New emission features in the 11-13 micron region and their relationship to polycyclic aromatic hydrocarbons

If the "11.3 microns" emission feature seen in the spectra of many planetary nebulae, H II regions, and reflection nebulae is due to polycyclic aromatic hydrocarbons (PAHs), then additional features should be present between 11.3 and 13.0 microns (885 and 770 cm-1). Moderate-resolution spectra of NGC 7027, HD 44179, IRAS 21282+5050, and BD + 30 degrees 3639 are presented which show that the "11.3 microns" feature actually peaks at 11.22 microns (891 cm-1). The spectra also show evidence of new emission features near 11.9 and 12.7 microns (840 and 787 cm-1). These are consistent with an origin from PAHs and can be used to constrain the molecular structure of the family of PAHs responsible for the infrared features. The observed asymmetry of the "11.3 microns" band is consistent with the slight anharmonicity expected in the C--H out-of-plane bending mode in PAHs. Laboratory experiments show that the intensity of this mode relative to the higher frequency modes depends on the extent of molecular "clustering." The observed strengths of the "11.3 microns" interstellar bands relative to the higher frequency bands are most consistent with the features originating from free molecular PAHs. The intensity and profile of the underlying broad structure, however, may well arise from PAH clusters and amorphous carbon particles. Analysis of the 11-13 microns (910-770 cm-1) emission suggests that the molecular structures of the most intensity emitting free PAHs vary somewhat between the high-excitation environment in NGC 7027 and the low-excitation but high-flux environment close to HD 44179. Finally, a previously undetected series of regularly spaced features between 10 and 11 microns (1000 and 910 cm-1) in the spectrum of HD 44179 suggests that a simple polyatomic hydride is present in the gas phase in this object.     

Hydrogenated polycyclic aromatic hydrocarbons and the 2940 and 2850 wavenumber (3.40 and 3.51 micron) infrared emission features

The 3150-2700 cm-1 (3.17-3.70 microns) range of the spectra of a number of Ar-matrix-isolated PAHs containing excess H atoms (Hn-PAHs) are presented. This region covers features produced by aromatic and aliphatic C-H stretching vibrations as well as overtone and combination bands involving lower lying fundamentals. The aliphatic C-H stretches in molecules of this type having low to modest excess H coverage provide excellent fits to a number of the weak emission features superposed on the plateau between 3080 and 2700 cm-1 (3.25 and 3.7 microns) in the spectra of many planetary nebulae, reflection nebulae, and H II regions. Higher H coverage is implied for a few objects. We compare these results in context with the other suggested identifications of the emission features in the 2950-2700 cm-1 (3.39-3.70 microns) region and briefly discuss their astrophysical implications.     

Insoluble organic material of the Orgueil carbonaceous chondrite and the unidentified infrared bands

Deuterium abundance measurements and the 13C NMR spectrum of the HF/HCl insoluble residue of the Orgueil carbonaceous chondrite indicate the presence of an extensive component of polycyclic aromatic hydrocarbons (PAH) that is of possible interstellar origin or is similar to PAH hypothesized to exist in interstellar space. Infrared spectra have been obtained using an FTIR spectrometer of the acid insoluble residue, the residue after heating in vacuum, and condensate. Bulk acid insoluble residue was pressed into KBr pellets and also heated under high vacuum to sublimate a volatile component onto KBr disks. The remaining non-volatile organic component of the Orgueil meteorite from such evaporations pressed into KBr pellets exhibits a spectral signature similar to that observed in emission from the Orion Nebula and found in Raman spectra of interplanetary dust particles (IDPs). In addition it has an 11.3 microns (885 cm-1) band indicating PAH having single hydrogens per peripheral aromatic ring. We conclude the nonvolatile material is similar to interstellar PAH because the observed 11.3 microns (885 cm-1) unidentified infrared (UIR) emission suggests interstellar PAH have single hydrogens per peripheral aromatic ring. The volatile fraction of the Orgueil shows an aliphatic CH stretch feature and its spectrum in the 2-25 microns range is similar to that of the bulk residue.     

