Post-depositional 137Cs Mobility in the Sediments of Three Shallow Coastal Lagoons, SW England

We present ¹³⁷Cs profiles for three low lying coastal lagoons in Southwest England that show a decline in activity with sediment depth. ¹³⁷Cs inventories are lower than expected by comparison with local reference inventories despite the fact that sampling was undertaken in the deep-water zone of each lake where sediment and ¹³⁷Cs focusing would be expected. At all three locations, lake sediment ⁷Be and unsupported ²¹⁰Pb (²¹⁰Pb_un) inventories are not significantly lower than the local reference inventory. ¹³⁷Cs inventories in the study cores range from 38 to 95% of local reference inventories. The standing water level and mud: water interface at two sites are below maximum tide level and, at all three sites, salinity increases significantly in the water columns between low and high tide and in the pore waters of the underlying sediments. We suggest that the difference in hydrostatic pressure between sea level and standing water levels in the lagoons forces salt water up through the sediment column and that monovalent cations (especially Na⁺ and K⁺) replace ¹³⁷Cs on exchange sites leading to the upward migration and loss of ¹³⁷Cs. Rising sea levels may therefore contribute to remobilisation and release of ¹³⁷Cs to the aquatic environment from the sediments of coastal lagoons.     

A model of Cs activity profile for soil erosion studies in uncultivated soils of Mediterranean environments

A model to simulate ¹³⁷Cs profiles in soils during the time in which they are being eroded is proposed. The model uses one parameter to characterize the cesium transference in the soil and another to express the erosion rate. To test the model, ¹³⁷Cs profiles of stable and eroded soils were collected at sampling sites located on semi-arid and temperate slopes in the Central Ebro basin, Spain. The ¹³⁷Cs profiles, corresponding to uncultivated soils with natural vegetation cover, were simulated using this model. The ¹³⁷Cs inventories and profiles calculated with the model are very similar to those measured experimentally, and thus it is possible to calculate soil erosion rates in physiographically diverse Mediterranean environments.     

Quantifying sediment transport across an undisturbed prairie landscape using cesium-137 and high resolution topography

Soil erosion is a global environmental problem, and anthropogenic fallout radionuclides offer a promising tool for describing and quantifying soil redistribution on decadal time scales. To date, applications of radioactive fallout to trace upland sediment transport have been developed primarily on lands disturbed by agriculture, grazing, and logging. Here we use ¹³⁷Cs to characterize and quantify soil erosion at the Konza Prairie Long-Term Ecological Research (LTER) site, an undisturbed grassland in northeastern Kansas. We report on the small scale (< 10 m) and landscape scale (10 to 1000 m) distribution of fallout ¹³⁷Cs, and show significant variability in the concentrations and amounts of ¹³⁷Cs in soils at our site. ¹³⁷Cs soil concentrations and amounts typically vary by 10% to 30% on small scales, which most likely represents the spatial heterogeneity of the depositional processes. Landscape scale variability of soil ¹³⁷Cs was significantly higher than small scale variability. Most notably, soils collected on convex (divergent) landforms had ¹³⁷Cs inventories of 2500 to 3000 Bq m^− 2, which is consistent with the expected atmospheric inputs to the study area during the 1950s and 1960s. Concave landforms, however, had statistically lower inventories of 1800 to 2300 Bq m^− 2. The distribution of ¹³⁷Cs on this undisturbed landscape contrasts significantly with distributions observed across disturbed sites, which generally have accumulations of radioactive fallout in valley bottoms. Because the upslope contributing area at each sampling point had a significant negative correlation with the soil inventory of ¹³⁷Cs, we suggest that overland flow in convergent areas dominates soil erosion at Konza on time scales of decades. Very few points on our landscape had ¹³⁷Cs inventories significantly above that which would be predicted from direct deposition of ¹³⁷Cs on the soil surface; we conclude therefore that there is little net sediment storage on this undisturbed landscape.     

