略论煤的变质问题

我国煤的变质作用根据受热的主要热源及其作用方式和煤质特征，可归纳为三种基本类型。即：深成变质作用、岩浆热变质作用和动力变质作用。此外，1988年中国地质大学潘治贵等，通过对青海热水矿区研究发现而命名为一种新变质作用类型-热水变质作用。在前人研究的基础上，笔者拟就影响变变质的主要因素谈谈看法，供讨论。     

变质作用分类的历史回顾和新的试行分类雏议

根据变质作用分类研究的历史回顾和最新进展,本文介绍了一个试行的、较系统的变质作用分类方案,可分为局部性的变质作用和区域性的变质作用两个大类9个类型.局部性的变质作用包括以下5个类型:(1)接触变质作用,包括热变质作用、接触交代变质作用和高热变质作用3个亚类;(2)低-中-高温动力变质作用,包括低-中-高温韧性剪切带变质作用和温压递进逆冲断层变质作用2个亚类;(3)冲击变质作用;(4)水热变质作用;(5)燃烧变质作用.区域性的变质作用可分为以下4个类型:(6)早前寒武纪克拉通基底变质作用-低中压-中高温区域变质作用,可分为5个亚类,分别是低-中压角闪岩相变质作用、低-中压麻粒岩相变质作用、低-中压角闪岩相-麻粒岩相变质作用、低-中压绿片岩相-角闪岩相递增的变质作用和区域超高温麻粒岩相变质作用;(7)造山带变质作用,可分为3个亚类,分别是低温-低压区域动力变质作用、碰撞造山变质作用和深俯冲高压-超高压区域变质作用;(8)埋深变质作用;(9)洋底变质作用.     

冀东麻粒岩相区的变质作用及其演化

根据对表壳岩、中酸性侵入岩和基性岩墙的变质变形作用及相互关系的深入研究,确定冀东麻粒岩相区在早前寒武纪时期主要经历了两期变质作用,每期变质作用均经历了一个长期的演化过程,峰期阶段的变质条件均达到了麻粒岩相。第一期变质作用(3000～2500Ma)的PTt演化具近等压冷却(IBC)特点的逆时针轨迹,第二期变质作用(2300～2000Ma)是近等压加热(IBH)特点的顺时针轨迹,反映两期变质作用具有不同的构造环境和演化过程。     

21世纪最初十年变质岩石学研究进展

21世纪以来变质岩石学发展迅猛.对大型俯冲带和造山带综合数值模拟研究,所得到的变质作用p-T-t与以往一维热模拟结果很不相同;利用内部一致性热力学数据库,进行变质相平衡的定量研究,改变了人们对变质反应和相平衡关系的理解,开辟了定量研究变质作用的新阶段;超高压变质作用的深入研究,发现了更多超高压变质作用的标志及地体,指示陆壳俯冲深度可能达300～350 km,并对地壳岩石深俯冲的机理及变质作用演化进行了进一步探讨;对麻粒岩尤其是高压和超高温麻粒岩的研究,进一步了解了麻粒岩相条件下的深熔作用与熔体演化机理,为认识早前寒武纪的板块作用与造山过程提供了新的窗口;利用多种方法对俯冲带变质流体的研究,为深刻认识俯冲带的岩浆作用及地幔演化提供了更为广阔的视野.     

极端条件下的变质作用——变质地质学研究的前沿

在简单回顾变质地质学形成和发展的不同历程的基础上,扼要地总结了近年来有关极端条件下的超高压变质作用、超高温变质作用和很低温变质作用研究的现状和存在的问题。根据峰期变质温度的不同,结合其矿物组合和地质产状特征,进一步提出将超高压变质作用划分为低温超高压变质作用(峰期变质温度低于600℃)、中温超高压变质作用(峰期变质温度介于600~900℃)和高温超高压变质作用(峰期变质温度大于900℃)。低温超高压变质作用与大洋板块的冷俯冲作用有关,其研究对于探讨俯冲带水流体的循环和地幔水流体的成因具有重要意义;中、高温超高压变质作用与大陆深俯冲作用相关,是目前超高压变质作用研究的热点领域;高温超高压变质作用的研究与探讨地球内(深)部组成和结构相关,一直是地质学家关注的前沿问题。超高温变质作用研究正在向深入发展,中国有关超高温变质作用的研究才刚刚起步;很低温变质作用的研究长期以来没有得到应有的重视,随着研究手段和方法的不断完善和提高,将会有大的发展。极端条件下的变质作用是近年来固体地球科学研究取得的重要进展,是目前变质地质学研究的前沿领域。     