Detection of the 2165 inverse centimeter (4.619 micron) XCN band in the spectrum of L1551 IRS 5

We report the detection of a broad absorption band at 2165 cm-1 (4.619 microns) in the spectrum of L1551 IRS 5. New laboratory results over the 2200-2100 cm-1 wavenumber interval (4.55-4.76 microns), performed with realistic interstellar ice analogs, suggest that this feature is due to a CN-containing compound. We will refer to this compound as XCN. We also confirm the presence of frozen CO (both in nonpolar and polar matrices) through absorption bands at 2140 cm-1 (4.67 microns) and 2135 cm-1 (4.68 microns). The relative abundance of solid-state CO to frozen H2O is approximately 0.13 while the abundance of XCN seems comparable to that of frozen CO.     

The infrared emission bands. II. A spatial and spectral study of the Orion Bar

We have studied the spectral and spatial distribution across the Orion Bar of the 3-14 micrometers emission, including hydrogen Brackett alpha and 12.8 micrometers [Ne II] emission lines and several "dust" emission features. The data indicate that the "dust" consists of three components; (1) "classical" dust with a temperature of approximately 60 K accounting for emission longward of 20 micrometers, (2) amorphous carbon particles or polycyclic aromatic hydrocarbon (PAH) clusters (approximately 400 C atoms) which produce broad emission features in the 6-9 and 11-13 micrometers bands, and (3) free PAHs which emit in sharper bands (most strongly at 3.3, 6.2, 7.7, 8.6, and 11.3 micrometers). The 3.3 and 11.3 micrometers features, which are due to C-H modes, are well correlated spatially, while the 7.7 micrometers band, due to C=C modes, has a different distribution than the 3.3 and 11.3 micrometers bands. We conclude that the sharp emission bands arise in the photodissociation transition region between the H II region and the molecular cloud and are not present in the H II region. The broad continuum feature extending from 11-13 micrometers is strong in both regions. Previous broad-band observations of the 10 and 20 micrometers flux distributions, which show that the 10 micrometers radiation extends farther into the neutral gas to the south than the 20 micrometers radiation, suggest that some of the 10 micrometers flux is supplied via a nonthermal mechanism, such as fluorescence.     

Heterodyne spectroscopy of the 158 micron C II line in M42

We have obtained velocity-resolved spectra of the 12C II 157.8 microns 2P3/2-2P1/2 fine structure line in the M42 region of Orion. Observations at 0.8 km s-1 resolution with a laser heterodyne spectrometer show multiple velocity components in some locations, with typical linewidths of 3-5 km s-1. Spectra of theta 1C and BN-KL also show weak emission from the F = 2-1 hyperfine component of the equivalent 13C II line. From the observed 12C II/13C II line intensity ratios, we deduce that the 12C II emission is optically thick with tau approximately 5 at both positions. Excitation temperatures of 128 K and 90 K, together with column densities of approximately 1 x 10(19) cm-2 and approximately 4 x 10(18) cm-2, are derived for theta 1C and BN-KL, respectively.     

Discovery of a New Pulsating X-Ray Source with a 1549.1 Second Period, AX J183220-0840

A new pulsating X-ray source, AX J183220-0840, with a 1549.1 s period was discovered at R.A.=18h32m20s and decl.=-8&j0;40'30" (J2000, with an uncertainty of 0&farcm;6) during an ASCA observation on the Galactic plane. The source was observed two times, in 1997 and in 1999. A phase-averaged X-ray flux of 1.1x10-11 ergs cm-2 s-1 and a pulsation period of 1549.1+/-0.4 s were consistently obtained from these two observations. The X-ray spectrum was represented by a flat, absorbed power law with a photon index of Gamma approximately 0.8 and an absorption column density of NH approximately 1.3x1022 cm-2. Also, a signature of iron K-shell line emission with a centroid of 6.7 keV and an equivalent width of approximately 450 eV was detected. From the pulsation period and the iron-line feature, AX J183220-0840 is likely to be a magnetic white dwarf binary with a complexly absorbed thermal spectrum with a temperature of about 10 keV.     

