A portable instrument for the measurement of salinity of rainwater using FET's

A portable salinity meter with field effect transistors for the continuous recording of salinity of rainwater is described. The variations in salinity are converted into current variations by using a D.C. differential amplifier and is recorded on an Esterline Angus Recorder. The Meter enables us to measure rainfall intensity as well as salinity simultaneously. The chief advantages of the present instrument are that it is portable and has a range of measurement from 1×10^–4 to 1×10^–1 ppm on a linear scale.     

The characteristics of rain electricity in Nigeria. I — Magnitudes and variations

The characteristics of rain and point charges based on routine measurements extending over four rainy seasons are presented. An average rain current density of (1.0±0.1)×10^–10 A m^–2 and charge per unit volume of rain water of (0.43±0.02)×10^–4 C m^–3 for the locality are obtained, which are compared with data obtained elsewhere by other workers. The point-discharge current measurements lead to a revised estimate of (0.86±0.08)×10^–9 A m^–2 for the average point discharge current below storm clouds.     

A crystal pyrradiometer

Summary A pyrradiometer, which is a single sided instrument for measuring both long and short wavelength radiation, has been developed. The instrument is protected from the wind by polythene hemispheres, and usesY-cut quartz crystals as temperature sensors. The output is in terms of frequency, the sensitivity being 13.1 Hertz (mW)^–1 cm^–2.     

Drifter observations of the Hebrides slope current and nearby circulation patterns

The mean flow at and around the Hebrides and Shetland Shelf slope is measured with ARGOS tracked drifters. Forty-two drifters drogued at 50 m were deployed in three circles over the Hebrides slope at 56.15°N in two releases, one on 5th December, 1995 and the second on 5–9th May, 1996. The circles span a distance of some 20 km from water depths of 200 m to 1200 m. Drifters are initially advected poleward along-slope by the Hebrides slope current at between 0.05 and 0.70 m s^–1 in a laterally constrained (25–50 km wide) jet-like flow. Drifters released in winter remained in the slope current for over 2000 km whilst summer drifters were lost from the slope current beyond the Wyville-Thomson Ridge, a major topographic feature at 60°N. Dispersion from the slope region into deeper waters occurs at bathymetric irregularities, particularly at the Anton Dohrn Seamount close to which the slope current is found to bifurcate, both in summer and winter, and at the Wyville-Thomson Ridge where drifters move into the Faeroe Shetland Channel. Dispersion onto the continental shelf occurs sporadically along the Hebrides slope. The initial dispersion around the Hebrides slope is remarkably sensitive to initial position, most of the drifters released in shallower water moving onto the shelf, whilst those in 1000 m or more are mostly carried away from the slope into deeper water near the Anton Dohrn Seamount. The dispersion coefficients estimated in directions parallel and normal to the local direction of the 500 m contour, approximately the position of the slope current core, are approximately 8.8 × 10³ m² s^–1 and 0.36 × 10³ m² s^–1, respectively, during winter, and 11.4 × 10³ m² s^–1 and 0.36 x 10³ m² s^–1, respectively, during summer. At the slope there is a minimum in across-slope mean velocity, Reynolds stress, and across-slope eddy correlations. The mean across-slope velocity associated with mass flux is about 4 × 10^–3 m s^–1 shelfward across the shelf break during winter and 2 × 10^–3 m s^–1 during summer. The drifters also sampled local patterns of circulation, and indicate that the source of water for the seasonal Fair Isle and East Shetland currents are the same, and drawn from Atlantic overflows at the Hebrides shelf.     

The effect of water on stress relaxation of faulted and unfaulted sandstone

A series of stress relaxation experiments have been carried out on faulted and intact Tennessee sandstone to explore the influence of pore water on strength at different strain rates. Temperatures employed were 20, 300 and 400°C, effective confining pressure was 1.5 kb and strain rates as low as 10^–10 sec^–1 were achieved. Most samples were prefaulted at 2.5 kb confining pressure and room temperature. This is thought to have secured a reproducible initial microstructure.The strength of the dry rock was almost totally insensitive to strain rate in the range 10^–4 to 10^–10 sec^–1. In contrast, the strength of the wet rock decreased rapidly with strain rate at rates less than 10^–6 sec^–1. Brittle fracture of the quartz grains which constitute this rock is the most characteristic mode of failure under the test conditions used.The experimental data are discussed in terms of the possible deformation rate controlling processes, and it is suggested that in the wet experiments at intermediate to high strain rates (10^–7 to 10^–4 sec^–1) the observed deformation rate is controlled by the kinetics of water assisted stress corrosion, whilst deformation at low strain rates (ca. 10^–9 sec^–1) is controlled by a pressure solution process.The results have implications for the rheology of fault rocks at depths of perhaps 10 to 15 km in sialic crust.     

