Sunrise Hill unconformity: A newly discovered regional hiatus between Archaean granites and greenstones in the northeastern Pilbara Craton

Contacts between Archaean granites and greenstones in the northeastern part of the Pilbara Craton have been described as intrusive and tectonic. New field observations in the Shay Gap region demonstrate that greenstones of the Gorge Creek Group unconformably overlie the Muccan and Warrawagine batholiths. Regionally, the unconformity is marked by a persistent but relatively thin basal clastic sequence, locally with a granite boulder conglomerate, overlain by ore‐bearing banded iron‐formation, fine‐grained clastic rocks and chert. The granite basement is dated at 3443 ± 6 Ma. The precise age of the hiatus is unknown but its maximum effect might have been the removal of a substantial thickness of Early to Middle Archaean strata.     

Middle Archean ocean ridge hydrothermal metamorphism and alteration recorded in the Cleaverville area, Pilbara Craton, Western Australia

A hydrothermally metamorphosed greenstone complex, capped by bedded cherts and banded iron formations (BIFs), is exposed in the Cleaverville area, Pilbara Craton, Western Australia. It has been interpreted as an accretionary complex characterized by both a duplex structure and an oceanic plate stratigraphy, and is shown to represent a 3.2 Ga upper oceanic crust. Three metamorphic zones are identified in the basaltic greenstones. The metamorphic grade increases from sub-greenschist facies (zones A and B) to greenschist facies (zone C) under low-pressure conditions. The boundaries between three mineral zones are subparallel to the bedding plane of overlying chert/BIF, and metamorphic temperature increases stratigraphically downward. The zones correspond to the thermal structure of ocean-floor metamorphism, at a mid-ocean ridge.
The uppermost greenstone in the study area is more pervasively altered and carbonatized than the modern upper oceanic crust. This indicates the enrichment of CO₂ in the metamorphic fluid by which widespread formation of carbonate occurred, compared with a narrow stability region of Ca-Al silicates. It is, therefore, suggested that the Archean hydrothermal alteration played a more important role in fixation of CO₂ than present-day ocean-ridge hydrothermal alteration, as an interaction between sea water and oceanic crust.     

Fluid fluxes during low-temperature alteration: implications of multi-style alteration assemblages from the Welsh Borderland,UK

Localized (domainal) low-temperature alteration may indicate variations in the chemistry of alteration fluids and/or discrete fluid flow paths during metamorphism. Occurrences of epidote- and pumpellyite-dominated domains are often used as evidence for large fluxes of Ca-rich fluids. However, comparative studies of two domainal alteration styles from basaltic to andesitic lavas and volcaniclastic rocks at Builth Wells, Wales, UK suggest that such interpretations cannot be applied universally. Here, only one set of domains can be attributed to large fluxes of Ca-rich fluids. In contrast, the second set of domains formed where the host rock supplied the necessary Ca, and fluid/rock ratios were relatively low. These domains are hosted by rocks which show a Caledonian regional metamorphic imprint, characterized by the alteration assemblage albite+chlorite+titanite±prehnite±pumpellyite±calcite±muscovite±quartz (considered to have formed at c. 200°C and ≤2.5 kbar). Type 1 domains lie along fluid channelways, such as veins. Pumpellyite is the dominant secondary mineral, but the alteration assemblage is variable with pumpellyite±prehnite±calcite±titanite±chlorite (±quartz). The domains formed at temperatures of 130–230°C during Ordovician hydrothermal activity, before the peak of regional metamorphism. In contrast, Type 2 domains are not associated with obvious fluid channelways. A central prehnite-dominated zone typically has a rim with the assemblage pumpellyite+calcite±prehnite±chlorite±titanite±K-rich phyllosilicate. These domains probably formed from pelitic xenoliths which contained a volcaniclastic component at temperatures of 130–230°C and at relatively low fluid/rock ratios. However, the timing of domain formation is uncertain. Pyrobitumen, in veins and disseminated throughout the rock, may have influenced the formation of both types of domain by stabilizing pumpellyite in preference to epidote and causing metamorphic calcite formation through the release of CO₂ to the alteration fluids. © 1996 John Wiley & Sons, Ltd.     

