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1.
The effectiveness of aquifer remediation is typically expressed in terms of a reduction in contaminant concentrations relative to a regulated maximum contaminant level (MCL), and is usually confirmed by sparse monitoring data and/or simple model calculations. Here, the effectiveness of remediation is re-examined from a more thorough risk-based perspective that goes beyond the traditional MCL concept. A methodology is employed to evaluate the health risk to individuals exposed to contaminated household water that is produced from groundwater. This approach explicitly accounts for differences in risk arising from variability in individual physiology and water use, the uncertainty in estimating chemical carcinogenesis for different individuals, and the uncertainties and variability in contaminant concentrations within groundwater as affected by transport through heterogeneous geologic media. A hypothetical contamination scenario is developed as a case study in a saturated, alluvial aquifer underlying an actual Superfund site. A baseline (unremediated) human exposure and health risk scenario, as induced by contaminated groundwater pumped from this site, is predicted and compared with a similar estimate based upon pump-and-treat exposure intervention. The predicted reduction in risk in the remediation scenario is not an equitable one—that is, it is not uniform to all individuals within a population and varies according to the level of uncertainty in prediction. The importance of understanding the detailed hydrogeologic connections that are established in the heterogeneous geologic regime between the contaminated source, municipal receptors, and remediation wells, and its relationship to this uncertainty is demonstrated. Using two alternative pumping rates, we develop cost-benefit curves based upon reduced exposure and risk to different individuals within the population, under the presence of uncertainty.  相似文献   

2.
Industrially sourced dense non-aqueous phase liquids (DNAPLs) contaminated an alluvial aquifer in France decades ago. The location(s) and nature of the pollution source zone(s) were unknown, and the dissolved concentrations of volatile organic compounds in the monitoring wells varied greatly with time. The aquifer was in hydraulic equilibrium with an artificial canal whose water level was highly variable (up to 5 m). These variations propagated into the aquifer, causing changes in the groundwater flow direction; a transient numerical model of flow and solute transport showed that they correlate with the concentration variations because the changes in the flow direction resulted in the contaminant plume shifting. The transient hydrogeological numerical model was built, taking into account solvent biodegradation with first-order chain, since biodegradation has a significant influence on the pollutant concentration evolution. The model parameterization confirms the position of the source zones among the potential troughs in the bedrock where DNAPLs could have accumulated. The groundwater model was successfully calibrated to reproduce the observed concentration variations over several years and allowed a rapid validation of the hypotheses on the functioning of the polluted system.  相似文献   

3.
Groundwater chemistry and tracer-based age data were used to assess contaminant movement and geochemical processes in the middle Claiborne aquifer (MCA) of the Mississippi embayment aquifer system. Water samples were collected from 30 drinking-water wells (mostly domestic and public supply) and analyzed for nutrients, major ions, pesticides, volatile organic compounds (VOCs), and transient age tracers (chlorofluorocarbons, tritium and helium-3, and sulfur hexafluoride). Redox conditions are highly variable throughout the MCA. However, mostly oxic groundwater with low dissolved solids is more vulnerable to nitrate contamination in the outcrop areas east of the Mississippi River in Mississippi and west Tennessee than in mostly anoxic groundwater in downgradient areas in western parts of the study area. Groundwater in the outcrop area was relatively young (apparent age of less than 40 years) with significantly (p < 0.05) higher dissolved oxygen and nitrate–N concentrations and higher detections of pesticides and VOCs compared to water samples from wells in downgradient areas. Oxygen reduction and denitrification rates were low compared to other aquifers in the United States (zero order rate constants for oxygen reduction and denitrification were 4.7 and 5–10 μmol/L/year, respectively). Elevated concentrations of nitrate–N, and detections of pesticides and VOCs in some deep public supply wells (>50 m depth) indicated contaminant movement from shallow parts of the aquifer into deeper oxic zones. Given the persistence of nitrate in young oxic groundwater that was recharged several decades ago, and the lack of a confining unit, the downward movement of young contaminated water may result in higher nitrate concentrations over time in deeper parts of the aquifer containing older oxic water.  相似文献   