Zero-frequency tidal distrotion due to the orbital elements of tide-forming bodies

Summary It has been proved that orbital elements of perturbing bodies should be taken into account when 10^–10 accuracy is required for zero-frequency tidal distortion in the second zonal Stokes parameter of the geopotential. A solution at the 10^–15 level of magnitude has been presented. The zero-frequency tidal distortion in the fourth zonal Stokes parameter has been derived as 1·3×10^–10 if the secular Love number is unity. It should be reflected in the geopotential models respecting the 10^–10 level of magnitude.     

Transport ofBe andBe in the ocean

Beryllium isotopes (¹⁰Be and⁹Be) have been measured in suspended particles of < 1 mm size collected by mid-water sediment traps deployed in the eastern Pacific at MANOP sites H (6°32′N, 92°50′W, water depth 3600 m) and M (8°50′N, 104°00′W, 3100 m). For comparison, surface sediments from box cores taken from the two sites were also studied. The concentrations of¹⁰Be and⁹Be in sediment-trap particles are about an order of magnitude smaller than those in the bottom sediments which contain about 8 × 10⁹ and 6 × 10¹⁶ atoms g⁻¹ of¹⁰Be and⁹Be, respectively. The sediment trap samples collected from 50 m off the bottom showed significant (26–63%) contributions from resuspended bottom sediments. The¹⁰Be/⁹Be ratio in trap samples varies from 3 to 20 × 10⁻⁸. The variation may partly result from varied proportion of authigenic/detrital material. The fluxes of both isotopes exhibit a very strong seasonality. The fluxes of¹⁰Be into the traps at about 1500 m are estimated as 9 × 10⁵ and 4 × 10⁵ atoms cm⁻² a⁻¹ at sites H and M respectively. These values are to be compared with the fluxes into the sediments of 4–5 × 10⁵ atoms cm⁻² a⁻¹ at both locations. Good correlations exist between¹⁰Be,⁹Be and²⁷Al indicating that the primary carrier phase(s) for the beryllium isotopes in the water column may be aluminosilicates.     

On the reynolds stress and lateral eddy viscosity due to transient oceanic Rossby waves

Summary From numerical solutions of a wind-driven homogeneous ocean model, anegative lateral eddy viscosity of the order 10⁴ cm² sec^–1 is inferred from the large-scale time-dependent currents in the interior of an enclosed shallow basin. The transient Rossby waves in this region produce a systematic convergence of eddy momentum at the latitude of the maximum average eastward current, and thus effect a transfer of zonal momentum from the large-scale eddies to the mean flow. In this sense they are analogous to the Rossby waves in the atmospheric general circulation, and it is speculated that such waves may help to maintain the mean zonal ocean currents. Although this negative viscosity induced by the large-scale transients is relatively small compared with the prescribed lateral viscosity of 10⁸ cm² sec^–1 and should be given a quite different physical interpretation, it is evidently an important viscous effect for the mean flow in the interior of the basin. The prescribed viscosity, on the other hand, is effective in controlling the model's simulated sub-grid scale dissipation, which occurs almost entirely in the nearby steady boundary currents.     

Precision A.C. bridge set for measuring magnetic susceptibility of rocks and its anisotropy

Summary A bridge set for measuring the magnetic susceptibility of rocks and its anisotropy is described. The classical transformer bridge has been supplemented with an auxiliary compensating arm for balancing the bridge without any mechanical infringement of the measuring coils. By employing this principle and the appropriate methods a sensitivityof 4 × 10 ^–8 SI units (3 × 10 ^–9 e.m.u./cm³) has been achieved for a sample of 8 cm³ in volume. In addition to its high sensitivity the device has a considerable accuracy, which makes it suitable for susceptibility anisotropy measurements even of samples with a very low susceptibility and only slight anisotropy. Well-reproducible results have been achieved for samples with a mean susceptibility of the order of10 ^–5 SI units with an anisotropy degree of only about 1.05.Institute of Applied Geophysics.     

