Some physicochemical features of a meromictic Lake Suigetsu

Physicochemical features of a typically meromictic lake, Lake Suigetsu, are studied. Vertical distributions of temperature and chlorinity show that the lake is well stratified, and no marked mixing occurs between the upper fresh water and lower salt water. In the chemocline, the vertical gradient of density is large, and the vertical eddy diffusion coefficient is as low as 1.5 × 10^–2 cm² sec.^–1 Dissolved oxygen is saturated in the surface portion of the upper water, and then rapidly decreases with depth towards the chemocline, where sulfide first appears and increases towards the bottom. In the chemocline oxygen consumption is prominent process reaching 290 mg 0₂/m²/day. The oxidation of sulfide, supplied from the underlying water layer, is the main factor causing the oxygen consumption in the chemocline.     

Sedimentary and water column processes in the Oyster Grounds: a potentially hypoxic region of the North Sea

The purpose of this research was to investigate the potential causes of low oxygen levels in the bottom water of the Oyster Grounds region of the shallow southern North Sea, an area which provides suitable conditions for low oxygen levels to develop. At the end of the summer stratified period, relevant biogeochemical processes were investigated using a combination of sedimentary and water column rate measurements. Phytoplankton nitrate and ammonium uptake was measured throughout the water column using (15)N labelled isotopes and showed ammonium uptake dominated in the upper and bottom mixed layer with a maximum 294.4 micromol N m(-3)h(-1). In the deep chlorophyll maximum at the thermocline, primary production was dominated by nitrate uptake, with an average of 35.0 micromol N m(-3)h(-1), relative to ammonium uptake, with an average of 24.6 micromol N m(-3)h(-1). This high relative nitrate uptake will in part result in exportable new production to the isolated bottom mixed layer and sediments, as opposed to regenerated ammonium driven uptake. This biomass export was indicated by significant benthic oxygen consumption rates in the stratified region (782-1275 micromol O(2)m(-2)h(-1)micromol N m(-3)h(-1)) long after the end of the spring bloom. The sediments were also an active net source of nitrate, ammonium, phosphate and silicate into the bottom mixed layer of 4.4, 8.4, 2.3 and 68.8 micromol m(-2)h(-1), respectively. The export of new production within the thermocline to the bottom mixed layer and the consequent sediment oxygen consumption in the isolated bottom mixed layer in the Oyster Grounds are expected to have contributed to the low bottom water oxygen concentrations of 2.07 mg l(-1) (64.7 micromol l(-1)) measured. The long stratified period associated with this low oxygen is predicted to occur more regularly in the future and continued monitoring of this ecologically important region is therefore essential if the causes of these potentially damaging low oxygen levels are to be fully understood.     

Spectral radiometric measurements of the temperature and radiation capacity of a rough sea surface

The results of radiometric remote simultaneous field measurements of the temperature and radiation capacity of the upper layer of the sea-surface temperature film 0.2 mm thick are presented. The measurements were conducted in the presence of wind waves and were characterized by an increased accuracy, which was achieved owing to the use of measurements of the intensity of radio radiation from the surface illuminated by radiation of a specified varying power. In our experiment, this illumination was provided by the radio radiation of the atmosphere, whose radiance temperature varies significantly, depending on the frequency at the slope of the absorption band of molecular oxygen (52.5–56 GHz). As a result, the radiation capacity and temperature of the skin layer were determined from the correlation dependence between the radiance temperatures of the surface and atmosphere measured by a radiometer-spectrometer in a number of channels separated in frequency. The radiance temperatures of the sea and atmosphere were measured at four frequencies of the 5-mm spectral range (53–55 GHz) on a vertical polarization. For absolute measurements, a calibration method was developed on the basis of a blackbody disk and two reflecting mirrors with the same solid angles. The measured values of the radiation capacity are variable and substantially smaller than the theoretical values determined by the models accepted for the permittivity of water and sea roughness. A possible cause of this can be the change of the permittivity of water in a thin surface layer of the temperature film (0.2 mm) due to the concentration of gases dissolved in water and surface-active substances within this layer.     