4.
Temporal monitoring of the pesticide 1,2-dibromo-3-chloropropane (DBCP) and nitrate and indicators of mean groundwater age were used to evaluate the transport and fate of agricultural chemicals in groundwater and to predict the long-term effects in the regional aquifer system in the eastern San Joaquin Valley, California. Twenty monitoring wells were installed on a transect along an approximate groundwater flow path. Concentrations of DBCP and nitrate in the wells were compared to concentrations in regional areal monitoring networks. DBCP persists at concentrations above the US Environmental Protection Agency’s maximum contaminant level (MCL) at depths of nearly 40 m below the water table, more than 25 years after it was banned. Nitrate concentrations above the MCL reached depths of more than 20 m below the water table. Because of the intensive pumping and irrigation recharge, vertical flow paths are dominant. High concentrations (above MCLs) in the shallow part of the regional aquifer system will likely move deeper in the system, affecting both domestic and public-supply wells. The large fraction of old water (unaffected by agricultural chemicals) in deep monitoring wells suggests that it could take decades for concentrations to reach MCLs in deep, long-screened public-supply wells, however.  相似文献   

5.
A tanker truck overturned releasing about 11,350 l of aviation fuel. As two municipal supply wells were within about 396 m of the release, contaminated soil was excavated and an assessment of hydrologic conditions was completed. A recovery well (RW) and five monitoring wells were installed. Ground-water samples were collected periodically from these wells and the municipal supply wells for analysis for volatile organic compounds. Pumping tests were completed on the RW and one municipal supply well. The results of the pumping test on the RWs were used to design a remediation system to remove jet fuel components from the ground water. The pumping tests also demonstrated that there was a ground-water divide separating the spill site from the municipal supply wells. After about 7 months of remediation, samples from the RW and municipal supply wells were clean and the state issued a clean closure.  相似文献   

6.
Monitoring of municipal wells near the town of Sidney and domestic wells near Oshkosh in Nebraska's Panhandle indicated the nitrate-nitrogen (NO3-N) levels were increasing and exceeded the maximum contaminant level of 10 mg/l NO3-N in several wells. Both areas are located in narrow stream valleys that are characterized by well-drained soils, highly permeable intermediate vadose zones, shallow depths to groundwater, and intensive irrigated corn production. Both areas also have a large confined cattle feeding operation near the suspected contamination and potentially could be contaminated by more than on nitrate source.At Sidney NO3-N concentrations were measured in 13 monitoring wells installed along an east-west transect im the direction of groundwater flow, 26 private wells, and eight municipal wells. Nitrate-nitrogen concentrations were homogeneous beneath a 5 km by 1.2 km area and averaged 11.3 ± 1.8 mg/l NO3-N. The δ15N-NO3 values in the monitoring and municipal wells had a narrow range from +5.8 to +8.8%. The isotopic ratios are indicative of a mixed source of nitrate contamination, which originates from agronomic (commercial fertilizer N and mineralized N) N and animal waste. Both commercial fertilizer N and animal wastes are applied to the irrigated fields.Nitrate-nitrogen concentrations in two multilevel samplers installed downgradient from irrigated cornfields at the Oshkosh site averaged 20.1 ± 13.3 mg/l NO3-N and 37.3 ± 8.2 mg/l NO3-N. The δ15N-NO3 values spanned a narrow range from +3.5 to +5.9% and averaged +4.0 ± 0.5% and +5.0 ± 0.6%. These low values are indicative of leachates from commercial fertilizer applied to the irrigated fields.  相似文献   

7.
The Gavbast karstic aquifer located in southern Iran is in direct contact with an exposed salt diapir. To assess the influence of the diapir on the quality of groundwater in the karstic aquifer, electrical conductivity, total dissolved solids, flow rate, temperature and major ion concentrations were measured at 57 sampling sites, including springs, surface waters and wells. A conceptual model of groundwater flow is proposed for the Gavbast karstic aquifer based on the geological setting, water budget, local base of erosion, and hydrochemistry of the sampling sites. The model suggests two subbasins in the Gavbast Anticline draining into two distinct discharging alluvial sections. Unexpectedly, groundwater discharging from the carbonate Gavbast aquifer is saline or brackish and water is of chloride type. The study indicates that the source of salinity of the Gavbast aquifers is infiltration of surface diapir-derived brine into the aquifer. The contribution of the diapir brine in the Gavbast karst aquifer is calculated about 4 L/s, using chloride mass balance. Construction of salt basins to evaporate brine discharging from the diapir springs is proposed to reduce the salinity of karst water. A row of strategically placed wells in the Gavbast karst aquifer would potentially exploit large volumes of fresh groundwater before it is contaminated by the salt. Such low-cost remediation should allow the agricultural exploitation of 40 km2 of currently barren land.  相似文献   

