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1.
Large crystals of boron-free kornerupine occurring in MgAl-rich inclusions within meta-anorthosites are partially replaced by symplectitic pseudomorphs consisting essentially of the assemblage sapphirine-cordieritegedrite. The highly magnesian, hydrous kornerupines (F= 0.10–0.14) have compositions close to the oxide ratio (Mg, Fe) O· Al2O3· SiO2. Sapphirines (F=0.09) show decreasing Al-contents with continued grain growth and equilibration. Gedrite (F=0.15) contains sodium in amounts near the limit of solid solution, although the kornerupine starting material is free of this element and it is very rare in the enclosing rock. Cordierite (F=0.05) is also free from sodium.For conditions of P H2O = P tot the appearance of boron-free kornerupine requires relatively high temperatures (> 700 °C) and a minimum pressure near 4 kb within this zone of the Limpopo Belt. The subsequent replacement reaction occurred nearly isochemically except for Na and probably H2O, which were introduced into the symplectite. Textural features suggest that the breakdown reaction of kornerupine is actually governed by the magnitude of sodium activity: Relatively low values would favor the appearance of boron-free kornerupine, whereas higher values lead to the more common assemblage sapphirine-cordierite-gedrite.  相似文献   

2.
The Southern Marginal Zone of the Limpopo Belt in South Africa is characterised by a granulite and retrograde hydrated granulite terrane. The Southern Marginal Zone is, therefore, perfectly suitable to study fluids during and after granulite facies metamorphism by means of fluid inclusions and equilibrium calculations. Isolated and clustered high-salinity aqueous and CO2(-CH4) fluid inclusions within quartz inclusions in garnet in metapelites demonstrate that these immiscible low H2O activity fluids were present under peak metamorphic conditions (800-850 °C, 7.5-8.5 kbar). The absence of widespread high-temperature metasomatic alteration indicates that the brine fluid was probably only locally present in small quantities. Thermocalc calculations demonstrate that the peak metamorphic mineral assemblage in mafic granulites was in equilibrium with a fluid with a low H2O activity (0.2-0.3). The absence of water in CO2-rich fluid inclusions is due to either observation difficulties or selective water leakage. The density of CO2 inclusions in trails suggests a retrograde P-T path dominated by decompression at T<600 °C. Re-evaluation of previously published data demonstrates that retrograde hydration of the granulites at 600 °C occurred in the presence of H2O and CO2-rich fluids under P-T conditions of 5-6 kbar and ~600 °C. The different compositions of the hydrating fluid suggest more than one fluid source.  相似文献   

3.
An assemblage consisting of corundum, sapphirine, spinel, cordierite, garnet, biotite and bronzite is described from the Messina area of the Limpopo Mobile Belt, and consideration given to its petrogenesis. Various geothermometers and geobarometers have been applied in an attempt to determine the temperatures and pressures of metamorphism.
A former coexistence of garnet and corundum is suggested to have developed during the earliest high pressure phase of the metamorphism, where temperatures exceeded 800°C and pressures as high as 10kbar may have been experienced. Subsequently, continuous retrograding reactions from medium pressure granulite facies at about 800°C and 8kbar towards amphibolite facies generated spinel, cordierite, sapphirine and possibly also bronzite. The most notable reaction was probably of the form: garnet + corundum = cordierite + sapphirine + spinel.  相似文献   

