Radionuclide adsorption to sediments from nuclear waste dumping sites in the Kara Sea

Environmental parameters (salinity, sediment concentration, equilibration time) affecting radionuclide partitioning between sediment and seawater were experimentally investigated for Kara Sea sediments collected from nuclear waste dumping sites in Abrosimov and Stepovogo Bays off Novaya Zemlya. Adsorption kinetics were examined and the influence of salinity and sediment concentration were evaluated over the range of concentrations expected in the bays for the following radionuclides: ^{110 m}Ag; ²⁴¹Am; ¹⁰⁹Cd; ⁶⁰Co; ⁵⁷Co-cobalamine; ¹³⁴Cs; ¹⁵²Eu; ⁵⁴Mn; ¹³³Ba; ¹⁰⁶Ru; and ⁸⁵Sr. The major findings of this investigation are that 1. radionuclide distribution coefficients (K_ds) were most sensitive to variations in sediment character (²⁴¹Am, ⁶⁰Co, ¹⁰⁹Cd) and concentration (⁵⁷Co-cobalamine, ⁸⁵Sr, and ¹³³Ba), 2. distribution coefficients generally decreased with increasing sediment concentration and 3. fast adsorption kinetics (near equilibrium ≈1 day) were observed only for ¹³⁷Cs and ^{110 m}Ag. The observed differences in K_ds for sediments from the two dumpsites exemplifies the importance of undertaking site-specific determinations of K_ds. For purposes of confining radioactive wastes to the dumpsites in Stepovogo and Abrosimov Bays, the findings of this study indicate that based on sediment character alone, Stepovogo Bay will be more effective at retaining radionuclides than Abrosimov Bay. This is unfortunate since less radioactive waste resides in Stepovogo Bay (0.6 PBq) than in Abrosimov Bay (1.4 PBq).     

Bioaccumulation of radiocaesium in Arctic seals

Seals are high trophic level feeders that bioaccumulate many contaminants to a greater degree than most lower trophic level organisms. Their trophic status in the marine food web and wide-spread distribution make seals useful sentinels of arctic environmental change. The purpose of this investigation is to document the levels and bioaccumulation potential of radiocaesium in high latitude seal species for which data have not previously been available. The study was carried out on harp, ringed, and bearded seals caught north of the island archipelago of Svalbard (82°N) in 1999. The results are then compared with previous studies in order to elucidate factors responsible for bioaccumulation in Arctic seals. Concentrations of ¹³⁷Cs were determined in muscle, liver and kidney samples from a total of 10 juvenile and one adult seal. The mean concentration in muscle samples for all animals was 0.23±0.045 Bq/kg f.w. ¹³⁷Cs concentrations in both liver and kidney samples were near detection limits (≈0.2 Bq/kg f.w.). The results are consistent with previous studies indicating low levels of radiocaesium in Arctic seals in response to a long term trend of decreasing levels of ¹³⁷Cs in the Barents Sea region. Bioconcentration factors (BCFs) estimated for seals from NE Svalbard are low, ranging from 34 to 130. Comparing these values with reported BCFs for Greenland seals from other sectors of the European Arctic, we suggest that the combination of physiological and ecological factors on radiocaesium bioaccumulation is comparable among different Arctic seal populations. The application of this work to Arctic monitoring and assessment programs is discussed.     

Pu, Cs and excess Pb in Russian Arctic sediments

The activity ratios of Pu and radiocesium isotopes have been used to delineate the major sources (such as global and close-in (debris) fallout, nuclear fuel reprocessing and fabrication plant effluents) in the environment. We have measured ²³⁸Pu, ^239,240Pu, ¹³⁷Cs, and excess ²¹⁰Pb concentrations in 107 surficial sediments as well as in 5 sediment cores collected in the summer months of 1993 and 1994 from the Ob and Yenisey Rivers (Russia) and the Kara sea. A comparison of the sediment core inventories of ^239,240Pu and ¹³⁷Cs, along with the ²³⁸Pu/^239,240Pu activity ratios, with those expected from global fallout allows us to estimate the relative amounts, if any, of reactor-derived ²³⁸Pu and ^239,240Pu from the dumped reactor sites in the study area.