Using unsupported lead-210 measurements to investigate soil erosion and sediment delivery in a small Zambian catchment

Traditional techniques used to assemble information on rates of erosion and soil redistribution possess many important limitations. As a result, the use of environmental radionuclides, and more particularly ¹³⁷Cs measurements, has attracted increasing attention in recent years as a means of obtaining spatially distributed information on rates of erosion and deposition. The application of the ¹³⁷Cs approach is, however, hampered in some areas of the world where ¹³⁷Cs inventories are low and the low concentrations of ¹³⁷Cs found in soils and sediments cause problems for laboratory analysis. These problems will increase as time progresses due to the radioactive decay of the existing inventory, most of which was deposited as fallout ca. 40 years ago. This contribution explores the potential for using another fallout radionuclide, namely unsupported ²¹⁰Pb, as an alternative to ¹³⁷Cs, in the small (63 km²) Upper Kaleya catchment in southern Zambia where ¹³⁷Cs inventories are already very low. The approach employed with unsupported ²¹⁰Pb is similar to that used for ¹³⁷Cs, although the essentially constant fallout of unsupported ²¹⁰Pb through time means that the resulting estimates of erosion and soil redistribution rates reflect a longer period of time (ca. 100 years rather than ca. 40 years). The estimates of erosion and deposition rates derived from the unsupported ²¹⁰Pb measurements are used to construct typical sediment budgets for the three main land-use types in the Upper Kaleya catchment, namely, commercial cultivation, communal cultivation and bush grazing. The results obtained from the unsupported ²¹⁰Pb are compared with equivalent results based on ¹³⁷Cs measurements provided by a previous investigation undertaken in the study catchment. The two sets of results are highly consistent. The study reported confirms the viability of using unsupported ²¹⁰Pb as an alternative to ¹³⁷Cs in this environment and demonstrates that conjunctive use of both radionuclides can provide additional information on the erosional history of a study area.     

川中丘陵区和三峡地区小流域侵蚀产沙的塘库沉积137Cs断代

选择川中丘陵区和三峡地区四川盐亭、南充和重庆开县的4个小流域,采集塘库沉积泥沙137Cs样品,确定了1963年以来塘库淤沙量,并据此分析了流域输沙模数和侵蚀模数。研究表明,开县春秋沟的淤沙模数最高,为1869t.km-2.a-1;盐亭武家沟和集流沟分别为701t.km-2.a-1和710 t.km-2.a-1;南充天马湾沟为566 t.km-2.a-1。对小流域地貌特征的分析和谷地水田取样结果表明,除塘库淤积区外,各小流域谷地内基本无泥沙淤积。因此,除南充天马湾沟按现有水面面积作为淤积面积求算的淤沙模数明显偏小外,其他小流域的塘库淤沙模数基本可以表征各研究小流域的侵蚀模数。对研究小流域侵蚀产沙影响因素的分析表明,除降雨和土地利用状况外,地形起伏、土壤抗蚀性及岩层产状也是三地侵蚀程度差异的重要原因。     

Sediment focusing in six small lakes inferred from radionuclide profiles

Sediment focusing in six small lake basins is inferred from sedimentary radionuclide profiles. The activities of¹³⁷Cs and⁹⁺²⁴⁰Pu do not decrease to zero above the sub-surface maximum but tail off gradually. Similar behavior is observed in the sediments of three lakes for¹³⁴Cs and⁶⁰Co, which were added only to the lake. This upward tailing is not caused by bioturbation or erosion from the watershed. Sediment focusing is the likely cause, further substantiated by inventories in deep sediments of⁹⁺²⁴⁰Pu and²¹⁰Pb that are twice as high as expected from atmospheric fallout. Inventories in deep sediments of¹³⁷Cs are in several cases lower than expected from atmospheric fallout, and cannot be explained by hydraulic flushing from the lakes, as this would require unreasonable flushing rates. The low¹³⁷Cs inventories and the sedimentary profiles of the¹³⁷Cs/⁹⁺²⁴⁰Pu ratio are consistent with¹³⁷Cs removal from the water column by boundary scavenging to shallow sediments. The profiles and inventories of all three nuclides could be reproduced with a simple three box model, assuming focusing of shallow sediments (50–60% of total sediment area) to deep sediments with a rate constant of 5–10% yr^–1.This is the seventh of a series of papers to be published by this journal following the 20 ^th anniversary of the first application of²¹⁰Pb dating of lake sediment. Dr P. G. Appleby is guest editing this series.     

