Space/time tectono-sedimentary evolution of the Umbria-Romagna-Marche Miocene Basin (Northern Apennines, Italy): a foredeep model

The space/time evolution of the Umbria-Romagna-Marche domains of the northern Apennine Miocene foredeep is proposed. In this period, the turbidite siliciclastic sedimentation is represented mainly by the Miocene Marnoso-Arenacea Formation, which generally ends with mainly marly deposits. From the internal Apennine sectors (Umbria-Romagna domain) to the external Adriatic Margin (Marche domain) the siliciclastic succession overlies hemipelagic marly deposits (Schlier Formation). The whole depositional area can be considered as a single wide basin with depocenter or main sedimentation areas progressively migrating eastwards. This basin is characterized by some morphological highs which did not constitute real dams for the sedimentary flows (turbidity currents). Multiple feeding (arkose, litharenites, calcarenites) from different sources is related to palaeogeographical and palaeotectonic reorganization of the most internal, previously deformed, Apennine areas. The activation of the foredeep stage is marked by the beginning of the siliciclastic sedimentation (Late Burdigalian in the most internal sector). This sedimentation ends in the most external sector in the Early Messinian, pointing to a depositional cycle of about 9?C10?Ma. The diachronism of the base of the siliciclastic deposition proves to be almost 5?Ma. The syn-depositional compressional deformation, which shows a marked diachronism, affected the internal area of the foredeep in the Early-Middle Serravallian, and progressively migrated up to Late Miocene, involving more and more external sectors. The deformed siliciclastic sedimentary wedge constitutes an orogenic pile incorporated in the Apennine Chain, represented by different tectonic elements superimposed by means of NE-vergent thrusts. The main stratigraphic and tectonic events of the Toscana-Romagna-Marche Apennines are presented in a general framework, resulting also in a terminological revision.     

Turbidites facies response to the morphological confinement of a foredeep (Cervarola Sandstones Formation,Miocene, northern Apennines,Italy)

The Cervarola Sandstones Formation, Aquitanian–Burdigalian in age, was deposited in an elongate, north‐west stretched foredeep basin formed in front of the growing northern Apennines orogenic wedge. As other Apennine foredeep deposits, such as the Marnoso‐arenacea Formation, the stratigraphic succession of the Cervarola Sandstones Formation records the progressive closure of the basin due to the propagation of thrust fronts towards the north‐east, i.e. towards the outer and shallower foreland ramp. This process produces a complex foredeep that is characterized by syn‐sedimentary structural highs and depocentres that strongly influence lateral and vertical turbidite facies distribution. This work describes and discusses this influence, providing a high‐resolution physical stratigraphy with ‘bed by bed’ correlations of an interval ca 1000 m thick, parallel and perpendicular to the palaeocurrents and to the main structural alignments, on an area of ca 30 km that covers the proximal portion of the Cervarola basin in the northern Apennines. The main aim is to show, for the first time ever, a detailed facies analysis of the Cervarola Sandstones Formation, based on a series of bed types that have proven fundamental to understand the morphology of the basin. The knowledge of the vertical and lateral distribution of these bed types, such as contained‐reflected and slurry (i.e. hybrid) beds, together with other important sedimentary structures, i.e. cross‐bedded bypass facies and delamination structures, is the basis for better understanding of facies processes, as well as for proposing an evolutionary model of the foredeep in relation to the syn‐sedimentary growth of the main tectonic structures. This makes the Cervarola Sandstones, like the Marnoso‐arenacea Formation, a typical example of foredeep evolution.     