东海PN断面夏季温盐及化学要素的分布特征

由东海PN断面夏季温鼻度及化学要素CTD资料分析表明，东海夏季的温跃层和盐跃层在次表层生成，其强度随着跃层自陆架坡折区至近岸和外海的上移逐渐减弱。陆架区近表层的温度和盐度呈垂直均匀分布，冲绳海槽次表层呈高温、高盐，近表层呈高温，近表层呈高温、低盐，底层呈低温、次高盐特征。溶解氧浓度自近岸到外海由低变高，表层至底层溶解氧浓度在陆架区由高变低，冲绳海槽区则先由低变高然后又由变低。总二氧化碳浓度自表层至底层和自陆架坡折区到近岸和外海由低变高。磷酸盐和硅酸盐浓度自近岸至外海由高变低，而自表层至底层由低变高。陆架区的近表层和陆架坡折区分别有一个高碱度区。温盐及化学要素的分布特征与夏季海区垂直环流的反气旋运动、长江冲淡水及黑潮水入侵和海面强热辐射有关。此外，化学要素分布还与夏季海区的温盐结构、表混合层与大气间二氧化碳气体交换及表混合层中碳和营养盐光合作用的利用有关。     

Two-dimensional numerical simulation of vertical distributions of dissolved oxygen in Huanghai Sea

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Simulation of the Seasonal Variability of Hydrothermodynamical Fields in Lake Kinneret

We discuss the results of a numerical experiment devoted to the investigation of the variability of the three-dimensional fields of temperature and current velocity brought about by the seasonal variability of external factors: solar radiation, atmospheric fields, discharge of the river Jordan, and water intake for economic necessities. We use a multilayer model in isopycnic coordinates with an upper mixed layer. We set atmospheric factors in the form of monthly average fields that are uniform over space and linearly interpolated in time. We compare the computed fields of heat flux and evaporation through the lake surface, level, temperature, and currents with data of observations. We note a qualitative agreement of temperature fields during the whole year and current velocities in winter when the lake is, in fact, barotropic. In summer when the lake is stratified, currents in the model turn out to be weaker than in observations.     

Variations of mixed layer properties in the Norwegian Sea for the period 1948-1999

The mixed layer of the ocean and the processes therein affect the ocean’s biological production, the exchanges with the atmosphere, and the water modification processes important in a climate change perspective. To provide a better understanding of the variability in this system, this paper presents time series of the mixed layer properties depth, temperature, salinity, and oxygen from Ocean Weather Station M (OWSM; 66° N,2° E) as well as spatial climatologies for the Norwegian Sea. The importance of underlying mechanisms such as atmospheric fluxes, advective signals, and dynamic control of isopycnal surfaces are addressed. In the region around OWSM in the Norwegian Atlantic Current (NwAC) the mixed layer depth varies between ∼20 m in summer and ∼300 m in winter. The depth of the wintertime mixing here is ultimately restrained by the interface between the Atlantic Water (AW) and the underlying water mass, and in general, the whole column of AW is found to be mixed during winter. In the Lofoten Basin the mean wintertime mixed layer reaches a depth of ∼600 m, while the AW fills the basin to a mean depth of ∼800 m. The temperature of the mixed layer at OWSM in general varies between 12 °C in summer and 6 °C in winter. Atmospheric heating controls the summer temperatures while the winter temperatures are governed by the advection of heat in the NwAC. Episodic lateral Ekman transports of coastal water facilitated by the shallow summer mixed layer is found important for the seasonal salinity cycle and freshening of the northward flowing AW. Atmospheric freshwater fluxes have no significant influence on the salinity of the AW in the area. Oxygen shows a clear annual cycle with highest values in May-June and lowest in August-September. Interannual variability of mixed layer oxygen does not appear to be linked to variations in any of the physical properties of the mixed layer.     

