Composition and genesis of the organic matter in the bottom sediments of the East Siberian Sea

The chemical composition of organic matter (C_org, N_org, δ¹³C, δ¹⁵N, and n-alkanes) was studied in the top layer of bottom sediments of the East Siberian Sea. Possible ways were proposed to estimate the amount of the terrigenous component in their organic matter (OM). The fraction of terrigenous OM estimated by the combined use of genetic indicators varied from 15% in the eastern part of the sea, near the Long Strait, to 95% in the estuaries of the Indigirka and Kolyma rivers, averaging 62% over the sea area.     

Composition of interstitial waters and forms of sulfur compounds in bottom sediments in the northeastern Black Sea

Study of sediments and water column in the Black Sea has been carried out for a long time. However, issues of the formation of seawater and sediments in the geological (ancient) and Recent marine history remain debatable so far. Studies of the physical, biological, and biogeochemical settings in the northeastern part of the Black Sea carried out onboard the R/V Professor Shtokman in 2009 yielded new data on this region. The present paper reports the results of study of the chemical composition of bottom sediments and interstitial waters from the meridional profile extending from the Kerch Peninsula to the central part of the eastern deep-water depression.     

Influence of natural organic acids on the Mg/Ca ratio in the bottom sediments of highly mineralized lakes

Thermodynamic modeling of equilibria in the system water–rock–organic acids was used to study the influence of organic acids on Ca and Mg redistribution between a solution and a solid phase in connection with the use of calcites of variable composition Ca_xMg_1–xCO₃ as indicators of paleoclimatic environments. In the thermodynamic model, high-molecular humic substances (fulvic + humic acids) were represented by a set of independent metal-binding centers. Therefore, their number was preset based on the given density of proton- or metal-binding sites. The numerical implementation of several geochemical situations involving the dissolution/deposition of calcites with different Mg contents showed that the main effect of fulvic and humic acids is the acidification of solutions and the reduction of carbonate stability. Although humic substances can play an important role in fixing Ca and Mg and removing them from solution, their actual concentrations in natural media (<<1 g/L) do not cause significant changes in the composition of Ca_xMg_1–xCO₃ phases. On the other hand, there is quantitative evidence that variations in the Mg/Ca ratio in a solution and a solid phase are significantly influenced by the evaporative concentration of Mg-oversaturated solutions, alkalization/acidification during their evolution, or CO₂ content variations owing to changes in climate and lake activity.     

Volatile organic compounds in Quaternary sediments

The distribution of volatile organic compounds in surface sediments varies widely with the depositional environment. Oxygen and sulfur compounds, alkenes and arenes, are more abundant than alkanes in strongly reducing sediments such as those from around Walvis Bay, West Africa. Among the compounds identified by GC-MS were toluene, benzene, 2-methyl-2-butene, 3,5-dimethylcyclopentene, 3-menthylfuran, 3-methylfuran, 2-methylbutanol, 3-methylbutanol, 3-pentanone, 2-methylthiophene, 3-methylthiophene and dimethylsulfide. Some of these compounds have the isoprene carbon skeleton.In a less reducing environment such as the Arabian Sea-Persian Gulf area, a more diverse alkene assemblage was observed including ethylene, propylene, pentenes, hexenes, cyclohexene, methylpentenes and dimethylcyclopentenes. Also, the sediments contained a few very specific alkane structures. The gem-dimethyl hydrocarbons (neopentane, neohexane, and neoheptane) were dominant among the branched hydrocarbons. The high concentration of volatile alkenes and oxygen and sulfur compounds is not observed in deep sea drilling samples at depths greater than about 100 m.     