A study on the relationships between metamorphic anatexis and petrogenesis and mineralization

Metamorphic processes are closely associated with the formation and evolution of the crust and highly related to petrogenesis and mineralization processes. Dynamic systematic analysis indicates that regional metamorphism-migmatization-metamorphic anatexis process is a temperature-pressure progressive process. Metamorphic anatexis process is a critical part with its unique pressure/temperature and thermodynamic, dynamic and geochemical characteristics. The concept of metamorphic anatexis system (MAS) introduced by the author includes the essential factors of material resources, energy resources, process format, material transportation and concentration, occurring time and location. Based on the essential factors of MAS, metamorphic anatexis process-related granitic rocks and deposit cases are discussed on their petrogenesis and/or mineralizaion mechanisms. The discussion points out that granites in the Ailaoshan and Yunkai metamorphic zones are of metamorphic anatexis origin. The genesis of pegmatite ore deposits in metamorphic zones and shear zone gold deposits in shear zones are highly related to metamorphic anatexis process. The study of metamorphism process involved in ore formation and material transport is a hot subject concerned by the international geological circles. Thorough investigations into the relationships between metamorphic anatexis and petrogenesis-meneralization processes are of great importance not only in geological theory, but also in industrial practice.     

信息动态

变质岩是组成硅酸盐地球的三大岩石之一,对了解深部地壳的组成和地壳演化、研究地壳热结构历史记录、恢复变质岩原岩建造和指导找矿都具有重要意义.本文综述了近十年来我国变质岩学科在超高压/高温变质作用、相平衡、变质流体以及变质岩地球化学等几方面的研究进展.在已有研究基础上,近十年来我国学者又相继在柴北缘野马滩、南阿尔金、东昆仑、北秦岭及西南天山的不同类型岩石中发现了柯石英、斯石英假象(副象)以及其他一些特征的超高压变质指示矿物和结构,确定了这些超高压变质带的野外分布特征.在超高温变质作用研究方面,识别并确定了华北克拉通孔兹岩带超高温变质岩石的出露规模,准确的变质时代和时间尺度的限定以及P-T-t轨迹的构建,尤其是在进变质阶段的确定方面取得了一系列进展.在变质相平衡研究方面,在热力学数据库和矿物相及熔体活度模型进一步完善的基础上,开发了新的模拟计算软件GeoPS,建立了基于ACF组分分析的变质基性岩完整相平衡关系;同时在深熔作用与花岗质岩石成因的定量模拟方面也有重要进展.在矿物温压计研究方面,首次建立了与斜长石无关的GBAQ压力计、二云母压力计和白云母Ti温度计.在元素地球化学方面,高场强元素(如Ti、Nb、Ta、Zr、Hf等)和卤族元素(如F、Cl、Br和I)在变质脱水过程中的迁移和分异,以及变价元素(如V、Fe、W和Mo等)对指示氧逸度的变化研究方面都取得了一系列进展.在变质流体研究方面,对俯冲带高压-超高压流体活动的证据、流体成分的确定及流体活动时限等方面的研究也取得了明显进展.     

Influences of the unsaturated,saturated, and riparian zones on the transport of nitrate near the Merced River,California, USA

Transport and transformation of nitrate was evaluated along a 1-km groundwater transect from an almond orchard to the Merced River, California, USA, within an irrigated agricultural setting. As indicated by measurements of pore-water nitrate and modeling using the root zone water quality model, about 63% of the applied nitrogen was transported through a 6.5-m unsaturated zone. Transport times from recharge locations to the edge of a riparian zone ranged from approximately 6 months to greater than 100 years. This allowed for partial denitrification in horizons having mildly reducing conditions, and essentially no denitrification in horizons with oxidizing conditions. Transport times across a 50–100-m-wide riparian zone of less than a year to over 6 years and more strongly reducing conditions resulted in greater rates of denitrification. Isotopic measurements and concentrations of excess N₂ in water were indicative of denitrification with the highest rates below the Merced River. Discharge of water and nitrate into the river was dependent on gradients driven by irrigation or river stage. The results suggest that the assimilative capacity for nitrate of the groundwater system, and particularly the riverbed, is limiting the nitrate load to the Merced River in the study area.     