Numerical Study of Formation of Dichothermal Water in the Bering Sea

A one-dimensional numerical model with a level-2.5 turbulent closure scheme to provide vertical mixing coefficients has been used to investigate the process by which the dichothermal water is formed in the Bering Sea, the density of which is about 26.6 sigma-theta. The water column to be simulated is assumed to move along a predetermined path. That is, the present model is of the Lagrangian-type. Surface boundary conditions are given using the climatologies of heat, freshwater and momentum fluxes. In order to obtain a plausible moving speed of the water column along the path, pre-liminary experiments were done using the surface fluxes in the central part of the Bering Sea for the initial temperature and salinity profiles at the entrance of the Sea. As a result, it was found that the temperature minimum layer, i.e., the dichothermal water with temperature similar to the climatology at the exit of the Bering Sea, was formed after about two years of integration. Based on the result, the movement speed of the water column along the path was set as 4.5 cm/s in the standard run. It was found that this model could plausibly reproduce the subsurface temperature minimum layer. That is, the dichothermal water was formed in the winter mixed layer process in the Bering Sea. The existence of the subsurface halocline (pycnocline) prohibited the deeper penetration of the winter mixed layer, and therefore water with a temperature colder than that under the mixed layer was formed in the mixed layer due to wintertime surface cooling. In the warming season this water remains as the subsurface temperature minimum layer between the upper seasonal thermocline and the lower halocline. This revised version was published online in August 2006 with corrections to the Cover Date.     

人类活动对海洋生态系统影响的空间量化评价——以莱州湾海域为例

本文针对海域管理中难以量化人类活动对海洋生态系统影响的问题,提出人海关系空间量化模型,通过完善概念模型、构建指标体系、确定权重及标准,最终利用作用强度和位置关系量化人类活动对海洋生态系统的影响,数值在0—1之间,等分为四个影响程度,由弱到强依次为微弱、中等、强烈和极强,并将该模型和量化方法应用于莱州湾海域。研究结果表明:整个莱州湾受人类活动的综合影响均值为0.425,处于中等影响程度;其中污水排放、围填海工程及港口航运是对莱州湾生态系统影响比较强烈的人类活动;研究海域中40%受到人类活动的强烈影响,44%为中等影响,16%为微弱影响。空间量化分析显示,人类活动对莱州湾近岸海域的综合影响比邻近外海强烈,其中影响较强烈的区域出现在西南近岸海区,而影响较微弱的海区则为莱州湾北部外海。该方法空间量化结果与莱州湾实际情况相符,说明人海关系空间量化模型适合定量化评估人类活动对该海域生态系统的影响,可为"山东半岛蓝色经济区"海域管理提供技术支持。     

白洋淀水循环特点及其对生态环境的影响

在理想假设下,利用MITgcm模式研究了风对白洋淀内水体循环流动的影响。研究指出:(1)风应力可看作是水体循环的主要驱动力;(2)在风应力的作用下,水体表层的流动主方向与风的方向一致,下层水体的流动方向与表层方向相逆或近似相逆;(3)表层以下水体流动复杂,次表层水平流动有明显的双漩涡结构;(4)淀底地形对水体垂向流动影响很大,垂向速度变化复杂,垂向上有双涡流动现象,靠近岸边多有上升流和下降流;(5)淀内水体流动沿着水平和垂向两个方向流动,在冬季和夏季流向相反。在分析以上流动特点的基础上,讨论了流动对各个不同子区域的生态环境可能造成的影响:I区域是一个相对独立的水体区域,该区域内的水体污染物自成系统,与外界交换较少。而对A、B、C、D四个区域内的污染物分布等要统一考虑,四个区域内的水体交换,可看作是一个统一的整体。E、F区域内的水体流动受到上述A、B、C、D四区内双涡流动的影响,但在这两个区域靠近岸边有强烈的上升流和下降流,有可能使得污染物的分布更加复杂。G、H水深很浅,水流速度缓慢,受到污染后污染物不易扩散。     

The distributions of iodate and iodide in Rogoznica Lake (East Adriatic Coast)

