秦岭群条带状混合岩矿物空间分布的研究

由于条带状混合岩具多成因,因此,研究混合岩关键的问题之一是确定其成因。矿物空间分布特征可以用来区分混合岩的成因。本文研究表明,石英正长岩质黑云杆状混合岩其脉体、基体均为聚集分布,为分异作用形成,并同变形作用有关。用Wilcoxon秩和检验对比了花岗岩和含榴矽线黑云条带混合岩的脉体,结果表明两者的矿物空间分布一致,且趋于随机分布,这些脉体为部分熔融或注入形成。区域变质岩趋向于规则分布。组成混合岩的不同部分在矿物空间分布上可有也可以没有差异,例如,含榴矽线黑云条带混合岩中古成体同脉体有明显差异,而石英正长岩质黑云杆状混合岩基体和脉体无差异。     

粤西福湖岭混合岩及其原岩的地质年代学研究

为了深入认识华夏地块早古生代陆内造山作用相应的地壳再造过程,本文选取粤西福湖岭混合岩进行了详细的岩相学以及锆石U-Pb年代学研究。根据混合岩化程度,粤西福湖岭混合岩剖面由上而下可以分为3部分:混合岩化沉积变质岩、条带状混合岩和混合花岗岩。根据岩性与岩相学特征,福湖岭混合岩又可分为古成体、暗色体和浅色体。LA-ICP-MS锆石U-Pb定年结果及与区域上基底变质岩资料的对比研究表明,福湖岭混合岩的原岩(古成体)是形成于新元古代的变质沉积岩。粤西福湖岭混合岩的形成时代为441~435 Ma,是华夏地块早古生代陆内造山事件的重要产物。     

西拉木伦断裂带双井微地块北缘混合岩的基本特征及其成因机制讨论

西拉木伦断裂带双井微地块北部边缘出露有以条带状为主的混合岩,岩石中中色体-暗色体-浅色体明显分带,岩相学特征显示暗色体和浅色体经历了较高温的交代变质作用。对该混合岩浅色体的矿物空间分布分析显示浅色体重结晶现象显著,新生石英、长石聚集分布,是交代或变质分异的结果。质量平衡计算结果表明本区混合岩形成于开放体系,有物质的带进带出。对中色体、暗色体、浅色体进行单独的地球化学分析,结果显示暗色体与中色体元素组成具有相似性,而浅色体与中色体的元素组成差异较大。电子探针数据显示浅色体中斜长石的An牌号低于暗色体,中色体中角闪石压力计计算平均压力为0.81 GPa,钙质角闪石-斜长石相平衡温度计求得混合岩形成温度为584℃。综合分析认为该混合岩在成因上早期以岩浆注入为主导,晚期则以高温交代为主导。混合岩的岩浆注入成因可能意味着混合岩的形成与区域的岩浆活动有关。     

中天山地块南缘两类混合岩的成因及其地质意义

中天山地块是位于中亚造山带西南缘的西天山造山带的重要组成块体,其基底演化和构造亲缘性对恢复西天山的增生造山方式和大地构造格局具有重要意义。混合岩在中天山地块的高级变质地体中广泛分布,是揭示中天山地块基底演化和构造属性的窗口。本文通过开展锆石U-Pb年代学和Hf同位素及岩石地球化学研究,确定了中天山地块南缘乌瓦门杂岩的两类条带状混合岩的原岩性质和形成时代以及混合岩化作用时代和成因机制。第一类条带状混合岩的原岩为中基性岩屑砂岩,混合岩化时代为～1. 8Ga,是在同期角闪岩相变质过程中通过变质分异形成的。第二类条带状混合岩的古成体包括黑云角闪斜长片麻岩和黑云斜长角闪片麻岩,原岩均形成于～2. 5Ga,并叠加～1. 8Ga角闪岩相变质作用,是洋陆俯冲背景下由俯冲洋壳或岩石圈地幔部分熔融形成。侵入古成体的变基性岩墙形成于～1. 72Ga,具有Fe-Ti玄武岩的地球化学特征,起源于后碰撞伸展背景下的软流圈地幔。该类混合岩的浅色体同时穿插古成体和变基性岩墙,呈现突变的野外接触关系,与区域内约787～785Ma混合岩化同期,即混合岩化作用是外来岩浆注入的结果,可能是造山带垮塌引发地壳深熔作用的产物。乌瓦门杂岩记录的～2. 5Ga岩浆活动、～1. 8Ga变质作用和～790Ma混合岩化作用可以和塔里木北缘进行对比,暗示中天山地块是一个具有确切新太古代-古元古代结晶基底的微陆块,并且和塔里木克拉通存在构造亲缘性。     

