New emission features in the 11-13 micron region and their relationship to polycyclic aromatic hydrocarbons

If the "11.3 microns" emission feature seen in the spectra of many planetary nebulae, H II regions, and reflection nebulae is due to polycyclic aromatic hydrocarbons (PAHs), then additional features should be present between 11.3 and 13.0 microns (885 and 770 cm-1). Moderate-resolution spectra of NGC 7027, HD 44179, IRAS 21282+5050, and BD + 30 degrees 3639 are presented which show that the "11.3 microns" feature actually peaks at 11.22 microns (891 cm-1). The spectra also show evidence of new emission features near 11.9 and 12.7 microns (840 and 787 cm-1). These are consistent with an origin from PAHs and can be used to constrain the molecular structure of the family of PAHs responsible for the infrared features. The observed asymmetry of the "11.3 microns" band is consistent with the slight anharmonicity expected in the C--H out-of-plane bending mode in PAHs. Laboratory experiments show that the intensity of this mode relative to the higher frequency modes depends on the extent of molecular "clustering." The observed strengths of the "11.3 microns" interstellar bands relative to the higher frequency bands are most consistent with the features originating from free molecular PAHs. The intensity and profile of the underlying broad structure, however, may well arise from PAH clusters and amorphous carbon particles. Analysis of the 11-13 microns (910-770 cm-1) emission suggests that the molecular structures of the most intensity emitting free PAHs vary somewhat between the high-excitation environment in NGC 7027 and the low-excitation but high-flux environment close to HD 44179. Finally, a previously undetected series of regularly spaced features between 10 and 11 microns (1000 and 910 cm-1) in the spectrum of HD 44179 suggests that a simple polyatomic hydride is present in the gas phase in this object.     

The discovery of a new infrared emission feature at 1905 wavenumbers (5.25 microns) in the spectrum of BD +30 degrees 3639 and its relation to the polycyclic aromatic hydrocarbon model

We have discovered a new IR emission feature at 1905 cm-1 (5.25 microns) in the spectrum of BD +30 degrees 3639. This feature joins the family of well-known IR emission features at 3040, 2940, 1750, 1610, "1310," 1160, and 890 cm-1 (3.3, 3.4, 5.7, 6.2, "7.7," 8.6, and 11.2 microns). The origin of this new feature is discussed and it is assigned to an overtone or combination band involving C-H bending modes of polycyclic aromatic hydrocarbons (PAHs). Laboratory work suggests that spectral studies of the 2000-1650 cm-1 (5.0-6.1 microns) region may be very useful in elucidating the molecular structure of interstellar PAHs. The new feature, in conjunction with other recently discovered spectral structure, suggests that the narrow IR emission features originate in PAH molecules rather than large carbon grains. Larger species are likely to be the source of the broad underlying "plateaus" seen in many of the spectra.     

Insoluble organic material of the Orgueil carbonaceous chondrite and the unidentified infrared bands

Deuterium abundance measurements and the 13C NMR spectrum of the HF/HCl insoluble residue of the Orgueil carbonaceous chondrite indicate the presence of an extensive component of polycyclic aromatic hydrocarbons (PAH) that is of possible interstellar origin or is similar to PAH hypothesized to exist in interstellar space. Infrared spectra have been obtained using an FTIR spectrometer of the acid insoluble residue, the residue after heating in vacuum, and condensate. Bulk acid insoluble residue was pressed into KBr pellets and also heated under high vacuum to sublimate a volatile component onto KBr disks. The remaining non-volatile organic component of the Orgueil meteorite from such evaporations pressed into KBr pellets exhibits a spectral signature similar to that observed in emission from the Orion Nebula and found in Raman spectra of interplanetary dust particles (IDPs). In addition it has an 11.3 microns (885 cm-1) band indicating PAH having single hydrogens per peripheral aromatic ring. We conclude the nonvolatile material is similar to interstellar PAH because the observed 11.3 microns (885 cm-1) unidentified infrared (UIR) emission suggests interstellar PAH have single hydrogens per peripheral aromatic ring. The volatile fraction of the Orgueil shows an aliphatic CH stretch feature and its spectrum in the 2-25 microns range is similar to that of the bulk residue.     

