Correlation of the zoning suggests that the thin massive layer is stratigraphically condensed, and aggraded relatively slowly during the same time interval as did the much thicker (≤50 m) massive layer.Editorial responsibility: J McPhie     

Vesiculation of high fountaining Hawaiian eruptions: episodes 15 and 16 of 1959 Kīlauea Iki

The 1959 summit eruption of Kīlauea volcano produced the highest recorded Hawaiian fountain in Hawai‘i. Quantitative analysis of closely spaced samples from the final two high-fountaining episodes of the eruption result in a fine-scale textural study of pyroclasts and provide a record of postfragmentation processes. As clast vesicularity increases, the vesicle number density decreases and vesicle morphology shifts from small and round to larger and more irregular. The shift in microtexture corresponds to greater degrees of postfragmentation expansion of clasts with higher vesicularity. We suggest the range of clast morphologies in the deposit is related to thermal zonation within a Hawaiian fountain where the highest vesicularity clasts traveled in the center and lowest traveled along the margins. Vesicle number densities are greatest in the highest fountaining episode and therefore scale with intensity of activity. Major element chemical analyses and fasciculate crystal textures indicate microlite-rich zones within individual clasts are portions of recycled lava lake material that were incorporated into newly vesiculating primary melt.