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1.
We have observed emission from HCN, H13CN, HC15N, HN13C, H15NC, HC3N, CH3CN, and possibly CH3NC, and determined an upper limit for NH2CN, toward the cold, dark cloud TMC-1. The abundance ratio [HNC]/[HCN] = 1.55 +/- 0.16 is at least a factor approximately 4 and approximately 100 greater than that observed toward the giant molecular clouds DR 21(OH) and Orion KL, respectively. In contrast, for the corresponding methylated isomers we obtain [CH3NC]/CH3CN] < or approximately 0.1. We also find [NH2CN]/[CH3CN] < or approximately 0.1 and [HC3N]/[CH3CN] = 30 +/- 10. We find no evidence for anomalous hyperfine ratios for H13CN, indicating that the ratios for HCN (cf. recent work of Walmsley et al.) are the result of self-absorption by cold foreground gas.  相似文献   

2.
Observations of comet Hale-Bopp (C/1995 O1) have been carried out near perihelion (1997 March) at millimeter wavelengths using the NRAO 12 m telescope. The J=1-->0, 2-->1, and 3-->2 lines of HCN at 88, 177, and 265 GHz were measured in the comet as well as the J=3-->2 lines of H13CN, HC15N, and HNC. The N=2-->1 transition of CN near 226 GHz was also detected, and an upper limit was obtained for the J=2-->1 line of HCNH+. From the measurements, column densities and production rates have been estimated. A column density ratio of [HCN]/[HNC] = 7+/-1 was observed near perihelion, while it was found that [HCN]/[HCNH+] greater, similar 1. The production rates at perihelion for HCN and CN were estimated to be Q(HCN) approximately 1x1028 s-1 and Q(CN) approximately 2.6x1027 s-1, respectively, resulting in a ratio of [HCN]/[CN] approximately 3. Consequently, HCN is sufficiently abundant to be the parent molecule of CN in Hale-Bopp, and HCNH+ could be a source of HNC. Finally, carbon and nitrogen isotope ratios of 12C/13C = 109+/-22 and 14N/15N = 330+/-98 were obtained from HCN measurements, in agreement with previous values obtained from J=4-->3 data. Such ratios suggest that comet Hale-Bopp formed coevally with the solar system.  相似文献   

3.
Interstellar hydrogen sulfide (H2S) and its isotopic variant (H2(34)S) have been observed toward several positions in OMC-1 via their 1(10)-1(01) transitions near 168 GHz using the FCRAO 14 m telescope. We derive total column densities toward Orion(KL) for the extended ridge, for the plateau, and for the hot core, in addition to values for other positions in OMC-1. The fractional abundance of H2S (approximately 10(-9)) in the quiescent regions of OMC-1 seems to be difficult to explain by currently known ion-molecule reactions. The fractional abundance of H2S relative to H2 is enhanced by a factor of 1000 in the hot core and the plateau relative to the quiescent clouds. This enhancement may be a result of grain surface chemistry and/or of high-temperature gas-phase chemistry. From the nondetection of HDS in its 2(11)-2(12) transition, we estimate the abundance ratio [HDS]/H2S] < or = 0.02 in the hot core.  相似文献   

4.
We have performed high-resolution spectral observations at mid-infrared wavelengths of CH4 (8.14 micrometers), C2H6 (12.16 micrometers), and C2H2 (13.45 micrometers) on Jupiter. These emission features probe the stratosphere of the planet and provide information on the carbon-based photochemical processes taking place in that region of the atmosphere. The observations were performed using our cryogenic echelle spectrometer CELESTE, in conjunction with the McMath-Pierce 1.5-m solar telescope between November 1994 and February 1995. We used the methane observations to derive the temperature profile of the jovian atmosphere in the 1-10 mbar region of the stratosphere. This profile was then used in conjunction with height-dependent mixing ratios of each hydrocarbon to determine global abundances for ethane and acetylene. The resulting mixing ratios are 3.9(+1.9)(-1.3) x 10(-6) for C2H6 (5 mbar pressure level), and 2.3 +/- 0.5 x 10(-8) for C2H2 (8 mbar pressure level), where the quoted uncertainties are derived from model variations in the temperature profile which match the methane observation uncertainties.  相似文献   