Gold deposits of the Bardoc Tectonic Zone: a distinct style of orogenic gold in the Archaean Eastern Goldfields Province,Yilgarn Craton,Western Australia

The Bardoc Tectonic Zone is an ～80 km-long and up to 12 km wide, intensely sheared corridor of Late Archaean supracrustal rocks that is bounded by pre- to syn-tectonic granites in the Eastern Goldfields Province, Yilgarn Craton. This zone has produced over 100 t of gold from a range of deposits, the largest being Paddington (～40 t Au). This shear system is connected along strike to the Boulder – Lefroy Shear Zone, which hosts considerably larger deposits including the giant Golden Mile Camp (>1500 t produced Au). In contrast to the diverse characteristics of gold deposits associated with the Boulder – Lefroy Shear Zone, mineralogical and geochemical data from five representative localities in the Bardoc Tectonic Zone have relatively uniform features. These are: (i) quartz – carbonate veins in competent mafic units with wall-rock alteration characterised by carbonate + quartz + muscovite + chlorite ± biotite + sulf-arsenide + sulfide + oxide + gold assemblages; (ii) arsenopyrite as the dominant sulfur-bearing mineral; (iii) a unique three-stage paragenetic history, commencing with pyrrhotite, and progressing to arsenopyrite and then to pyrite-dominated alteration; (iv) a lack of minerals indicative of oxidising conditions, such as hematite and sulfates; (v) δ³⁴ sulfur compositions of pre- to syn-gold iron sulfides ranging from 1 to 9 ‰; and (vi) a lack of tellurides. These features characterise a coherent group of moderately sized orogenic-gold deposits, and when compared with the larger gold deposits of the Boulder – Lefroy Shear Zone, potentially highlight the petrological and geochemical differences between high-tonnage and smaller deposits in the Eastern Goldfields Province.     

Woodcutters goldfield: Gold in an Archaean granite,Kalgoorlie, Western Australia

The 43 t (1.4 Moz) of gold in the Woodcutters goldfield 50 km north of Kalgoorlie has wide geological significance in terms of gold in Archaean granite, as well as its local commercial and exploration significance. Woodcutters is already one of the largest Archaean gold systems in granite, and is unusual in being so far laterally from the nearest greenstone belt. Gold in the Federal zone, one of the deposits making up the Woodcutters goldfield, is hosted in hornblende‐biotite granodiorite,6 km from the mapped contact with greenstone. In Federal open pit, the granodiorite is coarse‐grained in the northern half, and a fine‐grained granodiorite in the south, with both hosting gold. These two types of granodiorite are rather similar in both mineralogy and geochemistry. There is also a subordinate fine‐grained monzodiorite. The Federal gold mineralisation is in a northwest‐striking, northeast‐dipping (315° strike/60°E dip) shear zone in the Scotia granite. Variation in grainsize of the host rocks might have affected the style of deformation with more brittle fabrics in the coarse‐grained phase and more ductile fabrics prominent in the fine‐grained granodiorite. Hydrothermal alteration is extensively developed around the Federal deposit and is a useful vector towards gold mineralisation. Distal epidote alteration surrounds a proximal muscovite‐biotite alteration zone that contains quartz‐sulfide veins. The alteration shares some of the common alteration characteristics of Archaean greenstone‐hosted gold, but differs in that carbonate‐chlorite alteration is only weakly developed. This difference is readily explained in terms of host‐rock composition and lower concentrations of Fe, Mg and Ca in the granite compared with greenstone. Fluid‐inclusion studies demonstrate that the fluids associated with the hydrothermal alteration at Woodcutters shared the common characteristics of fluids in Archaean greenstone gold, namely low‐salinity and dominant H₂O–CO₂. Fluid inclusions with moderate salinity were found in one fresh sample away from mineralisation, and are inferred to represent possible magmatic fluid. There is no evidence of a granite‐derived fluid being responsible for gold mineralisation. The granodiorite host rock had cooled, crystallised and had at least started to undergo deformation prior to gold introduction. The distribution of gold mineralisation in the Woodcutters goldfield has the style, shape and orientation comparable with greenstone‐hosted gold deposits in the same region. The northwest trend, the quartz veining and simple pyrite mineralogy are all features common to other greenstone‐hosted gold deposits near Kalgoorlie such as Mt Pleasant. The alteration fluid appears to have penetrated the granite on the scale of many hundreds of metres, causing large‐scale alteration. Woodcutters gold mineralisation resulted from the same metamorphic fluid processes that led to formation of greenstone gold deposits. In this metamorphic model, granitic rocks are predicted to be less‐favourable gold hosts than mafic rocks for two reasons. Granitic rocks do not generally fracture during regional deformation in such a way as to create large‐scale dilation. Furthermore, with less iron and no carbon, granitic rocks have lower potential to precipitate gold from solution by wall‐rock reaction. The metamorphic model predicts that those granite types with higher Fe should host better gold deposits, all other factors being equal. Accordingly, tonalite‐trondhjemite and hornblende‐bearing granodiorite should provide better environments for major gold deposits compared with monzogranite, and granite sensu stricto, as borne out by Woodcutters, but mafic rocks should be better hosts than any of these felsic to intermediate rocks.     