This study was performed in order to obtain information on the influence of an acute anoxic event (September, 1997) on distribution and speciation of inorganic iodine in the water column of a small, intensely eutrophicated salt lake. The variations in iodate and iodide depth distributions during the investigated period (1998–2000) were in accord with seasonal changes in redox conditions. During the stratification period (spring and summer), the concentration ratio between iodate and iodide in the upper layers was high, whereas during late summer and autumn, as a result of water column de-stratification and mixing of highly reducing deep water with the oxic layer, lower ratios and more uniform depth distributions were observed.The massive mortality of lake organisms induced by anoxic conditions and sulphide presence throughout the water column was registered by the end of September 1997, when overturn of the lake occurred. The concentrations of iodate in the oxic upper layers were elevated for more than a year after the mass-mortality event (up to 0.55 μmol L⁻¹), whereas iodide concentrations remained high for more than 2 years in deep anoxic water (up to 2.27 μmol L⁻¹). These data suggest that biogeochemical renewal processes affecting the concentrations of inorganic iodine in the lake water are slow compared to those that govern the speciation of iodine. The role of sediment–water interactions and iodine-rich organic species in the production of iodide are discussed.     

One-dimensional nonstationary model of vertical exchange in the Black Sea with regard for the mechanism of winter convection in the surface layer

We construct a one-dimensional nonstationary isopycnic model of vertical exchange in the Black Sea with regard for the processes of draining and transformation of waters of the Sea of Marmara (or “plume”), vertical diffusion, and the action of winter convection in the upper layer. It is assumed that mixing in the basin is local in space and time and that the winter wind action remains constant from year to year in the analyzed version of the model. The temperature of the upper mixed layer introduced to simulate the winter conditions is regarded as the principal external variable factor. Within the framework of the accepted restrictions, the model enables us to study the annual and interannual variability of the thermohaline characteristics and hydrochemical parameters in the water column of the sea. As an example, we perform the numerical analysis of the periodic action of external thermal conditions on the characteristics of the system with a period of six years. __________ Translated from Morskoi Gidrofizicheskii Zhurnal, No. 5, pp. 3–21, September–October, 2006.     

Evidence for water exchange between the South China Sea and the Pacific Ocean through the Luzon Strait

An analysis of historical oxygen data provides evidence on the water exchange between theSouth China Sea (SCS) and the Pacific Ocean (PO). In the vicinity of the Luzon Strait (LS) , the dissolved oxygen concentration of sea water is found to be lower on the Pacific side than on the SCS side at depths between 700 and 1500 m (intermediate layer) , while the situation is reversed above 700 m (upper layer) and below 1 500 m (deep layer). The evidence suggests that water exits the SCS in the intermediate layer but enters it from the Pacific in both the upper and the deep layers, supporting the earlier speculation that the Luzon Strait transport has a sandwiched structure in the vertical. Within the SCS basin, the oxygen distribution indicates widespread vertical movement, including the upwelling in the intermediate layer and the downwelling in the deep layer.     

春末黄东海域溶解氧分布与水团关系

以１９８７年５—６月中日台作黄东海域综合调查的溶解氧资料为主，探讨调查海区溶解氧分布特征与水团的对应关系。指出：近岸水团溶解氧合量高，远海低；上层水团高，下层低。在黄海冷水和东海北部底层冷水的上界出现明显的溶解氧垂直分布最大值及封闭形高氧区。水团边界区，氧跃层明显。溶解氧含量变化与水团温盐特性有关。通过分析发现，溶解氧对鉴别次表层以深各水团，特别对鉴别东海次表层水及黑潮次表层以深各水团，可作为一种有效的指标。     

Winkler's method overestimates dissolved oxygen in seawater: Iodate interference and its oceanographic implications