The infrared spectra of nitriles and related compounds frozen in Ar and H2O

We present the 2320-2050 cm-1 (4.31-4.88 micrometers) infrared spectra of 16 solid-state nitriles, isonitriles, and related compounds in order to facilitate the assignment of absorption features in a spectral region now becoming accessible to astronomers for the first time through the Infrared Space Observatory (ISO). This frequency range spans the positions of the strong C triple bond N stretching vibration of these compounds and is inaccessible from the ground due to absorption by CO2 in the terrestrial atmosphere. Band positions, profiles, and intrinsic strengths (A values) were measured for compounds frozen in Ar and H2O matrices at 12 K. The molecular species examined included acetonitrile, benzonitrile (phenylcyanide), 9-anthracenecarbonitrile, dimethylcyanamide, isopropylnitrile (isobutyronitrile), methylacrylonitrile, crotononitrile, acrylonitrile (vinyl cyanide), 3-aminocrotononitrile, pyruvonitrile, dicyandiamide, cyanamide, n-butylisocyanide, methylisocyanoacetate, diisopropylcarbodiimide, and hydrogen cyanide. The C triple bond N stretching bands of the majority of nitriles fall in the 2300-2200 cm-1 (4.35-4.55 micrometers) range and have similar positions in both Ar and H2O matrices, although the bands are generally considerably broader in the H2O matrices. In contrast, the isonitriles and a few exceptional nitriles and related species produce bands at lower frequencies spanning the 2200-2080 cm-1 (4.55-4.81 micrometers) range. These features also have similar positions in both Ar and H2O matrices, and the bands are broader in the H2O matrices. Three of the compounds (pyruvonitrile, dicyandiamide, and cyanamide) show unusually large shifts of their C triple bond N stretching frequencies when changing from Ar to H2O matrices. We attribute these shifts to the formation of H2O:nitrile complexes with these compounds. The implications of these results for the identification of the 2165 cm-1 (4.62 micrometers) "XCN" interstellar feature and the 4550 cm-1 (2.2 micrometers) feature of various objects in the solar system are discussed.     

Circumstellar PAHs and Carbon Stardust

The SWS on ISO has revealed the incredible richness of IR emission features in the spectra of post-AGB objects and planetary nebulae. Besides the well known features at 3.3, 6.2, 7.7, 8.6, and 11.3 μm, a wealth of weaker features is present as well. These studies also reveal detailed variations from source to source, which may be of key importance in the molecular identification process. The emission from Polycyclic Aromatic Hydrocarbon molecules and carbon dust are contrasted with an emphasis on the expected temperature and the feature-to-continuum ratio. Graphite stardust, isolated from carbonaceous meteorites, consist of a core of microcrystalline aromatic moieties mantled by crystalline graphite. This structure suggests the importance of two distinct growth stages or processes. The cores resemble terrestrial soot and indicate formation at relatively low temperature where kinetic factors played an important role, presumably involving PAH formation through reactions of C2H2 and its radical progeny, followed by coagulation of these PAHs as well as further chemical growth. The mantle seems to reflect slow chemical growth at higher temperatures of relatively few PAHs accreted onto these cores. This revised version was published online in September 2006 with corrections to the Cover Date.     

Laboratory comparisons of organic materials to interstellar dust and the Murchison meteorite

Spectra of objects which lie along several lines of sight through the diffuse interstellar medium (DISM) reveal an absorption feature near 3.4 micrometers, which has been attributed to saturated aliphatic hydrocarbons on interstellar grains. The similarity of the absorption bands near 3.4 micrometers (2950 cm-1) along different lines of sight indicates that the carrier of this band lies in the diffuse dust. Several materials have been proposed as "fits" to the 3.4 micrometers feature over the years. A comparison of these identifications is presented. These comparisons illustrate the need for high resolution, high signal-to-noise observational data as a means of distinguishing between laboratory organics as matches to the interstellar material. Although any material containing hydrocarbons will produce features in the 3.4 micrometers region, the proposed "matches" to the DISM do differ in detail. These differences may help in the analyses of the chemical composition and physical processes which led to the production of the DISM organics, although ISO Observations through the 5-8 micrometers spectral region are essential for a definitive identification. A remarkable similarity between the spectrum of the diffuse dust and an organic extract from the Murchison meteorite suggests that some of the interstellar organic material may be preserved in primitive solar system bodies. The 3.4 micrometers absorption feature (in the rest frame) has recently been detected in external galaxies, indicating the widespread availability of organic material for incorporation into planetary systems.     

Reversed far-infrared line emission from OH in Orion

The fundamental OH rotational transition at 2514 GHz (119.2 micrometers) has been observed in the Orion IRc2 region at a spectral resolution of 0.6 km s-1. The emission is spatially compact (< 25" FWHM) and centered near IRc2. A comparison of the observed profile with spectra of other species known to exist in the region suggests that the entire blueshifted side of the OH profile has been "self-absorbed," leaving only a redshifted emission component. In addition, there is pronounced absorption near 5 km s-1 VLSR indicative of the "hot core" source. The presence of the 119 micrometers absorption provides a straightforward explanation for the high ratio of 163/119 micrometers integrated line intensities which was previously considered anomalous.     