The 3.2–3.5 μm region revisited – II. A theoretical study of the effects of hydrogenation on some model PAHs

In this second paper on the 3.2–3.5 μm region, we report the results of a theoretical study of the possible contributions of hydrogenated compounds to the observed infrared emission. We consider small aromatic species to which hydrogens have been added directly on the polycyclic frame, in both neutral and ionized forms, to mimic typical structural situations expected for larger polycyclic aromatic hydrocarbons (PAHs). The evolution of the infrared spectra for PAHs having increasingly higher excess H coverage is investigated up to saturation. The present study shows that hydrogenated PAHs produce series of bands that may be at the origin of the broad plateau observed below the 3.4- and 3.5-μm features, together with the features themselves. Ionization produces the usual collapse of the aromatic CH intensities, but it also affects the alicyclic CH intensities, although less drastically, in contrast to the CH intensities of aliphatic substituents.     

Heterodyne spectroscopy of the 158 micron C II line in M42

We have obtained velocity-resolved spectra of the 12C II 157.8 microns 2P3/2-2P1/2 fine structure line in the M42 region of Orion. Observations at 0.8 km s-1 resolution with a laser heterodyne spectrometer show multiple velocity components in some locations, with typical linewidths of 3-5 km s-1. Spectra of theta 1C and BN-KL also show weak emission from the F = 2-1 hyperfine component of the equivalent 13C II line. From the observed 12C II/13C II line intensity ratios, we deduce that the 12C II emission is optically thick with tau approximately 5 at both positions. Excitation temperatures of 128 K and 90 K, together with column densities of approximately 1 x 10(19) cm-2 and approximately 4 x 10(18) cm-2, are derived for theta 1C and BN-KL, respectively.     

Detection of the 2165 inverse centimeter (4.619 micron) XCN band in the spectrum of L1551 IRS 5

We report the detection of a broad absorption band at 2165 cm-1 (4.619 microns) in the spectrum of L1551 IRS 5. New laboratory results over the 2200-2100 cm-1 wavenumber interval (4.55-4.76 microns), performed with realistic interstellar ice analogs, suggest that this feature is due to a CN-containing compound. We will refer to this compound as XCN. We also confirm the presence of frozen CO (both in nonpolar and polar matrices) through absorption bands at 2140 cm-1 (4.67 microns) and 2135 cm-1 (4.68 microns). The relative abundance of solid-state CO to frozen H2O is approximately 0.13 while the abundance of XCN seems comparable to that of frozen CO.     

The infrared emission bands. II. A spatial and spectral study of the Orion Bar

We have studied the spectral and spatial distribution across the Orion Bar of the 3-14 micrometers emission, including hydrogen Brackett alpha and 12.8 micrometers [Ne II] emission lines and several "dust" emission features. The data indicate that the "dust" consists of three components; (1) "classical" dust with a temperature of approximately 60 K accounting for emission longward of 20 micrometers, (2) amorphous carbon particles or polycyclic aromatic hydrocarbon (PAH) clusters (approximately 400 C atoms) which produce broad emission features in the 6-9 and 11-13 micrometers bands, and (3) free PAHs which emit in sharper bands (most strongly at 3.3, 6.2, 7.7, 8.6, and 11.3 micrometers). The 3.3 and 11.3 micrometers features, which are due to C-H modes, are well correlated spatially, while the 7.7 micrometers band, due to C=C modes, has a different distribution than the 3.3 and 11.3 micrometers bands. We conclude that the sharp emission bands arise in the photodissociation transition region between the H II region and the molecular cloud and are not present in the H II region. The broad continuum feature extending from 11-13 micrometers is strong in both regions. Previous broad-band observations of the 10 and 20 micrometers flux distributions, which show that the 10 micrometers radiation extends farther into the neutral gas to the south than the 20 micrometers radiation, suggest that some of the 10 micrometers flux is supplied via a nonthermal mechanism, such as fluorescence.     