4.
Anatexis of metapelitic rocks at the Bandelierkop Quarry (BQ) locality in the Southern Marginal Zone of the Limpopo Belt occurred via muscovite and biotite breakdown reactions which, in order of increasing temperature, can be modelled as: (1) Muscovite + quartz + plagioclase = sillimanite + melt; (2) Biotite + sillimanite + quartz + plagioclase = garnet + melt; (3) Biotite + quartz + plagioclase = orthopyroxene ± cordierite ± garnet + melt. Reactions 1 and 2 produced stromatic leucosomes, which underwent solid‐state deformation before the formation of undeformed nebulitic leucosomes by reaction 3. The zircon U–Pb ages for both leucosomes are within error identical. Thus, the melt or magma formed by the first two reactions segregated and formed mechanically solid stromatic veins whilst temperature was increasing. As might be predicted from the deformational history and sequence of melting reactions, the compositions of the stromatic leucosomes depart markedly from those of melts from metapelitic sources. Despite having similar Si contents to melts, the leucosomes are strongly K‐depleted, have Ca:Na ratios similar to the residua from which their magmas segregated and are characterized by a strong positive Eu anomaly, whilst the associated residua has no pronounced Eu anomaly. In addition, within the leucosomes and their wall rocks, peritectic garnet and orthopyroxene are very well preserved. This collective evidence suggests that melt loss from the stromatic leucosome structures whilst the rocks were still undergoing heating is the dominant process that shaped the chemistry of these leucosomes and produced solid leucosomes. Two alternative scenarios are evaluated as generalized petrogenetic models for producing Si‐rich, yet markedly K‐depleted and Ca‐enriched leucosomes from metapelitic sources. The first process involves the mechanical concentration of entrained peritectic plagioclase and garnet in the leucosomes. In this scenario, the volume of quartz in the leucosome must reflect the remaining melt fraction with resultant positive correlation between Si and K in the leucosomes. No such correlation exists in the BQ leucosomes and in similar leucosomes from elsewhere. Consequently, we suggest disequilibrium congruent melting of plagioclase in the source and consequential crystallization of peritectic plagioclase in the melt transfer and accumulation structures rather than at the sites of biotite melting. This induces co‐precipitation of quartz in the structures by increasing SiO2 content of the melt. This process is characterized by an absence of plagioclase‐induced fractionation of Eu on melting, and the formation of Eu‐enriched, quartz + plagioclase + garnet leucosomes. From these findings, we argue that melt leaves the source rapidly and that the leucosomes form incrementally as melt or magma leaving the source dumps its disequilibrium Ca load, as well as quartz and entrained ferromagnesian peritectic minerals, in sites of magma accumulation and escape. This is consistent with evidence from S‐type granites suggesting rapid magma transfer from source to high level plutons. These findings also suggest that leucosomes of this type should be regarded as constituting part of the residuum from partial melting.  相似文献   

5.
SHRIMP dating of titanite from metasyenites in the Central Zone of the Limpopo Belt yields a mean 207Pb/206Pb age of 2010.3 ±4.5 Ma calculated from 23 analyses. This age, combined with petrographic and field observations, suggests the metamorphism in the syenites occurred during Palaeoproterozoic event.  相似文献   

6.
Contrary to previously suggested north-directed thrust emplacement of the central zone of the Limpopo mobile belt, we present evidence indicating west-directed emplacement. The central zone differs from the marginal zones in rock types, structural style and isotopic signature and is an allochthonous thrust sheet. It is bounded in the north by the dextral Tuli-Sabi shear zone and in the south by the sinistral Palala shear zone which are crustal-scale lateral ramps. Published gravity data suggest that the lateral ramps are linked at depth and they probably link at the surface, in a convex westward frontal ramp, in the vicinity of longitude 26°30′E in eastern Botswana. Two phases of movement, the first between 2.7 and 2.6 Ga and the second between 2.0 and 1.8 Ga. occurred on both the Tuli-Sabi and the Palala shear zones.  相似文献   

7.
The proposed retrograde orthoamphibole isograd in the Southern Marginal Zone of the Limpopo Belt separates hydrated, amphibolite grade metapelites from their granulite grade precursors and provides an intriguing geological dilemma. Widespread rehydration of metapelitic granulites under conditions of 660–600 °C and ≥0.6 GPa, and CO2-dominated fluid-inclusion populations appear to suggest thorough flushing of the high-grade crust with an externally derived carbonic fluid. However, past studies of the carbon and oxygen isotope geochemistry of the hydrated rocks have not demonstrated the involvement of any voluminous out of equilibrium’ fluid in the evolution of the rocks. This contribution proposes a model wherein the hydrating fluids are derived from crystallizing anatectic leucosomes, generated by in situ fluid-absent biotite melting along the prograde path. Model equilibrium fluid compositions suggest that reaction between this melt-derived H2O and biogenic graphite produced CO2-rich fluid compositions and potentially high fluid:rock ratios at the wet granite solidus. Declining temperature resulted in fluid compositions shifting to higher XH2O, with the precipitation of graphite essentially at the sites of initial fluid generation, thereby preserving original (pre-metamorphic) isotopic heterogeneities. The hydration pattern of the Southern Marginal Zone appears to be a function of melt migration. In the hydrated zone, leucosomes generally approximate minimum melt compositions and in this zone H2O was effectively recycled between the prograde and retrograde assemblages. In contrast, leucosomes in the granulite grade portion of the terrane have lost a K2O- and H2O-rich melt fraction, and although some hydration has occurred in this zone, orthopyroxene is generally preserved in metapelites. In a general context, in situ crystallization of graphitic partially melted source rocks has the potential to produce high fluid-rock ratios at temperatures close to the wet granite solidus. This single process holds the potential for widespread retrogression of formerly high-grade assemblages, at a variety of aH2O values, without external fluid input.  相似文献   