云开隆起区热中心式区域混合岩的成因研究

云开隆起区不同混合岩化程度的混合岩在空间多以黑云母花岗岩为中心，呈环带状分布，混合岩的矿物空间分布研究表明，亲成体矿物具有随机分布特点，说明为熔浆结晶成因，结晶温度在５６０－５８０℃，条带状混凳夺的质量平衡研究表明，新成体和古成体的成分具有很好的相关性，递进熔融作用合理解释了这种混合岩的成因及其空间分布规律。     

米易海塔地区混合岩型铀矿微量元素特征

通过研究海塔地区混合岩型铀矿各类岩矿石的微量元素、稀土元素地球化学特征表明,区内矿化长英质脉体和晚期沿韧脆性剪切带充填的长英质脉体微量元素与稀土元素特征相似,说明其成因一致。区内印支期花岗岩、五马箐组片岩、片麻岩以及混合岩化长英质脉体在微量元素与稀土元素特征上有一定相似性,反映由片岩进一步衍生形成的花岗岩、片麻岩以及混合岩化长英质脉体对其原岩的成分具有明显的继承性。综合研究表明,混合岩化作用不是海塔地区混合岩型铀矿形成的主要机制,铀成矿主要与后期的构造热液活动有关。     

蚀变作用的多原岩系统及质量平衡

介绍了造成岩石地球化学不均匀性的原因，主要有测量误差、闭合问题及岩石学方面的控制等。各有其不同的研究和解决方法。对于蚀变岩的多原岩系统，常用不相容高场强元素（HFSE）来描述岩石性质，用其作为监视器，可作出各相容元素（或成分）的分异线；用不活动元素蚀变线与分异线的产点来确定原始成分，并在此基础上进行蚀变岩质量变化的计算。     

华北克拉通怀安杂岩中早前寒武纪两期变质表壳岩的重新厘定:岩石学及锆石U-Pb年代学证据

华北克拉通怀安杂岩中早前寒武纪变质表壳岩具有变质程度深（麻粒岩相）、连续性差、变形及构造置换强烈等特征,地层划分及形成时代一直存在较大争议.通过详细的地质调查、岩石学及年代学研究,新厘定出新太古代桑干岩群铁英岩岩组、石榴黑云片麻岩岩组以及古元古代集宁岩群黄土窑岩组石榴高压基性麻粒岩-大理岩岩段和含石墨矽线石榴片麻岩-变粒岩-大理岩岩段4套变质表壳岩单元,并建立了相应的岩石学识别标志.新太古代变质表壳岩一般呈透镜体或带状体产出于新太古代变质深成岩中,且锆石年龄存在~2.5 Ga和~1.8 Ga两个峰值.铁英岩岩组原岩为一套基性火山岩夹磁铁石英岩建造,产出阿尔戈马型BIF铁矿,形成年龄为2 489±19 Ma;石榴黑云片麻岩岩组主体岩石为条带状石榴黑云斜长片麻岩,原岩为杂砂岩建造,物源来自新太古代TTG岩石.古元古代石榴高压基性麻粒岩-大理岩岩段原岩为一套基性火山岩夹大理岩建造,形成年龄早于~2.03 Ga;含石墨矽线石榴片麻岩-变粒岩-大理岩岩段野外呈带状构造岩片体产出,连续性较好,为一套"有层无序"的孔兹岩组合,碎屑锆石年龄介于2.30~1.99 Ga,与区域上孔兹岩年龄结构一致,形成时代为古元古代晚期（1.99~1.95 Ga）.新太古代和古元古代变质表壳岩均卷入古元古代末期的造山过程（1.95~1.80 Ga）,遭受麻粒岩相变质与变形作用.区内孔兹岩可能是造山过程卷入的构造岩片.本研究进一步明确了晋冀蒙交界地区存在与孔兹岩不同的新太古代陆源碎屑岩和古元古代洋壳残片,这对重新认识本区早前寒武纪地质演化具有重要意义.      

