清镇顽火辉石球粒陨石的矿物学特征及其成因

清镇陨石以具有高度还原的矿物组合为特征。普通球粒陨石和碳质球粒陨石中的亲石元素在顽火辉石球粒陨石内显示亲铜或亲铁的性质。在该陨石中发现的矿物有陨硫钙石。硫镁矿、钾的硫化物——硫铜钾矿,含Si的铁纹石及Ni的硅化物——硅磷镍矿等。顽火辉石和斜顽火辉石具有低的FeO含量,其FeO/(FeO+MgO)比值范围为0.004—0.01。在未完全熔融的球粒中发现具尘粒状贫Ni金届包裹体的残余橄榄石颗粒。本文首次报道陨石中含Ga的闪锌矿和发现陨石中稀少的碱硅镁柱石。金属-硫化物组合显示再加热和熔融的结构特征,金属发生硫化作用并被硫化物所取代。清镇陨石(EH_3)的化学成分与EH_(4,5)球粒陨石很相似,其La/Sm比值比平均EL高,Co/Ni则比EL低。清镇陨石的形成部位比任何其他球粒陨石群更靠近太阳,可能形成于水星-金星区。     

清镇顽火辉石球粒陨石及我国新近降落的不同类型陨石宇宙成因核的研究

The measurements are present in the paper of cosmogenic radionuclides in various types of meteorites falling recently in China. In particular, a full diseussion is also given to the provenance of the Qingzhen enstatite condrite. Based upon the measored Al^26 specific activity, an estimation has been made of the aphelion of the Qingzhen orbit (q‘≤1.9 AU). It is, therefore, concluded that the provenance of enstatite chondrites may be much closer to the sun as compared with ether types of meteorites.     

清镇陨石中顽火辉石的高分辨电镜研究

清镇陨石中顽火辉石的(010)取向结构象清楚地显示出单斜顽火辉石(CLEN)和顽火辉石(OREN)连生现象其特点说明它经历了急冷且受到很弱的后期热变质作用,同时,电子衍射和光学衍射及结构象均显示其中有27的长周期结构。     

GRV 13100顽火辉石球粒陨石中金属硫化物特征与成因

顽火辉石球粒陨石中的大量金属硫化物形成于早期极还原的太阳星云条件。GRV13100是一块发现于南极格罗夫山的顽火辉石球粒陨石,不透明矿物包括陨硫铁、陨硫铬铁矿、陨硫镁矿、陨硫钙矿、含硅铁纹石、陨磷铁矿、硅磷镍矿等金属硫化物和磷化物,总丰度达21%,经历了一定程度的热变质。通过对其岩石学和矿物化学特征研究,并和其它顽火辉球粒陨石进行对比分析,结果表明:(1)陨硫镁矿中FeS含量可以反映母体变质温度,GRV 13100中大部分陨硫镁矿变质温度为200℃～300℃,个别经历了400℃～800℃的高温,可能为外来吸入成因,或者代表了原始星云的凝聚或结晶温度;(2)陨硫镁矿形成于太阳星云的直接凝聚,并在橄榄石和顽火辉石冷凝结晶之后形成;(3)陨硫铁的成因分为原生和次生两种,原生的陨硫铁由太阳星云直接凝聚而成,次生的陨硫铁是在后期热变质过程中由铁镍金属经过硫化作用或者由陨硫镁矿分解而形成;(4)硅磷镍矿可能来自含硅铁纹石的出溶。本论文的研究工作为太阳系早期高度还原星云演化及其后期热变质提供了约束。     

顽辉石陨石中A,B矿的微量元素化学意义

运用电子探针和中子活化分析方法测定了清镇和Ｂｕｓｔｅｅ顽辉石无球粒陨石中含铬硫化物相的组成和微量元素含量。正如早期的报告结果，电子探针分析结果不足１００％，表明有相当含量的轻元素（ｚ〈１０）存在。     

吉林陨石的不透明矿物

Opaque minerals in the Jilin meteorite inelude kamacite, taenite troilite, chromite, ilmenite, schreibersite, pyrite, pyrrhotite, chalcopyrite, sphalerite and graphite.Five of the above-mentioned minerals have been discussed in more detail in terms of optical and physical properties, chemical composition, coexisting relationship, and the order of crystallization. It is indicated from this study that, with the exception of a small amount of Ni-Fe cbondrules, silicate minerals are the first to erystallize followed by chromite, ilmenite at the early stage of nebula condensation, while Ni-Fe phase in the matrix is considered to be of a more later erigin. At the late stage of nebula condensation troilite resulted from the reaction of Ni-Fe metal with residual H2S vapor. As indicated by the occurrence of coarse grained Ni-Fe metal, the recrystallization of troilite and the apparent Neumann lines in kamaeite, it is expected that opaque minerals in the Jilin metevrite have undergone different degrees of thermal and impact metamorphisms.     