8.
Sapphirine/kornerupine-bearing rocks occur within the anorthosites of the Messina layered intrusion in the Limpopo mobile belt of Zimbabwe. The XMg range of the major minerals is as follows: cordierite (0.98-0.93); enstatite (0.97-0.86); chlorite (0.98-0.92); phlogopite (0.98-0.90); sapphirine (0.98-0.86); kornerupine (0.94-0.88); gedrite (0.96-0.85); spinel (0.92-0.78). There are four rock types, the constituent minerals of which have different values, which decrease in the above mineral order; other minerals are corundum, sillimanite and relict kyanite. We recognise twenty reactions without phlogopite and nine reactions involving phlogopite. The textural relations and the plots of the microprobe data of coexisting minerals in the MgO-Al2O3-SiO2-(H2O) system are consistent with the following sequence of main reactions: (1) enstatite+corundum cordierite+sapphirine; (4) sapphirine+sillimanite cordierite+corundum; (8) kornerupine+corundum cordierite+sapphirine; (13) kornerupine cordierite+sapphirine+enstatite; (15) enstatite+spinel chlorite+sapphirine; (18) cordierite+sapphirine chlorite+corundum; (20) sapphirine chlorite+corundum+spinel. The early reactions are shown by coarse-grained reaction intergrowths, kornerupine and gedrite breakdown is shown by finer-grained symplectites, and the latest reactions by very fine-grained products in micro-fractures. These selected reactions illustrate a remarkably steep trajectory from thePT peak close to 10 kbar and 800° C to the minimum observable at 3.5–4.5 kbar and 700° C as indicated by the pure MASH system. Very rapid uplift took place under nearly isothermal conditions. The protolith of this material was possibly sedimentary, derived from altered volcanic rocks. The bulk composition is close to the composition of kornerupine or to a mixture of alunite, chlorite and pyrophyllite. These texturally and mineralogically complex rocks contain a wealth of relevant data for documenting crustal uplift history.  相似文献   

9.
Differentiation of the continental crust is the result of complex interactions between a large number of processes, which govern partial melting of the deep crust, magma formation and segregation, and magma ascent to significantly higher crustal levels. The anatectic metasedimentary rocks exposed in the Southern Marginal Zone of the Limpopo Belt represent an unusually well‐exposed natural laboratory where the portion of these processes that operate in the deep crust can be directly investigated in the field. The formation of these migmatites occurred via absent incongruent melting reactions involving biotite, which produced cm‐ to m‐scale, K2O‐poor garnet‐bearing stromatic leucosomes, with high Ca/Na ratios relative to their source rocks. Field investigation combined with geochemical analyses, and phase equilibrium modelling designed to investigate some aspects of disequilibrium partial melting show that the outcrop features and compositions of the leucosomes suggest several steps in their evolution: (1) Melting of a portion of the source, with restricted plagioclase availability due to kinetic controls, to produce a magma (melt + entrained peritectic minerals in variable proportions relative to melt); (2) Segregation of the magma at near peak metamorphic conditions into melt accumulation sites (MAS), also known as future leucosome; (3a) Re‐equilibration of the magma with a portion of the bounding mafic residuum via chemical diffusion (H2O, K2O), which triggers the co‐precipitation of quartz and plagioclase in the MAS; (3b) Extraction of melt‐dominated magma to higher crustal levels, leaving peritectic minerals entrained from the site of the melting reaction, and the minerals precipitated in the MASs to form the leucosome in the source. The key mechanism controlling this behaviour is the kinetically induced restriction of the amount of plagioclase available to the melting reaction. This results in elevated melt H2O and K2O and chemical potential gradient for these components across the leucosome/mafic residuum contact. The combination of all of these processes accurately explains the composition of the K2O‐poor leucosomes. These findings have important implications for our understanding of melt segregation in the lower crust and minimum melt residency time which, according to the chemical modelling, is <5 years. We demonstrate that in some migmatitic granulites, the leucosomes constitute a type of felsic refractory residuum, rather than evidence of failed magma extraction. This provides a new insight into the ways that source heterogeneity may control anatexis.  相似文献   