Comment on “Comparison of the composition of the Tempel 1 ejecta to the dust in Comet C/Hale-Bopp 1995 O1 and YSO HD 100546” by C.M. Lisse, K.E. Kraemer, J.A. Nuth III, A. Li, D. Joswiak [2007. Icarus 187, 69-86]

Lisse et al. [Lisse, C.M., Kraemer, K.E., Nuth III, J.A., Li, A., Joswiak, D., 2007. Icarus 187, 69-86] recently presented a new analysis of an ISO spectrum of Comet C/1995 O1 (Hale-Bopp), from which they claimed the identification of many new dust species. Among them are PAHs, which were not found in our first analysis of the ISO spectra. We present here a re-examination of the ISO observations of Comet Hale-Bopp. From the absence of PAHs features in the 5.25-8.5 μm region, we infer that PAHs are at least twice less abundant than derived by Lisse et al. The carbonate feature at 7.00 μm is marginally present, but lower by a factor 2 to 3 than predicted by the model of Lisse et al.     

Spectral study of BIG objects on the 2.6-m telescope at the Byurakan astrophysical observatory

Results of spectral observations of 45 objects from the BIG sample (corresponding to 35 IRAS sources) obtained on the 2.6-m telescope at the BAO are reported. Emission lines are observed for 42 galaxies, 1 object is an absorption galaxy, and 2 turned out to be stars. The red shifts are determined, the radial velocities, distances, sizes, and absolute stellar magnitudes are calculated, the parameters of the spectral lines are determined, the objects are classified according to their activity type, and the IR and far IR luminosities are calculated. Of the 42 emission galaxies, 1 was type Sy2, 2 were LINERs, 1 was an AGN (Sy2 or LINER), 4 were composite, 25 were HII (including 6 with nuclear star-formation activity), and 9 were Em of undetermined type (3 of which may be AGN). Calculations show that 23 of the objects are LIG. A physical coupling is discovered for 9 multiple systems. Spectra of some of the galaxies are shown. __________ Translated from Astrofizika, Vol. 49, No. 1, pp. 23–40 (February 2006).     

Infrared spectroscopy of interstellar nanodiamonds from the Orgueil meteorite

Abstract— We present results from an ongoing study of the infrared (IR) and optical properties of nanodiamonds, an objective of which is to identify spectral features in the laboratory that could also be used telescopically to trace the presence of these particles in the interstellar medium (ISM). Fourier transform mid-and far-infrared spectra of nanodiamond residue extracted from the Orgueil (CI) chondrite were acquired. All of the mid-IR bands initially present were found to diminish, with the exception of a band at ～1100 cm^?1, following additional oxidation of the diamonds. The ～1100 cm^?1 band can be predominantly attributed to adsorbed species, especially an ether-type linkage, while the “oxidisable” features seem to be associated with less stable, surface-bonded species and residual carbonaceous material. We obtained three far-IR features but are uncertain about the origin of those at 475 and 188 cm^?1. We did not obtain a feature at ～120 cm^?1 reported by another group but do not discount the possibility that the band at 188 cm^?1 could be related to it. The weak absorption band at 475 cm^?1 (21 μm) is especially interesting because it may be strong in emission from hot nanodiamonds and, therefore, related to the unidentified infrared feature (UIF) observed at this wavelength in the spectra of some C-rich protoplanetary nebulae.     

Photodissociation regions and star formation in the Carina nebula

We have obtained wide-field thermal infrared (IR) images of the Carina nebula, using the SPIREX/Abu telescope at the South Pole. Emission from polycyclic aromatic hydrocarbons (PAHs) at 3.29 μm, a tracer of photodissociation regions (PDRs), reveals many interesting well-defined clumps and diffuse regions throughout the complex. Near-IR images  (1–2 μm)  , along with images from the Midcourse Space Experiment ( MSX ) satellite  (8–21 μm)  have been incorporated to study the interactions between the young stars and the surrounding molecular cloud in more detail. Two new PAH emission clumps have been identified in the Keyhole nebula, and have been mapped in  ¹²CO(2–1)  and  (1–0)  using the Swedish–ESO Submillimetre Telescope (SEST). Analysis of their physical properties reveals that they are dense molecular clumps, externally heated with PDRs on their surfaces and supported by external pressure in a similar manner to the other clumps in the region. A previously identified externally heated globule containing IRAS 10430−5931 in the southern molecular cloud shows strong 3.29-, 8- and 21-μm emission, the spectral energy distribution (SED) revealing the location of an ultracompact (UC) H  ii region. The northern part of the nebula is complicated, with PAH emission intermixed with mid-IR dust continuum emission. Several point sources are located here, and through a two-component blackbody fit to their SEDs we have identified three possible UC H  ii regions as well as a young star surrounded by a circumstellar disc. This implies that star formation in this region is ongoing and not halted by the intense radiation from the surrounding young massive stars.     

