南非巴伯顿绿岩带条带状铁建造岩石磁学及磁性矿物的组成特征

条带状铁建造(BIFs)中含有大量的亚铁磁性矿物,其组成及来源是认识BIF成因的重要依据。本文研究了南非巴伯顿绿岩带无花果树群(距今约32亿年)恩圭尼亚组的BIFs样品的磁学和矿物学特征。通过测量富铁层与富硅层的磁滞回线、等温剩磁获得曲线与退磁曲线、矫顽力谱分析、一阶反转曲线(FORC)、低温(20～300K)有场/无场冷却曲线以及k-T曲线、Lowrie三轴热退磁曲线,结合扫描电镜观测,揭示出研究样品中磁性矿物主要为赤铁矿和磁铁矿。基于矫顽力谱分析,富铁层中磁铁矿主要是多畴及假单畴颗粒,相对含量平均为2. 1%;赤铁矿的相对含量平均为97. 9%。富硅层中磁铁矿主要为假单畴及超顺磁性颗粒,相对含量平均为4. 6%;赤铁矿相对含量平均为95. 4%。测试样品具有Morin转变特征,转变温度介于250～260K,说明BIFs中主要为赤铁矿(0. 5～6mm)。富硅层样品出现～107K、～125K两个Verwey转变温度,表明其中可能存在生物成因和非生物成因两种类型磁铁矿。     

Magnetic mineralogy of some ring complexes from the South Eastern Desert,Egypt

Ore microscopic study was carried out on a great number of samples collected from four well-dated alkaline rock masses (ring complexes), namely Gabal Mishbeh, Gabal Nigrub El Fogani, Gabal Nigrub El Tahtani, and Gabal El Gezira located in the Eastern Desert of Egypt. These rings consist mainly of wide variety of rock types ranging from basic to acidic and from under saturated to quartz bearing. The opaques of the basic rocks consist mainly of various ilmenite–magnetite intergrowths and differ essentially from those of the acidic rocks where minor amount of titanomagnetite is present. Numerous exsolution, replacement, and deformational textures were described. The distribution of opaque minerals and their intergrowths in the four well-defined ring complexes is described. Systematic rock magnetic measurements such as natural remanent magnetization intensity and initial susceptibility, Curie point, saturation magnetization, and coercive force were carried out, and their results were discussed in the light of opaque mineralogical studies.     

The influence of particle size variations on the magnetic properties of sediments from the north-eastern Irish Sea

This paper considers the magnetic properties of a range of recent and contemporary sediments from the north eastern part of the Irish Sea. Principal component ordinations of the results show a close link between magnetic property variations and particle size. The magnetic properties of a subset of samples, particles sized by a combination of sieving and pipette analysis, confirm that variations in ferrimagnetic (‘magnetite’) grain size parallel those in particle size, despite the fact that the magnetic grains in the fine grades have diameters 1–2 orders of magnitude smaller than those of the particle size fraction in which they occur. This is best explained by postulating that the fine magnetic grains occur in the clay fraction but are present in declining concentrations in the coarser grades up to 4ø as an artefact of the pipette method. Most samples have a biomodal distribution of magnetic minerals, with a coarse mode associated with heavy minerals in the sands or coarse silts, and a fine mode in the clays. Magnetic susceptibility (x) and saturation isothermal remanent magnetization (SIRM) largely pick out the coarse mode where present; anhysteretic remanent magnetization (ARM) largely picks out the fine mode. The results open up the possibility of normalizing samples from these environments for particle size and, more specifically, clay content, by means of ARM or ARM/x values. The most likely source for the uniform and almost exclusive stable single domain magnetite, which dominates the magnetic properties of the clays, is thought to be bacterial magnetosomes. The measurements as a whole do not appear to hold much promise for discriminating sediment source types.     