10.
11.
A petrogenetic grid in the model system CaO–FeO–MgO–Al2O3–SiO2–H2O is presented, illustrating the phase relationships among the minerals grunerite, hornblende, garnet, clinopyroxene, chlorite, olivine, anorthite, zoisite and aluminosilicates, with quartz and H2O in excess. The grid was calculated with the computer software thermocalc , using an upgraded version of the internally consistent thermodynamic dataset HP98 and non‐ideal mixing activity models for all solid solutions. From this grid, quantitative phase diagrams (PT pseudosections) are derived and employed to infer a PT path for grunerite–garnet‐bearing amphibolites from the Endora Klippe, part of the Venetia Klippen Complex within the Central Zone of the Limpopo Belt. Agreement between calculated and observed mineral assemblages and garnet zonation indicates that this part of the Central Zone underwent a prograde temperature and pressure increase from c. 540 °C/4.5 kbar to 650 °C/6.5 kbar, followed by a post‐peak metamorphic pressure decrease. The inferred PT path supports a geotectonic model suggesting that the area surrounding the Venetia kimberlite pipes represents the amphibolite‐facies roof zone of migmatitic gneisses and granulites that occur widely within the Central Zone. In addition, the PT path conforms to an interpretation that the Proterozoic evolution of the Central Zone was controlled by horizontal tectonics, causing stacking and differential heating at c. 2.0 Ga.  相似文献   

12.
The Mozambique belt of eastern and southern Africa is polyorogenic and marks the sites for the assembly (collision and suturing) and dispersion (rifting and drifting) of the Proterozoic supercontinents. Subduction zones and collisional sutures in this belt are of variable ages. Reliable isotope and geological data from the Mozambique belt of Holmes (1951) suggest that there existed three major Proterozoic oceans within this belt: the Palaeoproterozoic, Mesoproterozoic and Neoproterozoic “Mozambique Oceans”. However, the accretion and collisional tectonic history of this orogenically coalescent belt are complex and thus still enigmatic.  相似文献   

13.
14.
15.
The integration of new and published geochronologic data with structural, magmatic/anatectic and pressure–temperature (P–T) process information allow the recognition of high-grade polymetamorphic granulites and associated high-grade shear zones in the Central Zone (CZ) of the Limpopo high-grade terrain in South Africa. Together, these two important features reflect a major high-grade D3/M3 event at ~ 2.02 Ga that overprinted the > 2.63 Ga high-grade Neoarchaean D2/M2 event, characterized by SW-plunging sheath folds. These major D2/M2 folds developed before ~ 2.63 Ga based on U–Pb zircon age data for precursors to leucocratic anatectic gneisses that cut the high-grade gneissic fabric. The D3/M3 shear event is accurately dated by U–Pb monazite (2017.1 ± 2.8 Ma) and PbSL garnet (2023 ± 11 Ma) age data obtained from syntectonic anatectic material, and from sheared metapelitic gneisses that were completely reworked during the high-grade shear event. The shear event was preceded by isobaric heating (P = ~ 6 kbar and T = ~ 670–780 °C), which resulted in the widespread formation of polymetamorphic granulites. Many efforts to date high-grade gneisses from the CZ using PbSL garnet dating resulted in a large spread of ages (~ 2.0–2.6 Ga) that reflect the polymetamorphic nature of these complexly deformed high-grade rocks.  相似文献   