~(137)Cs示踪法土壤侵蚀量估算的本底值问题

137Cs示踪法因能快速、相对简便地估算土壤侵蚀量而在土壤侵蚀定量研究中得到广泛应用。本底值获取是137Cs示踪法的关键和基础。在具有空间异质性多因素综合作用下,本底值呈现高度的空间异质性。针对本底值空间变异性,从气候气象要素、地形、土壤属性、土地利用/覆被四个方面阐明各因素与本底值空间变异的作用机理。分析了当前137Cs示踪法应用中在本底值获取时参考点存在性及选点的准确性、单个或几个本底值对研究区本底值的代表性和参考点采样设计。提出划分侵蚀测定单元、建立多本底值体系和进行地形校正解决当前137Cs示踪法中本底值存在问题的对策。侵蚀测定计算单元的划分原则和方法、根据已有参考点的137Cs本底值推算各单元137Cs本底值的技术方法、定量化研究各因素对137Cs的作用是今后需要深入的工作。     

Chernobyl radiocaesium in upland watershed-lake systems,Galloway, south west Scotland

Levels of Chernobyl radiocaesium found in the upland region of Galloway, south west Scotland were relatively high e.g. catchment mean¹³⁴Cs inventories ranged from 5.72±2.64 kBq m² to 8.72±1.46 kBq m². The nuclear weapons test¹³⁷Cs content of soils and peats was significantly augmented. Accurate assessment of spatial variations and temporal changes in the levels of contamination, however, are inhibited by its marked, short-range heterogeneity. No significant change in mean catchment inventories was detected over a twelve month period. Lake sediment inventories, however, were consistently enhanced from initially lower levels of contamination than their catchments' surfaces. Pre Chernobyl catchment and lake sediment¹³⁷Cs inventories, however, show no such contrast. Both are substantially lower than rainfall based predictions. These observations of the relative levels of Chernobyl and pre-existing radiocaesium in watersheds and their waterbodies have important implications for both the assessment of the catchment and lake residence times of particle-associated contaminants and the use of lake sediment records as monitors of such pollutants.     

The role of soil erosion and fluvial processes in the post-fallout redistribution of Chernobyl-derived caesium-137: a case study of the Lapki catchment, Central Russia

The central area of the Russian Plain received substantial amounts Cs-137 fallout as a result of the Chernobyl accident in 1986, with inventories exceeding 40 kBq m⁻² in many of the areas close to Chernobyl. Concern over the longer-term fate of this contamination has focused attention on the need to predict the post-fallout redistribution of the radiocaesium and, thus, future changes in the spatial distribution of contamination in the landscape. Since radiocaesium reaching the land surface as fallout is rapidly and strongly adsorbed by soil and sediment particles, any attempt to predict its post-fallout redistribution must focus on erosion and sediment delivery processes and must rely heavily on a knowledge of the geomorphological processes involved. This paper reports a detailed investigation of post-fallout Cs-137 redistribution in the 2.18-km² Lapki catchment in the Middle-Russian Upland, which has required consideration of soil erosion processes, sediment delivery pathways, sediment delivery ratios and sediment sinks. The time elapsed since the Chernobyl accident is currently insufficient to result in significant reduction of Cs-137 inventories in eroding areas, but areas of deposition on both the lower slopes and on the balka sides and bottoms are already marked by significant increases in Cs-137 inventories. The results obtained emphasise that any attempt to develop meaningful predictions of the longer-term redistribution of Chernobyl-derived Cs-137 fallout within the Russian Plain must be based on a sound and detailed understanding of the linkage between the slopes and the balka systems and the fate of sediment entering the balka systems.     

Variability in soil redistribution in the northern Chihuahuan Desert based on Cesium measurements

A hypothesis for understanding the stability of northern Chihuahuan Desert landscapes is that the distribution of soil resources changes from spatially homogeneous in arid grasslands to spatially heterogeneous in invading shrublands. Since radioactive fallout ¹³⁷Cesium (¹³⁷Cs) was deposited uniformly across the landscape during the 1950s and 1960s and was quickly adsorbed to soil particles, any redistribution of ¹³⁷Cs across the landscape would be due to soil redistribution or instability at either plant-interspaces or on a landscape scale. The concentration of ¹³⁷Cs in soils collected from different vegetation communities (black grama grass, tarbush, tobosa grass, and mesquite) at the USDA-ARS Jornada Experimental Range in the Northern Chihuahuan Desert in New Mexico was determined. At the black grama grass and tobosa grass sites, ¹³⁷Cs was uniformly distributed at the plant interspace scale. At the mesquite sites, ¹³⁷Cs was concentrated in the dune area under mesquite shrubs with little to no ¹³⁷Cs in the interdune areas. ¹³⁷Cs data support the hypothesis that significant soil redistribution has occurred at dune sites created by invading mesquite. In the arid grassland-shrub sites with black grama grass, tobosa grass, and tarbush the ¹³⁷Cs data support the hypothesis of spatially homogeneous distribution of soil resources. High concentrations of ¹³⁷Cs in the biological soil crusts (0–5 mm) at the tarbush sites indicate that biological soil crusts can contribute to the stability of these sites.     