The role of hematite–ilmenite solid solution in the production of magnetic anomalies in ground- and satellite-based data

Remanent magnetization (RM) of rocks with hematite–ilmenite solid solution (HISS) minerals, at all crustal levels, may be an important contribution to magnetic anomalies measured by ground and satellite altitude surveys. The possibility that lower thermal gradient relatively deep in the crust can result in exsolution of HISS compositions with strong remanent magnetizations (RM) was studied for two bulk compositions within the HISS system. Samples from granulite-terrane around Wilson Lake, Labrador, Canada contains titanohematite with exsolved ferrian ilmenite lamellae. Other samples from the anorthosite-terrane of Allard Lake, Quebec, Canada contain ferrian ilmenite with exsolved titanohematite lamellae. In both cases, the final exsolved titanohematite has similar Ti content and carries dominant magnetic remanence with REM (=NRM/SIRM, where NRM is the natural remanent magnetization and SIRM is the saturation isothermal remanent magnetization) that is comparable to the Ti-free end member. The RM was acquired prior to exsolution and the ilmeno-hematite-rich rock possesses thermal remanent magnetization (TRM), whereas rocks with hemo-ilmenite possess chemical remanent magnetization (CRM). In both cases, we found fairly large homogeneous grains with low demagnetizing energy that acquired intense RM. The magnetism of the ilmeno-hematite solid solution phases is not significantly perturbed by the continuous reaction: ilmeno-hematitetitanohematite solid solution. Hence, the occurrence of HISS in rocks that cooled slowly in a low intensity magnetic field will have an intense magnetic signature characterized by a large REM.     

磁异常解释中的剩余磁化问题

磁铁矿矿石与强磁性火山岩磁性有明显的差别,前者以感应磁化为主,后者以剩余磁化为主.推荐一种利用地磁场变化磁场确定磁异常源磁性特征的方法,评论了几种涉及由剩余磁化引起的磁异常的解释方法.     

武昌地区街道尘埃磁学特征及其对环境污染的指示意义

对在武昌地区4个功能区域(青山、洪山、东湖风景区、东湖开发区)主要交通街道收集的尘埃样品进行详细的环境磁学测量,包括质量磁化率、频率磁化率、等温剩磁退磁系数以及典型样品的磁滞回线参数等。研究结果表明:尘埃样品中剩磁载体均以亚铁磁性矿物为主,样品中的磁性颗粒呈现低矫顽力的磁铁矿特征,软磁性的磁性矿物是样品剩余磁性的主要载体。尘埃样品χ、SIRM的区域分布特征受区域周围工业、车流量及道路状况等多种环境因素的影响,在4个功能区域中存在明显的磁性差异:青山工业区污染较重,东湖开发区、洪山、东湖风景区次之;硬剩磁(HIRM)的分布可能指示了道路交通来源的磁颗粒特征,东湖开发区和青山工业区由于行驶的货车和重型车辆较多,表现出硬剩磁量值较高。与其他城市(兰州、西安、南京、徐州等)相比,整个武昌地区街道尘埃样品的磁性含量仍较高,说明在城市环境方面还有待于进一步改善和保护。     

汶川地震断裂带多次地震活动新证据

虹口乡八角庙出露完整的映秀—北川断裂带剖面断层岩,高分辨率磁化率测试揭示出多个具有高磁化率特征的断层岩带。系统的岩石磁学分析证明一层褐色断层岩相对围岩具有最大的磁化率值,存在新生成的磁铁矿和拥有相似的天然剩磁(NRM)和非磁滞剩磁(ARM)强度衰减过程。高磁化率特征是含铁顺磁性矿物受到断层滑移过程产生摩擦生热作用生成磁铁矿所致。同时断层岩还获得了热剩磁,记录了地震活动磁学信息。结合汶川地震科学钻探项目1号孔(WFSD-1)磁化率和岩石磁学研究结果,说明映秀—北川断裂带包含多层具有高磁化率特征的断层岩,暗示了多次强震的发生。具有高磁化率特征的断层岩可以作为判定地震活动的标志之一。     

Reliable Determination of Paleointensity in Igneous Rocks Bearing Thermochemical Remanent Magnetization

Doklady Earth Sciences - Oxidation decomposition of titanomagnetite grains to the magnetite–ilmenite lattice during the formation of igneous rock can lead to thermochemical remanent...     