Duplex architecture and late‐orogenic backthrusting in Foredeep Units of the Northern Apennines (Italy)

The Northern Apennines of Italy is a fold and thrust belt that resulted from the NE‐ward progressive overthrusting of a Mesoalpine stacking (the ocean‐derived Ligurian Units) onto the detached sedimentary cover of the Adria plate continental margin (Foredeep Units). The Futa Pass area represents a key sector for the reconstruction of the deformation history of two Foredeep Units (Acquerino and Carigiola Units). The tectonic evolution of this sector is characterized by the superposition of three main deformation stages, with a constant NNE–SSW compression direction. The oldest structure is represented by the NNE‐verging Acquerino Unit duplex structure, the roof thrust of which is represented by the Ligurian stacking basal thrust. The interpretation of this structure as a large‐scale duplex is supported by the presence in the outer sectors of the Northern Apennines belt of Ligurian Units directly overthrust on younger Foredeep Units. In the second deformation stage the NNE‐verging Tavaiano Thrust developed. This regionally significant tectonic surface juxtaposes the Acquerino Unit (already developed as a duplex) and the overlying Ligurian Units, onto the Carigiola Unit. During this stage the fault pattern of the Carigiola Unit was also developed, characterized by two conjugate fault systems, coherent with a NNE–SSW maximum compression direction. During the last deformation stage, a backthrusting with a top‐to‐the SSW sense of movement (the Marcoiano Backthrust) brings the Carigiola Unit and its tectonic cover over the Acquerino and Ligurian Units, with the development of a large footwall syncline. The deformation history presented here differs from previous studies, and so provides a contribution to the debate on Northern Apennines tectonic evolution. Copyright © 2008 John Wiley & Sons, Ltd.     

Stratigraphic architecture and quaternary evolution of the Val d'Agri intermontane basin (Southern Apennines,Italy)

The sedimentary record of the Val d'Agri basin is of great importance for understanding the Quaternary tectonic activity and climatic variability in the Southern Apennines. Changes in tectonic controls, sediment supply and climatic input have been identified. The interval from ～ 56 to ～ 43 ka was associated with asymmetric subsidence restricted to the north-eastern actively faulted margin of the basin and development of axial braided river and transverse alluvial fan systems. Short-lasting Mediterranean-type pedogenesis between ～ 43 and ～ 32 ka (MIS Stage 3) coexisted with progradation–aggradation of the southern alluvial fan deposits and southwards tilting of the basin floor. Aggradation ended with consumption of accommodation space after 32 ka. During a subsequent stage of decline of vegetation cover, possibly as a consequence of climatic cooling (probably MIS Stage 2), active progradation of alluvial fans occurred. Breakthrough of the basin threshold and entrenchment of the drainage network must therefore be attributed to a latest Pleistocene to Holocene age. The first stages of basin opening and fill, predating ～ 56 ka have only been inferred by stratigraphic considerations: the earliest lacustrine sedimentation should be middle Pleistocene or older in age. The following south-eastward basin widening allowed progradation of alluvial fan systems, which completely filled the lacustrine area (tentatively late middle Pleistocene). Pedogenesis in “Mediterranean-like” climate conditions caused the final development of a highly mature fersiallitic paleosol at the top of the fan surfaces, in areas of morpho-tectonic stability, plausibly during MIS Stage 5. The study results demonstrate the potential of applying a multidisciplinary approach in an intermontane continental settings marked by a relative rapid and constant tectonic subsidence and a high rate of sediment supply during the Pleistocene glacial–interglacial cycles.     

Stratigraphy and depositional setting of slurry and contained (reflected) beds in the Marnoso‐arenacea Formation (Langhian‐Serravallian) Northern Apennines,Italy