In surficial sediment samples collected in 1993 and 1994, the ^239,240Pu concentrations varied between 4.2 and 856 mBq kg⁻¹, with a mean of 239 mBq kg⁻¹. In samples with a measurable ²³⁸Pu, the ²³⁸Pu/^239,240Pu activity ratios varied between 0.010 and 0.069, with an average value of 0.035 ± 0.014. This range can be compared to the average ²³⁸Pu/^239,240Pu activity ratio of 0.030 for the year 1993 from nuclear weapons testing and SNAP fallout obtained from soil studies, indicating very little (≤ 5%) additional sources of ²³⁸Pu to the sediments in the study area. The inventories of Pu in the 5 sediment cores from the study area varied between 2.67 ± 0.67 and 24.5 ± 2.2 Bq m⁻² with a mean value of 8.83 Bq m⁻². The ¹³⁷Cs concentrations in the upper 3 cm of the sediments varied between below detection limit to 71.4 Bq kg⁻¹, with a mean of 14.9 Bq kg⁻¹. The ¹³⁷Cs inventories in the 5 sediment cores varied between 156.7 ± 28.3 and 1600 ± 153.3 Bq m⁻², with a mean value of 583.3 Bq m⁻². The mean ratio of inventories of Pu to that of ¹³⁷Cs, 0.015, is comparable to the values in other places in the Arctic region. There is a significant correlation between total organic carbon and concentrations of ¹³⁷Cs, ^239,240Pu and ²¹⁰Pb, suggesting that organic matter-enriched fine particles are a likely carrier phase for these nuclides. The ratio of ¹³⁷Cs/^239,240Pu also suggests that most of these nuclides are derived from global fallout.     

Distribution of Cs and Pu in the surface waters of the East Sea (Sea of Japan)

Surface and subsurface water samples for ¹³⁷Cs and ^239,240Pu analysis were collected in the East Sea (Sea of Japan) during August 1993. The ¹³⁷Cs levels of the surface waters are quite homogeneous in the East Sea (average = 3.1±0.2 mBq kg⁻¹). The ^239,240Pu levels vary from 6 to 10 μBq kg⁻¹ in the surface. ^239,240Pu to ¹³⁷Cs ratios in the surface water are within 0.002 to 0.003. The East Sea may be regarded as a part of the North Pacific Ocean in terms of ¹³⁷Cs dispersal in the surface, where the ¹³⁷Cs contents of the surface seawater seem to be controlled primarily by the atmospheric input. However, since our sampling was made just two months prior to the widely publicized Russian dumping incident on the 17th October 1993, our measurements may provide background data to assess the immediate impact of the Russian dumping on the levels of ¹³⁷Cs and ^239,240Pu in the East Sea.     

Zinc stable isotopes in seafloor hydrothermal vent fluids and chimneys

Many of the heaviest and lightest natural zinc (Zn) isotope ratios have been discovered in hydrothermal ore deposits. However, the processes responsible for fractionating Zn isotopes in hydrothermal systems are poorly understood. In order to better assess the total range of Zn isotopes in hydrothermal systems and to understand the factors which are responsible for this isotopic fractionation, we have measured Zn isotopes in seafloor hydrothermal fluids from numerous vents at 9–10°N and 21°N on the East Pacific Rise (EPR), the TAG hydrothermal field on the Mid-Atlantic Ridge, and in the Guaymas Basin. Fluid δ⁶⁶Zn values measured at these sites range from + 0.00‰ to + 1.04‰. Of the many physical and chemical parameters examined, only temperature was found to correlate with fluid δ⁶⁶Zn values. Lower temperature fluids (< 250 °C) had both heavier and more variable δ⁶⁶Zn values compared to higher temperature fluids from the same hydrothermal fields. We suggest that subsurface cooling of hydrothermal fluids leads to precipitation of isotopically light sphalerite (Zn sulfide), and that this process is a primary cause of Zn isotope variation in hydrothermal fluids. Thermodynamic calculations carried out to determine saturation state of sphalerite in the vent fluids support this hypothesis with isotopically heaviest Zn found in fluids that were calculated to be saturated with respect to sphalerite. We have also measured Zn isotopes in chimney sulfides recovered from a high-temperature (383 °C) and a low-temperature (203 °C) vent at 9–10°N on the EPR and, in both cases, found that the δ⁶⁶Zn of chimney minerals was lighter or similar to the fluid δ⁶⁶Zn. The first measurements of Zn isotopes in hydrothermal fluids have revealed large variations in hydrothermal fluid δ⁶⁶Zn, and suggest that subsurface Zn sulfide precipitation is a primary factor in causing variations in fluid δ⁶⁶Zn. By understanding how chemical processes that occur beneath the seafloor affect hydrothermal fluid δ⁶⁶Zn, Zn isotopes may be used as a tracer for studying hydrothermal processes.     