Physical properties and petrologic description of rock samples from an IOCG mineralized area in the northern Fennoscandian Shield, Sweden

The Tjårrojåkka Fe–Cu-prospect in northern Sweden is considered an example of a Fe-oxide Cu–Au (IOCG) deposit and is hosted in metamorphosed Paleoproterozoic volcanic and intrusive rocks. Rock samples from 24 outcrops were collected for petrophysical analysis (magnetic susceptibility, remanent magnetization, variation of magnetic susceptibility with temperature, Curie temperature and density). The major Cu-prospect in the area has been studied by magnetic and electron microprobe analyses of four selected rock samples. The samples are from an exploration well that intersects the main Cu-mineralized body.The magnetic analyses show that magnetite is the dominant magnetic mineral, while hematite and other Fe-minerals are present in minor amounts. The electron microprobe observations confirm the presence of magnetite and further indicate that hematite is an alteration product of magnetite. Moreover, microprobe observations indicate that Fe-sulfides are present in negligible amounts in the samples from the Tjårrojåkka area. The strong spatial relationship of Cu-minerals (e.g., chalcopyrite) and the oxidation of magnetite to hematite suggest that the presence of rocks with low magnetic susceptibility in areas dominated by high susceptibility rocks may be a signal of related Cu-prospects.     

Investigating the potential of using environmental magnetism techniques as pollution proxy in urban road deposited sediment

The use of mineral magnetic techniques as pollution proxy for road deposited sediment was explored using various statistical approaches. Standard techniques were adopted for measurement of mineral magnetic and geochemical parameters. The analyses of magnetic parameters revealed that the samples were dominated by ferrimagnetic minerals and multidomain grains. This implied that the magnetic fractions in the samples might be of anthropogenic origin. Results also indicate that the samples were dominated by low coercive, magnetically soft minerals. Thermomagnetic curves confirmed magnetite as the remanence bearing magnetic mineral having a Curie point temperature of ~580 °C. The strong association observed between magnetic susceptibility, susceptibility of anhysteric remanent magnetization and saturation isothermal remanent magnetization and aluminum, titanium, manganese, iron, chromium and lead demonstrated that these metals occurred as ferrimagnetic particles of technogenic origin resulting from vehicular sources. Assessment of pollution status of the road deposited sediment identified silicon and lead as the priority pollutants of concern. Generally, pollution load index was <1 (mean, 0.66 ± 0.14), indicating that the samples were not polluted in the overall, but the metals were in the buildup stage requiring constant monitoring. The sources of pollutants from principal component and cluster analyses identified the sources of pollution to be mainly from vehicular emissions such as brake linings, exhaust materials, tire wear, corroded metal parts, abrasion of lubricating oil and road construction materials. This study found that mineral magnetic techniques offer great potential as pollution proxy for soil pollution studies.     

马兰黄土和离石黄土的磁学性质

中国黄土-古土壤系列的磁学性质,如磁化率等被广泛用于古气候和古环境研究,这必须建立在对黄土-古土壤的剩磁的性质和获得剩磁的机制以及古土壤磁性增强的原因有深入了解的基础之上。作者通过对洛川和吉县剖面马兰黄土和离石黄土的磁学性质的深入研究,对黄土与古土壤磁学性质差异的各种表现,对它们剩磁的性质,对古土壤磁性增强的原因以及磁性变化对古气候、古环境研究的意义进行了讨论,并对利用某些磁学性质建立的黄土-古土壤形成的时间模式提出了质疑。     

Depositional magnetization of Carboniferous Limestones from the Craven Basin of northern England

Carboniferous Limestones in the Craven Basin of northern England carry a stable natural remanent magnetization (NRM) the intensity of which is facies dependent. Dark argillaceous limestones are most strongly magnetized and pure, pale coloured limestones most weakly magnetized. Partial thermal and alternating field demagnetization suggest that magnetite is the principal carrier of the remanence although some haematite is present in the limestone. The presence of magnetite is confirmed by the low temperature transition, isothermal remanent magnetization (IRM build-up curves) and microprobe analysis. Partial demagnetization of IRM and ARM suggest that the magnetite is relatively coarse grained and in the multidomain state. There are no indications of pseudo-single domain behaviour but magnetite of this type cannot be excluded as a possible remanence carrier. A grain size estimate of 10–20 μm based on coercive force and remanent coercive force is compatible with the theoretical consideration of grain size. The limestones show a weak but marked magnetic susceptibility anisotropy. This anisotropy defines a depositional fabric which indicates that the magnetization is a depositional remanent magnetization (DRM). A DRM was acquired by each specimen before compaction and cementation and was preserved because of the reducing conditions which prevailed in the early diagenetic environments of the limestones.     