Speciation of some heavy metals in bottom sediments of the Ob and Yenisei estuarine zones

The speciation of Fe, Mn, Zn, Cu, Co, Ni, Cr, Pb, and Cd was studied in 52 samples of bottom sediments collected during Cruise 49 of the R/V Dmitrii Mendeleev in estuaries of the Ob and Yenisei rivers in the southwestern Kara Sea. Immediately after sampling, the samples were subjected to on-board consecutive extraction to separate metal species according to their modes of occurrence in the sediments: (1) adsorbed, (2) amorphous Fe-Mn hydroxides and related metals, (3) organic + sulfide, and (4) residual, or lithogenic. The atomic absorption spectroscopy of the extracts was carried out at a stationary laboratory. The distribution of Fe, Zn, Cu, Co, Ni, Cr, Pb, and Cd species is characterized by the predominance of lithogenic or geochemically inert modes (70–95% of the bulk content), in which the metals are bound in terrigenous and clastic mineral particles and organic detritus. About half of the total Mn amount and 15–30% Zn and Cu is contained in geochemically mobile modes. The spatiotemporal variations in the proportions of metal species in the surface layer of sediments along the nearly meridional sections and through the vertical sections of bottom sediments cores testify that Mn and, to a lesser extent, Cu are the most sensitive to changes in the sedimentation environment. The role of their geochemically mobile species notably increases under reducing conditions.     

The relationship between zinc and organic content in centre-lake bottom sediments

The relationship between Zn and organic content, the latter measured by percentage weight loss on ignition (LOI) is investigated in a suite of 3844 centre-lake bottom sediments from east-central Saskatchewan. The data indicate that Zn values have a strong sympathetic increase with LOI below 12% LOI. Zn values tend to stabilize above 12% LOI, in actuality they decrease slowly from 12 to 50% LOI before decreasing at an accelerated rate over 50% LOI.It is proposed that the change from a sympathetic Zn vs. LOI relationship to an antipathetic relationship occurs because there is insufficient Zn available, from weathering, etc., in the lake water of sampled lakes to maintain the sympathetic relationship. Therefore, the lack of Zn, together with the increasing availability of organic material, creates an excess adsorption capacity of the lake sediments. Below 12% LOI, in lake sediments that do not have an excess adsorption capacity, Zn distribution patterns will be partly controlled by the amount of organic material present. Thus, Zn in these lake sediments may not truly reflect the chemistry of a drainage basin. Whereas, above 12% LOI, where there is an excess adsorption capacity in the sediments, the Zn distribution patterns will more closely reflect the chemistry of a drainage basin. The observed decrease in Zn values obvious over 50% LOI may be reflecting a dilution factor introduced by the ever increasing load of organic material to a system which is not receiving more Zn.It is concluded that centre-lake bottom sediments whose organic content is dominantly in the range of 12–50% LOI form the most effective sample media for regional lake sediment surveys.     

The regularities of distribution of radionuclides and reare-earth elements in bottom sediments of Siberian lakes

Geochemical studies of the ecosystems of 184 Siberian lakes in three largest zones of northern Asia (humid, arid, and semiarid) and in mountainous area were carried out. The contents of natural radionuclides, radiocesium, and rare-earth elements in conjugate components of the systems and the types of the main sources of the bottom sediment material have been determined.Dating of the bottom sediments was made by the activity of radioisotopes ¹³⁷Cs and ²¹⁰Pb, which permitted estimation of the sedimentation rates in lakes in different regions of Siberia: 0.35 cm/year in the south and 0.25–0.3 cm/year in the north.Six main ions have been determined in the waters of the studied lakes: Ca²⁺, Mg²⁺, Na⁺, HCO₃^?, SO₄^2?, and Cl^?. The distribution of natural radionuclides in the stratified sections of bottom sediments of Siberian lakes evidences the stable sedimentation and characterizes their contents in the soils of water-catchment areas, which can be considered background contents there. Sediments enriched in organic matter have higher concentrations of U and lower ones of Th and K. The Th/K ratio in the studied bottom sediments is the same as in the soils. The Th/U ratios are somewhat lower than those in the soils because U is accumulated by chemogenic and organic components. The overall ¹³⁷Cs pollution of bottom sediments of Siberian lakes is close to the global background (40 mCi /km² in 2000), but in the Altai Territory and Buryatia and Altai Republics it is twice higher. The uneven areal and temporal distribution of residual radiocesium is observed not only in the lacustrine sediments but also in the lake water areas. The REE patterns of bottom sediments of different mineral types are similar to those of continental crust and clays of the Russian Platform, though organogenic and carbonate sediments have higher absolute REE contents than terrigenous ones. Pelitic fraction is the main REE concentrator in the bottom sediments.     