5.
The kinetic reactions in N2-xCH4(C2H2) gas discharges with x less than 1% have been studied by emission spectroscopy in the afterglow of D.C. discharges and by mass spectroscopy from radiolysis ionization using alpha particles. The pressure range is from several Torr to 100 Torr. At the end of N2 D.C. discharges at room temperature, for a residence time of about 10(-2) s, the dominant active species are the N atoms with density of 10(14)-10(15) cm-3 for N2 density of about 10(17) cm-3 (3 Torr), the N2(X,V) vibrational molecules with for example [N2(X,V = 10)] approximately 10(14) cm-3 and the electronic metastable molecules N2(A 3 sigma u +) with a density of 10(12) cm-3. In such conditions, the following kinetic reactions have been studied: N2(A) + N2(A) --> N2(C,B,V') + N2(X), N2(A) + N2(X,V>5) --> N2(X) + N2(B,V') in pure N2 post-discharges and N2(A) + CH4 --> products, C + N + M2 --> CN(B,V') + M2, N2(X,V>4) + CN --> N2(X) + CN(B,A,V'), in N2-1% CH4 post-discharges. The clustering reactions of N2-(1-5%)CH4(C2H2) gas mixtures after radiolysis ionization have been studied for the H2CN+ nN2 ions and the equilibrium constants have been determined in the temperature range T = 140-300 K.  相似文献   

6.
We present near-infrared spectra of seven radio-loud quasars with a median redshift of 2.1, five of which were previously known to have Ly α nebulae. Extended [O  iii ] λ 5007 and H α emission are evident around six objects, at the level of a few times 10−16 erg cm−2 arcsec−2 s−1 within ≃2 arcsec of the nucleus (≡16 kpc in the adopted cosmology). Nuclear [O  ii ] λ 3727 is detected in three of the five quasars studied at this wavelength and clearly extended in one of them.
The extended [O  iii ] tends to be brighter on the side of the nucleus with the stronger, jet-like radio emission, indicating at least that the extranuclear gas is distributed anisotropically. It is also typically redshifted by several hundred km s−1 from the nuclear [O  iii ], perhaps because of the latter being blueshifted from the host galaxy's systemic velocity. Alternatively, the velocity shifts could be due to infall (which is suggested by linewidths ∼1000 km s−1 FWHM) in combination with a suitable dust geometry. Ly α /H α ratios well below the case B value suggest that some dust is present.
Photoionization modelling of the [O  iii ]/[O  ii ] ratios in the extended gas suggests that its pressure is around or less than a few times 107 cm−3 K; any confining intracluster medium is thus likely to host a strong cooling flow. A comparison with lower redshift work suggests that there has been little evolution in the nuclear emission-line properties of radio-loud quasars between redshifts 1 and 2.  相似文献   

7.
Upper limits are placed on the D/H ratio in the observed portions of the atmospheres of Jupiter and Saturn from observations at high S/N over the region of the 5-0 R(1) line of HD. The upper limits of 4 × 10?5 and 6 × 10?5 D/H on Jupiter and Saturn, respectively, are not inconsistent with present models for abundance ratios in the primitive solar nebula or with other estimates of this quantity from observations.  相似文献   

8.
We have defined a sample of 63 active galactic nuclei with strong forbidden high-ionization line (FHIL) emission. These lines, with ionization potentials  ≳100  eV, respond to a portion of the spectrum that is often difficult to observe directly, thereby providing constraints on the extreme ultraviolet-soft X-ray continuum. The sources are selected from the Sloan Digital Sky Survey (SDSS) on the basis of their [Fe  x ]λ6374 Å emission, yielding one of the largest and the most homogeneous samples of FHIL-emitting galaxies. We fit a sequence of models to both FHILs ([Fe  xi ], [Fe  x ] and [Fe  vii ]) and lower ionization emission lines ([O  iii ], [O  i ],  Hα  , [N  ii ], [S  ii ]) in the SDSS spectra. These data are combined with X-ray measurements from the ROSAT satellite, which are available for half of the sample. The correlations between these parameters are discussed for both the overall sample and subsets defined by spectroscopic classifications. The primary results are evidence that (1) the [Fe  x ] and [Fe  xi ] lines are photoionized and their strength is proportional to the continuum flux around 250 eV, (2) the FHIL-emitting clouds form a stratified outflow in which the [Fe  x ] and [Fe  xi ] source regions extend sufficiently close to the broad-line region that they are partially obscured in Seyfert 2s, whereas the [Fe  vii ] source region is more extended and is unaffected by obscuration, (3) narrow-lined Seyfert 1s (NLS1s) tend to have the strongest [Fe  x ] flux (relative to lower ionization lines) and (4) the most extreme [Fe  x ] ratios (such as [Fe  x ]/[O  iii ] or [Fe  x ]/[Fe  vii ]) are found in the NLS1s with the narrowest broad lines and appear to be an optical-band indication of objects with strong X-ray soft excesses.  相似文献   