Iodine-129 concentrations in marginal seas of the north Pacific and Pacific-influenced waters of the Arctic Ocean

Water sampling during the 1993 IV Russian–US Joint Expedition to the Bering and Chukchi Seas (BERPAC) indicates that Pacific Ocean burdens of the long-lived radionuclide ¹²⁹I are relatively low in the Pacific-influenced Arctic, particularly compared to high latitude waters influenced by the North Atlantic. These low concentrations occur despite the presence of potential submerged anthropogenic sources in the East Sea (Sea of Japan), and in the northwest Pacific Ocean, east of the Kamchatka Peninsula. The concentration of ¹²⁹I entering the Arctic Ocean through Bering Strait, 0.7×10⁸ atoms kg⁻¹, is only slightly higher than observed in deep Pacific waters. Similar concentrations (0.44–0.76×10⁸ atoms kg⁻¹) measured in Long Strait indicate no significant transfer of ¹²⁹I eastward into the Chukchi Sea in the Siberian Coastal Current from the Siberian marginal seas to the west. However, the concentrations reported here are more than an order of magnitude higher than the Bering Strait input concentration estimated (1.0×10⁶ atoms kg⁻¹) from bomb fallout mass balances, which supports other existing evidence for a significant atmospheric deposition term for this radionuclide in surface ocean waters. Near-bottom water samples collected in productive waters of the Bering and Chukchi Seas also suggest that sediment regeneration may locally elevate ¹²⁹I concentrations, and impact its utility as a water mass tracer. As part of this study, two deep ¹²⁹I profiles were also measured in the East Sea in 1993–1994. The near-surface concentration of ¹²⁹I ranged from 0.12 to 0.31×10⁸ atoms kg⁻¹. The ¹²⁹I concentration showed a steady decrease with depth, although because of active deep water ventilation, the entire 3000 m water column exceeded natural concentrations of the radionuclide. Atom ratios of ¹²⁹I/¹³⁷Cs in the East Sea also suggest an excess of ¹²⁹I above bomb fallout estimates, also possibly resulting from atmospheric deposition ultimately originating from nuclear facilities.     

Glacial–interglacial changes in Subantarctic sea surface temperature and δO-water using foraminiferal Mg

Laboratory culturing experiments with living Globigerina bulloides indicate that Mg/Ca is primarily a function of seawater temperature and suggest that Mg/Ca of fossil specimens is an effective paleotemperature proxy. Using culturing results and a core-top Neogloboquadrina pachyderma calibration, we have estimated glacial–interglacial changes in sea surface temperature (SST) using planktonic Mg/Ca records from core RC11-120 in the Subantarctic Indian Ocean (43°S, 80°E) and core E11-2 in the Subantarctic Pacific Ocean (56°S, 115°W). Our results suggest that glacial SST was about 4°C cooler in the Subantarctic Indian Ocean and 2.5°C cooler in the Subantarctic Pacific. Comparison of SST and planktonic δ¹⁸O records indicates that changes in SST lead changes in δ¹⁸O by on average 1–3 kyr. The glacial–interglacial temperature change indicated by the Subantarctic Mg/Ca records suggests that temperature accounts for 40–60% of the foraminiferal δ¹⁸O change. We have used the Mg/Ca-based SST estimates and δ¹⁸O determinations to generate site-specific seawater δ¹⁸O records, which suggest that seawater δ¹⁸O was on average 1‰ more positive during glacial episodes compared with interglacial episodes.     

Biokinetics of Radiocobalt in the Asteroid Asterias rubens (Echinodermata): Sea Water and Food Exposures

Uptake and loss of cobalt-57 were investigated in the starfish Asterias rubens, in order to assess its value as a sentinel organism for nearshore radionuclide contamination. Whole-body uptake from sea water was linear over a 32-day exposure period and reached wet weight concentration factor (CF) of 23 ± 5. Bioaccumulation of ⁵⁷Co was dependent upon body compartment, the aboral part of the body wall concentrating cobalt to the greatest degree (wet weight CF: 77 ± 16). After restoration of uncontaminated conditions, radiocobalt was released following an exponential loss kinetics characterized by a biological half-life (T_b1/2) of 27 ± 6 day. Dietary radiocobalt (taken up during a short-term feeding for 24 h on radiolabelled mussels) showed a much more rapid turnover time (T_b1/2: 14 ± 4 d), suggesting that A. rubens accumulates this radionuclide predominantly from sea water. A. rubens, and more particularly the aboral part of its body wall, would readily reveal the presence of an environmental contamination by radiocobalt and could preserve this information over a period of few months.     