This work presents the stratigraphy and facies analysis of an interval of about 2500 m in the Langhian and Serravallian stratigraphic succession of the foredeep turbidites of the Marnoso‐arenacea Formation. A high‐resolution stratigraphic analysis was performed by measuring seven stratigraphic logs between the Sillaro and Marecchia lines (60 km apart) for a total thickness of about 6700 m. The data suggest that the stratigraphy and depositional setting of the studied interval was influenced by syndepositional structural deformations. The studied stratigraphic succession has been subdivided into five informal stratigraphic units on the basis of how structurally controlled topographic highs and depocentres, a consequence of thrust propagation, change over time. These physiographic changes of the foredeep basin have also been reconstructed through the progressive appearance and disappearance of thrust‐related mass‐transport complexes and of five bed types interpreted as being related to structurally controlled basin morphology. Apart from Bouma‐like Type‐4 beds, Type‐1 tripartite beds, characterized by an internal slurry unit, tend to increase especially in structurally controlled stratigraphic units where intrabasinal topographic highs and depocentres with slope changes favour both mud erosion and decelerations. Type‐2 beds, with an internal slump‐type chaotic unit, characterize the basal boundary of structurally controlled stratigraphic units and are interpreted as indicating tectonic uplift. Type‐3 beds are contained‐reflected beds that indicate different degrees of basin confinement, while Type‐5 are thin and fine‐grained beds deposited by dilute reflected turbulent flows able to rise up the topographic highs. The vertical and lateral distribution of these beds has been used to understand the synsedimentary structural control of the studied stratigraphic succession, represented in the Marnoso‐arenacea Formation by subtle topographic highs and depocentres created by thrust‐propagation folds and emplacements of large mass‐transport complexes.     

Miocene low-angle detachments and upper crust megaboudinage in the Mt. Amiata geothermal area (Northern Apennines,Italy)

Information from surface and subsurface geology (boreholes and seismic reflection lines) are used to depict the geometry of the extensional structures (low-angle normal faults and related Tuscan Nappe megaboudins) affecting the Mt. Amiata geothermal area and developed during the early stage of the extensional tectonics which affected the inner Northern Apennines and Tyrrhenian Sea from the Early-Middle Miocene. Normal faulting involved the thickened middle-upper crust after the collisional stage and, in the Mt. Amiata region, took place over relatively short periods (5-7 Ma) characterised by rapid extensional strain rates. Normal faults showing articulated geometry (flat-ramp-flat) characterised by subhorizontal detachments (flats) and synthetic ramps, caused widespread megaboudinage mainly in the sedimentary tectonic units and particularly in the Tuscan Nappe. Evaporites occurring at the base of the Tuscan Nappe, the deepest sedimentary tectonic unit of the Northern Apennines, controlled the geometry of the faults, and rift-raft tectonics may be the style of this first extensional phase. Three Tuscan Nappe extensional horses (megaboudins) have been recognised in the subsurface of the Mt. Amiata area. They are characterised, in map view, by elliptical shapes and show a mean NNW-SSE lengthening. They are delimited at the base and at the top by east-dipping flats, while their western and eastern margins coincide with east-dipping ramps. On the whole, considering their geometrical features, these megaboudins correspond to extensional horses belonging to an asymmetrical east-dipping extensional duplex system.

Rollover anticlines deformed the western ramp of the megaboudins and rotated the uppermost flat as well as all the structures previously developed, which became steeply-dipping to the west.     

Origin and evolution of a salty gypsum/anhydrite karst spring: the case of Poiano (Northern Apennines, Italy)

Poiano is the largest karst spring of the Emilia Romagna region (northern Italy). It drains an aquifer of unique properties composed of anhydrite with halite lenses at depth and gypsum at the surface (both with high NaCl content). Hydrogeological research has been undertaken using automatically recorded hourly data on temperature, electrical conductivity, and water level. Water feeding the Poiano spring is restricted within the gypsum/anhydrite outcrop between the Lucola, Sologno and Secchia rivers. Karstification in the Upper Secchia Valley only concerns the gypsum rocks mainly present along the border and in the shallower parts of the sulfate outcrop and does not appear to occur at depth. Data strongly support the hypothesis that the salt content in the spring water derives from active halokinetic movements. For the first time, the fundamental hydrogeological importance of the anhydrite part inside the sulfate rocks is demonstrated. If gypsum prevails over anhydrite the karst drainage network can extend deep into the rocks following a network of fractures and fissures. Instead, if in the deep parts of the aquifer anhydrite prevails over gypsum, the karst evolution cannot take place at depth and the structure of the underground drainage paths only follows near-surface paths in gypsum.     