红粘土的磁学性质研究

本文对陕西宝鸡剖面红粘土上部进行了详细的岩石磁学研究，确定了该地区红粘土的主要磁性矿物是磁铁矿。赤铁矿相对含量很少，对剩余磁性贡献较小。磁性质不稳定的磁赤铁矿存在于红粘土中，但不影响剩磁稳定性。特征剩磁载体主要是磁铁矿。磁性矿物的粒度是以准单畴为主。红粘土的短时间弛豫粘滞剩磁很强，因此在零磁空间进行退磁和剩磁测量是非常重要的。     

Palaeomagnetism and rock magnetism of the Deccan traps

Extensive work on the palaeomagnetism of the Deccan traps by several workers has revealed only one reversal (normal-reverse-normal) of the geomagnetic field during the period of eruption of these flows. The scatter in the natural remanent magnetic directions of different flows in a sequence of these traps is rather large and it persists even after magnetic cleaning. Generally this large scatter of directions is attributed to the geomagnetic secular variation during formation of the traps. Recent studies of the magnetic properties of the trap samples indicate that the presence of multidomain magnetite in a lava sequence differs from locality to locality in the Deccan trap province and so the stability of their natural remanent magnetization. While these features can be clearly perceived, an understanding of the same seems to be quite difficult. However, it appears that part of the scatter in directions could be due to the alteration of the magnetic minerals in the Deccan traps and hence it would not be proper to relate the entire scatter to the secular variation.     

Mass and magnetic properties for 3D geological and geophysical modelling of the southern Agnew–Wiluna Greenstone Belt and Leinster nickel deposits,Western Australia

Physical property measurements provide a critical link between geological observations and geophysical measurements and modelling. To enhance the reliability of gravity and magnetic modelling in the Yilgarn Craton's Agnew–Wiluna Greenstone Belt, mass and magnetic properties were analysed on 157 new rock samples and combined with an existing corporate database of field measurements. The new samples include sulfide ore, serpentinised and olivine-bearing ultramafic host-rocks, granitoid, and felsic and mafic volcanic and volcaniclastic country rock. Synthesis of the data provides a useful resource for future geophysical modelling in the region. Several rock types in the region have sufficiently distinct physical properties that a discriminant diagram is proposed to facilitate a basic classification of rock types based on physical properties. However, the accumulation of emplacement, metamorphic, hydrothermal and structural processes has complicated the physical properties of the rocks by imposing duplicate and sometimes opposing physical property trends. The data confirm that massive sulfide and ultramafic rocks have the most distinctive mass and magnetic properties but with variability imposed by their complex history. Sulfide content imposes the strongest control on densities, but can only be identified when comprising >10 vol% of the rock. The pyrrhotite-rich Ni-sulfide assemblages generally have similar magnetic properties to the host ultramafic rocks, but can have much lower susceptibilities where the thermal history of the rocks has favoured development of hexagonal pyrrhotite over monoclinic pyrrhotite. In ultramafic rocks that contain <10 vol% sulfides, density and susceptibility are primarily controlled by serpentinisation, with olivine breaking down to serpentine and magnetite in the presence of water. Serpentinisation dramatically lowered densities and increased susceptibilities, but had limited influence on the intensity of remanent magnetisation. All ultramafic rocks contain multidomain magnetite, and most contain low coercivity grains prone to overprinting by in situ viscous remanent magnetisation or drilling-induced isothermal remanent magnetisation during extraction. Despite the low coercivities, Koenigsberger ratios of 1–20 are observed indicating that viscous remanent magnetisation aligned parallel to the present Earth field must be considered in any magnetic modelling. It is also noted that coarser-grained intrusive varieties of all rock types (e.g. granite, gabbro) show remanent magnetisation intensities 1–2 orders of magnitude greater than their extrusive equivalents (felsic and basaltic volcanics).     

