Phase state of the carbonaceous matter in the metalliferous shales of the Russian Far East

Carbonaceous matter (CM) in shales of some deposits and occurrences of the Russian Far East has been studied by scanning and transmission electron microscopy, Raman spectroscopy, and X-ray phase and differential thermal analyses. It was shown that the carbonaceous matter in the high-temperature shales (amphibolite facies) of the Soyuznoe deposit is represented by holocrystalline graphite, while the low-temperature (greenschist facies) shales of the Sutyr and Kimkan sequences contain mainly nanocrystalline graphite. It was substantiated for natural objects that platinum is assimilated by graphite at high temperatures. This should be taken into account in planning the prospecting works, as well as in developing a technique for enrichment of carbonaceous ore, because high-temperature carbonaceous shales with holocrystalline graphite are promising for Pt, unlike their low-temperature analogues with nanocrystalline graphite.     

Accumulation and fractionation of rare earth elements in surface waters of the Russian Far East under the conditions of natural and anthropogenic anomalies

The distribution and fractionation of rare earth elements were studied in surface waters from areas with different anthropogenic impacts in the southern part of the Russian Far East and in natural anomalous waters from areas with intense volcanic-hydrothermal activity. The levels of REE contents and their fractionation in the sequence from the light to heavy REE were estimated in different waters, and their connections with major ions and other trace elements, primarily Al, Fe, and Mn, were determined. The relations of the main forms of REE migration (dissolved and suspended) in surface waters were evaluated, and fundamental differences were detected in the accumulation of REE in the natural acid waters of the Kuril Islands and under continental conditions related to their deep input and redistribution in streams.     

Mesozoic Metallogeny of the Russian Far East

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俄罗斯远东岗仁地体金铜矿床地质、地球化学特征及其LA-ICP-MS 锆石U-Pb 年龄

岗仁地体位于额尔古纳超地体北部边缘,蒙古—鄂霍茨克构造带南部,该区分布着大量的大型、超大型金矿床,这些矿床在成因上与中酸性侵入岩和浅成次火山岩关系密切。岩石地球化学研究表明,花岗闪长岩-闪长岩组合明显富集大离子亲石元素、不相容元素和轻稀土元素,亏损高场强元素和重稀土元素。球粒陨石标准化稀土配分模式为轻稀土元素富集、重稀土元素亏损的右倾型,具有微弱的负Eu异常或基本无Eu异常,无Ce异常,元素地球化学性质反映出花岗闪长岩-闪长岩组岩浆具有壳幔混合的特征,且形成于大陆边缘的火山弧环境。LA-ICP-MS锆石U-Pb测年结果揭示,皮奥涅尔金银矿床含矿闪长玢岩的206Pb/238U年龄加权平均值为113.8±2.0Ma,博尔古利坎铜金钼矿床赋矿二长闪长斑岩的206Pb/238U年龄加权平均值为112.7±2.8Ma,与皮奥涅尔金银矿床和博尔古利坎铜金钼矿床成矿有关的奥列佳花岗闪长岩体的年龄分别为117.2±1.3Ma和117.0±3.6Ma。由此可知,皮奥涅尔金银矿床和博尔古利坎铜金钼矿床形成于燕山早期,与中国黑龙江地区三道湾子金矿、东安金矿等金矿床形成时代一致。     