8.
Determination of total petroleum hydrocarbon distribution (TPH) in groundwater of Dezful aquifer was the main purpose of this study. The study area, which is located between latitudes 32°00′ and 32°35′?N and longitudes 48°10′ and 49°35′?E, covers about 1,920 km2 in the north of Khuzestan Province, Iran. Hydrocarbon pollutants in the area were being released into the aquifer, from a variety of sources. An oil pipe crash accident, which occurred on 19 Feb. 2009 in the vicinity of the northern part of the study area, released about 6,000 barrels of crude oil to the Karkhe River. Other possible sources of TPH in the region are asphalt factories, gas stations, and the Sabzab oil pump station. Since the main source of drinking water in the Dezful area is groundwater reservoirs, this study would be very crucial, especially when there is considerable agricultural activity in the area as well. In order to determine the presence of TPH and heavy metals in the groundwater, samples were taken from wells with different usage within two periods, i.e., in Nov. 2008 and May 2009. The second sampling operation was carried out to determine the effect of the accident in the water resources. In situ groundwater parameter measurements including pH, dissolved oxygen, temperature, and electrical conductivity were also carried out in the field. Based on the results, there are four zones in the study area which were contaminated with TPH from different origins: (1) southeast of Dezful City, which was contaminated by Shokati gas station; (2) southeast of Shush City, which was contaminated by an asphalt factory; (3) southwest of Dezful City, which was contaminated by Sabzab oil pump station; and (4) the shores of Karkhe River which were contaminated due to the pipeline crash accident. This could be a serious threat to the environment and human health because TPH concentration was higher than the EPA standard in the study area. Heavy metals were not distributed in a uniform pattern in the aquifer. The concentrations were lower than the contamination level based on the EPA drinking standard, and there was no meaningful relation between concentrations of TPH and the heavy metals. It was recommended that a monitoring network should be designed to monitor oil contaminants in the ground and surface water monthly because of importance of the water resources and presence of potential oil contaminant sources.  相似文献   

9.
The Corallian limestone of northern England (UK) is widely exploited for water supplies and exhibits the karstic phenomena of sinking rivers, conduit development and groundwater velocities of several kilometres per day. To test a number of model-derived source protection zones and elucidate contaminant transport mechanisms in the aquifer, three tracer tests were conducted from a set of swallow-holes draining the River Derwent toward public water supply wells in the eastern part of the aquifer. Tracers used included: Enterobacter cloacae (bacteriophage), Photine C (optical brightener), sodium fluorescein (fluorescent dye) and sulphur hexafluoride (dissolved gas), the varying properties of which make them suitable analogues for different types of potential contaminant. Observed tracer transport times and arrival patterns indicate that tracer transport occurs through karstic channels embedded in a network of primary fissures which exert control over tracer concentrations once initial tracer plumes have passed. A dipole flow system is observed between the swallow-holes and the closest abstraction well, whilst previously modelled source protection zones do not accurately reflect either groundwater velocity or those areas of the aquifer supplying the wells. These findings imply that managing such aquifers for potential contamination should rely upon empirical tracer evidence for source-protection zone modelling.  相似文献   

10.
Numerical groundwater flow and contaminant transport modeling incorporating three alternative conceptual models was conducted in 2005 to assess remedial actions and predict contaminant concentrations in an unconfined glacial aquifer located in Milford, Michigan, USA. Three alternative conceptual models were constructed and independently calibrated to evaluate uncertainty in the geometry of an aquitard underlying the aquifer and the extent to which infiltration from two manmade surface water bodies influenced the groundwater flow field. Contaminant transport for benzene, cis-DCE, and MTBE was modeled for a 5-year period that included a 2-year history match from July 2003 to May 2005 and predictions for a 3-year period ending in July 2008. A postaudit of model performance indicates that predictions for pumping wells, which integrated the transport signal across multiple model layers, were reliable but unable to differentiate between alternative conceptual model responses. In contrast, predictions for individual monitoring wells with limited screened intervals were less consistent, but held promise for evaluating alternative hydrogeologic models. Results of this study suggest that model conceptualization can have important practical implications for the delineation of contaminant transport pathways using monitoring wells, but may exert less influence on integrated predictions for pumping wells screened over multiple numerical model layers.  相似文献   