Preliminary results of usingCs to study wind erosion in the Qinghai-Tibet Plateau

The world fallout of caesium-137 (¹³⁷Cs) associated with nuclear weapons testing during the 1950s and 1960s has provided a valuable man-made tracer for studies of soil erosion and sediment delivery. But relatively few researchers have used it to estimate wind erosion. In this paper, the¹³⁷Cs technique is introduced into the study of wind erosion and its modern processes in the Qinghai-Tibet Plateau. Two¹³⁷Cs reference inventories of 982·11 and 2376·04 Bq m⁻²was established preliminarily, which distribute in the south and mid-north parts of the study area respectively. By analysing the patterns of¹³⁷Cs depth profiles from sampling sites, the aeolian processes of erosion and deposition along nearly 40 years has been revealed, i.e. the shrub coppice dunes(S1) and semi-fixed dunefields (S3) had experienced the alternation of erosion and deposition, while the grasslands (S4, S6 and S7) and dry farmlands (S5) suffered erosion only. By using the¹³⁷Cs model, the average wind erosion rates for shrub coppice dune (S1), semi-fixed dunefields (S3), dry farmlands (S5) and grasslands (S4, S6 and S7) were estimated to be 84·14, 69·43, 30·68 and 21·84 tha⁻¹a⁻¹respectively, and for the whole Plateau, averaging 47·59 ha⁻¹a⁻¹which can be regarded as the medium erosion standard. These results derived from¹³⁷Cs for the first time have significant implications for the further research of wind erosion and desertification control in the Qinghai-Tibet Plateau.     

The sedimentary record of spheroidal carbonaceous fly-ash particles in shallow Danish lakes

Spheroidal carbonaceous particles (SCP) from combustion of oil and coal have been quantified in cores from top sediments of Danish shallow lakes. Chronologies were provided by ²¹⁰Pb-dating supplemented by measurements of other radionuclides (¹³⁷Cs, ¹³⁴Cs, ²⁴¹Am). All cores show indications of sediment mixing but most still retain a characteristic SCP record. Deposition rates of SCP were low until the 1920s, increased strongly after World War II, reached maximum levels around 1970 and decreased thereafter. These results were used to infer a new chronology for a sediment core from a shallow lake, from which a ²¹⁰Pb chronology had previously been published.SCP inventories are positively correlated with ²¹⁰Pb inventories and dry matter accumulated since 1900, suggesting that absolute SCP accumulation rates may be more influenced by sedimentary processes than by atmospheric fluxes. The concentrations of SCP in surface sediments of the six lakes do, however, correlate with regional SO₂ emissions.     

Environmental Change and Atmospheric Contamination on Svalbard: Sediment Chronology

Sediment cores collected from eight lakes along the western coast of Svalbard as part of a project investigating atmospheric pollution and environmental change in Arctic regions were dated radiometrically using natural (²¹⁰Pb) and artificial (¹³⁷Cs and ²⁴¹Am) fallout radionuclides. At four sites the sedimentation rates were relatively uniform, and in consequence the ²¹⁰Pb dates were relatively unambiguous. At the remaining sites there were irregularities in the ²¹⁰Pb activity versus depth profiles, indicating significant variations in the net sediment accumulation rate during the past 120 years. At these sites, there were significant differences between ²¹⁰Pb dates calculated using the two standard simple dating models, constant rate of supply (CRS) and constant initial concentration (CIC). In most cases, stratigraphic dates based on the ¹³⁷Cs and ²⁴¹Am records supported use of the CRS model, though at one site (Ossian Sarsfjellet) the CIC model appeared more appropriate. The irregularities in the ²¹⁰Pb records were mainly caused by episodes of accelerated sedimentation due, for example, to inwash or slump events, though at some sites there appears to have been a systematic increase in sediment accumulation rates in recent decades. Sediment accumulation rates were generally lower at the northern sites, and higher at the more southerly locations. Mean sediment accumulation rates varied by an order of magnitude, ranging from 0.002 to 0.050 g cm⁻² y⁻¹ (0.02–0.10 cm y⁻¹). ²¹⁰Pb fluxes measured from the core inventories were mostly in the range 34–80 Bq m⁻² y⁻¹ typical of Arctic sites. Much higher values, recorded at two sites (Birgervatnet and Daltjørna), may be due to significant inputs from the catchments during spring thaw.     