Tectonics and quaternary evolution of the Northern Apennines watershed area (upper course of Arno and Tiber rivers,Italy)

This work examines the connection between Quaternary tectonics and erosion/incision processes in the primary Tuscan‐Romagna watershed of the Northern Apennines, which essentially coincides with the topographic culmination of the Nero Unit structural ridge. Tectonic and geomorphic information were collected in the area where this ridge is crossed by the upper Tiber River course forming a deep gorge. Structural analysis and field mapping have revealed that the region experienced polyphase tectonics with superposed thrust folding events identifiable both at the map and mesoscopic scales. Hinterland‐SSW‐verging thrusts and thrust‐related folds deformed the whole thrust pile during the latest deformation phase. Backthrusts/backfolds controlled the development of intermountain basins nearby the main watershed during the Early Pleistocene and seemingly deformed, in the Tiber gorge, a low‐relief landscape developed in the Early Pleistocene (ca. 1.1 Ma). Successively, the upper Tiber River course area and Apennines axial zone underwent a generalized uplift, which is manifested by the deep incision of palaeo‐morphologies. This proposed sequence of events correlates well with the major geodynamic change of the Apennines revealed by an acceleration of uplift rates in the Middle–Late Pleistocene. This latter event may also correlate with increased rates of river incision recorded in Europe as a consequence of uplift and/or climate change. Copyright © 2008 John Wiley & Sons, Ltd.     

Structural development of the Neogene Radicondoli–Volterra and adjoining hinterland basins in Western Tuscany (Northern Apennines,Italy)

This paper presents a geological–structural study of some Neogene hinterland basins of the Northern Apennines, located on the Tyrrhenian side of the chain. These basins developed on the already delineated thrust-fold belt from middle–late Tortonian times. Their evolution has been commonly referred to an extensional tectonic regime, related to the opening of the Tyrrhenian Sea. New data have allowed us to hypothesize a different tectonic evolution for the chain, where compressive tectonics plays a major role both in the external and in the hinterland area. In this frame, the hinterland area located west of a major outcropping crustal thrust (Mid-Tuscany Metamorphic Ridge) has been the target of a geological–structural investigation. The field mapping and structural analysis has been focused on the syntectonic sediments of the Radicondoli–Volterra basin as well as on adjoining minor basins. These basins commonly display a synclinal structure and are generally located in between basement culminations, probably corresponding to thrust anticlines. Sediments of the hinterland basins have been affected by compressive deformation and regional unconformities separate stratigraphic units due to the activity of basement thrusts. In the study area, normal faulting either accommodates the thrusting processes or post-dates compressive deformation. A chronology of faulting and a six-stage evolution of this area are presented, providing further insights for the Neogene tectonic evolution of the Northern Apennines. Copyright © 1998 John Wiley & Sons, Ltd.     

From platform to basin: the evolution of a Paleocene carbonate margin (Eastern Desert, Egypt)

In this study, progradation and the subsequent retrogradation of a late Paleocene isolated carbonate platform (Galala Mountains, Eastern Desert, Egypt) is demonstrated by variations of distinct facies associations from the platform margin in the north to the hemipelagic basin in the south. A combination of a sea-level drop and tectonic uplift at around 59 Ma (calcareous nannofossil biozone NP5) favored the initiation of the carbonate platform. From this time onwards, the facies distribution along the platform–basin transect can be subdivided into five facies belts comprising nine different facies associations. Their internal relationships and specific depositional settings are strongly coupled with the Maastrichtian–Paleocene seafloor topography, which resulted from local tectonic movements. Patch reefs and reef debris were deposited at the platform margin and the horizontally bedded limestones on the upper slope. Slumps and debris flows were stored on the lower slope. In the subhorizontal toe-of-slope facies belt, mass-flow deposits pass into calciturbidites. Further southwards in the basin, only hemipelagic marls were deposited. Between 59 and 56.2 Ma (NP5–NP8), the overall carbonate platform system prograded in several pulses. Distinct changes in facies associations from 56.2 to 55.5 Ma (NP9) resulted from rotational block movements. They led to increased subsidence at the platform margin and a coeval uplift in the toe-of-slope areas. This resulted in the retrogradation of the carbonate platform. Furthermore the patch-reef and reef-debris facies associations were substituted by the larger foraminifera shoal association. The retrogradation is also documented by a significant decrease in slump and debris-flow deposits on the slope and calciturbidites at the toe of slope.     