Production of selected cosmogenic radionuclides by muons: 2. Capture of negative muons

We have determined the production yields for radionuclides in Al₂O₃, SiO₂, S, Ar, K₂SO₄, CaCO₃, Fe, Ni and Cu targets, which were irradiated with slow negative muons at the Paul Scherrer Institute in Villigen (Switzerland). The fluences of the stopped negative muons were determined by measuring the muonic X-rays. The concentrations of the long-lived and short-lived radionuclides were measured with accelerator mass spectrometry (AMS) and γ-spectroscopy, respectively. Special emphasis was put on the radionuclides ¹⁰Be, ¹⁴C and ²⁶Al produced in quartz targets, ²⁶Al in Al₂O₃ and S targets, ³⁶Cl in K₂SO₄ and CaCO₃ targets, and ⁵³Mn in Fe₂O₃ targets. These targets were selected because they are also the naturally occurring target minerals for cosmic ray interactions in typical rocks. We also present results of calculations for depth-dependent production rates of radionuclides produced after cosmic ray μ⁻ capture, as well as cosmic ray-induced production rates of geologically relevant radionuclides produced by the nucleonic component, by μ⁻ capture, by fast muons and by neutron capture.     

Dating earthquakes with high-precision thorium-230 ages of very young corals

Mass spectrometric techniques have recently yielded significant increases in precision and sensitivity over previous methods for measuring²³⁰Th abundance in corals. To assess the accuracy of²³⁰Th ages, three corals from Vanuatu, whose ages were known from counting annual growth bands, were analyzed. For each sample, the date of growth determined by²³⁰Th analysis (A.D.1969 ± 3, 1932 ± 5,and1806 ± 5; 2σ uncertainties based on analytical error) was indistinguishable from the date determined by counting bands (A.D. 1971–1973, 1935–1937, and 1804–1810), indicating that the²³⁰Th dates are accurate.²³⁰Th dates were also determined for two adjacent emerged heads from Santo Is., Vanuatu, which were thought to have died when they were raised above sea level during coseismic uplift. The dates (A.D.1864 ± 4, 1866 ± 4) were the same, indicating that the heads died at the same time and consistent with the idea that they were killed by coseismic emergence around A.D. 1865. The difference between this date and the date of the only major historically documented earthquake that caused uplift (A.D. 1973,M_s = 7.5), suggests a seismic recurrence interval of108 ± 4y for Santo. Analogous emerged corals from Malekula Is., Vanuatu yielded²³⁰Th dates that were similar to each other (A.D.1729 ± 3, 1718 ± 5) and are inferred to have died during coseismic emergence around A.D. 1729. In conjunction with the date of the only large historically documented earthquake that caused uplift (A.D. 1965,M_s = 7.5), the recurrence interval for Malekula is236 ± 3y. If similar emerged corals can be found, this appraoch may be extended back in time and to other localities because it appears that such features can now be dated both accurately and precisely.     

Helium isotope geochemistry of mid-ocean ridge basalts from the South Atlantic

We report new helium isotope results for 49 basalt glass samples from the Mid-Atlantic Ridge between 1°N and 47°S.³He/⁴He in South Atlantic mid-ocean ridge basalts (MORB) varies between 6.5 and 9.0 R_A (R_A is the atmospheric ratio of1.39 × 10⁻⁶), encompassing the range of previously reported values for MORB erupted away from high³He/⁴He hotspots such as Iceland. He, Sr and Pb isotopes show systematic relationships along the ridge axis. The ridge axis is segmented with respect to geochemical variations, and local spike-like anomalies in³He/⁴He, Pb and Sr isotopes, and trace element ratios such as(La/Sm)_N are prevalent at the latitudes of the islands of St. Helena, Tristan da Cunha and Gough to the east of the ridge. The isotope systematics are consistent with injection beneath the ridge of mantle “blobs” enriched in radiogenic He, Pb and Sr, derived from off-axis hotspot sources. The variability in³He/⁴He along the ridge can be used to refine the hotspot source-migrating-ridge sink model.