9.
Limb and nadir spectra acquired by Cassini/CIRS (Composite InfraRed Spectrometer) are analyzed in order to derive, for the first time, the meridional variations of diacetylene (C4H2) and methylacetylene (CH3C2H) mixing ratios in Saturn’s stratosphere, from 5 hPa up to 0.05 hPa and 80°S to 45°N. We find that the C4H2 and CH3C2H meridional distributions mimic that of acetylene (C2H2), exhibiting small-scale variations that are not present in photochemical model predictions. The most striking feature of the meridional distribution of both molecules is an asymmetry between mid-southern and mid-northern latitudes. The mid-southern latitudes are found depleted in hydrocarbons relative to their northern counterparts. In contrast, photochemical models predict similar abundances at north and south mid-latitudes. We favor a dynamical explanation for this asymmetry, with upwelling in the south and downwelling in the north, the latter coinciding with the region undergoing ring shadowing. The depletion in hydrocarbons at mid-southern latitudes could also result from chemical reactions with oxygen-bearing molecules.Poleward of 60°S, at 0.1 and 0.05 hPa, we find that the CH3C2H and C4H2 abundances increase dramatically. This behavior is in sharp contradiction with photochemical model predictions, which exhibit a strong decrease towards the south pole. Several processes could explain our observations, such as subsidence, a large vertical eddy diffusion coefficient at high altitudes, auroral chemistry that enhances CH3C2H and C4H2 production, or shielding from photolysis by aerosols or molecules produced from auroral chemistry. However, problems remain with all these hypotheses, including the lack of similar behavior at lower altitudes.Our derived mean mixing ratios at 0.5 hPa of (2.4 ± 0.3) × 10−10 for C4H2 and of (1.1 ± 0.3) × 10−9 for CH3C2H are compatible with the analysis of global-average ISO observations performed by Moses et al. (Moses, J.I., Bézard, B., Lellouch, E., Gladstone, G.R., Feuchtgruber, H., Allen, M. [2000a]. Icarus 143, 244-298). Finally, we provide values for the ratios [CH3C2H]/[C2H2] and [C4H2]/[C2H2] that can constrain the coupled chemistry of these hydrocarbons.  相似文献   

10.
We have searched for millimetre-wave line emission from ethylene oxide (c-C2H4O) and its structural isomer acetaldehyde (CH3CHO) in 11 molecular clouds using SEST. Ethylene oxide and acetaldehyde were detected through multiple lines in the hot cores NGC 6334F, G327.3-0.6, G31.41+0.31, and G34.3+0.2. Acetaldehyde was also detected towards G10.47+0.03, G322.2+0.6, and Orion 3'N, and one ethylene oxide line was tentatively detected in G10.47+0.03. Column densities and rotational excitation temperatures were derived using a procedure which fits the observed line intensifies by finding the minimum chi 2-value. The resulting rotational excitation temperatures of ethylene oxide and acetaldehyde are in the range 16-38 K, indicating that these species are excited in the outer, cooler parts of the hot cores or that the excitation is significantly subthermal. For an assumed source size of 20", the deduced column densities are (0.6-1)x10(14) cm-2 for ethylene oxide and (2-5)x10(14) cm-2 for acetaldehyde. The fractional abundances with respect to H2 are X[c-C2H4O]=(2-6)xl0(-10), and X[CH3CHO]=(0.8-3)x10(-9). The ratio X[CH3CHO]/X[c-C2H4O] varies between 2.6 (NGC 6334F) and 8.5 (G327.3-0.6). We also detected and analysed multiple transitions of CH3OH, CH3OCH3, C2H5OH, and HCOOH. The chemical, and possibly evolutionary, states of NGC 6334F, G327.3-0.6, G31.41+0.31, and G34.3+0.2 seem to be very similar.  相似文献   