Structural evolution of the Tuscan Nappe in the southeastern sector of the Apuan Alps metamorphic dome (Northern Apennines,Italy)

Structural analysis carried out in the Tuscan Nappe (TN) in the southeastern sector of the Apuan Alps highlights a structural evolution much more complex than that proposed so far. The TN has been deformed by structures developed during four deformation phases. The three early phases resulted from a compressive tectonic regime linked to the construction of the Apenninic fold‐and‐thrust‐belt. The fourth phase, instead, is connected with the extensional tectonics, probably related to the collapse of the belt and/or to the opening of the Tyrrhenian Sea. Our structural and field data suggest the following. (1) The first phase is linked to the main crustal shortening and deformation of the Tuscan Nappe in the internal sectors of the belt. (2) The second deformation phase is responsible for the prominent NW–SE‐trending folds recognized in the study area (Mt. Pescaglino and Pescaglia antiforms and Mt. Piglione and Mt. Prana synforms). (3) The direction of shortening related to the third phase is parallel to the main structural trend of the belt. (4) The interference between the third folding phase and the earlier two tectonic phases could be related to the development of the metamorphic domes. The two directions of horizontal shortening induced buckling and vertical growth of the metamorphic domes, enhancing the process of exhumation of the metamorphic rocks. (5) The exhumation of the Tuscan Nappe occurred mostly in a compressive tectonic setting. A new model for the exhumation of the metamorphic dome of the Apuan Alps is proposed. Its tectonic evolution does not fit with the previously suggested core complex model, but is due to compressive tectonics. Copyright © 2004 John Wiley & Sons, Ltd.     

Tectono-sedimentary evolution of the External Liguride units (Northern Apennines,Italy): insights in the pre-collisional history of a fossil ocean-continent transition zone

Abstract

In the Northern Apennines, the External Liguride (EL) units are interpreted as derived from the domain that joined the Ligure–Piemontese oceanic basin to the Adriatic plate continental margin. The EL units can be divided into two different groups according to the lithostratigraphic features of the basal complexes underlying the Upper Cretaceous–Lower Tertiary carbonate flysch (e.g. Helminthoid flysch). The first group includes the western successions characterized by Santonian–Campanian sedimentary melanges where slide blocks of lherzolitic mantle, gabbros, basalts, granulites, continental granitoids are represented. The second group is represented by the eastern successions where the Cenomanian–Campanian basal complexes mainly consist of sandstones and conglomerates where the mafic and ultramafic rocks are scarce or completely lacking. Their original substrate is represented by the Middle Triassic to Lower Cretaceous, mainly platform carbonate deposits, found as slices at the base of the eastern successions.

The stratigraphic features shown by the basal complexes allow the reconstruction of their source area that is assumed to be also representative for the pre-Upper Cretaceous setting. The proposed reconstruction suggests the occurrence in the EL domain of two distinct domains. The eastern domain was characterized by a thinned and faulted continental crust belonging to the Adriatic continental margin. The western domain was instead floored by subcontinental mantle associated with lower and upper continental crust, representing the ocean–continent transition. This setting is interpreted as the result of the opening of the Ligure–Piemontese oceanic basin by passive rifting, mainly developed by simple shear, asymmetric extension of the continental crust. © 2001 Éditions scientifiques et médicales Elsevier SAS     

Tectono-sedimentary evolution of the External Liguride units (Northern Apennines,Italy): insights in the pre-collisional history of a fossil ocean-continent transition zone