Distribution ofBe andBe in the Pacific Ocean

The vertical distributions of¹⁰Be and⁹Be at three locations in the Pacific (25°N, 170°E; 17°N, 118°W; 3°S, 117°W) are presented. The results show that both isotopes exhibit nutrient-like profiles. From the surface to the bottom, the increase for¹⁰Be is two- to threefold and that for⁹Be is about fivefold. While the inter-station variations in surface water concentrations may reach a factor of two, deep-water values tend to be much more uniform averaging about 2000 atoms/g for¹⁰Be and 30 pM for⁹Be. A similar situation applies to the¹⁰Be/⁹Be ratio; it varies approximately from 1 to 3 × 10⁻⁷ (atom/atom) at shallow depths but tends toward a value close to 1.1 × 10⁻⁷ in the deep ocean. The variation of¹⁰Be/⁹Be can be viewed as resulting from the fact that¹⁰Be in a given parcel of water consists of two components: recycled and primary. The recycled component is that part of¹⁰Be which has reached tracer equilibrium with⁹Be, as opposed to the primary component which, upon entering the sea from the atmosphere, has yet to equilibrate with⁹Be through particle cycling and mixing processes. It is estimated that 70% to nearly 100% of¹⁰Be at the three stations are being recycled, and the recycled beryllium bears an atomic ratio of¹⁰Be/⁹Be close to 1 × 10⁻⁷. The oceanic residence time of Be is of the order of 1000–4000 years, comparable to or slightly longer than the ocean mixing time.     

A portable magnetic susceptibility meter for measurements on rocks in situ and in laboratory

Summary An instrument for the measurement of the magnetic susceptibility of rocks in situ or in the laboratory has been described. The instrument is a completely portable and transistorised unit having a range from 5 to 50000×10^–6 CGS units of volume susceptibility. The accuracy of measurements is ±5%. It is rapid and simple in operation.This paper is published by the kind permission of the Director General, Geological Survey of India.     

Effect of displacement rate on the real area of contact and temperatures generated during frictional sliding of Tennessee sandstone

Summary The real area of contact has been determined, and measurements of the maximum and average surface temperatures generated during frictional sliding along precut surfaces in Tennessee sand-stone have been made, through the use of thermodyes. Triaxial tests have been made at 50 MPa confining pressure and constant displacement rates of 10^–2 to 10^–6 cm/sec, and displacements up to 0.4 om. At 0.2 cm of stable sliding, the maximum temperature decreases with decreasing nominal displacement rate from between 1150° to 1175°C at 10^–2 cm/sec to between 75° to 115°C at 10^–3 cm/sec. The average temperature of the surface is between 75 and 115°C at 10^–2 cm/sec, but shows no rise from room temperature at 10^–3 cm/sec. At 0.4 cm displacement, and in the stick-slip mode, as the nominal displacement rate decreases from 10^–3 to 10^–6 cm/sec, the maximum temperature decreases from between 1120° to 1150°C to between 1040° to 1065°C. The average surface temperature is 115° to 135°C at displacement rates from 2.6×10^–3 to 10^–4 cm/sec.With a decrease in the displacement rate from 10^–2 to 10^–6 cm/sec, the real area of contact increases from about 5 to 14 percent of the apparent area; the avergge area of asperity contact increases from 2.5 to 7.5×10^–4 cm². Although fracture is the dominate mechanism during stick-up thermal softening and creep may also contribute to the unstable sliding process.     

The shelf-edge current north-west of Ireland

Measurements of the slope current at two locations north-west of Ireland have been made between April and December 1994, 40 m above the seabed in a water depth of 660 m. A persistent poleward along-slope current was observed at both locations, with measured means of 10 and 21cms^–1 respectively. A CTD transect across the slope near one mooring indicated the presence of a light, warm, saline core of water at the shelf edge. Peak currents were 0(50) cms^–1, with strongest mean flow at the location with steeper slope. Variability at sub-tidal periods, principally 2–5 and 11–12 days, was apparent. The shorter-period variability was well correlated with coastal sea-level variations measured at a land point near to one of the moorings. The variability in the slope current at this period appeared to be a result of the warm current core movement up/down slope, probably as a result of interaction with higher-mode shelf waves. Some suggestion of a bottom-trapped diurnal wave was also found at one location.     