吉林陨石的透明矿物

Principal transparent minerals in the Jilin meteorite include forsterite (Fa 17.8--19.5), orthopyroxenes (mainly Fs 14.1-15.8), clinopyroxenes (clinobronzite, diopside and pigeonite), plagioclase (An 8--12), orthoclase and whitlockite. Among the 17 accessory and minor minerals recognized are: tremolite, zircon, sodalite, calcite, siderite,moissanite, quartz, christobalite and rutile. The chemical composition of olivine is relatlvely uniform. Of pyroxenes orthopyroxenc predominates while clinopyroxenes are rare. Optical measurement indicates a limited compositional variation for orthopyroxene. Feldspars occur mainly as microcrystals and glass chondrules have mostly devitrified into crystallites, microcrystals or even to perfect crystals. The outline of chondrules is partly clear or, in some cases,merely recoguizable. The Jilin meteorite should belong to the type of 4-5, basically type H 5, in accordance with the petrochemical classification suggested by W. R. van Schmns in 1967.     

清镇陨石（EH3）硫镁矿微量元素化学特征

本文应用电子探针和中子活化分析方法详细研究了清镇陨石(EH 3)中硫镁矿的化学组成和微量元素分布、硫镁矿携带了部分HREE、高度富集钪等难熔亲石元素,论证了该矿物的高温成因,REE丰度可能与陨硫钙石互补。该矿物含有钠-硒组分,可能是顽火辉石陨石独有的组分。铬归一化的钠-钴(原子比)相关关系具有CI一致的趋势,表明其母体来自太阳组成的气体星云。     

庐江陨石中的不透明矿物

庐江陨石是一化学岩石类型为ＬＬ６的球粒石陨石。研究表明该陨石中不透明矿物有铁纹石,镍纹石,陨硫铁,铬铁矿,钛铁矿和赤铁矿等。本文对它们的产状,成分和结构进行了研究。     

安徽亳县陨石不透明矿物研究

毫县陨石的不透明矿物有陨硫铁、铁纹石、镍纹石、镍黄铁矿、镁铁尖晶石、自然铜、石墨、方铁矿、铬铁矿、钛铁矿、磁铁矿、张衡矿及x矿物等。本文对它们进行了反光显微镜鉴定、X射线分析、反射率测定和电子探针分析。总结了不同化学群的球粒陨石中FeO和MgO的含量变化规律。     

随州陨石不透明矿物研究

随州陨石不透明矿物有陨硫铁、铁纹石、镍纹石、自然铜、含镍黄铜矿、洛铁矿、钛铁矿等。本文对它们进行了反光显微镜鉴定、X射线分析、反射率及硬度的测定和电子探针分析，总结了不同化学群的球粒陨石铬铁矿、钛铁矿中FeO、MgO含量变化规律。     

肇东和亳县陨石中的黑包体及其成因意义

肇东、毫县陨石中的黑包体在总体成分、形状、大小上与陨石球粒相似,但两者的内部结构以及矿物组合不同。黑包体中矿物呈密堆状,主要由细粒橄榄石以及其它硅酸盐微晶组成,不含火成玻璃等特点表明黑包体未经历过熔融,它们可能是形成球粒的毛坯。因此认为球粒的形成有三个阶段:星云凝聚形成尘粒—尘粒吸积形成黑包体—黑包体熔融形成球粒。     

新疆铁陨石的矿物学特征及其母体形成条件

作者详细观测研究了新疆铁陨石24块不同取样点样品的矿物组成、化学成分和结构构造特征。鉴定出12种不透明矿物,其中高钴合金球粒为铁陨石表面方铁矿中首次发现,方铁矿,陨硫铬铁和陨碳铁镍矿也为国内铁陨石中首次发现。矿物学特征表明新疆铁陨石母体形成于岩浆成因,母体半径约280km,具有半径约140km的金属核,母体中心压力约2.5kbar。     

REE and Other Trace Element Chemistry of Oldhamite（CaS） in the Qingzhen Chondrite（EH3） and Their Genetic Implications

Instrumental neutron activation analysis(INAA) of 14 single oldhamite grains separated from the Qingzhen chondrite (EH3) for refractory(La,Ce,Sm ,Eu,Yb,Lu,Ca,Sc,Hf, and Th),volatile (Na,Cr,Zn,Se,Br,etc.)and siderophile elements (Fe,Ni,Co,Ir,Au ,and As) revealed that oldhamite is highly rich in refractory elements.The mineral serves as the principal carrier of REE and contains about 80% of the REEs in the Qingzhen enstatite chondrite .Furthermore, the large enrichment of LREE relative to HREE is noticed in oldhamite from the Qingzhen .In general, the oldhamite from metal-sulfide assemblages is richer in REE than that from the matrix,i.e.,the earlier the oldhamite grains condensed, the richer they are in REE. Meanwhile.oldhamite is also rich in vol-atile elements such as Se,Br, etc.In terms of the distribution of trace elements in oldhamitc from the Qingzhen ,the chondrite is srggested to have resulted from high-temperature condensation of solar nebula.