Dissolved oxygen in seawater has been determined by using the Winkler's reaction scheme for decades. An interference in this reaction scheme that has been heretofore overlooked is the presence of naturally occurring iodate in seawater. Each mole of iodate can result in an apparent presence of 1.5 mol of dissolved oxygen. At the concentrations of iodate in the surface and deep open ocean, it can lead to an overestimation of 0.52 ± 0.15 and 0.63 ± 0.05 μmol kg^− 1 of oxygen in these waters respectively. In coastal and inshore waters, the effect is less predictable as the concentration of iodate is more variable. The solubility of oxygen in seawater was likely overestimated in data sources that were based on the Winkler's reaction scheme for the determination of oxygen. The solubility equation of García and Gordon [Garcia H.E., Gordon, L.I., 1992. Oxygen solubility in seawater: Better fitting equations. Limnol. Oceanogr. 37, 1307–1312] derived from the results of Benson and Krause [Benson, F.B., Krause, D. Jr., 1984. The concentration and isotopic fractionation of oxygen dissolved in freshwater and seawater in equilibrium with the atmosphere. Limnol. Oceanogr. 29, 620–632] is free from this source of error and is recommended for general use. By neglecting the presence of iodate, the average global super-saturation of oxygen in the surface oceans and the corresponding efflux of oxygen to the atmosphere both have been overestimated by about 8%. Regionally, in areas where the degree of super-saturation or under-saturation of oxygen in the surface water is small, such as in the tropical oceans, the net air–sea exchange flux can be grossly under- or overestimated. Even the estimated direction of the exchange can be reversed. Furthermore, the presence of iodate can lead to an overestimation of the saturation anomaly of oxygen in the upper ocean attributed to biological production by 0.23 ± 0.07%. AOU may have been underestimated by 0.52 ± 0.15 and 0.63 ± 0.05 μmol kg^− 1 in the surface mixed layer and deep water, while preformed phosphate and preformed nitrate may have been overestimated by 0.004 ± 0.001 and 0.06 ± 0.02 μmol kg^− 1 in the surface mixed layer, and 0.005 ± 0.0004 and 0.073 ± 0.006 μmol kg^− 1 in the deep water. These are small but not negligible corrections, especially in areas where the values of these parameters are small. At the increasing level of sophistication in the interpretation of oxygen data, this source of error should now be taken into account. Nevertheless, in order to avoid confusion, an internationally accepted standard needs to be adopted before these corrections can be applied.     

Study of Water Motion at the Dissolved Oxygen Minimum Layer and Local Oxygen Consumption Rate from the Lagrangian Viewpoint

By using the Euler-Lagrangian method, we examine water movements within the layer of minimum oxygen concentration and estimate local oxygen consumption rates for 15 regions of the global ocean. To do this, a number of labeled particles (which represent water parcels) are deployed at the center of a grid with 15 depth levels and tracked backward in time for 50 years in a three-dimensional velocity field. We assume that a particle picks up oxygen when it encounters the point of maximum oxygen concentration along the 50 years segment of its path. We introduce a contribution rate from waters distributed throughout the global ocean to the oxygen concentration of a local layer under consideration. Water parcels which are assumed to pick up oxygen within the oxygen minimum layer of an oceanic region under consideration make a very small contribution to the overall oxygen concentration of this layer. In addition, these parcels move out of the layer and water parcels from the upper layers take their place. The averaged Lagrangian local oxygen consumption rate is 0.033 ml/l/yr for the depth of the oxygen minimum layer, 0.20 ml/l/yr at 100 m depth (euphotic layer), 0.043 ml/l/yr for layers from 150 m to 800 m depth and 0.012 ml/l/yr for deep layers from 800 m to 3000 m. The present Lagrangian numerical experiment produces a maximum difference between observed and calculated concentrations of oxygen and, therefore, a maximum oxygen consumption rate. Although the present method has an ambiguity as to how oxygen is picked up, we nevertheless were able to identify regions in which the water parcels pick up oxygen of maximum concentration. We found that the South Equatorial Current (SEC) transports oxygen of higher concentration to the middle latitude regions of both the North Atlantic and the North Pacific across the equator.     

Heat and mass transfer effects during displacement of deepwater methane hydrate to the surface of Lake Baikal

The present paper focuses on heat and mass exchange processes in methane hydrate fragments during in situ displacement from the gas hydrate stability zone (GHSZ) to the water surface of Lake Baikal. After being extracted from the methane hydrate deposit at the lakebed, hydrate fragments were placed into a container with transparent walls and a bottom grid. There were no changes in the hydrate fragments during ascent within the GHSZ. The water temperature in the container remained the same as that of the ambient water (~3.5 °С). However, as soon as the container crossed the upper border of the GHSZ, first signs of hydrate decomposition and transformation into free methane gas were observed. The gas filled the container and displaced water from it. At 300 m depth, the upper and lower thermometers in the container simultaneously recorded noticeable decreases of temperature. The temperature in the upper part of the container decreased to –0.25 °С at about 200 m depth, after which the temperature remained constant until the water surface was reached. The temperature at the bottom of the container reached –0.25 °С at about 100 m depth, after which it did not vary during further ascent. These observed effects could be explained by the formation of a gas phase in the container and an ice layer on the hydrate surface caused by heat consumption during hydrate decomposition (self-preservation effect). However, steady-state simulations suggest that the forming ice layer is too thin to sustain the hydrate internal pressure required to protect the hydrate from decomposition. Thus, the mechanism of self-preservation remains unclear.     