In the Northern Apennines, the External Liguride (EL) units are interpreted as derived from the domain that joined the Ligure–Piemontese oceanic basin to the Adriatic plate continental margin. The EL units can be divided into two different groups according to the lithostratigraphic features of the basal complexes underlying the Upper Cretaceous–Lower Tertiary carbonate flysch (e.g. Helminthoid flysch). The first group includes the western successions characterized by Santonian–Campanian sedimentary melanges where slide blocks of lherzolitic mantle, gabbros, basalts, granulites, continental granitoids are represented. The second group is represented by the eastern successions where the Cenomanian–Campanian basal complexes mainly consist of sandstones and conglomerates where the mafic and ultramafic rocks are scarce or completely lacking. Their original substrate is represented by the Middle Triassic to Lower Cretaceous, mainly platform carbonate deposits, found as slices at the base of the eastern successions.The stratigraphic features shown by the basal complexes allow the reconstruction of their source area that is assumed to be also representative for the pre-Upper Cretaceous setting. The proposed reconstruction suggests the occurrence in the EL domain of two distinct domains. The eastern domain was characterized by a thinned and faulted continental crust belonging to the Adriatic continental margin. The western domain was instead floored by subcontinental mantle associated with lower and upper continental crust, representing the ocean–continent transition. This setting is interpreted as the result of the opening of the Ligure–Piemontese oceanic basin by passive rifting, mainly developed by simple shear, asymmetric extension of the continental crust.     

Fluid‐induced breakdown of monazite in medium‐grade metasedimentary rocks of the Pontremoli basement (Northern Apennines,Italy)

The last (decompression) stages of the metamorphic evolution can modify monazite microstructure and composition, making it difficult to link monazite dates with pressure and temperature conditions. Monazite and its breakdown products under fluid‐present conditions were studied in micaschist recovered from the cuttings of the Pontremoli1 well, Tuscany. Coronitic microstructures around monazite consist of concentric zones of apatite + Th‐silicate, allanite and epidote. The chemistry and microstructure of the monazite grains, which preserve a wide range of chemical dates ranging from Upper Carboniferous to Tertiary times, suggest that this mineral underwent a fluid‐mediated coupled dissolution–reprecipitation and crystallization processes. Consideration of the chemical zoning (major and selected trace elements) in garnet, its inclusion mineralogy (including xenotime), monazite breakdown products and phase diagram modelling allow the reaction history among accessory minerals to be linked with the reconstructed P–T evolution. The partial dissolution and replacement by rare earth element‐accessory minerals (apatite–allanite–epidote) occurred during a fluid‐present decompression at 510 ± 35 °C. These conditions represent the last stage of a metamorphic history consisting of a thermal metamorphic peak at 575 °C and 7 kbar, followed by the peak pressure stage occurring at 520 °C and 8 kbar. An anticlockwise P–T path or two clockwise P–T loops can fit the above P–T constraints. The former path may be related to a context of late Variscan strike‐slip‐dominated exhumation with minor Tertiary (Alpine‐related) reworking and fluid infiltration, while the latter requires an Oligocene–Miocene fluid‐present tectono‐metamorphic overprint on the Variscan paragenesis.     

意大利亚平宁地区第三纪中新世“Calcaria Lucina”冷泉碳酸盐岩中结晶扇的沉积岩石学及地球化学特征

结晶扇是冷泉碳酸盐岩的一种标志性沉积构造,主要由文石或重晶石等矿物呈放射状聚集形成。意大利亚平宁地区的第三纪中新统广泛发育冷泉碳酸盐岩,其中"Calcari a Lucina"冷泉碳酸盐岩中发育有典型的结晶扇。结晶扇主要由放射状文石聚集形成,含少量的方解石,具有明显的生长纹层。文石纹层的δ13CPDB为-37.9‰~-53.5‰,δ18OPDB为+2.4‰~+6.0‰,相邻文石纹层之间的δ13CPDB和δ18OPDB值差别明显,可能是与碳和氧的来源及流体渗漏速度有关。全岩稀土元素总量很低,w(REE)为0.23×10-6,页岩标准化模式具有明显的Ce负异常,显示结晶扇形成于氧化环境。     

Sudoite,a rock-forming mineral in Verrucano of the Northern Apennines (Italy) and the sudoite-chloritoid-pyrophyllite assemblage in prograde metamorphism