Ion microprobe baddeleyite and zircon ages for Late Archaean mafic dykes of the Pilbara Craton,Western Australia

Ion microprobe U–Th–Pb analyses of baddeleyite and zircon yield precise ages for several mafic intrusions in the Pilbara Craton of Western Australia. Baddeleyite was dated from four dolerite dykes of the north‐northeast‐trending Black Range swarm intruded into granitoid‐greenstone basement in the northern part of the craton. The mean ²⁰⁷Pb*/²⁰⁶Pb* age of 2772 ± 2 Ma, interpreted as an unambiguous age of emplacement for the dykes, is within error of previous ion microprobe U–Pb zircon ages for the Mt Roe flood basalts and confirms that the dykes acted as feeders to the volcanic rocks. The Sylvania Inlier, in the southeastern Pilbara Craton, also contains north‐northeast‐trending dykes that were correlated previously with the Black Range swarm. Based on concordant and discordant zircon analyses from samples of two dykes, the best estimate of the age of the Sylvania dykes is 2747 ± 4 Ma. The Sylvania dykes thus appear to be significantly younger than, and hence unrelated to, the Black Range swarm, but may have acted as feeders to younger volcanic units in the Fortescue Group such as the Kylena Formation.     

热液成矿作用地球化学:以金矿为例

文中以金矿为例总结了热液成矿地球化学特征,包括热液蚀变、金在成矿热液中的地球化学行为、富集-沉淀机制以及在硫化物中的存在形式。热液蚀变过程中形成的矿物组合反映了成矿流体的地球化学特征,蚀变模式具有重要的找矿勘探意义。在热液体系中,金主要以Au-Cl或者Au-S络合物的形式进行运移,体系温度、压力、氧逸度以及硫逸度等条件的变化是导致络合物分解、金沉淀的主要机制。在较高压力条件下,金趋向于在热液蒸汽相中富集。As和Sb是金矿热液体系中常见的伴生元素,在较低硫逸度条件下,形成自然砷/自然锑-自然金组合。金从热液中沉淀后主要以显微包裹体或者固溶体金的形式赋存于黄铜矿、毒砂、磁黄铁矿以及黄铁矿等硫化物中,而硫化物中固溶体金的量主要受热液H_2S活动性的控制。     

