Laboratory detection of a new interstellar free radical CH2CN(2B1)

An asymmetric-top free radical CH2CN, which as a 2B1 ground state, was detected for the first time by laboratory microwave spectroscopy. The radical was produced in a free-space absorption cell by a DC glow discharge in pure CH3CN gas. About 60 fine-structure components were observed for the N = 11-10 to 14-13 a-type rotational transitions in the frequency region of 220-260 GHz, and many hyperfine resolved components for the N = 4-3 and 5-4 transitions in the 80 and 100 GHz regions, respectively. The molecular constants, including the rotational constants, centrifugal distortion constants, and spin-rotation coupling constants with centrifugal distortion correction terms were determined from the fine-structure resolved transitions, and the hyperfine coupling constants due to the hydrogen and nitrogen nuclei were obtained from the low-N transitions. As a result we assigned U100602 and U80484 from Sgr B2, and U40240 and U20120 from TMC-1, to the N = 5-4, 4-3, 2-1, and 1-0 transitions with K-1 = 0 of the CH2CN radical.     

Vibrationally excited molecular hydrogen in circumstellar clouds and the interstellar CH+ abundance

The production of CH⁺ in dense interstellar clouds under intense UV irradiation is discussed. A model applicable to the cloud towards the star 20 Tau is described.     

Theoretical investigation of the interstellar CH3NC/CH3CN ratio

Calculations have been performed to determine the abundance ratio of the metastable isomer CH3NC to the stable isomer CH3CN in dense interstellar clouds. According to gas phase, ion-molecule treatments, these molecules are both synthesized via protonated ion precursors. We have calculated the ratio of the formation rates of the protonated precursor ions-- CH3NCH+ and CH3CNH+ --synthesized via the radiative association reaction between CH3+ and HCN, which is thought to the dominant formation process of the two isomeric ions. Our calculations, which involve both ab initio quantum chemistry and equilibrium determinations, lead to a predicted CH3NCH+/CH3CNH+ formation rate ratio between 0.1 and 0.4. If this ratio is maintained in the neutral species formed from the precursor ions, theory predicts a sizable abundance for methyl isocyanide (CH3NC) and lends credence to its tentative observation.     

Correlations between parameters of massive cores in interstellar molecular clouds

Based on a CS and C³⁴S survey of dense molecular-cloud cores in regions of high-mass-star formation, we analyze the correlations between line width and size (ΔV-L), as well as between mean density and size (n-L). There is virtually no correlation between ΔV and L (ΔV ∝ L ^0.2±0.1). The velocity dispersion is several times higher in absolute value than that in CO and dark clouds of the same size. The mean density decreases with increasing size considerably faster than L ^?1, so the column density also decreases. Possible effects of selection and of the technique for determining object parameters on these results are discussed. Possible physical causes of the above correlations are considered.     

Discussion session on star formation,molecular clouds and the interstellar medium

In this panel discussion contributions were made by K. Strom, L. Nordh and H. Zinnecker on the contributions of surveys to the study of star formation regions, by B. Burton on a survey of galactic H I and by E. Dwek on the detection of galactic supernovae by infrared surveys. The contributions of K. Strom, L. Nordh and E. Dwek are summarized here.     

A new interstellar polyatomic molecule: detection of propynal in the cold cloud TMC-1

We report the detection of the acetylene derivative propynal (HC triple bond CCHO) in the cold cloud TMC-1, with an abundance that is very close to that for the related species tricarbon monoxide (C3O). Propadienone, an isomer of propynal with the formula H2C=C=C=O, was not detected and is hence less abundant than either C3O or HC2CHO.     

Time dependent chemical study of contracting interstellar clouds. III. the charge distribution in interstellar clouds

We have constructed a chemical reaction model in a contracting interstellar cloud including 104 species which are involved in a network of 557 reactions. The chemical kinetic equations were integrated as a function of time by using gear package. The evolution of the system was followed in the density range 10–10⁷ particles cm^-3.The calculated fractional abundances of the charged species are in good agreement with those given by other investigators. The charge density has been followed in diffuse, intermediate and dense regions. The most dominant ionic species are metallic ions, HCO⁺ and H ₃ ⁺ in the shielded regions and atomic ions H⁺, C⁺, Si⁺, He⁺, S⁺ and metal ions in the diffuse and intermediate regions. The abundances of negatively charged ions were found to be negligible. The results of the calculations on the different metallic ions are interpreted.     

A search for propylene oxide and glycine in Sagittarius B2 (LMH) and Orion

We have used the Mopra Telescope to search for glycine and the simple chiral molecule propylene oxide in the Sgr B2 (LMH) and Orion KL, in the 3-mm band. We have not detected either species, but have been able to put sensitive upper limits on the abundances of both molecules. The 3σ upper limits derived for glycine conformer I are  3.7 × 10¹⁴ cm⁻²  in both Orion-KL and Sgr B2 (LMH), comparable to the reported detections of conformer I by Kuan et al. However, as our values are 3σ upper limits rather than detections we conclude that this weighs against confirming the detection of Kuan et al. We find upper limits for the glycine II column density of  7.7 × 10¹² cm⁻²  in both Orion-KL and Sgr B2 (LMH), in agreement with the results of Combes et al. The results presented here show that glycine conformer II is not present in the extended gas at the levels detected by Kuan et al. for conformer I. Our ATCA results have ruled out the detection of glycine (both conformers I and II) in the compact hot core of the LMH at the levels reported, so we conclude that it is unlikely that Kuan et al. have detected glycine in either Sgr B2 or Orion-KL. We find upper limits for propylene oxide abundance of  3.0 × 10¹⁴ cm⁻²  in Orion-KL and  6.7 × 10¹⁴ cm⁻²  in Sgr B2 (LMH). We have detected fourteen features in Sgr B2 and four features in Orion-KL which have not previously been reported in the interstellar medium, but have not been able to plausibly assign these transitions to any carrier.     