Magnetic properties of bottom sediments from Meromectic Shira Lake (Siberia,Russia)

Magnetic properties were studied in bottom sediments of saline meromictic Shira Lake by the methods of static magnetometry and resonance Mössbauer spectroscopy for the first time. All layers of bottom sediments contain nanosized single-domain magnetite particles produced by magnetotactic bacteria. The concentration of magnetite in bottom sediments decreased with depth, reaching a local minimum in the layer corresponding to the minimal level of the lake observed in 1910–1930. It is demonstrated that biogenic magnetite may indicate climate-related changes in the level of Shira Lake, in addition to the other biological and geochemical characteristics.     

Holocene peat and carbon accumulation rates in the southern taiga of western Siberia

Although recent studies have recognized peatlands as a sink for atmospheric CO₂, little is known about the role of Siberian peatlands in the global carbon cycle. We have estimated the Holocene peat and carbon accumulation rate in the peatlands of the southern taiga and subtaiga zones of western Siberia. We explain the accumulation rates by calculating the average peat accumulation rate and the long-term apparent rate of carbon accumulation (LORCA) and by using the model of Clymo (1984, Philosophical Transactions of the Royal Society of London Series B 303, 605-654). At three key areas in the southern taiga and subtaiga zones we studied eight sites, at which the dry bulk density, ash content, and carbon content were measured every 10 cm. Age was established by radiocarbon dating. The average peat accumulation rate at the eight sites varied from 0.35 ± 0.03 to 1.13 ± 0.02 mm yr⁻¹ and the LORCA values of bogs and fens varied from 19.0 ± 1.1 to 69.0 ± 4.4 g C m⁻² yr⁻¹. The accumulation rates had different trends especially during the early Holocene, caused by variations in vegetation succession resulting in differences in peat and carbon accumulation rates. The indirect effects of climate change through local hydrology appeared to be more important than direct influences of changes in precipitation and temperature. River valley fens were more drained during wetter periods as a result of deeper river incision, while bogs became wetter. From our dry bulk density results and our age-depth profiles we conclude that compaction is negligible and decay was not a relevant factor for undrained peatlands. These results contribute to our understanding of the influence of peatlands on the global carbon cycle and their potential impact on global change.     

Geochemical signature of bottom sediments in the mixing zones of Ob and Yenisei waters with Kara Sea water

This paper reports the results of a study of the geochemistry of bottom sediments from the zones of mixing between the freshwater of the Ob and Yenisei rivers and the saline water of the Kara Sea by means of neutron activation analysis. Using separate datasets for the sediments of the Ob and Yenisei estuaries accumulated under identical facies conditions, some characteristic features of the distribution of a number of chemical elements (mostly lithophile group elements) were established. The differences between them were attributed to distinctive regional geological and geochemical features of the catchments of the Ob and Yenisei, which are inherited by the geochemical characteristics of terrigenous material transported to the sea. The choice of the most informative indicator elements and their grouping on the basis of the character of behavior demonstrated that bottom sediments of the Ob or Yenisei origin can be identified in the marine region studied using the geochemical characteristics of a small group of samples.     

Geochemistry of organic matter of bottom sediments in the rises of the central Arctic Ocean

Based on geomorphological, lithological, and facial characteristics of the East Arctic continental margin, we studied the main factors controlling the Late Cenozoic supply of organic matter (OM) to the bottom sediments of the Central Arctic rises of the Arctic Ocean. Complex analysis of dispersed OM in the samples taken during the expeditions of the R/V “Akademik Fedorov” in 2000 and 2005 showed a significant difference between the sediments of the Lomonosov Ridge and Mendeleev Rise. The bottom sediments of the latter are strongly transformed and lack terrigenous components, as evidenced results from the main geochemical characteristics (contents of C_org, C_carb, N_org, bitumens, and humic acids) and the composition and distribution of hydrocarbon molecular markers (alkanes, saturated and aromatic cyclanes). The obtained data evidence that ancient sedimentary rocks containing genetically uniform deeply transformed (up to mesocatagenesis) OM played a significant role in the formation of the Pleistocene–Holocene sediments of the axial part of the Mendeleev Rise.     