MORB from the 2–7°S segment are systematically the least radiogenic samples found along the mid-ocean ridge system to date. Here the depleted mantle source is characterized by⁸⁷Sr/⁸⁶Sr of 0.7022, Pb isotopes close to the geochron and with²⁰⁶Pb/²⁰⁴Pb of 17.7, and³He/⁴He of 8.6–8.9 R_A. The “background contamination” of the subridge mantle, by radiogenic helium derived from off-ridge hotspots, displays a maximum between 20 and 24°S. The HePb and HeSr isotope relations along the ridge indicate that the³He/⁴He ratios are lower for the hotspot sources of St. Helena, Tristan da Cunha and Gough than for the MORB source, consistent with direct measurements of³He/⁴He ratios in the island lavas. Details of the HeSrPb isotope systematics between 12 and 22°S are consistent with early, widespread dispersion of the St. Helena plume into the asthenosphere, probably during flattening of the plume head beneath the thick lithosphere prior to continental breakup. The geographical variation in theHe/Pbratio deduced from the isotope systematics suggests only minor degassing of the plume during this stage. Subsequently, it appears that the plume component reaching the mid-Atlantic ridge was partially outgassed of He during off-ridge hotspot volcanism and related melting activity.

Overall, the similar behavior of He and Pb isotopes along the ridge indicates that the respective mantle sources have evolved under conditions which produced related He and Pb isotope variations.     

Analysis of the time-scaling behaviour in the sequence of the aftershocks of the Bovec (Slovenia) April 12, 1998 earthquake

Analysis of the temporal fluctuations, described by a power spectral density S(f) decaying as 1/f with exponent >0, in the sequence of aftershocks of the Bovec (Slovenia) earthquake of April 12, 1998 has been performed, using the Allan Factor (AF) method. The sequence of the occurrence times of the events with threshold magnitude M_th≥2.0 is characterised by a scale-invariant behaviour from the time scale τ2·10⁴ s with a scaling coefficient 0.9, evaluated by a least-square method. By gradually increasing the threshold magnitude up to M_th=2.9, the AF curves, associated, respectively with the processes of selected events with magnitude M≥M_th, indicate a monotonic decrease of the value of the scaling exponent , in the range of time scales stretching from 10² to 5·10⁵ s. For all the thresholds considered, the AF curves increase monotonically with the counting time and are well fitted by an increasing power-law function for counting times greater than approximately 2·10⁴ s. This monotonic power-law increase indicates the presence of fluctuations on many time scales and therefore of fractal clustering.     

Radionuclide fluxes in the Arabian Sea: the role of particle composition

We investigated the influence of the composition of the vertical particle flux on the removal of particle reactive natural radionuclides (²³⁰Th and ²³¹Pa) from the water column to the sediments. Radionuclide concentrations determined in sediment traps moored in the western, central and eastern Arabian Sea were related to the major components (carbonate, particulate organic matter (POC), opal, lithogenic material) of the particle flux. These data were combined with sediment trap data previously published from the Southern Ocean, Equatorial Pacific and North Atlantic [Z. Chase, R.F. Anderson, M.Q. Fleisher, P.W. Kubik, The influence of particle composition and particle flux on scavenging of Th, Pa and Be in the ocean, Earth Planet. Sci. Lett. 204 (2002) 215–229; J.C. Scholten, F. Fietzke, S. Vogler, M. Rutgers van der Loeff, A. Mangini, W. Koeve, J. Waniek, P. Stoffers, A. Antia, J. Kuss, Trapping efficiencies of sediment traps from the deep eastern North Atlantic: The ²³⁰Th calibration, Deep Sea Research II 48 (2001) 2383–2408]. The correlations observed between the particle-dissolved distribution coefficients (K_d) of ²³⁰Th and ²³¹Pa and the concentrations of the particle types depend on the sediment trap data set used. This result suggests that scavenging affinities of the nuclides differ between oceanic regions. Several factors (K_d values, reactive surface areas of particles, inter-correlations in closed data set) can, however, influence the observed relationships and thus hamper the interpretation of these correlation coefficients as a measure of relative scavenging affinities of the nuclides to the particle types investigated. The mean fractionation factor (F(Pa/Th)=K_d(Pa)/K_d(Th)) from the Equatorial Pacific (F=0.11±0.03) is similar to that from the North Atlantic (F(Pa/Th)=0.077±0.026), and both are lower than the factors from the Arabian Sea (F(Pa/Th)=0.35±0.12) and from the Southern Ocean (F(Pa/Th)=0.87±0.4). For opal concentrations exceeding 60%, an increase in the fractionation factors is observed causing a higher mean fractionation factor for the Southern Ocean trap data set. For the other areas investigated, differences in the mean fractionation factors cannot be related to the particles types considered. In the Arabian Sea, seasonally variable ²³¹Pa_ex/²³⁰Th_ex ratios observed in the sediment traps as well as differences of the ratios between recently deposited phytodetritus (fluff) and normal surface sediments indicate seasonal changes in scavenging processes which the generally accepted reversible scavenging models do not envisage. We assume that variable sinking rates of particles, and/or particles not considered in this study (e.g. colloids, manganese oxides, transparent exopolymer particles) may play an important but as yet unexplored role in deep-water scavenging processes.     