俄罗斯远东岗仁地体金铜矿床地质、地球化学特征及其LA-ICP-MS锆石U-Pb年龄

岗仁地体位于额尔古纳超地体北部边缘,蒙古—鄂霍茨克构造带南部,该区分布着大量的大型、超大型金矿床,这些矿床在成因上与中酸性侵入岩和浅成次火山岩关系密切。岩石地球化学研究表明,花岗闪长岩-闪长岩组合明显富集大离子亲石元素、不相容元素和轻稀土元素,亏损高场强元素和重稀土元素。球粒陨石标准化稀土配分模式为轻稀土元素富集、重稀土元素亏损的右倾型,具有微弱的负Eu异常或基本无Eu异常,无Ce异常,元素地球化学性质反映出花岗闪长岩-闪长岩组岩浆具有壳幔混合的特征,且形成于大陆边缘的火山弧环境。LA-ICP-MS锆石U-Pb测年结果揭示,皮奥涅尔金银矿床含矿闪长玢岩的206Pb/238U年龄加权平均值为113.8±2.0Ma,博尔古利坎铜金钼矿床赋矿二长闪长斑岩的206Pb/238U年龄加权平均值为112.7±2.8Ma,与皮奥涅尔金银矿床和博尔古利坎铜金钼矿床成矿有关的奥列佳花岗闪长岩体的年龄分别为117.2±1.3Ma和117.0±3.6Ma。由此可知,皮奥涅尔金银矿床和博尔古利坎铜金钼矿床形成于燕山早期,与中国黑龙江地区三道湾子金矿、东安金矿等金矿床形成时代一致。     

The evolution of alkaline, saline ground- and surface waters in the southern Siberian steppes

Groundwaters, river and lake waters have been sampled from the semi-arid Siberian Republic of Khakassia. Despite the relatively sparse data set, from a diversity of hydrological environments, clear salinity-related trends emerge that indicate the main hydrochemical evolutionary processes active in the region. Furthermore, the major ion chemistry of the evolution of groundwater baseflow, via rivers, to terminal saline lake water, can be adequately and simply modelled (using PHREEQCI) by invoking: (i) degassing of CO₂ from groundwater as it emerges as baseflow in rivers (rise in pH); (ii) progressive evapoconcentration of waters (parallel accumulation of Cl⁻, Na⁺, SO₄²⁻, and increase in pH due to common ion effect); and (iii) precipitation of calcite (depletion of Ca from waters, reduced rate of accumulation of alkalinity). Dolomite precipitation is ineffective at constraining Mg accumulation, due to kinetic factors. Silica saturation appears to control dissolved Si in low salinity waters and groundwaters, while sepiolite saturation and precipitation depletes Si from the more saline surface waters. Gypsum and sodium sulphate saturation are only approached in the most saline environments. Halite remains unsaturated in all waters. Sulphate reduction processes are important in the lower part of lakes.     

Noble metal-bearing ferromanganese deposits in the Kimkan basin,Russian Far East

It has been established that large ferromanganese deposits enriched in noble metals, Co, U, V, and REE in the Kimkan sedimentary basin are confined to Vendian–Cambrian black shales. Lithostratigraphy plays an important role in the localization of such deposits and promising ore-bearing fields. Deposits and occurrences of complex iron and ferromanganese ores are polygenous and polychronous, because they underwent intense hydrothermal alterations with the superposition of noble metal and uranium mineralization in the Cretaceous. Efficient utilization of complex iron ores in the Kimkan open pit needs the construction of a metallurgical plant.     

Organic films on particulate matter in surface waters off eastern Asia

SEM examination of suspended material collected by filtration from samples of surface waters over continental shelves and deeper areas off eastern Asia reveals the presence of irregular organic films that are longer, cover more filter area, and have more tapered edges in samples from nearshore than offshore regions. Associated diatoms include species diagnostic of coastal environments. Films and coastal diatoms are most abundant in waters above continental shelves where river discharges cause the waters to be more dilute than 33.5‰ salinity. Farther from shore, both films and skeletal elements are broken and partly dissolved. Skeletal elements, faecal matter, and other debris are trapped or adhere to the films, which therefore provide a concentrated food source for small organisms beyond nearshore regions of high primary productivity. The films contribute an unknown percentage of the total organic matter that reaches bottom sediments.     