贺兰山北段牛头沟金矿区围岩的原岩恢复、时代及其地质意义

牛头沟金矿区位于华北陆块鄂尔多斯地块西缘贺兰山北段之基底杂岩带,赋矿地层为一套古元古界宗别立群第二亚群(Pt1Z2)中-深程度变质岩系,主要岩石类型是黑云斜长片麻岩和变粒岩。岩石地球化学特征分析及原岩恢复说明,蚀变岩型金矿体的围岩由正、副变质岩类共同组成,其中变粒岩的原岩为沉积碎屑岩,黑云斜长片麻岩的原岩为花岗闪长质侵入岩。离子探针锆石U-Pb定年表明,表壳岩的形成时代小于2120Ma,花岗闪长岩锆石U-Pb年龄为1950±8.9Ma,辉绿岩脉的侵入与花岗闪长岩属同期。综合研究表明,矿区变质岩的原岩形成时代不是前人认为的晚太古代,而是古元古代。同时应将属于正变质岩类黑云斜长片麻岩(原岩为花岗闪长岩)从宗别立群(Pt1Z)地层中分离出来,作为侵入岩单元考虑。     

巴西典型祖母绿矿床介绍

巴西的祖母绿矿床主要属于所谓的片岩型祖母绿矿床。它们产于富含暗色岩和伟晶岩的古老地盾区内。与矿化有关的伟晶岩往往脉幅小，分异不完全。最有利于矿化的围岩是富镁的滑石片岩，含滑石片岩，含滑石大理岩和黑云母片岩等。     

Isocon analysis of migmatization in the Front Range, Colorado, USA

Isocon analysis has been applied to five sets of leucosome, mafic selvages and immediately adjacent mesosome in the migmatites from a 15-m outcrop in the Colorado Front Range. The results show: (i) mafic selvages formed from the adjacent mesosome by loss of felsic components and therefore the mesosomes are indeed palaeosomes or protoliths; (ii) the leucosomes did not form in a closed system from the palaeosome (in which case the material lost from the palaeosome during selvage formation would become the leucosome). The observed volumes and compositions of leucosomes require that the present leucosome must contain some material in addition to the felsic components lost from the selvages. The materials that must be added are leucotonalitic to granitic in composition, varying greatly in K/(Na + Ca) ratio. The trend in leucosome composition can be reproduced by assuming that a metasomatic exchange, KNa + Ca, modified originally leucotonalitic leucosomes to more K-rich compositions. These leucosomes most likely formed by injection of silicate melts accompanied, or followed, by metasomatism. The trend of leucosome compositions in this study reflects the general trend in the leucosome compositions which have been published from other areas, indicating that the proposed mechanism can be applicable to other regional migmatites.     

Mass-balance and mass-transfer in migmatites from the Colorado Front Range

Metasomatic exchanges between the infiltrating fluids and wall rocks most likely initiated the formation of nine leucosomes in two large samples of the Precambrian biotite-quartz-feldspar migmatites from the east-central Colorado Front Range. The leucosomes, 2 to 20 mm thick and enclosed in mafic salvages 1 to 10 mm thick, are granitic to tonalitic in composition. Mass-balance calculations suggest that each leucosome formed by local introduction of mass. The net gains and losses calculated assuming that all such gains and losses were contained within the leucosome show that, in general, neither the gains nor the losses fit the composition of any silicate melt. It is more likely that the components were transported in a fluid. Recalculated on constant Al basis, the most significant relative mass transfers were gain of K and losses of Na and Mg by the rocks. The metasomatic reactions calculated are those for replacement of plagioclase by microcline and breakdown of biotite. The reactions must have been the cause of incipient migmatization. A mafic selvage formed from the paleosome by the loss of material whose composition is tonalitic to granodioritic varying systematically with the paleosome composition.It is proposed that an infiltrating fluid caused metasomatism and partial melting along its path and that the melt, segregated from the mafic residues, combined with the introduced material to form a leucosome. The degree of melting was controlled by the paleosome composition and by the net amount (but not the composition) of the introduced material. The cause of melting of the paleosome was most likely an increased due to the influx of H₂O from the water-rich fluid.The compositional range of the metamorphic solution in equilibrium with these rocks was calculated from available experimental data. The sample calculations show that such fluid could have been responsible for the reactions and mass transfers observed.     

鄂东北大别杂岩中深熔混合岩存在的地质地球化学证据

基于地质地球化学研究结果提出识别大别杂岩中深熔混合岩的证据：①浅色体粗大可横切面理，伴有复杂褶皱，帮助发育；②浅色体和古成体中斜长石牌号有明显差异；③矿物成分和组合指示曾达到深熔条件；④浅色体中富含Ａｌ２Ｏ３、Ｆｅ２Ｏ３、ＴｉＯ２和不活动、不相容元素，如ＬＲＥＥ、Ｔｈ、Ｈｆ、Ｚｒ。最结合混合岩矿物空间分布和质量平衡研究结果得出结论：大别核心杂岩中混合岩的主导成因机制是深熔。     

The composition and role of the fluid in migmatites: a fluid inclusion study of the Front Range rocks