恒山绿岩带的构造特征—晚太古代大陆裂谷作用证据

恒山太古宙绿岩带呈断片或复式向形穿插于片麻岩基底内，绿岩带地层连续性较好，可以恢复出完整的沉积－火山地层序列。主要经历二期变形，早期逆冲褶皱变形和晚期右旋走滑变形。为绿帘角闪岩相－角闪岩相变质。构造恢复表明，绿岩带的形成明显晚于基底，并整合其上，且在其演化过程中对基底产生叠加影响，最合适的构造环境为大陆裂谷，在大陆裂谷闭合过程中。绿岩带及克拉通基底曾发生双向的逆冲作用，基底发生重新活动，并且受到开裂时形成的正断层的控制。当裂谷闭合到一定程度，由于受北部刚性基底的制约，横向挤压不再能调节压应力时，发生了右旋走滑变形，并使早先构造线向ＮＥＥ－ＥＷ向偏转。恒山绿岩带对应于五台山区、太行山北段、灵丘南山等地的五台群，有力地证明绿岩带形成于太古代末期－早元古代陆内裂谷环境，代表华北克技通演化过程中的重要事件，标志着晚太古代华北克拉通已达到相当大的规模，并发生ＮＥ向的刚性破裂。     

Taxonomy and biogenicity of Archaean spheroidal microfossils (ca. 3.0 Ga) from the Mount Goldsworthy–Mount Grant area in the northeastern Pilbara Craton, Western Australia

Microstructures recently reported from an Archaean sedimentary succession (ca. 3.0 Ga) in the Mount Goldsworthy–Mount Grant area in the northeastern Pilbara Craton meet the criteria for compelling evidence of biogenicity [Sugitani, K., Grey, K., Allwood, A., Nagaoka, T., Mimura, K., Minami, M., Marshall, C.P., Van Kranendonk, M.J., Walter, M.R., 2007. Diverse microstructures from Archaean chert from the Mount Goldsworthy–Mount Grant area, Pilbara Craton, Western Australia: microfossils, dubiofossil, or pseudofossils. Precambrian Res. 158, 228–262]. The structures are morphologically diverse. Although they were tentatively classified into five major morphological types (thread-like, film-like, small (<15 μm) and large (>15 μm) spheroidal, and spindle-like), the possible taxonomic significance of these groups was not discussed. Building on our earlier analysis, we focus on the morphology of the larger spheroids, as well as presenting further evidence relating spindles and several bizarre forms, and attempt to group them taxonomically and adduce additional evidence for their biogenicity.Taphonomic features were identified in each of the various morphological groups, but the range of morphological diversity of the spheroids cannot be attributed solely to taphonomic alteration. Four subdivisions of spheroids are proposed: (1) simple single-walled spheroids, (2) thin-walled spheroids having a diffuse envelope, (3) thick-walled spheroids, and (4) spheroids having an extensively folded wall. Simple single-walled spheroids, 15–60 μm in diameter, with various wall textures but commonly lacking envelopes or appendages form the dominant subgroup. Other complex morphologies are present and include aligned or associated bodies of thin-walled spheroids with diffuse envelopes, and spindle-like structures containing inner spheroidal bodies. The degree of morphological complexity and associations between structures suggest the presence of reproductive phases. If correct, this implies that the early Earth (ca. 3.0 Ga) showed a higher level of biodiversity than is currently postulated.     

A mineral equilibria study of the hydrothermal alteration in mafic greenschist facies rocks at Kalgoorlie, Western Australia

The influx of a H₂O–CO₂‐dominated fluid into actinolite‐bearing metabasic rocks during greenschist facies metamorphism in the Kalgoorlie area of Western Australia resulted in a zoned alteration halo around inferred fluid conduits that contain gold mineralisation. The alteration halo is divided into two outer zones, the chlorite zone and the carbonate zone, and an inner pyrite zone adjacent to the inferred fluid conduits. Reaction between the fluid and the protolith resulted in the breakdown of actinolite and the development of chlorite, dolomite, calcite and siderite. In addition, rocks in the pyrite zone developed muscovite‐bearing assemblages as a consequence of the introduction of potassium by the fluid. Mineral equilibria calculations undertaken using the computer software thermocalc in the model system Na₂O–CaO–K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O–CO₂ show that mineral assemblages in the outer zones of the alteration halo are consistent with equilibrium of the protoliths with a fluid of composition X_CO2 = CO₂/(CO₂ + H₂O) = 0.1–0.25 for temperatures of 315–320 °C. The inner zone of the alteration halo reflect equilibrium with a fluid of composition X_CO2≈ 0.25. Fluid‐rock buffering calculations show that the alteration halo is consistent with interaction with a single fluid composition and that the zoned structure of the halo reflects the volume of this fluid with which the rocks reacted. This fluid is likely to have also been the one responsible for the gold mineralisation at Kalgoorlie.     