11.
The Large Sky Area Multi-Object Fiber Spectroscopic Telescope(LAMOST) published its first data release(DRl)in 2013,which is currently the largest dataset of stellar spectra in the world.We combine the PASTEL catalog and SIMBAD radial velocities as a testing standard to validate stellar parameters(effective temperature T_(eff),surface gravity log g,metallicity[Fe/H]and radial velocity V_r)derived from DR1.Through cross-identification of the DR1 catalogs and the PASTEL catalog,we obtain a preliminary sample of 422 stars.After removal of stellar parameter measurements from problematic spectra and applying effective temperature constraints to the sample,we compare the stellar parameters from DR1 with those from PASTEL and SIMBAD to demonstrate that the DR1 results are reliable in restricted ranges of T_(eff).We derive standard deviations of 110 K,0.19 dex and 0.11 dex for T_(eff),log g and[Fe/H]respectively when T_(eff)8000 K,and 4.91 km S~(-1) for V_r when T_(eff)10 000 K.Systematic errors are negligible except for those of V_r.In addition,metallicities in DR1 are systematically higher than those in PASTEL,in the range of PASTEL[Fe/H]-1.5.  相似文献   

12.
The abundances of PH3, CH3D, and GeH4 are derived from the 2100- to 2250-cm?1 region of the Voyager 1 IRIS spectra. No evidence is seen for large-scale variations of the phosphine abundance over Jovian latitudes between ?30 and +30°. In the atmospheric regions corresponding to 170–200°K, the derived PH3/H2 value is (4.5 ± 1.5) × 10?7 or 0.75 ± 0.25 times the solar value. This result, compared with other PH3 determinations at 10 μm, suggests than the PH3/H2 ratio on Jupiter decreases with atmospheric pressure. In the 200–250°K region, we derive, within a factor of 2, CH3D/H2 and GeH4/H2 ratios of 2.0 × 10?7 and 1.0 × 10?9, respectively. Assuming a C/H value of 1.0 × 10?3, as derived from Voyager, our CH3D/H2 ratio implies a D/H ratio of 1.8 × 10?5, in reasonable agreement with the interstellar medium value.  相似文献   

13.
Laboratory measurements and calculations have been performed to determine the abundance ratio of the deuterated ethynyl radical (CCD) to the normal radical (CCH) which can be achieved in dense interstellar clouds via isotopic fractionation in the C2H2+ (HD) = C2HD+ (H2) system of reactions. According to this limited treatment, the CCD/CCH abundance ratio which can be attained is in the range 0.02-0.03 for the Orion molecular cloud and 0.01-0.02 for TMC-1. These ranges of numbers are in reasonable agreement with the observed values in Orion and TMC-1. However, the analysis of the CCD/CCH abundance ratio is complicated via the presence of competing fractionation mechanisms, especially in the low-temperature source TMC-1.  相似文献   

14.
We have studied the velocity field of the blue compact dwarf galaxy Mrk 86 (NGC 2537) using data provided by 14 long-slit optical spectra obtained in 10 different orientations and positions. This kinematical information is complemented with narrow-band ([O  iii ]5007 Å and H α ) and broad-band ( B , V , Gunn r and K ) imaging. The analysis of the galaxy global velocity field suggests that the ionized gas could be distributed in a rotating inclined disc, with projected central angular velocity of Ω=34 km s−1 kpc−1. The comparison between the stellar, H  i and modelled dark matter density profile indicates that the total mass within its optical radius is dominated by the stellar component. Peculiarities observed in its velocity field can be explained by irregularities in the ionized gas distribution or local motions induced by star formation.
Kinematical evidences for two expanding bubbles, Mrk 86–B and Mrk 86–C, are given. They show expanding velocities of 34 and 17 km s−1, H α luminosities of 3×1038 and 1.7×1039 erg s−1, and physical radii of 374 and 120 pc, respectively. The change in the [S  ii ]/H α , [N  ii ]/H α , [O  ii ]/[O  iii ] and [O  iii ]/H β line ratios with the distance to the bubble precursor suggests a diminution in the ionization parameter and, in the case of Mrk 86–B, an enhancement of the shock-excited gas emission. The optical–near-infrared colours of the bubble precursors are characteristic of low‐metallicity star‐forming regions (∼0.2 Z) with burst strengths of about 1 per cent in mass.  相似文献   