山西五台山区滹沱群变质玄武岩岩石学、地球化学特征及其成因意义

在野外地质调查的基础上,选取滹沱群豆村亚群底部四集庄组玄武岩、顶部青石村组玄武岩和东冶亚群中下部河边村组玄武岩,进行岩石学和地球化学研究。分析结果表明：玄武岩主量元素高TiO2、TFeO,低MgO,具有演化的基性岩浆的特征。稀土元素含量相对较高,具有弱—中等程度的轻稀土元素富集,中等程度的轻重稀土元素分异,轻微的Eu异常;玄武岩中Cr、Ni含量变化较大,但与Mg#具有很好的正相关性。微量元素配分图解中具有明显的Sr负异常,部分样品具有Nb、Ta和Ti负异常,无Zr、Hf负异常,与岛弧火山岩不同;同时Nb、Ta无分异,Zr/Hf值较高,具有板内玄武岩浆的特征。综合分析认为,滹沱群玄武岩可能形成于板内裂谷环境。在岩浆上升过程中发生橄榄石与尖晶石的分离结晶作用,同时不同程度地受到地壳的混染。     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

深港西部通道填海区地下水铜、钒、铊、镉、钨迁移的实验研究

填海工程使滨海地区的地下水物理化学条件改变,导致该区域地下水中重金属浓度升高。本文以深港西部通道填海区为例,采用实验室模拟填海条件的办法,初步探讨了影响填海区地下水重金属迁移的关键因素。模拟实验结果表明,填海区地下水中钨元素含量升高与地下水淡化、淤泥氧化过程以及填料风化有关;铜元素含量升高则与淤泥氧化过程以及填料风化有关;钒元素含量升高与地下水淡化和淤泥氧化过程有关,而其他元素含量升高则主要与填料风化释放有关。     

贵州岑巩羊桥罗家塘杷榔动物群的发现及其后生动物早期演化的意义

岑巩县羊桥乡罗家塘杷榔组仅出露中-上部地层,岩性单一,均为青灰、灰绿色粉砂质泥、页岩.在其上部层位发现了俞氏贵州始海百合(Guizhoueocrinus yui Zhao,Parsley et Peng,2007),计有棘皮动物始海百合、腕足动物、软体动物-软舌螺、节肢动物-三叶虫等8属9种,包括了2个未定名的新种和1...     

扬子北缘马元铅锌矿床闪锌矿微量元素及S-Pb-He-Ar-C同位素地球化学研究

马元铅锌矿床是近年扬子陆块北缘铅锌找矿的新突破。矿体呈层状、似层状产于碑坝隆起翼部震旦系灯影组角砾状白云岩层间构造带中,围岩蚀变很弱。矿石中硫化物以闪锌矿、方铅矿为主,中粗粒晶质结构,充填于白云岩角砾间。闪锌矿富集Cd、Ge、Ag,贫In、Tl、Se,Ga/In为6~132,Ge/In多1000,成矿温度以中-低温为主。金属硫化物ε~(34)S值相对集中,为12.9‰~19.4‰,平均为17.4‰,来自于海相硫酸盐的还原。铅同位素组成稳定,~(206)Pb/~(204)Pb为17.858~17.918:~(207)Pb/~(204)Pb为15.603~15.694;~(208)Pb/~(204)Pb为37.756~38.046,具有造山带和上地壳铅的特征,震旦系可能提供了金属成矿物质。闪锌矿中流体包裹体的~3He/~4He为0.03Ra~1.05Ra,~(40)Ar/~(36)Ar为326.1~765.1,~(38)Ar/~(36)Ar为0.183~0.204,表明成矿流体主要为地壳流体和饱和大气水(大气降水或海水)的混合。闪锌矿内流体包裹体挥发分δ~(13)C_(CH_4)值为-36.01‰~-28.80‰,δ~(13)C_(C_2H_6)值为-27.72‰~-22.44‰,δ~(13)C_(CO_2)值为-23.24‰~-9.68‰,表明有机流体参与了成矿作用。石英、方解石的H-O同位素结果表明具有海水和有机水混合的特征。可见,成矿流体具有两种流体混合的特征,一为蒸发海水与围岩反应所形成的盆地卤水,二为有机流体。推测矿区可能存在一个古油气藏,由于TSR生成一高硫气藏,为区内还原性有机流体的主要来源。当富含Pb、Zn等成矿物质的成矿流体运移至富含CH_4和H_2S的还原性流体的矿区角砾岩带时,两种流体混合,Pb、Zn等遇到H_2S发生反应而沉淀成矿,并伴生热液白云石等,形成了马元铅锌矿床。综上所述,我们认为马元矿床属MVT型铅锌矿床。     