Conditions of the accumulation of organic matter and metals in the bottom sediments of the Chukchi Sea

The chemical composition of bottom sediments in the Chukchi and, partly, East Siberian Seas was studied. In the south and west of the Chukchi Sea, a zone has been detected with the accumulation of sediments rich in organic carbon, an increased background content and anomalies of sulfophile metals (Mo, Zn, Hg, Ag, Au), iron-group metals (V, Ni, Co), and some PGE (Ru, Pt). This zone is confined to the neotectonic active system of rift troughs extending from the Bering Strait and eastern Chukchi Peninsula to the continental slope, where it is bounded by the Cenozoic Charlie rift basin of the Canadian hollow. The geochemical features of the carbon-enriched sediments evidence that they formed under oxygen-deficient conditions and, sometimes, in suboxic and anoxic environments near endogenic water and gas sources. The high carbon and metal contents suggest that the very fine-grained sediments in the rift troughs of the Chukchi Sea are a possible analog of some types of ancient highly carbonaceous sediments belonging to black shales.     

Geochemical factors for endogenic mineral formation in the bottom sediments of the Tazheran lakes (Baikal area)

We studied recent sedimentation in small saline and brackish lakes located in the Ol’khon region (western Baikal area) with arid and semiarid climate. The lakes belong to the Tazheran system; it is a series of compactly located closed shallow lakes, with a limited catchment area and different mineralization, under the same landscape, climatic, geologic, and geochemical conditions. Two complementary approaches are applied in the research: (1) a detailed study of individual lake and (2) a comparison of the entire series of lakes, which can be considered a natural model for studying the relationship between endogenic mineral formation and the geochemistry of lake waters. The lake waters and bottom sediments were studied by a set of modern methods of geochemistry, mineralogy, and crystal chemistry. The mineral component of the bottom sediments was analyzed by powder X-ray diffraction (XRD), IR spectroscopy, and electron microscopy. The lakes are characterized by predominant carbonate sedimentation; authigenic pyrite, smectite, chlorite, and illite are detected in assemblage with carbonate minerals in the bottom sediments. Carbonate phases have been identified, and their proportions have been determined in the samples by decomposition of the complex XRD profiles of carbonate minerals into peaks using the Pearson VII function. Mathematical modeling of the XRD profiles of carbonates has revealed that predominantly Mg-calcites with variable Mg content and excess-Ca dolomite accumulate in lake bottom sediments influenced by biogenic processes. Aragonite, monohydrocalcite, and rhodochrosite form in some lakes along with carbonates of the calcite-dolomite series. We show a dependence of the composition of the assemblages of the newly formed endogenic carbonate minerals and their crystallochemical characteristics on the chemical composition of lake waters.     

Distribution of rare earth elements in waters and bottom sediments of mineralized lakes in the eastern Transbaikal region (Russia)

Contents of rare earth elements in waters and bottom sediments are maximum in the most mineralized soda lakes. It is shown that REE occur in waters mainly as carbonate (LnСО₃)⁺ and oxyhydroxide LnO₂H, LnO⁺, (LnO₂)^– complexes, whose activity in the La → Lu series changes in opposite directions. It has been determined that increase of mineralization leads mainly to higher concentrations of the dissolved HREE. Prevalence of the absolute values of MREE and HREE is recorded in basins with the development of bacterial processes. Geochemical barrier for the accumulation of LREE in waters can be represented by fluorcarbonates, whose saturation degree in the soda lake waters can be several orders of magnitude higher than the solubility products (SP). Oxidative and reductive settings in lakes are favorable for the formation of Ce(OH)₄ and Ce(OH)₃, respectively.     