15.
T. Encrenaz  M. Combes 《Icarus》1982,52(1):54-61
Using a method defined in a previous paper [M. Combes and T. Encrenaz, Icarus39 1–27 (1979)], we reestimated the C/H ratio in the atmospheres of Jupiter and Saturn by the measurements of the weak visible CH4 bands, the CH43 band, and the (3-0) and (4-0) quadrupole bands of H2. In the case of Jupiter we conclude that the C/H ratio is enriched by a factor ranging from 1.7 to 3.6 relative to the solar value. In the case of Saturn, our derived C/H value ranges from 1.2 to 3.2 times the solar value. The Jovian D/H ratio derived from this study is 1.2 × 10?5 < D/H < 3.1 × 10?5. The value derived for the D/H ratio on Saturn is not precise enough to be conclusive.  相似文献   

16.
We report observations of the 2(12)-1(01) rotational transition of the 13C isotopic species of cyclopropenylidene (C3H2) toward TMC-1, Sgr B2, and IRC +10216 using the laboratory rest frequencies which have recently become available. Our detections allow estimates to be made of the fractional abundance of the unsubstituted similar species in these sources. The fractional abundance relative to H2, f(C3H2), is 1-2 x 10(-8) in TMC-1, and this is similar to the abundance of HCN, one of the more abundant organic molecules in the interstellar medium. In IRC +10216 f(C3H2) is one order of magnitude greater than in TMC-1. The 12C species in Sgr B2 shows a self-absorbed profile and the relative abundance of C3H2 estimated to be about an order of magnitude less than in TMC-1.  相似文献   

17.
High spectral resolution observations from the Cassini Composite Infrared Spectrometer [Flasar, F.M., and 44 colleagues, 2004. Space Sci. Rev. 115, 169-297] are analysed to derive new estimates for the mole fractions of CH4, CH3D and 13CH4 of (4.7±0.2)×10−3, (3.0±0.2)×10−7 and (5.1±0.2)×10−5 respectively. The mole fractions show no hemispherical asymmetries or latitudinal variability. The analysis combines data from the far-IR methane rotational lines and the mid-IR features of methane and its isotopologues, using both the correlated-k retrieval algorithm of Irwin et al. [Irwin, P., and 9 colleagues, 2008. J. Quant. Spectrosc. Radiat. Trans. 109, 1136-1150] and a line-by-line approach to evaluate the reliability of the retrieved quantities. C/H was found to be enhanced by 10.9±0.5 times the solar composition of Grevesse et al. [Grevesse, N., Asplund, M., Sauval, A., 2007. Space Sci. Rev. 130 (1), 105-114], 2.25±0.55 times larger than the enrichment on Jupiter, and supporting the increasing fractional core mass with distance from the Sun predicted by the core accretion model of planetary formation. A comparison of the jovian and saturnian C/N, C/S and C/P ratios suggests different reservoirs of the trapped volatiles in a primordial solar nebula whose composition varies with distance from the Sun. This is supported by our derived D/H ratio in methane of (1.6±0.2)×10−5, which appears to be smaller than the jovian value of Lellouch et al. [Lellouch, E., Bézard, B., Fouchet, T., Feuchtgruber, H., Encrenaz, T., de Graauw, T., 2001. Astron. Astrophys. 370, 610-622]. Mid-IR emission features provided an estimate of , which is consistent with both the terrestrial ratio and jovian ratio, suggesting that carbon was accreted from a shared reservoir for all of the planets.  相似文献   