Repeated thermal resetting of phengites in the Mulhacen Complex (Betic Zone, southeastern Spain) shown byAr/Ar step heating and single grain laser probe dating

This study reports the results of the first⁴⁰Ar/³⁹Ar combined induction furnace and laser probe dating of phengites from the Mulhacen HP/LT metamorphic complex in the Betic Cordilleras, southern Spain. Laser step heating and spot fusion analyses on different halves of a split single grain were made with a continuous laser probe. Spot fusion analysis resulted in ages of about 30–31 Ma in the core and ages as low as 25–26 Ma in the rim. Laser step heating on the other half of the grain gave a spectrum with apparent ages increasing from about 25 Ma to 29.5 Ma. The age spectrum and the decreasing ages towards the rim of the grain may imply that resetting essentially occurred by volume diffusion of radiogenic⁴⁰Ar due to late stage reheating resulting from extensional tectonics. Ages around 30 Ma in the core of the grain are interpreted as minimum estimates of the cooling age of the main tectono-metamorphic phaseD₂.

Induction furnace step heating on phengite separates from mica schists and one gneiss resulted in two types of age spectra. Type I spectra show monotonously rising apparent ages from14.5 ± 1.9 Ma to20.7 ± 0.2 Ma, and in a second sample from16.9 ± 0.7 to29.7 ± 0.2 Ma. Type II spectra are characterized by plateaus of14.4 ± 0.1 Ma (the gneiss sample),17.3 ± 0.1 Ma and17.6 ± 0.1 Ma. Type II spectra show low temperature apparent ages significantly below the plateau age, implying resetting subsequent to initial cooling. Modelling of the age spectra demonstrated that the plateau ages are possibly the result of strong resetting (75–85% of argon loss) of an older isotope system. Total fusion of a number of phengite single grains from marbles taken close to type II mica schists yielded ages of15.4 ± 1.2 Ma and17.0 ± 0.7 Ma. The observed repeated resetting is coeval with major volcanic activity in basins adjacent to the metamorphic ranges, pointing to a resetting by advective fluid transport related to volcanism.     

A metamorphic history from micron-scale Pb/Pb chronometry of Archean monazite

Ion microprobe measurements of Pb isotope ratios in monazites have been obtained, in situ, from thin sections using the Cambridge ISOLAB 120. Molecular interferences are sufficiently resolved at an RP of 6500 to allow ²⁰⁷Pb/²⁰⁶Pb dating of monazite with precisions as low as 4–5 Ma (2σ). The results presented here provide important information on the chronological history of the Late Archean metamorphism of the Wind River Range, Wyoming (USA).

Matrix monazites and monazite inclusions in garnets from a metapelite from the northern Wind River Range have been analysed by SIMS. In a previous study peak metamorphic conditions (T = 800°C; P = 8 ± 1 kb^*) were estimated using inclusion assemblages in garnets from this same sample. Isolated monazite inclusions in garnet yield ²⁰⁷Pb/²⁰⁶Pb age estimates of 2781 ± 6 to 2809 ± 10 Ma. Those along fractures yield lower ages (2603–2687 Ma) which are similar to TIMS and SIMS ages of matrix monazites. A single large (500 μm) monazite grain locally preserves growth zoning, but has a recrystallised core and a resorbed (recrystallised?) rim. Age estimates for these three regions are 2788 ± 9 Ma, 2663 ± 4 and 2523 ± 6 Ma, respectively. Thus the inclusion assemblages of Sharp and Essene^* may record peak metamorphic conditions at ca. 2.8 Ga, and indicate a phase of metamorphism that predates by over 100 Ma the emplacement of the Bridger Batholith, the major lithologic component of the northern Wind River Range.