2009-2010年冬季南海东北部中尺度过程观测

根据南海北部陆架陆坡海域2009-2010年冬季航次的CTD调查资料,发现西北太平洋水在上层通过吕宋海峡入侵南海,其对南海东北部上层水体温盐性质的影响自东向西呈减弱趋势,影响范围可达114°E附近。入侵过程中受东北部海域反 气旋式涡旋(观测期间,其中心位于20.75°N,118°E附近) 的影响,海水的垂向和水平结构发生了很大变化,特别是涡旋中心区域,上层暖水深厚,混合层和盐度极大值层显著深于周边海域。该暖涡在地转流场、航载ADCP观测海流及卫星高度计资料中均得到了证实。暖涡的存在还显著影响了海水化学要素的空间分布,暖涡引起的海水辐聚将上层溶解氧含量较高的水体向下输运,使次表层的暖涡中心呈现高溶解氧的分布特征。     

On the parameterisation of oceanic sensible heat loss to the atmosphere and to ice in an ice-covered mixed layer in winter

In high-latitude oceans with seasonal ice cover, the ice and the low-salinity mixed layer form an interacting barrier for the heat flux from the ocean to the atmosphere. The presence of a less dense surface layer allows ice to form, and the ice cover reduces the heat loss to the atmosphere. The ice formation weakens the stability at the base of the mixed layer, leading to stronger entrainment and larger heat flux from below. This heat transport retards, and perhaps stops, the growth of the ice cover. As much heat is then entrained from below as is lost to the atmosphere. This heat loss further reduces the stability, and unless a net ice melt occurs, the mixed layer convects. Two possibilities exist: (1) A net ice melt, sufficient to retain the stability, will always occur and convection will not take place until all ice is removed. The deep convection will then be thermal, deepening the mixed layer. (2) The ice remains until the stability at the base of the mixed layer disappears. The mixed layer then convects, through haline convection, into the deep ocean. Warm water rises towards the surface and the ice starts to melt, and a new mixed layer is reformed. The present work discusses the interactions between ice cover and entrainment during winter, when heat loss to the atmosphere is present. One crucial hypothesis is introduced: “When ice is present and the ocean loses sensible heat to the atmosphere and to ice melt, the buoyancy input at the sea surface due to ice melt is at a minimum”. Using a one-dimensional energy-balance model, applied to the artificial situation, where ice melts directly on warmer water, it is found that this corresponds to a constant fraction of the heat loss going to ice melt. It is postulated that this partitioning holds for the ice cover and the mixed layer in the high-latitude ocean. When a constant fraction of heat goes to ice melt, at least one deep convection event occurs, before the ice cover can be removed by heat entrained from below. After one or several convection events the ice normally disappears and a deep-reaching thermal convection is established. Conditions appropriate for the Weddell Sea and the Greenland Sea are examined and compared with field observations. With realistic initial conditions no convection occurs in the warm regime of the Weddell Sea. A balance between entrained heat and atmospheric heat loss is established and the ice cover remains throughout the winter. At Maud Rise convection may occur, but late in winter and normally no polynya can form before the summer ice melt. In the central Greenland Sea the mixed layer generally convects early in winter and the ice is removed by melting from below as early as February or March. This is in agreement with existing observations.     

海洋岛附近海域春季海洋水文测量结果分析

利用2006年4月在海洋岛附近海域的CTD测量资料,系统分析了该海域温度、盐度、密度和声速的平面分布和垂直分布特征,并探讨了其形成机理。分析指出:4月份是海洋岛附近海域季节性跃层的生成期,海区会产生正跃层、逆跃层、冷中间层、暖中间层等复杂的垂直结构;中间层和底层水文要素受海流的影响较大,而表层水文要素主要受海面风场和气温的影响。