Monophase negative-crystal shaped CO₂ inclusions occurring isolated, in small clusters, or in well-healed intragranular fractures are common in the leucosome quartz of the 1700m.y.-old migmatites from the east-central Colorado Front Range. They are, however, quite rare in the mafic selvage and paleosome (host rock) quartz. The mode of occurrence suggests that these are the earliest inclusions to form. In addition to the difference in abundance of the inclusions, there is a difference in CO₂-density distribution between migmatitic zones. The temperatures of homogenization for the leucosome inclusions range and +l°C from –67° C to +20° C with two maxima (at –21° C) while those for the paleosome and selvage inclusions are –37° C to +20° C with a single maximum at + 5° C. These differences between the migmatitic zones which occur on the scale of a few centimeters suggest that the formation of these inclusions was related to the migmatization process. The densities corresponding to the Th maxima are appropriate for the P-T conditions for migmatization estimated from the mineral geobarometer/geothermometer. These inclusions must contain nearly pure CO₂, as their final melting temperatures (–56.5° to –57.2° C) are very close to that of the triple point of CO₂. Their composition also was confirmed by Raman spectroscopic analyses.It has been proposed by other workers that CO₂ fluid in the inclusions could form from an H₂O-CO₂ fluid when H₂O is partitioned into the silicate melt. Such partitioning should result in some early H₂O-rich inclusions: H₂O must be released as the melt crystallizes. As found in migmatites from other areas, most aqueous inclusions in the Front Range rocks are obviously much younger than the early CO₂ ones. However, early H₂O-rich fluid may still be preserved, at least in three ways: (A) in rare, isolated or clustered inclusions within quartz inclusions in feldspar; (B) as inclusions in microcline porphyroblasts; (C) in hydrous alteration products of feldspar. (A) contain dilute fluids, 1 to 6 wt% NaCl equivalent. The densities of (A) as well as those of the early CO₂ inclusions found in the quartz inclusions in feldspar are appropriate for the range of P — T conditions estimated for migmatization. These early inclusions must have been preserved because of protected environment. Inclusions (B), found to contain H₂O (and possibly CO₂) by infrared analyses, must be early because they are absent from recrystallized grains. (B) and (C) are much more common in the leucosome than in the other zones suggesting that they are related to migmatization process. The concentration of early CO₂ inclusions in the leucosome is consistent with the model of migmatization in which fluid concentration in the leucosome was a cause of melting.     

Geological and Geochemical Evidence for Discriminating Anatectic and Subsolidus Migmatites in the Dabieshan Complex,Northeastern Hubei Province

Based on the geological and geochemical information about migmatites,the following lines of evidence have been proposed for discriminating the anatectic leucosome in the Dabieshan Complex:(1)its width is larger than that derived from the subsolidus genesis,cutting across regional foliation,thus giving rise to complicated folds and wider selvages;(2)it is composed of melanic and accessory minerals in addition to quartz and feldspars;(3)the significant dfference in anorthites of plagioclase between paleosome and leucosome;(4)temperature and pressure(P/T) conditions revealed by the mineral compositions and assemblages are over those for the onset of anatexis;and (5)it is enriched in the major elements(e.g.Al2O3.Fe2O3and TiO2)and immobile and incompatible elements(e.g.LREE,Th,Hf and Zr).Finally,by combining the geological and geochemical features with the statistical data for the spatial distribution of minerals and mass-balance in the migatites,it is concluded that anatexis is the cardinal mechanism of migmatization in the Dabieshan Complex.     

Water-assisted migmatization of metagraywackes in a Variscan shear zone, Aiguilles-Rouges massif, western Alps

Migmatitic rocks developed in metagraywackes during the Variscan orogeny in the Aiguilles-Rouges Massif (western Alps). Partial melting took place 320 Ma ago in a 500 m-wide vertical shear zone. Three leucosome types have been recognised on the basis of size and morphology: (1) large leucosomes > 2 cm wide and > 40 cm long lacking mafic selvage, but containing cm-scale mafic enclaves; (2) same as 1 but with thick mafic selvage (melanosome); (3) small leucosomes < 2 cm and < 40 cm) with thin dark selvages (stromatic migmatites). Types 1 + 2 have mineralogical and chemical compositions in keeping with partial melting experiments. But Type 3 leucosomes have identical plagioclase composition (An_19–28) to neighbouring mesosome, both in terms of major- and trace-elements. Moreover, whole-rock REE concentrations in Type 3 leucosomes are only slightly lower than those in the mesosomes, unlike predicted by partial melting experiments. The main chemical differences between all leucosome types can be related to the coupled effect of melt segregation and late chemical reequilibration.