18.
The abundances of 22 heavy elements from Sr to Pb have been determined for the halo star HD 29907 (T eff = 5500 K, log g = 4.64) with [Fe/H] = −1.55 using high-quality VLT/UVES spectra (ESO, Chile). The star has a moderate enhancement of r-process elements (Eu-Tm) with [r/Fe] = 0.63. In the range from Ba to Yb, the derived abundance pattern agrees well with those for strongly r-process enhanced stars (r-II stars with [Eu/Fe] > 1 and [Ba/Eu] < 0), such as CS 22892-052 and CS 31082-001, as well as with the scaled solar r-process curve and the r-process model HEW. Thus, Ba-Yb in HD 29907 originate in the r-process. Just as other moderately r-process enhanced stars studied in the literature, HD 29907 exhibits higher Sr, Y, and Zr abundances than those for r-II stars. These results confirm the assumption by other authors about the existence of an additional Sr-Zr synthesis mechanism in the early Galaxy before the onset of nucleosynthesis in asymptotic giant branch (AGB) stars. The same mechanism can be responsible for the enhancement of Mo-Ag in the star being investigated compared to r-II stars. There are no grounds to suggest the presence of s-nuclei of lead in the material of the star being investigated, because its measured abundance ratio log ɛ(Pb/Eu) = 1.20 lies within the range for the comparison stars: from log ɛ(Pb/Eu) = 0.17 (CS 31082-001) to < 1.55 (HE 1219-0312). Thus, even if there was a contribution of AGB stars to the heavy-element enrichment of the interstellar medium at the epoch with [Fe/H] = −1.55, it was small, at the level of the abundance error.  相似文献   

19.
The results of an investigation of polarimetric and IR (IRAS) observations of 12 B-A-F stars are presented. It is shown that the polarization parameters (P % and θ°) for the stars 66 Oph, SU Cas, HD 206773, EW Lac, and HD 216411 differ markedly in different colors (U, B, V, R). Color-color diagrams of the dependence of [12] - [60] on [12] - [25], of V- [12] on B - V, and of [12] - [25] on V- [12] are given. It is shown that the stars SU Cas, α CrB, γ Ser, γ Oph, QR Vul, and HD 183362 have dust shells of the Vega type. The stars 66 Oph and EWLac are similar in IR color indices to 51 Oph (B9.5Ve), while HD 206773, HD 208682, HD 216411, and HD 179761 are similar to HD 9672, β Pic, and HR 4796, which have more extended shells. Translated from Astrofizika, Vol. 43, No. 3, pp. 353-360, July–September, 2000.  相似文献   

20.
By means of a detailed chemical evolution model, we follow the evolution of barium (Ba) and europium (Eu) in four Local Group Dwarf Spheroidal (dSph) galaxies, in order to set constraints on the nucleosynthesis of these elements and on the evolution of this type of galaxies compared with the Milky Way. The model, which is able to reproduce several observed abundance ratios and the present-day total mass and gas mass content of these galaxies, adopts up-to-date nucleosynthesis and takes into account the role played by supernovae (SNe) of different types (II, Ia) allowing us to follow in detail the evolution of several chemical elements (H, D, He, C, N, O, Mg, Si, S, Ca, Fe, Ba and Eu). By assuming that Ba is a neutron-capture element produced in low-mass asymptotic giant branch stars by s-process but also in massive stars (in the mass range 10–30 M) by r-process, during the explosive event of SNe of Type II, and that Eu is a pure r-process element synthesized in massive stars also in the range of masses 10–30 M, we are able to reproduce the observed [Ba/Fe] and [Eu/Fe] as functions of [Fe/H] in all four galaxies studied. We confirm also the important role played by the very low star formation (SF) efficiencies (ν= 0.005–0.5 Gyr−1) and by the intense galactic winds (6–13 times the star formation rate) in the evolution of these galaxies. These low SF efficiencies (compared to the one for the Milky Way disc) adopted for the dSph galaxies are the main reason for the differences between the trends of [Ba/Fe] and [Eu/Fe] predicted and observed in these galaxies and in the metal-poor stars of our Galaxy. Finally, we provide predictions for Sagittarius galaxy for which data of only two stars are available.  相似文献   

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