Evidence of Late Pleistocene ice-dammed lakes in West Siberia

The article discusses geological data on proglacial lakes and spillways in the West Siberian Plain, data on crucial features of the Late Pleistocene reorganization of the drainage pattern of northern Eurasia. The discussion focuses on Late Pleistocene sediments along the margin of the last ice sheet and south of it, including new data recently obtained by the Russian-Norwegian project PECHORA in Trans-Uralia. Based on these data, the margin of the last ice sheet in the western and central parts of West Siberia is localized well above the Arctic Circle, i.e. 150-250 km north of the previously suggested ice limit. The available geochronological evidence indicates that the last ice dam across West Siberia, which diverted the great Siberian rivers to the south, appeared at early stages of the last, Weichselian ice age. The normal, northbound, drainage was restored later, within the time-span accessible to radiocarbon dating, when two pre-Holocene river terraces with mammal fauna were formed. The Late Weichselian was the driest period with ubiquitous aeolian activity and an absence of large water bodies. Preceding ice-dammed lakes of West Siberia could only drain through the Turgai valley which leads southward into the Aral and Caspian seas. The sedimentary sequence of this passage consists of lacustrine clay, diamictic gravity flows and aeolian sediments younger than 29 kyr which infilled the former spillway mainly in the Late Weichselian. The basal sand and gravel mantling the bedrock floor, which descends from 55 m a.s.l. at 55°N to 30-40 m a.s.l. in the south, is the only signature of a southward drainage. This fluvial episode probably reflects overflow of a Siberian proglacial lake whose water level could reach 60 m a.s.l. prior to 29 kyr BP.     

Correlation of upper Bajocian-Bathonian zones in Siberia with the stage standard

The suggestions to transfer the Arcticoceras ishmae Zone from the middle to the lower Bathonian and the Arctocephalites arcticus Zone from the lower Bathonian to the upper Bajocian put forward by some researchers, are critically considered. These suggestions are based on paleontological records from the Sokur quarry near Saratov. Based on paleontological data from Siberia represented in a number of regional ammonite, belemnite, and retroceram zonations, we infer that the proposed zonal subdivision of the Jurassic in the Sokur quarry to be untrue and believe the revision of the correlation of the above-mentioned zones with the stage and zonal standard to be premature because of insufficient argumentation.     

Palynofacies in upper cretaceous sediments of northern Siberia

Different palynomorph groups (spores and pollen of terrestrial plants, dinoflagellate cysts, prasinophytes, acritarchs, Zygnemataceae algae, and others) have been thoroughly studied to define major patterns in their distribution depending on the impact of different environmental factors and to establish their paleoecological characteristics. The comparative analysis of palynomorph assemblages from coeval Cenomanian-Coniacian sediments of the Ust’-Yenisei area, Berezovskaya 23k, Yuzhno-Russkaya 113, Leningradskaya-1 boreholes and Santonian-Campanian sequences of the Ust’-Yenisei, Khatanga and Polar Urals regions reveals transgressive-regressive cycles, which are best evident in coastal sections and smoothed in their marine counterparts. The biofacies and compositions of palynomorphs form the regular succession from the periphery toward central parts of the West Siberian basin. The facies successions in Santonian-Campanian sections of the eastern and western parts of the basin are inconsistent with each other, which may be explained by influence of both the West Siberian and Russian seas on sedimentation in its western areas.     

Thermal conductivity of sediments in high-latitude West Siberia

The thermal conductivity of rocks (λ) used previously to estimate heat flow in high-latitude Siberia was assumed to be λ = 1.8–2.0 W/(m?K), according to published evidence, but was almost never measured specially. We measured the thermal conductivity of core samples from boreholes drilled in the northeastern West Siberian Plate and in the Yenisei–Khatanga basin in the 1990s, using two advanced instruments: a comparator and a scanner of thermal conductivity. Altogether there were 305 samples of air-dry sediments (λ_d) from the 1100–4200 m interval of 23 holes, out of which 77 samples were then moistened (λ_w). The average thermal conductivities of rocks in dry and wet conditions were found to be λ_d = 1.9 ± 0.2 and λ_w = 2.6 ± 0.1 W/(m?K), respectively. Thus, the true thermal conductivity of sediments, which are saturated with water in this northern area, must be about 20–30% higher than that assumed in the previous heat flow determinations, and the latter are thus underestimated correspondingly. The updates to the thermal conductivity values imply major revision to the existing ideas of the thermal regime in the Siberian high latitudes. Such a serious revision of geothermal data will obviously require a large amount of additional experimental work.