Lithological composition of island-arc complexes in the Russian Far East

The results of study of geochemistry of terrigenous rocks from the contrast (in structure) Cretaceous-Paleogene complexes of Sikhote Alin and Kamchatka are summarized. The data obtained were interpreted based on comparison with the geochemical composition of recent and ancient sediments accumulated in the well-known geodynamic settings. It is shown that the chemical composition of terrigenous rocks and some petrochemical ratios can serve as reliable indicators of various island-arc settings. These indicators make it possible to discriminate sufficiently reliably these settings in paleobasins of orogenic zones.     

Resource-based development in the Russian Far East: Problems and prospects

The paper examines the prospects for resource-based development in the Russian Far East. It adopts a critical perspective on the potential for resource-based development by examining problems with Far East resource industries, specifically by looking at the experience of the other resource economies more generally. In particular, it highlights the new geo-economic context for resource development in the Far East of Russia as the world economy approaches the much touted, and now questioned, ‘Pacific Century’.     

Geochemistry of the mineral waters and gases of the Mukhen deposit,Far East

This work reports new hydrochemical data on the two types of cold high p CO₂ groundwaters from the Mukhen deposit (Khabarovsk district). The first type is classed with HCO₃-Ca-Mg waters with a relatively low TDS (up to 1.7 g/l) and high concentrations of Fe²⁺, Mn²⁺, Ba²⁺, and SiO₂. The second type is of HCO₃-Na composition with high TDS (up to 14 g/l) and elevated Li⁺, B, Sr²⁺, Br^?, and I^?. New oxygen (δ¹⁸O) and hydrogen (δD) isotopic data on the waters and carbon (δ¹³C) isotopic data on the gas phase, together with a detailed geological and hydrogeological analysis of the study area, allowed us to decipher the origin of both the mineral waters. Based on the tritium content (³H) in the ground and surface waters of the area, the duration of the mineral water circulation was estimated. It was established that the both types of groundwaters were formed during interaction of meteoric water with bedrock under active influence of CO₂, however HCO₃-Na groundwaters have longer residence time than HCO₃-Ca-Mg groundwaters.     

Tungsten accessory minerals in lithium-fluoric granites of the Russian Far East

By means of the technique of local analysis, the presence of a wide variety of tungsten and tungsten-containing accessories was first revealed in the composition of lithium-fluoric granites of the Far East, which represents a substantial similarity and regional peculiarity of these rocks. It was concluded that the tungsten accessory mineralization might be considered as an indication of the genetic relationship of the mineralization of the East Asian tin-tungsten zone to the Pacific rare-metal granites.     

俄罗斯远东金属矿床形成条件的古地球动力学分析

根据本区地质构造的新资料,提出了区域板块构造模型。研究了从俯冲到加利福尼亚型转换和由后者又到俯冲的古地球动力学环境更替的意义。这种更替发生在对本区最重要的中—新生代历史时期,对区域成矿带整体乃至一些金属矿床的形成具有重要影响。论证了一些地体性质,尤其是俯冲-增生杂岩对矿床形成的重要意义。     

Fahlores of the Prasolovka Au-Ag volcanogenic deposit, Kunashir Island, Russian Far East

The chemical study shows that fahlores from the Prasolovka deposit are complex compounds with significant variations in their composition and the proportions of their constituent elements. Based on their major-element composition, they are subdivided into 3 species and 11 inter-and intra-species varieties. The chemical composition of the fahlores in different mineral assemblages from different ore types indicates that As fahlores subsequently replaced by Sb, Te-Sb, and Te fahlores during ore precipitation. The revealed evolution of the ore solutions from the early to late stages testifies that different ores at the Prasolovka deposit were formed under different physicochemical conditions.     