Archaean lode gold mineralisation in banded iron formation at the Kalahari Goldridge deposit, Kraaipan Greenstone Belt, South Africa

The Kalahari Goldridge Mine is located within the Archaean Kraaipan Greenstone Belt, about 60 km southwest of Mafikeng in the North West Province, South Africa. The ore body thickness varies from 15 to 45 m along a strike length of about 1.5 km within approximately N–S striking banded iron formation (BIF). The stratabound ore body is hosted primarily by BIF, which consists of alternating chert and magnetite–chlorite–stilpnomelane–sulphide–carbonate bands of millimetre- to centimetre scale. A footwall of sericite–carbonate–chlorite schist underlain by mafic amphibolite occurs to the west and carbonaceous metapelites in the hanging wall to the east. Overlying the hanging wall, carbonaceous metapelites, units of coarse-grained metagreywackes fining upwards, become increasingly conglomeratic up the stratigraphy. Small-scale isoclinal folds, brecciation, extension fractures and boudinage of cherty BIF units reflect brittle-ductile deformation. Fold axial planes have foliation, with subvertical plunges parallel to prominent rodding and mineral lineation in the footwall rocks. Gold mineralisation is associated with two generations of quartz–carbonate veins, dipping approximately 20° to 40° W. The first generation consists of ladder-vein sets (group IIA) preferentially developed in centimetre-scale Fe-rich mesobands, whereas the second generation consists of large quartz–carbonate veins (group IIB), which locally crosscut the entire ore body and extend into the footwall and hanging wall. The ore body is controlled by mesoscale isoclinal folds approximately 67° E, orthogonal to the plane of mineralised, gently dipping veins, defining the principal stretching direction and development of fluid-focussing conduits. The intersections of the mineralised veins and foliation planes of the host rock plunges approximately 08° to the north. Pervasive hydrothermal alteration is characterised by chloritisation, carbonatisation, sulphidation and K-metasomatism. Gold is closely associated with sulphides, mainly pyrite and pyrrhotite, and to a lesser extent, with bismuth tellurides and carbonate minerals. Mass balance transfer calculations indicate that hydrothermal alteration of BIF involved enrichment of Au, Ag, Bi, Te, S and CO₂ (LOI), MgO, Ba, K and Rb, but significant depletion of SiO₂ and, to a lesser extent, Fe₂O₃. Extensive replacement of magnetite and chlorite in BIF and other pelitic sedimentary rocks by sulphide and carbonate minerals, both on mesoscopic and microscopic scales, is evidence of interaction of CO₂- and H₂S-bearing fluids with the Fe-rich host rocks. The fineness of gold grains ranges from 823 to 921, similar to that of other epigenetic Archaean BIF-hosted gold deposits, worldwide.     

西藏羊八井地热田水热蚀变的时空演化特征

西藏亚东—谷露裂谷中—北段的羊八井地热田是我国著名的高温地热田,研究其水热蚀变的时空演化有助于更好地认识藏南地热的发育特征。通过对羊八井地热田及其水热蚀变岩开展地表调查、显微特征与X衍射分析等工作,总结了其主要蚀变类型特征,划分出黄褐色蚀变中心带、灰白色中强蚀变带、灰白色中等蚀变带和浅灰白色弱蚀变带4个不同的水热蚀变带,并区分出红褐色—黄褐色蚀变期、灰白色蚀变期和淡黄色—灰色蚀变期共3期蚀变。研究结果揭示,羊八井地热田高温地热活动中心一直在北区硫磺沟区域,其水热蚀变活动主要受亚东—谷露裂谷内部的活动断裂构造控制,并与断裂构造活动具同步性;地热水的排泄方式早期为沿北东向断裂构造直接排泄,晚期为经浅层第四系径流后再排泄,由直接排泄向间接排泄转变;中高温地热水的排泄区由北区硫磺沟地区向南区藏布曲迁移。根据研究结果推断,硫磺沟区域的北东向断裂与北西向断裂交汇区可作为羊八井热田北区深部地热勘查的主要方向。     