The analysed monazite grains appear to preserve ca. 300 Ma history, even within a single grain. Monazite inclusions in garnet that are fully armoured may provide estimates for the time of garnet growth, even in high grade terranes where most chronometers are reset. The age pattern preserved by the large monazite grain cannot be simply related to diffusion controlled closure. Instead, a chronology is preserved which can be related to the petrographic setting of indicidual grains through in situ analysis.     

Brine history indicated by argon, krypton, chlorine, bromine, and iodine analyses of fluid inclusions from the Mississippi Valley type lead-fluorite-barite deposits at Hansonburg, New Mexico

Argon, krypton, chlorine, bromine, and iodine were measured in a homogeneous population of high-salinity hydrothermal fluid inclusions from the Tertiary-age Mississippi Valley-type (MVT) lead-fluorite-barite deposits at Hansonburg, New Mexico to establish new types of evidence for the history of both the fluid and the major dissolved salts. Noble gases and halogens in fluid inclusions containing 10⁻¹⁰–10⁻⁹ L of brine (Cl= 3 molal) were analyzed by laser microprobe noble-gas mass spectrometry (lmngms) on neutron-irradiated samples.

The concentrations of³⁶Ar (4.7 × 10⁻⁸ molal) and⁸⁴Kr1.8 × 10⁻⁹ molal) in the fluid inclusions are equal to those of fresh surface waters in equilibrium with air at approximately20 ± 5°. The mole ratios ofBr/Cl (1.2 × 10⁻⁴) andI/Cl (1–2 × 10⁻⁶) are among the lowest measured in any natural waters, similar to those of modern brines formed by dissolution of Permian NaCl-bearing evaporites in southeast New Mexico.⁴⁰Ar/³⁶Ar ratios (600) are twice that of air, and indicate that the fluid inclusions had excess radiogenic⁴⁰Ar (1.4 × 10⁻⁵ molal) when trapped. The amount of excess⁴⁰Ar appears to be too large to have been acquired with Cl by congruent dissolution of halite-bearing evaporites, and possibly too small to have been acquired with Pb by congruent dissolution of granitic basement rocks with Proterozoic KAr ages.

From thelmngms data, combined with published Pb and S isotope data, we infer the following sequence of events in the history of the Hansonburg MVT hydrothermal brine: (1) the brine originated as relatively dilute meteoric water, and it did not gain or lose atmospheric Ar or Kr after recharge; (2) the originally dilute fluid acquired the bulk of its Cl and sulfate in the subsurface after recharge by dissolving halite-bearing Permian? marine evaporites; (3) the high salinity brine then acquired most of its Pb and excess radiogenic⁴⁰Ar from interactions with aquifer rocks other than evaporites, possibly clastic sedimentary rocks or basement rocks with Phanerozoic KAr “ages”; and (4) the brine deposited fluorite without having boiled or degassed.     

The effects of a spillage of diesel fuel on a rocky shore in the sub-Antarctic region (Macquarie Island)

On 3 December 1987, the supply ship Nella Dan ran aground at Macquarie Island (54°29′S, 158°58′E) releasing about 270 000 I of oil, mostly light marine diesel, into the sea. At the time of the incident, many marine invertebrates were washed up dead along 2 km of shoreline. Twelve months later, the shore community was investigated using 1. algal and invertebrate populations of the littoral and sublittoral rocky shore, and 2. the invertebrate communities living in the holdfasts of the giant kelp Durvillaea antarctica, which were collected for later examination. Investigations were undertaken at both affected and control locations. Analyses of differences in community structure involved nested ANOVA and multidimensional scaling techniques. On the rocky substrate, the effect of the spill was restricted to some biota of the lower littoral and sublittoral zones—particularly echinoderms and the patellid limpet Nacella macquariensis. There were differences in cover for some algal species between locations. Within the kelp holdfasts, communities were dominated by peracarid crustaceans at control locations and by polychaetes (particularly the opportunistic groups—capitellids, cirratulids and spionids) at oil-affected locations.

The communities have recently been re-surveyed (in the summer of 1994–1995) to assist in the interpretation of the results and to gauge the extent of recovery of the affected biota.     