Late Jurassic-Early Cretaceous coal-forming plants of the Bureya Basin,Russian Far East

The analysis of the composition of fossil palynomorphs from coals and clastic rocks of the Talyndzhan, Dublikan, Soloni, Chagdamyn, and Chemchuko formations of the Bureya coaliferous Basin revealed that the main coal-forming plants during the Talyndzhan and Dublikan time were represented by cyatheaceous ferns, plants similar to Pinaceae, and plants produced Ginkgocycadophytus pollen. In the Soloni time, the boggy plant communities were composed of dominant Cyatheaceae, subordinate Pinaceae, rare Gleichenaceae representatives, and Ginkgocycadophytus-producing plants. During the Chagdamyn time, the main coal-forming role belonged to gleicheniaceous ferns, bryophytes, and lycopsids, while the Chemchuko time was marked by the dominant contribution of Gleicheniaceae, Cyatheaceae, Ginkgocycadophytus, and plants close to Taxodiaceae to the coal formation.     

Deep structure,genesis, and seismic activation of the Bureya orogen,Russian Far East

The Bureya orogen is a special object among the geodynamic factors determining the high seismicity of the Lower Amur region. Its location and deep structure are studied on the basis of comprehensive geophysical and tectonic data. This orogen is a low-density lithospheric domain expressed by an intensive negative gravity anomaly and Moho sunken down to 40 km depth. Within the limits of this lithospheric structure, contemporary uplifting takes place to form a meridional dome peaking at more than 2000 m altitude. The position of the orogen in the regional structure gives us grounds to think that the Bureya orogen formed in the Paleogene, at the finishing stage of tectonic block movement along the Pacific margin represented by the NE-trending strike-slip faults of the Tang Lu Fault Zone. Compression was concentrated at the triple junction between the Central Asian, Mongolian–Okhotian, and Sikhote Alin tectonic belts. The meridional orientation of the Bureya orogen is associated with the parallel elongated Cenozoic depressions in the region. The united morphotectonic system may have formed resulting from lithospheric folding under horizontal shortening in the Paleocene–Eocene. The wavelength of the Lower Amurian fold system is 250 km, which is consistent with the theoretical estimates and examples of lithospheric folds in other regions. The contemporary activation of the Bureya orogen began in the Miocene, under the effect of the Amurian Plate front moving in the northeastern direction. As a result of shortening, the meridional cluster of weak (M ≥ 2.0) earthquakes formed along the western boundary of the orogenic dome. The most intensive deformations caused another type of seismicity associated with the activation-related uplift of the mentioned orogen. As a result, the so-called Bureya seismic zone formed above the apex of the dome, and it is here that the strongest regional earthquakes (M ≥ 4.5) occur.     

Complex mineralization at large ore deposits in the Russian Far East

Genetic and mineralogical features of large deposits with complex Sn, W, and Mo mineralization in the Sikhote-Alin and Amur-Khingan metallogenic provinces are considered, as well as those of raremetal, rare earth, and uranium deposits in the Aldan-Stanovoi province. The spatiotemporal, geological, and mineralogical attributes of large deposits are set forth, and their geodynamic settings are determined. These attributes are exemplified in the large Tigriny Sn-W greisen-type deposit. The variation of regional tectonic settings and their spatial superposition are the main factor controlling formation of large deposits. Such a variation gives rise to multiple reactivation of the ore-magmatic system and long-term, multistage formation of deposits. Pulsatory mineralogical zoning with telescoped mineral assemblages related to different stages results in the formation of complex ores. The highest-grade zones of mass discharge of hydrothermal solutions are formed at the deposits. The promising greisen-type mineralization with complex Sn-W-Mo ore is suggested to be an additional source of tungsten and molybdenum. The Tigriny, Pravourminsky, and Arsen’evsky deposits, as well as deposits of the Komsomol’sk and Khingan-Olonoi ore districts are examples. Large and superlarge U, Ta, Nb, Be, and REE deposits are localized in the southeastern Aldan-Stanovoi Shield. The Ulkan and Arbarastakh ore districts attract special attention. The confirmed prospects of new large deposits with Sn, W, Mo, Ta, Nb, Be, REE, and U mineralization in the south of the Russian Far East assure expediency of further geological exploration in this territory.