含铀副矿物的热液蚀变：来自华南鹿井矿田碎裂蚀变岩型铀矿床的矿物学研究

花岗岩型铀矿中铀的来源问题,长期以来是铀矿床学研究的热点问题之一。大多数学者认为其成矿物质主要来源于花岗岩本身的含铀副矿物,然而对于含铀副矿物热液蚀变行为研究较少。鹿井铀矿田位于诸广山复式岩体的中部,是华南最主要花岗岩型铀矿田之一,碎裂蚀变岩型铀矿化在该矿田内占主导地位。小山铀矿床位于鹿井矿田中部,是近些年新发现的碎裂蚀变岩型矿床。本文以钻孔ZK1-1为研究对象,对热液蚀变带开展了精细矿物学研究。研究表明：蚀变带中发育有晶质铀矿、铀石—钍石、独居石、磷钇矿、锆石、磷灰石、金红石等含铀副矿物。晶质铀矿、铀石—钍石中铀含量高,热液蚀变条件不稳定,铀容易释放;独居石蚀变为直氟碳钙铈矿和磷钇矿蚀变为次生磷灰石过程中容易释放出铀;锆石因结构稳定,铀难以释放;磷灰石、金红石中铀含量较低,供铀能力差。综合分析认为花岗岩中晶质铀矿、铀石—钍石是主要铀源矿物,独居石、磷钇矿为次要铀源矿物。     

Palaeoenvironmental significance of rounded pyrite in siliciclastic sequences of the Late Archaean Witwatersrand Basin: oxygen‐deficient atmosphere or hydrothermal alteration?

Petrographic and sulphur isotope studies support the long‐held contention that rounded grains of pyrite in siliciclastic sequences of the Late Archaean Witwatersrand Supergroup originated as placer grains. The grains are concentrated at sites where detrital heavy minerals are abundant within quartz‐pebble conglomerates and quartzose sandstones. Depositional sites with abundant pyrite are: (1) within the matrix of bar‐type, clast‐supported conglomerates; (2) on scoured or winnowed surfaces; and (3) on stratification planes. The grains are internally compact or porous, with truncation of internal structure at outer margins indicating fragmentation and rounding of pyritic source‐rocks during erosion and sediment transport. A large range in textures reflects source‐rock lithologies, with known varieties linked to sedimentary‐hosted diagenetic pyrite, volcanic‐hosted massive sulphide deposits and hydrothermal pyrite. Laser ablation sulphur isotope analysis of pyrite reveals a broader range in δ³⁴S values (? 5·3 to + 6·7‰) than that of previously reported conventional bulk‐grain analyses (? 1 to + 4‰). Rounded pyrite from the Steyn Reef has significant variation in δ³⁴S values (? 4·7 to + 6·7‰) that establishes heterogeneous sulphur compositions, with even adjacent grains having diverse isotopic signatures. The heterogeneity supports a placer origin for rounded pyrite. Euhedral pyrite and pyrite overgrowths which are undoubtedly authigenic have restricted δ³⁴S values (? 0·5 to + 2·5‰), are chemically distinct from rounded pyrite and are probably the products of metamorphism or hydrothermal alteration. The placer origin of rounded pyrite indicates that pyrite was a stable heavy mineral during erosion and transport in the early atmosphere. Its distribution in three sequences (Witwatersrand Supergroup, Ventersdorp Contact Reef and Black Reef), and in other sequences not linked to Witwatersrand‐type Au‐U ore deposits, implies deposition of redox‐sensitive detrital heavy minerals during the Late Archaean. Consequently, rounded grains of detrital pyrite are strong indicators of an oxygen‐poor atmosphere. While not confirming a placer origin for gold in Witwatersrand Au‐U ore deposits, the palaeoenvironmental significance of rounded pyrite negates its link to hydrothermal mineralization.     