The infrared spectra of nitriles and related compounds frozen in Ar and H2O

We present the 2320-2050 cm-1 (4.31-4.88 micrometers) infrared spectra of 16 solid-state nitriles, isonitriles, and related compounds in order to facilitate the assignment of absorption features in a spectral region now becoming accessible to astronomers for the first time through the Infrared Space Observatory (ISO). This frequency range spans the positions of the strong C triple bond N stretching vibration of these compounds and is inaccessible from the ground due to absorption by CO2 in the terrestrial atmosphere. Band positions, profiles, and intrinsic strengths (A values) were measured for compounds frozen in Ar and H2O matrices at 12 K. The molecular species examined included acetonitrile, benzonitrile (phenylcyanide), 9-anthracenecarbonitrile, dimethylcyanamide, isopropylnitrile (isobutyronitrile), methylacrylonitrile, crotononitrile, acrylonitrile (vinyl cyanide), 3-aminocrotononitrile, pyruvonitrile, dicyandiamide, cyanamide, n-butylisocyanide, methylisocyanoacetate, diisopropylcarbodiimide, and hydrogen cyanide. The C triple bond N stretching bands of the majority of nitriles fall in the 2300-2200 cm-1 (4.35-4.55 micrometers) range and have similar positions in both Ar and H2O matrices, although the bands are generally considerably broader in the H2O matrices. In contrast, the isonitriles and a few exceptional nitriles and related species produce bands at lower frequencies spanning the 2200-2080 cm-1 (4.55-4.81 micrometers) range. These features also have similar positions in both Ar and H2O matrices, and the bands are broader in the H2O matrices. Three of the compounds (pyruvonitrile, dicyandiamide, and cyanamide) show unusually large shifts of their C triple bond N stretching frequencies when changing from Ar to H2O matrices. We attribute these shifts to the formation of H2O:nitrile complexes with these compounds. The implications of these results for the identification of the 2165 cm-1 (4.62 micrometers) "XCN" interstellar feature and the 4550 cm-1 (2.2 micrometers) feature of various objects in the solar system are discussed.     

Search for HH-objects and emission stars in star formation regions. VI. Herbig-Haro objects and emission stars in the region of the GM 1-64 and GM 2-4 nebulae

Three new Herbig-Haro and 12 emission stars, mainly belonging to the T Tau class, have been discovered in a study of the region of the GM 1-64 and GM 2-4 nebulae in the direction of the galactic anticenter. GM 1-64 and GM 2-4 are typical cometary nebulae illuminated by emission stars. In GM 2-4 the central star is surrounded by a dense dust envelope and is observed only in the IR. Two stellar-like sources which are bright in the IR are found in this same region and can be regarded as young, Class 1 stars. One of them (CPM 19) is surrounded by a compact group of fainter PMS objects. It is found that CPM 19 shows up clearly in the optical range and undergoes large amplitude brightness variations.     

Emission-line CCD imaging of three southern symbiotic stars

Symbiotic stars that are strong radio sources and have cool dust emitting in the infrared are expected to have extended emission nebulae around them. In order to search for such emission nebulae, we have carried out CCD imaging of three symbiotic stars (R Aqr, RR Tel and H1-36) with narrow-band filters centred at the emission lines of [O III] λ5007, Hα λ6563, [N II] λ6584, [S II] λ6717 + 6731. RR Tel and H1-36 images do not show any extended nebulosities around them. The CCD image of the R Aqr nebulosity in the high excitation [O m] line is different from its image in Hα and the low excitation lines of [N II] and [S II] indicating ionization-stratification in the nebula. In H1-36 the optical nebulosity (if it exists) is smaller than ∽2 arcsec while the radio image size is known to be large (∽5 arcsec). This behaviour is opposite to that seen in R Aqr in which the radio emission comes from the core region of a much larger optical nebulosity. Interstellar and/or circumstellar extinctions are suggested to be responsible for this difference     