11.
This paper presents results from a site characterization and monitoring study at Karaduvar area (Mersin, SE Turkey), where high concentrations of refined petroleum products have been detected in domestic and irrigation water wells. The saturated and unsaturated zones in the deltaic aquifer are contaminated by large quantities of gasoline and diesel range fuel hydrocarbons (GRHs and DRHs) released from diverse sources that include accidental spills, storage tank fires, pipeline breaks, deliberate discharge of waste petroleum products from slop tanks and illegal tanker truck washing facilities. At the site, due to the complex nature of the pollution sources, overlapping contaminant plumes exist and cover an area of about 0.5 km2. In both polluted and unpolluted parts of the aquifer, monitoring of groundwater physicochemical parameters in a total of 55 sampling points was carried out between 2006 and 2007. The results show that the terminal electron acceptors (e.g. dissolved oxygen, nitrate, Mn(IV), Fe(III), sulfate) were reduced near the source area(s) indicating presence of actively operating biodegradation processes at the site. Close to the contaminant source area(s), conditions in the plume are highly anoxic and reducing; where high amounts of transformation products (e.g. bicarbonate, dissolved iron, and manganese) are present in solution. Additionally, at the site, excessive pumping, careless land use, and deliberate wastewater discharges significantly deteriorated the quality and quantity of groundwater. Excessive groundwater pumping for industrial and agricultural uses has resulted in substantial water level declines (2–3 m) near the coastal part where seawater intrusion threatens the groundwater resources.  相似文献   

12.
《Applied Geochemistry》2006,21(1):83-97
Groundwater in the Gwelup groundwater management area in Perth, Western Australia has been enriched in As due to the exposure of pyritic sediments caused by reduced rainfall, increased groundwater abstraction for irrigation and water supply, and prolonged dewatering carried out during urban construction activities. Groundwater near the watertable in a 25–60 m thick unconfined sandy aquifer has become acidic and has affected shallow wells used for garden irrigation. Arsenic concentrations up to 7000 μg/L were measured in shallow groundwater, triggering concerns about possible health effects if residents were to use water from household wells as a drinking water source. Deep production wells used for public water supply are not affected by acidity, but trends of progressively increasing concentrations of Fe, SO4 and Ca over a 30-a period indicate that pyrite oxidation products extend to the base of the unconfined aquifer. Falling Eh values are triggering the release of As from the reduction of Fe(III) oxyhydroxide minerals near the base of the unconfined aquifer, increasing the risk that groundwater used as a drinking water source will also become contaminated with high concentrations of As.  相似文献   

13.
The Guadalupe Valley aquifer is the only water source for one of the most important wine industries in Mexico, and also the main public water supply for the nearby city of Ensenada. This groundwater is monitored for major ion, N-NO3, P-PO4, Fe, As, Se, Mo, Cd, Cu, Pb, Zn and Sb concentrations, as well as TDS, pH, dissolved oxygen and temperature. High concentrations of N-NO3 (26 mg l−1), Se (70 μg l−1), Mo (18 μg l−1) and Cu (4.3 μg l−1) suggest that groundwater is being polluted by the use of fertilizers only in the western section of the aquifer, known as El Porvenir graben. Unlike the sites located near the main recharge area to the East of the aquifer, the water in El Porvenir graben has low tritium concentrations (<1.9 TU), indicating a pre-modern age, and thus longer water residence time. No significant variations in water quality (generally <10%) were detected throughout 2001–2002 in the aquifer, suggesting that reduced rainfall and recharge during this dry period did not significantly affect water quality. However, the wells nearest to the main recharge area in the Eastern aquifer show a slight but constant increase in TDS with time, probably as a result of the high (∼200 L S−1) uninterrupted extraction of water at this specific recharge site. Relatively high As concentrations for the aquifer (10.5 μg l−1) are only found near the northern limit of the basin associated with a geological fault.  相似文献   