Magnetic polarity zonation within the El Teniente copper–molybdenum porphyry deposit, central Chile

El Teniente porphyry copper deposit, the world’s greatest intrusion-related Cu–Mo ore body, is hosted within basaltic–andesitic volcanic and gabbroic rocks (mafic complex). This ore body is strongly affected by multiple events of alteration/mineralization with pervasive potassic and chloritic alteration and coetaneous with associated copper mineralization. We present paleomagnetic results obtained from oriented samples at four locations within the mine and from two drill cores, 200 and 400 m long, respectively. Samples are representative of all the main hydrothermally altered rock units, with emphasis on the mafic host rock and dacitic (Teniente dacite porphyry) and dioritic porphyry intrusions. Magnetic experiments [hysteresis loop, isothermal remanent magnetization (IRM), k–T curves, thermal, and alternating field demagnetization] show the presence of prevailing magnetite. Microscope and SEM observations show two families of magnetite, (a) large multidomain magnetite grains, associated with biotite and chlorite of various different hydrothermal alteration events, and (b) abundant small to medium grain-size magnetite (<10 μm) contained within plagioclase, either related to an early Na–Ca–Fe alteration or included within plagioclase during magmatic crystal growth. While the Teniente dacite porphyry and the quartz diorite–tonalite have low magnetic susceptibility (<0.0005 SI) and low natural remanent magnetization (NRM, 10⁻⁴–10⁻³ Am⁻¹), the mineralized mafic host rocks have usually high susceptibility (>0.01 and up to 0.2 SI) with NRM in the range 0.1–2 Am⁻¹. Most mafic complex rock samples have univectorial magnetizations during alternating field or thermal demagnetization. Within the mine, the magnetic polarity is spatially distributed. In the northern part of the deposit, the Teniente dacite porphyry, the associated hydrothermal breccias, and the hosting mafic complex record a reverse polarity magnetization, also observed in the El Teniente sub-6 mine sector immediately to the east and southeast. In the eastern part of the deposit, a normal polarity is observed for samples of the mafic complex from the two long drill cores. There is no evidence for superimposed magnetizations of opposite polarities in samples of the mafic complex. Anhysteretic remanent magnetization (ARM) in a DC field of 40 μT and NRM have similar magnitude and comparable behavior upon alternating field demagnetization. The well-defined strong remanent magnetizations associated with high unblocking temperatures (>500°C) indicate an acquisition of remanent magnetization during mineralization by circulating high temperature fluids related with ore deposition. Paleomagnetic results and the recorded polarity zonation suggest multiple mineralization events occurred at El Teniente, each one with its own evolution stages, superimposed within the district. These results indicate that a simplified broad four-stage model for El Teniente, as presented and overly employed by many authors, divided in (1) late magmatic, (2) main hydrothermal, (3) late hydrothermal, and (4) posthumous stage, does not recognize various short-lived single mineralization events, some superimposed and some distinctly separated in time and space. There is no paleomagnetic evidence for post-mineralization deformation     

碳酸盐岩中磁性矿物及其在古地理研究中的作用

磁性矿物及其转化现象在碳酸盐岩中十分常见。在其沉积演化各个阶段形成的磁性矿物,分别携带了它们形成时的古环境信息,是沉积古地理学和环境磁学的直接研究对象。磁性矿物在其形成过程中还受到地磁场的磁化作用,致使其获得了原生剩磁。鉴于对这类磁性矿物的准确鉴定及其所携带的原生剩磁成分的准确辨识,是获得可靠古地磁资料和建立地块极移曲线、编制非当今界限的古地理图与进行古地理重建的前提,从而成为古地磁学和大地构造古地理学的主要研究对象。在后生阶段形成的磁性矿物,通常由原有的磁性矿物转化而成,这种转化作用常起因于构造运动及与其密切相关的岩浆活动和流体活动。由于在其转化过程中,地磁场也相应发生了变化,所以新生磁性矿物就携带上新的剩磁（重磁化剩磁）,因而它们也应该是古地磁学和大地构造古地理学的重要研究对象。如果在进行古地磁研究时,增加与构造事件和热事件相关样品的采集,加强磁性矿物的成因矿物学研究,那么就可以为进行古地理重建,提供更加可靠和更加丰富的古地磁资料。由此表明,在古地理学这一门综合性很强的地球科学,发展到巳经形成许多分支学科的今天,有必要关注磁性矿物与古地理研究之间的密切联系。     