The metamorphic evolution of granulites at Fyfe Hills; implications for Archaean crustal thickness in Enderby Land, Antarctica

Abstract Granulites at Fyfe Hills in Enderby Land, Antarctica, crystallized at temperatures in excess of 850°C, and possibly as high as 1000°C, and at pressures of 8-10kbar during the mid to late Archaean. A number of features, including repeated retrograde metamorphism at 5.5-8kbar, retrograde reaction textures, and rimward zoning in pressure sensitive systems, suggest that following peak metamorphism the granulites stabilized at a depth of 18-26 km. After stabilization, the granulites cooled near-isobarically to temperatures of 600-700°C. Assuming a total crustal thickness of 35-40 km during this late Archaean interval of isobaric cooling, the peak metamorphic crustal thickness is estimated at 35-56 km. This estimate is significantly less than the 60-70 km obtained by summing the depths of the present levels of exposure (26-34 km) and the thickness of the crust presently beneath Fyfe Hills (approxi-mately 35km) and is, therefore, consistent with independent evidence for extensive post-Archaean thickening of the Enderby Land crust.     

长白山地区水热蚀变分布与主要断裂带的空间关系

基于Landsat8 OLI数据,针对长白山地区综合使用比值法和主成分分析法提取水热蚀变信息,提取精度经野外验证为83.3%。利用等距分区加权叠加分析的统计方法对该地区水热蚀变分布和主要断裂带的空间关系进行了定量分析。研究结果表明水热蚀变的强度与该区域距断裂带的距离呈现负相关。新形成的断裂带附近以及断裂带的交汇处水热蚀变强度较大。     

The Hydrothermal Na—Ca Alteration at the Marginal Part of the Florina Granite and the Associated Magnetite—Hematite Bands With Thorium and Uranium Mineralization

The Oxia mineralized granite is the product of differentiation in the external parts of the Florina magmatic mass. Acidic hydrothermal solutions either of magmatic or of meteoric origin reacted with the upper tectonically fractured parts of the Florina granite and became enriched in iron, thorium, uranium, zircon and rare-earth elements. The most abundant alteration minerals are sericite and quartz, while the minerals of the mineralization bands include magnetite, hematite, thorite, monazite and zircon. The outer parts of the Oxia granite made it easy the percolation of hydrothermal solutions from the deeper heater to the upper cooler parts of the granite which acted as a hot spot.     

Structural control and hydrothermal alteration at the BIF-hosted Raposos lode-gold deposit, Quadrilátero Ferrífero, Brazil

In the Raposos orogenic gold deposit, hosted by banded iron-formation (BIF) of the Archean Rio das Velhas greenstone belt, the hanging wall rocks to BIF are hydrothermally-altered ultramafic schists, whereas metamafic rocks and their hydrothermal schistose products represent the footwall. Planar and linear structures at the Raposos deposit define three ductile to brittle deformational events (D₁, D₂ and D₃). A fourth group of structures involve spaced cleavages that are considered to be a brittle phase of D₃. The orebodies constitute sulfide-bearing D₁-related shear zones of BIF in association with quartz veins, and result from the sulfidation of magnetite and/or siderite. Pyrrhotite is the main sulfide mineral, followed by lesser arsenopyrite and pyrite. At level 28, the hydrothermal alteration of the mafic and ultramafic wall rocks enveloping BIF define a gross zonal pattern surrounding the ore zones. Metabasalt comprises albite, epidote, actinolite and lesser Mg/Fe–chlorite, calcite and quartz. The incipient stage includes the chlorite and chlorite-muscovite alteration zone. The least-altered ultramafic schist contains Cr-bearing Mg-chlorite, actinolite and talc, with subordinate calcite. The incipient alteration stage is subdivided into the talc–chlorite and chlorite–carbonate zone. For both mafic and ultramafic wall rocks, the carbonate–albite and carbonate–muscovite zones represent the advanced alteration stage.Rare earth and trace element analyses of metabasalt and its alteration products suggest a tholeiitic protolith for this wall rock. In the case of the ultramafic schists, the precursor may have been peridotitic komatiite. The Eu anomaly of the Raposos BIF suggests that it was formed proximal to an exhalative hydrothermal source on the ocean floor. The ore fluid composition is inferred by hydrothermal alteration reactions, indicating it to having been H₂O-rich containing CO₂ + Na⁺ and S. Since the distal alteration halos are dominated by hydrated silicate phases (mainly chlorite), with minor carbonates, fixation of H₂O is indicated. The CO₂ is consumed to form carbonates in the intermediate alteration stage, in halos around the chlorite-dominated zones. These characteristics suggest variations in the H₂O to CO₂-ratio of the sulfur-bearing, aqueous-carbonic ore fluid, which interacted at varying fluid to rock ratios with progression of the hydrothermal alteration.     