Deriving hillslope sediment budgets in wildfire-affected forests using fallout radionuclide tracers

Information on post-fire sediment and nutrient redistribution is required to underpin post-fire catchment management decisions. Fallout radionuclide budgets (²¹⁰Pb_xs, ¹³⁷Cs and ⁷Be) were derived to quantify soil redistribution and sediment yield in forested terrain following a moderately severe wildfire in a small (89 ha) water supply catchment in SE Australia. Application of these techniques in burnt terrain requires careful consideration of the partitioning of radionuclides between organic and mineral soil components. Beryllium-7 and ²¹⁰Pb_xs were shown to be closely associated with ash, litter and soil organic matter whereas ¹³⁷Cs was more closely associated with subsurface coarse mineral soil. Comparison of the three tracer budgets indicated that the dominant sediment source areas were ridgetops and steep valley sideslopes, from which burnt surface material was conveyed to the stream network via pre-existing gullies. Erosion was predominantly driven by sheetwash, enhanced by soil water repellency, and modified by bioturbation which both supplies subsurface sediment and provides sinks for erosive overland flow. Footslope and riparian zones were not important sediment source areas. The estimated event-based (wildfire and subsequent rainfall) sediment yield is 58 ± 25 t km^− 2, based on fallout ⁷Be measurements. The upper estimate of total particulate phosphorus yield (0.70 kg ha^− 1) is more than 10 times that at equivalent unburnt sites. This illustrates that, soon after fire, burnt eucalypt forest can produce nutrient loads similar to those of agricultural catchments. The tracer budgets indicate that wildfire is an important control on sediment and phosphorus inputs to the stream network over the decadal timeframe and the pulsed nature of this release is an important concern for water quality management.     

Application of210Pb in soils

The spectroscopic measurement of soil samples is described.²¹⁰Pb data from a soil survey in western-Europe are briefly reviewed. The average²¹⁰Pb flux from the atmosphere, as determined from²¹⁰Pb _exc soil inventories, is 90 Bq m^–2a^–1. A simple one-dimensional box-chain model is described. The model simulates the vertical, post depositional transport of natural and fall-out radionuclides in the soil. Simulation of measured²¹⁰Pb _exc ,¹³⁴Cs,¹³⁷Cs, and²⁴¹Am soil profiles shows that mixing (bioturbation) is a very efficient transport mechanism. Lead seems to be strongly fixed to organic and clay particles. It is transported by the displacement of the organic and clay carrier substances. The mean residence time of lead, caesium, plutonium and americium in organic rich forest soils is in the order of 250–1000 years. An applicability study in investigate the use of²¹⁰Pb in erosion problems showed erosion rates from 60–180 g m^–2a^–1 on organic rich forest and meadow sites with 10°–25° slopes.This is the eighth of a series of papers to be published by this journal following the 20 ^th anniversary of the first application of²¹⁰Pb dating of lake sediments. Dr P. G. Appleby is guest editing this series.     

Assessing the accumulation of sorbed isotope <Superscript>137</Superscript>Cs within the upper components of the fluvial network in the zone of Chernobyl contamination

We examine the use of two alternative techniques for assessing the redistribution volumes of sorbed ¹³⁷Cs within the upper components of the fluvial network, based on the concept of catchment as a lithodynamical system. In terms of one of them, we made a substantive analysis of changes in reserves on accumulative positions where the ¹³⁷Cs distribution curves showed a significant increase in radionuclide content levels. We carried out a typization o the accumulation surfaces in order to extrapolate data, obtained for a group of soil profiles, to the territory of the entire catchment and to make a direct assessment of the increases in accumulation. An alternative technique was used to assess the volumes of accumulated sediment loads on accumulative positions by analyzing the ¹³⁷Cs distribution curves, and to correlate with denudation zones in the drainage area under consideration. Values of the wash-out rates for the period 1986–2012 have been obtained, which are necessary for the formation of the accumulative layer observed. We calculated the volume of ¹³⁷Cs swept away during 26 years after the Chernobyl accident, based on information regarding the volumes of initial reserves in the denudation zones and a correlation between the erosion rate and a specific reduction in reserves. It is established that the technique on the basis of analyzing the wash-out zones featuring high economical efficiency can be used in assessing ¹³⁷Cs migration for larger territories with relatively low labor-consuming effort.     