Sudoite, the di-trioctahedral chlorite with ideal composition (Mg₂Al)(Al₂)(Si₃Al)O₁₀(OH)₈ is a widespread rock-forming mineral in meta-siltstones and psammites of the Verrucano sequence of the Northern Apennines. Sub-ellipsoidal aggregates, probably derived from muscovite clasts, consisting of sudoite, pyrophyllite and muscovite, are common; sudoite may also occur as thin blades in the rock matrix. The co-existence of sudoite, Ferich chloritoid and pyrophyllite, reported here for the first time, has been observed in specimens from the M. Argentario and Monticiano-Roccastrada areas. This three-phase assemblage, diagnostic of a specific metamorphic facies, may be a tool for detailed zonation of low-grade terranes.     

Multi-stage rodingitization of ophiolitic bodies from Northern Apennines (Italy): Constraints from petrography,geochemistry and thermodynamic modelling

The investigated mantle bodies from the External Ligurians (Groppo di Gorro and Mt. Rocchetta) show evidences of a complex evolution determined by an early high temperature metasomatism, due to percolating melts of asthenospheric origin, and a later metasomatism at relatively high temperature by hydrothermal fluids, with formation of rodingites. At Groppo di Gorro, the serpentinization and chloritization processes obliterated totally the pyroxenite protolith, whereas at Mt. Rocchetta relics of peridotite and pyroxenite protoliths were preserved from serpentinization. The rodingite parageneses consist of diopside ​+ ​vesuvianite ​+ ​garnet ​+ ​calcite ​+ ​chlorite at Groppo di Gorro and garnet ​+ ​diopside ​+ ​serpentine ​± ​vesuvianite ​± ​prehnite ​± ​chlorite ​± ​pumpellyite at Mt. Rocchetta. Fluid inclusion measurements show that rodingitization occurred at relatively high temperatures (264–334 ​°C at 500 ​bar and 300–380 ​°C at 1 ​kbar). Garnet, the first phase of rodingite to form, consists of abundant hydrogarnet component at Groppo di Gorro, whereas it is mainly composed of grossular and andradite at Mt. Rocchetta. The last stage of rodingitization is characterized by the vesuvianite formation. Hydrogarnet nucleation requires high Ca and low silica fluids, whereas the formation of vesuvianite does not need CO₂-poor fluids. The formation of calcite at Groppo di Gorro points to mildly oxidizing conditions compatible with hydrothermal fluids; the presence of andradite associated with serpentine and magnetite at Mt. Rocchetta suggests Fe³⁺-bearing fluids with fO₂ slightly higher than iron-magnetite buffer. We propose that the formation of the studied rodingite could be related to different pulses of hydrothermal fluids mainly occurring in an ocean-continent transitional setting and, locally, in an accretionary prism associated with intra-oceanic subduction.     

Organic geochemical studies of a Messinian evaporitic basin,northern Apennines (Italy) I: Hydrocarbon biological markers for a hypersaline environment

This paper describes the occurrence and significance of hydrocarbons present in two bituminous marl layers and one distinct gypsum layer from a Messinian sedimentary basin, where hypersaline conditions prevailed. Several new compounds were detected and tentatively identified: of these 20R and 20S 4α, 24-dimethyl-5α(H),14β(H),17β(H) and 20R and 20S 4β,24-dimethyI-5α(H),14β(H),17β(H) cholestanes; 4-methylspirosterenes; 4,4-dimethyl-5α(H),14β(H),17β(H) pregnanes and homopregnanes are discussed in this paper. Several of these compounds might be considered as biological markers for a (hyper)saline environment. The short side chain 4-desmethylsteranes, 5α(H),14β(H),17β(H), 5α(H),14β(H),17α(H) and 5α(H),14α(H), 17α(H) pregnanes and homopregnanes, are the most abundant compounds in the extract from the gypsum sample. It is suggested that in this case these compounds do not reflect the stage of diagenesis but are related to certain organisms exclusively occurring in hypersaline environments. In addition the very low pristane/phytane ratio, often considered as an indicator for anoxicity, could also be interpreted as a useful indicator for hypersalinity.