An integrated paleomagnetic study of Rio Grande de Santiago volcanic succession (trans-Mexican volcanic belt): revisited

We carried out an integrated paleomagnetic, rock-magnetic and paleointensity study of Miocene volcanic succession from the trans-Mexican volcanic belt (TMVB) north of Guadalajara. A total of 37 consecutive basaltic lava flows (326 oriented standard paleomagnetic cores) were collected at Lazo locality. Continuous susceptibility measurements with temperature and hysteresis experiments yield in most cases reasonably reversible curves with Curie points close to that of pseudo-single-domain magnetite. Two geomagnetic reversals were observed in the 300 m thick composite section. Paleosecular variation was lower than the one observed in general during Miocene. It appears that the volcanic units have been emplaced during a relatively short time span of about 1 Ma. The mean paleomagnetic directions obtained from this study do not differ significantly from that expected for the middle Miocene. The mean paleomagnetic direction calculated from all data is I=31.1°, D=354.6°, k=124 and ₉₅=2.1°, N=37. Seventy-two samples with apparently preserved primary magnetic mineralogy and without secondary magnetization, mostly belonging to reverse polarity chron were pre-selected for Thellier paleointensity determination. The flow-mean paleointensity values are ranging from 22.4±3.4 to 53.8±6.0 μT and the corresponding virtual dipole moments (VDMs) are ranging from (5.4±0.8) to (12.0±1.4)×10²² A m². This corresponds to mean value of (7.7±2.2)×10²² A m², which is close to present day geomagnetic field strength. Altogether, our data suggest the existence of relatively high geomagnetic field strength undergoing low fluctuations.     

日本熊本地区高频衰减参数κ与Vs30统计研究

地震工程学中高频衰减参数κ是一个重要的参数。距离为0 km处的参数κ₀在地震动模拟中最常用,其主要控制傅里叶谱在高频部分的衰减特征。计算了日本熊本地区矩震级M_w为5.0~7.1级且震中距小于250 km的81个台站水平方向的κ和V_s30（距离地表30 m深度的平均剪切波速）。在不同矩震级和不同场地距离下,用线性拟合和二次拟合统计了κ与V_s30的关系,并与全球平均水平进行了比较。结果表明:κ与V_s30呈很强的负相关性,相关性随矩震级的增大而增大,且熊本地区的κ要高于全球平均水平。矩震级较小时,二次拟合的效果好于线性拟合,建议用二次拟合的经验关系式进行κ或V_s30的估计。近场情况下,κ总体要小于远场,线性拟合与二次拟合的效果差异不大。对C类场地,拟合的κ与全球平均水平较接近。对B类场地,拟合的κ高于全球平均水平。远场情况下,二次拟合的效果好于线性拟合,但对B类和C类场地,κ均小于全球平均水平。本文的研究结果既能在随机模拟方法中结合场地的地壳放大使用来达到提高模拟精度的目的,又能为只有钻孔信息的地区提供κ的估计。     

Sulfate reduction using methane in sediments beneath a bathyal “cold seep” giant clam community off Hatsushima Island, Sagami Bay, Japan

Two sandy sediment cores (Cores D227-120 and D380) were collected from inside a deep-sea giant clam (Calyptogena soyoae) community off Hatsushima Island, western Sagami Bay, central Japan (35°59.9′N, 139°13.6′E; 1160 m deep) and a muddy sediment core (Core D227-202) was obtained from outside the community by the submersibleShinkai 2000. The chloride concentration of the pore waters is constant vertically and sulfate reduction using sedimentary organic matter occurs in Core D227-202 (21 cm long). The chloride concentrations are lower by 7% at the 7.5–9 cm depth in Core D227-120 (9 cm long) and by 3% at the 11–12 cm depth in Core D380 (16 cm long) than those of the overlying bottom waters in the cores from inside of the community. Sulfate concentration decreases remarkably and dissolved inorganic carbon, alkalinity, ammonium-N, and hydrogen sulfide concentrations increase significantly with increasing depth in Core D380.δ³⁴S values of sulfate ions increase from +20.5 to +35.3‰ andδ¹³C values of dissolved inorganic carbon decrease drastically from −7.0 to −45‰ with increasing depth from the top to the bottom of the core, although theδ¹³C values of the organic carbon of the sediments are−23.7 ± 0.9‰ in Core D380. These results indicate that sulfate reduction using methane is active within the sediments just beneath the living clams and that the hydrogen sulfide produced can be used by endosymbiotic sulfur oxidizing bacteria living in the gills ofC. soyoae in the community.