On the CH B‐X (1, 0) band in translucent clouds

We present observations of CH B‐X (1, 0) band toward 13 translucent sightlines. The given precise positions (at 3627.403, 3633.289, 3636.222 Å) are derived by means of shifting our spectra to the rest velocity frame using B‐X (0, 0) features (at 3878, 3886 and 3890 Å). The proposed oscillator strengths (equal to 0.00035, 0.00104, 0.00069, respectively) are based on f ‐values of the CH B‐X (0, 0) system, i.e. 0.00110, 0.00320, 0.00210 (© 2011 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Shock waves and the chemical structure of interstellar clouds

In this paper we study the effect of shock waves on the chemical structure of the interstellar clouds. A model of molecular cloud has been assumed. The chemistry is investigated in a time dependent model. Our chemical network contains 56 species in 251 reactions to including molecules of the elements H, O, C, N, S, and Si.The results indicate that the calculated fractional abundance of the molecules NS, H₂O, CN, NH, CO, and SO agrees well with the observations. The molecules OH, H₂S, CS, H₂CS, HS, NO, SiO, CH, CH₂, CH₃, HCO, C₂, and HCN reach high post-shock abundances.     

Interstellar scintillation and clouds of the interstellar turbulent plasma

Data on interstellar diffraction and refraction scintillation of pulsars are analyzed. Comparison between theory and the observational data shows that two types of spectra for electron density fluctuations are realized in the interstellar medium: pure power law and piecewise with a break. The distribution of turbulent plasma in the Galaxy has a three component structure. Component A is diffuse and it is distributed outside of the spiral arms of the Galaxy. Component BI is cloudy and associated with Galactic arms. Component BII is extremely nonuniform and associated with HII regions and supernova remnants. The origin of the interstellar plasma turbulence is considered, and possible sources of turbulent energy are discussed. The contribution of supernova bursts in the interstellar gas ionization and generation of turbulence are analyzed among other factors. This revised version was published online in July 2006 with corrections to the Cover Date.     

A study of interstellar Na i D absorption lines towards the Lupus molecular clouds

Intermediate-resolution (60 000 R 120 000) observations of interstellar Na  i lines towards 29 stars in the general direction of the Lupus molecular clouds (330°≲ l ≲350°; 0°≲ b ≲25°) are presented. Previously published spectra towards an additional seven stars are also included. Based on the Hipparcos distances to these stars, and the minimum distance at which strong interstellar Na  i lines appear in the spectra, I obtain a distance of ~150±10 pc to the Lupus molecular complex. While in agreement with a number of other independent estimates, this result is at odds with the value of 100 pc recently obtained by Knude & Høg from a Hipparcos -based study of interstellar extinction. A possible explanation for this discrepancy is discussed, and it is concluded that the value of 150±10 pc obtained here is to be preferred. In addition, these observations have some other implications for the structure of the interstellar medium in this direction, and these are briefly considered.     

The rate of the reaction between CN and C2H2 at interstellar temperatures

The rate coefficient for the important interstellar reaction between CN and C2H2 has been calculated as a function of temperature between 10 and 300 K. The potential surface for this reaction has been determined through ab initio quantum chemical techniques; the potential exhibits no barrier in the entrance channel but does show a small exit channel barrier, which lies below the energy of reactants. Phase-space calculations for the reaction dynamics, which take the exit channel barrier into account, show the same unusual temperature dependence as determined by experiment, in which the rate coefficient at first increases as the temperature is reduced below room temperature and then starts to decrease as the temperature drops below 50-100 K. The agreement between theory and experiment provides strong confirmation that the reaction occurs appreciably at cool interstellar temperatures.     

Far UV radiation transfer and H2CO lifetime in dense interstellar clouds

The UV radiation transfer within spherical interstellar dust clouds is analyzed using the method of successive scatterings. The results are used to determine the lifetime of interstellar H₂CO against photo-destruction. The effectiveness of this process is compared with those of chemical mechanisms.     

Evolution of the fractal structure of interstellar clouds in the galaxy

The internal stability of the fractal structure of interstellar clouds in the Galaxy is considered. The conditions under which gravitational interactions between components lead to disruption of the fractal structure are clarified. Model numerical calculations and analytical estimates of the characteristic time of decay of structures are made. It is found that this time is on the same order as the lifetime of interstellar molecular clouds determined from observations. Translated from Astrofizika, Vol. 41, No. 1, pp. 81–90, January-March, 1998.     

The chemistry of interstellar CH: The contribution of Bates and Spitzer (1951)

We review the present understanding of interstellar CH⁺. We show that the essential chemistry was correctly identified by Bates and Spitzer in 1951. More recent work has been concerned with defining appropriate venues within which this chemistry can function efficiently. This process had led to a much fuller understanding of the nature of the interstellar medium.