The application of P–T–X(CO2) modelling in constraining metamorphism and hydrothermal alteration at the Damang gold deposit,Ghana

Orogenic gold mineralization at the Damang deposit, Ghana, is associated with hydrothermal alteration haloes around gold‐bearing quartz veins, produced by the infiltration of a H₂O–CO₂–K₂O–H₂S fluid following regional metamorphism. Alteration assemblages are controlled by the protoliths with sedimentary rocks developing a typical assemblage of muscovite, ankerite and pyrite, while intrusive dolerite bodies contain biotite, ankerite and pyrrhotite, accompanied by the destruction of hornblende. Mineral equilibria modelling was undertaken with the computer program thermocalc , in subsets of the model system MnO–Na₂O–CaO–K₂O–FeO–MgO–Al₂O₃–SiO₂–CO₂–H₂O–TiO₂–Fe₂O₃, to constrain conditions of regional metamorphism and the subsequent gold mineralization event. Metapelites with well‐developed amphibolite facies assemblages reliably constrain peak regional metamorphism at ~595 °C and 5.5 kbar. Observed hydrothermal alteration assemblages associated with gold mineralization in a wide compositional range of lithologies are typically calculated to be stable within P–T–X(CO₂) arrays that trend towards lower temperatures and pressures with increasing equilibrium fluid X(CO₂). These independent P–T–X(CO₂) arrays converge and the region of overlap at ~375–425 °C and 1–2 kbar is taken to represent the conditions of alteration approaching equilibrium with a common infiltrating fluid with an X(CO₂) of ~0.7. Fluid‐rock interaction calculations with M–X(CO₂) diagrams indicate that the observed alteration assemblages are consistent with the addition of a single fluid phase requiring minimum fluid/rock ratios on the order of 1.     

Highly alkaline,high-temperature hydrothermal fluids in the early Archean ocean

Based on the petrology of hydrothermally altered Archean basaltic greenstones, thermodynamic calculations of phase equilibria were conducted to estimate the composition of a high-temperature (∼350 °C) hydrothermal fluid in an Archean subseafloor basalt-hosted hydrothermal system. The results indicate that the hydrothermal fluid was highly alkaline attributed to the presence of calcite in the alteration minerals under a high-CO₂ condition, and predict a generation of SiO₂-rich, Fe-poor hydrothermal fluids in the Archean subseafloor hydrothermal system. The chemically reactive mixing zones between alkaline hydrothermal fluids and slightly acidic-neutral seawater are characterized by inverse pH and chemical polarity to modern hydrothermal systems, leading to extensive precipitation of silica and iron oxyhydroxides on/under the seafloor. Such processes can be responsible for the abiotic formation of voluminous chert and subseafloor silica dike, the mechanism of silicification, and the pH-controlled generation of banded iron formation that has been arising mainly from the redox chemistry in the Archean ocean. Such high-temperature alkaline fluids could have had a significant role not only in the early ocean geochemical processes but also in the early evolution of life.