Magnetic Fabric Studies of High-Grade Metamorphic Rocks from the Juiz de Fora Complex,Ribeira Belt,Southeastern Brazil

Granulite from 66 sites along the Além-Paraiba dextral shear zone were collected for magnetic analyses. The rocks were affected by the Braziliano orogeny, which was responsible for the present structural pattern. Magnetic fabrics were determined applying anisotropy of low—field magnetic susceptibility (AMS, all sites) and anisotropy of remanence magnetization (ARM, in 21 sites). The ferromagnetic minerals are magnetite, titanohematite, and in some samples, minor pyrrhotite. Hysteresis curves show that both para— and ferromagnetic minerals are the carriers of AMS. Thus AMS is due to the preferred crystallographic orientation of paramagnetic matrix minerals and titanohematite, to the shape anisotropy of magnetite grains, or to a combination of all three. ARM was performed imposing both anhysteretic remanence (AAR) and isothermal remanence (AIRM). The AMS, AAR, and AIRM fabrics are coaxial and are tectonic in origin. Their parallelism indicates that both ferromagnetic and paramagnetic minerals recorded the same metamorphic event. A passive—marker model is suggested for ferromagnetic minerals at the outcrop scale. The magnetic foliation is very close to the strike of the Além Paraíba shear zone, suggesting that this generated the local rock fabrics during the Braziliano orogeny.     

Paleomagnetism and rock magnetism of the Neoproterozoic Itajaí Basin of the Rio de la Plata craton (Brazil): Cambrian to Cretaceous widespread remagnetizations of South America

A detailed rock magnetic and paleomagnetic study was performed on samples from the Neoproterozoic Itajaí Basin in the state of Santa Catarina, Brazil, in order to better constrain the paleogeographic evolution of the Rio de la Plata craton between 600 and 550 Ma. However, rock magnetic properties typical of remagnetized rocks and negative response in the fold test indicated that these rocks carried a secondary chemical remanent magnetization. After detailed AF and thermal cleaning, almost all samples showed a normal polarity characteristic remanent magnetization component close to the present geomagnetic field. The main magnetic carriers are magnetite and hematite, probably of authigenic origin. The mean paleomagnetic pole of the Itajaí Basin is located at Plat = − 84°, Plong = 97.5° (A95 = 2°) and overlaps the lower Cretaceous segment of the apparent polar wander path of South America, suggesting a cause and effect with the opening of the South Atlantic Ocean. A compilation of remagnetized paleomagnetic poles from South America is presented that highlights the superposition of several large-scale remagnetization events between the Cambrian and the Cretaceous. It is suggested that some paleomagnetic poles used to calibrate the APWP of Gondwana at Precambrian times need to be revised; the indication of remagnetized areas in southern South America may offer some help in the selection of sites for future paleomagnetic investigations in Precambrian rocks.     

Case studies on the use of temperature-dependent susceptibility for the characterisation of magneto-mineralogical changes during metamorphism

Based on three case studies we show that low-, and high-temperature measurements of magnetic susceptibility (κ(T)-curves) in combination with other mineralogical and rock magnetic methods constitute a sensitive tool for the identification of magnetic minerals. In this study, changes in mineral composition and grain texture, related to various metamorphic processes, are shown for minerals from the titanomagnetite and ilmenite-hematite series. If magnetite is associated with titanomagnetite, the shape of the κ(T)-curve at low temperature is significantly different from that of pure magnetite and pure titanomagnetite and we suspect that susceptibility measurements, especially low temperature, are sensitive to magnetic textures and superimposing effects due to different magnetic phases.