14.
The combined effects of low rainfall, groundwater withdrawal in excess of 300 GL/year and reduced recharge in areas covered by pine plantations has caused the water table in a sandy unconfined aquifer on the Gnangara Mound in Western Australia to drop by up to 5 m and aquifer storage to decline by about 500 GL over the last 20 years. Groundwater has become acidic in areas of high drawdown, with pH values typically being less than 5.0 at the water table, and elevated concentrations of SO4 2?, Al, Fe, Zn, Cu, Ni and Pb. Trends of increasing acidity and base cation concentrations in deep water supply wells in the Mirrabooka wellfield indicate that about 0.7 keq/ha/year of base cations are being leached from soil within cones of depression of pumping wells. These results indicate that the assessment of the sustainable yields of aquifers under conditions of low rainfall needs to consider geochemical interactions between groundwater, aquifer sediments, soils and vegetation, and not be just based on aquifer hydraulics and water-balance changes.  相似文献   

15.
Wells along two regional flow paths were sampled to characterize changes in water quality and the vulnerability to contamination of the Memphis aquifer across a range of hydrologic and land-use conditions in the southeastern United States. The flow paths begin in the aquifer outcrop area and end at public supply wells in the confined parts of the aquifer at Memphis, Tennessee. Age-date tracer (e.g. SF6, 3H, 14C) data indicate that a component of young water is present in the aquifer at most locations along both flow paths, which is consistent with previous studies at Memphis that documented leakage of shallow water into the Memphis aquifer locally where the overlying confining unit is thin or absent. Mixtures of young and old water were most prevalent where long-term pumping for public supply has lowered groundwater levels and induced downward movement of young water. The occurrence of nitrate, chloride and synthetic organic compounds was correlated to the fraction of young water along the flow paths. Oxic conditions persisted for 10 km or more down dip of the confining unit, and the presence of young water in confined parts of the aquifer suggest that contaminants such as nitrate-N have the potential for transport. Long-term monitoring data for one of the flow-path wells screened in the confined part of the aquifer suggest that the vulnerability of the aquifer as indicated by the fraction of young water is increasing over time.  相似文献   

16.
Dissolved benzene was detected in the shallow unconfined Liwa aquifer, UAE, which represents the main freshwater source for the nearby residence Bu Hasa camp area. The main source of this contamination is believed to be the rejected water released from Bu Hasa liquid recovery plant. In this paper, a finite element model (METABIOTRANS) is used to simulate the fate and transport of the dissolved benzene plume in Liwa aquifer. Different remediation scenarios were simulated in which the slow-release oxygen source (SOS) technique is utilized to minimize benzene concentrations at the nearest camp supply wells downstream of the contamination zone. Results of the remediation scenarios show that the highest biodegradation rates occur when the oxygen source is placed near the plume center; where higher benzene concentrations exist. The nearest oxygen release source to the contamination zone caused higher stimulation to bacterial growth than further down-gradient oxygen sources. It also exhibited longer resident time of oxygen in the aquifer; and therefore, yielded higher reductions in benzene concentrations. However, using one central SOS proved to be insufficient as contaminant escaped laterally. Additional four transverse oxygen sources were necessary to capture benzene that laterally spread away from the contamination zone. These lateral SOSs were essential to reduce benzene concentrations at the supply wells that are located at the plume fringes. Finally, it was found that increasing oxygen release from one source did not always improve remediation; and that using several SOSs with lower release rates could be a more practical approach to enhance benzene biodegradation in the aquifer.  相似文献   