Fresnel modeling of hematite crystal surfaces and application to martian hematite spherules

The gray crystalline hematite at Meridiani Planum first discovered by the Mars Global Surveyor Thermal Emission Spectrometer (MGS-TES) instrument occurs as spherules that have been interpreted as concretions. Analysis of the TES and mini-TES spectra shows that no 390 cm⁻¹ feature is present in the characteristic martian hematite spectrum. Here, we incorporate the mid-IR optical constants of hematite into a simple Fresnel reflectance model to understand the effect of emission angle and crystal morphology on the presence or absence of the 390 cm⁻¹ feature in an IR hematite spectrum. Based on the results we offer two models for the internal structure of the martian hematite spherules.     

Search for HH-objects and emission stars in star formation regions. VI. Herbig-Haro objects and emission stars in the region of the GM 1-64 and GM 2-4 nebulae

Three new Herbig-Haro and 12 emission stars, mainly belonging to the T Tau class, have been discovered in a study of the region of the GM 1-64 and GM 2-4 nebulae in the direction of the galactic anticenter. GM 1-64 and GM 2-4 are typical cometary nebulae illuminated by emission stars. In GM 2-4 the central star is surrounded by a dense dust envelope and is observed only in the IR. Two stellar-like sources which are bright in the IR are found in this same region and can be regarded as young, Class 1 stars. One of them (CPM 19) is surrounded by a compact group of fainter PMS objects. It is found that CPM 19 shows up clearly in the optical range and undergoes large amplitude brightness variations.     

Investigation of OH and H<Subscript>2</Subscript>O masers in the star-forming region G 188.946+0.886

We present the results of our observations of the maser radio emission source G188.946+0.886 in hydroxyl (OH) molecular lines with the radio telescope of the Nançay Observatory (France) and in the H₂O line at λ = 1.35 cm with the RT-22 radio telescope at the Pushchino Observatory (Russia). An emission feature in the 1720-MHz satellite line of the OH ground state has been detected for the first time. The radial velocity of the feature, V _LSR = 3.6 km s^?1, has a “blue” shift relative to the range of emission velocities in the main 1665- and 1667-MHz OH lines, which is 8–11 km s^?1. This suggests a probable connection of the observed feature in the 1720-MHz line with the “blue” wing of the bipolar outflow observed in this region in the CO line. We have estimated the magnetic field strength for three features (0.90 and 0.8 mG for 1665 MHz and 0.25 mG for 1720 MHz) from the Zeeman splitting in the 1665- and 1720-MHz lines. No emission and (or) absorption has been detected in the other 1612-MHz satellite OH line. Three cycles of H₂O maser activity have been revealed. The variability is quasi-periodic in pattern. There is a general tendency for the maser activity to decrease. Some clusters of H2O maser spots can form organized structures, for example, chains and other forms.     

Optical and UV observations of the intermediate polar 3A0729+103. Modulation with the orbital period

3A0729+103 (=BG CMi) is an intermediate polar discovered through its X-ray emission (McHardy et al. 1981, 1984). The orbital period is 3.235 hours and the rotation period is 15.2 minutes. For ephemeris and references on the source we refer to McHardy et al. (1984). We report here on optical (4025 to 5090 A) and ultraviolet (1200 to 3200 A) spectroscopy obtained, respectively, on Dec 1, 1984 and April 21, 1985. Our data show clear modulation of spectral features with the orbital period.Paper presented at the IAU Colloquium No. 93 on Cataclysmic Variables. Recent Multi-Frequency Observations and Theoretical Developments, held at Dr. Remeis-Sternwarte Bamberg, F.R.G., 16–19 June, 1986.