滇西和黔中表土中7Be与137Cs分布特征对比研究

滇西和黔中28个表土剖面分层土样^7Be、^137Cs比活度对比分析可见：滇西地区表土层顶部^7Be/^137Cs为100－1000，而黔中地区仅10－100；两地区表土层中^7Be的表观比活度和最大渗透深度总体相近；^137Cs在黔中表土层中的比活度总体较滇西地区略高。而黔中表土中^7Be累计值的偏低现象，映射了该地区强烈的水土流失。为解释滇西和黔中地区之间表土层顶部^7Be/^137Cs的地区差异，需进一步讨论两核素的湖泊沉积物蓄积特征。     

Distribution of <Superscript>137</Superscript>Cs and <Superscript>210</Superscript>Pb in sediments of tidal flats in north Jiangsu Province

Seven cores were collected from different sediment zones of tidal flats at Xinyanggang in north Jiangsu province in August 2007. Sediment grain-size distribution and radioisotopes of ¹³⁷Cs and ²¹⁰Pb analysis were carried out for these cores. Sediment rates of the cores and radioisotopes distribution in surface sediment in different zones of the tidal flat were calculated from the ¹³⁷Cs and ²¹⁰Pb activities in sediments cores. The results indicated that each tidal zone had experienced different evolution phases, hydrological dynamics in the tidal flats made the grain-size of the surface sediment change gradually. ¹³⁷Cs and ²¹⁰Pb activities on the superficial layer of the cores varied spatially and the reason was discussed. On tidal flats, the fluctuation of ¹³⁷Cs and ²¹⁰Pb activities in the cores reflected the special sedimentary characteristics. Vegetation affects the grain-size distribution and the vertical profiles of ¹³⁷Cs and ²¹⁰Pb in the upper depths. ¹³⁷Cs and ²¹⁰Pb chronology got the comparable average sediment rates on the tidal flat. The characteristics of ¹³⁷Cs and ²¹⁰Pb in the cores reflected various depositional dynamical environments in different tidal zones and gave information on the different evolvement phases of the tidal zones. Based on the information of grain-size distribution, texture of the cores, sediment rates and topography, the evolution lines of the tidal flat were reconstructed.     

Sediment accumulation of Dianchi Lake determined by 137Cs dating

The water quality of Dianchi Lake declines quickly and the eutrophication is getting serious. To identify the internal pollution load of Dianchi Lake it is necessary to evaluate its sediment accumulation. Sedimentation rates of Dianchi Lake are determined by ¹³⁷Cs dating. However, ¹³⁷Cs vertical distribution in sediment cores of Dianchi Lake has special characteristics because Dianchi Lake is located on the southeast of the Qinghai-Tibet Plateau, the Kunming quasi-stationary front is over the borders of Yunnan and Guizhou where the specific precipitation is distributed. Besides 1954, 1963 and 1986 ¹³⁷Cs marks can be determined in sediment cores, a ¹³⁷Cs mark of 1976 representing the major period of ¹³⁷Cs released from China unclear test can be determined and used for an auxiliary dating mark. Meanwhile Dianchi Lake is divided into seven sections based on the water depth, basin topography, hydrological features and supplies of silt and the lakebed area of each section is calculated. The mean annual sedimentation rates for seven sections are 0.0810, 0.1352, 0.1457, 0.1333, 0.0904, 0.1267 and 0.1023 g/cm²a in 1963–2003, respectively. The gross sediment accumulation of the lake is 26.18×10⁴ t/a in recent 17 years and 39.86×10⁴ t/a in recent 50 years. Foundation: National Natural Science Foundation of China, No.40771186; The Key Project of the State Key Laboratory of Soil Sustainable Agriculture, Nanjing Institute of Soil Sciences, Chinese Academy of Sciences, No.5022505 Author: Zhang Yan (1962–), Ph.D and Associate Professor, specialized in environmental change.