High-resolution spectroscopy and broad-band imaging of the young planetary nebula K 3-35

We present high-resolution echelle and long-slit spectra and broad-band ( R , I ) images of the very young planetary nebula K 3-35. Several emission lines are identified, including the He  ii  4686 line and strong [N  ii ]6548, 6583 and [O  iii ]4959, 5007 emissions [ I ([N  ii ])/ I (H α )≃5.5, I ([O  iii ])/ I (H β )≃30]. A systemic velocity V _LSR≃10±2 km s⁻¹ for K 3-35 is obtained from the optical emission lines. Two different kinematic components are identified in the nebula. One of them is probably related to the elliptical envelope previously observed. The second component exhibits systematic changes of the radial velocity with position, and a relatively small velocity width. This component may be attributed to the precessing jet-like outflows previously identified. The R and I images and the deduced R − I colour map strongly support the existence of a dense, partially neutral disc-like region in the equatorial plane of the nebula, which probably represents an equatorial density enhancement in a previously ejected slow wind. Diagnostic diagrams for line intensity ratios in K 3-35 and collimated components of other planetary nebulae suggest that the emission spectrum of this kind of structure is a combination of radiative and shock excitation, in agreement with recent models of shocks in a strongly photoionized medium.     

恒星形成区GGD12-15的近红外观测

给出恒星形成区GGD12-15的宽波段JHK和窄波段H2v=1-0S(1)近红外成像观测．观测图像揭示了致密的年轻红外星团和与红外源成协的红外星云，并发现了以H2发射结表征的星团外流活动．大多数红外点源在光学波段不可见；对76颗红外点源的JHK′测光结果显示，有32颗具有红外超，其中5颗表现原恒星特征，表明分子云中的恒星形成活动很活跃．以B8光谱型作为大质量星分界，由色星等图估计出大质量星所占星团比例为-10％～26％．GGD12—15星团的K′星等分布的峰值位于15.0mag，并在13．0mag-16．0mag平坦分布；[H—K′]色分布的峰值出现在-0．7mag，在此以上更红的星团成分占70％．在GGD12-15区新发现的氢分子发射结集中在星团中心领域，其空间分布明显与剧烈的恒星形成活动相关；有5个发射结位于分子外流的中心区域，暗示其激发可能与分子外流同源．     

Continuum beyond the Lyman limit and effective temperatures of the nuclei of planetary nebulae

Using published data on Hß-,λ4471 Hel- and λ4686 Hell-line fluxes for planetary nebulae the energy distribution in their nuclei is calculated in the wavelength range 100–912 Å by supposing that 1) the spectrum inclination is the same in the regions of continuous absorption of Hl, Hel, and Hell atoms; and 2) discontinuities at 504 Å and 228 Å are present in the nuclei spectra. From 40 investigated nebulae, only for two nuclei the distribution in all three intervals 504–912 Å, 228–504 Å and λ ≦ 228 Å corresponds to one and the same temperature of black-body emission. In 24 cases the emission temperature is the same for the first and the second interval. The energy distribution in the wavelength range shorter than 228 Å corresponds systematically to very high temperatures T_* > 100,000 K. It is concluded that the emission temperature over the surface of nuclei is markedly inhomogeneous and/or the nuclei of planetary nebulae possess a hot corona.     