Mercury's magnetic field: a thermoelectric dynamo?

Permanent magnetism and conventional dynamo theory are possible but problematic explanations for the magnitude of the Mercurian magnetic field. A new model is proposed in which thermoelectric currents driven by temperature differences at a bumpy core-mantle boundary are responsible for the (unobserved) toroidal field, and the helicity of convective motions in a thin outer core (thickness 10² km) induces the observed poloidal field from the toroidal field. The observed field of 3 × 10⁻⁷ T can be reproduced provided the electrical conductivity of Mercury's semiconducting mantle approaches 10³ Ω⁻¹ m⁻¹. This model may be testable by future missions to Mercury because it predicts a more complicated field geometry than conventional dynamo theories. However, it is argued that polar wander may cause the core-mantle topography to migrate so that some aspects of the rotational symmetry may be reflected in the observed field.     

The fate of Chernobyl radiocesium in the River Öre catchment,northern Sweden

A¹³⁷Cs-balance for the catchment of the River Öre in central northern Sweden which received about 30 kBq m^–2 of radiocesium from the Chernobyl accident was calculated for the period 1986–1991. Altogether, slightly less than 10% of the total deposition in the catchment was estimated to be exported from the terrestrial parts during this period of time. More than 90% of this loss is transported with the River Öre to the outer sea of the Gulf of Bothnia. The retention in Lake Örträsket which is the only lake along the river course and the Öre Estuary outside the river mouth was thus slightly less than 10%. Nearly all of the radiocesium deposited in the lake is permanently retained in the sediments and successively covered with less radioactive sediment. A considerable export of radiocesium from the estuary to the outer sea takes place due to resuspension and subsequent transport by wind and wave generated currents.     

Differential mill for measuring electric fields and conductivities in thunderclouds

Summary A differential rotating mill for the measurement of electric fields has been designed and built. The instrument was specifically designed to be insensitive to the effects of space charge and frictional charging so that it could operate in the environment of an active thundercloud. The electric field range of the device is 100 to 250,000 volts per meter, (however, corona should occur before the maximum measurable field is reached) and the conductivity range is approximately (depending on the electric field) 10^–11 to 10^–13 mhos/meter.Forty of these devices have been parachuted into active, and potentially active, thunderclouds around Tucson, Arizona. Although the presently available measurements are too few for an unequivocal conclusion, the data strongly support the presence of very high conductivities in thunderstorms.This research was supported by the Atmospheric Sciences Section, National Science Foundation under Grant GA-701.     

Effusive history of the Grande Découverte Volcanic Complex, southern Basse-Terre (Guadeloupe, French West Indies) from new K–Ar Cassignol–Gillot ages

The Grande Découverte Volcanic Complex (GDVC), active since at least 0.2 Ma, is the most recent volcanic complex of the Basse-Terre Island (Guadeloupe, Lesser Antilles Arc). A detailed geochronological study using the K–Ar Cassignol–Gillot technique has been undertaken in order to reconstruct the history of effusive activity of this long-lived volcanic system. Twenty new ages permit to suggest that the GDVC experienced at least six main effusive stages, from 200 ka to present time. To the north of the GDVC, the GDS (Grande Découverte–Soufrière volcano) has been active since at least 200 ka, and to the south, the TRMF (Trois-Rivières–Madeleine Field), started to be emplaced 100 ka. Morphological investigations suggest that the whole TRMF volcanism was emitted from vents distinct from the GDS, most probably a large E–W fissure network linked to the Marie-Galante rift. The mean age of 62 ± 5 ka, obtained for the E–W Madeleine–Le Palmiste alignment suggests that a fissure-opening event occurred at that time. However, whole-rock major and trace element signatures are similar for both systems, suggesting that a common complex magma-plumbing system has fed the overall GDVC. We report very young ages for lava flows from the TRMF, which implies that < 10 ka volcanic activity is now identified for both massifs. Although hazards associated with such effusive volcanism are much lower than those associated with potential flank-collapse of the Soufrière lava dome or a magmatic dome eruption with explosive phases within the GDS, the emplacement of relatively large Holocene age lava flows (3–1 × 10⁸ m³) suggests that a revised integrated volcanic hazard assessment for Southern Basse-Terre should now consider the potential for renewed future activity from two Holocene volcanic centers including the TRMF.     