16.
《Gondwana Research》2009,15(4):644-662
The integration of new and published geochronologic data with structural, magmatic/anatectic and pressure–temperature (P–T) process information allow the recognition of high-grade polymetamorphic granulites and associated high-grade shear zones in the Central Zone (CZ) of the Limpopo high-grade terrain in South Africa. Together, these two important features reflect a major high-grade D3/M3 event at ~ 2.02 Ga that overprinted the > 2.63 Ga high-grade Neoarchaean D2/M2 event, characterized by SW-plunging sheath folds. These major D2/M2 folds developed before ~ 2.63 Ga based on U–Pb zircon age data for precursors to leucocratic anatectic gneisses that cut the high-grade gneissic fabric. The D3/M3 shear event is accurately dated by U–Pb monazite (2017.1 ± 2.8 Ma) and PbSL garnet (2023 ± 11 Ma) age data obtained from syntectonic anatectic material, and from sheared metapelitic gneisses that were completely reworked during the high-grade shear event. The shear event was preceded by isobaric heating (P = ~ 6 kbar and T = ~ 670–780 °C), which resulted in the widespread formation of polymetamorphic granulites. Many efforts to date high-grade gneisses from the CZ using PbSL garnet dating resulted in a large spread of ages (~ 2.0–2.6 Ga) that reflect the polymetamorphic nature of these complexly deformed high-grade rocks.  相似文献   

17.
L. Millonig  A. Zeh  A. Gerdes  R. Klemd 《Lithos》2008,103(3-4):333-351
The Bulai pluton represents a calc-alkaline magmatic complex of variable deformed charnockites, enderbites and granites, and contains xenoliths of highly deformed metamorphic country rocks. Petrological investigations show that these xenoliths underwent a high-grade metamorphic overprint at peak P–T conditions of 830–860 °C/8–9 kbar followed by a pressure–temperature decrease to 750 °C/5–6 kbar. This P–T path is inferred from the application of P–T pseudosections to six rock samples of distinct bulk composition: three metapelitic garnet–biotite–sillimanite–cordierite–plagioclase–(K-feldspar)–quartz gneisses, two charnoenderbitic garnet–orthopyroxene–biotite–K-feldspar–plagioclase–quartz gneisses and an enderbitic orthopyroxene–biotite–plagioclase–quartz gneiss. The petrological data show that the metapelitic and charnoenderbitic gneisses underwent uplift, cooling and deformation before they were intruded by the Bulai Granite. This relationship is supported by geochronological results obtained by in situ LA-ICP-MS age dating. U–Pb analyses of monazite enclosed in garnet of a charnoenderbite gneiss provide evidence for a high-grade structural-metamorphic–magmatic event at 2644 ± 8 Ma. This age is significantly older than an U–Pb zircon crystallisation age of 2612 ± 7 Ma previously obtained from the surrounding, late-tectonic Bulai Granite. The new dataset indicates that parts of the Limpopo's Central Zone were affected by a Neoarchaean high-grade metamorphic overprint, which was caused by magmatic heat transfer into the lower crust in a ‘dynamic regional contact metamorphic milieu’, which perhaps took place in a magmatic arc setting.  相似文献   

18.
A new occurrence of the rare corundum + quartz assemblage and magnesian staurolite has been found in a gedrite–garnet rock from the Central Zone of the Neoarchean Limpopo Belt in Zimbabwe. Poikiloblastic garnet in the sample contains numerous inclusions of corundum + quartz ± sillimanite, magnesian staurolite + sapphirine ± orthopyroxene, and sapphirine + sillimanite assemblages, as well as monophase inclusions. Corundum, often containing subhedral to rounded quartz, occurs as subhedral to euhedral inclusions in the garnet. Quartz and corundum occur in direct grain contact with no evidence of a reaction texture. The textures and Fe–Mg ratios of staurolite inclusions and the host garnet suggest a prograde dehydration reaction of St → Grt + Crn + Qtz + H2O to give the corundum + quartz assemblage. Peak conditions of 890–930 °C at 9–10 kbar are obtained from orthopyroxene + sapphirine and garnet + staurolite assemblages. A clockwise PT path is inferred, with peak conditions being followed by retrograde conditions of 4–6 kbar and 500–570 °C. The presence of unusually magnesian staurolite (Mg / [Fe + Mg] = 0.47–0.53) and corundum + garnet assemblages provides evidence for early high-pressure metamorphism in the Central Zone, possibly close to eclogite facies. The prograde high-pressure event followed by high- to ultrahigh-temperature metamorphism and rapid uplifting of the Limpopo Belt could have occurred as a result of Neoarchean collisional orogeny involving the Zimbabwe and Kaapvaal Cratons.  相似文献   