Retrieval and tentative indentification of the 3 μm spectral feature in Titan's haze

Recently, an unidentified 3.3-3.4 μm feature found in the solar occultation spectra of the atmosphere of Titan observed by Cassini/VIMS was tentatively attributed to the C-H stretching mode of aliphatic hydrocarbon chains attached to large organic molecules, but without properly extracting the feature from adjacent influences of strong CH₄ and weak C₂H₆ absorptions (Bellucci et al., 2009). In this work, we retrieve the detailed spectral feature using a radiative transfer program including absorption and fluorescent emission of both molecules, as well as absorption and scattering by haze particles. The spectral features of the haze retrieved from the VIMS data at various altitudes are similar to each other, indicating relatively uniform spectral properties of the haze with altitude. However, slight deviations observed near 127 km and above 300 km suggest inhomogeneity at these altitudes. We find that the positions of the major spectral peaks occur at 3.33-3.37 μm, which are somewhat different from the typical 3.3 μm aromatic or 3.4 μm aliphatic C-H stretches usually seen in the spectra of dust particles of the interstellar medium and comets. The peaks, however, coincide with those of the solid state spectra of C₂H₆, CH₄, and CH₃CN; and a broad shoulder from 3.37 to 3.50 μm coincides with those of C₅H₁₂ and C₆H₁₂ as well as those of typical aliphatic C-H stretches. This result combined with high-altitude (∼1000 km) haze formation process recently reported by Waite et al. (2007) opens a new question on the chemical composition of the haze particles. We discuss the possibility that the 3 μm feature may be due to the solid state absorption bands of these molecules (or some other molecules) and we advocate additional laboratory measurements for the ices of hydrocarbon and nitrogen-bearing molecules present in Titan's atmosphere for the identification of this 3 μm feature.     

Isolated neutron stars: magnetic fields, distances,and spectra

We present timing measurements, astrometry, and high-resolution spectra of a number of nearby, thermally emitting, isolated neutron stars. We use these to infer magnetic field strengths and distances, but also encounter a number of puzzles. We discuss three specific ones in detail: (i) For RX J0720.4-3125 and RX J1308.6+2127, the characteristic ages are in excess of 1 Myr, while their temperatures and kinematic ages indicate that they are much younger; (ii) For RX J1856.5-3754, the brightness temperature for the optical emission is in excess of that measured at X-ray wavelengths for reasonable neutron-star radii; (iii) For RX J0720.4-3125, the spectrum changed from an initially featureless state to one with an absorption feature, yet there was only a relatively small change in T _eff. Furthermore, we attempt to see whether the spectra of all seven sources, in six of which absorption features have now been found, can be understood in the context of strongly magnetised hydrogen atmospheres. We find that the energies of the absorption features can be reproduced, but that it remains puzzling that, for J0720.4-3125 specifically, the spectrum was featureless in one state, and that, generally, the spectra do not have high-energy tails that are harder than the Wien-like ones obseved.      

The Galactic disc distribution of planetary nebulae with warm dust emission features – I

We investigate the Galactic disc distribution of a sample of planetary nebulae characterized in terms of their mid-infrared spectral features. The total number of Galactic disc PNe with 8–13 μm spectra is brought up to 74 with the inclusion of 24 new objects, the spectra of which we present for the first time. 54 PNe have clearly identified warm dust emission features, and form a sample that we use to construct the distribution of the C/O chemical balance in Galactic disc PNe. The dust emission features complement the information on the progenitor masses brought by the gas-phase N/O ratios: PNe with unidentified infrared emission bands have the highest N/O ratios, while PNe with the silicate signature have either very high N enrichment or close to none. We find a trend for a decreasing proportion of O-rich PNe towards the third and fourth Galactic quadrants. Two independent distance scales confirm that the proportion of O-rich PNe decreases from     per cent inside the solar circle to     per cent outside. PNe with warm dust are also the youngest. PNe with no warm dust are uniformly distributed in C/O and N/O ratios, and do not appear to be confined to     They also have higher 6-cm fluxes, as expected from more evolved PNe. We show that the IRAS fluxes are a good representation of the bolometric flux for compact and IR-bright PNe, which are probably optically thick. Selection of objects with     should probe a good portion of the Galactic disc for these young, dense and compact nebulae, and the dominant selection effects are rooted in the PN catalogues.     