Pressure Increases, the Formation of Chromite Seams, and the Development of the Ultramafic Series in the Stillwater Complex, Montana

This paper explores the hypothesis that chromite seams in theStillwater Complex formed in response to periodic increasesin total pressure in the chamber. Total pressure increased becauseof the positive V of nucleation of CO₂ bubbles in the melt andtheir subsequent rise through the magma chamber, during whichthe bubbles increased in volume by a factor of 4–6. Byanalogy with the pressure changes in the summit chambers ofKilauea and Krafla volcanoes, the maximum variation was 0•2–0•25kbar, or 5–10% of the total pressure in the Stillwaterchamber. An evaluation of the likelihood of fountaining andmixing of a new, primitive liquid that entered the chamber withthe somewhat more evolved liquid already in the chamber is basedupon calculations using observed and inferred velocities andflow rates of basaltic magmas moving through volcanic fissures.The calculations indicate that hot, dense magma would have oozed,rather than fountained into the chamber, and early mixing ofthe new and residual magmas that could have resulted in chromitecrystallizing alone did not take place. Mixing was an important process in the Stillwater magma chamber,however. After the new magma in the chamber underwent {smalltilde}5% fractional crystallization, its composition, temperature,and density approached those of the overlying liquid in thechamber and the liquids then mixed. If this process occurredmany times over the course of the development of the Ultramaficseries, a thick column of magma with orthopyroxene on its liquiduswould have been the result. Thus, the sequence of multiple injections,fractionation, and mixing with previously fractionated magmacould have been the mechanism that produced the thick bronzitecumulate layer (the Bronzitite zone) above the cyclic units.     

西藏南木林县秦马弄地区二长花岗岩体岩石成因

以出露在西藏南木林县秦马弄地区二长花岗岩体为研究对象,从野外地质调查、岩石学、LA-ICP-MS锆石U-Pb定年、元素和Lu-Hf同位素地球化学等方面对其进行了分析研究。结果显示：秦马弄地区二长花岗岩体类似于A型花岗岩,形成于古近纪(E1),其LA-ICP-MS锆石U-Pb年龄为(62.0±0.5)~(63.0±0.5) Ma;岩体形成的温度较高(锆石饱和温度为745~805 ℃,平均766 ℃);岩石富SiO2(72.6%~75.0%)、Na2O(2.86%~3.59%)和K2O(4.12%~5.25%),贫CaO(0.72%~1.39%)和MgO(0.26%~0.36%),高FeOT/MgO值(7.26~10.3),属高钾钙碱性系列,弱过铝质;岩石具明显的负Eu异常(Eu/Eu*=0.40~0.70),普遍表现出Ba、Sr、P、Ti元素的亏损和Rb、Th、K、Zr、Hf元素的富集。εHf(t)值为-4.7~-1.8,其两阶段地壳Hf模式年龄tDM2为(1.1~1.3) Ga。秦马弄A型花岗岩体是冈底斯基底地壳物质部分熔融的岩浆产物,形成于古近纪印度板块与欧亚板块俯冲碰撞引起的总体为岛弧背景下的局部拉张构造环境。