19.
The metamorphic history of the Southern Marginal Zone (SMZ) of the Limpopo Belt, South Africa, possibly provides insight into one of the oldest preserved continental collision zones. The SMZ consists of granitoid gneisses (the Baviaanskloof Gneiss) and subordinate, infolded metasedimentary, metamafic and meta‐ultramafic lithologies (the Bandelierkop Formation) and is regarded as the c. 2700 Ma granulite facies reworked equivalent of the Kaapvaal craton basement. The granulite facies metamorphism is proposed to have occurred in response to collision between the Kaapvaal and Zimbabwe cratons. Previous studies have proposed a wide variety of P–T loops for the granulites, with considerable discrepancy in both the shapes of the retrograde paths and the magnitude of the peak P–T conditions. To date, the form of the prograde path and the timing of the onset of metamorphism remain unknown. This study has used a range of different metasedimentary rocks from a large migmatitic quarry outcrop to better constrain the metamorphic history and the timing of metamorphism in the SMZ. Detrital zircon ages reveal that the protoliths to the metasedimentary rocks were deposited subsequent to 2733 ± 13 Ma. Peak metamorphic conditions of 852.5 ± 7.5 °C and 11.1 ± 1.3 kbar were attained at 2713 ± 8 Ma. The clockwise P–T path is characterized by heating in the sillimanite field along a P–T trajectory which approximately parallels the kyanite to sillimanite transition, followed by near‐isothermal decompression at peak temperature and near‐isobaric cooling at ~6.0 kbar. These results support several important conclusions. First, the sedimentary rocks from the Bandelierkop Formation are not the equivalent of any of the greenstone belt sedimentary successions on the Kaapvaal craton, as has been previously proposed. Rather, they post‐date the formation of the Dominion and Witwatersrand successions on the Kaapvaal craton. From the age distribution of detrital zircon, they appear to have received significant input from various origins. Consequently, at c. 2730 Ma, the Baviaanskloof Gneiss most likely acted as basement onto which the sedimentary succession represented by the Bandelierkop Formation metapelites was deposited. Second, the rocks of the SMZ underwent rapid evolution from sediment to granulite facies anatexis, with a burial rate of ~0.17 cm yr?1. Peak metamorphism was followed by an isothermal decompression to 787.5 ± 32.5 °C and 6.7 ± 0.5 kbar and isobaric cooling to amphibolite facies conditions, below 640 °C prior to 2680 ± 6 Ma. This age for the end of the high‐grade metamorphic event is marked by the intrusion of crosscutting, undeformed pegmatites that are within error the same age as the crosscutting Matok intrusion (2686 ± 7 Ma). Collectively, the burial rate of the sedimentary rocks, the shape of the P–T path, the burial of the rocks to in excess of 30 km depth and the post‐peak metamorphic rapid decompression argue strongly that the SMZ contains sediments deposited along an active margin during lateral convergence, and that the SMZ was metamorphosed as a consequence of continental collision along the northern margin of the Kaapvaal craton at c. 2700 Ma.  相似文献   

20.
The article evaluates household vulnerability after the 2000 flood in two poor communities of the Limpopo Province, South Africa. The study analyses the forms of vulnerability which disasters such as floods present. Using data gathered from a survey of households, the study presents the impacts, coping and adapting strategies of households after the 2000 flood. The article argues that beyond the concern over socio-economic circumstances as the major determinant of household vulnerability, the management of the disaster can serve to perpetuate vulnerability.  相似文献   

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