17.
Airports are potential, and quite frequently also actual, sources of serious groundwater pollution. This is due to the large amounts of liquid fuel being handled all the time, to the physicochemical properties of oil hydrocarbons, and often to technical errors in the transport and storage of fuels. The environment is further affected by liquid and gaseous emissions escaping during the take-off and landing of aircraft Snow in the vicinity of runways has been found to contain oil hydrocarbons in concentrations of tenths to units of milligrams per liter Moreover, soil tends to accumulate carcinogenous benzopyrenes. In rock formations, oil hydrocarbons spread as a separate layer as well as in solution in porous permeable formations, pollution by a free product affects areas on the order of tens of meters, while hydrocarbons in solution penetrate to distances of hundreds of meters or even kilometers. More complex conditions for the spreading of oil-based substances arise in fissured rocks. Aviation kerosene as a separate phase was found to migrate over 700 meters within 5 months through fissure systems in sandstones Prevention is the most efficient way of protecting groundwater from oil pollution. Preventive surveys are based on the drilling of observation wells at suitable points of the potentially endangered areas. Monitoring of these wells provides timely detection of possible leaks of oil products into the aquifer In the case of an emergency, it is necessary to remove, as soon as possible, the oil substances from the surface or to remove the contaminated soil. When the contaminant has penetrated into the aquifer, the reparatory measures are usually based on hydraulic protection which consists of a system of boreholes. The respective hydrocarbon product is removed from the formation by pumping, the process being speeded up by the change in groundwater flow caused by the creation of depression cones The example of Prague Airport is suitable for describing a successful, although complex and expensive, purification of a Chalk aquiter polluted among other things by a leak amounting to 300 m3 of aviation kerosene. Vapex filters have proven very satisfactory for purifying the contaminated water Preventive protection of groundwater and mineral waters using monitoring devices is being carried out at Karlovy Vary Airport No groundwater pollution has so far been observed in this instance. However, a seasonal variation in the content of hydrocarbons dissolved in groundwater has been established. The highest content occurs in the spring months. Observation wells situated in the tectonic zone can also be utilized for reparative pumping  相似文献   

18.
This study provides a solution for groundwater contamination problems. High anthopogenic loading on the water intake area makes it difficult to predict the migration of a contaminant to water supply wells, despite the known source location. Predictions were made using finite-difference grid models. The study provides an evaluation of the effects of the aquifer heterogeneity on the simulation results.  相似文献   

19.
The Grombalia aquifer (NE Tunisia) is an example of an important source of water supply for regional and national development, where the weak controls over abstraction, fertilizer application and waste disposal, coupled with limited knowledge of aquifer dynamics, is causing aquifer over-exploitation and water quality degradation. Assessing the key role of groundwater in water-resources security is therefore of paramount importance to support new actions to preserve water quality and quantity in the long-run. This study presents one of the first investigations targeted at a complete assessment of aquifer dynamics in the Grombalia aquifer. A multi-tracer hydrogeochemical and isotopic (δ2H, δ18O and 3H) approach was used to study the influence of seasonal variation on piezometric levels, chemical and isotopic compositions, and groundwater recharge. A total of 116 samples were collected from private wells and boreholes during three periods in a 1 year monitoring campaign (February–March 2014, September 2014 and February 2015). Results revealed the overall unsuitability of groundwater for drinking and irrigation purposes (NO3?>?50 mg/L in 51% of the wells; EC >1,000 μS/cm in 99% of the wells). Isotopic balance coupled to piezometric investigation indicated the contribution of the shallow aquifer to deep groundwater recharge. The study also revealed the weakness of ‘business as usual’ management practices, highlighting possible solutions to tackle water-related challenges in the Grombalia region, where climate change, population growth and intensive agricultural activities have generated a large gap between demand and available water reserves, hence becoming a possible driver for social insecurity.  相似文献   

20.
About 40% of the water supply of Cairo, Egypt, is drawn from a groundwater reservoir located southeast of the Nile Delta. Several thousand shallow wells supply drinking water to the farmers from the same groundwater reservoir, which is recharged by seepage from Ismailia canal, the irrigation canal network, and other wastewater lagoons in the same areas. Sewage water lagoons were located at the high ground of the area, recharging contaminated water into the aquifer. Since the groundwater in this area is used for drinking purposes, it was decided to treat the sewage water recharging the aquifer for health reasons. In this paper a solution to the problem is presented using an injection well recharging good quality water into the aquifer. A pumping well located at a distance downstream is used to pump the contaminated water out of the aquifer. A three-dimensional solute transport model was developed to study the concentration distribution with remediation time in the contaminated zone.  相似文献   

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