Gamma-rays and cosmic rays from a pulsar in Cygnus OB2

We argue that γ-ray sources observed in the direction of the Cygnus OB2 association in the GeV and TeV energy range are due to a pulsar that was created by a supernova a few tens of thousands of years ago. The GeV emission is produced by a middle-aged pulsar, a factor of 2 older than the Vela pulsar. The TeV emission is produced by high-energy hadrons and/or leptons accelerated in pulsar wind nebulae. We suggest, moreover, that the excess of cosmic rays at ∼10¹⁸ eV observed from the direction of the Cygnus region can also be related to the appearance of this very energetic pulsar in the Cyg OB2 association. Some of the relativistic hadrons, captured in strong magnetic fields of a high-density region of Cyg OB2, produce neutrons and γ-rays in collisions with matter. These neutrons can arrive from Cyg OB2, creating an excess of cosmic rays.     

Multi-wavelength correlation studies of diffuse emission from the Aquila Rift

We present a multi-wavelength correlation study of diffuse ultraviolet radiation using GALEX observations towards the Aquila Rift. Apart from airglow and zodiacal emissions, we find a diffuse background of \(1300\mbox{--} 3700~\mbox{ph}\,\mbox{cm}^{-2}\,\mbox{s}^{-1}\,\mbox{sr}^{-1}\,\mathring{\mathrm{A}}^{-1}\) in the far-ultraviolet (FUV, 1350–1750 Å) band and \(1300\mbox{--}2800~\mbox{ph}\,\mbox{cm}^{-2}\,\mbox{s}^{-1}\,\mbox{sr}^{-1}\,\mathring{\mathrm{A}}^{-1}\) in the near-ultraviolet (NUV, 1750–2850 Å) band. The observed diffuse UV emissions are saturated with total as well as neutral hydrogen column density in the region due to high optical depth in UV (\(\tau \), 0.91–23.38). Higher values of FUV/NUV ratio in the region, greater than the threshold value of 0.6, along with the positive correlation between the ratio and FUV intensity are due to excess emission in the FUV band which is absent in the NUV band. We estimated the excess emission to be in the range \(\sim 400\mbox{--} 2700~\mbox{ph}\,\mbox{cm}^{-2}\,\mbox{s}^{-1}\,\mbox{sr}^{-1}\,\mathring{\mathrm{A}}^{-1}\), plausibly due to H₂ fluorescence, ion line emissions and two-photon continuum emissions from the region in the FUV band, which also shows saturation in optically thick regions with N(H₂) as well as \(\mbox{H}\alpha \) emissions. Since N(H₂) and \(\mbox{H}\alpha \) emissions spread all over the region, the excess emission from the field is composite in nature and a detailed spectroscopic analysis is needed to disentangle the contribution from individual components.     

Hα emission objects in Circinus

We present a new survey for Hα emission objects in the Circinus cloud complex and introduce an efficient photometric method for detecting Hα emission via observations in a narrow‐band filter. The observed flux is compared to a blackbody fit of the continuum. Our search strategy reveals 20 stars with strong Hα emission (EW > 10 Å), eight of them being new detections. All Hα stars display infrared excess corroborating their youth. On the other hand, the region contains a number of infrared excess objects that do not show Hα emission. Our results support the picture that accretion – as witnessed by Hα emission – is a highly variable phenomenon. Therefore, Hα surveys can only trace the temporarily active objects. In contrast, infrared excess is a more robust tracer that reveals most of the population of young stellar objects in a star forming region. Our analysis of the general stellar content of the region yields a reliable distance of 450 pc for the Circinus cloud. Moreover, we find a ratio of total‐to‐selective extinction of R^V = 2.8 suggesting that smaller‐than‐normal dust grains may be present. (© 2013 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)