A fracture mechanics study of subcritical tensile cracking of quartz in wet environments

Load relaxation and cross-head displacement rate-change experiments have been used to establish log₁₀ stress intensity factor (K) versus log₁₀ crack velocity (v) diagrams for double torsion specimens, of synthetic quartz cracked on thea plane in liquid water and moist air.For crack propagation normal toz and normal tor at 20°C,K _Ic (the critical stress intensity factor) was found to be 0.852±0.045 MN·m^–3/2 and 1.002±0.048 MN·m^–3/2, respectively.Subcritical crack growth at velocities from 10^–3 m·s^–1 to 10^–9 m·s^–1 at temperatures from 20°C to 80°C is believed to be facilitated by chemical reaction between the siloxane bonds of the quartz and the water or water vapour of the environment (stress corrosion). The slopes, of isotherms in theK-v diagrams are dependent upon crystallographic orientation. The isotherms have a slope of 12±0.6 for cracking normal tor and 19.9±1.7 for cracking normal toz. The activation enthalpy for crack propagation in the former orientation in liquid water at temperatures from 20°C to 80°C is 52.5±3.8 kJ·mole^–1.A discussion is presented of the characteristics of theK-v diagrams for quartz.     

Temporal and spatial variation on codaQ −1 associated with the North Palm Springs earthquake of July 8, 1986

A temporal and spatial change of codaQ ^–1 associated with the occurrence of the North Palm Springs earthquake of July 8, 1986 was studied by using 242 small local earthquakes in the vicinity of the mainshock. We found that the codaQ ^–1 of earthquakes which occurred before the mainshock was significantly higher than that of the aftershocks in the mainshock area while the codaQ ^–1 for the surrounding area remained almost constant throughout 1986. CodaQ ^–1 was determined separately for the lapse time windows of 10 to 20 sec. and 15 to 40 sec. for the period from 1981 to 1987. The result for the time window 10 to 20 sec. showed a peak in codaQ ^–1 before the time of mainshock at all frequencies. The peak appeared earlier at lower frequencies. There was no significant change in codaQ ^–1 for the time window 15 to 40 sec., probably because the change was restricted to a small area.     

Effect of high-pressures on the electrical resistivity of natural zeolites from Deccan Trap, Maharashtra, India

We report here the electrical resistivity measurements on two natural zeolites–natrolite and scolecite (from the Killari borehole, Maharashtra, India) as a function of pressure up to 8 GPa at room temperature. High-pressure electrical resistivity studies on hydrous alumino-silicate minerals are very helpful in understanding the role of water in deep crustal conductivities obtained from geophysical models. The results obtained by magneto-telluric (MT) soundings and direct current resistivity surveys, along with the laboratory data on the electrical resistivity of minerals and rocks at high-pressure–temperature are used to determine the electrical conductivity distribution in continental lithosphere. The electrical resistivity of natural natrolite decreases continuously from 2.9 × 10⁹ Ω cm at ambient condition to 7.64 × 10² Ω cm at 8 GPa, at room temperature. There is no pressure-induced first order structural phase transitions in natrolite, when it is compressed in non-penetrating pressure transmitting medium up to 8 GPa. On the other hand scolecite exhibits a pressure-induced transition, with a discontinuous decrease of the electrical resistivity from 2.6 × 10⁶ to 4.79 × 10⁵ Ω cm at 4.2 to 4.3 GPa. The observed phase transition in scolecite is found to be irreversible. Vibrational spectroscopic and X-ray diffraction studies confirm the amorphous nature of the high-pressure phase. The results of the present high-pressure studies on scolecite are in good agreement with the high-pressure Raman spectroscopic data on scolecite. The thermo gravimetric studies on the pressure-quenched samples show that the samples underwent a pressure-induced partial dehydration. Such a pressure-induced partial dehydration, which has been observed in natural scolecite could explain the presence of high conductive layers in the earth's deep-crust.