Mineral assemblages and thermodynamic modelling on bulk-rock composition restrict partial melting to  650 °C at 400 MPa. The large volume of leucosome (20 vol.%) thus generated requires addition of 1 wt.% external water. Restriction of extensive migmatization to the shear zone, without melting of neighbouring metapelites, also points to external fluid circulation within the shear zone as the cause of melting.     

Muscovite dehydration melting in Si-rich metapelites: microstructural evidence from trondhjemitic migmatites,Roded, Southern Israel

Making a distinction between partial melting and subsolidus segregation in amphibolite facies migmatites is difficult. The only significant melting reactions at lowpressures, either vapour saturated or muscovite dehydration melting, do not produce melanocratic peritectic phases. If protoliths are Si-rich and K-poor, then peritectic sillimanite and K-feldspar will form in scarce amounts, and may be lost by retrograde rehydration. The Roded migmatites of southern Israel (northernmost Arabian Nubian Shield) formed at P = 4.5 ± 1 kbar and T ≤ 700 °C and include Si-rich, K-poor paragneissic paleosome and trondhjemitic leucosomes. The lack of K-feldspar in leucosomes was taken as evidence for the non-anatectic origin of the Roded migmatites (Gutkin and Eyal, Isr J Earth Sci 47:117, 1998). It is shown here that although the Roded migmatites experienced significant post-peak deformation and recrystallization, microstructural evidence for partial melting is retained. Based on these microstructures, coupled with pseudosection modelling, indicators of anatexis in retrograded migmatites are established. Phase diagram modelling of neosomes shows the onset of muscovite dehydration melting at 4.5 kbar and 660 °C, forming peritectic sillimanite and K-feldspar. Adjacent non-melted paleosomes lack muscovite and would thus not melt by this reaction. Vapour saturation was not attained, as it would have formed cordierite that does not exist. Furthermore, vapour saturation would not allow peritectic K-feldspar to form, however K-feldspar is ubiquitous in melanosomes. Direct petrographic evidence for anatexis is rare and includes euhedral plagioclase phenocrysts in leucosomes and quartz-filled embayments in corroded plagioclase at leucosome-melanosome interfaces. In deformed and recrystallized rocks muscovite dehydration melting is inferred by: (1) lenticular K-feldspar enclosed by biotite in melanosomes, (2) abundant myrmekite in leucosomes, (3) muscovite–quartz symplectites after sillimanite in melanosomes and associated with myrmekite in leucosomes. While peritectic K-feldspar formed in melanosomes by muscovite dehydration melting reaction, K-feldspar crystallizing from granitic melt in adjacent leucosome was myrmekitized. Excess potassium was used in rehydration of sillimanite to muscovite.     

Petrogenesis of a Stromatic Migmatite (Nelaug, Southern Norway)

The stromatic migmatites of Nelaug (Tvedestrand area, SouthernNorway) are investigated in detail. They show well developedlayers of leucosomes, mesosomes and melanosomes. It is establishedthat the mesosomes and leucosomes of these migmatites are differentfrom each other texturally, mineralogically, and chemically.Also combinations of leucosome plus adjacent melanosome portionsare chemically different from those of the mesosomes. Theseobservations do not agree with the findings of Mehnert (1971)and do not fit into his genetic model. The mesosome layers and the leucosome + melanosome combinationsare taken to represent the chemical compositions of the countryrock, a metagraywacke with relicts of primary rhythmic layering(Touret, 1965). The mineralogical composition of the layersvaries from granitic to tonalitic. Relict textures indicatethat the leucosome portions were initially occupied by layersof granitic composition relatively rich in K-feldspar, whereasthe mesosomes are the representatives of those metagraywackelayers which were relatively rich in plagioclase. An almostisochemical transformation of a paragneiss into the investigatedstromatic migmatite is established. Melting experiments performed at PH₂O= 5 Kb yielded solidustemperatures of 640±7 °C for all layers. The Composition of plagioclases present in the different layersis explained by isochemical partial melting and in situ crystallization.The chemical, mineralogical, and textural findings support themodel of almost isochemical transformation already establishedfor the Arvika migmatites (Johannes & Gupta, 1982).     

变质分异作用中的质量迁移

变质分异作用中的质量迁移徐士进，陆建军，尹宏伟（南京大学地球科学系．南京２１００９３）关键词武功山，变质分异，质量迁移变质分异作用（ｍｅｔａｍｏｒｐｈｉｃｄｉｆｆｅｒｅｎｔｉａｔｉｏｎ）这一名词是Ｆ．Ｌ．Ｓｔｉｌｌｗｅｌｌ于１９１８年首次提出，意指成...